ES-TOF Biopolymer Analysis Reference Mass Standards Kit : G1969-85003

Hazard statements (CLP)

H225, H302, H302+H312+H332, H312, H319, H332

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

1272/2008]

Product definition

1.0 M Ammonium Mixture formate in deionized, nanopure water 5mM Purine in Mixture Acetonitrile Solution 0.5 mM Tris Mixture (2,4,6-trifluoromethyl) -1,3,5 triazine in acetonitrile 0.1 mM Mixture Hexamethoxyphosphazine in acetonitrile 0.2 mM Hexakis(1H,1H, Mixture 4H-hexafluorobutyloxy) phosphazine in acetonitrile 0.2 mM Hexakis(1H,1H, Mixture 6H-decafluorohexyloxy) phosphazine in acetonitrile 0.5 mM Hexakis(1H,1H, Mixture 8H- tetradecafluorooctyloxy) phosphazine in acetonitrile

Hazard pictograms

5mM Purine in Acetonitrile Solution 0.5 mM Tris (2,4,6-trifluoromethyl) -1,3,5 triazine in acetonitrile 0.1 mM Hexamethoxyphosphazine in acetonitrile 0.2 mM Hexakis(1H,1H, 4H-hexafluorobutyloxy) phosphazine in acetonitrile 0.2 mM Hexakis(1H,1H, 6H-decafluorohexyloxy) phosphazine in acetonitrile 0.5 mM Hexakis(1H,1H, 8H- tetradecafluorooctyloxy) phosphazine in acetonitrile

Signal word

1.0 M Ammonium No signal word. formate in deionized, nanopure water 5mM Purine in Danger Acetonitrile Solution 0.5 mM Tris Danger (2,4,6-trifluoromethyl) -1,3,5 triazine in acetonitrile 0.1 mM Danger Hexamethoxyphosphazine in acetonitrile 0.2 mM Hexakis(1H,1H, Danger 4H-hexafluorobutyloxy) phosphazine in acetonitrile 0.2 mM Hexakis(1H,1H, Danger 6H-decafluorohexyloxy) phosphazine in acetonitrile 0.5 mM Hexakis(1H,1H, Danger 8H- tetradecafluorooctyloxy) phosphazine in acetonitrile

Hazard statements

1.0 M Ammonium No known significant effects or critical hazards. formate in deionized, nanopure water 5mM Purine in H225 - Highly flammable liquid and vapour. Acetonitrile Solution H302 + H312 + H332 - Harmful if swallowed, in contact with skin or if inhaled. H319 - Causes serious eye irritation. 0.5 mM Tris H225 - Highly flammable liquid and vapour. (2,4,6-trifluoromethyl) -1,3,5 triazine in acetonitrile H302 + H312 + H332 - Harmful if swallowed, in contact with skin or if inhaled. H319 - Causes serious eye irritation. 0.1 mM H225 - Highly flammable liquid and vapour. Hexamethoxyphosphazine in acetonitrile H302 + H312 + H332 - Harmful if swallowed, in contact with skin or if inhaled. H319 - Causes serious eye irritation. 0.2 mM Hexakis(1H,1H, H225 - Highly flammable liquid and vapour. 4H-hexafluorobutyloxy) phosphazine in acetonitrile H302 + H312 + H332 - Harmful if swallowed, in contact with skin or if inhaled. H319 - Causes serious eye irritation. 0.2 mM Hexakis(1H,1H, H225 - Highly flammable liquid and vapour. 6H-decafluorohexyloxy) phosphazine in acetonitrile H302 + H312 + H332 - Harmful if swallowed, in contact with skin or if inhaled. H319 - Causes serious eye irritation. 0.5 mM Hexakis(1H,1H, H225 - Highly flammable liquid and vapour. 8H- tetradecafluorooctyloxy) phosphazine in acetonitrile H302 + H312 + H332 - Harmful if swallowed, in contact with skin or if inhaled. H319 - Causes serious eye irritation.

Prevention

1.0 M Ammonium Not applicable. formate in deionized, nanopure water 5mM Purine in P280 - Wear protective gloves and protective clothing. Wear Acetonitrile Solution eye or face protection. P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P261 - Avoid breathing vapour. P270 - Do not eat, drink or smoke when using this product. 0.5 mM Tris P280 - Wear protective gloves and protective clothing. Wear (2,4,6-trifluoromethyl) eye or face protection. -1,3,5 triazine in acetonitrile P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P261 - Avoid breathing vapour. P270 - Do not eat, drink or smoke when using this product. 0.1 mM P280 - Wear protective gloves and protective clothing. Wear Hexamethoxyphosphazine eye or face protection. in acetonitrile P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P261 - Avoid breathing vapour. P270 - Do not eat, drink or smoke when using this product. 0.2 mM Hexakis(1H,1H, P280 - Wear protective gloves and protective clothing. Wear 4H-hexafluorobutyloxy) eye or face protection. phosphazine in acetonitrile P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P261 - Avoid breathing vapour. P270 - Do not eat, drink or smoke when using this product. 0.2 mM Hexakis(1H,1H, P280 - Wear protective gloves and protective clothing. Wear 6H-decafluorohexyloxy) eye or face protection. phosphazine in acetonitrile P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P261 - Avoid breathing vapour. P270 - Do not eat, drink or smoke when using this product. 0.5 mM Hexakis(1H,1H, P280 - Wear protective gloves and protective clothing. Wear 8H- eye or face protection. tetradecafluorooctyloxy) phosphazine in acetonitrile P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P261 - Avoid breathing vapour. P270 - Do not eat, drink or smoke when using this product.

Response

1.0 M Ammonium Not applicable. formate in deionized, nanopure water 5mM Purine in P304 + P312 - IF INHALED: Call a POISON CENTER or Acetonitrile Solution doctor if you feel unwell. 0.5 mM Tris P304 + P312 - IF INHALED: Call a POISON CENTER or (2,4,6-trifluoromethyl) doctor if you feel unwell. -1,3,5 triazine in acetonitrile 0.1 mM P304 + P312 - IF INHALED: Call a POISON CENTER or Hexamethoxyphosphazine doctor if you feel unwell. in acetonitrile 0.2 mM Hexakis(1H,1H, P304 + P312 - IF INHALED: Call a POISON CENTER or 4H-hexafluorobutyloxy) doctor if you feel unwell. phosphazine in acetonitrile 0.2 mM Hexakis(1H,1H, P304 + P312 - IF INHALED: Call a POISON CENTER or 6H-decafluorohexyloxy) doctor if you feel unwell. phosphazine in acetonitrile 0.5 mM Hexakis(1H,1H, P304 + P312 - IF INHALED: Call a POISON CENTER or 8H- doctor if you feel unwell. tetradecafluorooctyloxy) phosphazine in acetonitrile

Storage

1.0 M Ammonium Not applicable. formate in deionized, nanopure water 5mM Purine in Not applicable. Acetonitrile Solution 0.5 mM Tris Not applicable. (2,4,6-trifluoromethyl) -1,3,5 triazine in acetonitrile 0.1 mM Not applicable. Hexamethoxyphosphazine in acetonitrile 0.2 mM Hexakis(1H,1H, Not applicable. 4H-hexafluorobutyloxy) phosphazine in acetonitrile 0.2 mM Hexakis(1H,1H, Not applicable. 6H-decafluorohexyloxy) phosphazine in acetonitrile 0.5 mM Hexakis(1H,1H, Not applicable. 8H- tetradecafluorooctyloxy) phosphazine in acetonitrile

Disposal

1.0 M Ammonium Not applicable. formate in deionized, nanopure water 5mM Purine in P501 - Dispose of contents and container in accordance Acetonitrile Solution with all local, regional, national and international regulations. 0.5 mM Tris P501 - Dispose of contents and container in accordance (2,4,6-trifluoromethyl) with all local, regional, national and international regulations. -1,3,5 triazine in acetonitrile 0.1 mM P501 - Dispose of contents and container in accordance Hexamethoxyphosphazine with all local, regional, national and international regulations. in acetonitrile 0.2 mM Hexakis(1H,1H, P501 - Dispose of contents and container in accordance 4H-hexafluorobutyloxy) with all local, regional, national and international regulations. phosphazine in acetonitrile 0.2 mM Hexakis(1H,1H, P501 - Dispose of contents and container in accordance 6H-decafluorohexyloxy) with all local, regional, national and international regulations. phosphazine in acetonitrile 0.5 mM Hexakis(1H,1H, P501 - Dispose of contents and container in accordance 8H- with all local, regional, national and international regulations. tetradecafluorooctyloxy) phosphazine in acetonitrile

Hazardous Ingredients

5mM Purine in acetonitrile Acetonitrile Solution 0.5 mM Tris acetonitrile (2,4,6-trifluoromethyl) -1,3,5 triazine in acetonitrile 0.1 mM acetonitrile Hexamethoxyphosphazine in acetonitrile 0.2 mM Hexakis(1H,1H, acetonitrile 4H-hexafluorobutyloxy) phosphazine in acetonitrile 0.2 mM Hexakis(1H,1H, acetonitrile 6H-decafluorohexyloxy) phosphazine in acetonitrile 0.5 mM Hexakis(1H,1H, acetonitrile 8H- tetradecafluorooctyloxy) phosphazine in acetonitrile

Supplemental label elements

1.0 M Ammonium Safety data sheet available on request. elements formate in deionized, nanopure water 5mM Purine in Not applicable. Acetonitrile Solution 0.5 mM Tris Not applicable. (2,4,6-trifluoromethyl) -1,3,5 triazine in acetonitrile 0.1 mM Not applicable. Hexamethoxyphosphazine in acetonitrile 0.2 mM Hexakis(1H,1H, Not applicable. 4H-hexafluorobutyloxy) phosphazine in acetonitrile 0.2 mM Hexakis(1H,1H, Not applicable. 6H-decafluorohexyloxy) phosphazine in acetonitrile 0.5 mM Hexakis(1H,1H, Not applicable. 8H- tetradecafluorooctyloxy) phosphazine in acetonitrile Annex XVII - Restrictions : 1.0 M Ammonium Not applicable. on the manufacture, formate in deionized, placing on the market nanopure water and use of certain 5mM Purine in Not applicable. dangerous substances, Acetonitrile Solution mixtures and articles 0.5 mM Tris Not applicable. (2,4,6-trifluoromethyl) -1,3,5 triazine in acetonitrile 0.1 mM Not applicable. Hexamethoxyphosphazine in acetonitrile 0.2 mM Hexakis(1H,1H, Not applicable. 4H-hexafluorobutyloxy) phosphazine in acetonitrile 0.2 mM Hexakis(1H,1H, Not applicable. 6H-decafluorohexyloxy) phosphazine in acetonitrile 0.5 mM Hexakis(1H,1H, Not applicable. 8H- tetradecafluorooctyloxy) phosphazine in acetonitrile

Special packaging requirements

Tactile warning of : 1.0 M Ammonium Not applicable. danger formate in deionized, nanopure water 5mM Purine in Not applicable. Acetonitrile Solution 0.5 mM Tris Not applicable. (2,4,6-trifluoromethyl) -1,3,5 triazine in acetonitrile 0.1 mM Not applicable. Hexamethoxyphosphazine in acetonitrile 0.2 mM Hexakis(1H,1H, Not applicable. 4H-hexafluorobutyloxy) phosphazine in acetonitrile 0.2 mM Hexakis(1H,1H, Not applicable. 6H-decafluorohexyloxy) phosphazine in acetonitrile 0.5 mM Hexakis(1H,1H, Not applicable. 8H- tetradecafluorooctyloxy) phosphazine in acetonitrile

2.3 Other hazards

Product meets the : 1.0 M Ammonium This mixture does not contain any substances that are criteria for PBT or vPvB formate in deionized, assessed to be a PBT or a vPvB. according to nanopure water Regulation (EC) No. 5mM Purine in This mixture does not contain any substances that are

2.1 Classification of the substance or mixture

nanopure water 5mM Purine in None known. Acetonitrile Solution 0.5 mM Tris None known. (2,4,6-trifluoromethyl) -1,3,5 triazine in acetonitrile 0.1 mM None known. Hexamethoxyphosphazine in acetonitrile 0.2 mM Hexakis(1H,1H, None known. 4H-hexafluorobutyloxy) phosphazine in acetonitrile 0.2 mM Hexakis(1H,1H, None known. 6H-decafluorohexyloxy) phosphazine in acetonitrile 0.5 mM Hexakis(1H,1H, None known. 8H- tetradecafluorooctyloxy) phosphazine in acetonitrile