Cavalier Herbicide

Hazard statements (CLP)

H227, H304, H315, H320, H335, H360, H410

Code

Statements

H227

Combustible liquid

SECTION 2: Hazards identification

Hazard statements

This product is classified as: Hazardous according to the criteria of SWA Australia. Not subject to the ADG Code when transported in Australia by Road or Rail in packages 500kg(L) or less; or IBCs (refer to SP AU01). However if transported by Air or Sea, this provision does not apply. Then the product is classed as Dangerous (Class 9 Environmentally Hazardous) by IATA and IMDG/IMSBC respectively. See details below and in Section 14 of this SDS. H227: Combustible liquid. H304: May be fatal if swallowed and enters airways. H315: Causes skin irritation. H320: Causes eye irritation. H335: May cause respiratory irritation. H360: May damage fertility or the unborn child. H410: Very toxic to aquatic life with long lasting effects.

SUSMP Classification

S5

ADG classification

Class 9 Miscellaneous dangerous goods

UN Number

3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S

Signal word

DANGER Flammable liquids Category 4

Aspiration hazard

Category 1 Skin Corrosion /Irritation Category 2 Serious eye damage/eye irritation Category 2B Specific Target Organ Toxicity - Single Exposure Category 3 Reproductive Toxicity Category 1 Hazardous to aquatic environment Short term/Chronic Category 1

Prevention

P102: Keep out of reach of children. P201: Obtain special instructions before use. P202: Do not handle until all safety precautions have been read and understood. P210: Keep away from heat, sparks, open flames and hot surfaces. - No smoking. P261: Avoid breathing fumes, mists, vapours or spray. P262: Do not get in eyes, on skin, or on clothing. P264: Wash contacted areas thoroughly after handling. P271: Use only outdoors or in a well ventilated area. P273: Avoid release to the environment. P280: Wear protective gloves, protective clothing and eye or face protection.

Response

P312: Call a POISON CENTRE or doctor if you feel unwell. P362: Take off contaminated clothing and wash before reuse. P301+P310 IF SWALLOWED Immediately call a POISON CENTRE or doctor P301+P330+P331 IF SWALLOWED Rinse mouth. Do NOT induce vomiting P302+P352 IF ON SKIN Wash with plenty of soap and water P304+P340 IF INHALED Remove victim to fresh air and keep at rest in a position comfortable for breathing P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P332+P313 If skin irritation occurs Get medical advice P337+P313 If eye irritation persists Get medical advice P391: Collect spillage. P370+P378: Not combustible. Use extinguishing media suited to burning materials. Alcohol resistant foam is the preferred firefighting medium but, if it is not available, normal foam can be used.

Storage

P405: Store locked up. P410: Protect from sunlight. P402+P404: Store in a dry place. Store in a closed container. P403+P235: Store in a well-ventilated place. Keep cool.

Disposal

P501: Dispose of contents and containers as specified on the registered label. Emergency Overview Physical Description & colour: Clear, dark amber liquid. Odour: Aromatic, fragrant floral odour.

Health hazards

Oxyfluorfen is practically nontoxic by ingestion, with reported oral LD50 values of 5000 mg/kg in both rats and dogs, and 2700 to 5000 mg/kg in mice. The dermal LD50 is greater than 5000 mg/kg in both rats and rabbits, also indicating slight toxicity by this route. It causes no skin irritation in rabbits, no skin sensitization in guinea pigs, and moderate eye irritation in rabbits. This product is irritating to eyes and skin.