Warden 100 SC Insecticide

ADAMA Australia Pty Ltd

Revision date : 2021-07-05

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GHS07 GHS08 GHS09
Health risk rating 4
Safety risk rating 1
Environmental risk rating 5

Note: Ingredients listed on restricted chemical lists

EC/CAS

120068-37-3

Name of the chemical

Fipronil; 5-Amino-1-[2,6-dichloro-4-(trifluoromethyl)phenyl]-4-[(trifluoromethyl)sulfinyl]-1H-pyrazole-3-carbonitrile

Concentration

N/A

General Information

Revision date

2021-07-05

Product name

Warden 100 SC Insecticide

CAS No.

120068-37-3

1.2.1 Relevant identified uses

Termiticide for use as described on the product label

Emergency telephone

1800 024 973 (24 hours

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Company Information

company name

ADAMA Australia Pty Ltd

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H302, H312, H315, H320, H332, H335, H372, H410

Hazard statements

Code

Statements

H302

Harmful if swallowed

Section 2

Hazard statements

This product is classified as: Hazardous according to the criteria of SWA. Not subject to the ADG Code when transported in Australia by Road or Rail in packages 500kg(L) or less; or IBCs (refer to SP AU01). However if transported by Air or Sea, this provision does not apply. Then the product is classed as Dangerous (Class 9 Environmentally Hazardous) by IATA and IMDG/IMSBC respectively. See details below and in Section 14 of this SDS. H302: Harmful if swallowed. H312: Harmful in contact with skin. H315: Causes skin irritation. H320: Causes eye irritation. H332: Harmful if inhaled. H335: May cause respiratory irritation. H372: Causes damage to organs through prolonged or repeated exposure. H410: Very toxic to aquatic life with long lasting effects.

SUSMP Classification

S5

ADG classification

Class 9 Miscellaneous dangerous goods

UN Number

3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S

Signal word

DANGER Acute Toxicity Oral Category 4 Acute Toxicity Dermal Category 4 Skin Corrosion /Irritation Category 2 Serious eye damage/eye irritation Category 2B Acute Toxicity Inhalation Category 4 Specific Target Organ Toxicity - Single Exposure Category 3 Specific Target Organ toxicity - repeated exposure Category 1 Hazardous to aquatic environment Short term/Chronic Category 1

Prevention

P261: Avoid breathing fumes, mists, vapours or spray. P262: Do not get in eyes, on skin, or on clothing. P264: Wash contacted areas thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P271: Use only outdoors or in a well ventilated area. P273: Avoid release to the environment. P280: Wear protective gloves, protective clothing and eye or face protection.

Response

P314: Get medical advice or attention if you feel unwell. P362: Take off contaminated clothing and wash before reuse. P301+P330+P331 IF SWALLOWED Rinse mouth. Do NOT induce vomiting P302+P352 IF ON SKIN Wash with plenty of soap and water P304+P340 IF INHALED Remove victim to fresh air and keep at rest in a position comfortable for breathing P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P332+P313 If skin irritation occurs Get medical advice P337+P313 If eye irritation persists Get medical advice P391: Collect spillage.

Storage

P403: Store in a well-ventilated place. P405: Store locked up. P410: Protect from sunlight. P403+P233: Store in a well-ventilated place. Keep container tightly closed.

Disposal

P501: Dispose of contents and containers as specified on the registered label. Emergency Overview Physical Description & colour: Light brown coloured viscous liquid. Odour: No odour.

Health hazards

In a toxicity study involving rats, the clinical signs of toxicity did not reach their peak until two days after treatment in some animals, and deaths did not occur until four days after treatment. Some signs of toxicity and body-weight loss were still evident when the observation period ended at day 7 after treatment. Harmful by inhalation, in contact with skin, and if swallowed, irritating to eyes and skin.

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