1-Naphthylmagnesium bromide, 0.25M solution in THF

Hazard statements (CLP)

H225, H260, H314, H335, H351

Code

Statements

H225

Highly Flammable liquid and vapour

Physical hazards

Flammable liquids Category 2 Substances/mixtures which, in contact with water, emit flammable gases Category 1

Health hazards

Skin Corrosion/irritation Category 1 B Serious Eye Damage/Eye Irritation Category 1 Carcinogenicity Category 2 Specific target organ toxicity - (single exposure) Category 3

Environmental hazards

Based on available data, the classification criteria are not met

EU Classification

Directives 67/548/EEC or 1999/45/EC

Hazard pictograms

F - Highly flammable Xn - Harmful

R-phrase(s)

R11 - Highly flammable R19 - May form explosive peroxides R40 - Limited evidence of a carcinogenic effect R41 - Risk of serious damage to eyes R14/15 - Reacts violently with water, liberating extremely flammable gases R37/38 - Irritating to respiratory system and skin For the full text of the R-phrases and H-Statements mentioned in this Section, see Section 16

Signal word

Danger

Hazard statements

H260 - In contact with water releases flammable gases which may ignite spontaneously H225 - Highly flammable liquid and vapor H314 - Causes severe skin burns and eye damage H335 - May cause respiratory irritation H351 - Suspected of causing cancer EUH019 - May form explosive peroxides EUH014 - Reacts violently with water

Precautionary statements

P280 - Wear eye protection/ face protection P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a POISON CENTER or doctor/ physician P261 - Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray P402 + P404 - Store in a dry place. Store in a closed container P210 - Keep away from heat/sparks/open flames/hot surfaces. - No smoking