Fairgro Fungicide

Hazard statements (CLP)

H302, H315, H317, H319, H332, H335, H373, H410

Code

Statements

H302

Harmful if swallowed

Hazard statements

This product is classified as: Hazardous according to the criteria of SWA Australia. Not subject to the ADG Code when transported in Australia by Road or Rail in packages 500kg(L) or less; or IBCs (refer to SP AU01). However if transported by Air or Sea, this provision does not apply. Then the product is classed as Dangerous (Class 9 Environmentally Hazardous) by IATA and IMDG/IMSBC respectively. See details below and in Section 14 of this SDS. H302: Harmful if swallowed. H315: Causes skin irritation. H317: May cause an allergic skin reaction. H319: Causes serious eye irritation. H332: Harmful if inhaled. H335: May cause respiratory irritation. H373: May cause damage to organs through prolonged or repeated exposure. H410: Very toxic to aquatic life with long lasting effects.

SUSMP Classification

S6

ADG classification

Class 9 Miscellaneous dangerous goods

UN Number

3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Thiram, Thiabendazole)

Signal word

WARNING Acute Toxicity Oral Category 4 Skin Irritation Category 2 Skin Sensitisation Category 1 Serious eye irritation Category 2 Acute Toxicity Inhalation Category 4 Specific Target Organ Toxicity - Single Exposure Category 3 Specific Target Organ toxicity - repeated exposure Category 2 Hazardous to aquatic environment Short term/Chronic Category 1

Prevention

P260: Do not breathe fumes, mists, vapours or spray. P262: Do not get in eyes, on skin, or on clothing. P264: Wash contacted areas thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P271: Use only outdoors or in a well ventilated area. P272: Contaminated work clothing should not be allowed out of the workplace. P273: Avoid release to the environment. P280: Wear protective gloves, protective clothing and eye or face protection.

Response

P314: Get medical advice or attention if you feel unwell. P362: Take off contaminated clothing and wash before reuse. P301+P330+P331 IF SWALLOWED Rinse mouth. Do NOT induce vomiting P302+P352 IF ON SKIN Wash with plenty of soap and water P304+P340 IF INHALED Remove victim to fresh air and keep at rest in a position comfortable for breathing P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333+P313 If skin irritation or rash occurs Get medical advice P337+P313 If eye irritation persists Get medical advice P391: Collect spillage. P370+P378: Not combustible. Use extinguishing media suited to burning materials. Alcohol resistant foam is the preferred firefighting medium but, if it is not available, normal foam can be used.

Storage

P405: Store locked up. P403+P233: Store in a well-ventilated place. Keep container tightly closed. P410+P403: Protect from sunlight. Store in a well-ventilated place.

Disposal

P501: Dispose of contents and containers as specified on the registered label. Emergency Overview Physical Description & colour: Opaque green liquid. Odour: Mild odour.

Health hazards

Thiram is irritating to the eyes, skin, and respiratory tract. It is a skin sensitizer. Symptoms of acute inhalation exposure to Thiram include itching, scratchy throat, hoarseness, sneezing, coughing, inflammation of the nose or throat, bronchitis, dizziness, headache, fatigue, nausea, diarrhoea, and other gastrointestinal complaints. Persons with chronic respiratory or skin disease are at increased risk from exposure to Thiram. Ingestion of Thiram and alcohol together may cause stomach pains, nausea, vomiting, headache, slight fever, and possible dermatitis. May cause irreversible effects, harmful by inhalation and if swallowed, irritating to eyes and respiratory system, possible skin sensitiser.