OQ - PV Chemicals Standards Kit 1 : 5063-6503

Hazard statements (CLP)

H225, H290, H302, H304, H315, H315+H320, H320, H335, H336, H361, H371, H373, H400, H410, H411, H412

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

OSHA Hazards Classification of the substance or mixture

Hazard pictograms

nHexane Solvent Blank Potassium Dichromate Solution (600.6 mg/L) (60.06 mg/L) Toluene Solution (0.02%) Sodium Nitrite Solution (50 g/L)

Signal word

nHexane Solvent Blank Danger Potassium Dichromate Solution Warning (600.6 mg/L) (60.06 mg/L) Sulfuric Acid Solution (.01N) No signal word. Toluene Solution (0.02%) Danger Potassium Chloride Solution (12 g/ No signal word. L) Sodium Iodide Solution (10 g/L) No signal word. Sodium Nitrite Solution (50 g/L) Warning

Hazard statements

nHexane Solvent Blank H225 - Highly flammable liquid and vapor. H304 - May be fatal if swallowed and enters airways. H315 + H320 - Causes skin and eye irritation. H335 - May cause respiratory irritation. H336 - May cause drowsiness or dizziness. H361 - Suspected of damaging fertility or the unborn child. H373 - May cause damage to organs through prolonged or repeated exposure. (nervous system) (inhalation) H411 - Toxic to aquatic life with long lasting effects. Potassium Dichromate Solution H290 - May be corrosive to metals. (600.6 mg/L) (60.06 mg/L) Sulfuric Acid Solution (.01N) No known significant effects or critical hazards. Toluene Solution (0.02%) H225 - Highly flammable liquid and vapor. prolonged or repeated exposure. Potassium Chloride Solution (12 g/ No known significant effects or critical hazards.

Precautionary statements

L) Sodium Iodide Solution (10 g/L) H412 - Harmful to aquatic life with long lasting effects. Sodium Nitrite Solution (50 g/L) H302 - Harmful if swallowed. H371 - May cause damage to organs. H410 - Very toxic to aquatic life with long lasting

Prevention

nHexane Solvent Blank P201 - Obtain special instructions before use. P280 - Wear protective gloves, protective clothing and eye or face protection. P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P241 - Use explosion-proof electrical, ventilating or lighting equipment. P242 - Use non-sparking tools. P243 - Take action to prevent static discharges. P273 - Avoid release to the environment. P260 - Do not breathe vapor. P264 - Wash thoroughly after handling. Potassium Dichromate Solution P234 - Keep only in original packaging. (600.6 mg/L) (60.06 mg/L) Sulfuric Acid Solution (.01N) Not applicable. Toluene Solution (0.02%) P201 - Obtain special instructions before use. Potassium Chloride Solution (12 g/ Not applicable. L) Sodium Iodide Solution (10 g/L) P273 - Avoid release to the environment. Sodium Nitrite Solution (50 g/L) P273 - Avoid release to the environment. P260 - Do not breathe vapor. P270 - Do not eat, drink or smoke when using this product. P264 - Wash thoroughly after handling.

Response

nHexane Solvent Blank P391 - Collect spillage. P308 + P313 - IF exposed or concerned: Get medical advice or attention. P304 + P312 - IF INHALED: Call a POISON CENTER or doctor if you feel unwell. P301 + P310, P331 - IF SWALLOWED: Immediately call a POISON CENTER or doctor. Do NOT induce vomiting. P362 + P364 - Take off contaminated clothing and wash it before reuse. P302 + P352 - IF ON SKIN: Wash with plenty of water. P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 - If eye irritation persists: Get medical advice or attention. Potassium Dichromate Solution P390 - Absorb spillage to prevent material damage. (600.6 mg/L) (60.06 mg/L) Sulfuric Acid Solution (.01N) Not applicable. Toluene Solution (0.02%) P391 - Collect spillage. Potassium Chloride Solution (12 g/ Not applicable. L) Sodium Iodide Solution (10 g/L) Not applicable. Sodium Nitrite Solution (50 g/L) P391 - Collect spillage. P308 + P311 - IF exposed or concerned: Call a POISON CENTER or doctor.

Storage

nHexane Solvent Blank P403 + P233 - Store in a well-ventilated place. Keep container tightly closed. P403 + P235 - Keep cool. Potassium Dichromate Solution Not applicable. (600.6 mg/L) (60.06 mg/L) Sulfuric Acid Solution (.01N) Not applicable. Toluene Solution (0.02%) P403 + P233 - Store in a well-ventilated place. Potassium Chloride Solution (12 g/ Not applicable. L) Sodium Iodide Solution (10 g/L) Not applicable. Sodium Nitrite Solution (50 g/L) Not applicable.

Disposal

nHexane Solvent Blank P501 - Dispose of contents and container in accordance with all local, regional, national and international regulations. Potassium Dichromate Solution Not applicable. (600.6 mg/L) (60.06 mg/L) Sulfuric Acid Solution (.01N) Not applicable. Toluene Solution (0.02%) P501 - Dispose of contents and container in Potassium Chloride Solution (12 g/ Not applicable. L) Sodium Iodide Solution (10 g/L) P501 - Dispose of contents and container in accordance with all local, regional, national and international regulations. Sodium Nitrite Solution (50 g/L) P501 - Dispose of contents and container in

Supplemental label elements

nHexane Solvent Blank Eliminate sources of ignition. Avoid spark promoters. Ground/bond container and receiving equipment. These alone may be insufficient to remove static electricity. Potassium Dichromate Solution None known. (600.6 mg/L) (60.06 mg/L) Sulfuric Acid Solution (.01N) None known. Toluene Solution (0.02%) Eliminate sources of ignition. Avoid spark Potassium Chloride Solution (12 g/ None known.

2.3 Other hazards

L) Sodium Iodide Solution (10 g/L) None known. Sodium Nitrite Solution (50 g/L) None known. : nHexane Solvent Blank Static accumulating flammable liquid can become electrostatically charged even in bonded and grounded equipment. Sparks may ignite liquid and vapor may cause flash fire or explosion. Potassium Dichromate Solution None known. (600.6 mg/L) (60.06 mg/L) Sulfuric Acid Solution (.01N) None known. Toluene Solution (0.02%) Static accumulating flammable liquid can become Potassium Chloride Solution (12 g/ None known. L) Sodium Iodide Solution (10 g/L) None known. Sodium Nitrite Solution (50 g/L) None known.

2.1 Classification of the substance or mixture

OSHA/HCS status : nHexane Solvent Blank This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Potassium Dichromate This material is considered hazardous by the OSHA Solution (600.6 mg/L) Hazard Communication Standard (29 CFR 1910.1200). Potassium Dichromate This material is considered hazardous by the OSHA Solution (60.06 mg/L) Hazard Communication Standard (29 CFR 1910.1200). Sulfuric Acid Solution (.01N) While this material is not considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200), this SDS contains valuable information critical to the safe handling and proper use of the product. This SDS should be retained and available for employees and other users of this product. Toluene Solution (0.02%) This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Section 2. Hazards identification Potassium Chloride Solution While this material is not considered hazardous by the (12 g/L) OSHA Hazard Communication Standard (29 CFR 1910.1200), this SDS contains valuable information critical to the safe handling and proper use of the product. This SDS should be retained and available for employees and other users of this product. Sodium Iodide Solution (10 This material is considered hazardous by the OSHA g/L) Hazard Communication Standard (29 CFR 1910.1200). Sodium Nitrite Solution (50 This material is considered hazardous by the OSHA g/L) Hazard Communication Standard (29 CFR 1910.1200). Classification of the substance or mixture nHexane Solvent Blank H225 FLAMMABLE LIQUIDS - Category 2 H315 SKIN IRRITATION - Category 2 H320 EYE IRRITATION - Category 2B H361 TOXIC TO REPRODUCTION - Category 2 H335 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 H336 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 H373 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 H304 ASPIRATION HAZARD - Category 1 H411 AQUATIC HAZARD (LONG-TERM) - Category 2 Potassium Dichromate Solution (600.6 mg/L) H290 CORROSIVE TO METALS - Category 1 Potassium Dichromate Solution (60.06 mg/L) H290 CORROSIVE TO METALS - Category 1 Toluene Solution (0.02%) H225 FLAMMABLE LIQUIDS - Category 2 H315 SKIN IRRITATION - Category 2 H320 EYE IRRITATION - Category 2B H361 TOXIC TO REPRODUCTION - Category 2 H335 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 H336 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 H373 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 H304 ASPIRATION HAZARD - Category 1 H411 AQUATIC HAZARD (LONG-TERM) - Category 2 Sodium Iodide Solution (10 g/L) H412 AQUATIC HAZARD (LONG-TERM) - Category 3 Sodium Nitrite Solution (50 g/L) H302 ACUTE TOXICITY (oral) - Category 4 H371 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) - Category 2 H400 AQUATIC HAZARD (ACUTE) - Category 1 H410 AQUATIC HAZARD (LONG-TERM) - Category 1