Note: Ingredients listed on restricted chemical lists
EC/CAS
67-56-1
Name of the chemical
Methanol
Concentration
65-75
General Information
Version
9
Revision date
2021-09-16
Product name
Tetrabutylammonium hydroxide, 1M solution in methanol
supplier name
Fisher Scientific UK
Emergency telephone
+32 14 57 52 11, 001-201-796-7100, +32 14 57 52 99, 001-800-424-9300, 001-703-527-3887
Icons in SDS
Company Information
company name
Acros Organics BVBA
e-mail address of the competent person responsible for the Safety Data Sheet
info@acros.com, acros.techsupport@thermofisher.com
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H225, H301+H311+H331, H314, H317, H370
Hazard statements
Code
Statements
H225
Highly Flammable liquid and vapour
Section 2
SECTION 2: Hazards identification
Physical State
Appearance/Odor
Liquid Clear No information available Emergency Overview Highly flammable liquid and vapor. Toxic if swallowed. Toxic in contact with skin. Toxic if inhaled. Causes severe skin burns and eye damage. Causes damage to organs. May cause an allergic skin reaction.
2.1 Classification of the substance or mixture
Flammable liquids. Category 2 Acute Oral Toxicity Category 3 Acute Dermal Toxicity Category 3 Acute Inhalation Toxicity - Vapors Category 3 Skin Corrosion/Irritation Category 1 B Serious Eye Damage/Eye Irritation Category 1 Skin Sensitization Category 1 Specific target organ toxicity - (single exposure) Category 1
Signal word
Danger
Hazard statements
H225 - Highly flammable liquid and vapor H301 + H311 + H331 - Toxic if swallowed, in contact with skin or if inhaled H314 - Causes severe skin burns and eye damage H317 - May cause an allergic skin reaction H370 - Causes damage to organs
Prevention
P210 - Keep away from heat/sparks/open flames/hot surfaces. - No smoking P240 - Ground/bond container and receiving equipment P241 - Use explosion-proof electrical/ ventilating/ lighting equipment P242 - Use non-sparking tools P243 - Take precautionary measures against static discharge P264 - Wash face, hands and any exposed skin thoroughly after handling P270 - Do not eat, drink or smoke when using this product P271 - Use only outdoors or in a well-ventilated area P272 - Contaminated work clothing should not be allowed out of the workplace P280 - Wear protective gloves/protective clothing/eye protection/face protection
Response
P303 + P361 + P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a POISON CENTER or doctor/physician P330 - Rinse mouth P331 - Do NOT induce vomiting P363 - Wash contaminated clothing before reuse P370 + P378 - In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction
Storage
P403 + P233 - Store in a well-ventilated place. Keep container tightly closed P405 - Store locked up
Disposal
P501 - Dispose of contents/ container to an approved waste disposal plant
Other physicochemical hazards
Vapors may cause flash fire or explosion. Highly flammable.
Health hazards
Toxic if swallowed. Toxic in contact with skin. Toxic if inhaled. Harmful if inhaled. Corrosive. Causes skin and eye burns. Causes serious eye damage. Causes damage to organs. May cause an allergic skin reaction.
Environmental hazards
Contains no substances known to be hazardous to the environment or not degradable in waste water treatment plants. Will likely be mobile in the environment due to its volatility. Will likely be mobile in the environment due to its water solubility. The product contains volatile organic compounds (VOC) which will evaporate easily from all surfaces. The product is water soluble, and may spread in water systems.
2.3 Other hazards
Toxic to terrestrial vertebrates.