Note: Ingredients listed on restricted chemical lists
EC/CAS
120068-37-3
Name of the chemical
Fipronil; 5-Amino-1-[2,6-dichloro-4-(trifluoromethyl)phenyl]-4-[(trifluoromethyl)sulfinyl]-1H-pyrazole-3-carbonitrile
Concentration
N/A
General Information
Revision date
2021-07-05
Product name
Warden 100 SC Insecticide
CAS No.
120068-37-3
1.2.1 Relevant identified uses
Termiticide for use as described on the product label
Emergency telephone
1800 024 973 (24 hours
Icons in SDS
Company Information
company name
ADAMA Australia Pty Ltd
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H302, H312, H315, H320, H332, H335, H372, H410
Hazard statements
Code
Statements
H302
Harmful if swallowed
Section 2
Hazard statements
This product is classified as: Hazardous according to the criteria of SWA. Not subject to the ADG Code when transported in Australia by Road or Rail in packages 500kg(L) or less; or IBCs (refer to SP AU01). However if transported by Air or Sea, this provision does not apply. Then the product is classed as Dangerous (Class 9 Environmentally Hazardous) by IATA and IMDG/IMSBC respectively. See details below and in Section 14 of this SDS. H302: Harmful if swallowed. H312: Harmful in contact with skin. H315: Causes skin irritation. H320: Causes eye irritation. H332: Harmful if inhaled. H335: May cause respiratory irritation. H372: Causes damage to organs through prolonged or repeated exposure. H410: Very toxic to aquatic life with long lasting effects.
SUSMP Classification
S5
ADG classification
Class 9 Miscellaneous dangerous goods
UN Number
3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S
Signal word
DANGER Acute Toxicity Oral Category 4 Acute Toxicity Dermal Category 4 Skin Corrosion /Irritation Category 2 Serious eye damage/eye irritation Category 2B Acute Toxicity Inhalation Category 4 Specific Target Organ Toxicity - Single Exposure Category 3 Specific Target Organ toxicity - repeated exposure Category 1 Hazardous to aquatic environment Short term/Chronic Category 1
Prevention
P261: Avoid breathing fumes, mists, vapours or spray. P262: Do not get in eyes, on skin, or on clothing. P264: Wash contacted areas thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P271: Use only outdoors or in a well ventilated area. P273: Avoid release to the environment. P280: Wear protective gloves, protective clothing and eye or face protection.
Response
P314: Get medical advice or attention if you feel unwell. P362: Take off contaminated clothing and wash before reuse. P301+P330+P331 IF SWALLOWED Rinse mouth. Do NOT induce vomiting P302+P352 IF ON SKIN Wash with plenty of soap and water P304+P340 IF INHALED Remove victim to fresh air and keep at rest in a position comfortable for breathing P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P332+P313 If skin irritation occurs Get medical advice P337+P313 If eye irritation persists Get medical advice P391: Collect spillage.
Storage
P403: Store in a well-ventilated place. P405: Store locked up. P410: Protect from sunlight. P403+P233: Store in a well-ventilated place. Keep container tightly closed.
Disposal
P501: Dispose of contents and containers as specified on the registered label. Emergency Overview Physical Description & colour: Light brown coloured viscous liquid. Odour: No odour.
Health hazards
In a toxicity study involving rats, the clinical signs of toxicity did not reach their peak until two days after treatment in some animals, and deaths did not occur until four days after treatment. Some signs of toxicity and body-weight loss were still evident when the observation period ended at day 7 after treatment. Harmful by inhalation, in contact with skin, and if swallowed, irritating to eyes and skin.