Argosy

ADAMA New Zealand Ltd

Revision date : 2024-03-13

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GHS09 GHS08 GHS07
Health risk rating 5
Safety risk rating 1
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

EC/CAS

1689-99-2

Name of the chemical

2,6-Dibrom-4-cyanphenyloctanoat

Concentration

N/A

EC/CAS

68412-54-4

Name of the chemical

Nonylphenolethoxylates (NPEO)

Concentration

5-10

General Information

Revision date

2024-03-13

Product name

Argosy

Chemical name

Blend of diflufenican and bromoxynil in a suitable solvent

1.2.1 Relevant identified uses

Herbicide

1.2.2. Uses advised against

Refer to Section 15

Emergency telephone

+64 3 543 8275, +64 3 543 8274

Icons in SDS

GHS07 GHS08 GHS09 M009 M010

Company Information

company name

ADAMA New Zealand Ltd

GHS Information

Signal word

DANGER

Hazard Codes

Hazard statements (CLP)

H227, H302, H313, H315, H317, H319, H332, H360, H373, H421, H432

Hazard statements

Code

Statements

H227

Combustible liquid

Section 2

SECTION 2: Hazards identification

Notice 2017 This substance is hazardous according to the Hazardous Substances (Classification) Notice 2017 EPA Approval No: HSR100855

Hazard pictograms

Toxic/Irritant Chronic Ecotoxic

Signal word

DANGER HSNO Hazard Code Hazard Statement

Hazard categories

Classification 3.1D H227 Combustible liquid Flam. Liq. 4 6.1D (oral) H302 Harmful if swallowed Acute Tox. 4 6.1D (inh) H332 Harmful if inhaled Acute Tox. 4 6.1E (dermal) H313 May be harmful in contact with Acute Tox. 5 skin 6.3A H315 Causes skin irritation Skin Irrit. 2 6.4A H319 Causes serious eye irritation Eye Irrit. 2A 6.5B H317 May cause an allergic skin reaction. Skin Sens. 1 6.8A H360 May damage fertility or the unborn Repr. 1A/Repr. 1B child May cause damage to organs 6.9B H373 through prolonged or repeated STOT RE 2 exposure if swallowed 9.1A H410 Very toxic to aquatic life with long Aquatic Acute lasting effects 1/Aquatic Chronic 1 9.2A H421 Very toxic to the soil environment 9.3B H432 Toxic to terrestrial vertebrates Prevention Prevention Statement Code P102 Keep out of reach of children P103 Read label before use P201 Obtain special instructions before use P202 Do not handle until all safety precautions have been read and understood P210 Keep away from heat, sparks, open flames or hot surfaces. No smoking P260 Do not breathe fumes, mist, vapours or spray P264 Wash hands thoroughly after handling P270 Do not eat, drink or smoke when using this product P271 Use only outdoors or in a well-ventilated area P272 Contaminated work clothing should not be allowed out of the workplace P273 Avoid release to the environment P280 Wear protective clothing as detailed in Section 8 P281 Use personal protective equipment as required Response Code Response Statement P101 If medical advice is needed, have product container or label at hand P312 Call a POISON CENTER or doctor/physician if you feel unwell P330 Rinse mouth P362 Take off contaminated clothing and wash before re-use P391 Collect spillage P301 + P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell P302 + P352 IF ON SKIN: Wash with plenty of soap and water P304 + P340 IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing P305 + IF IN EYES: Rinse cautiously with water for several minutes. Remove P351+P338 contact lenses, if present and easy to do. Continue rinsing P308 + P313 IF exposed or concerned: Get medical advice/ attention P333 + P313 If skin irritation or rash occurs: Get medical advice/attention P337 + P313 If eye irritation persists: Get medical advice/attention Storage Code Storage Statement P405 Store locked up P403 + P235 Store in a well-ventilated place. Keep cool Disposal Code

Disposal

P501 Wherever possible completely use material by using according to label instructions. Dispose of unwanted product and wastes from spillages as hazardous substances in accordance with local and national regulations using a licensed waste disposal company. Triple rinse containers and add rinsate to spray tank before puncturing and offering for recycling or landfill. Do not allow product to enter waterways. Do not burn product or container.

2.1 Classification of the substance or mixture

Classification 3.1D H227 Combustible liquid. Flam. Liq. 4 6.1D (oral) H302 Harmful if swallowed. Acute Tox. 4 6.1D (inh) H332 Harmful if inhaled. Acute Tox. 4 6.1E (dermal) H313 May be harmful in contact with Acute Tox. 5 skin. 6.3A H315 Causes skin irritation. Skin Irrit. 2 6.4A H319 Causes serious eye irritation. Eye Irrit. 2A 6.5B H317 May cause an allergic skin reaction. Skin Sens. 1 6.8A H360 May damage fertility or the unborn Repr. 1A/Repr. 1B child. May cause damage to organs 6.9B H373 through prolonged or repeated STOT RE 2 exposure if swallowed. 9.1A H410 Very toxic to aquatic life with long Aquatic Acute lasting effects. 1/Aquatic Chronic 1 9.2A H421 Very toxic to the soil environment. - 9.3B H432 Toxic to terrestrial vertebrates. - Prevention Prevention Statement Code P102 Keep out of reach of children. P103 Read label before use. P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat, sparks, open flames or hot surfaces. No smoking. P260 Do not breathe fumes, mist, vapours or spray. P264 Wash hands thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective clothing as detailed in Section 8. P281 Use personal protective equipment as required. Response Code Response Statement P101 If medical advice is needed, have product container or label at hand. P312 Call a POISON CENTER or doctor/physician if you feel unwell. P330 Rinse mouth. P362 Take off contaminated clothing and wash before re-use. P391 Collect spillage. P301 + P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P304 + P340 IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. P305 + IF IN EYES: Rinse cautiously with water for several minutes. Remove P351+P338 contact lenses, if present and easy to do. Continue rinsing. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P333 + P313 If skin irritation or rash occurs: Get medical advice/attention. P337 + P313 If eye irritation persists: Get medical advice/attention. Storage Code Storage Statement P405 Store locked up. P403 + P235 Store in a well-ventilated place. Keep cool. Disposal Code

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