Amino Acids Kit, Part Number 5063-6588

Hazard statements (CLP)

H225, H290, H302, H302+H312+H332, H312, H314, H315, H317, H319, H332, H335, H360FD, H411

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]]

Product definition

Sarcosine Mono-constituent substance L-Trytophan Mono-constituent substance L-Norvaline Mono-constituent substance L-Glutamine Mono-constituent substance L-Asparagine Mono-constituent substance L-4-Hydroxyproline Mono-constituent substance 3,3′-Dithiodipropionic Mono-constituent substance Acid FMOC reagent 10 Mixture ampoules 1ml ea for AAA OPA reagent, 10 mg/ml, Mixture 6 ampoules AA, std 10pmol 10/PK Mixture AA, std 25pmol 10/PK Mixture AA, standard 100PMOL Mixture 10/PK td 1nmol 10/PK Mixture AA, standard 250PMOL Mixture 10/PK

CLP CLASSIFICATION

3,3′-Dithiodipropionic Acid H315 SKIN CORROSION/IRRITATION Category 2 H319 SERIOUS EYE DAMAGE/EYE IRRITATION Category 2 H335 SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE Category 3 (Respiratory tract irritation) FMOC reagent 10 ampoules 1ml ea for AAA H225 FLAMMABLE LIQUIDS Category 2 H302 ACUTE TOXICITY (oral) Category 4 H312 ACUTE TOXICITY (dermal) Category 4 H332 ACUTE TOXICITY (inhalation) Category 4 H319 SERIOUS EYE DAMAGE/EYE IRRITATION Category 2 OPA reagent, 10 mg/ ml, 6 ampoules H290 CORROSIVE TO METALS Category 1 H302 ACUTE TOXICITY (oral) Category 4 H314 SKIN CORROSION/IRRITATION Category 1A H317 SKIN SENSITISATION Category 1 H360FD REPRODUCTIVE TOXICITY Category 1B H411 LONG-TERM (CHRONIC) AQUATIC HAZARD Category 2 AA, std 10pmol 10/PK H290 CORROSIVE TO METALS Category 1 AA, std 25pmol 10/PK H290 CORROSIVE TO METALS Category 1 AA, standard 100PMOL 10/PK H290 CORROSIVE TO METALS Category 1 td 1nmol 10/PK H290 CORROSIVE TO METALS Category 1 AA, standard 250PMOL 10/PK H290 CORROSIVE TO METALS Category 1 Ingredients of unknown : OPA reagent, 10 mg/ml, 6 Percentage of the mixture consisting of ingredient(s) of toxicity ampoules unknown acute dermal toxicity: 1 - 10% Percentage of the mixture consisting of ingredient(s) of unknown acute inhalation toxicity: 1 - 10% See Section 16 for the full text of the H statements declared above. See Section 11 for more detailed information on health effects and symptoms.

Hazard pictograms

3,3′-Dithiodipropionic Acid FMOC reagent 10 ampoules 1ml ea for AAA OPA reagent, 10 mg/ml, 6 ampoules AA, std 10pmol 10/PK AA, std 25pmol 10/PK AA, standard 100PMOL 10/PK td 1nmol 10/PK AA, standard 250PMOL 10/PK

Signal word

Sarcosine No signal word. L-Trytophan No signal word. L-Norvaline No signal word. L-Glutamine No signal word. L-Asparagine No signal word. L-4-Hydroxyproline No signal word. 3,3′-Dithiodipropionic Warning Acid FMOC reagent 10 Danger ampoules 1ml ea for AAA OPA reagent, 10 mg/ml, Danger 6 ampoules AA, std 10pmol 10/PK Warning AA, std 25pmol 10/PK Warning AA, standard 100PMOL Warning 10/PK td 1nmol 10/PK Warning AA, standard 250PMOL Warning 10/PK

Hazard statements

Sarcosine No known significant effects or critical hazards. L-Trytophan No known significant effects or critical hazards. L-Norvaline No known significant effects or critical hazards. L-Glutamine No known significant effects or critical hazards. L-Asparagine No known significant effects or critical hazards. L-4-Hydroxyproline No known significant effects or critical hazards. 3,3′-Dithiodipropionic H315 - Causes skin irritation. Acid H319 - Causes serious eye irritation. H335 - May cause respiratory irritation. FMOC reagent 10 H225 - Highly flammable liquid and vapour. ampoules 1ml ea for AAA H302 + H312 + H332 - Harmful if swallowed, in contact with skin or if inhaled. H319 - Causes serious eye irritation. OPA reagent, 10 mg/ml, H290 - May be corrosive to metals. 6 ampoules H302 - Harmful if swallowed. H314 - Causes severe skin burns and eye damage. H317 - May cause an allergic skin reaction. H360FD - May damage fertility. May damage the unborn child. H411 - Toxic to aquatic life with long lasting effects. AA, std 10pmol 10/PK H290 - May be corrosive to metals. AA, std 25pmol 10/PK H290 - May be corrosive to metals. AA, standard 100PMOL H290 - May be corrosive to metals. 10/PK td 1nmol 10/PK H290 - May be corrosive to metals. AA, standard 250PMOL H290 - May be corrosive to metals. 10/PK

Prevention

Sarcosine Not applicable. L-Trytophan Not applicable. L-Norvaline Not applicable. L-Glutamine Not applicable. L-Asparagine Not applicable. L-4-Hydroxyproline Not applicable. 3,3′-Dithiodipropionic P280 - Wear protective gloves. Wear eye or face protection. Acid P261 - Avoid breathing dust or mist. P264 - Wash thoroughly after handling. FMOC reagent 10 P280 - Wear protective gloves and protective clothing. Wear ampoules 1ml ea for AAA eye or face protection. P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P261 - Avoid breathing vapour. P270 - Do not eat, drink or smoke when using this product. OPA reagent, 10 mg/ml, P201 - Obtain special instructions before use. 6 ampoules P280 - Wear protective gloves, protective clothing and eye or face protection. P273 - Avoid release to the environment. AA, std 10pmol 10/PK P234 - Keep only in original packaging. AA, std 25pmol 10/PK P234 - Keep only in original packaging. AA, standard 100PMOL P234 - Keep only in original packaging. 10/PK td 1nmol 10/PK P234 - Keep only in original packaging. AA, standard 250PMOL P234 - Keep only in original packaging. 10/PK

Response

Sarcosine Not applicable. L-Trytophan Not applicable. L-Norvaline Not applicable. L-Glutamine Not applicable. L-Asparagine Not applicable. L-4-Hydroxyproline Not applicable. 3,3′-Dithiodipropionic P304 + P312 - IF INHALED: Call a POISON CENTER or Acid doctor if you feel unwell. FMOC reagent 10 P304 + P312 - IF INHALED: Call a POISON CENTER or ampoules 1ml ea for AAA doctor if you feel unwell. OPA reagent, 10 mg/ml, P391 - Collect spillage. 6 ampoules P308 + P313 - IF exposed or concerned: Get medical advice or attention. AA, std 10pmol 10/PK P390 - Absorb spillage to prevent material damage. AA, std 25pmol 10/PK P390 - Absorb spillage to prevent material damage. AA, standard 100PMOL P390 - Absorb spillage to prevent material damage. 10/PK td 1nmol 10/PK P390 - Absorb spillage to prevent material damage. AA, standard 250PMOL P390 - Absorb spillage to prevent material damage. 10/PK

Storage

Sarcosine Not applicable. L-Trytophan Not applicable. L-Norvaline Not applicable. L-Glutamine Not applicable. L-Asparagine Not applicable. L-4-Hydroxyproline Not applicable. 3,3′-Dithiodipropionic P403 + P233 - Store in a well-ventilated place. Keep Acid container tightly closed. FMOC reagent 10 Not applicable. ampoules 1ml ea for AAA OPA reagent, 10 mg/ml, Not applicable. 6 ampoules AA, std 10pmol 10/PK Not applicable. AA, std 25pmol 10/PK Not applicable. AA, standard 100PMOL Not applicable. 10/PK td 1nmol 10/PK Not applicable. AA, standard 250PMOL Not applicable. 10/PK

Disposal

Sarcosine Not applicable. L-Trytophan Not applicable. L-Norvaline Not applicable. L-Glutamine Not applicable. L-Asparagine Not applicable. L-4-Hydroxyproline Not applicable. 3,3′-Dithiodipropionic P501 - Dispose of contents and container in accordance with Acid all local, regional, national and international regulations. FMOC reagent 10 P501 - Dispose of contents and container in accordance with ampoules 1ml ea for AAA all local, regional, national and international regulations. OPA reagent, 10 mg/ml, P501 - Dispose of contents and container in accordance with 6 ampoules all local, regional, national and international regulations. AA, std 10pmol 10/PK Not applicable. AA, std 25pmol 10/PK Not applicable. AA, standard 100PMOL Not applicable. 10/PK td 1nmol 10/PK Not applicable. AA, standard 250PMOL Not applicable. 10/PK

Supplemental label elements

Sarcosine Not applicable. elements L-Trytophan Not applicable. L-Norvaline Not applicable. L-Glutamine Not applicable. L-Asparagine Not applicable. L-4-Hydroxyproline Not applicable. 3,3′-Dithiodipropionic Not applicable. Acid FMOC reagent 10 Not applicable. ampoules 1ml ea for AAA OPA reagent, 10 mg/ml, Contains isocyanates. May produce an allergic reaction. 6 ampoules AA, std 10pmol 10/PK Not applicable. AA, std 25pmol 10/PK Not applicable. AA, standard 100PMOL Not applicable. 10/PK td 1nmol 10/PK Not applicable. AA, standard 250PMOL Not applicable. 10/PK Annex XVII - Restrictions : Sarcosine Not applicable. on the manufacture, L-Trytophan Not applicable. placing on the market L-Norvaline Not applicable. and use of certain L-Glutamine Not applicable. dangerous substances, L-Asparagine Not applicable. mixtures and articles L-4-Hydroxyproline Not applicable. 3,3′-Dithiodipropionic Not applicable. Acid FMOC reagent 10 Not applicable. ampoules 1ml ea for AAA OPA reagent, 10 mg/ml, Restricted to professional users. 6 ampoules AA, std 10pmol 10/PK Not applicable. AA, std 25pmol 10/PK Not applicable. AA, standard 100PMOL Not applicable. 10/PK td 1nmol 10/PK Not applicable. AA, standard 250PMOL Not applicable. 10/PK

Special packaging requirements

Containers to be fitted Sarcosine Not applicable. with child-resistant L-Trytophan Not applicable. fastenings L-Norvaline Not applicable. L-Glutamine Not applicable. L-Asparagine Not applicable. L-4-Hydroxyproline Not applicable. 3,3′-Dithiodipropionic Not applicable. Acid FMOC reagent 10 Not applicable. ampoules 1ml ea for AAA OPA reagent, 10 mg/ml, Not applicable. 6 ampoules AA, std 10pmol 10/PK Not applicable. AA, std 25pmol 10/PK Not applicable. AA, standard 100PMOL Not applicable. 10/PK td 1nmol 10/PK Not applicable. AA, standard 250PMOL Not applicable. 10/PK Tactile warning of Sarcosine Not applicable. danger L-Trytophan Not applicable. L-Norvaline Not applicable. L-Glutamine Not applicable. L-Asparagine Not applicable. L-4-Hydroxyproline Not applicable. 3,3′-Dithiodipropionic Not applicable. Acid FMOC reagent 10 Not applicable. ampoules 1ml ea for AAA OPA reagent, 10 mg/ml, Not applicable. 6 ampoules AA, std 10pmol 10/PK Not applicable. AA, std 25pmol 10/PK Not applicable. AA, standard 100PMOL Not applicable. 10/PK td 1nmol 10/PK Not applicable. AA, standard 250PMOL Not applicable. 10/PK

2.3 Other hazards

Product meets the

PBT Substances

P B T

vPvB Substances

vP vB criteria for PBT or vPvB according to Regulation Sarcosine (EC) No. 1907/2006, N/A Annex XIII L-Trytophan No N/A No N/A L-Norvaline N/A L-Glutamine No N/A No N/A L-Asparagine No N/A No N/A L- 4-Hydroxyproline No N/A No N/A 3,3′- Dithiodipropionic Acid No N/A No N/A FMOC reagent 10 This mixture does not contain any substances that are ampoules 1ml ea for AAA assessed to be a PBT or a vPvB. OPA reagent, 10 mg/ml, This mixture does not contain any substances that are 6 ampoules assessed to be a PBT or a vPvB. AA, std 10pmol 10/PK This mixture does not contain any substances that are assessed to be a PBT or a vPvB. AA, std 25pmol 10/PK This mixture does not contain any substances that are assessed to be a PBT or a vPvB. AA, standard 100PMOL This mixture does not contain any substances that are 10/PK assessed to be a PBT or a vPvB. td 1nmol 10/PK This mixture does not contain any substances that are assessed to be a PBT or a vPvB. AA, standard 250PMOL This mixture does not contain any substances that are 10/PK assessed to be a PBT or a vPvB. Other hazards which do : Sarcosine May form combustible dust concentrations in air. not result in L-Trytophan May form combustible dust concentrations in air.

Classifications

L-Norvaline May form combustible dust concentrations in air. L-Glutamine May form combustible dust concentrations in air. L-Asparagine May form combustible dust concentrations in air. L-4-Hydroxyproline May form combustible dust concentrations in air. 3,3′-Dithiodipropionic May form combustible dust concentrations in air. Acid FMOC reagent 10 None known. ampoules 1ml ea for AAA OPA reagent, 10 mg/ml, Causes severe digestive tract burns. 6 ampoules AA, std 10pmol 10/PK None known. AA, std 25pmol 10/PK None known. AA, standard 100PMOL None known. 10/PK td 1nmol 10/PK None known. AA, standard 250PMOL None known. 10/PK