“1 SHOT  ” Lettering Enamels

SECTION 2: Hazards identification

OSHA HMIS HEALTH 2 * FLAMMABILITY 2 REACTIVITY 0 0 = Least 1 = Slight 2 = Moderate 3 = High 4 = Extreme

Potential chronic health

method ASTM OTHER* equivalent * * * * * * or OXIDE 20 15 5 24 < < < Method FERRIC ZINC < < 5 10 COPPER 25 30 20 EPA < < < Reference 25 25 25 PARAFFINIC SOLVENT of calculations % < < < Weight -- 1,3,5-TRIMETHYL- BENZENE the inks and 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 < < < < < < < < < < < < < < < < < < < < < < < < < < < < < ENAMELS and BARIUM SULFATE LETTERING 5 5 5 < < < coatings ANTIMONY TRIOXIDE adhesives, 5 5 5 1 5 1 1 1 < < < < < < < < OF for solvents, INGREDIENTS MOLYBDATE exempt LEAD 5 5 5 1 5 < < < < < LEAD SULFATE ADDITIONAL 20 1 1 10 OTHER water 1 1 5 table basis, components. and < < < < < < < for less LEAD < < < CHROMATE < < < < < < < < 25 15 5 25 25 40 30 10 20 15 this of solids TITANIUM DIOXIDE at 40 5 35 20 35 40 5 5 5 5 <40 < 30 10 40 15 20 35 5 5 < < < < < < < < <10 < < < < < < < < < < 15 end the percent a CARBON BLACK Ingredients” 1 1 0.02 using < < < by < office. V.O.C.‡ LBS/GL Addtional is 3.3 3.0 3.3 3.0 3.1 3.2 4.0 3.9 4.0 3.4 3.3 3.1 3.2 3.0 3.0 3.3 3.3 3.3 3.2 3.4 3.4 3.3 3.3 3.3 3.3 3.0 3.4 3.4 3.0 3.5 3.3 3.3 determined 10.7 11.6 9.5 11.7 9.2 8.4 10.5 10.5 10.6 9.6 9.2 11.2 10.3 11.3 11.9 10.8 11.6 11.7 11.0 9.6 8.6 9.3 9.0 10.2 9.0 11.3 9.0 9.2 10.9 8.2 8.3 8.8 executive DENSITY LBS/GL Other

Contains

the 8 of by of “List VOC 2 PRODUCT# 100-L 101-L 102-L 103-L 104-L 108-L 109-L 110-L 111-L 114-L 115-L 116-L 117-L 118-L 120-L 124-L 130-L 132-L 134-L 142-L 143-L 144-L 148-L 149-L 150-L 151-L 152-L 153-L 154-L 155-L 156-L 157-L * ‡ See The approved Page method ASTM * OTHER equivalent * * * or OXIDE 5 5 24 < < No No No Method FERRIC ZINC No No No COPPER EPA No No No Reference (continued) PARAFFINIC SOLVENT calculations of 30 < No No No % 1,2,4-TRIMETHYL- and Weight No No No the and 1 1 1 1 1 1 1 1 1 1 1 < < < < < < < < < < < -- BENZENE inks ENAMELS BARIUM SULFATE ANTIMONY TRIOXIDE only) CARCINOGENICITY No No No Yes No No No No No No No No 5 < No No No coatings NTP (IARC, Yes No No LETTERING adhesives, 1 1 < < for solvents, OF MOLYBDATE exempt < < < < < < < < < < < <20 5 5 5 1 5 5 5 5 5 5 5 LEAD No No No PERCENT components. and 1 < No No No CAS# INGREDIENTS LEAD SULFATE water 10361-37-2 64742-88-7 64742-88-7 14808-60-7 1332-58-7 1332-58-7 471-34-1 471-34-1 471-34-1 64742-82-1 1332-58-7 7429-90-5 1 OTHER < for less ADDITIONAL CHROMATE this of solids medium medium 5 15 LEAD Yes Yes No < < table basis, aliphatic aliphatic 5 5 5 5 TITANIUM DIOXIDE end at heavy INGREDIENTS INGREDIENT < <10 Yes No No 20 (petroleum), (petroleum), 15 15 35 20 20 office. ADDITIONAL Chloride Naphtha Naphtha Carbonate Carbonate Carbonate hydrodesulfurized < < < < < < < < < < No No No the percent a CARBON BLACK Ingredients” OTHER Silica 1 using < by V.O.C.‡ LBS/GL IARC NTP OSHA Addtional is determined 3.0 3.3 3.2 3.5 3.3 3.3 3.4 3.1 3.2 4.0 3.2 2.2 8.3 9.4 8.3 8.2 8.8 8.7 8.3 11.2 11.1 8.8 9.6 7.8 executive the OTHER Barium Solvent Solvent Crystalline Kaolin Kaolin Calcium Calcium Calcium Naphtha, Kaolin Aluminum DENSITY LBS/GL Other of 8 by OF of “List VOC 3 PRODUCT# 158-L 160-L 161-L 162-L 163-L 164-L 165-L 168-L 191-L 193-L 195-L 199-L Carcinogenicity: * ‡ approved * See The LIST PRODUCT# 100-L 109-L 111-L 115-L 124-L 134-L 142-L 150-L 152-L 165-L 191-L 193-L Page Routes of Entry: Inhalation, Absorption, Ingestion, Skin contact, Eye contact.

Medical Conditions Generally Aggravated by Exposure

Eye disease, Skin disease including eczema and sensitization, Kidney disease, Liver disease, Digestive tract disease. Immediate (Acute) Health Effects: Inhalation: Can cause moderate respiratory irritation, dizziness, weakness, fatigue, nausea and headache. THE FOLLOWING EFFECTS ARE CAUSED BY INGREDIENTS, IF ANY, high levels of airborne or ingested lead may produce symptoms of anemia, insomnia, weakness, constipation, nausea and abdominal pain. Overexposure may cause damage to blood-forming, nervous, reproductive, intestinal and urinary systems. Toxic. Can cause systemic damage, see target organs below. Respiratory failure is possible at high doses. Skin Contact: Can cause minor skin irritation, defatting, and dermatitis. THE FOLLOWING EFFECTS ARE CAUSED BY INGREDIENTS, IF ANY, moderate injury (reddening and swelling). Can be absorbed through the skin to cause kidney and liver damage. Continued or prolonged contact may irritate the skin and cause a skin rash (dermatitis). Can cause severe irritation, defatting, and dermatitis. Irritation effects may last for hours or days but will not likely result in permanent damage. Eye Contact: Can cause moderate irritation, tearing and reddening, but not likely to permanently injure eye tissue. THE FOLLOWING EFFECTS ARE CAUSED BY INGREDIENTS, IF ANY, cause eye irritation and transient corneal damage. Skin Absorption: Skin absorption may be a significant source of exposure. THE FOLLOWING EFFECTS ARE CAUSED BY INGREDIENTS, IF ANY, absorbed through the skin to cause kidney and liver damage. Ingestion: Harmful if swallowed. May cause systemic poisoning. Can cause abdominal discomfort, nausea, vomiting and diarrhea. Aspiration of material into the lungs can cause chemical pneumonitis. THE FOLLOWING EFFECTS ARE CAUSED BY INGREDIENTS, IF ANY, target organ failure and/or death. Large exposure may be fatal. Muscular weakness Tremors Loss of appetite Anemia Insomnia Irritating to mouth, throat, and stomach. Target Organ Acute Toxicity: Eyes, Skin, Respiratory System, Kidneys, Nervous System, Blood, Liver, Digestive Tract, Thyroid, Pituitary, Testes. Lead-containing ingredients may also target the following in addition to those listed above: Reproductive System and Gingival Tissue. Long-Term (Chronic) Health Effects: Inhalation: Upon prolonged and/or repeated exposure, can cause moderate respiratory irritation, dizziness, weakness, fatigue, nausea and headache. THE FOLLOWING EFFECTS ARE CAUSED BY INGREDIENTS, IF ANY, tract sensitization, characterized by asthma-like symptoms such as tightness in the chest, difficulty breathing, and wheezing may result from prolonged or repeated inhalation of dust/processing fumes of this product. Pulmonary edema (fluid buildup in the lungs) Ulceration and perforation of the nasal septum. Skin Contact: Upon prolonged or repeated contact, can cause moderate skin irritation, defatting, and dermatitis. Not likely to cause permanent damage. THE FOLLOWING EFFECTS ARE CAUSED BY INGREDIENTS, IF ANY, sensitization. Upon prolonged or repeated contact, may lead to a metallic taste in mouth. Skin rashes Eye Contact: Upon prolonged or repeated contact, can cause moderate irritation, tearing and reddening, but not likely to permanently injure eye tissue. THE FOLLOWING EFFECTS ARE CAUSED BY INGREDIENTS, IF ANY, Skin Absorption: Upon prolonged or repeated exposure, harmful if absorbed through the skin. May cause severe irritation and systemic damage. Carcinogenicity:

Additional information

on other components Target Organ Chronic Toxicity: Nervous System, Eyes, Skin, Respiratory System, Kidneys, Blood, Liver, Digestive Tract, Pituitary, Testes. Lead-containing ingredients may also target the following in addition to those listed above: Reproductive System and Gingival Tissue. NOTICE - Reports have associated repeated and prolonged occupational overexposure to solvents with brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. Lifetime inhalation exposure of rats and mice to high concentrations of ethylbenzene (750 ppm) resulted in increases in certain types of cancer, including kidney, lung and liver tumors. Testicular adenomas were increased as were thyroid effects in rats at 750 ppm. Pituitary effects were observed in female mice at 250 ppm. These effects were absent when exposure was below 75 ppm ethylbenzene. The study does not address the relevance of these results to humans. Cutting, sanding or grinding dried or cured material may release particles of crystalline silica (quartz). Exposure to airborne particles may cause lung damage including a risk of cancer. Chronic exposure may result in chest pain, difficulty breathing, lung damage and silicosis. (Silicosis is the permanent deposition of silica in lung tissue that results in lung damage.) There may exist a relationship between silicosis and certain cancers. This product contains pigments which may become a dust nuisance when removed by abrasive blasting, sanding or grinding. See additional information above in this section for products containing Crystalline Silica. IV. FIRST AID Inhalation: Remove to fresh air. If breathing is difficult, have a trained individual administer oxygen. If not breathing, give artificial respiration and have a trained individual administer oxygen. Get medical attention immediately.