ES-TOF Biopolymer Analysis Reference Mass Standards Kit, Part Number

Hazard statements (CLP)

H225, H302, H302+H312+H332, H312, H319, H332, H373

Code

Statements

H225

Highly Flammable liquid and vapour

2.1 Classification of the substance or mixture

OSHA/HCS status : 1.0 M Ammonium formate While this material is not considered hazardous by the in deionized, nanopure water OSHA Hazard Communication Standard (29 CFR 1910. 1200), this SDS contains valuable information critical to the safe handling and proper use of the product. This SDS should be retained and available for employees and other users of this product. 5mM Purine in Acetonitrile This material is considered hazardous by the OSHA Solution Hazard Communication Standard (29 CFR 1910.1200). 0.5 mM Tris(2,4, This material is considered hazardous by the OSHA 6-trifluoromethyl)-1,3,5 Hazard Communication Standard (29 CFR 1910.1200). triazine in acetonitrile 0.1 mM This material is considered hazardous by the OSHA Hexamethoxyphosphazine Hazard Communication Standard (29 CFR 1910.1200). in acetonitrile 0.2 mM Hexakis(1H,1H,4H- This material is considered hazardous by the OSHA hexafluorobutyloxy) Hazard Communication Standard (29 CFR 1910.1200). phosphazine in acetonitrile 0.2 mM Hexakis(1H,1H,6H- This material is considered hazardous by the OSHA decafluorohexyloxy) Hazard Communication Standard (29 CFR 1910.1200). phosphazine in acetonitrile 0.5 mM Hexakis(1H,1H,8H- This material is considered hazardous by the OSHA tetradecafluorooctyloxy) Hazard Communication Standard (29 CFR 1910.1200). phosphazine in acetonitrile 5mM Purine in Acetonitrile Solution H225 FLAMMABLE LIQUIDS - Category 2 H302 ACUTE TOXICITY (oral) - Category 4 H312 ACUTE TOXICITY (dermal) - Category 4 H332 ACUTE TOXICITY (inhalation) - Category 4 H319 EYE IRRITATION - Category 2A H373 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (blood system, central nervous system (CNS), kidneys, liver) - Category 2 0.5 mM Tris(2,4, 6-trifluoromethyl)-1,3,5 triazine in acetonitrile H225 FLAMMABLE LIQUIDS - Category 2 H302 ACUTE TOXICITY (oral) - Category 4 H312 ACUTE TOXICITY (dermal) - Category 4 H332 ACUTE TOXICITY (inhalation) - Category 4 H319 EYE IRRITATION - Category 2A H373 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (blood system, central nervous system (CNS), kidneys, liver) - Category 2 0.1 mM Hexamethoxyphosphazine in acetonitrile H225 FLAMMABLE LIQUIDS - Category 2 H302 ACUTE TOXICITY (oral) - Category 4 H312 ACUTE TOXICITY (dermal) - Category 4 H332 ACUTE TOXICITY (inhalation) - Category 4 H319 EYE IRRITATION - Category 2A H373 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (blood system, central nervous system (CNS), kidneys, liver) - Category 2 0.2 mM Hexakis(1H,1H,4H- hexafluorobutyloxy) phosphazine in acetonitrile H225 FLAMMABLE LIQUIDS - Category 2 H302 ACUTE TOXICITY (oral) - Category 4 H312 ACUTE TOXICITY (dermal) - Category 4 H332 ACUTE TOXICITY (inhalation) - Category 4 H319 EYE IRRITATION - Category 2A H373 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (blood system, central nervous system (CNS), kidneys, liver) - Category 2 0.2 mM Hexakis(1H,1H,6H- decafluorohexyloxy) phosphazine in acetonitrile H225 FLAMMABLE LIQUIDS - Category 2 H302 ACUTE TOXICITY (oral) - Category 4 H312 ACUTE TOXICITY (dermal) - Category 4 H332 ACUTE TOXICITY (inhalation) - Category 4 H319 EYE IRRITATION - Category 2A H373 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (blood system, central nervous system (CNS), kidneys, liver) - Category 2 0.5 mM Hexakis(1H,1H,8H- tetradecafluorooctyloxy) phosphazine in acetonitrile H225 FLAMMABLE LIQUIDS - Category 2 H302 ACUTE TOXICITY (oral) - Category 4 H312 ACUTE TOXICITY (dermal) - Category 4 H332 ACUTE TOXICITY (inhalation) - Category 4 H319 EYE IRRITATION - Category 2A H373 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (blood system, central nervous system (CNS), kidneys, liver) - Category 2 Ingredients of unknown 1.0 M Ammonium formate in Percentage of the mixture consisting of ingredient toxicity deionized, nanopure water (s) of unknown dermal toxicity: 1 - 10% Percentage of the mixture consisting of ingredient (s) of unknown inhalation toxicity: 1 - 10% Percentage of the mixture consisting of ingredient (s) of unknown oral toxicity: 1 - 10%

Hazard pictograms

5mM Purine in Acetonitrile Solution 0.5 mM Tris(2,4,6-trifluoromethyl) -1,3,5 triazine in acetonitrile 0.1 mM Hexamethoxyphosphazine in acetonitrile 0.2 mM Hexakis(1H,1H,4H- hexafluorobutyloxy)phosphazine in acetonitrile 0.2 mM Hexakis(1H,1H,6H- decafluorohexyloxy)phosphazine in acetonitrile 0.5 mM Hexakis(1H,1H,8H- tetradecafluorooctyloxy) phosphazine in acetonitrile

Signal word

1.0 M Ammonium formate in No signal word. deionized, nanopure water 5mM Purine in Acetonitrile Danger Solution 0.5 mM Tris(2,4,6-trifluoromethyl) Danger -1,3,5 triazine in acetonitrile 0.1 mM Hexamethoxyphosphazine Danger in acetonitrile 0.2 mM Hexakis(1H,1H,4H- Danger hexafluorobutyloxy)phosphazine in acetonitrile 0.2 mM Hexakis(1H,1H,6H- Danger decafluorohexyloxy)phosphazine in acetonitrile 0.5 mM Hexakis(1H,1H,8H- Danger tetradecafluorooctyloxy) phosphazine in acetonitrile

Hazard statements

1.0 M Ammonium formate in No known significant effects or critical hazards. deionized, nanopure water 5mM Purine in Acetonitrile H225 - Highly flammable liquid and vapor. Solution H302 + H312 + H332 - Harmful if swallowed, in contact with skin or if inhaled. H319 - Causes serious eye irritation. H373 - May cause damage to organs through prolonged or repeated exposure. (blood system, central nervous system (CNS), kidneys, liver) 0.5 mM Tris(2,4,6-trifluoromethyl) H225 - Highly flammable liquid and vapor. -1,3,5 triazine in acetonitrile H302 + H312 + H332 - Harmful if swallowed, in contact with skin or if inhaled. H319 - Causes serious eye irritation. H373 - May cause damage to organs through prolonged or repeated exposure. (blood system, central nervous system (CNS), kidneys, liver) 0.1 mM Hexamethoxyphosphazine H225 - Highly flammable liquid and vapor. in acetonitrile H302 + H312 + H332 - Harmful if swallowed, in contact with skin or if inhaled. H319 - Causes serious eye irritation. H373 - May cause damage to organs through prolonged or repeated exposure. (blood system, central nervous system (CNS), kidneys, liver) 0.2 mM Hexakis(1H,1H,4H- H225 - Highly flammable liquid and vapor. hexafluorobutyloxy)phosphazine in acetonitrile H302 + H312 + H332 - Harmful if swallowed, in contact with skin or if inhaled. H319 - Causes serious eye irritation. H373 - May cause damage to organs through prolonged or repeated exposure. (blood system, central nervous system (CNS), kidneys, liver) 0.2 mM Hexakis(1H,1H,6H- H225 - Highly flammable liquid and vapor. decafluorohexyloxy)phosphazine in acetonitrile H302 + H312 + H332 - Harmful if swallowed, in contact with skin or if inhaled. H319 - Causes serious eye irritation. H373 - May cause damage to organs through prolonged or repeated exposure. (blood system, central nervous system (CNS), kidneys, liver) 0.5 mM Hexakis(1H,1H,8H- H225 - Highly flammable liquid and vapor. tetradecafluorooctyloxy) phosphazine in acetonitrile H302 + H312 + H332 - Harmful if swallowed, in contact with skin or if inhaled. H319 - Causes serious eye irritation. H373 - May cause damage to organs through prolonged or repeated exposure. (blood system, central nervous system (CNS), kidneys, liver)

Prevention

1.0 M Ammonium formate in Not applicable. deionized, nanopure water 5mM Purine in Acetonitrile P280 - Wear protective gloves. Wear eye or face Solution protection. Wear protective clothing. P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P241 - Use explosion-proof electrical, ventilating, lighting and all material-handling equipment. P242 - Use only non-sparking tools. P243 - Take precautionary measures against static discharge. P233 - Keep container tightly closed. P271 - Use only outdoors or in a well-ventilated area. P260 - Do not breathe vapor. P270 - Do not eat, drink or smoke when using this product. P264 - Wash hands thoroughly after handling. 0.5 mM Tris(2,4,6-trifluoromethyl) P280 - Wear protective gloves. Wear eye or face -1,3,5 triazine in acetonitrile protection. Wear protective clothing. P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P241 - Use explosion-proof electrical, ventilating, lighting and all material-handling equipment. P242 - Use only non-sparking tools. P243 - Take precautionary measures against static discharge. P233 - Keep container tightly closed. P271 - Use only outdoors or in a well-ventilated area. P260 - Do not breathe vapor. P270 - Do not eat, drink or smoke when using this product. P264 - Wash hands thoroughly after handling. 0.1 mM Hexamethoxyphosphazine P280 - Wear protective gloves. Wear eye or face in acetonitrile protection. Wear protective clothing. P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P241 - Use explosion-proof electrical, ventilating, lighting and all material-handling equipment. P242 - Use only non-sparking tools. P243 - Take precautionary measures against static discharge. P233 - Keep container tightly closed. P271 - Use only outdoors or in a well-ventilated area. P260 - Do not breathe vapor. P270 - Do not eat, drink or smoke when using this product. P264 - Wash hands thoroughly after handling. 0.2 mM Hexakis(1H,1H,4H- P280 - Wear protective gloves. Wear eye or face hexafluorobutyloxy)phosphazine in protection. Wear protective clothing. acetonitrile P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P241 - Use explosion-proof electrical, ventilating, lighting and all material-handling equipment. P242 - Use only non-sparking tools. P243 - Take precautionary measures against static discharge. P233 - Keep container tightly closed. P271 - Use only outdoors or in a well-ventilated area. P260 - Do not breathe vapor. P270 - Do not eat, drink or smoke when using this product. P264 - Wash hands thoroughly after handling. 0.2 mM Hexakis(1H,1H,6H- P280 - Wear protective gloves. Wear eye or face decafluorohexyloxy)phosphazine protection. Wear protective clothing. in acetonitrile P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P241 - Use explosion-proof electrical, ventilating, lighting and all material-handling equipment. P242 - Use only non-sparking tools. P243 - Take precautionary measures against static discharge. P233 - Keep container tightly closed. P271 - Use only outdoors or in a well-ventilated area. P260 - Do not breathe vapor. P270 - Do not eat, drink or smoke when using this product. P264 - Wash hands thoroughly after handling. 0.5 mM Hexakis(1H,1H,8H- P280 - Wear protective gloves. Wear eye or face tetradecafluorooctyloxy) protection. Wear protective clothing. phosphazine in acetonitrile P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P241 - Use explosion-proof electrical, ventilating, lighting and all material-handling equipment. P242 - Use only non-sparking tools. P243 - Take precautionary measures against static discharge. P233 - Keep container tightly closed. P271 - Use only outdoors or in a well-ventilated area. P260 - Do not breathe vapor. P270 - Do not eat, drink or smoke when using this product. P264 - Wash hands thoroughly after handling.

Response

1.0 M Ammonium formate in Not applicable. deionized, nanopure water 5mM Purine in Acetonitrile P314 - Get medical attention if you feel unwell. Solution P304 + P340 + P312 - IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. P301 + P312 + P330 - IF SWALLOWED: Call a POISON CENTER or physician if you feel unwell. Rinse mouth. P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. P302 + P352 + P312 + P362+P364 - IF ON SKIN: Wash with plenty of soap and water. Call a POISON CENTER or physician if you feel unwell. Take off contaminated clothing and wash it before reuse. P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 - If eye irritation persists: Get medical attention. 0.5 mM Tris(2,4,6-trifluoromethyl) P314 - Get medical attention if you feel unwell. -1,3,5 triazine in acetonitrile P304 + P340 + P312 - IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. P301 + P312 + P330 - IF SWALLOWED: Call a POISON CENTER or physician if you feel unwell. Rinse mouth. P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. P302 + P352 + P312 + P362+P364 - IF ON SKIN: Wash with plenty of soap and water. Call a POISON CENTER or physician if you feel unwell. Take off contaminated clothing and wash it before reuse. P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 - If eye irritation persists: Get medical attention. 0.1 mM Hexamethoxyphosphazine P314 - Get medical attention if you feel unwell. in acetonitrile P304 + P340 + P312 - IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. P301 + P312 + P330 - IF SWALLOWED: Call a POISON CENTER or physician if you feel unwell. Rinse mouth. P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. P302 + P352 + P312 + P362+P364 - IF ON SKIN: Wash with plenty of soap and water. Call a POISON CENTER or physician if you feel unwell. Take off contaminated clothing and wash it before reuse. P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 - If eye irritation persists: Get medical attention. 0.2 mM Hexakis(1H,1H,4H- P314 - Get medical attention if you feel unwell. hexafluorobutyloxy)phosphazine in acetonitrile P304 + P340 + P312 - IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. P301 + P312 + P330 - IF SWALLOWED: Call a POISON CENTER or physician if you feel unwell. Rinse mouth. P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. P302 + P352 + P312 + P362+P364 - IF ON SKIN: Wash with plenty of soap and water. Call a POISON CENTER or physician if you feel unwell. Take off contaminated clothing and wash it before reuse. P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 - If eye irritation persists: Get medical attention. 0.2 mM Hexakis(1H,1H,6H- P314 - Get medical attention if you feel unwell. decafluorohexyloxy)phosphazine in acetonitrile P304 + P340 + P312 - IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. P301 + P312 + P330 - IF SWALLOWED: Call a POISON CENTER or physician if you feel unwell. Rinse mouth. P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. P302 + P352 + P312 + P362+P364 - IF ON SKIN: Wash with plenty of soap and water. Call a POISON CENTER or physician if you feel unwell. Take off contaminated clothing and wash it before reuse. P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 - If eye irritation persists: Get medical attention. 0.5 mM Hexakis(1H,1H,8H- P314 - Get medical attention if you feel unwell. tetradecafluorooctyloxy) phosphazine in acetonitrile P304 + P340 + P312 - IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. P301 + P312 + P330 - IF SWALLOWED: Call a POISON CENTER or physician if you feel unwell. Rinse mouth. P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. P302 + P352 + P312 + P362+P364 - IF ON SKIN: Wash with plenty of soap and water. Call a POISON CENTER or physician if you feel unwell. Take off contaminated clothing and wash it before reuse. P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 - If eye irritation persists: Get medical attention.

Storage

1.0 M Ammonium formate in Not applicable. deionized, nanopure water 5mM Purine in Acetonitrile P403 - Store in a well-ventilated place. Solution P235 - Keep cool. 0.5 mM Tris(2,4,6-trifluoromethyl) P403 - Store in a well-ventilated place. -1,3,5 triazine in acetonitrile P235 - Keep cool. 0.1 mM Hexamethoxyphosphazine P403 - Store in a well-ventilated place. in acetonitrile P235 - Keep cool. 0.2 mM Hexakis(1H,1H,4H- P403 - Store in a well-ventilated place. hexafluorobutyloxy)phosphazine in acetonitrile P235 - Keep cool. 0.2 mM Hexakis(1H,1H,6H- P403 - Store in a well-ventilated place. decafluorohexyloxy)phosphazine in acetonitrile P235 - Keep cool. 0.5 mM Hexakis(1H,1H,8H- P403 - Store in a well-ventilated place. tetradecafluorooctyloxy) phosphazine in acetonitrile P235 - Keep cool.

Disposal

1.0 M Ammonium formate in Not applicable. deionized, nanopure water 5mM Purine in Acetonitrile P501 - Dispose of contents and container in Solution accordance with all local, regional, national and international regulations. 0.5 mM Tris(2,4,6-trifluoromethyl) P501 - Dispose of contents and container in -1,3,5 triazine in acetonitrile accordance with all local, regional, national and international regulations. 0.1 mM Hexamethoxyphosphazine P501 - Dispose of contents and container in in acetonitrile accordance with all local, regional, national and international regulations. 0.2 mM Hexakis(1H,1H,4H- P501 - Dispose of contents and container in hexafluorobutyloxy)phosphazine in accordance with all local, regional, national and acetonitrile international regulations. 0.2 mM Hexakis(1H,1H,6H- P501 - Dispose of contents and container in decafluorohexyloxy)phosphazine accordance with all local, regional, national and in acetonitrile international regulations. 0.5 mM Hexakis(1H,1H,8H- P501 - Dispose of contents and container in tetradecafluorooctyloxy) accordance with all local, regional, national and phosphazine in acetonitrile international regulations.

Supplemental label elements

1.0 M Ammonium formate in None known. elements deionized, nanopure water 5mM Purine in Acetonitrile None known. Solution 0.5 mM Tris(2,4,6-trifluoromethyl) None known. -1,3,5 triazine in acetonitrile 0.1 mM Hexamethoxyphosphazine None known. in acetonitrile 0.2 mM Hexakis(1H,1H,4H- None known. hexafluorobutyloxy)phosphazine in acetonitrile 0.2 mM Hexakis(1H,1H,6H- None known. decafluorohexyloxy)phosphazine in acetonitrile 0.5 mM Hexakis(1H,1H,8H- None known. tetradecafluorooctyloxy) phosphazine in acetonitrile

2.3 Other hazards

Hazards not otherwise : 1.0 M Ammonium formate in None known. classified deionized, nanopure water 5mM Purine in Acetonitrile None known. Solution 0.5 mM Tris(2,4,6-trifluoromethyl) None known. -1,3,5 triazine in acetonitrile 0.1 mM Hexamethoxyphosphazine None known. in acetonitrile 0.2 mM Hexakis(1H,1H,4H- None known. hexafluorobutyloxy)phosphazine in acetonitrile 0.2 mM Hexakis(1H,1H,6H- None known. decafluorohexyloxy)phosphazine in acetonitrile 0.5 mM Hexakis(1H,1H,8H- None known. tetradecafluorooctyloxy) phosphazine in acetonitrile