General Information
Revision date
2016-05-17
Product name
In the Garden Rose and Geranium SM003 RG
Product Synonyms
None
CAS No.
65405-77-8
Emergency telephone
0203 488 2001
Icons in SDS
Company Information
company name
Active Minds
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H302, H315, H317, H318, H319
Hazard statements
Code
Statements
H302
Harmful if swallowed
Section 2
CLP CLASSIFICATION
Class and category of Eye Damage /Irritation Category 2 danger: Sensitization - Skin Category 1 H317, May cause an allergic skin reaction. H319, Causes serious eye irritation. Classification under Directive 1999/45/EC
Hazard pictograms
Xi, Irritant.
Hazard statements
R43, May cause sensitisation by skin contact. H317, May cause an allergic skin reaction. H319, Causes serious eye irritation. Page 2 ( 7 ) Active M1i!s Issue date 17/0512016 Version: 4 (17/05/2016) SAFETY DATA SHEET In accordance with REACH Regulation EC No.1907/2006 Product In the Garden Rose and Geranium SM003 RG Version: 4 Supplemental EUH208, Contains Nerol. May produce an allergic reaction. lnfonnation:
Signal word
Warning
Precautionary statements
P261, Avoid breathing vapour or dust. P264, Wash hands and other contacted skin thoroughly after handling. P272, Contaminated work clothing should not be allowed out of the workplace. P280, Wear protective gloves/eye protection/face protection. P302/352, IF ON SKIN: Wash with plenty of soap and water. P305/351/338, IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333/313, If skin irritation or rash occurs: Get medical advice/attention. P337/313, If eye irritation persists: Get medical advice/attention. P363, Wash contaminated clothing before reuse. P501, Dispose of contents/container to approved disposal site, in accordance with local regulations. Plctograms:
2.3 Other hazards
None Section 3. Composition I infonnation on Ingredients 3.2 Mixtures
Contains
Name CAS EC REACH Registration % Classification for (DSD) Classification for (CLP) No.
67/548/EEC
127212008 Phenethyl alcohol 60-12-8 200-456-2 1-<5% Xn; R22-R36 ATO 4-ED12,H302-H319,- di-Citronellol 106-22-9 203-375·0 1-<5% Xi-N ; R38-R43-R51/53 SCI 2-EDI 2-SS 1 B;H31 5- H317-H319- Geraniol 106-24-1 203-377-1 0.1-<1% Xi ; R38-R41-R43 SCI2-EDI 1-SS 1;H315- H317-H318- Nero! 106-25-2 203-378-7 10.1-<1% Xi ; R43-R36138 SCI2-EDI 2-SS 1B;H315- H317-H319.- Substances with Community workplace exposure limits, not listed above: Not Applicable Substances that are persistent, bioaccumulative and toxic or very persistent and very bloaccumulative, greater than 0.1%: Not Applicable Page 3 ( 7 ) Issue date 17/05/2016 Version: 4 (1710512016) SAFETY DATA SHEET In accordance with REACH Regulation EC No.190712006 Product In the Garden Rose and Geranium SM003 RG Version: 4 Section 4. First-aid measures 4.1 Desaiption of first aid measures IF ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. 4.2 Most Important symptoms and effects, both acute and delayed May cause an allergic skin reaction. Causes serious eye irritation. 4.3 Indication of any immediate medical attention and special treatment needed None expected, see Section 4.1 for further information. SECTION 5: Eireflghtlng measures 5.1 Extinguishing media Suitable media: Carbon dioxide, Dry chemical, Foam. 5.2 Special hazards arising from the substance or mixture In case of fire, may be liberated: Carbon monoxide, Unidentified organic compounds. 5.3 Advice for fire fighters: In case of insufficient ventilation, wear suitable respiratory equipment. Section 6. Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures: Avoid inhalation. Avoid contact with skin and eyes. See protective measures under Section 7 and 8. 6.2 Environmental precautions: Keep away from drains, surface and ground water, and soil. 6.3 Methods and material for containment and cleaning up: Remove ignition sources. Provide adequate ventilation. Avoid excessive inhalation of vapours. Contain spillage immediately by use of sand or inert powder. Dispose of according to local regulations. 6.4 Reference to other sections: Also refer to sections 8 and 13. Page 4 (7) Active M1f!s Issue date 17/0512016 Version: 4 (17/0512016) SAFETY DATA SHEET In accordance with REACH Regulation EC No.1907/2006 Product: In the Garden Rose and Geranium SM003 RG Version: 4 Section 7. Handling and storage 7.1 Precautions for safe handling: Keep away from heat, sparks, open flames and hot surfaces. - No smoking. Use personal protective equipment as required. Use in accordance with good manufacturing and industrial hygiene practices. Use in areas with adequate ventilation Do not eat, drink or smoke when using this product. 7.2 Conditions for safe storage, Including any incompatibilities: Store in a well-ventilated place. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical, ventilating and lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. 7.3 Specific end use(s): Room Fragrance: Use in accordance with good manufacturing and industrial hygiene practices. Section 8, Exposure controiJlpei"'Ioal protection 8.1 Control parameters Wortcplace exposure limits: Not Applicable 8.2 Exposure Controls Eye I Skin Protection Wear protective gloves/eye protection/face protection Respiratory Protection Under normal conditions of use and where adequate ventilation is available to prevent build up of excessive vapour, this material should not require special engineering controls. However, in conditions of high or prolonged use, or high temperature or other conditions which increase exposure, the following engineering controls can be used to minimise exposure to personnel: a) Increase ventilation of the area with local exhaust ventilation. b) Personnel can use an approved, appropriately fitted respirator with organic vapour cartridge or canisters and particulate filters. c) Use closed systems for transferring and processing this material. Also refer to Sections 2 and 7. Sectioo 9. Physical and chemical properties 9.1 lnfonnation on basic physical and chemical properties
Appearance/Odor
Not determined Not determined pH: Not determined Initial bolllng point I range: Not determined Flash point: > 70 oc Vapour pressure: Not determined Relative density: Not determined Solubility(les): Not determined Page 5 ( 7 ) Active Mtf!s Issue date 17/0512016 Version: 4 (17/05/2016) SAFETY DATA SHEET In accordance with REACH Regulation EC No.1907/2006 Product: In the Garden Rose and Geranium SM003 RG Version: 4
Further information
None available Section 1 0. Stability and reactivitY 10.1 Reactivity: Presents no significant reactivity hazard, by itself or in contact with water. 10.2 Chemical stability: Good stability under normal storage conditions. 10.3 Possibility of hazardous reactions: Not expected under normal conditions of use. 10.4 Conditions to avoid: Avoid extreme heat. 10.51ncompatible materials: Avoid contact with strong acids, alkalis or oxidising agents. 10.6 Hazardous decomposition products: Not expected. Section 11. Toxjcologjcal infonnation 11.1 Information on toxicological etrecta This mixture has not been tested as a whole for health effects. The health effects have been calculated using the methods outlined in Regulation (EC) No 1272/2008 (CLP). May cause an allergic skin reaction. Causes serious eye irritation. Aaaumed Toxicity Value (LD50 or ATE) for Acute Oral Toxicity: >5000 Aaaumed Toxicity Value (LD50 or ATE) for Acute Dermal Toxicity: >5000 Aaaumed Toxicity Value (LC50 or ATE) for Acute Inhalation Toxicity: Not Available Inhalation Route: Not Available Information about hazardous Ingredients In the mixture Ingredient CAS EC LD501A IE Oral LD50/ATE LC50/ATE LC50 Route Dermal Inhalation Phenethyl alcohol 60-12-8 200-456-2 1610 2500 Not available Refer to Sections 2 and 3 for additional information. Page6(7) Active M1f!s Issue date 17/0512016 Version: 4 (17/05/2016) SAFETY DATA SHEET In accordance with REACH Regulation EC No.1907/2006 Product: In the Garden Rose and Geranium SM003 RG Version: 4 Section 12. Ecologjcal lnfonnation 12.1 Toxicity: Not available 12.2 Persistence and degradability: Not available 12.3 Bloaccumulatlve potential: Not available 12.4 Mobility in soil: Not available
Results of PBT and vPvB assessment
This substance does not meet the PBT/vPvB criteria of REACH, annex XIII.
Other hazards
Not available Section 13. Disposal considerations 13.1 Waste treatment methods: Dispose of in accordance with local regulations. Avoid disposing into drainage systems and into the environment. Empty containers should be taken to an approved waste handling site for recycling or disposal. Section 14. Transport information
UN Number
Not classified 14.2 UN Proper Shipping Name: Not classified 14.3 Transport hazard ctass(es): Not classified Sub Risk: Not classified 14.4. Packing Group: Not classified
Environmental hazards
Not environmentally hazardous for transport 14.6 Special precautions for user: None additional 14.7 Transport in bulk according to Annex II of MARPOL73178 and the IBC Code: Not classified Section 15. RegulatoJY infonnatjon 15.1 Safety, health and environmental regulation&negislation specific for the substance or mixture None additional 15.2 Chemical Safety Assessment A Chemical Safety Assessment has not been carried out for this product. Section 16. Other lnfonnation Concentration % Umlts: EDI2=65.18% SS 1=41.16% Total Fractional Values: EDI 2=1 .53 SS 1 =2.43 Page7(7 Active Mtf!s ) Issue date 17/05/2016 Version: 4 (17/05/2016) SAFETY DATA SHEET In accordance with REACH Regulation EC No.1907/2006 Product: In the Garden Rose and Geranium SM003 RG Version: 4 Key to revisions: Classification under Directive 67/548/EEC Concentration % Limits Information about hazardous ingredients in the mixture