Note: Ingredients listed on restricted chemical lists
EC/CAS
137-26-8
Name of the chemical
Thiram
Concentration
<=100
General Information
Version
4
Revision date
2023-09-05
Product name
Tetramethylthiuram disulfide
Product Synonyms
Thiram; TMTD; Bis(dimethylthiocarbamyl) disulfide
CAS No.
137-26-8
supplier name
Fisher Scientific UK
Emergency telephone
001-800-227-6701, +32 14 57 52 11, 001-201-796-7100, +32 14 57 52 99, 001-800-424-9300, 001-703-527-3887
Icons in SDS
Company Information
company name
Acros Organics BV
e-mail address of the competent person responsible for the Safety Data Sheet
info@acros.com, acros.techsupport@thermofisher.com
GHS Information
Signal word
Warning
Hazard Codes
Hazard statements (CLP)
H302+H332, H315, H317, H319, H373, H410
Hazard statements
Code
Statements
H302+H332
Harmful if swallowed or if inhaled
Section 2
SECTION 2: Hazards identification
Physical State
Appearance/Odor
Powder Solid White Strong Emergency Overview Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. Harmful to aquatic life. Very toxic to aquatic life with long lasting effects. Harmful if swallowed. Harmful if inhaled. May cause damage to organs through prolonged or repeated exposure. May form combustible dust concentrations in air.
2.1 Classification of the substance or mixture
Acute Oral Toxicity Category 4 Acute Inhalation Toxicity - Dusts and Mists Category 4 Skin Corrosion/Irritation Category 2 Serious Eye Damage/Eye Irritation Category 2 Skin Sensitization Category 1 Specific target organ toxicity - (repeated exposure) Category 2 Acute aquatic toxicity Category 1 Chronic aquatic toxicity Category 1
Signal word
Warning
Hazard statements
H315 - Causes skin irritation H317 - May cause an allergic skin reaction H319 - Causes serious eye irritation H410 - Very toxic to aquatic life with long lasting effects H373 - May cause damage to organs through prolonged or repeated exposure H302 + H332 - Harmful if swallowed or if inhaled
Prevention
P264 - Wash face, hands and any exposed skin thoroughly after handling P270 - Do not eat, drink or smoke when using this product P271 - Use only outdoors or in a well-ventilated area P272 - Contaminated work clothing should not be allowed out of the workplace P280 - Wear protective gloves/protective clothing/eye protection/face protection
Response
P330 - Rinse mouth P302 + P352 - IF ON SKIN: Wash with plenty of soap and water P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P312 - Call a POISON CENTER or doctor if you feel unwell P362 + P364 - Take off contaminated clothing and wash it before reuse
Storage
P403 + P233 - Store in a well-ventilated place. Keep container tightly closed
Disposal
P501 - Dispose of contents/ container to an approved waste disposal plant
Other physicochemical hazards
None identified. May form combustible dust concentrations in air.
Health hazards
Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. Harmful if swallowed. Harmful if inhaled. May cause damage to organs through prolonged or repeated exposure.
Environmental hazards
Harmful to aquatic life. Very toxic to aquatic life with long lasting effects. . Will likely be mobile in the environment due to its water solubility. The product is water soluble, and may spread in water systems.
2.3 Other hazards
May form explosible dust-air mixture if dispersed. Toxic to terrestrial vertebrates. This product does not contain any known or suspected endocrine disruptors.