LiquidWood B

Hazard statements (CLP)

H302, H312, H314, H317, H318, H335, H411

Code

Statements

H302

Harmful if swallowed

SECTION 2: Hazards identification

(29 CFR 1910.1200) Emergency Overview: Danger! Irritant. Clear, dark amber colored liquid with a slightly irritating ammonia odor. Material causes skin irritation and prolonged contact may lead to sensitization and an allergic skin reaction. Material causes severe eye irritation. Material is harmful if inhaled and can cause severe respiratory tract irritation.

2.1 Classification of the substance or mixture

Category Acute Toxicity, Dermal Category 4 Acute Toxicity, Oral Category 4 Serious Eye Damage Category 1 Skin Sensitization Category 1 Skin Corrosion/Irritation Category 1C Specific Target Organ Toxicity (STOT) Single Exposure Category 3 (respiratory tract irritation) Chronic Aquatic Toxicity Category 2 Hazard Pictograms Page | 1 Signal Word: Danger Hazard Category Statements H312 Harmful in contact with skin H318 Causes serious eye damage H314 Causes severe skin burns and eye damage H317 May cause an allergic skin reaction H335 May cause respiratory irritation H302 Harmful if swallowed H411 Toxic to aquatic life with long lasting effects Precautionary Statements P280: Wear protective gloves and eye protection. P270: Do not eat, drink or smoke when using this product. P262: Do not get in eyes, on skin, or on clothing. P260: Do not breathe vapors. P264: Wash hands thoroughly after handling. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313: If eye irritation persists: Get medical advice. P302+P352: IF ON SKIN: wash with plenty of soap and water. P303+P361+P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P333+P313: If skin irritation or a rash occurs: Get medical advice. P362: Take off contaminated clothing and wash before reuse. P272: Contaminated work clothing should not be allowed out of the workplace. P301+P330+P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P310: Immediately call a POISON CENTER or doctor. P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing. P273: Avoid release to the environment. P391: Collect spillage. P501: Dispose of container to be specified in accordance with regulations. SECTION 3: Composition/Information on Ingredients Composition: The exact composition is a trade secret. Proprietary liquid amidoamines. Hazardous Ingredients Substance Name CAS Number Concentration (%) Hazard Classification Fatty acids, tall-oil, reaction 68953-36-6 90 – 100% Eye Dam. 2 H318 products with Eye Irit. 2 H319 tetraethylenepentamine Skin Sens. 1 H317 Skin Irrit. 2 H315 STOT SE 3 H335 Page | 2 3,6,9- 112-57-2 0 – 10% Acute Tox. 4 H302 triazaundecamethylenediamine Acute Tox. 4 H312 (tetraethylenepentamine) Skin Sens. 1 H317 Skin Corr. 1B H314 Aquatic Chronic 2 H411 SECTION 4: First Aid Measures Eye Contact: Immediately flush eyes with water for at least 15 minutes and check for and remove contacts. Do not delay. Hold eyelids apart to rinse entire eye surface. Seek medical attention if irritation persists. Continue washing if medical attention is not immediately available. Skin Contact: Wipe off excess immediately and wash affected area with soap and water for at least 15 minutes. Remove contaminated clothing or shoes and seek medical attention if irritation persists. Continue washing if irritation persists. NOTE TO PHYSICIANS: Application of corticosteroid cream has been effective in treating skin irritation. Inhalation: If inhaled, remove victim to fresh air and consult medical personnel immediately. If person is not breathing or breathing is irregular, provide oxygen with the aid of trained personnel only. If unconscious, place in recovery position and seek medical attention immediately. Ingestion: Wash out mouth with small amounts of water and remove person to fresh air. Do not induce vomiting unless directed to do so by medical personnel. Prevent aspiration of vomit. Seek medical attention immediately. Turn victim’s head to one side. If unconscious, place in recovery position. Never give anything by mouth to an unconscious person. Primary Routes of Entry: Eye and skin contact, breathing vapors. SECTION 5: Fire-Fighting Measures Flash Point: >200 ºF (>93.3 °C) Flammable Limits (STP In Air) Method Used: ASTM D3278-96 LFL/UFL: Not Determined Suitable Extinguishing Media: Water fog, alcohol-resistant foam, CO2, and dry chemicals such as sand and powdered limestone Unsuitable Extinguishing Media: None known Specific Hazards and Procedures: Heated containers may burst. Ammonia gas may be liberated at high temperatures. Incomplete combustion may result in the formation of toxic nitrogen oxide compounds (NOx) and carbon monoxide. Burning produces noxious and toxic fumes. Downwind personnel must be evacuated. The material is toxic to aquatic life. Fire residues and water contaminated with this material must be contained and prevented from entering waterways, sewers or drains. Hazardous Combustion Products: Burning material may generate ammonia gas and noxious and toxic fumes. Combustion and/or decomposition products include carbon monoxide and nitrogen oxides (NOx). Page | 3 SECTION 6: Accidental Release Measures Personal Protective Measures: Provide adequate ventilation and keep all unnecessary and unprotected personnel from entering the area. Do not touch or walk through spilled material. Avoid breathing vapor or mist. Wear an appropriate respirator when ventilation is inadequate. Use appropriate safety equipment before taking any action. Methods and Material for Containment and Cleaning Up: Stop flow of material with sand or other inert material and move container from spill area. Absorb spill with an inert material, scrape up and place in appropriate waste disposal container. Remove residual resin with non-flammable solvent and flush contaminated area with hot water. Do not dump waste into any sewers, on the ground or into any body of water. Avoid dispersal of spilled material and runoff. All disposal methods must be compliant with all Federal, State, and local laws and regulations. SECTION 7: Handling and Storage Precautions for Safe Handling: Wear safety glasses. Do not combine this product with sodium nitrite or other nitrosating agents. Suspected cancer-causing nitrosamines could be formed. Avoid contact with acids, oxidizers, acrylates, alcohols, aldehydes, ketones and halogenated hydrocarbons. Avoid contact with metal such as copper, copper alloys, brass and bronze. Wear personal protection equipment including safety glasses. Do not get in eyes, on skin or on clothing. Avoid any forms of ingestion. Do not breathe vapor, mist or spray. Use only with good ventilation or use suitable respiratory protection. Persons with a history of skin sensitization problems should avoid contact with any process in which this product is used. Do not ingest. Avoid release to the environment. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. Conditions for Safe Storage, Including Any Incompatibilities: Store in tightly sealed, original container in a cool, dry and well-ventilated place protected from direct sunlight. Keep container sealed until use. Keep containers tightly closed when not in use. Store away from incompatible materials such as acids and food and drink. Use appropriate containment to avoid environmental contamination. Product may freeze with extended exposure to low temperatures. If this occurs, warm the product to 100 – 140°F (38 – 60°C) for one hour and stir until clear. SECTION 8: Exposure Controls/Personal Protection Occupational Exposure Limits: OSHA PEL/TWA Not available for formulated product. ACGIH TLV/TWA Not available for formulated product. Chemical CAS # AIHA TLV 8-hr TWA (aerosol) Tetraethylenepentamine 112-57-2 5 mg/m3 (skin sensitizer) Engineering Controls: Good general ventilation should be sufficient to control worker exposure to airborne contaminants. If user operations generate vapor, process enclosures or local exhaust may be necessary. Individual Protection Measures Page | 4 Eye/Face Protection: Use properly fitted safety glasses. If vapor exposure causes eye discomfort, a full-face respirator may be necessary. Skin Protection: Wear protective clothing suitable to the conditions of use. Clean, body-covering clothing and protective gloves should be worn at all times when handling the product. Respiratory Protection: If local exhaust ventilation is inadequate, use a properly fitted, air-purifying mask suitable to the level of anticipated exposure. Hygiene Measures: Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Wash contaminated clothing before reusing. SECTION 9: Physical and Chemical Properties Physical State: Clear amber/reddish brown liquid Odor: Irritating, amine Odor Threshold: Not determined pH: 11.5 (neat) Melting Point/Freezing Point: Not determined Boiling Point: 218 °C (425 °F) Flash Point: >93.4 °C (>200°F) Evaporation Rate: 1 (n-butyl acetate =1) Flammability: Not available Explosive Limits: Not available Vapor Pressure: <5.17 mm Hg at 21 °C (70 °F) Relative Vapor Density: >1 (Air =1) Relative Density (water = 1): 0.96@ 21°C Solubility: insoluble in water Partition Coefficient: Not available Auto-Ignition Temp.: Not available Decomposition Temperature: Not available Viscosity: 250-800 cps Explosive Properties: Not applicable Oxidizing Properties: None SECTION 10: Stability and Reactivity Reactivity: Product reacts exothermically with epoxide resins. Product by itself is stable and relatively non-reactive under normal conditions of use, storage and shipping. Chemical Stability: Product is stable under normal use and temperature conditions. Prolonged excessive heat may cause partial degradation. Possibility of Hazardous Reactions: Under normal conditions of storage and use, hazardous reactions will not occur. Conditions to Avoid: Avoid contact with incompatible materials. Avoid excessive heat. Store between 60-90°F. Incompatible Materials: Avoid contact with acids, oxidizers, acrylates, alcohols, aldehydes, ketones and halogenated hydrocarbons. Avoid contact with metal such as copper, copper alloys, brass and bronze. Avoid bulk contact with epoxides. Material reacts with considerable heat release with some epoxide resins. Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, acrid smoke and fumes Hazardous Polymerization: Will not occur by itself, but hazardous polymerizations may occur with aliphatic amines in masses greater than one pound with considerable heat buildup. Page | 5 SECTION 11: Toxicological Information Acute Toxicity: The formulated product is not considered to be acutely toxic. Component Oral LD50 Dermal LD 50 Inhalation LC 50 Fatty acids, tall-oil, reaction products - 1,100 mg/kg with tetraethylenepentamine - Tetraethylenepentamine 3.99 g/kg (rat) 660 mg/kg (rabbit) - Skin Corrosion/Irritation: The formulated product is considered a severe skin irritant. Brief contact may cause skin burns. Component Species Skin Exposure Observation Tetraethylenepentamine Rabbit 5 mg, 24 hours Severe Irritant Serious Eye Damage/Irritation: The formulated product is considered a severe eye irritant. Exposure may cause severe irritation with corneal injury which may result in permanent impairment of vision. Component Species Eye Exposure Observation Tetraethylenepentamine Rabbit 100 mg, 24 hours Moderate Irritant Respiratory or Skin Sensitization: Sensitization is possible through skin contact. Sensitization has occurred in lab animals after repeated exposures. Germ Cell Mutagenicity: No data for the product itself. For tetraethylenepentamine, CAS # 112-57-2, in-vitro genetic toxicity studies were positive. Animal genetic toxicity studies were negative. Carcinogenicity: No components of this product are listed or classified as carcinogens by IARC, NTP, OSHA or ACGIH. Reproductive Toxicity: Not available STOT-Single Exposure: Not available for the product itself Component Category Route of Exposure Observation Fatty acids, tall-oil, reaction products with 3 Inhalation Respiratory tract tetraethylenepentamine irritation STOT-Repeat Exposure: Not Available Routes of Exposure: Skin contact, eye contact, vapor inhalation. Primary Symptoms: Material is a severe eye and skin irritant and moderate skin sensitizer. Prolonged exposure can cause dryness and cracking of the skin. Material vapor can be irritating to the respiratory and digestive tracts, and may be harmful if swallowed or inhaled in large amounts. Effects of Overexposure: Overexposure to vapors can cause dizziness, headaches and other central nervous system effects. Page | 6 SECTION 12: Ecological Information Acute (short-term) toxicity: The formulated product is toxic to aquatic organisms on an acute basis. Component: Tetraethylenepentamine (following OECD Test Guidelines 203, 202 and 201 as appropriate) Species Result Exposure Poecilia reticulate (guppy) LC50: 420 mg/L 96 hour; semi-static Daphnia magna (water flea) EC50: 24.1 mg/L 48 hour; static Pseudokirchneriella subcapitata (green algae) ErC50: 6.8 mg/L 72 hour; growth rate inhibition Chronic (long-term) toxicity: The formulated product may cause long-term effects in the aquatic environment. Persistence and Degradability: No information for the product itself. Tetraethylpentamine is not readily biodegradable. Bioaccumulative potential: Partition coefficient n-octanol /water (log Pow): Not Available Mobility in soil: Not Available SECTION 13: Disposal Considerations Disposal considerations apply only to the product as shipped in its original container. Waste Disposal: The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer. The generation of waste should be avoided or minimized wherever possible. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. SECTION 14: Transportation Information US DOT: UN Number: UN2735 UN Proper Shipping Name: Polyamines, Liquid, Corrosive, n.o.s. Transport Hazard Class: 8 Packing Group: III Marine Pollutant: Yes In quantities not to exceed 1 gallon, this product can be shipped by land as a limited quantity. In quantities not to exceed 5kg/5L per single or inner packaging, marine pollutants are not subject to regulation by ground, air, or vessel. See 49 CFR 171.4(c)(2). SECTION 15: Regulatory Information HCS Classification: Irritating material, Sensitizing material Page | 7 TSCA Status: All materials are either included on or exempt from the TSCA Inventory of Chemical Substances. This product does not contain any components subject to TSCA 12(b) export notification. Global Chemical Inventory Status: All materials are either listed, compliant with or exempt from listing on the following global inventories: Country/Region Inventory Name Listed? Australia Australian Inventory of Chemical Substances (AICS) Yes Canada Domestic Substances List (DSL) Yes China Inventory of Existing Chemical Substances in China (IECSC) Yes EU European List of Existing Commercial Chemical Substances (EINECS) Yes EU European List on Notified Chemical Substances (ELINCS) No Japan Inventory of Existing and New Chemical Substances (ENCS) No Korea Existing Chemicals List (ECL) Yes New Zealand New Zealand Inventory of Chemicals (NZIoC) Yes Philippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) Yes USA Toxic Substances Control Act Inventory (TSCA) Yes Other Regulations: This product contains no Extremely Hazardous Substances, EPCRA Sec.311, Appendix A and B, or chemicals listed in EPCRA Sec. 313, Table II. SECTION 16: Other Information HMIS Rating: The Hazardous Materials Identification System (HMIS) is a rating system with 0 representing a minimal risk or hazard and 4 representing a significant risk or hazard. Health 2 Flammability 1 Physical Hazard 0 SDS History: Version: 3.2 Revision Date: August 16, 2022 Previous Update: March 4, 2020 Creation Date: April 1, 2000 Revision Notes: Updated company information, updated transportation information THE INFORMATION HEREIN IS GIVEN IN GOOD FAITH, BUT NO WARRANTY, EXPRESS OR IMPLIED, IS MADE. Page | 8

Precautionary statements

P280: Wear protective gloves and eye protection. P270: Do not eat, drink or smoke when using this product. P262: Do not get in eyes, on skin, or on clothing. P260: Do not breathe vapors. P264: Wash hands thoroughly after handling. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 If eye irritation persists Get medical advice P302+P352 IF ON SKIN wash with plenty of soap and water P303+P361+P353 IF ON SKIN (or hair) Take off immediately all contaminated clothing. Rinse skin with water. P333+P313 If skin irritation or a rash occurs Get medical advice P362: Take off contaminated clothing and wash before reuse. P272: Contaminated work clothing should not be allowed out of the workplace. P301+P330+P331 IF SWALLOWED Rinse mouth. Do NOT induce vomiting P310: Immediately call a POISON CENTER or doctor. P304+P340 IF INHALED Remove person to fresh air and keep comfortable for breathing P273: Avoid release to the environment. P391: Collect spillage. P501: Dispose of container to be specified in accordance with regulations.