ES-TOF Biopolymer Analysis Reference Mass Standards Kit, Part Number G1969-85003 G1969-85003

Hazard statements (CLP)

H225, H302, H302+H312+H332, H312, H319, H332

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

5mM Purine in Acetonitrile Solution H225 FLAMMABLE LIQUIDS - Category 2 H302 ACUTE TOXICITY (oral) - Category 4 H312 ACUTE TOXICITY (dermal) - Category 4 H332 ACUTE TOXICITY (inhalation) - Category 4 H319 SERIOUS EYE DAMAGE/EYE IRRITATION - Category 2A 0.5 mM Tris (2,4,6-trifluoromethyl)-1,3,5 triazine in acetonitrile H225 FLAMMABLE LIQUIDS - Category 2 H302 ACUTE TOXICITY (oral) - Category 4 H312 ACUTE TOXICITY (dermal) - Category 4 H332 ACUTE TOXICITY (inhalation) - Category 4 H319 SERIOUS EYE DAMAGE/EYE IRRITATION - Category 2A 0.1 mM Hexamethoxyphosphazine in acetonitrile H225 FLAMMABLE LIQUIDS - Category 2 H302 ACUTE TOXICITY (oral) - Category 4 H312 ACUTE TOXICITY (dermal) - Category 4 H332 ACUTE TOXICITY (inhalation) - Category 4 H319 SERIOUS EYE DAMAGE/EYE IRRITATION - Category 2A 0.2 mM Hexakis(1H,1H,4H- hexafluorobutyloxy) phosphazine in acetonitrile H225 FLAMMABLE LIQUIDS - Category 2 H302 ACUTE TOXICITY (oral) - Category 4 H312 ACUTE TOXICITY (dermal) - Category 4 H332 ACUTE TOXICITY (inhalation) - Category 4 H319 SERIOUS EYE DAMAGE/EYE IRRITATION - Category 2A 0.2 mM Hexakis(1H,1H,6H- decafluorohexyloxy) phosphazine in acetonitrile H225 FLAMMABLE LIQUIDS - Category 2 H302 ACUTE TOXICITY (oral) - Category 4 H312 ACUTE TOXICITY (dermal) - Category 4 H332 ACUTE TOXICITY (inhalation) - Category 4 H319 SERIOUS EYE DAMAGE/EYE IRRITATION - Category 2A 0.5 mM Hexakis(1H,1H,8H- tetradecafluorooctyloxy) phosphazine in acetonitrile H225 FLAMMABLE LIQUIDS - Category 2 H302 ACUTE TOXICITY (oral) - Category 4 H312 ACUTE TOXICITY (dermal) - Category 4 H332 ACUTE TOXICITY (inhalation) - Category 4 H319 SERIOUS EYE DAMAGE/EYE IRRITATION - Category 2A 1.0 M Ammonium formate Percentage of the mixture consisting of ingredient(s) in deionized, nanopure water of unknown acute dermal toxicity: 1 - 10% Percentage of the mixture consisting of ingredient(s) of unknown acute inhalation toxicity: 1 - 10% Percentage of the mixture consisting of ingredient(s) of unknown acute oral toxicity: 1 - 10% 1.0 M Ammonium formate Percentage of the mixture consisting of ingredient(s) in deionized, nanopure water of unknown hazards to the aquatic environment: 6.3%

Hazard pictograms

5mM Purine in Acetonitrile Solution 0.5 mM Tris (2,4,6-trifluoromethyl)-1,3,5 triazine in acetonitrile 0.1 mM Hexamethoxyphosphazine in acetonitrile 0.2 mM Hexakis(1H,1H,4H- hexafluorobutyloxy) phosphazine in acetonitrile 0.2 mM Hexakis(1H,1H,6H- decafluorohexyloxy) phosphazine in acetonitrile 0.5 mM Hexakis(1H,1H,8H- tetradecafluorooctyloxy) phosphazine in acetonitrile

Signal word

1.0 M Ammonium formate No signal word. in deionized, nanopure water 5mM Purine in Acetonitrile DANGER Solution 0.5 mM Tris DANGER (2,4,6-trifluoromethyl)-1,3,5 triazine in acetonitrile 0.1 mM DANGER Hexamethoxyphosphazine in acetonitrile 0.2 mM Hexakis(1H,1H,4H- DANGER hexafluorobutyloxy) phosphazine in acetonitrile 0.2 mM Hexakis(1H,1H,6H- DANGER decafluorohexyloxy) phosphazine in acetonitrile 0.5 mM Hexakis(1H,1H,8H- DANGER tetradecafluorooctyloxy) phosphazine in acetonitrile

Hazard statements

1.0 M Ammonium formate No known significant effects or critical hazards. in deionized, nanopure water 5mM Purine in Acetonitrile H225 - Highly flammable liquid and vapour. Solution H302 + H312 + H332 - Harmful if swallowed, in contact with skin or if inhaled. H319 - Causes serious eye irritation. 0.5 mM Tris H225 - Highly flammable liquid and vapour. (2,4,6-trifluoromethyl)-1,3,5 triazine in acetonitrile H302 + H312 + H332 - Harmful if swallowed, in contact with skin or if inhaled. H319 - Causes serious eye irritation. 0.1 mM H225 - Highly flammable liquid and vapour. Hexamethoxyphosphazine in acetonitrile H302 + H312 + H332 - Harmful if swallowed, in contact with skin or if inhaled. H319 - Causes serious eye irritation. 0.2 mM Hexakis(1H,1H,4H- H225 - Highly flammable liquid and vapour. hexafluorobutyloxy) phosphazine in acetonitrile H302 + H312 + H332 - Harmful if swallowed, in contact with skin or if inhaled. H319 - Causes serious eye irritation. 0.2 mM Hexakis(1H,1H,6H- H225 - Highly flammable liquid and vapour. decafluorohexyloxy) phosphazine in acetonitrile H302 + H312 + H332 - Harmful if swallowed, in contact with skin or if inhaled. H319 - Causes serious eye irritation. 0.5 mM Hexakis(1H,1H,8H- H225 - Highly flammable liquid and vapour. tetradecafluorooctyloxy) phosphazine in acetonitrile H302 + H312 + H332 - Harmful if swallowed, in contact with skin or if inhaled. H319 - Causes serious eye irritation.

Prevention

1.0 M Ammonium formate Not applicable. in deionized, nanopure water 5mM Purine in Acetonitrile P280 - Wear protective gloves. Wear eye or face Solution protection. Wear protective clothing. P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P241 - Use explosion-proof electrical, ventilating, lighting and all material-handling equipment. P242 - Use only non-sparking tools. P243 - Take precautionary measures against static discharge. P233 - Keep container tightly closed. P271 - Use only outdoors or in a well-ventilated area. P261 - Avoid breathing vapour. P270 - Do not eat, drink or smoke when using this product. P264 - Wash hands thoroughly after handling. 0.5 mM Tris P280 - Wear protective gloves. Wear eye or face (2,4,6-trifluoromethyl)-1,3,5 protection. Wear protective clothing. triazine in acetonitrile P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P241 - Use explosion-proof electrical, ventilating, lighting and all material-handling equipment. P242 - Use only non-sparking tools. P243 - Take precautionary measures against static discharge. P233 - Keep container tightly closed. P271 - Use only outdoors or in a well-ventilated area. P261 - Avoid breathing vapour. P270 - Do not eat, drink or smoke when using this product. P264 - Wash hands thoroughly after handling. 0.1 mM P280 - Wear protective gloves. Wear eye or face Hexamethoxyphosphazine in protection. Wear protective clothing. acetonitrile P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P241 - Use explosion-proof electrical, ventilating, lighting and all material-handling equipment. P242 - Use only non-sparking tools. P243 - Take precautionary measures against static discharge. P233 - Keep container tightly closed. P271 - Use only outdoors or in a well-ventilated area. P261 - Avoid breathing vapour. P270 - Do not eat, drink or smoke when using this product. P264 - Wash hands thoroughly after handling. 0.2 mM Hexakis(1H,1H,4H- P280 - Wear protective gloves. Wear eye or face hexafluorobutyloxy) protection. Wear protective clothing. phosphazine in acetonitrile P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P241 - Use explosion-proof electrical, ventilating, lighting and all material-handling equipment. P242 - Use only non-sparking tools. P243 - Take precautionary measures against static discharge. P233 - Keep container tightly closed. P271 - Use only outdoors or in a well-ventilated area. P261 - Avoid breathing vapour. P270 - Do not eat, drink or smoke when using this product. P264 - Wash hands thoroughly after handling. 0.2 mM Hexakis(1H,1H,6H- P280 - Wear protective gloves. Wear eye or face decafluorohexyloxy) protection. Wear protective clothing. phosphazine in acetonitrile P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P241 - Use explosion-proof electrical, ventilating, lighting and all material-handling equipment. P242 - Use only non-sparking tools. P243 - Take precautionary measures against static discharge. P233 - Keep container tightly closed. P271 - Use only outdoors or in a well-ventilated area. P261 - Avoid breathing vapour. P270 - Do not eat, drink or smoke when using this product. P264 - Wash hands thoroughly after handling. 0.5 mM Hexakis(1H,1H,8H- P280 - Wear protective gloves. Wear eye or face tetradecafluorooctyloxy) protection. Wear protective clothing. phosphazine in acetonitrile P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P241 - Use explosion-proof electrical, ventilating, lighting and all material-handling equipment. P242 - Use only non-sparking tools. P243 - Take precautionary measures against static discharge. P233 - Keep container tightly closed. P271 - Use only outdoors or in a well-ventilated area. P261 - Avoid breathing vapour. P270 - Do not eat, drink or smoke when using this product. P264 - Wash hands thoroughly after handling.

Response

1.0 M Ammonium formate Not applicable. in deionized, nanopure water 5mM Purine in Acetonitrile P304 + P340 + P312 - IF INHALED: Remove victim Solution to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. P301 + P312 + P330 - IF SWALLOWED: Call a POISON CENTER or physician if you feel unwell. Rinse mouth. P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. P302 + P352 + P312 - IF ON SKIN: Wash with plenty of soap and water. Call a POISON CENTER or physician if you feel unwell. P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 - If eye irritation persists: Get medical attention. 0.5 mM Tris P304 + P340 + P312 - IF INHALED: Remove victim (2,4,6-trifluoromethyl)-1,3,5 to fresh air and keep at rest in a position comfortable triazine in acetonitrile for breathing. Call a POISON CENTER or physician if you feel unwell. P301 + P312 + P330 - IF SWALLOWED: Call a POISON CENTER or physician if you feel unwell. Rinse mouth. P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. P302 + P352 + P312 - IF ON SKIN: Wash with plenty of soap and water. Call a POISON CENTER or physician if you feel unwell. P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 - If eye irritation persists: Get medical attention. 0.1 mM P304 + P340 + P312 - IF INHALED: Remove victim Hexamethoxyphosphazine in to fresh air and keep at rest in a position comfortable acetonitrile for breathing. Call a POISON CENTER or physician if you feel unwell. P301 + P312 + P330 - IF SWALLOWED: Call a POISON CENTER or physician if you feel unwell. Rinse mouth. P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. P302 + P352 + P312 - IF ON SKIN: Wash with plenty of soap and water. Call a POISON CENTER or physician if you feel unwell. P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 - If eye irritation persists: Get medical attention. 0.2 mM Hexakis(1H,1H,4H- P304 + P340 + P312 - IF INHALED: Remove victim hexafluorobutyloxy) to fresh air and keep at rest in a position comfortable phosphazine in acetonitrile for breathing. Call a POISON CENTER or physician if you feel unwell. P301 + P312 + P330 - IF SWALLOWED: Call a POISON CENTER or physician if you feel unwell. Rinse mouth. P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. P302 + P352 + P312 - IF ON SKIN: Wash with plenty of soap and water. Call a POISON CENTER or physician if you feel unwell. P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 - If eye irritation persists: Get medical attention. 0.2 mM Hexakis(1H,1H,6H- P304 + P340 + P312 - IF INHALED: Remove victim decafluorohexyloxy) to fresh air and keep at rest in a position comfortable phosphazine in acetonitrile for breathing. Call a POISON CENTER or physician if you feel unwell. P301 + P312 + P330 - IF SWALLOWED: Call a POISON CENTER or physician if you feel unwell. Rinse mouth. P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. P302 + P352 + P312 - IF ON SKIN: Wash with plenty of soap and water. Call a POISON CENTER or physician if you feel unwell. P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 - If eye irritation persists: Get medical attention. 0.5 mM Hexakis(1H,1H,8H- P304 + P340 + P312 - IF INHALED: Remove victim tetradecafluorooctyloxy) to fresh air and keep at rest in a position comfortable phosphazine in acetonitrile for breathing. Call a POISON CENTER or physician if you feel unwell. P301 + P312 + P330 - IF SWALLOWED: Call a POISON CENTER or physician if you feel unwell. Rinse mouth. P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. P302 + P352 + P312 - IF ON SKIN: Wash with plenty of soap and water. Call a POISON CENTER or physician if you feel unwell. P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 - If eye irritation persists: Get medical attention.

Storage

1.0 M Ammonium formate Not applicable. in deionized, nanopure water 5mM Purine in Acetonitrile P403 - Store in a well-ventilated place. Solution P235 - Keep cool. 0.5 mM Tris P403 - Store in a well-ventilated place. (2,4,6-trifluoromethyl)-1,3,5 triazine in acetonitrile P235 - Keep cool. 0.1 mM P403 - Store in a well-ventilated place. Hexamethoxyphosphazine in acetonitrile P235 - Keep cool. 0.2 mM Hexakis(1H,1H,4H- P403 - Store in a well-ventilated place. hexafluorobutyloxy) phosphazine in acetonitrile P235 - Keep cool. 0.2 mM Hexakis(1H,1H,6H- P403 - Store in a well-ventilated place. decafluorohexyloxy) phosphazine in acetonitrile P235 - Keep cool. 0.5 mM Hexakis(1H,1H,8H- P403 - Store in a well-ventilated place. tetradecafluorooctyloxy) phosphazine in acetonitrile P235 - Keep cool.

Disposal

1.0 M Ammonium formate Not applicable. in deionized, nanopure water 5mM Purine in Acetonitrile P501 - Dispose of contents and container in Solution accordance with all local, regional, national and international regulations. 0.5 mM Tris P501 - Dispose of contents and container in (2,4,6-trifluoromethyl)-1,3,5 accordance with all local, regional, national and triazine in acetonitrile international regulations. 0.1 mM P501 - Dispose of contents and container in Hexamethoxyphosphazine in accordance with all local, regional, national and acetonitrile international regulations. 0.2 mM Hexakis(1H,1H,4H- P501 - Dispose of contents and container in hexafluorobutyloxy) accordance with all local, regional, national and phosphazine in acetonitrile international regulations. 0.2 mM Hexakis(1H,1H,6H- P501 - Dispose of contents and container in decafluorohexyloxy) accordance with all local, regional, national and phosphazine in acetonitrile international regulations. 0.5 mM Hexakis(1H,1H,8H- P501 - Dispose of contents and container in tetradecafluorooctyloxy) accordance with all local, regional, national and phosphazine in acetonitrile international regulations.

Supplemental label elements

elements Additional warning : 1.0 M Ammonium formate Not applicable. phrases in deionized, nanopure water 5mM Purine in Acetonitrile Not applicable. Solution 0.5 mM Tris Not applicable. (2,4,6-trifluoromethyl)-1,3,5 triazine in acetonitrile 0.1 mM Not applicable. Hexamethoxyphosphazine in acetonitrile 0.2 mM Hexakis(1H,1H,4H- Not applicable. hexafluorobutyloxy) phosphazine in acetonitrile 0.2 mM Hexakis(1H,1H,6H- Not applicable. decafluorohexyloxy) phosphazine in acetonitrile 0.5 mM Hexakis(1H,1H,8H- Not applicable. tetradecafluorooctyloxy) phosphazine in acetonitrile Other hazards which do not : 1.0 M Ammonium formate None known. result in classification in deionized, nanopure water 5mM Purine in Acetonitrile None known. Solution 0.5 mM Tris None known. (2,4,6-trifluoromethyl)-1,3,5 triazine in acetonitrile 0.1 mM None known. Hexamethoxyphosphazine in acetonitrile 0.2 mM Hexakis(1H,1H,4H- None known. hexafluorobutyloxy) phosphazine in acetonitrile 0.2 mM Hexakis(1H,1H,6H- None known. decafluorohexyloxy) phosphazine in acetonitrile 0.5 mM Hexakis(1H,1H,8H- None known. tetradecafluorooctyloxy) phosphazine in acetonitrile