Calibrated Solutions Kit, Part Number 9910085200

Hazard statements (CLP)

H225, H272, H302, H304, H314, H315, H336, H361f, H373, H400, H411, H412

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

1272/2008]

Product definition

Hexane Blank Mono-constituent substance Water Blank Mono-constituent substance Holmium Perchlorate Mixture Reference Cell Hexane Reference Cell Mixture Potassium Chloride Mixture Reference Cell Sodium Iodide Mixture Reference Cell Potassium Dichromate Mixture Reference Cell - 60 Potassium Dichromate Mixture Reference Cell - 600 Perchloric Acid Blank Mixture Sodium Nitrite Mixture Reference Cell Potassium Dichromate Mixture Reference Cell - 40 mg/L Potassium Dichromate Mixture Reference Cell - 120 mg/ L

Aspiration hazard

Category 1 H411 LONG-TERM (CHRONIC) AQUATIC HAZARD Category 2 Holmium Perchlorate Reference Cell H272 OXIDISING LIQUIDS Category 2 H314 SKIN CORROSION/IRRITATION Category 1 H373 SPECIFIC TARGET ORGAN TOXICITY - REPEATED Category 2 EXPOSURE Hexane Reference Cell H225 FLAMMABLE LIQUIDS Category 2 H315 SKIN CORROSION/IRRITATION Category 2 H361f REPRODUCTIVE TOXICITY Category 2 H336 SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE Category 3 (Narcotic effects) H373 SPECIFIC TARGET ORGAN TOXICITY - REPEATED Category 2 EXPOSURE H304 Category 1 H411 LONG-TERM (CHRONIC) AQUATIC HAZARD Category 2 Sodium Iodide Reference Cell H373 SPECIFIC TARGET ORGAN TOXICITY - REPEATED Category 2 EXPOSURE H412 LONG-TERM (CHRONIC) AQUATIC HAZARD Category 3 Sodium Nitrite Reference Cell H302 ACUTE TOXICITY (oral) Category 4 H400 SHORT-TERM (ACUTE) AQUATIC HAZARD Category 1 Hexane Blank The product is classified as hazardous

Contains

3.6% of components with unknown hazards to the ecotoxicity Reference Cell aquatic environment See Section 16 for the full text of the H statements declared above. See Section 11 for more detailed information on health effects and symptoms.

Hazard pictograms

Hexane Blank Holmium Perchlorate Reference Cell Hexane Reference Cell Sodium Iodide Reference Cell Sodium Nitrite Reference Cell

Signal word

Hexane Blank Danger Water Blank No signal word. Holmium Perchlorate Danger Reference Cell Hexane Reference Cell Danger Potassium Chloride No signal word. Reference Cell Sodium Iodide Warning Reference Cell Potassium Dichromate No signal word. Reference Cell - 60 Potassium Dichromate No signal word. Reference Cell - 600 Perchloric Acid Blank No signal word. Sodium Nitrite Warning Reference Cell Potassium Dichromate No signal word. Reference Cell - 40 mg/L Potassium Dichromate No signal word. Reference Cell - 120 mg/ L

Hazard statements

Hexane Blank H225 - Highly flammable liquid and vapour. H304 - May be fatal if swallowed and enters airways. H315 - Causes skin irritation. H336 - May cause drowsiness or dizziness. H361f - Suspected of damaging fertility. H373 - May cause damage to organs through prolonged or repeated exposure. H411 - Toxic to aquatic life with long lasting effects. Water Blank No known significant effects or critical hazards. Holmium Perchlorate H272 - May intensify fire; oxidiser. Reference Cell H314 - Causes severe skin burns and eye damage. H373 - May cause damage to organs through prolonged or repeated exposure. Hexane Reference Cell H225 - Highly flammable liquid and vapour. H304 - May be fatal if swallowed and enters airways. H315 - Causes skin irritation. H336 - May cause drowsiness or dizziness. H361f - Suspected of damaging fertility. H373 - May cause damage to organs through prolonged or repeated exposure. H411 - Toxic to aquatic life with long lasting effects. Potassium Chloride No known significant effects or critical hazards. Reference Cell Sodium Iodide H373 - May cause damage to organs through prolonged or Reference Cell repeated exposure. H412 - Harmful to aquatic life with long lasting effects. Potassium Dichromate No known significant effects or critical hazards. Reference Cell - 60 Potassium Dichromate No known significant effects or critical hazards. Reference Cell - 600 Perchloric Acid Blank No known significant effects or critical hazards. Sodium Nitrite H302 - Harmful if swallowed. Reference Cell H400 - Very toxic to aquatic life. Potassium Dichromate No known significant effects or critical hazards. Reference Cell - 40 mg/L Potassium Dichromate No known significant effects or critical hazards. Reference Cell - 120 mg/ L

Prevention

Hexane Blank P280 - Wear protective gloves, protective clothing and eye or face protection. P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P273 - Avoid release to the environment. Water Blank Not applicable. Holmium Perchlorate P280 - Wear protective gloves, protective clothing and eye Reference Cell or face protection. P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P220 - Keep away from clothing and other combustible materials. P260 - Do not breathe vapour. Hexane Reference Cell P280 - Wear protective gloves, protective clothing and eye or face protection. P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P273 - Avoid release to the environment. Potassium Chloride Not applicable. Reference Cell Sodium Iodide P273 - Avoid release to the environment. Reference Cell P260 - Do not breathe vapour. Potassium Dichromate Not applicable. Reference Cell - 60 Potassium Dichromate Not applicable. Reference Cell - 600 Perchloric Acid Blank Not applicable. Sodium Nitrite P273 - Avoid release to the environment. Reference Cell P270 - Do not eat, drink or smoke when using this product. P264 - Wash thoroughly after handling. Potassium Dichromate Not applicable. Reference Cell - 40 mg/L Potassium Dichromate Not applicable. Reference Cell - 120 mg/ L

Response

Hexane Blank P391 - Collect spillage. Water Blank Not applicable. Holmium Perchlorate P304 + P310 - IF INHALED: Immediately call a POISON Reference Cell CENTER or doctor. Hexane Reference Cell P391 - Collect spillage. Potassium Chloride Not applicable. Reference Cell Sodium Iodide P314 - Get medical advice/attention if you feel unwell. Reference Cell Potassium Dichromate Not applicable. Reference Cell - 60 Potassium Dichromate Not applicable. Reference Cell - 600 Perchloric Acid Blank Not applicable. Sodium Nitrite P391 - Collect spillage. Reference Cell Potassium Dichromate Not applicable. Reference Cell - 40 mg/L Potassium Dichromate Not applicable. Reference Cell - 120 mg/ L

Storage

Hexane Blank P403 + P233 - Store in a well-ventilated place. Keep container tightly closed. Water Blank Not applicable. Holmium Perchlorate Not applicable. Reference Cell Hexane Reference Cell P403 + P233 - Store in a well-ventilated place. Keep container tightly closed. Potassium Chloride Not applicable. Reference Cell Sodium Iodide Not applicable. Reference Cell Potassium Dichromate Not applicable. Reference Cell - 60 Potassium Dichromate Not applicable. Reference Cell - 600 Perchloric Acid Blank Not applicable. Sodium Nitrite Not applicable. Reference Cell Potassium Dichromate Not applicable. Reference Cell - 40 mg/L Potassium Dichromate Not applicable. Reference Cell - 120 mg/ L

Disposal

Hexane Blank P501 - Dispose of contents and container in accordance with all local, regional, national and international regulations. Water Blank Not applicable. Holmium Perchlorate P501 - Dispose of contents and container in accordance Reference Cell with all local, regional, national and international regulations. Hexane Reference Cell P501 - Dispose of contents and container in accordance with all local, regional, national and international regulations. Potassium Chloride Not applicable. Reference Cell Sodium Iodide P501 - Dispose of contents and container in accordance Reference Cell with all local, regional, national and international regulations. Potassium Dichromate Not applicable. Reference Cell - 60 Potassium Dichromate Not applicable. Reference Cell - 600 Perchloric Acid Blank Not applicable. Sodium Nitrite P501 - Dispose of contents and container in accordance Reference Cell with all local, regional, national and international regulations. Potassium Dichromate Not applicable. Reference Cell - 40 mg/L Potassium Dichromate Not applicable. Reference Cell - 120 mg/ L

Hazardous Ingredients

Holmium Perchlorate perchloric acid Reference Cell Hexane Reference Cell n-hexane Sodium Iodide sodium iodide Reference Cell Sodium Nitrite sodium nitrite Reference Cell

Supplemental label elements

Hexane Blank Not applicable. elements Water Blank Not applicable. Holmium Perchlorate Not applicable. Reference Cell Hexane Reference Cell Not applicable. Potassium Chloride Not applicable. Reference Cell Sodium Iodide Not applicable. Reference Cell Potassium Dichromate Not applicable. Reference Cell - 60 Potassium Dichromate Not applicable. Reference Cell - 600 Perchloric Acid Blank Not applicable. Sodium Nitrite Not applicable. Reference Cell Potassium Dichromate Not applicable. Reference Cell - 40 mg/L Potassium Dichromate Not applicable. Reference Cell - 120 mg/ L Annex XVII - Restrictions : Hexane Blank Not applicable. on the manufacture, Water Blank Not applicable. placing on the market Holmium Perchlorate Not applicable. and use of certain Reference Cell dangerous substances, Hexane Reference Cell Not applicable. mixtures and articles Potassium Chloride Not applicable. Reference Cell Sodium Iodide Not applicable. Reference Cell Potassium Dichromate Not applicable. Reference Cell - 60 Potassium Dichromate Not applicable. Reference Cell - 600 Perchloric Acid Blank Not applicable. Sodium Nitrite Not applicable. Reference Cell Potassium Dichromate Not applicable. Reference Cell - 40 mg/L Potassium Dichromate Not applicable. Reference Cell - 120 mg/ L

Special packaging requirements

Tactile warning of : Hexane Blank Not applicable. danger Water Blank Not applicable. Holmium Perchlorate Not applicable. Reference Cell Hexane Reference Cell Not applicable. Potassium Chloride Not applicable. Reference Cell Sodium Iodide Not applicable. Reference Cell Potassium Dichromate Not applicable. Reference Cell - 60 Potassium Dichromate Not applicable. Reference Cell - 600 Perchloric Acid Blank Not applicable. Sodium Nitrite Not applicable. Reference Cell Potassium Dichromate Not applicable. Reference Cell - 40 mg/L Potassium Dichromate Not applicable. Reference Cell - 120 mg/ L

2.3 Other hazards

Product meets the

PBT Substances

P B T

vPvB Substances

vP vB criteria for PBT or vPvB according to Hexane Regulation (EC) No. Blank

2.1 Classification of the substance or mixture

Holmium Perchlorate Causes digestive tract burns. Reference Cell Hexane Reference Cell None known. Potassium Chloride None known. Reference Cell Sodium Iodide None known. Reference Cell Potassium Dichromate None known. Reference Cell - 60 Potassium Dichromate None known. Reference Cell - 600 Perchloric Acid Blank None known. Sodium Nitrite None known. Reference Cell Potassium Dichromate None known. Reference Cell - 40 mg/L Potassium Dichromate None known. Reference Cell - 120 mg/ L