CRACKBOND JF-90 HD PART A

Hazard statements (CLP)

H315, H317, H318, H351, H361, H410

Code

Statements

H315

Causes skin irritation

SECTION 2: Hazards identification

Signal word

Danger

Hazard statements

H315 - Causes skin irritation. H317 - May cause an allergic skin reaction. H318 - Causes serious eye damage. H351 - Suspected of causing cancer. H361 - Suspected of damaging fertility or the unborn child. H410 - Very toxic to aquatic life with long lasting effects.

Prevention

P201 - Obtain special instructions before use. P202 - Do not handle until all safety precautions have been read and understood. P280 - Wear protective gloves, protective clothing and eye or face protection. P273 - Avoid release to the environment. P261 - Avoid breathing vapor. P264 - Wash thoroughly after handling. P272 - Contaminated work clothing must not be allowed out of the workplace.

Response

P391 - Collect spillage. P308 + P313 - IF exposed or concerned: Get medical advice or attention. P362 + P364 - Take off contaminated clothing and wash it before reuse. P363 - Wash contaminated clothing before reuse. P302 + P352 - IF ON SKIN: Wash with plenty of water. P333 + P313 - If skin irritation or rash occurs: Get medical advice or attention. P305 + P351 + P338, P310 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor.

Storage

P405 - Store locked up.

Disposal

P501 - Dispose of contents and container in accordance with all local, regional, national and international regulations.

2.3 Other hazards

None known.

2.1 Classification of the substance or mixture

SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1 SKIN SENSITIZATION - Category 1 CARCINOGENICITY - Category 2 TOXIC TO REPRODUCTION - Category 2 AQUATIC HAZARD (ACUTE) - Category 1 AQUATIC HAZARD (LONG-TERM) - Category 1 GHS label elements Hazard pictograms : Signal word : Danger Hazard statements : H315 - Causes skin irritation. H317 - May cause an allergic skin reaction. H318 - Causes serious eye damage. H351 - Suspected of causing cancer. H361 - Suspected of damaging fertility or the unborn child. H410 - Very toxic to aquatic life with long lasting effects. Section 2. Hazards identification Precautionary statements Prevention : P201 - Obtain special instructions before use. P202 - Do not handle until all safety precautions have been read and understood. P280 - Wear protective gloves, protective clothing and eye or face protection. P273 - Avoid release to the environment. P261 - Avoid breathing vapor. P264 - Wash thoroughly after handling. P272 - Contaminated work clothing must not be allowed out of the workplace. Response : P391 - Collect spillage. P308 + P313 - IF exposed or concerned: Get medical advice or attention. P362 + P364 - Take off contaminated clothing and wash it before reuse. P363 - Wash contaminated clothing before reuse. P302 + P352 - IF ON SKIN: Wash with plenty of water. P333 + P313 - If skin irritation or rash occurs: Get medical advice or attention. P305 + P351 + P338, P310 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor. Storage : P405 - Store locked up. Disposal : P501 - Dispose of contents and container in accordance with all local, regional, national and international regulations. Hazards not otherwise : None known. classified Section 3. Composition/information on ingredients Substance/mixture : Mixture Other means of : identification Ingredient name % CAS number Propane, 2,2-bis[p-(2,3-epoxypropoxy) phenyl]-, polymers ≥50 - ≤75 25085-99-8 Oxirane, Mono[(C12-14-Alkyloxy)Methyl] Derivs. ≥10 - ≤25 68609-97-2 4-Nonylphenol, Branched <5 84852-15-3 Titanium dioxide ≥0.3 - ≤1 13463-67-7 Amide ≥0.3 - <1 - Any concentration shown as a range is to protect confidentiality or is due to batch variation. There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. Section 4. First aid measures Description of necessary first aid measures Eye contact : Get medical attention immediately. Call a poison center or physician. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 20 minutes. Chemical burns must be treated promptly by a physician. Section 4. First aid measures Inhalation : Get medical attention immediately. Call a poison center or physician. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Skin contact : Get medical attention immediately. Call a poison center or physician. Wash with plenty of soap and water. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 20 minutes. Chemical burns must be treated promptly by a physician. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse. Ingestion : Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove dentures if any. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Chemical burns must be treated promptly by a physician. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Most important symptoms/effects, acute and delayed Potential acute health effects Eye contact : Causes serious eye damage. Inhalation : No known significant effects or critical hazards. Skin contact : Causes skin irritation. May cause an allergic skin reaction. Ingestion : No known significant effects or critical hazards. Over-exposure signs/symptoms Eye contact : Adverse symptoms may include the following: pain watering redness Inhalation : Adverse symptoms may include the following: reduced fetal weight increase in fetal deaths skeletal malformations Skin contact : Adverse symptoms may include the following: pain or irritation redness blistering may occur reduced fetal weight increase in fetal deaths skeletal malformations Ingestion : Adverse symptoms may include the following: stomach pains reduced fetal weight increase in fetal deaths skeletal malformations Section 4. First aid measures Indication of immediate medical attention and special treatment needed, if necessary Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments : No specific treatment. Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. See toxicological information (Section 11) Section 5. Fire-fighting measures Extinguishing media Suitable extinguishing : Use an extinguishing agent suitable for the surrounding fire. media Unsuitable extinguishing : None known. media Specific hazards arising : This material is very toxic to aquatic life with long lasting effects. Fire water from the chemical contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain. Hazardous thermal : Decomposition products may include the following materials: decomposition products carbon dioxide carbon monoxide halogenated compounds Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable training. Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode. Section 6. Accidental release measures Personal precautions, protective equipment and emergency procedures For non-emergency : No action shall be taken involving any personal risk or without suitable training. personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Do not breathe vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities. Collect spillage. Section 6. Accidental release measures Methods and materials for containment and cleaning up Small spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Large spill : Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. Section 7. Handling and storage Precautions for safe handling Protective measures : Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Avoid exposure - obtain special instructions before use. Avoid exposure during pregnancy. Do not handle until all safety precautions have been read