Leopard 200 EC Herbicide

Hazard statements (CLP)

H227, H302, H304, H315, H320, H335, H360, H410

Code

Statements

H227

Combustible liquid

SECTION 2: Hazards identification

SUSMP Classification

S6

ADG classification

Class 9 Miscellaneous dangerous goods

UN Number

3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S

Signal word

DANGER Flammable liquids – category 4 Acute toxicity (oral) – category 4

Aspiration hazard

– category 1 Skin irritation – category 2 Eye irritation – category 2B Specific target organ toxicity (single exposure) – category 3 Reproductive toxicity – category 1 Hazardous to the aquatic environment (chronic) – category 1

Hazard statements

H227: Combustible liquid. AUH066: Repeated exposure may cause skin dryness or cracking. H302: Harmful if swallowed. H304: May be fatal if swallowed and enters airways. H315: Causes skin irritation. H320: Causes eye irritation. H335: May cause respiratory irritation. H360: May damage fertility or the unborn child. H410: Very toxic to aquatic life with long lasting effects.

Prevention

P201: Obtain special instructions before use. P202: Do not handle until all safety precautions have been read and understood. P210: Keep away from heat, sparks, open flames and hot surfaces. - No smoking. P261: Avoid breathing fumes, mists, vapours or spray. P264: Wash contacted areas thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P271: Use only outdoors or in a well ventilated area. P280: Wear protective gloves, protective clothing and eye or face protection. P281: Use personal protective equipment as required.

Response

P330: Rinse mouth. P331: Do NOT induce vomiting. P362: Take off contaminated clothing and wash before reuse. P301+P310 IF SWALLOWED Immediately call a POISON CENTRE or doctor P303+P361+P353 IF ON SKIN (or hair) Remove immediately all contaminated clothing. Rinse skin with water P304+P340 IF INHALED Remove victim to fresh air and keep at rest in a position comfortable for breathing P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 If exposed or concerned Get medical advice P332+P313 If skin irritation occurs Get medical advice P337+P313 If eye irritation persists Get medical advice P391: Collect spillage. P370+P378: In case of fire, use carbon dioxide, dry chemical, foam, water fog. Alcohol resistant foam is the preferred firefighting medium but, if it is not available, normal foam can be used.

Storage

P405: Store locked up. P402+P404: Store in a dry place. Store in a closed container. P403+P235: Store in a well-ventilated place. Keep cool.

Disposal

P501: Dispose of contents and containers as specified on the registered label. Emergency Overview Physical Description & colour: Clear amber coloured liquid. Odour: Characteristic odour.

Health hazards

Pure Quizalofop-p-ethyl is harmful by oral exposure. The reported oral LD50 values of the compound are 1210 to 1670 mg/kg in male rats, and 1182 to 1480 mg/kg in female rats. Mice are only slightly less susceptible to the compound. Quizalofop-p-ethyl has reported LD50 values of 1753 to 2350 mg/kg in male mice and 1805 to 2360 mg/kg in female mice. This product may cause harm to unborn children, irritating to eyes, respiratory system and skin, harmful if swallowed, if aspirated, may cause lung damage, repeated exposure may cause skin dryness or cracking.