Bronco MA Herbicide

Hazard statements (CLP)

H227, H302, H312, H315, H317, H320, H332, H335, H361, H410

Code

Statements

H227

Combustible liquid

Hazard statements

This product is classified as: Hazardous according to the criteria of SWA Australia. Not a Dangerous Good according to Australian Dangerous Goods (ADG) Code, IATA and IMDG/IMSBC criteria. R63, R20/21/22, R36/38. Possible risk of harm to the unborn child. Harmful by inhalation, in contact with skin, and if swallowed. Irritating to eyes and skin. H227: Combustible liquid. H302: Harmful if swallowed. H312: Harmful in contact with skin. H315: Causes skin irritation. H317: May cause an allergic skin reaction. H320: Causes eye irritation. H332: Harmful if inhaled. H335: May cause respiratory irritation. H361: Suspected of damaging fertility or the unborn child. H410: Very toxic to aquatic life with long lasting effects.

Precautionary statements

S20, S38, S24/25. When using, do not eat or drink. In case of insufficient ventilation, wear suitable respiratory equipment. Avoid contact with skin and eyes.

SUSMP Classification

S6

ADG classification

None allocated. Not a Dangerous Good

UN Number

None allocated

Signal word

WARNING Flammable liquids Category 4 Acute Toxicity Oral Category 4 Acute Toxicity Dermal Category 4 Skin Irritation Category 2 Skin Sensitisation Category 1 Eye irritation Category 2B Acute Toxicity Inhalation Category 4 Specific Target Organ Toxicity - Single Exposure Category 3 Reproductive Toxicity Category 2 Hazardous to aquatic environment Short term/Chronic Category 1

Prevention

P102: Keep out of reach of children. P201: Obtain special instructions before use. P202: Do not handle until all safety precautions have been read and understood. P210: Keep away from heat, sparks, open flames and hot surfaces. - No smoking. P261: Avoid breathing fumes, mists, vapours or spray. P262: Do not get in eyes, on skin, or on clothing. P264: Wash contacted areas thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P271: Use only outdoors or in a well ventilated area. P272: Contaminated work clothing should not be allowed out of the workplace. P273: Avoid release to the environment. P280: Wear protective gloves, protective clothing and eye or face protection.

Response

P362: Take off contaminated clothing and wash before reuse. P301+P312 IF SWALLOWED Call a POISON CENTRE or doctor if you feel unwell P301+P330+P331 IF SWALLOWED Rinse mouth. Do NOT induce vomiting P302+P352 IF ON SKIN Wash with plenty of soap and water P304+P340 IF INHALED Remove victim to fresh air and keep at rest in a position comfortable for breathing P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 If exposed or concerned Get medical advice P333+P313 If skin irritation or rash occurs Get medical advice P337+P313 If eye irritation persists Get medical advice P391: Collect spillage. P370+P378: In case of fire, use carbon dioxide, dry chemical, foam, water fog.

Storage

P405: Store locked up. P410: Protect from sunlight. P402+P404: Store in a dry place. Store in a closed container. P403+P235: Store in a well-ventilated place. Keep cool.

Disposal

P501: Dispose of contents and containers as specified on the registered label. Emergency Overview Physical Description & colour: Brown to amber coloured liquid. Odour: Characteristic odour.

Health hazards

Technical Bromoxynil has an oral LD50 of 190 mg/kg in rats, an LD50 of 260 mg/kg in rabbits, and an LD50 of 63 mg/kg in guinea pigs, indicating moderate acute toxicity. The dermal LD50 of Bromoxynil is greater than 2000 mg/kg in rabbits. The compound is a slight eye irritant but it is not a skin irritant in rabbits. However, when in contact with abraded skin, Bromoxynil may produce a mild irritation. Harmful by inhalation, in contact with skin, and if swallowed, irritating to eyes and skin, possible skin sensitiser, possible risk of harm to the unborn child.