4-Chlorophenylmagnesium bromide, 1M solution in THF/toluene

Hazard statements (CLP)

H225, H260, H304, H314, H318, H335, H336, H351, H361d, H373

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

CLP Classification - Regulation (EC) No 1272/2008 Classification of the substance or mixture

Physical hazards

Flammable liquids Category 2 (H225) Substances/mixtures which, in contact with water, emit flammable gases Category 1 (H260)

Health hazards

Aspiration Toxicity Category 1 (H304) Skin Corrosion/Irritation Category 1 B (H314) Serious Eye Damage/Eye Irritation Category 1 (H318) Carcinogenicity Category 2 (H351) Reproductive Toxicity Category 2 (H361d) Specific target organ toxicity - (single exposure) Category 3 (H335) (H336) Specific target organ toxicity - (repeated exposure) Category 2 (H373)

Environmental hazards

Based on available data, the classification criteria are not met Full text of Hazard Statements: see section 16

Signal word

Danger

Hazard statements

H225 - Highly flammable liquid and vapor H260 - In contact with water releases flammable gases which may ignite spontaneously H304 - May be fatal if swallowed and enters airways H314 - Causes severe skin burns and eye damage H335 - May cause respiratory irritation H336 - May cause drowsiness or dizziness H351 - Suspected of causing cancer H361d - Suspected of damaging the unborn child H373 - May cause damage to organs through prolonged or repeated exposure EUH014 - Reacts violently with water EUH019 - May form explosive peroxides

Precautionary statements

P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking P231 + P232 - Handle and store contents under inert gas. Protect from moisture P280 - Wear protective gloves/protective clothing/eye protection/face protection P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a POISON CENTER or doctor/physician

2.3 Other hazards

Reacts violently with water Toxic to terrestrial vertebrates

2.1 Classification of the substance or mixture

CLP Classification - Regulation (EC) No 1272/2008 Physical hazards Flammable liquids Category 2 (H225) Substances/mixtures which, in contact with water, emit flammable gases Category 1 (H260) Health hazards Aspiration Toxicity Category 1 (H304) Skin Corrosion/Irritation Category 1 B (H314) Serious Eye Damage/Eye Irritation Category 1 (H318) Carcinogenicity Category 2 (H351) Reproductive Toxicity Category 2 (H361d) Specific target organ toxicity - (single exposure) Category 3 (H335) (H336) Specific target organ toxicity - (repeated exposure) Category 2 (H373) Environmental hazards Based on available data, the classification criteria are not met Full text of Hazard Statements: see section 16