Diisobutylaluminium hydride, 1.1M solution in cyclohexane

Hazard statements (CLP)

H225, H260, H304, H314, H336, H410

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

Physical State

Appearance/Odor

Liquid Colorless sweet Emergency Overview Highly flammable liquid and vapor. In contact with water releases flammable gases which may ignite spontaneously. May be fatal if swallowed and enters airways. May cause drowsiness and dizziness. Harmful to aquatic life. Causes severe skin burns and eye damage. Very toxic to aquatic life with long lasting effects. Reacts violently with water. Moisture sensitive. Air sensitive.

2.1 Classification of the substance or mixture

Flammable liquids. Category 2 Substances/mixtures which, in contact with water, emit flammable gases Category 1 Aspiration Toxicity Category 1 Skin Corrosion/Irritation Category 1 A Serious Eye Damage/Eye Irritation Category 1 Specific target organ toxicity - (single exposure) Category 3 Acute aquatic toxicity Category 1 Chronic aquatic toxicity Category 1

Signal word

Danger

Hazard statements

H225 - Highly flammable liquid and vapor H260 - In contact with water releases flammable gases which may ignite spontaneously H304 - May be fatal if swallowed and enters airways H336 - May cause drowsiness or dizziness H314 - Causes severe skin burns and eye damage H410 - Very toxic to aquatic life with long lasting effects

Prevention

P210 - Keep away from heat/sparks/open flames/hot surfaces. - No smoking P231 + P232 - Handle under inert gas. Protect from moisture P240 - Ground/bond container and receiving equipment P242 - Use non-sparking tools P243 - Take precautionary measures against static discharge P264 - Wash face, hands and any exposed skin thoroughly after handling P271 - Use only outdoors or in a well-ventilated area P280 - Wear protective gloves/protective clothing/eye protection/face protection

Response

P303 + P361 + P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a POISON CENTER or doctor/physician P330 - Rinse mouth P331 - Do NOT induce vomiting P363 - Wash contaminated clothing before reuse P370 + P378 - In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction P302 + P335 + P334 - IF ON SKIN: Brush off loose particles from skin. Immerse in cool water

Storage

P402 + P404 - Store in a dry place. Store in a closed container

Disposal

P501 - Dispose of contents/ container to an approved waste disposal plant

Other physicochemical hazards

Highly flammable. Vapors may cause flash fire or explosion. Reacts violently with water, liberating extremely flammable gases. Reacts violently with water.

Health hazards

Aspiration hazard if swallowed - can enter lungs and cause damage. May cause drowsiness or dizziness. Corrosive. Causes skin and eye burns.

Environmental hazards

Harmful to aquatic life. Very toxic to aquatic life with long lasting effects. Reacts violently with water. . Toxic to terrestrial vertebrates.