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Hazard statements (CLP)

H333

Code

Statements

H333

May be harmful if inhaled

SECTION 2: Hazards identification

Hazard categories

​Sensitization Respiratory—Category 1 ​Eye Corrosive Category 1 ​Sensitization Skin—Category 1 ​Skin Irritation -- Category 2

Signal word

​Danger

Hazard statements

​Causes serious eye damage ​May cause allergy or asthma symptoms or breathing difficulties if inhaled. ​May cause allergic skin reaction.

Prevention

​Wear eye protection /face protection. ​Avoid breathing dust/fume/gas/mist/vapours/spray. ​In case of inadequate ventilation wear respiratory protection. ​IF INHALED: remove person to fresh air and keep comfortable for breathing. ​If experiencing respiratory symptoms: Call a POISON Center or doctor. ​Contaminated work clothing should not be allowed out of the workplace. ​Wear protective gloves. Wash hands thoroughly after handling.

Response

​IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. ​IF ON SKIN: Wash with plenty of water. ​If skin irritation or rash occurs: Get medical advice/attention. ​Take off contaminated clothing and wash it before reuse. ​Immediately call a POISON CENTER or doctor/physician.

Storage

​No Precautionary statement

Disposal

​Waste from Residues and Unused Products: Follow the waste disposal requirements of your country, state, or local authorities.

2.1 Classification of the substance or mixture

Not classified as hazardous based on IATA, IMDG, and DOT. FIRE AND EXPLOSION: ​Not considered flammable or combustible, but this product will burn if involved in a fire. ​Not classified as hazardous based on IATA, IMDG, and DOT. FIRE AND EXPLOSION: ​Not considered flammable or combustible, but this product will burn if involved in a fire.

Potential health effects

<0% of mixture consists of ingredients of unknown acute toxicity INGESTION: ​Slightly toxic by ingestion. ​<0% of mixture consists of ingredients of unknown acute toxicity INGESTION: ​Slightly toxic by ingestion. INHALATION: ​May be harmful if inhaled. Causes respiratory tract irritation. SKIN CONTACT: ​May cause slight irritation. May cause sensitization of susceptible persons. EYE CONTACT: ​Causes irritation with symptoms of reddening, tearing, stinging, and swelling. May cause corneal injury OTHER: ​Monomeric aziridines (ethyleneimine and propyleneimine) used to produce polyfunctional aziridine ​crosslinkers have shown positive genotoxic activity in all animal and bacterial systems tested and are ​known animal carcinogens, with unknown relevance to humans. Animal and bacterial studies on the ​crosslinker show a similar pattern of genotoxicity. Bioavailability of the crosslinker is less than the ​monomer, however, care should be taken to avoid exposure. CHRONIC EFFECTS OF OVEREXPOSURE: ​None APPEARANCE: ​Clear liquid

NFPA Ratings

Component Health (Blue) Flammability (Red) Reactivity (Yellow) Special (White) X - Linker