Note: Ingredients listed on restricted chemical lists
EC/CAS
237-158-7/9016-87-9
Name of the chemical
4,4'-Methylendiphenyldiisocyanat tech. (Polymeres) MDI, pMDI (in Form atembarer Aerosole, A-Fraktion)
Concentration
30-60
EC/CAS
200-857-2/13674-84-5
Name of the chemical
Tris(2-chloro-1-methylethyl) phosphate
Concentration
5-15
EC/CAS
204-065-8/75-28-5
Name of the chemical
iso-Butan, enthält 0,1% Butadien
Concentration
5-10
General Information
Revision date
2014-01-12
Product name
ARCTIC FOAM GUN GRADE B3
Icons in SDS
Company Information
company name
Aerosol-Service, a.s
e-mail address of the competent person responsible for the Safety Data Sheet
aerosol@aerosol.cz
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H222, H229, H315, H317, H319, H332, H334, H335, H351, H373
Hazard statements
Code
Statements
H222
Extremely flammable aerosol
Section 2
2.1 Classification of the substance or mixture
2.1.1 Classification in accordance with Directive No. 1999/45/EC Extremely flammable, F+, R12 Carc. cat 3; R40 Harmful, Xn; R20-48/20 Irritating, Xi; R36/37/38 Sensitisation; R42/43 The full text of the R phrases is stated in Section 16 of this Safety Data Sheet. 2.1.2
EU Classification
Regulation no. 1272/2008 Aerosol 1 H222, H229 Carc. 2 H351 Acute Tox. 4 H332 STOT RE 2 H373 Eye Irrit. 2 H319 STOT SE 3 H335 Skin Irrit. 2 H315 Resp. Sens. 1 H334 Skin Sens. 1 H317 The full text of “H-phrases” is stated in Section 16 of this Safety Data Sheet. Classification notes: Note: Classification of a mixture was based on the precautionary principle. The calculation method takes into account the requirements of the CLP Regulation for the classification of aerosols in line with paragraph 1.1.3.7 of Annex I, Part 1, CLP, i.e. a mixture of aerosol is classified in the same hazard category as the mixture which is not in a form of aerosol. This principle was also used in the case of classification according to Directive no. 1999/45 / EC (see section 2.1.1). 2.1.3 The most serious adverse physic-chemical effects Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C. Build up of explosive mixtures possible without sufficient ventilation. 2.1.4 The most serious adverse effects on human health Harmful by inhalation. Irritating to eyes, respiratory system and skin. Limited evidence of a carcinogenic effect. May cause sensitisation by inhalation and skin contact. Harmful: danger of serious damage to health by prolonged exposure through inhalation. Persons with airways hypersensitivity (e.g. asthma, chronic bronchitis) must not come into contact with the product. Symptoms may also occur with overexposure airways after a few hours. Dust, vapours and aerosols are harmful to respiratory tract. 2.1.5 The most serious adverse effects on the environment Presents no special hazards providing disposal requirements are followed together with national or local regulations (see section 13).
2.2 Label elements
2.2.1 Labelling harmonised with Directive 1999/45/EC extremely flammable harmful
Contains
isomers and homologues R 20 Harmful by inhalation. R 36/37/38 Irritating to eyes, respiratory system and skin. R 40 Limited evidence of a carcinogenic effect. R 42/43 May cause sensitisation by inhalation and skin contact. R 48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation. S2 Keep out of the reach of children. S23 Do not breathe vapour/spray S24/25 Avoid contact with skin and eyes. S36/37 Wear suitable protective clothing and gloves. S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S51 Use only in well-ventilated areas S60 his material and its container must be disposed of as hazardous waste Contains isocyanates. See information supplied by the manufacturer. Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. Keep away from sources of ignition - No smoking. Build up of explosive mixtures possible without sufficient ventilation 2.2.2 The label elements in accordance with Regulation no. (EC) no. 1272/2008 DANGER Diphenylmethanediisocyanate, isomers and homologues H222 Extremely flammable aerosol. H229 Pressurised container: May burst if heated. H332 Harmful if inhaled. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 May cause respiratory irritation. H351 Suspected of causing cancer H373 May cause damage to organs through prolonged or repeated exposure P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P251 Do not pierce or burn, even after use. P410+P412 Protect from sunlight. Do no expose to temperatures exceeding 50°C/122°F. P211 Do not spray on an open flame or other ignition source. P102 Keep out of reach of children. P261 Avoid breathing spray. P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P280 Wear protective gloves, protective clothing, and eye protection. P302 + P352 IF ON SKIN: Wash with plenty of water and soap. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P501 Dispose of container as hazardous waste. EUH204 Contains isocyanates. May produce an allergic reaction. Persons already sensitized to diisocyanates may develop allergic reactions when using this product. Persons suffering from asthma, eczema or skin problems should avoid contact, including dermal contact, with this product. This product should not be used under conditions of poor ventilation unless a protective mask with an appropriate gas filter (i.e. type A1 according to standard EN 14387) is used.
2.3 Other hazards
The mixture does not meet the criteria for PBT or vPvB in accordance with Annex XIII of EU Regulation 1907/2006. 2.4
Further information
Not to be used in a range of ignition sources. Further information necessary to be added to the product label complying with other regulations, see