HP60 Epoxy Hardener

Hazard statements (CLP)

H315, H317, H318, H411

Code

Statements

H315

Causes skin irritation

2.1 Classification of the substance or mixture

Skin Sensitisation Category 1A Skin Corrosion/Irritation Category 2 Serious Eye Damage/Eye Irritation Category 1 Aquatic Toxicity (chronic): Category 2 For the full text of the H-Statements mentioned in this Section, see Section 16.

Signal word

DANGER

SECTION 2: Hazards identification

Statement H315 Causes skin irritation H317 May cause an allergic skin reaction H318 Causes serious eye damage H411 Toxic to aquatic life with long lasting effects

Prevention

P201 Obtain special instructions before use P202 Do not handle until all safety precautions have been read and understood. P260 Do not breathe dust/gas/mist/vapours P261 Avoid breathing vapours P264 Wash hands thoroughly after handling P270 Do not eat, drink or smoke when using this product P271 Use only outdoors or in a well-ventilated area P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment P280 Wear protective gloves, protective clothing, eye protection and face protection

Response

P310 Immediately call a POISON CENTER or doctor/physician. P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353 + IF ON SKIN (or hair): Remove/Take off immediately all contaminated P352 clothing. Rinse skin with water/shower. Wash with plenty of water. P304 + P340 IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P338 P312 Call a POISON CENTER or doctor/physician if you feel unwell. P361 Take off immediately all contaminated clothing. P362 + P364 Take off contaminated clothing and wash before reuse. P333 + P313 If skin irritation or rash occurs: Get medical advice/attention. P361 Remove/Take off immediately all contaminated clothing. P363 Wash contaminated clothing before reuse. P391 Collect spillage.

Storage

P405 Store locked up. Precautions Keep container closed. Handle containers with care. Open slowly in order to control possible pressure release. Store in a cool, well ventilated area.ological safety Control parameters Exposure Limits This product, as supplied, does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies. Biological occupational exposure limits Not applicable Appropriate engineering controls Engineering Controls Ensure adequate ventilation, especially in confined areas. Individual protection measures, such as personal protective equipment Eye/face protection Tight sealing safety goggles. Skin and body protection Suitable protective clothing. Hand Protection Wear suitable gloves. Where respiratory protection is required, use a respirator selected and in Respiratory protection accordance with AS/NZS 1715 and AS/NZS 1716. Environmental exposure controls No information available. Appearance Liquid Colour Amber Odour Slight amine pH Not available Vapour pressure Not available Vapour density Not available Boiling Point Not available Melting/Freezing Point Not available Solubility (water) Soluble Specific Gravity/Density 0.96 gcm-3 @ 25°C Flash Point >150°C ( closed cup) Flammable Limits LFL Not available UFL Not available Auto-ignition Not available Chemical Stability Stable under recommended storage conditions. Conditions to avoid Avoid temperatures above 300°C. Potentially violent decomposition can occur, causing gas generation and pressure increases in closed systems. Materials to avoid Reactive or incompatible with the following materials: oxidizing materials. Slightly reactive or incompatible with the following materials: acids and alkalis. Hazardous Decomposition Decomposition products may include the following materials: Products carbon oxides, phenolics and water. Acute Toxicity Information on likely routes of exposure Product Information . Inhalation Specific test data for the substance or mixture is not available. May cause irritation of respiratory tract. Eye contact Specific test data for the substance or mixture is not available. (based on components). May cause redness, itching, and pain. Severely irritating to eyes. Risk of serious damage to eyes. May cause burns. Skin contact Specific test data for the substance or mixture is not available. Causes skin irritation. (based on components). May cause sensitisation by skin contact. Repeated or prolonged contact may cause allergic reactions in very susceptible persons. Specific test data for the substance or mixture is not available. Ingestion may Ingestion cause gastrointestinal irritation, nausea, vomiting and diarrhoea. Numerical measures of toxicity - Product Information 99.99% of the mixture consists of ingredient(s) of unknown toxicity 99.99 % of the mixture consists of ingredient(s) of unknown acute oral toxicity 99.99 % of the mixture consists of ingredient(s) of unknown acute dermal toxicity 99.99 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (gas) 99.99 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (vapour) 99.99 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (dust/mist) See section 16 for terms and abbreviations Delayed and immediate effects as well as chronic effects from short and long-term exposure Acute Toxicity Information on likely routes of exposure Product Information . Inhalation Specific test data for the substance or mixture is not available. May cause irritation of respiratory tract. Eye contact Specific test data for the substance or mixture is not available. (based on components). May cause redness, itching, and pain. Severely irritating to eyes. Risk of serious damage to eyes. May cause burns. Skin contact Specific test data for the substance or mixture is not available. Causes skin irritation. (based on components). May cause sensitisation by skin contact. Repeated or prolonged contact may cause allergic reactions in very susceptible persons. Specific test data for the substance or mixture is not available. Ingestion may Ingestion cause gastrointestinal irritation, nausea, vomiting and diarrhoea. Numerical measures of toxicity - Product Information 99.99% of the mixture consists of ingredient(s) of unknown toxicity 99.99 % of the mixture consists of ingredient(s) of unknown acute oral toxicity 99.99 % of the mixture consists of ingredient(s) of unknown acute dermal toxicity 99.99 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (gas) 99.99 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (vapour) 99.99 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (dust/mist) See section 16 for terms and abbreviations Delayed and immediate effects as well as chronic effects from short and long- term exposure Skin corrosion/irritation Classification based on individual ingredients of the mixture. Irritating to skin. Serious eye damage/eye irritation Classification based on individual ingredients of the mixture. Causes burns. Risk of serious damage to eyes. Sensitisation May cause sensitisation by skin contact. Germ Cell Mutagenicity No information available. Carcinogenicity No information available. Reproductive Toxicity No information available. STOT - Single Exposure No information available. STOT - Repeated Exposure No information available. Aspiration Hazard No information available. Ecotoxicity 0% of the mixture consists of components(s) of unknown hazards to the aquatic environment Unknown Aquatic Toxicity Persistence and degradability No information available. Bioaccumulative potential No information available. Mobility Mobility in soil No information available. Other adverse effects No information available. DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY OF WATER. All disposal methods must follow all Federal, State/Provincial, and local laws and regulations. FOR UNUSED AND UNCONTAMINATED PRODUCT, the preferred options include sending to a licensed, permitted: recycler, reclaimer, incinerator, or other destruction device. General information The generation of waste should be minimised or avoided wherever possible. This material and its container must be disposed of in a safe way. Disposal of this product, process solutions, residues and by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any local authority requirements. Care should be taken when handling emptied containers that have not been thoroughly cleaned or rinsed out. Empty containers or liners may retain some product residues and hence be potentially hazardous. Disposal methods Waste, residues, empty containers, discarded work clothes and contaminated cleaning materials should be collected in designated containers, labelled with their contents. Incineration or landfill should only be considered when recycling is not feasible. Do not discharge into drains or watercourses or onto the ground. ROAD, RAIL, SEA AND AIR TRANSPORT UN Number 2735 Proper Shipping name Polyamines, liquid, corrosive, n.o.s. (mixture contains Polyamide resin (aliphatic amines & derivatives)) DG Class

Disposal

P501 Dispose of contents/ container to an approved waste disposal plant. Restricted to professional users.

2.3 Other hazards

Substance / Mixture: Mixture

Hazardous Ingredients

Chemical Name CAS No. Concentration (%) Polyamide resin (aliphatic amines & derivatives) 103758-98-1 60 - 100 Other non-hazardous components to 100 If poisoning occurs, contact a doctor or Poisons Information Centre Phone 0800 764 766. General advice: Move out of dangerous area. Call a POISON CENTRE or doctor/physician if exposed or you feel unwell. Show this safety data sheet to the doctor in attendance. Do not leave the victim unattended. Obtain medical attention. Do not give milk or alcoholic beverages. Ingestion: Never give anything by mouth to an unconscious person. If symptoms persist, call a physician. Move to fresh air. Keep patient warm and at rest. If unconscious place Inhalation: in recovery position and seek medical advice Skin Contact: Remove contaminated clothing. If irritation develops, get medical attention. If on skin, rinse well with water. Wash contaminated clothing before re-use. If on clothes, remove clothes Eye Contact: Immediately flush eye(s) with plenty of water. Remove contact lenses. Protect unharmed eye. Symptoms: Signs and symptoms of exposure to this material Notes to physician: through breathing, swallowing, and/or passage of the material through the skin may include: stomach or intestinal upset (nausea, vomiting, diarrhoea) irritation (nose, throat, airways) confusion. Hazardous Combustion Products In case of fire, the following hazardous smoke fumes may be produced: Carbon Oxides, Nitrous gases, ammonia. Fire Fighting Procedures Clear fire area of all non-emergency personnel. Isolate fire and deny unnecessary entry. Cool fire exposed containers with water. Irritating fumes are released in fire situations. Move container from fire area if this is possible without hazard. Burning liquids may be moved by flushing with water to protect personnel and minimize property damage. Do not allow material or run-off to enter waterways. Stay upwind, keep out of low areas. Fire-fighting equipment Wear positive-pressure self-contained breathing apparatus (SCBA) and protective firefighting clothing (includes firefighting helmet, coat, trousers, boots, and gloves). Avoid contact with this material during firefighting operations. If contact is likely, change to full chemical resistant firefighting clothing with self-contained breathing apparatus. If this is not available, wear full chemical resistant clothing with self-contained breathing apparatus and fight fire from a remote location HAZCHEM *3Z Emergency procedures: Personal precautions: Evacuate personnel to safe areas. Remove all sources of ignition. Use personal protective equipment. Ensure adequate ventilation. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed. Comply with all applicable federal, state, and local regulations. Suppress (knock down) gases/vapours/mists with a water spray jet. Environmental precautions: Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. Methods for containment & Contain spillage, and then collect with noncombustible absorbent clean up: material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations Handling advice: Open drum carefully as content may be under pressure. Avoidformation of aerosol. Provide sufficient air exchange and/or exhaust in work rooms. Do not breathe vapours/dust. Do not smoke. Container hazardous when empty. Take precautionary measures against static discharges. Avoid exposure - obtain special instructions before use. Avoid contact with skin and eyes. Smoking, eating and drinking should be prohibited in the application area. For personal protection see section 8. Dispose of rinse water in accordance with local and national regulations. Secondary operations, such as grinding and sanding, may roduce dust. Maintain good housekeeping. Do not permit dust layers to accumulate, for example, on floors, ledges, and equipment, in order to avoid any potential for dust explosion hazards. Storage advice: Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Observe label precautions. No smoking. Electrical installations / working materials must comply with the technological safety standards. Handling Precautions: Avoid breathing vapors. Use in a well-ventilated area. Wear rubber gloves (nitrile or butyl) and chemical resistant apron. Wear chemical splash goggles. Do not reuse empty containers.