> G1385, PART B

Hazard statements (CLP)

H314, H318, H412

Code

Statements

H314

Causes severe skin burns and eye damage

SECTION 2: Hazards identification

No 1272/2008]

Hazard categories

Chronic hazards to the aquatic environment Category 3 Skin corrosion Category 1B Serious eye damage Category

Hazard statements

H412 Classification procedure According the classification criteria of CLP Regulation (EC) H314 Classification procedure According the classification criteria of CLP Regulation (EC) H318 Classification procedure According the classification criteria of CLP Regulation (EC)

R-phrase(s)

R22, R384, R52/53 4. FIRST AID MEASURES 4.1 Description of first aid measures: Eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. Skin contact Wash immediately with plenty of water and soap. If symptoms persist, seek medical advice. Ingestion Rinse mouth with plenty of water. Seek medical advice. Do not induce vomiting. Inhalation Take person to fresh air. If necessary, seek medical advice. 4.2 Most important symptoms and effects: Symptoms In normal conditions of use, no adverse effects are expected. If inhaled or ingestion: irritation. In case of eye contact: redness and pain. Upon contact with skin: redness, pain. 4.3 Indication of immediate medical attention and special treatment needed: General advice Calla physician immediately. 5. FIRE-FIGHTING MEASURES 5.1 Extinguishing media Suitable extinguishing media Alcohol-resistant foam., Carbon dioxide (CO2)., Dry extinguishing powder., Water. Extinguishing media which Do not use a solid water stream as It may scatter and spread must not be used for safety fire. reasons 5.2 Special hazards arising from the substance or mixture: Specific hazards during fire Do not use a solid water stream as it may scatter and spread fighting fire.

Further information

Collect contaminated fire extinguishing water separately. This must not be discharged into drains. 5.3 Advice for fire-fighters: Special protective equipment Regular fire intervention clothes. for fire-fighters 6. ACCIDENTAL RELEASE MEASURES 6.1 Personal precautions, protective equipment and emergency procedures: Personal precautions Cleanup personnel must use appropriate personal protective equipment. Additional advice Observe normal precautions when handling chemicals. 6.2 Environmental precautions: Environmental precautions The product should not be allowed to enter drains, water courses or the soil. 6.3 Methods and material for containment and cleaning up: Methods for cleaning up Dike the spill if necessary. If spill occurs, apply a suitable absorbent material and collect into an impervious waste container. Collect the product in a plastic vessel. Carefully collect leftovers. 6.4 Reference to other sections: For waste disposal see section 13. For personal protection see section 8. 7. HANDLING AND STORAGE 7.1 Precautions for safe handling: Advice on safe handling Prevent product from diffusing. Hygiene measures Observe normal precautions when handling chemicals.Keep away from foodstuffs, drinks and tobacco.Employees should wash their hands and face before eating, drinking, or using tobacco products. Advice on protection against Non-combustible (aqueous solution).No special protective fire and explosion measures against fire and explosion required. 7.2 Conditions for safe storage: Requirements for storage Keep container tightly closed. Protect from direct sunlight.Keep areas and containers in a dry place. Further information on storage Keep container in a well-ventilated place. conditions Advice on common storage Store away from strong alkalis and oxidizing agents. 7.3 Specific end use: This substance is used only by trained professionals under restricted conditions. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION 8.1 Control parameters: 8.1.1 Components with occupational exposure limits rsp. biological occupational exposure limits requiring monitoring: 8.1.1.1 Occupational exposure limits: Air limit values Diethylene glycol CAS-No.: 111-46-6 Basis Date: Value Type Date: EH40 WEL 2005 101 mg/m3 TWA Acetic acid CAS-No.: 64-19-7 Basis Date: Value Type Date: EU ELV 12 2009 25mg/m3 TWA Biological limit values State of matter liquid Form Liquid. Colour Colourless to yellowish Odour Smell of acetic acid Odour threshold No data available 9.1.2 Important health, safety and environmental information: pH (25 °C) 1.3 Method: Literature. Melting point/range <0°C Method: Literature. Boiling point/range > 100°C Method: Literature. Flash point >62°C Not combustible. Autoignition temperature No data available Vapour pressure Not applicable Relative vapour density No data available Relative density (20 °C) 1.104 Method: Literature. Density No data available Solubility/qualitative Miscible with water at all ratios. Water solubility No data available Partition coefficient (n- Not applicable octanol/water) Viscosity, dynamic No data available Viscosity, kinematic No data available Lower explosion limit No data available Upper explosion limit No data available Evaporation rate No data available Flammability (solid, gas) Not flammable. Method: Literature. VOC content 80.7% 10. STABILITY AND REACTIVITY 10.1 Reactivity: Reactivity Reactivity is not to be expected under normal conditions of temperature and pressureReacts with strong alkalis. 10.2 Chemical stability: Stability The product is stable under normal conditions of storage and use. 10.3 Possibility of hazardous reactions: Hazardous reactions Reacts with strong alkalis. 10.4 Conditions to avoid: Conditions to avoid Avoid contact with strong alkalis and oxidizing agents. Remove all chemicals and rinse the processing tanks thoroughly with water before using any cleansing products. 10.5 Materials to avoid: Materials to avoid No data available 10.6 Hazardous decomposition products: Hazardous decomposition No specified dangerous decomposition products are known. products 11. TOXICOLOGICAL INFORMATION 11.1 Information on toxicological effects Toxicity data specific for individual ingredients in their pure state: Toxicokinetics, metabolism and distribution: e Diethylene glycol No data available e Acetic acid No data available e 1-Phenyl-3-pyrazolidone No data available Acute effects (toxicity tests): > Acute Toxicity e Diethylene glycol Effectdose Species Value Method Acute oral toxicity LD50 rat 12,565 mg/kg Literature. Based on available data, the classification criteria are not met. Acute dermal toxicity LD50 rabbit 11,890 mg/kg Literature. Based on available data, the classification criteria are not met. Acute inhalation toxicity LC50 rat 4.6 mg/l/4h Literature. e Acetic acid Effectdose Species Value Method Acute oral toxicity LD50 rat 3,310 mg/kg Literature. Based on available data, the classification criteria are not met. Acute dermal toxicity LD50 rabbit 1,060 mg/kg Literature. Based on available data, the classification criteria are not met. Acute inhalation toxicity LC50 rat 11.4 mg/l/4 h Literature. Based on available data, the classification criteria are not met. e 1-Phenyl-3-pyrazolidone Effectdose Species Value Method Acute oral toxicity LD50 rat 200 mg/kg Literature. Acute dermal toxicity LD50 guinea pig > 1,000 mg/kg Literature. Acute inhalation toxicity No data available > Specific target organ toxicity (STOT): e Diethylene glycol Specitic effects Affected organs Kidney Central nervous GB 8/18 system Based on available data, the classification criteria are not met. e Acetic acid Specitic effects Affected organs Based on available data, the classification criteria are not met. e 1-Phenyl-3-pyrazolidone Specitic effects Affected organs No data available > Irritant and corrosive effects: e Diethylene glycol Exposure Species Evaluation Method time Primary irritation to the skin rat No skin irritation Literature. Irritation to eyes rabbit No eye irritation Literature. e Acetic acid Exposure Species Evaluation Method time Primary irritation to the skin rat Corrosive Literature. Exposure quickly causes a strong corrosive action upon all body tissue. Irritation to eyes rabbit Corrosive Literature. Risk of serious damage to eyes. e 1-Phenyl-3-pyrazolidone Exposure Species Evaluation Method time Primary irritation to the skin Literature. Repeated contact may cause allergic reactions in very susceptible persons. Irritation to eyes Literature. Contact with eyes may cause irritation. > Irritation to the respiratory tract: e Diethylene glycol No data available e Acetic acid May cause irritation of respiratory tract.Based on available data, the classification criteria are not met. e 1-Phenyl-3-pyrazolidone May cause irritation of respiratory tract. > Sensitisation: e Diethylene glycol Species Evaluation Method guinea pig Non-sensitizer Literature. GB 9/18 EN e Acetic acid Species Evaluation Method No data available e 1-Phenyl-3-pyrazolidone Species Evaluation Method Literature. Repeated contact may cause allergic reactions in very susceptible persons. > Aspiration hazard: e Diethylene glycol Based on available data, the classification criteria are not met. e Acetic acid Based on available data, the classification criteria are not met. e 1-Phenyl-3-pyrazolidone No data available Sub-acute, sub-chronic and chronic toxicity > Repeated dose toxicity: e Diethylene glycol No data available e Acetic acid No data available e 1-Phenyl-3-pyrazolidone No data available > Specific target organ toxicity (STOT): e Diethylene glycol Repeated exposure Specific effects Affected organs Central nervous system Liver Kidney Repeated or prolonged exposure: The substance can affect the liver, causing damage to the body. Does not meet the classification criteria of 3.9.2 of CLP-Regulation (EC) No 1272/2008. e Acetic acid Based on available data, the classification criteria are not met. e 1-Phenyl-3-pyrazolidone No information available. > CMR effects (carcinogenity, mutagenicity and toxicity for reproduction): - Carcinogenicity e Diethylene glycol No carcinogenic effects observed at the doses tested. Based on available data, the classification criteria are not met. GB 10/18 EN e Acetic acid No tumors were reported in mice following long-term dermal application. e 1-Phenyl-3-pyrazolidone No data available - Mutagenicity e Diethylene glycol The results of the mutagenicity tests (Ames and chromosome aberration test - metabolic activitated and non-activated groups)showed that DNA reactive metabolites (formed during hepatoic biotransformation) are not to be expected. e Acetic acid Studies using the 'Ames' test were generally negative. e 1-Phenyl-3-pyrazolidone No data available - Genetic toxicity in vitro e Diethylene glycol Type Test system Concentration Result Chromosome aberration Chinese hamster lung cells negative test in vitro Method: Literature. Based on available data, the classification criteria are not met. Ames test Escherichia coli WP2 uvr A; negative Salmonella typhimurium TA98, TA100, TA535, TA1537 Method: Literature. Based on available data, the classification criteria are not met. e Acetic acid Type Test system Concentration Result Ames test Escherichia coli WP2 uvr A; negative Salmonella typhimurium TA98, TA100, TA535, TA1537 Method: Literature. e 1-Phenyl-3-pyrazolidone No data available - Genetic toxicity in vivo e Diethylene glycol No data available e Acetic acid No data available e 1-Phenyl-3-pyrazolidone No data available - Teratogenicity e Diethylene glycol GB 11/18 EN Toxicity to bacteria No data available 12.2 Persistence and degradability: Physico-chemical removability The product evaporates slowly. Chemical Oxygen Demand (COD) Value | Method 1,150,000 mg/l | Tested according to Directive 92/69/EEC. Adsorbed organic bound halogens (AOX) Not applicable Biodegradation e Diethylene glycol Value | Exposure Method Evaluation time Literature. Readily biodegradable. e Acetic acid Value | Exposure Method Evaluation time 99% | 30d OECD 302B Inherent Readily biodegradable. biodegradability e 1-Phenyl-3-pyrazolidone Value | Exposure Method Evaluation time 64% | 28d OECD 302B Biodegradability Readily biodegradable, according to appropriate OECD test. Biochemical Oxygen Demand (BOD) e Diethylene glycol No data available e Acetic acid Concentration Incubation Value Method time 740 mg/g Literature. e 1-Phenyl-3-pyrazolidone No data available 12.3 Bioaccumulative potential: Partition coefficient (n-octanol/water) Not applicable Bioconcentration factor (BCF) Bioaccumulation is unlikely. GB 14/18 EN RID UN-No 2790 Proper shipping name ACETIC ACID SOLUTION Class 8 Packing group III Classification Code C3 Labelling No. 8 Risk No. 80 ADNR UN-No 2790 Proper shipping name ACETIC ACID SOLUTION Class 8 Packing group III Classification Code C3 Labelling No. 8 Risk No. 80 IMO /IMDG UN-No 2790 Proper shipping name ACETIC ACID SOLUTION Class 8 Packing group HI Labelling No. 8 EmS F-A, S-B Marine pollutant No ICAO / IATA cargo aircraft only UN-No 2790 Proper shipping name Acetic acid solution Class 8 Packing group HI Labelling No. 8 Packing instruction 856 ICAO / IATA passenger and cargo aircraft UN-No 2790 Proper shipping name Acetic acid solution Class Packing group HI Labelling No. 8 Packing instruction 852 15. REGULATORY INFORMATION