Note: Ingredients listed on restricted chemical lists
EC/CAS
67-56-1
Name of the chemical
Methanol
Concentration
N/A
General Information
Revision date
2013-02-28
Product name
MicroGuard AD708 Hard Tile Clear Gloss Treatment (Part A)
Product Synonyms
Methyl Alcohol
CAS No.
67-56-1
Icons in SDS
Company Information
company name
Adsil, Inc
Section 2
SECTION 2: Hazards identification
OSHA NFPA/HMIS Rating: Health 1, Flammability 3, Reactivity 0
Principle Routes of Exposure
Skin Contact, Eye Contact, Inhalation, Ingestion Effects of Overexposure: Skin: Causes skin irritation. Eyes: Causes eye irritation. Inhalation: Prolonged inhalation of spray mist can cause damage to respiratory tract. Ingestion: Product generates methyl alcohol, which may cause blindness and possibly death if swallowed. Signs & Symptoms of Exposure: Burning pain in the nose and throat (inhalation), pain, redness and tearing (eye exposure), itching or burning (skin exposure). SECTION 4: FIRST AID MEASURES Skin Contact: No first aid should be needed. If itching or burning occurs, wash area with soap and water. Eye Contact: Immediately flush with water for 15 minutes. Get medical attention. Inhalation: Remove to fresh air. Get medical attention if any ill effects persist. Ingestion: Get immediate medical attention. If conscious, give lukewarm water (pint or ½ liter). Do not induce vomiting. Lie down, keep warm and cover eyes to exclude light. Comments: Treat same as methyl alcohol poisoning. SECTION 5: FIRE FIGHTING MEASURES Flash Point: 46.90 F. / 8.30 C. Fire Hazards: Static electricity may accumulate and ignite vapors. Prevent a possible fire hazard by suitable means, such as bonding or grounding, vapor dilution and the like. Vapors are heavier than air and can travel along the ground to remote ignition sources such as pilot lights. Unusual Fire Hazards: Thermal breakdown of this product during fire or extremely high heat conditions may evolve the following hazardous decomposition products: Silicon Dioxide, Carbon Dioxide, and traces of incompletely burned carbon compounds, trace formaldehyde. Extinguishing Media: Carbon Dioxide (CO2), Water, Dry Chemical. Fire Fighting Procedures: Self contained breathing apparatus and full turn out gear should be worn when fighting fires involving chemicals. Heat exposure pressurizes closed containers. Evacuate area immediately. Page 2 SECTION 6: ACCIDENTAL RELEASE MEASURES Containment/Clean-up: Disposal of collected product, residues and cleanup materials may be governmentally regulated. Observe all applicable local, state and federal waste management regulations. Remove possible ignition sources and if needed, use non-sparking tools and equipment. To prevent spontaneous combustion, store rags, mops, absorbent, etc; used during cleanup only in appropriate containers or covered with water. Mop, wipe or soak up spills with absorbent material and contain for salvage or disposal. For large spills, provide diking or other appropriate containment to keep material from spreading. Clean any remaining slippery surfaces by appropriate techniques, such as washing with mild, caustic detergents or solutions or high pressure steam for larger areas. Observe any safety precautions applicable to the cleaning material used. SECTION 7: HANDLING & STORAGE Handling: No special precautions.
Storage
Keep container closed and store away from heat, sparks and open flame. Store in a cool, dry area and away from water or moisture. SECTION 8: EXPOSURE CONTROLS / PERSONAL PROTECTION Skin Protection: Wash at mealtime and end of shift; no special protection is generally needed. Eye Protection: Safety glasses at minimum. Respiratory Protection: Use respiratory protection at all times during handling and application. Protective Equipment: Eyewash station (bottle) should be within direct access of work area. Personal Hygiene: Do not get in eyes or absorbed into clothing. Avoid prolonged contact with skin. Wash thoroughly after handling. Wash contaminated clothing before reuse. Engineering Controls: For in field installations, use local exhaust ventilation when using in enclosed areas. For spray booth installations provide air-sampling data to show exposures are within recommended exposure guidelines. Industrial hygiene personnel can assist in judging the adequacy of engineering controls. SECTION 9: PHYSICAL & CHEMICAL PROPERTIES pH: Not Applicable (non-aqueous) Solubility in water: Hydrolyzes Appearance: Clear Liquid Odor: Strong Odor Specific Gravity @ 250 C: 0.95 Boiling Point: >350 C., > 950 F. Freeze Point: Not Applicable VOC Content: 310 grams per liter (Components A, B, C mixed) Method 24, adapted to multi-part coatings. SECTION 10: STABILITY & REACTIVITY Stability: Stable Hazardous Polymerization: Will not occur. Hazardous Decomposition: None known. Conditions to Avoid: Methyl alcohol forms when exposed to water or humid air. Materials to Avoid: Concentrated mineral acids, strong oxidizers, aldehydes, halogens and halogen compounds. Page 3
TOXICOLOGICAL INFORMATION
Methyl alcohol forms on contact with water, moisture or humid air. Provide ventilation to control exposure within guidelines of OSHA PEL TWA 200 ppm and ACGIH TLV – skin TWA 200 ppm, STEL 250 ppm
ECOLOGICAL INFORMATION
There is no data available. SECTION 13: DISPOSAL CONSIDERATIONS Use excess product in an alternate application. Handle disposal of waste material in a manner which complies with local, state, district and federal regulations. SECTION 14: TRANSPORT INFORMATION DOT Information (49 CFR 172.101) Proper Shipping Name: COATING SOLUTION Hazard Technical Name: ALKOXYSILANES
Hazard categories
3 Acute: Yes Chronic: Yes Fire: Yes Pressure: No Reactive: No Section 313 Toxic Chemicals: C.A.S. Number Wt% Ingredient Name 67-56-1 <2.0% Methyl Alcohol Other U.S. State Regulations: California Proposition 65: This material does not contain any chemicals known to the State of California to cause cancer or reproductive effects. Massachusetts Right-to-Know: This material contains no other listed components; Methyl Alcohol, 67-56-1. New Jersey Right-to-Know: This material contains no other listed components; Methyl Alcohol, 67-56-1. Pennsylvania Right-to-Know: This material contains no other listed components; Methyl Alcohol, 67-56-1. Canadian Regulations: This product has been classified by the raw material suppliers in accordance with the Hazard Criteria of the CPR and the MSDS contains all the information required by CPR. Canadian WHMIS: None. Canadian DSL Status: This material or its components are listed on the Canadian Domestic Substances List. Canadian Ingredient Disclosure List: This material contains no other listed components. Revision Date: February 2013 Prepared by: MSDS Coordinator @ 386-274-1382 Daytona Beach, Florida 32117 Page 4 MATERIAL SAFETY DATA SHEET SECTION 1: PRODUCT & COMPANY INFORMATION Material Identification: MicroGuard AD708 Hard Tile Clear Gloss Treatment (Part B) Adsil, Inc. 386-274-1382 PHONE 1901 Mason Avenue, Suite #101 386-274-1798 FAX Daytona Beach, FL 32117 CHEMTREC: 1-800-424-9300 SECTION 2: OSHA HAZARDOUS INGREDIENTS C.A.S. Number Wt% Ingredients Exposure Limits 7732-18-5 95-98% DI Water Not Applicable 64-19-7 2-5% Acetic Acid TWA 10 ppm, STEL n/e SECTION 3: HAZARDS IDENTIFICATION NFPA/HMIS Rating: Health 0, Flammability 0, Reactivity 0 Primary Routes of Entry: Skin Contact, Eye Contact, Inhalation, Ingestion Effects of Overexposure: Skin: May cause mild skin irritation. Eyes: May cause eye irritation. Inhalation: None. Ingestion: None.
UN Number
UN1139 Packing Group: II SECTION 15: REGULATORY INFORMATION TSCA Status: All chemical substances in this material are included on or exempted from listing on the TSCA Inventory of chemical substances. EPA SARA Title III Chemical Listings: Section 302 CERCLA Extremely Hazardous Substances: None Section 304 CERCLA Hazardous Substances: None