OQ - PV Chemicals Standards Kit 1

Hazard statements (CLP)

H225, H290, H302, H304, H315, H336, H361f, H373, H400, H411, H412

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

1272/2008]

Product definition

nHexane Solvent Blank Mono-constituent substance Potassium Dichromate Mixture Solution (600.6 mg/L) Potassium Dichromate Mixture Solution (60.06 mg/L) Sulfuric Acid Solution (. Mixture 01N) Toluene Solution (0.02%) Mixture Potassium Chloride Mixture Solution (12 g/L) Sodium Iodide Solution Mixture (10 g/L) Sodium Nitrite Solution Mixture (50 g/L)

Aspiration hazard

Category 1 H411 LONG-TERM (CHRONIC) AQUATIC HAZARD Category 2 Potassium Dichromate Solution (600.6 mg/L) H290 CORROSIVE TO METALS Category 1 Potassium Dichromate Solution (60.06 mg/L) H290 CORROSIVE TO METALS Category 1 Toluene Solution (0.02%) H225 FLAMMABLE LIQUIDS Category 2 H315 SKIN CORROSION/IRRITATION Category 2 H361f REPRODUCTIVE TOXICITY Category 2 H336 SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE Category 3 (Narcotic effects) H373 SPECIFIC TARGET ORGAN TOXICITY - REPEATED Category 2 EXPOSURE H304 Category 1 H411 LONG-TERM (CHRONIC) AQUATIC HAZARD Category 2 Sodium Iodide Solution (10 g/L) H412 LONG-TERM (CHRONIC) AQUATIC HAZARD Category 3 Sodium Nitrite Solution (50 g/L) H302 ACUTE TOXICITY (oral) Category 4 H400 SHORT-TERM (ACUTE) AQUATIC HAZARD Category 1 nHexane Solvent Blank The product is classified as hazardous

Hazard pictograms

nHexane Solvent Blank Potassium Dichromate Solution (600.6 mg/L) Potassium Dichromate Solution (60.06 mg/L) Toluene Solution (0.02%) Sodium Nitrite Solution (50 g/L)

Signal word

nHexane Solvent Blank Danger Potassium Dichromate Warning Solution (600.6 mg/L) Potassium Dichromate Warning Solution (60.06 mg/L) Sulfuric Acid Solution (. No signal word. 01N) Toluene Solution (0.02%) Danger Potassium Chloride No signal word. Solution (12 g/L) Sodium Iodide Solution No signal word. (10 g/L) Sodium Nitrite Solution Warning (50 g/L)

Hazard statements

nHexane Solvent Blank H225 - Highly flammable liquid and vapour. H304 - May be fatal if swallowed and enters airways. H315 - Causes skin irritation. H336 - May cause drowsiness or dizziness. H361f - Suspected of damaging fertility. H373 - May cause damage to organs through prolonged or repeated exposure. H411 - Toxic to aquatic life with long lasting effects. Potassium Dichromate H290 - May be corrosive to metals. Solution (600.6 mg/L) Potassium Dichromate H290 - May be corrosive to metals. Solution (60.06 mg/L) Sulfuric Acid Solution (. No known significant effects or critical hazards. 01N) Toluene Solution (0.02%) H225 - Highly flammable liquid and vapour. H304 - May be fatal if swallowed and enters airways. H315 - Causes skin irritation. H336 - May cause drowsiness or dizziness. H361f - Suspected of damaging fertility. H373 - May cause damage to organs through prolonged or repeated exposure. H411 - Toxic to aquatic life with long lasting effects. Potassium Chloride No known significant effects or critical hazards. Solution (12 g/L) Sodium Iodide Solution H412 - Harmful to aquatic life with long lasting effects. (10 g/L) Sodium Nitrite Solution H302 - Harmful if swallowed. (50 g/L) H400 - Very toxic to aquatic life.

Prevention

nHexane Solvent Blank P280 - Wear protective gloves, protective clothing and eye or face protection. P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P273 - Avoid release to the environment. Potassium Dichromate P234 - Keep only in original packaging. Solution (600.6 mg/L) Potassium Dichromate P234 - Keep only in original packaging. Solution (60.06 mg/L) Sulfuric Acid Solution (. Not applicable. 01N) Toluene Solution (0.02%) P280 - Wear protective gloves, protective clothing and eye or face protection. P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P273 - Avoid release to the environment. Potassium Chloride Not applicable. Solution (12 g/L) Sodium Iodide Solution P273 - Avoid release to the environment. (10 g/L) Sodium Nitrite Solution P273 - Avoid release to the environment. (50 g/L) P270 - Do not eat, drink or smoke when using this product. P264 - Wash thoroughly after handling.

Response

nHexane Solvent Blank P391 - Collect spillage. Potassium Dichromate P390 - Absorb spillage to prevent material damage. Solution (600.6 mg/L) Potassium Dichromate P390 - Absorb spillage to prevent material damage. Solution (60.06 mg/L) Sulfuric Acid Solution (. Not applicable. 01N) Toluene Solution (0.02%) P391 - Collect spillage. Potassium Chloride Not applicable. Solution (12 g/L) Sodium Iodide Solution Not applicable. (10 g/L) Sodium Nitrite Solution P391 - Collect spillage. (50 g/L)

Storage

nHexane Solvent Blank P403 + P233 - Store in a well-ventilated place. Keep container tightly closed. Potassium Dichromate Not applicable. Solution (600.6 mg/L) Potassium Dichromate Not applicable. Solution (60.06 mg/L) Sulfuric Acid Solution (. Not applicable. 01N) Toluene Solution (0.02%) P403 + P233 - Store in a well-ventilated place. Keep container tightly closed. Potassium Chloride Not applicable. Solution (12 g/L) Sodium Iodide Solution Not applicable. (10 g/L) Sodium Nitrite Solution Not applicable. (50 g/L)

Disposal

nHexane Solvent Blank P501 - Dispose of contents and container in accordance with all local, regional, national and international regulations. Potassium Dichromate Not applicable. Solution (600.6 mg/L) Potassium Dichromate Not applicable. Solution (60.06 mg/L) Sulfuric Acid Solution (. Not applicable. 01N) Toluene Solution (0.02%) P501 - Dispose of contents and container in accordance with all local, regional, national and international regulations. Potassium Chloride Not applicable. Solution (12 g/L) Sodium Iodide Solution P501 - Dispose of contents and container in accordance (10 g/L) with all local, regional, national and international regulations. Sodium Nitrite Solution P501 - Dispose of contents and container in accordance (50 g/L) with all local, regional, national and international regulations.

Hazardous Ingredients

Toluene Solution (0.02%) n-hexane Sodium Nitrite Solution sodium nitrite (50 g/L)

Supplemental label elements

nHexane Solvent Blank Not applicable. elements Potassium Dichromate Not applicable. Solution (600.6 mg/L) Potassium Dichromate Not applicable. Solution (60.06 mg/L) Sulfuric Acid Solution (. Not applicable. 01N) Toluene Solution (0.02%) Not applicable. Potassium Chloride Not applicable. Solution (12 g/L) Sodium Iodide Solution Not applicable. (10 g/L) Sodium Nitrite Solution Not applicable. (50 g/L) Annex XVII - Restrictions : nHexane Solvent Blank Not applicable. on the manufacture, Potassium Dichromate Not applicable. placing on the market Solution (600.6 mg/L) and use of certain Potassium Dichromate Not applicable. dangerous substances, Solution (60.06 mg/L) mixtures and articles Sulfuric Acid Solution (. Not applicable. 01N) Toluene Solution (0.02%) Not applicable. Potassium Chloride Not applicable. Solution (12 g/L) Sodium Iodide Solution Not applicable. (10 g/L) Sodium Nitrite Solution Not applicable. (50 g/L)

Special packaging requirements

Tactile warning of : nHexane Solvent Blank Not applicable. danger Potassium Dichromate Not applicable. Solution (600.6 mg/L) Potassium Dichromate Not applicable. Solution (60.06 mg/L) Sulfuric Acid Solution (. Not applicable. 01N) Toluene Solution (0.02%) Not applicable. Potassium Chloride Not applicable. Solution (12 g/L) Sodium Iodide Solution Not applicable. (10 g/L) Sodium Nitrite Solution Not applicable. (50 g/L)

2.3 Other hazards

Product meets the

PBT Substances

P B T

vPvB Substances

vP vB criteria for PBT or vPvB according to nHexane Regulation (EC) No. Solvent Blank

2.1 Classification of the substance or mixture

equipment. Sparks may ignite liquid and vapour may cause flash fire or explosion. Potassium Dichromate None known. Solution (600.6 mg/L) Potassium Dichromate None known. Solution (60.06 mg/L) Sulfuric Acid Solution (. None known. 01N) Toluene Solution (0.02%) Static accumulating flammable liquid can become electrostatically charged even in bonded and grounded equipment. Sparks may ignite liquid and vapour may cause flash fire or explosion. Potassium Chloride None known. Solution (12 g/L) Sodium Iodide Solution None known. (10 g/L) Sodium Nitrite Solution None known. (50 g/L)