Firepower Herbicide

Hazard statements (CLP)

H302, H315, H320, H332, H410

Code

Statements

H302

Harmful if swallowed

Hazard statements

This product is classified as: Xn, Harmful. Xi, Irritating. Hazardous according to the criteria of SWA. Not subject to the ADG Code when transported in Australia by Road or Rail in packages 500kg(L) or less; or IBCs (refer to SP AU01). However if transported by Air or Sea, this provision does not apply. Then the product is classed as Dangerous (Class 9 Environmentally Hazardous) by IATA and IMDG/IMSBC respectively. See details below and in Section 14 of this SDS. H302: Harmful if swallowed. H315: Causes skin irritation. H320: Causes eye irritation. H332: Harmful if inhaled. H410: Very toxic to aquatic life with long lasting effects.

SUSMP Classification

S6

ADG classification

Class 9 Miscellaneous dangerous goods

UN Number

3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S

Signal word

WARNING Acute Toxicity Oral Category 4 Skin Corrosion /Irritation Category 2 Serious eye damage/eye irritation Category 2B Acute Toxicity Inhalation Category 4 Hazardous to aquatic environment Short term/Chronic Category 1

Prevention

P102: Keep out of reach of children. P261: Avoid breathing fumes, mists, vapours or spray. P262: Do not get in eyes, on skin, or on clothing. P264: Wash contacted areas thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P271: Use only outdoors or in a well ventilated area. P273: Avoid release to the environment. P280: Wear protective gloves, protective clothing and eye or face protection.

Response

P312: Call a POISON CENTER or doctor if you feel unwell. P362: Take off contaminated clothing and wash before reuse. P301+P312 IF SWALLOWED Call a POISON CENTER or doctor if you feel unwell P301+P330+P331 IF SWALLOWED Rinse mouth. Do NOT induce vomiting P302+P352 IF ON SKIN Wash with plenty of soap and water P304+P340 IF INHALED Remove victim to fresh air and keep at rest in a position comfortable for breathing P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P332+P313 If skin irritation occurs Get medical advice P337+P313 If eye irritation persists Get medical advice P370+P378: Not combustible. Use extinguishing media suited to burning materials.

Storage

P410: Protect from sunlight. P402+P404: Store in a dry place. Store in a closed container. P403+P235: Store in a well-ventilated place. Keep cool.

Disposal

P501: Dispose of contents and containers as specified on the registered label. Emergency Overview Physical Description & colour: Brown coloured liquid. Odour: Characteristic solvent odour.

Health hazards

For Haloxyfop-methyl the oral LD50 is 393 mg/kg for rats. The LD50 is greater than 5,000 mg/kg for rabbits whose skin is exposed to Haloxyfop-methyl. Haloxyfop-ethoxyethyl has an oral LD50 of 518-531 mg/kg for rats. The dermal LD50 is greater than 2000 mg/kg for rats and greater than 5,000 mg/kg for rabbits. Both Haloxyfop forms are non-irritating to skin and do not cause skin sensitization. They are mild eye irritants. The symptoms of toxicity in rats are reduced food intake and reduced food consumption. They may also cause liver and kidney damage. irritating to eyes and skin, harmful if swallowed.