Threadlocker

SECTION 2: Hazards identification

Main Hazards ; F&47MEEGKG0I&ME&9MNM1I HE<&

Potential health effects

Eyes OGPHGI&/M5&4MHE0&E7G29F&F1M3EG03F&G11GFMFG 3<& Ingestion *QM77 QG32&/M5&9MR0&F90&K 77 QG32&0KK04FE=L&3MHE0M<& & 3. FIRST-AID MEASURES First Aid - Eyes SME9& HF&050&QGF9&8703F5& K&QMF01<&TJFMG3&/0IG4M7&MFF03FG 3&GK&E 1030EE& :1&10I30EE&801EGEFE<& First Aid - Skin SME9&EUG3&QGF9&E M8&M3I&QMF01<&V8875&M&104 3IGFG 3G32&EUG3&410M/<& First Aid - Ingestion SME9& HF&/ HF9&QGF9&QMF01<&W &3 F&G3IH40&R:/GFG32<& & 4. FIRE-FIGHTING MEASURES Extinguishing Media XE0&QMF01&E81M5Y&K M/Y&I15&490/G4M7& 1&4M1J 3&IG ZGI0<& Unsuitable Extinguishing Media W &3 F&HE0&QMF01&[0F<& Special Hazards of Product 69GE&81 IH4F&/M5&2GR0&1GE0&F &9MNM1I HE&KH/0E&G3&M&KG10<& Protective Equipment for Fire-Fighting S0M1&E07KL4 3FMG30I&J10MF9G32&M88M1MFHE<& & Eyes Liquid may cause slight transient irritation. Ingestion Swallowing may have the following effects:- nausea, drowsiness. Inhalation Exposure to vapour at high concentrations may have the following effects:- drowsiness. 4. FIRST-AID MEASURES First Aid - Eyes: Wash out eye with plenty of water. Obtain medical attention if soreness or redness persists. First Aid - Skin Wash skin with soap and water. Apply a reconditioning skin cream. First Aid - Ingestion Do not induce vomiting. Obtain medical attention. First Aid - Inhalation Remove from exposure. Keep warm and at rest. Seek medical attention if you feel unwell. 9804/8894 ISSUE 3 (REV.), NOVEMBER 1997 5. FIRE-FIGHTING MEASURES Extinguishing Media Use foam, dry chemical or carbon dioxide. Keep containers and surroundings cool with water spray. Unsuitable Extinguishing Media Do not use water jet. Special Hazards of Product Containers may explode in heat of fire. This product may give rise to hazardous fumes in a fire. Protective Equipment for Fire- Wear self contained breathing apparatus. Fighting 6. ACCIDENTAL RELEASE MEASURES Personal Precautions Eliminate all sources of ignition. Ventilate the area. Wear appropriate protective clothing. Environmental Precautions Try to prevent the material from entering drains or water courses. Spillages Allow to evaporate if it is safe to do so or contain and absorb using earth, sand or other inert material. Transfer into suitable containers for recovery or disposal. 7. HANDLING AND STORAGE Handling Use in well ventilated area. Eyes Vapour may cause conjunctival irritation. Inhalation Prolonged or repeated exposure will have the following effects:- irritation of nose, throat and respiratory tract. 4. FIRST-AID MEASURES Eye Contact: Immediately flood the eye with plenty of water for at least 10 minutes, holding the eye open. Obtain medical attention urgently. cont’d 9804/8976 ISSUE 3, (REV.) NOVEMBER 1997 Skin Contact: Wash skin thoroughly with soap and water. Ingestion: Do not induce vomiting. Have victim drink 240-300 ml of water. If vomiting occurs naturally, rinse mouth and repeat administration of water. Obtain medical attention. Inhalation: Remove from exposure. Obtain medical attention. 5. FIRE-FIGHTING MEASURES Extinguishing Media: Use foam, dry chemical or carbon dioxide. Special Hazards of Product: May form explosive mixtures with air. Vapours can travel a considerable distance to a source of ignition and flashback. Combustion will produce smoke, carbon dioxide and carbon monoxide. Protective Equipment for Fire-Fighting: Wear self-contained breathing apparatus. 6. ACCIDENTAL RELEASE MEASURES Personal Precautions: Wear appropriate protective clothing. Eliminate all sources of ignition. Spillages: Contain and absorb using earth, sand or other inert material. Transfer into suitable containers for recovery or disposal. Environmental Precautions: Try to prevent the material from entering drains or water courses. 7. HANDLING AND STORAGE Handling: Exposure by inhalation or skin contact should be minimised by good Industrial Hygiene practices. Avoid inhaling vapour. Avoid contact with eyes, skin and clothing. Use in well ventilated area. Keep container tightly closed when not in use. Man Made Mineral Fibres can cause irritation to the skin and eyes, and in excessively dusty conditions coarse fibres may cause irritation to the upper respiratory tract. Mose people become resistant after a transitory period. Control measures are aimed at protecting the eyes, skin and respiratory tract. Although there are fundamental differences between Man Made Mineral Fibres and asbestos, some fibres or similar dimensions to respirable asbestos fibres have been found in particular situations. Such "microfine" fibres are not present in any significant quantity in this product as supplied and would not be expected to be generated to any significant extent during normal usage. FIRE HAZARD Fire resistant material. 9804/8973 ISSUE 5 (REV), JUNE 2002 STORAGE PRECAUTIONS Standard warehouse conditions. TRANSPORT PRECAUTIONS No special precautions are required. HANDLING PRECAUTIONS An employee using this material should use it in such a way as to avoid creating and emitting dust as far as is possible. Where particularly dusty operations are unavoidable control of dust should primarily be by engineering control, where this is practicable. On some occasions respiratory protective equipment may be the only reasonably practicable precaution which can be taken to protect the respiratory system. Respiratory protective equipment should conform to either BS 2091, BS 4558, BS 4771 or BS 6016, dependent upon the concentration of dust and the length of exposure time. Further details can be obtained from the publications listed in the reference section below. For employees handling this material standard protective equipment should be routinely supplied for protecting the skin and eyes. Employees should be instructed in good work practices in order to minimise generation of and exposure to dust. Advice on personal hygiene should be given to employees, particularly as regards washing. The skin should first be rinsed with water before the application of soap to prevent aggravation of the skin by fibres. Loose clothing, avoiding tight constriction at the neck and wrist is best suited to most operators. Detailed requirements in any given usage situation will be determined by the required assessment carried out under the Control of Substances Hazardous to Health Regulations (1988). DISPOSAL PRECAUTIONS Waste Products are not hazardous and their disposal should be in accordance with local regulations. REFERENCES Health & Safety Executive Guidance Note EH46, Exposure to Mineral Wools (HMSO). Health & Safety Executive Guidance Note EH40/90, Occupational Exposure Limits 1990 (HMSO Publisher). Control of Substances Hazardous to Health Regulations 1988 (SI 1988/1657) (HMSO). Respiratory Protective Equipment - A Practical Guide for Users (ISBN 011 8855220) (HMSO Publisher). Respiratory Protective Equipment - legislative requirements and lists of HSE approved standards and type approved equipment (ISBN 0 11 885609 X) (HMSO) For further information JCB SERVICE - PARTS DIVISION contact : ROCESTER STAFFORDSHIRE ST14 5LS TELEPHONE 01889 590312 * Note: Items marked with an asterisk (*) have been amended since last issue. 9804/8934* ISSUE 4, (REV.) MAY 1997 4. FIRST-AID MEASURES Inhalation: Should not be a problem as product is of low volatility. However, if feeling unwell remove to fresh air. Skin Contact: Wash skin with plenty of soap and water. Eye Contact: Flush eyes immediately with plenty of water for at least 15 minutes. Ingestion: Rinse mouth with water, then give plenty of water or milk to drink. Do not induce vomiting. 5. FIRE-FIGHTING MEASURES Non flammable product (flash point is greater than 100 0C (CC)). If product is involved in fire extinguish with dry powder, foam or carbon dioxide. 6. ACCIDENTAL RELEASE MEASURES For small spills wipe up with paper towel and place in container for disposal. For large spills absorb onto inert absorbant material and place in sealed container for disposal. Ventilate area. 7. HANDLING AND STORAGE 7.1 Handling: Loctite applicators are recommended to minimise skin contact particularly where workers are handling sharp or threaded parts which might result in microlaceration of sensitive areas of the skin. Adequate ventilation is recommended to remove traces of odour. Inhalation Prolonged or repeated exposure will have the following effects:- irritation of nose, throat and respiratory tract. 4. FIRST-AID MEASURES Eye Contact: Immediately flood the eye with plenty of water for at least 10 minutes, holding the eye open. Obtain medical attention urgently. Skin Contact: Wash skin thoroughly with soap and water. Ingestion: Do not induce vomiting. Have victim drink 240-300ml of water. If vomiting occurs naturally, rinse mouth and repeat administration of water. Obtain medical attention. Inhalation: Remove from exposure. Obtain medical attention. 9804/8990 ISSUE 4, NOVEMBER 1997 5. FIRE-FIGHTING MEASURES Extinguishing Media: Use foam, dry chemical or carbon dioxide. Special Hazards of Product: May form explosive mixtures with air. Vapours can travel a considerable distance to a source of ignition and flashback. Protective Equipment for Fire-Fighting: Combustion will produce smoke, carbon dioxide and carbon monoxide. Wear self contained breathing apparatus. 6. ACCIDENTAL RELEASE MEASURES Personal Precautions: Wear appropriate protective clothing. Eliminate all sources of ignition. Spillages: Contain and absorb using earth, sand or other inert material. Transfer into suitable containers for recovery or disposal. Environmental Precautions: Try to prevent the material from entering drains or water courses. 7. HANDLING AND STORAGE Handling: Exposure by inhalation or skin contact should be minimised by good industrial Hygiene practices. Avoid inhaling vapour. Avoid contact with eyes, skin and clothing. Use in well ventilated areas. Keep container tightly closed when not in use. Under normal conditions of use, the mineral oils and other ingredients used in this product present no risk of acute intoxication. The product contains no eye or skin irritants and is not considered to be allergenic. On eyes: May cause temporary irritation and discomfort On skin: Generally non-irritant on incidental contact. Excessive or prolonged contact may give rise to slight irritation. By inhalation: Harmful concentrations of vapour do not normally arise except under high temperature or high atomisation. High concentrations of mist may give rise to respiratory irritation. By ingestion: Ingestion of large quantities may cause nausea, sickness and diarrhoea. Chronic: No hazard anticipated Other: Products which have become contaminated might present more serious health effects. 9804/9049 ISSUE 1, MARCH 2003

Health Effects - Skin

080MF0I&M3I# 1&81 7 320I&4 3FM4F&/M5&70MI&F &I01/MFGFGE<& Repeated and/or prolonged contact may lead to dermatitis. 4. FIRST-AID MEASURES Eye Contact: Wash out eye with plenty of water. Obtain medical assistance if soreness or redness persists. Skin Contact: Wash skin with soap and water. If grease has been injected under the skin, seek medical advice immediately. Ingestion: Do not induce vomiting. Obtain medical attention. 5. FIRE-FIGHTING MEASURES Extinguishing Media: Foam, dry chemical or carbon dioxide. Do not use water jet. Special fire fighting procedures: This product may give rise to hazardous fumes in a fire. cont’d 9804/8931 ISSUE 3 (REV.), JUNE 2002 Repeated or prolonged contact may produce defatting of the skin leading to irritation and dermatitis. Skin absorption may be a significant route for exposure. Material may cause slight irritation on prolonged or repeated contact. Skin absorbtion may be a significant route for exposure. Material might cause slight irritation on prolonged exposure.

Contains

9804/8947 ISSUE 3 (REV.), JULY 2000 5. ACCIDENTAL RELEASE MEASURES Personal Precautions S0M1&M881 81GMF0&81 F04FGR0&47 F9G32<& Environmental Precautions 615&F &810R03F&F90&/MF01GM7&K1:/&03F01G32&I1MG3E& 1&QMF01&4 H1E0E<& Spillages ( 3FMG3&M3I&MJE 1J&HEG32&0M1F9Y&EM3I& 1& F901&G301F&/MF01GM7<&61M3EK01& G3F &EHGFMJ70&4 3FMG301E&K 1&104 R015& 1&IGE8 EM7<& & 6. HANDLING AND STORAGE Handling ; &E804GM7&8104MHFG 3E&3040EEM15<& 9804/8947 ISSUE 3 (REV.), JULY 2000 12. DISPOSAL CONSIDERATIONS Product Disposal .34G301MFG 3<&WGE8 E0& K&G3&M44 1IM340&QGF9&M77&M887G4MJ70&7 4M7&M3I&3MFG 3M7& 102H7MFG:3E<& Container Disposal ; &E804GKG4&/0MEH10E&3040EEM15<& & 13. TRANSPORT INFORMATION UN Class ; F&47MEEGKG0I<& ADR/RID - Class ; F&47MEEGKG0I<& IMDG - Class ; F&47MEEGKG0I<& IATA - Class ; F&47MEEGKG0I<& & 14. REGULATORY INFORMATION 4. FIRST-AID MEASURES Eyes: Flush the eye with copious amounts of water. No emergency measures are necessary but if adverse eye effects follow, refer for medical attention. Skin: Wash the contaminated skin thoroughly with soap and water. No emergency measures are necessary but if adverse skin effects follow, refer for medical attention. Inhalation: Remove the affected person to fresh air. If recovery is not rapid, obtain medical attention. Ingestion: DO NOT INDUCE VOMITING. No emergency measures are needed but if adverse health effects follow, refer for medical attention. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering measures: No special measures needed. Control parameters: TWA TLV (ACGIH): 5 mg/m3 for oil mist. However, in all circumstances exposure should be kept as low as reasonably possible by good ventilation and safe working practices. Respiratory protection: Inhalation of vapours, fumes or mists should be avoided by safe working practices and good ventilation. Eye protection: If there is a risk of splashing while handling product, eye protection should be worn (e.g. full face shield or goggles with side shields). Skin protection: Prolonged and repeated skin contact should be avoided by the use of clean gloves and clean overalls. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Oily liquid Colour: Yellow R&S phrases: None 9804/8910 ISSUE 5, (REV.) JULY 2000 ' Product Name: JCB High Performance Multigrade Engine Oil 10W30 Grade: #"*+)"' Use ,-./0123045'607'86/'2-369630 ;';4504;<' Distributor: =>?'@ABCD>A' Emergency Contact : A9;/5;41E'F;7;GH64;'I6JK'L!!'M"N' 9804/8910 ISSUE 5, (REV.) JULY 2000 9804/8910 ISSUE 5, (REV.) JULY 2000 7. HANDLING AND STORAGE Handling U 60R'G/67645;R'6/'/;G;23;R'<W04'1643213J'U 60R'04H2723064'68' 2G6-/<&'90<3<'6/'8-9;<J'[6'463'];2/' 1643290423;R'1763H045J' ' 9804/8910 ISSUE 5, (REV.) JULY 2000 R&S phrases: I64;' ' Special fire fighting procedures: Water or foam may cause frothing. Use water to keep fire exposed containers cool. Water spray may be used to flush spills away from exposures. Prevent runoff from fire control or dilution from entering waterways or drinking water supply. Special Protective Equipment: For fires in enclosed areas, firefighters MUST use self-contained breathing apparatus. Unusual fire and explosion hazards: None Flash Point °C (°F): 238 (460) (IP 36/ASTM D-92) Flammable Limits: LEL NA, UEL NA. NFPA Hazard ID: Health: 0 Flammability: 1 Reactivity: 0 Hazardous decomposition products: Carbon monoxide. Metal oxides. Elemental oxides. 6. ACCIDENTAL RELEASE MEASURES Notification procedures: Report spills as required to appropriate authorities such as the local Environmental Health Officer or Fire Brigade. If spills are likely to enter any drain, waterway or groundwater, contact the Area Water Authority. In case of accident or road spill, contact the Police and Fire Brigade and, if appropriate, the Area Water Authority. Procedures if material is released or spilled: Contain and absorb on fire retardant treated sawdust, diatomaceous earth, etc. Shovel up and dispose of at an appropriate licensed waste disposal site in accordance with current applicable laws and regulations and product characteristics at time of disposal. Environmental Precautions: Prevent spills from entering storm sewers or drains and contact with soil. Personal precautions: See Section 8. 7. HANDLING AND STORAGE Handling: No special precautions are necessary beyond normal good hygiene practices. See Section 8 for additional personal protection advice when handling this product. Respiratory Protection No special requirements under ordinary conditions of use and with adequate ventilation. Ventilation No special requirements under ordinary conditions of use and with adequate ventilation. Exposure Limits This product does not contain any components which have recognised exposure limits. However, a threshold limit value of 5.00 mg/m3 is suggested for oil mist. 9. PHYSICAL AND CHEMICAL PROPERTIES Typical physical properties are given below. Consult Product Data Sheet for specific details. Physical State: Liquid Colour: Amber Odour: Mild Odour Threshold: NA pH: NA Boiling Point °C (°F): >316 (600) Melting Point °C (°F): NA Flash Point °C (°F): 238 (460) (IP 36/ASTM D-92) Flammability: NA Auto Flammability: NE Explosive Properties: NA Oxidising Properties: NA Vapour Pressure - mm Hg 20 °C: < 0.1 Vapour Density: NA Evaporation Rate: NA Relative Density: 15/4 °C: 0.888 Solubility in Water: Negligible Partition Coefficient: > 3.5 Viscosity at 40°C, cSt: 91.4 Viscosity at 100°C, cSt: 11.0 Pour Point °C (°F):: -23 (-9) Freezing Point °C (°F): NE NA = Not Applicable NE = Not Established D = Decomposes For further technical information contact JCB Service. 10. STABILITY AND REACTIVITY Stability (thermal, light etc.): Stable Conditions to avoid: Extreme heat Incompatibility (materials to avoid): Strong oxidisers Hazardous decomposition products: Carbon monoxide. Metal oxides. Elemental oxides. Hazardous polymerisation: Will not occur Skin irritation: Practically non-irritating. (Primary Irritation Index: greater than 0.5 but less than 3). Based on testing of similar products and/or the components. Other Acute Toxicity data: The acute toxicological results summarised previously are based on testing of representative products. Representative formulations have shown no acute effects, administered via the inhalation route, when tested at maximum attainable oil mist or vapour concentrations. Subchronic Toxicology (summary): Representative formulations have been tested by dermal applications 5 days/week for 90 days at doses significantly higher than those expected during normal industrial exposure. Extensive evaluations, including microscopic examination of internal organs and clinical chemistry of body fluids, showed no adverse effects. Reproductive Toxicology (summary): Dermal exposure of pregnant rats to representative formulations did not cause effects in either the mothers or their offspring. Chronic Toxicology (summary): The base oils in this product are severely solvent refined and/or severely hydrotreated. Chronic skin painting studies of severely treated oils showed no evidence of carcinogenic effects. These results are confirmed on a continuing basis. Sensitisation (summary): Representative formulations have not caused skin sensitisation in guinea pigs. Other Toxicology Data: Used gasoline engine oils have shown evidence of skin carcinogenic activity in laboratory tests when no effort was made to wash the oil off between applications. Used oil from diesel engines did not produce this effect. 15. REGULATORY INFORMATION 4. FIRST-AID MEASURES Eyes: Flush the eye with copious amounts of water. No emergency measures are necessary but if adverse eye effects follow, refer for medical attention. Skin: Wash the contaminated skin thoroughly with soap and water. No emergency measures are necessary but if adverse skin effects follow, refer for medical attention. Inhalation: Remove the affected person to fresh air. If recovery is not rapid, obtain medical attention. Ingestion: DO NOT INDUCE VOMITING. Obtain medical attention immediately. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering measures: No special measures needed. Control parameters: No internationally recognised exposure limit established. In all circumstances exposure should be kept as low as reasonably possible by good ventilation and safe working practices. Respiratory protection: Inhalation of vapours, fumes or mist should be avoided by safe working practices and good ventilation. Eye protection: If there is a risk of splashing while handling product, eye protection should be worn (e.g. full face shield or goggles with side shields). Skin protection: Skin contact should be avoided by the use of clean gloves and clean overalls. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Lliquid Colour: Light yellow R&S phrases: S 2: Keep out of reach of children. Injection under the skin of oil or grease under very high pressure is a serious emergency which should immediately be referred to hospital. A copy of this data sheet should accompany the casualty to hospital for the information of the medical staff. 4. FIRST-AID MEASURES Eyes: Flush the eye with copious amounts of water. No emergency measures are necessary but if adverse eye effects follow, refer for medical attention. Skin: Wash the contaminated skin thoroughly with soap and water. No emergency measures are necessary but if adverse skin effects follow, refer for medical attention. Inhalation: Remove the affected person to fresh air. If recovery is not rapid, obtain medical attention. Ingestion: DO NOT INDUCE VOMITING. No emergency measures are needed but if adverse health effects follow, refer for medical attention. 7. HANDLING AND STORAGE Handling: Avoid prolonged or repeated skin contact. Avoid inhalation of vapour, mist or fumes. Do not wear contaminated clothing. R&S phrases: None 4. FIRST-AID MEASURES Eyes: Flush the eye with copious amounts of water. No emergency measures are necessary but if adverse eye effects follow, refer for medical attention. Skin: Wash the contaminated skin thoroughly with soap and water. No emergency measures are necessary but if adverse skin effects follow, refer for medical attention. Inhalation: Remove the affected person to fresh air. If recovery is not rapid, obtain medical attention. Ingestion: DO NOT INDUCE VOMITING. No emergency measures are needed but if adverse health effects follow, refer for medical attention. 7. HANDLING AND STORAGE Handling: Avoid prolonged or repeated skin contact. Avoid inhalation of vapour, mist or fumes. Do not wear contaminated clothing. R&S phrases: None 4. FIRST-AID MEASURES Eyes: Flush the eye with copious amounts of water. No emergency measures are necessary but if adverse eye effects follow, refer for medical attention. Skin: Wash the contaminated skin thoroughly with soap and water. No emergency measures are necessary but if adverse skin effects follow, refer for medical attention. Inhalation: Remove the affected person to fresh air. If recovery is not rapid, obtain medical attention. Ingestion: DO NOT INDUCE VOMITING. No emergency measures are needed but if adverse health effects follow, refer for medical attention. 7. HANDLING AND STORAGE Handling: Avoid prolonged or repeated skin contact. Avoid inhalation of vapour, mist or fumes. Do not wear contaminated clothing. R&S phrases: None Special Protective Equipment: Wear self contained breathing apparatus. 6. ACCIDENTAL RELEASE MEASURES Procedures if material is released or spilled: Material can create slippery conditions underfoot. Transfer into suitable containers for recovery or disposal. 7. HANDLING AND STORAGE Handling: When applying by grease gun, care must be taken not to inject this product under the skin. Persistence/ Degradability: The product is expected to be resistant to biodegradation. Bio-accumulation: Product is not expected to bioaccumulate. 13. DISPOSAL CONSIDERATIONS Product Disposal Incineration or landfill. Dispose of in accordance with all applicable local and national regulations. Container Disposal No specific measures necessary. 14. TRANSPORT INFORMATION UN Class: Not classified ADR/RID Class: Not classified IMDG Class: Not classified IATA Class: Not classified 15. REGULATORY INFORMATION 4. FIRST-AID MEASURES Eyes: Flush the eye with copious amounts of water. No emergency measures are necessary but if adverse eye effects follow, refer for medical attention. Skin: Wash the contaminated skin thoroughly with soap and water. No emergency measures are necessary but if adverse skin effects follow, refer for medical attention. Inhalation: Remove the affected person to fresh air. If recovery is not rapid, obtain medical attention. Ingestion: DO NOT INDUCE VOMITING. No emergency measures are needed but if adverse health effects follow, refer for medical attention. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering measures: No special measures needed. Control parameters: TWA TLV (ACGIH): 5 mg/m3 for oil mist. However, in all circumstances exposure should be kept as low as reasonably possible by good ventilation and safe working practices. Respiratory protection: Inhalation of vapours, fumes or mists should be avoided by safe working practices and good ventilation. Eye protection: If there is a risk of splashing while handling product, eye protection should be worn (e.g. full face shield or goggles with side shields). Skin protection: Prolonged and repeated skin contact should be avoided by the use of clean gloves and clean overalls. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Oily liquid Colour: Brown R&S phrases: None 9804/8994 ISSUE 2, JULY 2000 Effects of Overexposure: *H2C&2002D@D2;CN& & 4. FIRST-AID MEASURES Eye Contact: _5=>L&DL;0;=IL5Q&G2DL&G@D/0N&.K&2002D@D2;C&;33=0>\&3@55&@&?;3D;0N& Skin Contact: ]@>L&3;CD@3D&@0/@>&G2DL&>;@A&@C?&G@D/0N&,/B;1/&3;CD@B2C@D/?&35;DL2CIN&O@=C?/0&3;CD@B2C@D/?&35;DL2CI&</K;0/& 0/E=>/N& Inhalation: ,/B;1/&K0;B&K=0DL/0&/JA;>=0/N&.K&0/>A20@D;0Q&2002D@D2;C\&?2ee2C/>>\&C@=>/@&;0&=C3;C>32;=>C/>>&;33=0>\&>//H& B/?23@5&@>>2>D@C3/&@C?&3@55&@C&@B<=5@C3/N&.K&<0/@DL2CI&L@>&>D;AA/?\&=>/&B;=DL&D;&B;=DL&0/>=>32D@D2;CN& & Ingestion: a;D&/JA/3D/?&D;&</&@&A0;<5/BN&d;G/1/0\&2K&I0/@D/0&DL@C&7&#:&52D0/&UA2CDV&2>&2CI/>D/?&;0&2K&K//52CI&=C3;BK;0D@<5/\&I21/& 7&D;&:&I5@>>/>&;K&G@D/0&@C?&;<D@2C&B/?23@5&@DD/CD2;C&;0&3@55&@C&@B<=5@C3/&K;0&@>>2>D@C3/N&[c&ac4&.a[f(+& -cM.4.aW&;0&I21/&@CQDL2CI&<Q&B;=DL&D;&@C&=C3;C>32;=>&A/0>;CN& & 5. FIRE-FIGHTING MEASURES Extinguishing Media: (@0<;C&?2;J2?/\&K;@B\&?0Q&3L/B23@5&@C?&G@D/0&K;IN& Special Fire Fighting Procedures: ]@D/0&;0&K;@B&B@Q&3@=>/&K0;DL2CIN&f>/&G@D/0&D;&H//A&K20/&/JA;>/?&3;CD@2C/0>&3;;5N&]@D/0&>A0@Q&B@Q&</&=>/?&D;& K5=>L&>A255>&@G@Q&K0;B&/JA;>=0/>N&R0/1/CD&0=C;KK&K0;B&K20/&3;CD0;5&;0&?25=D2;C&K0;B&/CD/02CI&G@D/0G@Q>&;0&?02CH2CI& G@D/0&>=AA5QN& & Special Protective Equipment: _;0&K20/>&2C&/C35;>/?&@0/@>\&K20/K2ILD/0>&Mf*4&=>/&>/5KE3;CD@2C/?&<0/@DL2CI&@AA@0@D=>N& & Unusual Fire and Explosion Hazards: +JA;>=0/&D;&K20/&3@C&I/C/0@D/&D;J23&K=B/>N& & Flash Point 9"&Z(&U!8 &Z_V&U.R&$! 9804/8994 ISSUE 2, JULY 2000 Environmental Precautions: R0/1/CD&>A255>&K0;B&/CD/02CI&>D;0B&>/G/0>&;0&?0@2C>&@C?&3;CD@3D&G2DL&>;25N& & Personal Precautions: *//&*/3D2;C&8N& & 7. HANDLING AND STORAGE Handling: P1;2?&3;CD@3D&G2DL&>H2CN& & 9804/8994 ISSUE 2, JULY 2000 10. STABILITY AND REACTIVITY Stability (Thermal, Light, etc.): *D@<5/& Conditions to Avoid: +JD0/B/&L/@D& Incompatibility (materials to avoid): *D0;CI&;J2?2>/0>& Hazardous Decomposition Products: (@0<;C&B;C;J2?/\&AL;>AL;0=>&;J2?/>& Hazardous Polymerisation: ]255&C;D&;33=0& & & 15. REGULATORY INFORMATION The following product ingredients are cited on the lists below: (L/B23@5&a@B/&(P*&a=B</0&O2>D&(2D@D2;C>& a;&0/A;0D@<5/&2CI0/?2/CD>& ,/I=5@D;0Q&O2>D>&*/@03L/?& 7i.P,(&7&Yiac&POO+,W.&77i[+&4+,P4&)&7Yi[+&(P,(&)&:7i(d&(P,(& i.P,(& P&`i*+&POO+,Wj&7 i[+&4+,P4&(&7`iP4&4+,P4&P& $i.P,(&:)&8i*+&(P,(&7$i[+&4+,P4&[&78iP4&4+,P4&)& !ia4R&(P,(&%i[b&(P,(&7!i[+&(P,(&P7&7%iP4&4+,P4&(& 9ia4R&*f*&7"i[+&4+,P4&P&79i[+&(P,(&P & "iP4&4+,P4&[& (P,(i(P,(.acW+aT&*f*i*f*R+(4+[&(P,(.acW+aT&4+,P4i4+,P4cW+a.(& P4iP=>D02@&[+iW/0B@CQ&acia;0G@Q& (di*G2De/05@C?&[bi[/CB@0H&*+i*G/?/C& & < 75% Health (Class): - Risk (R No.): Composition Comments: A blend of waxes, corrosion inhibitors, aliphatic solvents. Main Hazards: Flammable 4. FIRST-AID MEASURES Eye Contact: Promptly wash eyes with lots of water while lifting the eye lids. Continue to rinse for at least 15 minutes and get medical attention. Skin Contact: Wash the skin immediately with soap and water. Inhalation: Move the exposed person to fresh air at once. Perform artificial respiration if breathing has stopped. Keep the affected person warm and at rest. Get prompt medical attention. Ingestion: Do NOT induce vomiting. Get medical attention immediately. 9804/8895 ISSUE 3 (REV.), NOVEMBER 1997 5. FIRE-FIGHTING MEASURES Extinguishing Media: Powder, foam or CO2 Special fire fighting procedures: Cool containers exposed to fire with water spray. Unusual fire fighting procedures: Hazardous decomposition products: Irritating gases/vapours/fumes of carbon monoxide (CO). 6. ACCIDENTAL RELEASE MEASURES Spill clean up methods: Extinguish all ignition sources. Avoid sparks, flames, heat and smoking. Ventilate. Absorb in vermiculite, dry sand or earth and place into containers. Confine spill. Do not allow product to enter drains. Clean area with detergent due to risk of slippery surface. 7. HANDLING AND STORAGE Usage precautions: Keep away from heat, sparks and open flame. Avoid spilling, skin and eye contact. Storage precautions: Keep away from heat, sparks and open flame. Store in a cool, dry ventilated place. Keep away from childen. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Ingredient name: White spirit Cas No. 64742-88-7 STD OES LT Exp (8 hrs): 100 ppm ST Exp (15 mins): 125 ppm Eye Protection Wear chemical safety goggles where eye exposure is reasonably probable. Protective gloves Chemical resistant gloves required for prolonged or repeated contact. Respirators Where good natural (or mechanical exhaust) ventilation is not practicable, suitable respiratory equipment must be worn. 9. PHYSICAL AND CHEMICAL PROPERTIES Colour: Light brown Appearance: Viscous Liquid Odour/Taste: Characteristic Solubility description: Immiscible with water Solubility value (g/100g H20/20°C): N/D Specific gravity (Water = 1): 0.8 @ 20°C Evaporation rate (EtEt = 1): 63 Vapour pressure mmHg: 3.3 @ 20°C Vapour density (air = 1): N/D Boiling point (°C): 145°C 760 mmHg Flash point (°C): 35°C Flash point method: CC (Closed cup) Auto ignition temperature (°C): 230°C cont’d 9804/8895 ISSUE 3 (REV.), NOVEMBER 1997 Flammability limit lower %: 0.90% Flammability limit upper %: 8% 10. STABILITY AND REACTIVITY Materials to avoid: Strong oxidising agents. Hazardous decomposition products: Irritating gases/vapours/fumes of carbon monoxide (CO) Not applicable Substance identification number : Not applicable Other regulations : Government inventory status : All components registered in accordance with EINECS and TSCA. COSHH regulations : Product reviewed under COSHH. For further information JCB SERVICE - PARTS DIVISION contact : ROCESTER STAFFORDSHIRE ST14 5LS TELEPHONE 01889 590312 9804/8891 ISSUE 6, (REV.) MARCH 2003 JCB Universal Agricultural Oil Grade: Lubricating oil for tractors Severely solvent refined mineral oil (appr. 90%). Additives (appr. 10%), mainly: Poly olefin amines Zinc alkyldithiophosphate Calcium/magnesium sulphonates & phenates 4. FIRST-AID MEASURES Eyes: Flush the eye with copious amounts of water. No emergency measures are necessary but if adverse eye effects follow, refer for medical attention. Skin: Wash the contaminated skin thoroughly with soap and water. No emergency measures are necessary but if adverse skin effects follow, refer for medical attention. Inhalation: Remove the affected person to fresh air. If recovery is not rapid, obtain medical attention. Ingestion: DO NOT INDUCE VOMITING. No emergency measures are needed but if adverse health effects follow, refer for medical attention. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering measures: No special measures needed. Control parameters: TWA TLV (ACGIH): 5 mg/m3 for oil mist. However, in all circumstances exposure should be kept as low as reasonably possible by good ventilation and safe working practices. Respiratory protection: Inhalation of vapours, fumes or mist should be avoided by safe working practices and good ventilation. Eye protection: If there is a risk of splashing while handling product, eye protection should be worn (e.g. full face shield or goggles with side shields). Skin protection: Prolonged and repeated skin contact should be avoided by the use of clean gloves and clean overalls. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Oily liquid Colour: Light brown R&S phrases: None *4. FIRST-AID MEASURES Eye: Immediate medical attention is not required. Irrigate with eyewash solution or clean water until pain is relieved. If symptoms develop, obtain medical attention. Skin Contact: Immediate medical attention is not required. Wash skin with soap and water. If symptoms develop, obtain medical attention. Inhalation: Immediate medical attention is not required. Remove to fresh air. Get medical attention if irritation persists. Ingestion: Immediate medical attention is not required. Treat symptomatically and supportively. *5. FIRE-FIGHTING MEASURES Extinguishing Media: CO2; Dry Chemical; Foam; Water Fog Special Firefighting Procedures: Fire fighters should be equipped with self-contained breathing apparatus to protect against potentially toxic and irritating fumes. Fire & Explosion Hazards: Combustion may release noxious or toxic vapours. See below. Hazardous Combustion Products: Carbon monoxide, carbon dioxide, unknown hydrocarbons. Flash Point: > 100 °C *6. ACCIDENTAL RELEASE MEASURES Spill and Leak Procedures: Adsorb spillages onto sand, earth or any suitable adsorbent material. Scrape up and place in suitably labelled container for disposal. For safety and environmental precautions, please review entire Safety Data Sheet for necessary information. *7. HANDLING AND STORAGE Handling/Storage: Store in cool, dry place. Avoid the absence of air, and metal contamination. Sensitive to Static Electricity: No Sensitivity to Mechanical Impact: No Specific Uses: This product is not recommended for use in joints which will be in contact with either pure oxygen or steam. *8. EXPOSURE CONTROLS/PERSONAL PROTECTION OCCUPATIONAL EXPOSURE CONTROLS Ventilation Requirements: General. Eye Protection Requirements: Safety glasses, goggles or face shield to protect against splashing. Personal eye protection should conform to EN 166. Glove Requirements: Nitrile rubber or Viton™ gloves are recommended. Cotton or other absorbent gloves should not be worn. Gloves should conform to EN 374. Clothing Requirements: Uniforms, coveralls, or a lab coat should be worn. Wash requirements: Wash before eating, drinking, or using toilet facilities. Respiratory Requirements: None required under normal handling conditions. 9804/9000 ISSUE 2, (REV) SEPTEMBER 2002 *9. PHYSICAL AND CHEMICAL PROPERTIES Pure Substance or Preparation: Preparation Physical Form: Liquid *14. TRANSPORT INFORMATION (See also section 9) *5. FIRE-FIGHTING MEASURES Extinguishing Media: CO2; Dry Chemical; Foam Special Firefighting Procedures: Fire fighters should be equipped with self-contained breathing apparatus to protect against potentially toxic and irritating fumes. Fire & Explosion Hazards: Cloths used to wipe up spills may cause rapid polymerization that could generate sufficient heat to ignite the cloth. Hazardous Combustion Products: Decomposes upon heating to release toxic fumes of nitrogen oxides, carbon monoxide, carbon dioxide, and hydrogen cyanide. Flash Point: > 81 °C *6. ACCIDENTAL RELEASE MEASURES Spill and Leak Procedures: Small spills: wipe up with cloth. Immediately soak cloth with water to polymerize the adhesive. Caution! Cloth containing adhesive may undergo autoignition if not soaked with water. Large spills: flood area with water. When cured, remove film with a scraper. Wear approved respirator for organic vapours if needed, and protective clothing. For safety and environmental precautions, please review entire Safety Data Sheet for necessary information. *7. HANDLING AND STORAGE *9. PHYSICAL AND CHEMICAL PROPERTIES Pure Substance or Preparation: Preparation Physical Form: Liquid Colour: Colourless Odour: Pungnet Boiling Point: > 100 °C Solubility in Water: Insoluble Viscosity: Approximately 95 mPa.s Relative Density: 1.06 Vapour Pressure (mmHg): > 0.5 mm Hg Flash Point: > 81 °C *10. STABILITY AND REACTIVITY Stability: Stable Conditions to Avoid: Elevated temperatures. Materials to Avoid: Water., Amines., Bases., Peroxides. Hazardous decomposition Products: Decomposes upon heating to release toxic fumes of nitrogen oxides, carbon monoxide, carbon dioxide, and hydrogen cyanide. *14. TRANSPORT INFORMATION (See also section 9) Ethyl-2-cyanoacrylate Ingestion: Ethylene glycol and diethylene glycol are toxic when swallowed. A lethal dose for an adult is 1 - 2 ml per kilogram, or about 100 ml. Symptoms include staggering, slurred speech, loss of coordination, confusion, faintness, nausea, vomiting, increased heart rate, difficulty breathing, difficulty seeing, convulsions and collapse. Symptoms may be delayed. Decreased urine output, kidney failure, and nervous system damage may also occur. Aspiration may occur during swallowing or vomiting, resulting in lung damage. Chronic effects of exposure to man: Repeated ingestion may cause kidney damage. * 6. ACCIDENTAL RELEASE MEASURES Procedures in case of accidental Ventilate area. Avoid breathing vapour. Use self-contained breathing apparatus or release or leakage: supplied air mask for large spills or confined areas. Contain spill if possible. Wipe up or absorb on suitable material and shovel up. Prevent entry into sewers and waterways. Avoid contact with skin, eyes or clothing. * 7. HANDLING AND STORAGE Handling: Periods of exposure to high temperature should be minimised. Water contamination should be avoided. Eye contact: Unlikely to cause more than transient stinging or redness if accidental eye contact occurs. Ingestion: Harmful. Causes headache, weakness, confusion, loss of coordination, dizziness, difficulty walking, nausea, vomiting, decreased blood pressure, increased heart rate, pulmonary oedema, kidney failure, unconsciousness, convulsions, and coma. Symptoms may be delayed. Sever poisoning may cause death. Chronic Repeated ingestion may cause kidney damage. Repeated overexposure may aggravate an existing kidney disease. * 4. FIRST-AID MEASURES 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Wear goggles or safety glasses. Wear protective gloves (Rubber or Plastic). Avoid breathing mist or spray. Wear protective apron, suit and boots if danger of splashing (e.g. use via pressure washer). Refer to section 15. 9. PHYSICAL AND CHEMICAL PROPERTIES 14. TRANSPORT INFORMATION JCB Plantwash is not classified as hazardous for transportation. SIN: Not applicable ADR Hazard Class: Not applicable ADR List No.: Not applicable ADR Hazard No.: Not applicable 15. REGULATORY INFORMATION JCB Plantwash is regulated by CHIP as irritant for supply. Alkaline Detergent blend) Inhalation: High levels of vapour/mist may cause dizziness. Can cause irritation of the respiratory tract. Ingestion: Accidental ingestion is an unlikely event. 5. FIRST-AID MEASURES Eye Contact: Contact lenses should be removed. Irrigate copiously with clean, fresh water for at least 10 minutes, holding the eyelids apart. Seek medical advice. Skin Contact: Remove contaminated clothing. Wash skin thoroughly with soap and water or use a proprietary skin cleaner Inhalation: Remove to fresh air, keep the patient warm and at rest. If breathing is irregular or has stopped, administer artificial respiration. Give nothing by mouth. If unconscious, place in the recovery position and seek medical advice. Ingestion: If accidentally swallowed, obtain immediate medical attention. Keep at rest. DO NOT INDUCE VOMITTING. 6. FIRE-FIGHTING MEASURES Extinguising Media: Alcohol resistant foam/CO2/powder/water spray/mist.DO NOT USE WATER JET. Special Fire Fighting Procedures: Fire exposed containers should be sprayed with water to lessen risk of explosion. Unusual Fire and Explosion Hazards: Fire will produce dense black smoke containing combustion products which may be a health hazard. Appropriate self-contained breathing apparatus may be required. RUN OFF FROM FIRE MUST NOT ENTER DRAINS. 7. ACCIDENTAL RELEASE MEASURES Procedures for leaks or spillage: Exclude sources of ignition and ventilate the area. Exclude non-essential personnel. Avoid breathing vapours. Refer to protective measures listed in Sections 7 and 8. Contain and collect spillages with non-combustible absorbent materials e.g. sand, earth, vermiculite, diatomaceous earth and place in a suitable container for disposal in accordance with waste regulations (see Section 3). DO NOT ALLOW TO ENTER DRAINS OR WATER COURSES. Clean preferably with a detergent; avoid the use of solvents.If the product enters drains or sewers, the local water company should be contacted immediately, or in the case of contamination of streams, rivers or lakes, the National Rivers Authority. 8. HANDLING AND STORAGE Handling: Vapours are heavier than air and may spread along floors. They may form explosive mixtures with air. Prevent the creation of flammable or explosive concentrations of vapour in air and avoid vapour concentrations higher than the occupational exposure limits. DO NOT USE ON AN ENGINE WHILST IT IS RUNNING. Use only in areas from which all sources of heat, sparks and open flame have been excluded. Avoid skin and eye contact. 9804/9018 ISSUE 1, March 2001 Avoid inhalation of vapour and spray mist. Smoking, eating and drinking should be prohihited in areas of use and storage. READ DIRECTIONS FOR USE PRINTED ON EACH UNIT OF USE. Solubility (Solvent): Soluble in aliphatic hydrocarbons 11. STABILITY AND REACTIVITY Stability: Stable Conditions to Avoid: Naked flames, red hot surfaces, other high temperature sources that may induce thermal decomposition. Incompatibility (materials to avoid): Oxidising agents, strong acids, strong alkalis. Hazardous Decomposition Products: In a fire hazardous decomposition products such as smoke, carbon monoxide, carbon dioxide and oxides of nitrogen may be produced. Using the information provided in this data sheet, advice should be obtained from the Waste Regulation Authority as to whether the special waste regulations apply. 15. TRANSPORT INFORMATION CCCN: 3403 99 10 UN NO: 1950 AEROSOL: CLASS 2 ADR ITEM: 5 F PACKING GROUP: 2 DANGEROUS GOODS IN LIMITED QUANTITIES: EEC TARIFF NO. 340399-10-0 16. REGULATORY INFORMATION LABEL FOR SUPPLY: CAUTION FLAMMABLE *4. FIRST-AID MEASURES Eye: Immediate medical attention is not required. Irrigate with eyewash solution or clean water until pain is relieved. If symptoms develop, obtain medical attention. Skin Contact: Immediate medical attention is not required. Wash skin with soap and water. If symptoms develop, obtain medical attention. Inhalation: Immediate medical attention is not required. Remove patient from exposure. Ingestion: Obtain immediate medical attention. If swallowed, DO NOT induce vomiting. Keep at rest. *5. FIRE-FIGHTING MEASURES Extinguishiing Media: Dry Chemical; Foam Special Firefighting Procedures: Fire fighters should be equipped with self-contained breathing apparatus to protect against potentially toxic and irritating fumes. Fire & Explosion Hazards: Dangerous fire hazard when exposed to heat or flame. Hazardous Combustion Products: Thermal decomposition may release toxic and/or hazardous gases. Lower Explosion Limit (%): 1.4 % Upper Explosion Limit (%): 9.5 % Autoflammability: > 300 °C Flash Point: < -100 °C 6. ACCIDENTAL RELEASE MEASURES Spill and Leak Procedures: Shut off ignition sources. Stop leak if you can do it without risk. For small liquid spills, take up with sand or other absorbent material. For larger spills, dam far ahead of spill for later disposal. No smoking, flames or flares in hazard area. Keep unnecessary people away. For safety and environmental precautions, please review entire Safety Data Sheet for necessary information. *7. HANDLING AND STORAGE *9. PHYSICAL AND CHEMICAL PROPERTIES Pure Substance or Preparation: Preparation Physical Form: Liquid Colour: Colourless Odour: Petrol-like Boiling Point: Not applicable Solubility in Water: Insoluble Relative Density: 0.65 Vapour Density (air=1): >1.0 Volatile Organic Compounds: 100% Autoflammability: > 300 C Flash Point: < -100 °C *10. STABILITY AND REACTIVITY Stability: Stable *14. TRANSPORT INFORMATION (See also section 9) (class) (R No.) % Xylene, mixture of isomers 1330-20-7 Xn 20/21-38 5-10 Acetone 67-64-1 None 25-50 1-Methoxy-2-Propanol 107-98-2 None 1-5 Butane 106-97-8 None 10-25 Propane 74-98-6 None 10-25 (class) (R No.) % Xylene, mixture of isomers 1330-20-7 Xn 20/21-38 10-25 Acetone 67-64-1 None 25-50 Acrylic resin. 5-10 Wetting agents and plasticisers 1-5 Fillers and viscosity control compounds. 1-5 Pigments. 5-10 1-Methoxy Propan-2-ol Acetate 108-65-6 None 1-5 Aromatic hydrocarbon (contains <0.1% benzene) 64742-95-6 Xn 22 1-5 Butane 106-97-8 None 10-25 Propane 74-98-6 None 10-25 Eye contact: Irritating to eyes. Skin contact: Slight skin irritant. Prolonged or repeated contact can cause dermatitis. Inhalation: High levels of vapour/mist may cause dizziness. Can cause irritation of the respiratory tract. Ingestion: Accidental ingestion is an unlikely event. 9804/8952 ISSUE 2 (REV.), APRIL 1997 4. FIRST-AID MEASURES Eye contact: Contact lenses should be removed. Irrigate copiously with clean, fresh water for at least 10 minutes, holding the eyelids apart, and seek medical advice. Skin contact: Remove contaminated clothing. Wash skin thoroughly with soap and water or use a proprietary skin cleaner. DO NOT use solvents or thinners. If in doubt, seek medical advice. Inhalation: Remove to fresh air, keep the patient warm and at rest. If breathing is irregular or has stopped, administer artificial respiration. Give nothing by mouth. If unconscious, place in the recovery position and seek medical advice. Ingestion: If accidentally swallowed, obtain immediate medical attention. Keep at rest. DO NOT induce vomiting. 5. FIRE-FIGHTING MEASURES Extinguishing media: Alcohol resistant foam; CO2; powder; water spray/mist. Do not use: Water jet. Special fire fighting procedures: Fire exposed containers should be sprayed with water to lessen risk of explosion. Unusual fire and explosion hazards: Fire will produce dense black smoke containing combustion products which may be a health hazard. Appropriate self-contained breathing apparatus may be required. Run off from fire must not enter drains. 6. ACCIDENTAL RELEASE MEASURES Procedures for leaks or spillage: Exclude sources of ignition and ventilate the area. Exclude non-essential personnel. Avoid breathing vapours. Refer to protective measures listed in Sections 7 & 8. Contain and collect spillages with non-combustible absorbent materials, e.g. sand, earth, vermiculite, diatomaceous earth and place in a suitable container for disposal in accordance with waste regulations (see Section 13). Do not allow to enter drains or water courses. Clean preferably with a detergent; avoid the use of solvents. If the product enters drains or sewers, the local water company should be contacted immediately; in the case of contamination of streams, rivers or lakes, the National Rivers Authority. 7. HANDLING AND STORAGE Handling: Vapours are heavier than air and may spread along floors. They may form explosive mixtures with air. Prevent the creation of flammable or explosive concentrations of vapour in air and avoid vapour concentrations higher than the occupational exposure limits. Avoid inhalation of vapour and spray mist. Avoid skin and eye contact. Good housekeeping standards and regular safe removal of waste materials will minimise risks of spontaneous combustion and other fire hazards. Smoking, eating and drinking should be prohibited in areas of use and storage. (class) (R No.) % Xylene, mixture of isomers 1330-20-7 Xn 20/21-38 5-10 Acetone 67-64-1 None 25-50 1-Methoxy-2-Propanol 107-98-2 None 1-5 Butane 106-97-8 None 10-25 Propane 74-98-6 None 10-25 (class) (R No.) % Xylene, mixture of isomers 1330-20-7 Xn 20/21-38 5-10 Acetone 67-64-1 None 25-50 1-Methoxy-2-Propanol 107-98-2 None 1-5 Butane 106-97-8 None 10-25 Propane 74-98-6 None 10-25 HIGHER AROMATICS HIGHER AROMATICS HIGHER AROMATICS XYLENE, MIXTURE OF ISOMERS (class) (R No.) % Xylene, mixture of isomers 1330-20-7 Xn 20/21-38 5-10 Acetone 67-64-1 None 25-50 1-Methoxy-2-Propanol 107-98-2 None 1-5 Butane 106-97-8 None 10-25 Propane 74-98-6 None 10-25 * For all colours except those listed in Section 1 as containing lead chromate: R10 Flammable For colours listed in Section 1 as containing lead chromate: R10 Flammable R33 Danger of cumulative effects Carc. Cat. 3 R40 Possible risk of irreversible effects Repr. Cat. 1 R61 May cause harm to the unborn child Repr. Cat. 3 R62 Possible risk of impaired fertility 4. FIRST-AID MEASURES In all cases of doubt, or where symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. Inhalation: Remove to fresh air, keep patient warm and at rest. If breathing has stopped, administer artificial respiration. Give nothing by mouth. If unconscious, place in the recovery position and seek medical advice. Eye Contact: Contact lenses should be removed. Irrigate copiously with clean, fresh water for at least 10 minutes, holding the eyelids apart and seek medical advice. Skin Contact: Remove contaminated clothing. Wash skin thoroughly with soap and water, or use a proprietary skin cleanser. Do NOT use solvents or thinners. Ingestion: If accidentally swallowed obtain immediate medical attention. Keep at rest. Do NOT induce vomiting. 5. FIRE-FIGHTING MEASURES Extinguishing Media: Use alcohol resistant foam, carbon dioxide, dry powder or water spray/mist. Do NOT use water jet. Recommendations: Fire will produce dense black smoke containing hazardous products of combustion (see Section 10). Exposure to decomposition products may be a hazard to health. Appropriate self-contained breathing apparatus may be required. Cool closed containers exposed to fire with water spray. Do not allow run-off from fire-fighting to enter drains or water courses. 6. ACCIDENTAL RELEASE MEASURES Exclude sources of ignition and ventilate the area. Exclude non-essential personnel. Avoid breathing vapours. Refer to protective measures listed in sections 7 and 8. Contain and collect spillages with non-combustible absorbent materials e.g. sand, earth, vermiculite, diatomaceous earth and place in a suitable container for disposal in accordance with the waste regulations (see Section 13). Do not allow to enter drains or water courses. Clean preferably with a detergent; avoid the use of solvents. If the product enters drains or sewers, the local water company should be contacted immediately; in the case of contamination of streams, rivers or lakes, the National Rivers Authority. * 7. HANDLING AND STORAGE Handling For colours containing lead chromate (listed in Section 1), avoid the inhalation of dusts, particulates and spray mists rising from the use of these products. Cont..... 9804/8926 ISSUE 5 (REV.), MARCH 2002 Vapours are heavier than air and may spread along floors. They may form explosive mixtures with air. Prevent the creation of flammable or explosive concentrations of vapour in air and avoid concentrations higher than the occupational exposure limits. Additionally, the product should only be used in areas from which all naked lights and other sources of ignition have been excluded. Electrical equipment should be protected to the appropriate standard. Keep the container tightly closed. Exclude sources of heat, sparks and open flame. Non-sparking tools should be used. Required air quantity to 127 m3/ltr ventilate to 10% of the LEL The above figure is given as a guide only. Ventilation and extraction must be arranged so that all parts of the workplace are properly ventilated i.e. there are no recesses or pockets where high vapour concentrations are allowed to build up. If there is any doubt about the adequacy of the ventilation/extraction of solvent vapour, regular monitoring of confined workplaces should be carried out. Avoid skin and eye contact. Avoid inhalation of vapour and spray mist. Smoking, eating and drinking should be prohibited in areas of storage and use. For personal protection, see Section 8. Never use pressure to empty; the container is not a pressure vessel. The accumulation of contaminated rags and dry overspray, particularly in spray booth filters, may result in spontaneous combustion. Good housekeeping standards, regular safe removal of waste materials and regular maintenance of spray booth filters will minimise the risks of spontaneous combustion and other fire hazards. The Manual Handling Regulations may apply to the handling of containers/packages of this product. The following guide weight indicators are given to enable users to carry out assessments. 20 litre unit 22.0 - 28.0 kg 5 litre unit 5.5 - 6.5 kg 2.5 litre unit 2.8 - 3.5 kg 1 litre unit 1.1 - 1.4 kg Exposure Limits Occupational Exposure Standards and/or Maximum Exposure Limits have been established by the Health and Safety Commission or recommended by the supplier for certain of the ingredients. OELs are taken from the current versions of EH40 except those marked ‘Sup’, which are assigned by the supplier of the substance. Occupational exposure limits Substance 8 hr TWA (†) 15 min STEL(‡) Notes Lead compounds 0.15 mg/m3 (MEL) White spirit 100 ppm (OES) 125 ppm (OES) (†) Long term exposure limit - 8 hour time weighted average. (‡) Short term exposure limit - 15 minute reference period. (OES) Occupational exposure standard. (MEL) Maximum exposure limit. Further guidance on OES/MEL and the assessment of occupational exposure to harmful materials, including mixed exposures, is given in HSE Guidance Note EH40. Personal Protection All personal protective equipment, including respiratory protective equipment, used to control exposure to hazardous substances must be selected to meet the requirements of the COSHH Regulations. Respiratory Protection Air-fed respiratory protective equipment should be worn when this product is sprayed if the exposure of the sprayer or other people nearby cannot be controlled to below the Occupational Exposure limits and engineering controls and methods cannot reasonably be improved. When spraying colours containing lead chromate (listed in Section 1), air-fed respiratory protective equipment must be worn. This should be in addition to other measures taken to reduce exposure (e.g. in booth design and operation, and process modifications). Non- essential and unprotected people should be excluded from the area if exposure is possible. Dry sanding, flame cutting and/or welding of the dry paint film will give rise to dust and/or hazardous fumes. Wet sanding should be used wherever possible. If exposure cannot be avoided by the provision of local exhaust ventilation, suitable respiratory protective equipment should be used. Hand Protection When skin exposure may occur, advice should be sought from glove suppliers on appropriate types. Barrier creams may help to protect exposed areas of skin but are not substitutes for full physical protection. They should not be applied once exposure has occurred. Eye Protection Eye protection designed to protect against liquid splashes should be worn. Skin Protection Cotton or cotton/synthetic overalls or coveralls are normally suitable. Grossly contaminated clothing should be removed and the skin washed with soap and water or a proprietary skin cleaner. * 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Viscous liquid Odour: Characteristic odour Colour: Various Density: 1.1 g/cm3 Viscosity: 1.7 - 2.4 poise BS3900 : Part A7 at 25 °C Flash Point: 39 °C Cont..... 9804/8926 ISSUE 5 (REV.), MARCH 2002 Volatile Organic Content: 467 g/ltr Explosion limit - lower: 0.6% Water Solubility: Immiscible 10. STABILITY AND REACTIVITY Stable under the recommended storage and handling conditions (see Section 7). In a fire, hazardous decomposition products such as smoke, carbon monoxide, carbon dioxide and oxides of nitrogen may be produced. Keep away from oxidising agents and strongly alkaline and strongly acidic materials to prevent the possibility of exothermic reaction. Using information provided in this data sheet, advice should be obtained from the Environmental Agency whether the special waste regulations apply. * 14. TRANSPORT INFORMATION Transport within the user’s premises Always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of accident or spillage. The information contained in this data sheet does not constitute the user’s own assessment of workplace risks as required by other health and safety legislation. The provisions of the Health and Safety at Work etc. Act and the Control of Substances Hazardous to Health Regulations apply to the use of this product at work. * Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 * Note: Items marked with an asterisk (*) have been amended since last issue. 9804/8919 ISSUE 3 (REV.), APRIL 1997 Emergency Contact : Emergency Telephone No.: +44 (0) 1889 590312 Intended Use: Paint product for the decoration and protection of surfaces in the Commercial Vehicle, Plant and Building Industries. 2. COMPOSITION/INFORMATION ON INGREDIENTS Substances presenting a health hazard within the meaning of the Chemicals (Hazard Information and Packaging) Regulations 1993. Name Conc. range (%) Symbol Letter 4. FIRST-AID MEASURES In all cases of doubt, or where symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. Inhalation: Remove to fresh air, keep patient warm and at rest. If breathing has stopped, administer artificial respiration. Give nothing by mouth. If unconscious, place in the recovery position and seek medical advice. Eye Contact: Contact lenses should be removed. Irrigate copiously with clean, fresh water for at least 10 minutes, holding the eyelids apart and seek medical advice. Skin Contact: Remove contaminated clothing. Wash skin thoroughly with soap and water, or use a proprietary skin cleanser. Do NOT use solvents or thinners. Ingestion: If accidentally swallowed obtain immediate medical attention. Keep at rest. Do NOT induce vomiting. 5. FIRE-FIGHTING MEASURES Extinguishing Media: Use alcohol resistant foam, carbon dioxide, dry powder or water spray/mist. Do NOT use water jet. Recommendations: Fire will produce dense black smoke containing hazardous products of combustion (see Section 10). Exposure to decomposition products may be a hazard to health. Appropriate self-contained breathing apparatus may be required. Cool closed containers exposed to fire with water spray. Do not allow run-off from fire-fighting to enter drains or water courses. * 6. ACCIDENTAL RELEASE MEASURES Exclude sources of ignition and ventilate the area. Exclude non-essential personnel. Avoid breathing vapours. Refer to protective measures listed in sections 7 and 8. Contain and collect spillages with non-combustible absorbent materials e.g. sand, earth, vermiculite, diatomaceous earth and place in a suitable container for disposal in accordance with the waste regulations (see Section 13). Do not allow to enter drains or water courses. Clean preferably with a detergent; avoid the use of solvents. If the product enters drains or sewers, the local water company should be contacted immediately; in the case of contamination of streams, rivers or lakes, the relevant environment authority. * 7. HANDLING AND STORAGE Handling Vapours are heavier than air and may spread along floors. They may form explosive mixtures with air. Prevent the creation of flammable or explosive concentrations of vapour in air and avoid concentrations higher than the occupational exposure limits. Additionally, the product should only be used in areas from which all naked lights and other sources of ignition have been excluded. Electrical equipment should be protected to the appropriate standard. Keep the container tightly closed. Exclude sources of heat, sparks and open flame. Non-sparking tools should be used. Required air quantity to 224 m3/ltr ventilate to 10% of the LEL The above figure is given as a guide only. Ventilation and extraction must be arranged so that all parts of the workplace are properly ventilated i.e. there are no recesses or pockets where high vapour concentrations are allowed to build up. If there is any doubt about the adequacy of the ventilation/extraction of solvent vapour, regular monitoring of confined workplaces should be carried out. Avoid skin and eye contact. Avoid inhalation of vapour and spray mist. Smoking, eating and drinking should be prohibited in areas of storage and use. cont’d 9804/8958 ISSUE 3 (REV.), FEB 2002 For personal protection, see Section 8. Never use pressure to empty; the container is not a pressure vessel. The accumulation of contaminated rags and dry overspray, particularly in spray booth filters, may result in spontaneous combustion. Good housekeeping standards, regular safe removal of waste materials and regular maintenance of spray booth filters will minimise the risks of spontaneous combustion and other fire hazards. The Manual Handling Regulations may apply to the handling of containers/packages of this product. The following guide weight indicators are given to enable users to carry out assessments. Package Weight 25 litre drum 22.5 kg 5 litre can 4.5 kg Hand Protection When skin exposure may occur, advice should be sought from glove suppliers on appropriate types. Barrier creams may help to protect exposed areas of skin but are not substitutes for full physical protection. They should not be applied once exposure has occurred. Eye Protection Eye protection designed to protect against liquid splashes should be worn. Skin Protection Cotton or cotton/synthetic overalls or coveralls are normally suitable. Grossly contaminated clothing should be removed and the skin washed with soap and water or a proprietary skin cleanser. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Odour: Characteristic odour Colour: Clear, colourless Specific Gravity: 0.8 g/cm3 Flash Point: 39 °C Volatile Organic Content: 785 g/ltr Explosion limit - lower: 0.6% Water Solubility: Immiscible 10. STABILITY AND REACTIVITY Stable under the recommended storage and handling conditions (see Section 7). In a fire, hazardous decomposition products such as smoke, carbon monoxide, carbon dioxide and oxides of nitrogen may be produced. Keep away from oxidising agents and strongly alkaline and strongly acidic materials to prevent the possibility of exothermic reaction. 13. DISPOSAL CONSIDERATIONS Do not allow into drains or water courses or dispose of where ground or surface waters may be affected. Wastes, including emptied containers, are controlled wastes and should be disposed of in accordance with regulations made under the Control of Pollution Act and the Environmental Protection Act. Using information provided in this data sheet, advice should be obtained from the relevant environment agency whether the special waste regulations apply. * 14. TRANSPORT INFORMATION Transport within the user’s premises Always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of accident or spillage. * Eye Contact: Remove contact lenses and keep in a safe place. Irrigate copiously with clean water for at least 10 minutes holding eye lids apart and seek medical advice. Skin Contact: Remove contaminated clothing (including footwear). Wash skin thoroughly with soap and water or a proprietary skin cleanser. Do not use solvents or thinners. Ingestion: If accidentally swallowed obtain immediate medical attention. Keep at rest. Do not induce vomiting. 5. FIRE-FIGHTING MEASURES Extinguishing Media: Recommended: Alcohol resistant foam, CO2, dry powder or water spray/mist. Not to be used: Water jet. Recommendations: Fire will produce dense black smoke containing hazardous products of combustion (see Section 11). Decomposition products may be a hazard to health. Appropriate self-contained breathing apparatus may be required. Cool closed containers with water spray. Do not allow run-off from fire fighting to enter drains or water courses. 6. ACCIDENTAL RELEASE MEASURES Exclude sources of ignition and ventilate the area. Exclude non essential personnel. Avoid breathing vapours. Refer to protective measures listed in Sections 7 and 8. Contain and collect spillages with non combustible absorbent material i.e. sand, earth, vermiculite or diatomaceous earth. Place in a suitable container for disposal in accordance with Waste Regulations (see Section 13). Do not allow to enter drains or water courses. Clean, preferably with a detergent. Avoid the use of solvents. If the product enters drains or sewers, contact the local water company immediately. In the case of contamination of streams, lakes or canals, the National Rivers Authority. 7. HANDLING AND STORAGE Handling Vapours are heavier than air and may spread along floors. They may form explosive mixtures with air. Prevent the creation of flammable or explosive concentrations of vapour and avoid vapour concentrations higher than the occupational exposure limits. The product should only be used in areas from which all naked lights and other sources of ignition have been excluded. Electrical equipment should be protected to the appropriate standard. Keep container tightly closed. Exclude sources of heat, sparks and open flame. Non sparking tools should be used. Avoid skin and eye contact. Avoid the inhalation of vapour and spray mist. Smoking, eating and drinking should be prohibited in areas of storage and use. For personal protection see Section 8. Never use pressure to empty. The container is not a pressure vessel. Always keep in containers the same material as the supply container. Good housekeeping standards and regular safe removal of waste material will minimise the risks of spontaneous combustion and other fire hazards. The Manual Handling Operations Regulations will apply to the handling of containers of this product. Refer to the guide weight indicated on the container when carrying out assessments. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Measures Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust and good general ventilation. If these are insufficient to maintain concentrations of particulates and/or solvent vapours to below the relevant exposure limits, then suitable respiratory protection should be worn (see 8 ‘Personal Protection’). Exposure Limits Occupational exposure limits Substance 8 hr TWA (1) 15 min STEL (2) Notations (3) ppm (4) mgm/m3 (4) ppm (4) mgm/m3 (4) White spirit 100 575 125 720 Lead - 0.15 - NOTES: 1 Long term exposure limit - 8 hour time weighted average. 2 Short term exposure limit - 15 minute reference period. 3 ‘Sk’ indicates risks of absorption through the skin. ‘Sen’ indicates a respiratory sensitiser. 4 ‘OES’ indicates an occupational exposure standard. ‘MEL’ indicates a maximum exposure limit. OELs are taken from the current version of EH40 except those marked ‘SUP’ which are assigned by the supplier of the substance. G.V indicates Guidance Value (see EH40/95) Personal Protection All ppe, including rpe, used to control exposure to hazardous substances must be selected to meet the requirements of the COSHH Regulations. Respiratory Protection [Applicable to sprayed coatings containing solvents but not isocyanates.] Air fed respiratory protection should be worn when this product is sprayed if the exposure of the sprayer or other people nearby cannot be controlled to below the OES and Engineering Controls and other methods cannot be reasonably improved. Hand Protection Where skin exposure may occur, advice should be sought from glove suppliers on appropriate types. Barrier creams may help to protect exposed areas of skin but are not substitutes for full physical protection. They should not be applied once exposure has commenced. Eye Protection Eye protection designed to protect against liquid splashes should be worn. Skin Protection Cotton or cotton/synthetic overalls are normally suitable. Disposables offer protection during short periods of high exposure i.e. spraying. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Flash Point (closed cup): 38°C Viscosity: Mobile liquid Specific Gravity: 1.2 kg/litre Vapour Density: Heavier than air Lower Explosion Limit: 0.8% Solubility in Water: Immiscible 9804/8920 ISSUE 5 (REV.), JUNE 2002 10. STABILITY AND REACTIVITY Stable under the recommended storage and handling conditions (see Section 7). In a fire, hazardous decomposition products such as smoke, carbon monoxide, carbon dioxide, nitrogen oxides may be produced. Keep away from oxidising agents and strongly alkaline or acidic materials to prevent the possibility of exothermic reactions occurring. M.F.A.G. : 3-10 C.D.G. (CPL) : Exempt from Classification as flammable under C.D.G. (CPL) Regulations by virtue of Part III of Schedule I (high viscosity). 15. REGULATORY INFORMATION This product is classified and labelled for supplying in accordance with the Chemicals (Hazard Information and Packaging) Regulations as follows:- R10 Flammable S23 Do not breathe gas/fumes/vapour/spray. S28 After contact with skin, wash immediately with plenty of soap and water. P90 Contains lead. Should not be used on surfaces that are liable to be chewed or sucked by children. The information contained in this data sheet does not constitute the user’s own assessment of workplace risks as required by other Health and Safety Legislation. The provisions of the Health and Safety at Work etc. Act and the Control of Substances Hazardous to Health Regulations apply to the use of this product at work. 4. FIRST-AID MEASURES In all cases of doubt, or where symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. Inhalation: Remove to fresh air, keep patient warm and at rest. If breathing has stopped, administer artificial respiration. Give nothing by mouth. If unconscious, place in the recovery position and seek medical advice. Eye Contact: Contact lenses should be removed. Irrigate copiously with clean, fresh water for at least 10 minutes, holding the eyelids apart and seek medical advice. Skin Contact: Remove contaminated clothing. Wash skin thoroughly with soap and water, or use a proprietary skin cleanser. Do NOT use solvents or thinners. Ingestion: If accidentally swallowed obtain immediate medical attention. Keep at rest. Do NOT induce vomiting. 5. FIRE-FIGHTING MEASURES Extinguishing Media: Use alcohol resistant foam, carbon dioxide, dry powder or water spray/mist. Do NOT use water jet. Recommendations: Fire will produce dense black smoke containing hazardous products or combustion (see Section 10). Exposure to decomposition products may be a hazard to health. Appropriate self-contained breathing apparatus may be required. Cool closed containers exposed to fire with water spray. Do not allow run-off from fire-fighting to enter drains or water courses. 6. ACCIDENTAL RELEASE MEASURES Exclude sources of ignition and ventilate the area. Exclude non-essential personnel. Avoid breathing vapours. Refer to protective measures listed in sections 7 and 8. Contain and collect spillages with non-combustible absorbent materials e.g. sand, earth, vermiculite, diatomaceous earth and place in a suitable container for disposal in accordance with the waste regulations (see Section 13). Do not allow to enter drains or water courses. Clean preferably with a detergent; avoid the use of solvents. If the product enters drains or sewers, the local water company should be contacted immediately; in the case of contamination of streams, rivers or lakes, the National Rivers Authority. 7. HANDLING AND STORAGE Handling Avoid the inhalation of dust, particulates and spray mist arising from the use of this lead chromate containing product. For colours containing lead chromate (listed in Section 1), avoid the inhalation of dusts, particulates and spray mist rising from the use of these products. Vapours are heavier than air and may spread along floors. They may form explosive mixtures with air. Prevent the creation of flammable or explosive concentrations of vapour in air and avoid concentrations higher than the occupational exposure limits. Additionally, the product should only be used in areas from which all naked lights and other sources of ignition have been excluded. Electrical equipment should be protected to the appropriate standard. Keep the container tightly closed. Exclude sources of heat, sparks and open flame. Non-sparking tools should be used. Required air quantity to 129 m3/ltr ventilate to 10% of the LEL The above figure is given as a guide only. Ventilation and extraction must be arranged so that all parts of the workplace are properly ventilated i.e. there are no recesses or pockets where high vapour concentrations are allowed to build up. cont’d 9804/8957 ISSUE 4 (REV.), JUNE 2002 If there is any doubt about the adequacy of the ventilation/extraction of solvent vapour, regular monitoring of confined workplaces should be carried out. Avoid skin and eye contact. Avoid inhalation of vapour and spray mist. Smoking, eating and drinking should be prohibited in areas of storage and use. For personal protection, see Section 8. Never use pressure to empty; the container is not a pressure vessel. Good housekeeping standards and regular safe removal of waste material will minimise the risks of spontaneous combustion and other fire hazards. The Manual Handling Operations Regulations may apply to the handling of containers/packages of this product. The following guide weight indicators are given to enable users to carry out assessments. This information is also shown on the container label. 5 litre unit 6.0 kg 2.5 litre unit 3.0 kg 1 litre unit 1.2 kg Personal Protection All personal protective equipment, including respiratory protective equipment, used to control exposure to hazardous substances must be selected to meet the requirements of the COSHH Regulations. Respiratory Protection Air-fed respiratory protective equipment should be worn when this product is sprayed. This should be in addition to other measures taken to reduce exposure (e.g. in booth design and operation and process modifications). Non-essential and unprotected people should be excluded from the area if exposure is possible. When operators, whether spraying or not, have to work inside the spray booth, they should wear an air-fed respirator during the spraying process and until such time as the spray mist has cleared. However, persons entering the spray booths or enclosures for short periods (less than 15 minutes) when spraying is taking place may be protected from inhaling the spray mist by wearing suitable respirators with charcoal canisters. Care should be taken to ensure that filters are changed in accordance with the supplier’s instructions. The use of a canister respirator is considered very much a second choice to air-fed respiratory protective equipment. Dry sanding, flame cutting and/or welding of the dry paint film will give rise to dust and/or hazardous fumes. Wet sanding should be used wherever possible. If exposure cannot be avoided by the provision of local exhaust ventilation, suitable respiratory protective equipment should be used. Hand Protection When skin exposure may occur, advice should be sought from glove suppliers on appropriate types. Barrier creams may help to protect exposed areas of skin but are not substitutes for full physical protection. They should not be applied once exposure has occurred. Eye Protection Eye protection designed to protect against liquid splashes should be worn. Skin Protection Cotton or cotton/synthetic overalls or coveralls are normally suitable. Grossly contaminated clothing should be removed and the skin washed with soap and water or a proprietary skin cleaner. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Viscous liquid Odour: Characteristic odour Colour: Yellow Specific Gravity: 1.1 g/cm3 Viscosity: 2.0 - 3.0 poise BS3900 : Part A7 at 25 °C Flash Point: 39 °C Volatile Organic Content: 449 g/ltr Explosion limit - lower: 0.6% Water Solubility: Immiscible 10. STABILITY AND REACTIVITY Stable under the recommended storage and handling conditions (see Section 7). In a fire, hazardous decomposition products such as smoke, carbon monoxide, carbon dioxide and oxides of nitrogen may be produced. Keep away from oxidising agents and strongly alkaline and strongly acidic materials to prevent the possibility of exothermic reaction. 9804/8957 ISSUE 4 (REV.), JUNE 2002 For International Road/Rail Chemical Name : Paint Item Number : 31 °C Trem Card : 30G35 For Sea Transport Marine Pollutant : Yes EmS : 3 - 05 MFAG : 310 This information does not apply to carriage by air. Please contact JCB Supply Department if transport by air is required. 15. REGULATORY INFORMATION This product has been classified and labelled for supply in accordance with the CHIP 2 regulations as follows:- Full details of the hazard classifications are as follows:- Repr. Cat. 1 Toxic for reproduction - Category 1 Repr. Cat. 3 Toxic for reproduction - Category 3 Carc. Cat. 3 Carcinogenic - Category 3 Further information about hazard classifications can be found in the Approved Guide to the Classification and Labelling of Substances and Preparations Dangerous for Supply. The information in this data sheet is provided in accordance with the requirements of the Chemicals (Hazard Information and Packaging for Supply) Regulations 1994. The product should not be used for purposes other than those shown in Section 1 without first referring to the supplier and obtaining written handling instructions. As the specific conditions of use are outside the supplier’s control, the user is responsible for ensuring that the requirements of relevant legislation are complied with. The information contained in this data sheet is based on the present state of knowledge and current national legislation. It provides guidance on health, safety and environmental aspects of the product and should not be construed as any guarantee of technical performance or suitability for particular applications. Further information and relevant advice can be found in:- The Chemicals (Hazard Information and Packaging for Supply) Regulations 1994 (SI 1994 : 3247) Control of Lead at Work Regulations 1980 (SI 1980 : 1248) Control of Substances Hazardous to Health Regulations 1988 (SI 1988 : 1657) Manual Handling Operations Regulations 1992 (SI 1992: 2793) Environmental Protection (Duty of Care) Regulations 1992 (SI 1992 : 2839) Occupational Exposure Limits, EH40 The storage of flammable liquids in containers, HS(G)51 Storage of Packaged Dangerous Substances, HS(G)71 The Approved Guide to the Classification and Labelling of Substances and Preparations Dangerous for Supply (Second Edition), L63 The Approved Supply List, L61 The Approved Code of Practice: Safety Data Sheets for Substances and reparations Dangerous for Supply, L62 Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 * Note: Items marked with an asterisk (*) have been amended since last issue. Full Gloss Yellow/11/09/96 9804/8916 ISSUE 5 (REV.), JUNE 2002 Emergency Contact : Emergency Telephone No.: +44 (0) 1889 590312 Description: An anticorrosive primer for spray application to blast cleaned surfaces. Based on an alkyd resin system with zinc phosphate and other organic pigments and containing white spirit solvent. 2. COMPOSITION/INFORMATION ON INGREDIENTS The following ingredients have recognised health effects or exposure limits, and are present in concentrations above the limits laid down in the Chemicals (Hazard Information and Packaging for Supply) Regulations 1994 (CHIP 2). Weight Risk CAS Substance in paint 4. FIRST-AID MEASURES In all cases of doubt, or where symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. Inhalation: Remove to fresh air, keep patient warm and at rest. If breathing has stopped, administer artificial respiration. Give nothing by mouth. If unconscious, place in the recovery position and seek medical advice. Eye Contact: Contact lenses should be removed. Irrigate copiously with clean, fresh water for at least 10 minutes, holding the eyelids apart and seek medical advice. Skin Contact: Remove contaminated clothing. Wash skin thoroughly with soap and water, or use a proprietary skin cleanser. Do NOT use solvents or thinners. Ingestion: If accidentally swallowed obtain immediate medical attention. Keep at rest. Do NOT induce vomiting. 5. FIRE-FIGHTING MEASURES Extinguishing Media: Use alcohol resistant foam, carbon dioxide, dry powder or water spray/mist. Do NOT use water jet. Recommendations: Fire will produce dense black smoke containing hazardous products of combustion (see Section 10). Exposure to decomposition products may be a hazard to health. Appropriate self-contained breathing apparatus may be required. Cool closed containers exposed to fire with water spray. Do not allow run-off from fire-fighting to enter drains or water courses. 6. ACCIDENTAL RELEASE MEASURES Exclude sources of ignition and ventilate the area. Exclude non-essential personnel. Avoid breathing vapours. Refer to protective measures listed in sections 7 and 8. Contain and collect spillages with non-combustible absorbent materials e.g. sand, earth, vermiculite, diatomaceous earth and place in a suitable container for disposal in accordance with the waste regulations (see Section 13). Do not allow to enter drains or water courses. Clean preferably with a detergent; avoid the use of solvents. If the product enters drains or sewers, the local water company should be contacted immediately; in the case of contamination of streams, rivers or lakes, the relevant environment agency. 7. HANDLING AND STORAGE Handling Vapours are heavier than air and may spread along floors. They may form explosive mixtures with air. Prevent the creation of flammable or explosive concentrations of vapour in air and avoid concentrations higher than the occupational exposure limits. Additionally, the product should only be used in areas from which all naked lights and other sources of ignition have been excluded. Electrical equipment should be protected to the appropriate standard. Keep the container tightly closed. Exclude sources of heat, sparks and open flame. Non-sparking tools should be used. Required air quantity to ventilate to 10% of the LEL 126 m3/ltr The above figure is given as a guide only. Ventilation and extraction must be arranged so that all parts of the workplace are properly ventilated i.e. there are no recesses or pockets where high vapour concentrations are allowed to build up. If there is any doubt about the adequacy of the ventilation/extraction of solvent vapour, regular monitoring of confined workplaces should be carried out. Avoid skin and eye contact. Avoid inhalation of vapour and spray mist. Smoking, eating and drinking should be prohibited in areas of storage and use. cont’d 9804/8916 ISSUE 5 (REV.), JUNE 2002 For personal protection, see Section 8. Never use pressure to empty; the container is not a pressure vessel. The accumulation of contaminated rags and dry overspray, particularly in spray booth filters may result in spontaneous combustion. Good housekeeping standards, regular safe removal of waste materials and regular maintenance at spray booth filters will minimise the risks of spontaneous combustion and other fire hazards. The Manual Handling Regulations may apply to the handling of containers/packages of this product. The following guide weight indicators are given to enable users to carry out assessments. Package Weight 5 litre can 7.0 kg Respiratory Protection Air-fed respiratory protective equipment should be worn when this product is sprayed if the exposure of the sprayer or other people nearby cannot be controlled to below the Occupational Exposure Limits and engineering controls and methods cannot reasonably be improved. Dry sanding, flame cutting and/or welding of the dry paint film will give rise to dust and/or hazardous fumes. Wet sanding should be used wherever possible. If exposure cannot be avoided by the provision of local exhaust ventilation, suitable respiratory protective equipment should be used. Hand Protection When skin exposure may occur, advice should be sought from glove suppliers on appropriate types. Barrier creams may help to protect exposed areas of skin but are not substitutes for full physical protection. They should not be applied once exposure has occurred. Eye Protection Eye protection designed to protect against liquid splashes should be worn. Skin Protection Cotton or cotton/synthetic overalls or coveralls are normally suitable. Grossly contaminated clothing should be removed and the skin washed with soap and water or a proprietary skin cleanser. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Viscous Liquid Odour: Characteristic odour Colour: Grey Specific Gravity: 1.3 g/cm3 Viscosity: 1.0 - 1.3 poise BS3900: Part A7 at 25°C Flash Point: 46 °C Volatile Organic Content: 434 g/ltr Explosion limit - lower: 0.6% Water Solubility: Immiscible 10. STABILITY AND REACTIVITY Stable under the recommended storage and handling conditions (see Section 7). In a fire, hazardous decomposition products such as smoke, carbon monoxide, carbon dioxide and oxides of nitrogen may be produced. Keep away from oxidising agents and strongly alkaline and strongly acidic materials to prevent the possibility of exothermic reaction. Eye Contact: Contact lenses should be removed. Irrigate copiously with clean, fresh water for at least 10 minutes, holding the eyelids apart and seek medical advice. Skin Contact: Remove contaminated clothing. Wash skin thoroughly with soap and water, or use a proprietary skin cleanser. Do NOT use solvents or thinners. Ingestion: If accidentally swallowed obtain immediate medical attention. Keep at rest. Do NOT induce vomiting. 5. FIRE-FIGHTING MEASURES Extinguishing Media: Use alcohol resistant foam, carbon dioxide, dry powder or water spray/mist. Do NOT use water jet. Recommendations: Fire will produce dense black smoke containing hazardous products or combustion (see Section 10). Exposure to decomposition products may be a hazard to health. Appropriate self-contained breathing apparatus may be required. Cool closed containers exposed to fire with water spray. Do not allow run-off from fire-fighting to enter drains or water courses. 6. ACCIDENTAL RELEASE MEASURES Exclude sources of ignition and ventilate the area. Exclude non-essential personnel. Avoid breathing vapours. Refer to protective measures listed in sections 7 and 8. Contain and collect spillages with non-combustible absorbent materials e.g. sand, earth, vermiculite, diatomaceous earth and place in a suitable container for disposal in accordance with the waste regulations (see Section 13). Do not allow to enter drains or water courses. Clean preferably with a detergent; avoid the use of solvents. If the product enters drains or sewers, the local water company should be contacted immediately; in the case of contamination of streams, rivers or lakes, the National Rivers Authority. 7. HANDLING AND STORAGE Handling Vapours are heavier than air and may spread along floors. They may form explosive mixtures with air. Prevent the creation of flammable or explosive concentrations of vapour in air and avoid concentrations higher than the occupational exposure limits. Additionally, the product should only be used in areas from which all naked lights and other sources of ignition have been excluded. Electrical equipment should be protected to the appropriate standard. Keep the container tightly closed. Exclude sources of heat, sparks and open flame. Non-sparking tools should be used. Required air quantity to 131 m3/ltr ventilate to 10% of the LEL The above figure is given as a guide only. Ventilation and extraction must be arranged so that all parts of the workplace are properly ventilated i.e. there are no recesses or pockets where high vapour concentrations are allowed to build up. If there is any doubt about the adequacy of the ventilation/extraction of solvent vapour, regular monitoring of confined workplaces should be carried out. Avoid skin and eye contact. Avoid inhalation of vapour and spray mist. Smoking, eating and drinking should be prohibited in areas of storage and use. For personal protection, see Section 8. Never use pressure to empty; the container is not a pressure vessel. Good housekeeping standards and regular safe removal of waste material will minimise the risks of spontaneous combustion and other fire hazards. cont’d 9804/8923 ISSUE 5 (REV.), JUNE 2002 The Manual Handling Operations Regulations may apply to the handling of containers/packages of this product. The following guide weight indicators are given to enable users to carry out assessments. This information is also shown on the container label. 5 litre unit 5.5 kg 2.5 litre unit 2.8 kg 1 litre unit 1.1 kg Barrier creams may help to protect exposed areas of skin but are not substitutes for full physical protection. They should not be applied once exposure has occurred. Eye Protection Eye protection designed to protect against liquid splashes should be worn. Skin Protection Cotton or cotton/synthetic overalls or coveralls are normally suitable. Grossly contaminated clothing should be removed and the skin washed with soap and water or a proprietary skin cleaner. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Viscous liquid Odour: Characteristic odour Colour: Grey Specific Gravity: 1.0 g/cm3 Viscosity: 1.7 - 2.4 poise BS3900 : Part A7 at 25 °C Flash Point: 39 °C Volatile Organic Content: 458 g/ltr Explosion limit - lower: 0.6% Water Solubility: Immiscible 10. STABILITY AND REACTIVITY Stable under the recommended storage and handling conditions (see Section 7). In a fire, hazardous decomposition products such as smoke, carbon monoxide, carbon dioxide and oxides of nitrogen may be produced. Keep away from oxidising agents and strongly alkaline and strongly acidic materials to prevent the possibility of exothermic reaction. 13. DISPOSAL CONSIDERATIONS Do not allow into drains or water courses or dispose of where ground or surface waters may be affected. Wastes, including emptied containers, are controlled wastes and should be disposed of in accordance with regulations made under the Control of Pollution Act and the Environmental Protection Act. Using information provided in this data sheet, should be obtained from the Waste Regulation Authority whether the special waste regulations apply. 14. TRANSPORT INFORMATION Transport within the user’s premises Always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of accident or spillage. Transport Details Class : 3 Proper Shipping Name : Paint Sub Hazard : - The information contained in this data sheet does not constitute the user’s own assessment of workplace risks as required by other health and safety legislation. The provisions of the Health and Safety at Work etc. Act and the Control of Substances Hazardous to Health Regulations apply to the use of this product at work. 4. FIRST-AID MEASURES In all cases of doubt, or where symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. Inhalation: Remove to fresh air, keep patient warm and at rest. If breathing has stopped, administer artificial respiration. Give nothing by mouth. If unconscious, place in the recovery position and seek medical advice. Eye Contact: Contact lenses should be removed. Irrigate copiously with clean, fresh water for at least 10 minutes, holding the eyelids apart and seek medical advice. Skin Contact: Remove contaminated clothing. Wash skin thoroughly with soap and water, or use a proprietary skin cleanser. Do NOT use solvents or thinners. Ingestion: If accidentally swallowed obtain immediate medical attention. Keep at rest. Do NOT induce vomiting. 5. FIRE-FIGHTING MEASURES Extinguishing Media: Use alcohol resistant foam, carbon dioxide, dry powder or water spray/mist. Do NOT use water jet. Recommendations: Fire will produce dense black smoke containing hazardous products of combustion (see Section 10). Exposure to decomposition products may be a hazard to health. Appropriate self-contained breathing apparatus may be required. Cool closed containers exposed to fire with water spray. Do not allow run-off from fire-fighting to enter drains or water courses. 6. ACCIDENTAL RELEASE MEASURES Exclude sources of ignition and ventilate the area. Exclude non-essential personnel. Avoid breathing vapours. Refer to protective measures listed in sections 7 and 8. Contain and collect spillages with non-combustible absorbent materials e.g. sand, earth, vermiculite, diatomaceous earth and place in a suitable container for disposal in accordance with the waste regulations (see Section 13). Do not allow to enter drains or water courses. Clean preferably with a detergent; avoid the use of solvents. If the product enters drains or sewers, the local water company should be contacted immediately; in the case of contamination of streams, rivers or lakes, the National Rivers Authority. 7. HANDLING AND STORAGE Handling Avoid the inhalation of dust, particulates and spray mist arising from the use of this lead chromate containing product. For colours containing lead chromate (listed in Section 1), avoid the inhalation of dusts, particulates and spray mist arising from the use of these products. Vapours are heavier than air and may spread along floors. They may form explosive mixtures with air. Prevent the creation of flammable or explosive concentrations of vapour in air and avoid concentrations higher than the occupational exposure limits. Additionally, the product should only be used in areas from which all naked lights and other sources of ignition have been excluded. Electrical equipment should be protected to the appropriate standard. Keep the container tightly closed. Exclude sources of heat, sparks and open flame. Non-sparking tools should be used. Required air quantity to ventilate to 10% of the LEL 128 m3/ltr The above figure is given as a guide only. Ventilation and extraction must be arranged so that all parts of the workplace are properly ventilated i.e. there are no recesses or pockets where high vapour concentrations are allowed to build up. If there is any doubt about the adequacy of the ventilation/extraction of solvent vapour, regular monitoring of confined workplaces should be carried out. cont’d 9804/8922 ISSUE 5 (REV.), JUNE 2002 Avoid skin and eye contact. Avoid inhalation of vapour and spray mist. Smoking, eating and drinking should be prohibited in areas of storage and use. For personal protection, see Section 8. Never use pressure to empty; the container is not a pressure vessel. Good housekeeping standards and regular safe removal of waste material will minimise the risks of spontaneous combustion and other fire hazards. The Manual Handling Operations Regulations may apply to the handling of containers/packages of this product. The following guide weight indicators are given to enable users to carry out assessments. This information is also shown on the container label. 20 litre unit 24.0 kg 5 litre unit 6.0 kg 2.5 litre unit 3.0 kg 1 litre unit 1.2 kg Personal Protection All personal protective equipment, including respiratory protective equipment, used to control exposure to hazardous substances must be selected to meet the requirements of the COSHH Regulations. Respiratory Protection Air-fed respiratory protective equipment should be worn when this product is sprayed. This should be in addition to other measures taken to reduce exposure (e.g. in booth design and operation and process modifications). Non-essential and unprotected people should be excluded from the area if exposure is possible. When operators, whether spraying or not, have to work inside the spray booth, they should wear an air-fed respirator during the spraying process and until such time as the spray mist has cleared. However, persons entering the spray booths or enclosures for short periods (less than 15 minutes) when spraying is taking place may be protected from inhaling the spray mist by wearing suitable respirators with charcoal canisters. Care should be taken to ensure that filters are changed in accordance with the supplier’s instructions. The use of a canister respirator is considered very much a second choice to air-fed respiratory protective equipment. Dry sanding, flame cutting and/or welding of the dry paint film will give rise to dust and/or hazardous fumes. Wet sanding should be used wherever possible. If exposure cannot be avoided by the provision of local exhaust ventilation, suitable respiratory protective equipment should be used. Hand Protection When skin exposure may occur, advice should be sought from glove suppliers on appropriate types. Barrier creams may help to protect exposed areas of skin but are not substitutes for full physical protection. They should not be applied once exposure has occurred. Eye Protection Eye protection designed to protect against liquid splashes should be worn. Skin Protection Cotton or cotton/synthetic overalls or coveralls are normally suitable. Grossly contaminated clothing should be removed and the skin washed with soap and water or a proprietary skin cleaner. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Viscous Liquid Odour: Characteristic odour Colour: Various Specific Gravity: 1.1 g/cm3 Viscosity: 1.7 - 2.4 poise BS3900: Part A7 at 25°C Flash Point: 39 °C Volatile Organic Content: 447 g/ltr Explosion limit - lower: 0.6% Water Solubility: Immiscible 10. STABILITY AND REACTIVITY Stable under the recommended storage and handling conditions (see Section 7). In a fire, hazardous decomposition products such as smoke, carbon monoxide, carbon dioxide and oxides of nitrogen may be produced. Keep away from oxidising agents and strongly alkaline and strongly acidic materials to prevent the possibility of exothermic reaction. Exposure to organic solvent vapours may result in adverse health effects such as irritation of the mucous membrane and the respiratory system and adverse effects on the renal and central nervous systems. Symptoms include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases loss of consciousness. Repeated or prolonged contact with the product may lead to removal of natural fats from the skin resulting in non-allergic contact dermatitis and absorption through the skin. Splashes in the eyes may cause irritation and reversible local damage. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea. Other effects may be as described for exposure to vapours. Increased incidences of lung cancer have been identified in the chromate manufacturing industry. Epidemiological studies have shown that where lead chromates alone were manufactured there were no cancer excesses. Animal studies have shown that some insoluble chromates are carcinogenic but the data does not extend to lead chromate pigments. There is no evidence of a risk of lung cancer arising from the use of lead chromate containing Epidemiological data shows an association between elevated maternal blood lead levels and developmental effects in the offspring. Following the introduction of the criteria for Toxic to Reproduction hazard classification the EC has classified all lead compounds as causing developmental toxicity in humans. Lead chromate, although of a relatively low solubility and bioavailability, is included in this classification. For Sea Transport Marine Pollutant : Yes EmS : 3 - 05 MFAG : 310 This information does not apply to carriage by air. Please contact JCB Supply Department if transport by air is required. 15. REGULATORY INFORMATION This product has been classified and labelled for supply in accordance with the CHIP 2 regulations as follows:- Further information about hazard classifications can be found in the Approved Guide to the Classification and Labelling of Substances and Preparations Dangerous for Supply. The information in this data sheet is provided in accordance with the requirements of the Chemicals (Hazard Information and Packaging for Supply) Regulations 1994. The product should not be used for purposes other than those shown in Section 1 without first referring to the supplier and obtaining written handling instructions. As the specific conditions of use are outside the supplier’s control, the user is responsible for ensuring that the requirements of relevant legislation are complied with. The information contained in this data sheet is based on the present state of knowledge and current national legislation. It provides guidance on health, safety and environmental aspects of the product and should not be construed as any guarantee of technical performance or suitability for particular applications. Further information and relevant advice can be found in:- The Chemicals (Hazard Information and Packaging for Supply) Regulations 1994 (SI 1994 : 3247) Control of Lead at Work Regulations 1980 (SI 1980 : 1248) Control of Substances Hazardous to Health Regulations 1988 (SI 1988 : 1657) Manual Handling Operations Regulations 1992 (SI 1992: 2793) Environmental Protection (Duty of Care) Regulations 1992 (SI 1992 : 2839) Occupational Exposure Limits, EH40 The storage of flammable liquids in containers, HS(G)51 Storage of Packaged Dangerous Substances, HS(G)71 Approved Guide to the Classification and Labelling of Substances and Preparations Dangerous for Supply (Second Edition), L63 The Approved Supply List, L61 The Approved Code of Practice: Safety Data Sheets for Substances and Preparations Dangerous for Supply, L62 Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 * Note: Items marked with an asterisk (*) have been amended since last issue. 11.09.96/Rev.3 9804/8929 ISSUE 4 (REV.), JUNE 2002 Emergency Contact : Emergency Telephone No.: +44 (0) 1889 590312 Intended Use: Paint product for the decoration and protection of surfaces in the Commercial Vehicle, Plant and Building Industries. 2. COMPOSITION/INFORMATION ON INGREDIENTS Substances presenting a health hazard within the meaning of the Chemicals (Hazard Information and Packaging) Regulations 1993. Name Conc. range (%) Symbol Letter Eye Contact: Remove contact lenses and keep in a safe place. Irrigate copiously with clean water for at least 10 minutes holding eye lids apart and seek medical advice. Skin Contact: Remove contaminated clothing (including footwear). Wash skin thoroughly with soap and water or a proprietary skin cleanser. Do not use solvents or thinners. Ingestion: If accidentally swallowed obtain immediate medical attention. Keep at rest. Do not induce vomiting. 5. FIRE-FIGHTING MEASURES Extinguishing Media: Recommended: Alcohol resistant foam, CO2, dry powder or water spray/mist. Not to be used: Water jet. Recommendations: Fire will produce dense black smoke containing hazardous products of combustion (see Section 11). Decomposition products may be a hazard to health. Appropriate self-contained breathing apparatus may be required. Cool closed containers with water spray. Do not allow run-off from fire fighting to enter drains or water courses. 6. ACCIDENTAL RELEASE MEASURES Exclude sources of ignition and ventilate the area. Exclude non essential personnel. Avoid breathing vapours. Refer to protective measures listed in Sections 7 and 8. Contain and collect spillages with non combustible absorbent material i.e. sand, earth, vermiculite or diatomaceous earth. Place in a suitable container for disposal in accordance with Waste Regulations (see Section 13). Do not allow to enter drains or water courses. Clean, preferably with a detergent. Avoid the use of solvents. If the product enters drains or sewers, contact the local water company immediately. In the case of contamination of streams, lakes or canals, the National Rivers Authority. 7. HANDLING AND STORAGE Handling Vapours are heavier than air and may spread along floors. They may form explosive mixtures with air. Prevent the creation of flammable or explosive concentrations of vapour and avoid vapour concentrations higher than the occupational exposure limits. The product should only be used in areas from which all naked lights and other sources of ignition have been excluded. Electrical equipment should be protected to the appropriate standard. Keep container tightly closed. Exclude sources of heat, sparks and open flame. Non sparking tools should be used. Avoid skin and eye contact. Avoid the inhalation of vapour and spray mist. Smoking, eating and drinking should be prohibited in areas of storage and use. For personal protection see Section 8. Never use pressure to empty. The container is not a pressure vessel. Always keep in containers the same material as the supply container. Good housekeeping standards and regular safe removal of waste material will minimise the risks of spontaneous combustion and other fire hazards. The Manual Handling Operations Regulations will apply to the handling of containers of this product. Refer to the guide weight indicated on the container when carrying out assessments. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Measures Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust and good general ventilation. If these are insufficient to maintain concentrations of particulates and/or solvent vapours to below the relevant exposure limits, then suitable respiratory protection should be worn (see 8 ‘Personal Protection’). Dry sanding, flame cutting and/or through welding of dried paint films will give rise to dust and/or hazardous fumes. Wet sanding or extract sanders should be used wherever possible. If exposure cannot be controlled by local exhaust ventilation, then suitable respiratory protection should be worn. Exposure Limits Occupational exposure limits Substance 8 hr TWA (1) 10 min STEL (2) Notations (3) ppm (4) mgm/m3 (4) ppm (4) mgm/m3 (4) Aromatic Hydrocarbon 50 - SUP NOTES: 1 Long term exposure limit - 8 hour time weighted average. 2 Short term exposure limit - 10 minute reference period. 3 ‘Sk’ indicates risks of absorption through the skin. ‘Sen’ indicates a respiratory sensitiser. 4 ‘OES’ indicates an occupational exposure standard. ‘MEL’ indicates a maximum exposure limit. OELs are taken from the current version of EH40 except those marked ‘SUP’ which are assigned by the supplier of the substance. Personal Protection All ppe, including rpe, used to control exposure to hazardous substances must be selected to meet the requirements of the COSHH Regulations. Respiratory Protection Air-fed respiratory protective equipment should be worn when this product is sprayed if the exposure of the sprayer or other people nearby cannot be controlled to below the OES and engineering controls and methods cannot reasonably be improved. Hand Protection Where skin exposure may occur, advice should be sought from glove suppliers on appropriate types. Barrier creams may help to protect exposed areas of skin but are not substitutes for full physical protection. They should not be applied once exposure has commenced. Eye Protection Eye protection designed to protect against liquid splashes should be worn. Skin Protection Cotton or cotton/synthetic overalls are normally suitable. Disposables offer protection during short periods of high exposure i.e. spraying. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Flash Point (closed cup): Above 32°C Viscosity: Viscous liquid Specific Gravity: >0.8 <1.5 kg/litre Vapour Density: Heavier than air Lower Explosion Limit: 0.8% Solubility in Water: Immiscible 9804/8929 ISSUE 4 (REV.), JUNE 2002 10. STABILITY AND REACTIVITY Stable under the recommended storage and handling conditions (see Section 7). In a fire, hazardous decomposition products such as smoke, carbon monoxide, carbon dioxide, nitrogen oxides may be produced. Keep away from oxidising agents and strongly alkaline or acidic materials to prevent the possibility of exothermic reactions occurring. The information contained in this data sheet does not constitute the user’s own assessment of workplace risks as required by other Health and Safety Legislation. The provisions of the Health and Safety at Work etc. and the Control of Substances Hazardous to Health Regulations apply to the use of this product at work. Not applicable Substance identification number : Not applicable Other regulations : Government inventory status : All components registered in accordance with EINECS and TSCA. COSHH regulations : Product reviewed under COSHH. For further information JCB SERVICE - PARTS DIVISION contact : ROCESTER STAFFORDSHIRE ST14 5LS TELEPHONE 01889 590312 9804/8929 ISSUE 1, SEPTEMBER 1989 Page 2 of 2 9804/8964 ISSUE 3 (REV.), JUNE 2002 Emergency Contact : Emergency Telephone No.: +44 (0) 1889 590312 Description: A solvent cleanser/thinner based on aromatic hydrocarbon and 1-methoxypropan-2-ol. 2. COMPOSITION/INFORMATION ON INGREDIENTS The following ingredients have recognised health effects and are present in concentrations above the limits laid down in the Chemicals (Hazard Information and Packaging for Supply) Regulations 1994 (CHIP 2). Weight Risk CAS Substance in paint 4. FIRST-AID MEASURES In all cases of doubt, or where symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. Inhalation: Remove to fresh air, keep patient warm and at rest. If breathing is irregular or has stopped, administer artificial respiration. Give nothing by mouth. If unconscious, place in the recovery position and seek medical advice. Eye Contact: Contact lenses should be removed. Irrigate copiously with clean, fresh water for at least 10 minutes, holding the eyelids apart and seek medical advice. Skin Contact: Remove contaminated clothing. Wash skin thoroughly with soap and water, or use a proprietary skin cleanser. Do NOT use solvents or thinners. Ingestion: If accidentally swallowed obtain immediate medical attention. Keep at rest. Do NOT induce vomiting. 5. FIRE-FIGHTING MEASURES Extinguishing Media: Use alcohol resistant foam, carbon dioxide, dry powder or water spray/mist. Do NOT use water jet. Recommendations: Fire will produce dense black smoke containing hazardous products of combustion (see Section 10). Exposure to decomposition products may be a hazard to health. Appropriate self-contained breathing apparatus may be required. Cool closed containers exposed to fire with water spray. Do not allow run-off from fire-fighting to enter drains or water courses. 6. ACCIDENTAL RELEASE MEASURES Exclude sources of ignition and ventilate the area. Exclude non-essential personnel. Avoid breathing vapours. Refer to protective measures listed in sections 7 and 8. Contain and collect spillages with non-combustible absorbent materials e.g. sand, earth, vermiculite, diatomaceous earth and place in a suitable container for disposal in accordance with the waste regulations (see Section 13). Do not allow to enter drains or water courses. Clean preferably with a detergent; avoid the use of solvents. If the product enters drains or sewers, the local water company should be contacted immediately; in the case of contamination of streams, rivers or lakes, the National Rivers Authority. 7. HANDLING AND STORAGE Handling Vapours are heavier than air and may spread along floors. They may form explosive mixtures with air. Prevent the creation of flammable or explosive concentrations of vapour in air and avoid concentrations higher than the occupational exposure limits. Additionally, the product should only be used in areas from which all naked lights and other sources of ignition have been excluded. Electrical equipment should be protected to the appropriate standard. Keep the container tightly closed. Exclude sources of heat, sparks and open flame. Non-sparking tools should be used. Avoid skin and eye contact. Avoid inhalation of vapour. Smoking, eating and drinking should be prohibited in areas of storage and use. For personal protection, see Section 8. Never use pressure to empty; the container is not a pressure vessel. Good housekeeping standards and regular safe removal of waste material will minimise the risks of spontaneous combustion and other fire hazards. cont’d 9804/8964 ISSUE 3 (REV.), JUNE 2002 The Manual Handling Operations Regulations may apply to the handling of containers/packages of this product. The following guide weight indicators are given to enable users to carry out assessments. This information is also shown on the container label. 5 litre unit 5.0 kg 1 litre unit 1.0 kg Hand Protection When skin exposure may occur, advice should be sought from glove suppliers on appropriate types. Barrier creams may help to protect exposed areas of skin but are not substitutes for full physical protection. They should not be applied once exposure has occurred. Eye Protection Eye protection designed to protect against liquid splashes should be worn. Skin Protection Cotton or cotton/synthetic overalls or coveralls are normally suitable. Grossly contaminated clothing should be removed and the skin washed with soap and water or a proprietary skin cleaner. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Odour: Characteristic odour Colour: Clear, colourless Specific Gravity: 0.9 g/cm3 Flash Point: 32 °C Volatile Organic Content: 894 g/ltr Explosion limit - lower: 1.0% Water Solubility: Partly miscible 10. STABILITY AND REACTIVITY Stable under the recommended storage and handling conditions (see Section 7). In a fire, hazardous decomposition products such as smoke, carbon monoxide, carbon dioxide and oxides of nitrogen may be produced. Keep away from oxidising agents and strongly alkaline and strongly acidic materials to prevent the possibility of exothermic reaction. 13. DISPOSAL CONSIDERATIONS Do not allow into drains or water courses or dispose of where ground or surface waters may be affected. Wastes, including emptied containers, are controlled wastes and should be disposed of in accordance with regulations made under the Control of Pollution Act and the Environmental Protection Act. Using information provided in this data sheet, advice should be obtained from the Waste Regulation Authority whether the special waste regulations apply. 14. TRANSPORT INFORMATION Transport within the user’s premises Always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of accident or spillage. Transport Details Class : 3 Proper Shipping Name : Paint related material Sub Hazard : - The information contained in this data sheet does not constitute the user’s own assessment of workplace risks as required by other health and safety legislation. The provisions of the Health and Safety at Work etc. Act and the Control of Substances Hazardous to Health Regulations apply to the use of this product at work. 4. FIRST-AID MEASURES In all cases of doubt, or where symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. Inhalation: Remove to fresh air, keep patient warm and at rest. If breathing has stopped, administer artificial respiration. Give nothing by mouth. If unconscious, place in the recovery position and seek medical advice. Eye Contact: Contact lenses should be removed. Irrigate copiously with clean, fresh water for at least 10 minutes, holding the eyelids apart and seek medical advice. Skin Contact: Remove contaminated clothing. Wash skin thoroughly with soap and water, or use a proprietary skin cleanser. Do NOT use solvents or thinners. Ingestion: If accidentally swallowed obtain immediate medical attention. Keep at rest. Do NOT induce vomiting. 5. FIRE-FIGHTING MEASURES Extinguishing Media: Use alcohol resistant foam, carbon dioxide, dry powder or water spray/mist. Do NOT use water jet. Recommendations: Fire will produce dense black smoke containing hazardous products of combustion (see Section 10). Exposure to decomposition products may be a hazard to health. Appropriate self-contained breathing apparatus may be required. Cool closed containers exposed to fire with water spray. Do not allow run-off from fire-fighting to enter drains or water courses. 6. ACCIDENTAL RELEASE MEASURES Exclude sources of ignition and ventilate the area. Exclude non-essential personnel. Avoid breathing vapours. Refer to protective measures listed in sections 7 and 8. Contain and collect spillages with non-combustible absorbent materials e.g. sand, earth, vermiculite, diatomaceous earth and place in a suitable container for disposal in accordance with the waste regulations (see Section 13). Do not allow to enter drains or water courses. Clean preferably with a detergent; avoid the use of solvents. If the product enters drains or sewers, the local water company should be contacted immediately; in the case of contamination of streams, rivers or lakes, the National Rivers Authority. 7. HANDLING AND STORAGE Handling Vapours are heavier than air and may spread along floors. They may form explosive mixtures with air. Prevent the creation of flammable or explosive concentrations of vapour in air and avoid concentrations higher than the occupational exposure limits. Additionally, the product should only be used in areas from which all naked lights and other sources of ignition have been excluded. Electrical equipment should be protected to the appropriate standard. Keep the container tightly closed. Exclude sources of heat, sparks and open flame. Non-sparking tools should be used. Keep container tightly closed. Avoid skin and eye contact. Avoid inhalation of vapour and spray mist. Smoking, eating and drinking should be prohibited in areas of storage and use. For personal protection, see Section 8. Never use pressure to empty; the container is not a pressure vessel. Good housekeeping standards and regular safe removal of waste material will minimise the risks of spontaneous combustion and other fire hazards. cont’d 9804/8966 ISSUE 3 (REV.), JUNE 2002 The Manual Handling Operations Regulations may apply to the handling of containers/packages of this product. The following guide weight indicators are given to enable users to carry out assessments. This information is also shown on the container label. Base Additive Composite 5 litre unit 6.4 kg 1.1 kg 7.5 kg Hand Protection When skin exposure may occur, advice should be sought from glove suppliers on appropriate types. Barrier creams may help to protect exposed areas of skin but are not substitutes for full physical protection. They should not be applied once exposure has occurred. Eye Protection Eye protection designed to protect against liquid splashes should be worn. Skin Protection Cotton or cotton/synthetic overalls or coveralls are normally suitable. Grossly contaminated clothing should be removed and the skin washed with soap and water or a proprietary skin cleaner. 9. PHYSICAL AND CHEMICAL PROPERTIES The figures given below, unless otherwise stated, refer to the composite material. Physical State: Viscous liquid Odour: Characteristic odour Colour: Buff Specific Gravity: 1.3 g/cm3 Viscosity - base: 1.5-2.5 poise Rotothinner at 20°C Viscosity - additive: 46-50 seconds B2 cup at 20°C Flash Point - base: 27 °C Flash Point - additive: 30 °C Volatile Organic Content: 603 g/ltr Explosion limit - lower: 1.0% Water Solubility: Immiscible 10. STABILITY AND REACTIVITY Stable under the recommended storage and handling conditions (see Section 7). In a fire, hazardous decomposition products such as smoke, carbon monoxide, carbon dioxide and oxides of nitrogen may be produced. Keep away from oxidising agents and strongly alkaline and strongly acidic materials to prevent the possibility of exothermic reaction. For Sea Transport Marine Pollutant : No EmS : 3 - 05 MFAG : 310 This information does not apply to carriage by air. Please contact JCB Supply Department if transport by air is required. 15. REGULATORY INFORMATION This product has been classified and labelled for supply in accordance with the CHIP 2 regulations as follows:- Base: The information contained in this data sheet is based on the present state of knowledge and current national legislation. It provides guidance on health, safety and environmental aspects of the product and should not be construed as any guarantee of technical performance or suitability for particular applications. Further information and relevant advice can be found in:- The Chemicals (Hazard Information and Packaging for Supply) Regulations 1994 (SI 1994 : 3247) Highly Flammable Liquids and Liqueified Petroleum Gases Regulations 1972 (SI 1972 : 917) Control of Substances Hazardous to Health Regulations 1988 (SI 1988 : 1657) Manual Handling Operations Regulations 1992 (SI 1992: 2793) Environmental Protection (Duty of Care) Regulations 1992 (SI 1992 : 2839) Occupational Exposure Limits, EH40 The storage of flammable liquids in containers, HS(G)51 Storage of Packaged Dangerous Substances, HS(G)71 The Approved Guide to the Classification and Labelling of Substances and Preparations Dangerous for Supply (Second Edition), L63 The Approved Supply List, L61 The Approved Code of Practice: Safety Data Sheets for Substances and Preparations Dangerous for Supply, L62 Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 05.06.95/Rev. 2 9804/8997 ISSUE 2, (REV) SEPTEMBER 2002 COMPONENT EC NUMBER CONCENTRATION EC SYMBOL *4. FIRST-AID MEASURES Eye: Immediate medical attention is not required. Irrigate with eyewash solution or clean water until pain is relieved. If symptoms develop, obtain medical attention. Skin Contact: Immediate medical attention is not required. Wash skin with soap and water. If symptoms develop, obtain medical attention. Inhalation: Immediate medical attention is not required. Remove patient from exposure. If symptoms develop, obtain medical attention. Ingestion: Immediate medical attention is not required. Treat symptomatically and supportively. *5. FIRE-FIGHTING MEASURES Extinguishing Media: CO2; Dry Chemical; Foam; Water Fog Special Firefighting Procedures: Fire fighters should be equipped with self-contained breathing apparatus to protect against potentially toxic and irritating fumes. Fire & Explosion Hazards: Combustion may release noxious or toxic vapours. See below. Hazardous Combustion Products: Carbon monoxide, carbon dioxide, unknown hydrocarbons. Flash Point: > 100 °C *6. ACCIDENTAL RELEASE MEASURES Spill and Leak Procedures: Adsorb spillages onto sand, earth or any suitable adsorbent material. Scrape up and place in suitably labelled container for disposal. For safety and environmental precautions, please review entire Safety Data Sheet for necessary information. *7. HANDLING AND STORAGE Handling/Storage: Store in cool, dry place. Avoid the absence of air, and metal contamination. Sensitive to Static Electricity: No Sensitivity to Mechanical Impact: No Specific Uses: This product is not recommended for use in joints which will be in contact with either pure oxygen or steam. *8. EXPOSURE CONTROLS/PERSONAL PROTECTION OCCUPATIONAL EXPOSURE CONTROLS Ventilation Requirements: Local mechanical ventilation. Eye Protection Requirements: Safety glasses, goggles or face shield to protect against splashing. Personal eye protection should conform to EN 166. Glove Requirements: Nitrile rubber or Viton™ gloves are recommended. Cotton or other absorbent gloves should not be worn. Gloves should conform to EN 374. Clothing Requirements: Uniforms, coveralls, or a lab coat should be worn. Wash Requirements: Wash before eating, drinking, or using toilet facilities. Respiratory Requirements: None required under normal handling conditions. 9804/8997 ISSUE 2, (REV) SEPTEMBER 2002 *9. PHYSICAL AND CHEMICAL PROPERTIES Pure Substance or Preparation: Preparation Physical Form: Liquid Appearance/Odour: Blue Odour: Acrylic odour Boiling Point: Not applicable Solubility in Water: Insoluble Viscosity: 500 mPa.s Relative Density: 1.07 Volatile Organic Compounds: <5 g/litre Flash Point: >100 °C *10. STABILITY AND REACTIVITY Stability: Stable Conditions to Avoid: Avoid the absence of air, and metal contamination. Materials to Avoid: Metals and their salts., Reducing agents., Oxidizers., Free radical initiators Hazardous Decomposition Products: Thermal decomposition could produce carbon monoxide, carbon dioxide, and unidentified organic compounds. *14. TRANSPORT INFORMATION (See also section 9) Not applicable Substance identification number : Not applicable Other regulations : Government inventory status : COSHH regulations : Product reviewed under COSHH. For further information JCB SERVICE - PARTS DIVISION contact : ROCESTER STAFFORDSHIRE ST14 5LS TELEPHONE 01889 590312 9804/8934 ISSUE 2, SEPTEMBER 1995 Page 2 of 2 9804/8984 ISSUE 2, SEPTEMBER 1995 Loctite International SDS 128249 NBD - Health & Regulatory Affairs Safety Data Sheet - Made For JCB By Loctite Revision Date: 22/06/93 1. PRODUCT IDENTIFICATION 1.1. Product Name JCB Threadseal - Part No. 4102/1901 (Loctite 577) 1.2. Company Name Manufacturer : LOCTITE (Ireland) Limited Local Distributor : Loctite UK 1.3. Emergency Contact (24 Hour Service): First Call Local Distributor Tel - 0707 331277 Contact Name : Health & Safety Officer Manufacturer Tel +353-1-510433 or +353-1-519466, Fax +353-1-519073 2. COMPOSITIONAL INFORMATION Nature : Polyethyleneglycol based anaerobic composition. Component % by Wt* 5. FIRE-FIGHTING MEASURES Autoflammability: Not applicable Flash Point: >100 °C (Pensky-Martens Closed Tester) Extinguishing Media: CO2; Dry chemical; Foam; Water fog Special Firefighting Procedures: Fire fighters should be equipped with self-contained breathing apparatus to pro- tect against potentially toxic and irritating fumes. Fire & Explosion Hazards: Combustion may release noxious or toxic vapours. See below. Hazardous Combustion Products: Thermal decomposition could produce carbon monoxide, carbon dioxide, and unidentified organic compounds. Upper Explosion Limit (%): Not applicable Lower Explosion Limit (%): Not applicable 6. ACCIDENTAL RELEASE MEASURES Spill and Leak Procedures: Take up with sand or other absorbent material and place in container for later disposal. This material should not be spilled, dumped, or flushed into sewers or public waterways. For safety and environmental precautions, please review entire Safety Data Sheet for necessary information. 7. HANDLING AND STORAGE 9. PHYSICAL AND CHEMICAL PROPERTIES Pure Substance or Preparation: Preparation Physical Form: Liquid Appearance/Odour: Orange; Acrylic odour Odour Threshold: Not available pH as is: Not applicable Boiling Point: Not applicable Melting/Freezing Point: Not applicable Solubility in Water: Insoluble Partition Coefficient (n-octanol/water): Not applicable Relative Density: 1.090 Evaporation Rate: Not applicable Vapour Pressure (mmHg): Not applicable Vapour Density (air=1): Not applicable Viscosity: 500 mPa.s Volatiles: None Volatile Organic Compounds: <5 g/l Autoflammability: Not applicable Flash Point: >100 °C Oxidizing Properties: Not applicable 10. STABILITY AND REACTIVITY Stability: Stable Materials to Avoid: Acids; Bases; Peroxides Hazardous Decomposition Products: Thermal decomposition could produce carbon monoxide, carbon dioxide, and unidentified organic compounds. Hazardous Polymerization Conditions: An oxygen-free atmosphere may cause hazardous polymerization. *4. FIRST-AID MEASURES Eye: Immediate medical attention is not required. Irrigate with eyewash solution or clean water until pain is relieved. If symptoms develop, obtain medical attention. Skin contact: Immediate medical attention is not required. Wash skin with soap and water. If symptoms develop, obtain medical attention. Inhalation: Immediate medical attention is not required. Remove to fresh air. Get medical attention if irritation persists. Ingestion: Immediate medical attention is not required. Treat symptomatically and supportively. *5. FIRE-FIGHTING MEASURES Extinguishing Media: CO2; Dry Chemical; Foam; Water Fog Special Firefighting Procedures: Fire fighters should be equipped with self-contained breathing apparatus to protect against potentially toxic and irritating fumes. Fire & Combustion Hazards: Combustion may release noxious or toxic vapours. See below. Hazardous Combustion Products: Carbon monoxide, carbon dioxide, unknown hydrocarbons. Flash Point: > 100 °C *6. ACCIDENTAL RELEASE MEASURES Spill and Leak Procedures: Adsorb spillages onto sand, earth or any suitable adsorbent material. Scrape up and place in suitably labelled container for disposal. For safety and environmental precautions, please review entire Safety Data Sheet for necessary information. *7. HANDLING AND STORAGE Handling/Storage: Store in cool, dry place. Avoid the absence of air, and metal contamination. Sensitive to Static Electricity: No Sensitivity to Mechanical Impact: No Specific Uses: This product is not recommended for use in joints which will be in contact with either pure oxygen or steam. *8. EXPOSURE CONTROLS/PERSONAL PROTECTION OCCUPATIONAL EXPOSURE CONTROLS Ventilation Requirements: General. Eye Protection Requirements: Safety glasses, goggles or face shield to protect against splashing. Personal eye protection should conform to EN 166. Glove Requirements: Nitrile rubber or Viton™ gloves are recommended. Cotton or other absorbent gloves should not be worn. Gloves should conform to EN 374. Clothing Requirements: Uniforms, coveralls, or a lab coat should be worn. Wash Requirements: Wash before eating, drinking, or using toilet facilities. Respiratory Requirements: None required under normal handling conditions. 9804/9002 ISSUE 2, (REV) SEPTEMBER 2002 *9. PHYSICAL AND CHEMICAL PROPERTIES Pure Substance or Preparation: Preparation Physical Form: Liquid Colour: White Odour: Acrylic odour Boiling Point: Not applicable Solubility in Water: Insoluble Viscosity: Approximately 70000 mPa.s Relative Density: 1.09 Volatile Organic Compounds: < 5 g/litre Flash Point: >100 °C *10. STABILITY AND REACTIVITY Stability: Stable Conditions to Avoid: Avoid the absence of air, and metal contamination. Materials to Avoid: Metals and their salts., Reducing agents., Oxidizers., Free radical initiators Hazardous Decomposition Products: Thermal decomposition could produce carbon monoxide, carbon dioxide, and unidentified organic compounds. *14. TRANSPORT INFORMATION (See also section 9) *4. FIRST-AID MEASURES Eye: Immediate medical attention is not required. Irrigate with eyewash solution or clean water until pain is relieved. If symptoms develop, obtain medical attention. Skin Contact: Immediate medical attention is not required. Wash skin with soap and water. If symptoms develop, obtain medical attention. Inhalation: Immediate medical attention is not required. Remove to fresh air. Get medical attention if irritation persists. Ingestion: Immediate medical attention is not required. Treat symptomatically and supportively. *5. FIRE-FIGHTING MEASURES Extinguishing Media: CO2; Dry Chemical; Foam; Water Fog Special Firefighting Procedures: Fire fighters should be equipped with self-contained breathing apparatus to protect against potentially toxic and irritating fumes. Fire & Explosion Hazards: Combustion may release noxious or toxic vapours. See below. Hazardous Combustion Products: Carbon monoxide, carbon dioxide, unknown hydrocarbons. Flash Point: > 100 °C *6. ACCIDENTAL RELEASE MEASURES Spill and Leak Procedures: Adsorb spillages onto sand, earth or any suitable adsorbent material. Scrape up and place in suitably labelled container for disposal. For safety and environmental precautions, please review entire Safety Data Sheet for necessary information. *7. HANDLING AND STORAGE Handling/Storage: Store in cool, dry place. Avoid the absence of air, and metal contamination. Sensitive to Static Electricity: No Sensitivity to Mechanical Impact: No Specific Uses: This product is not recommended for use in joints which will be in contact with either pure oxygen or steam. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION OCCUPATIONAL EXPOSURE CONTROLS Ventilation Requirements: General. Eye Protection requirements: Safety glasses, goggles or face shield to protect against splashing. Personal eye protection should conform to EN 166. Glove requirements: Nitrile rubber or Viton™ gloves are recommended. Cotton or other absorbent gloves should not be worn. Gloves should conform to EN 374. Clothing Requirements: Uniforms, coveralls, or a lab coat should be worn. Wash requirements: Wash before eating, drinking, or using toilet facilities. Respiratory Requirements: None required under normal handling conditions. 9804/9005 ISSUE 2, (REV) SEPTEMBER 2002 *9. PHYSICAL AND CHEMICAL PROPERTIES Pure Substance or Preparation: Preparation Physical Form: Liquid *14. TRANSPORT INFORMATION (See also section 9) Chronic effects of exposure to man. 7. HANDLING AND STORAGE Handling Avoid prolonged or repeated contact with skin. Avoid breathing vapours. Ingestion Unlikely to cause harm if accidentally swallowed in small doses, though larger quantities may cause nausea and diarrhoea. Chronic Repeated skin contact may cause a persistent irritation or dermatitis. The Company accepts no responsibility for any injury, loss or damage, consequent upon any failure to follow the safety and other recommendations contained in this Material Safety Data Sheet, nor from any hazards inherent in the nature of the material, nor from any abnormal use of the material. Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 TEL: + 44 (0) 1889 590546 9804/8868 ISSUE 2 (REV.), MARCH 1997 Emergency Contact : Emergency Telephone No.: +44 (0) 1889 590312 2. COMPOSITION/INFORMATION ON INGREDIENTS Ingredients considered hazardous to health: This product is not hazardous to health as defined by the EC Dangerous Substances/Preparations Directives. See Section 15 for a regulatory analysis of the ingredients. Effects of overexposure: No significant effects expected. 4. FIRST-AID MEASURES Eye Contact: Flush thoroughly with water. If irritation occurs, call a doctor. Skin Contact: If burned by contact with hot material, cool molten material adhering to skin as quickly as possible with water and see a physician for removal of adhering material and treatment of burn. Wash contact areas with soap and water. Inhalation: Not expected to be a problem. Ingestion: Not expected to be a problem when ingested. If uncomfortable, obtain medical attention or call an ambulance. 9804/8868 ISSUE 2 (REV.), MARCH 1997 5. FIRE-FIGHTING MEASURES Extinguishing Media: Carbon dioxide, foam, dry chemical and water fog. Special fire fighting procedures: Water or foam may cause frothing. Use water to keep fire exposed containers cool. Water spray may be used to flush spills away from exposures. Prevent runoff from fire control or dilution from entering waterways or drinking water supply. Special protective equipment: For fires in enclosed areas, firefighters MUST use self-contained breathing apparatus. Unusual fire and explosion hazards: None. Flash Point °C (°F): > 176 (349) (IP 36/ASTM D-92). Flammable limits - LEL NA, UEL NA. NFPA Hazard ID: Health: 0 Flammability: 1 Reactivity: 0 Hazardous Decomposition Products: Carbon monoxide. 6. ACCIDENTAL RELEASE MEASURES Notification Procedures: Report spills as required to appropriate authorities such as the local Environmental Health Officer or Fire Brigade. If spills are likely to enter any drain, waterway or groundwater, contact the Area Water Authority. Procedures if Material is Released or Spilled: Contain and absorb on fire retardant treated sawdust, diatomaceous earth, etc. Shovel up and dispose of at an appropriate licensed waste disposal site in accordance with current applicable laws and regulations and product characteristics at time of disposal. Environmental Precautions: Prevent spills from entering storm sewers or drains and contact with soil. Personal Precautions: See Section 8. 7. HANDLING AND STORAGE Handling: No special precautions are necessary beyond normal good hygiene practices. See Section 8 for additional personal protection advice when handling this product. • 4. FIRST-AID MEASURES Eyes: ^<2AK'8K@'@H@']58K'6;J5;2A'7>;298A';=']78@4M'L;'@>@4:@96H'>@7A24@A'74@'9@6@AA74H'328'5='7S?@4A@'@H@'@==@68A' =;<<;]&'4@=@4'=;4'>@S567<'788@985;9M' Skin: 7AK'8K@'6;987>5978@S'AV59'8K;4;2 K<H']58K'A;7J'79S']78@4M'L;'@>@4 @96H'>@7A24@A'74@'9@6@AA74H'328'5='7S?@4A@' AV59'@==@68A'=;<<;]&'4@=@4'=;4'>@S567<'788@985;9M' Inhalation: E@>;?@'8K@'7==@68@S'J@4A;9'8;'=4@AK'754M'G='4@6;?@4H'5A'9;8'47J5S&';38759'>@S567<'788@985;9M' Ingestion: +_'L_I'GL+[C.'F_`GIGLaM'L;'@>@4:@96H'>@7A24@A'74@'9@@S@S'328'5='7S?@4A@'K@7<8K'@==@68A'=;<<;]&'4@=@4'=;4' >@S567<'788@985;9M' • 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering measures: L;'AJ@657<'>@7A24@A'9@@S@SM' Control parameters: I/-'I1F'P-CaGXQN'*'>:$>')'=;4';5<'>5A8M'X;]@?@4&'59'7<<'65462>A8796@A'@\J;A24@'AK;2<S'3@'V@J8'7A'<;]'7A'4@7A;973<H' J;AA53<@'3H' ;;S'?@985<785;9'79S'A7=@'];4V59 'J476856@AM' Respiratory protection: G9K7<785;9';='?7J;24A&'=2>@A';4'>5A8A'AK;2<S'3@'7?;5S@S'3H'A7=@'];4V59 'J476856@A'79S' ;;S'?@985<785;9M' Eye protection: G='8K@4@'5A'7'45AV';='AJ<7AK59 ']K5<@'K79S<59 'J4;S268&'@H@'J4;8@685;9'AK;2<S'3@'];49'P@M M'=2<<'=76@'AK5@<S';4' ; <@A']58K' A5S@'AK5@<SAQM' Skin protection: f4;<;9 @S'79S'4@J@78@S'AV59'6;98768'AK;2<S'3@'7?;5S@S'3H'8K@'2A@';='6<@79' <;?@A'79S'6<@79';?@47<<AM' ' • 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: _5<H'<5d25S' Colour: D4;]9' Appearance D45 K8'79S'6<@74' Odour: /@7V' pH ,<5 K8<H'7<V7<59@' Boiling range, ¡C G95857<'3;5<59 'J;598'P;5<'37A@Q'g')""' Pour/melting point, ¡C: h'0(Z' Flash point, ¡C g'(""'P-,I`'+R(&'C_CQ' Autoflammability/ignition, ¡C g')""'P;5<'37A@Q' Upper explosion limit: L;8'V9;]9' Lower explosion limit: L;8'V9;]9' Vapour pressure, 20 ¡C, kPa: h'"M"#'P;5<'37A@Q' Viscosity, kinematic, 40 ¡C, mm 2 /s: g'Z"' Relative density, 15 ¡C: "M%%' Water solubility: L;8'A;<23<@' Partition coefficient, n-octanol/water: L;8'V9;]9' Other data: • 10. STABILITY AND REACTIVITY Conditions/materials to avoid: 873<@M'`7H'4@768']58K'A84;9 ';\5S5A59 '7 @98AM' Hazardous decomposition products: IK@4>7<'S@6;>J;A585;9';4'596;>J<@8@'6;>32A85;9'>7H'J4;S26@';\5S@A';='6743;9'79S'544587859:'=2>@AM' ' 9804/9015 ISSUE 1, JULY 2000 R&S phrases: L;9@' ' 4. FIRST-AID MEASURES Eyes: `<2T>(8>A(A?A(^58>(6;C5;2T(7D;298T(;=(^78A4L(K;(ADA4:A96?(DA7T24AT(74A(9A6ATT74?(328(5=(7@SA4TA(A?A(A==A68T( =;<<;^'(4A=A4(=;4(DA@567<(788A985;9L( Skin: a7T>(8>A(6;987D5978A@(TZ59(8>;4;2 ><?(^58>(T;7C(79@(^78A4L(K;(ADA4 A96?(DA7T24AT(74A(9A6ATT74?(328(5=( 7@SA4TA(TZ59(A==A68T(=;<<;^'(4A=A4(=;4(DA@567<(788A985;9L( Inhalation: IAD;SA(8>A(7==A68A@(CA4T;9(8;(=4AT>(754L(,=(4A6;SA4?(5T(9;8(47C5@'(;38759(DA@567<(788A985;9L( Ingestion: +.(K.J(,K+]FH(/.b,J,K0L(K;(ADA4:A96?(DA7T24AT(74A(9AA@A@(328(5=(7@SA4TA(>A7<8>(A==A68T(=;<<;^'(4A=A4(=;4( DA@567<(788A985;9L( 9804/9016 ISSUE 1, JULY 2000 •••• 7. HANDLING AND STORAGE Handling: WS;5@(C4;<;9:A@(;4(4ACA78A@(TZ59(6;98768L(WS;5@(59>7<785;9(;=(S7C;24'(D5T8(;4(=2DATL(+;(9;8(^A74(6;987D5978A@( 6<;8>59:L( ( •••• 12. ECOLOGICAL INFORMATION J>A(37TA(;5<(6;DC;9A98T(74A(9;8(AUCA68A@(8;(3A(@79 A4;2T(8;(8>A(7B27856(A9S54;9DA98L(K;8(4A7@5<?(35;@A 47@73<AL( ( •••• 13. DISPOSAL CONSIDERATIONS J479TC;48(8;(728>;45TA@(^7T8A(<;6785;9'(;4(59659A4785;9(29@A4(6;984;<<A@(6;9@585;9TL( ( •••• 14. TRANSPORT INFORMATION UN-No: K;8(6<7TT5=5A@( ( IATA/ICAO: K;8(6<7TT5=5A@( RID/ADR: K;8(6<7TT5=5A@( ( Other: IMO: K;8(6<7TT5=5A@( ( •••• 15. REGULATORY INFORMATION K;(HF(AUC;T24A(<5D58(AT873<5T>A@L( EC Labelling/Classification: R&S phrases: K;9A( ( •••• 16. OTHER INFORMATION F.KFWaH(4AC;48(9;L(*$QX(i>A7<8>(7TCA68T(;=(<23456798TjL( ( ,8(5T(3A<5ASA@(8>78(7<<(8>A(59=;4D785;9(:5SA9(59(8>5T(32<<A859(O^>56>(T2CA4TA@AT(7<<(C4AS5;2T(5TT2ATP(5T(7662478A(78(8>A( 85DA(;=(C459859 L(-26>(59=;4D785;9(5T(;==A4A@(59( ;;@(=758>(328(^58>;28( 274798AA(79@(^58>;28(79?(4AC4ATA98785;9(8>78( 8>A(C4;@268(6;96A49A@(5T(T25873<A(=;4(79?(2TA(;4(7CC<56785;9L(a58>;28(<5D58785;9(;=(8>A(=;4A ;59 '(9;8>59 (>A4A59(T>7<<( 3A(6;9T842A@(7T(7(4A6;DDA9@785;9(=;4(2TAT(^>56>(59=459 A(S7<5@(C78A98T(;4(7T(AU8A9@59 (79?(<56A9TA(29@A4(S7<5@( C78A98TL( ( EFG(C24T2AT(7(C;<56?(;=(6;9T8798(4ATA746>(79@(@ASA<;CDA98(75DA@(78(C4;@268(5DC4;SADA98(79@'(8>A4A=;4A'( 4ATA4SAT(8>A(45 >8(8;(6>79 A(=;4D2<785;9'(TCA65=56785;9(79@(6>74768A45T856T(;=(58T(C4;@268T(^58>;28(9;856AL(]TA4( T>;2<@(SA45=?(6244A98(TCA65=56785;9T(^58>(EFG(79@(7T6A48759(8>78(C4;@268T(74A(T25873<A(=;4(598A9@A@(2TAT(79@( 7CC<56785;9TL( ( a>A4A(8>A(59=;4D785;9(C4;S5@A@(>A4A59(@5T6<;TAT(7(C;8A9857<(>7\74@(;4(>7\74@;2T(59 4A@5A98'(7@AB278A(^74959 ( D2T8(3A(C4;S5@A@(8;(ADC<;?AAT(79@(2TA4T(79@(7CC4;C4578A(C4A67285;9T(87ZA9'(596<2@59 (8>A(C476856A(;=( ;;@( 59@2T8457<(>?:5A9AL( ( `248>A4(,9=;4D785;9(6;98768M( ( JCB SERVICE WORLD PARTS CENTRE UTTOXETER STAFFORDSHIRE ST14 7BS TEL: + 44 (0) 1889 590312 9804/9016 ISSUE 1, JULY 2000 9804/8889 ISS.1 SEPT.89 PRODUCT SAFETY NOTICE To be read in conjunction with Product Safety Information (COSHH) leaflets. It is believed that all the information given in the accompanying leaflet is accurate at the time of printing. Such information is offered in good faith but without guarantee and without any representation that the product concerned is suitable for any particular use or application. Without limitation of the foregoing, nothing herein shall be construed as a recommendation for uses which infringe valid patents or as extending any licence under valid patents. JCB Service pursues a policy of constant development aimed at product improvement and, therefore, reserves the right to change formulation, specification and characteristics of its products without notice. Users should verify current specifications with JCB Service or their authorised distributors, and ascertain that products are suitable for intended uses or applications. Where the information provided herein discloses a potential hazard or hazardous ingredients, adequate warning must be provided to employees and users and appropriate precautions taken, including the practice of good industrial hygiene. PREPARED BY : JCB SERVICE FOR FURTHER INFORMATION CONTACT : JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TELEPHONE 01889 590312 9804/9007 ISSUE 2, SEPTEMBER 2001 Surface Primer Component CAS Number Concentration Ranges EEC Symbol/Risk Phrases Alkanes, C7-10-iso- 90622-56-3 35-50 F XN R11 R65 R67 N XI R50/53 R38 Emergency Overview: Irritant extremely flammable. Eye: Slight/Mild irritant. Skin Contact: Repeated of prolonged contact may cause defatting of the skin resulting in dryness, cracking and dematitis. Inhalation: The vapour has anaesthetic properties and when inhaled at concentrations above the occupational exposure limit, it may cause respiratory irritation, headache, fatigue, dizziness and incoordination. Ingestion: Low oral toxicity. *4. FIRST-AID MEASURES Eye: Irrigate with eyewash solution or clean water until pain is relieved. Skin Contact: Wash skin with soap and water. Inhalation: Remove patient from exposure. Ingestion: If swallowed, DO NOT induce vomiting. Keep at rest. Get prompt medical attention. 9804/9007 ISSUE 2, SEPTEMBER 2001 *5. FIRE-FIGHTING MEASURES Extinguishing Media: Dry chemical; Foam Special Firefighting Procedures: Fire fighters should be equipped with self-contained breathing apparatus to protect against potentially toxic and irritating fumes. Water or water foam can cause frothing which can be violent, especially if sprayed into container of hot burning liquid, and can possibly endanger fire fighter. Fire & Explosion Hazards: Dangerous fire hazard when exposed to heat or flame. Hazardous Combustion Products: Thermal decomposition may release toxic and/or hazardous gases. Lower Explosion Limit (%): 1.1 Upper Explosion Limit (%): 7.4 Autoflammability: >200 °C Flash Point: -26 °C (Tagliabue Closed Tester/Tag Closed Tester) 6. ACCIDENTAL RELEASE MEASURES Spill and Leak Procedures: Shut off ignition sources. Stop leak if you can do it without risk. For small liquid spills, take up with sand or other absorbent material. For larger spills, dam far ahead of spill for later disposal. No smoking, flames or flares in hazard area. Keep unnecessary people away. For safety and environmental precautions, please review entire Safety Data Sheet for necessary information. *7. HANDLING AND STORAGE Wash Requirements: Wash before eating, drinking, or using toilet facilities. Respiratory Requirements: Avoid prolonged or repeated breathing of vapour or mists. If exposure may or does exceed occupational exposure limits, use a NIOSH approved respirator to prevent overexposure. *9. PHYSICAL AND CHEMICAL PROPERTIES Pure Substance or Preparation: Preparation Physical Form: Liquid Inhalation: Remove to fresh air, keep patient warm and at rest. If breathing has stopped, administer artificial respiration. Give nothing by mouth. If unconscious, place in the recovery position and seek medical advice. Eye Contact: Contact lenses should be removed. Irrigate copiously with clean, fresh water for at least 10 minutes, holding the eyelids apart and seek medical advice. Skin Contact: Remove contaminated clothing. Wash skin thoroughly with soap and water, or use a proprietary skin cleanser. Do NOT use solvents or thinners. Ingestion: If accidentally swallowed obtain immediate medical attention. Keep at rest. Do NOT induce vomiting. 5. FIRE-FIGHTING MEASURES Extinguishing Media: Use alcohol resistant foam, carbon dioxide, dry powder or water spray/mist. Do NOT use water jet. Recommendations: Fire will produce dense black smoke containing hazardous products of combustion (see Section 10). Exposure to decomposition products may be a hazard to health. Appropriate self-contained breathing apparatus may be required. Cool closed containers exposed to fire with water spray. Do not allow run-off from fire-fighting to enter drains or water courses. 6. ACCIDENTAL RELEASE MEASURES Exclude sources of ignition and ventilate the area. Exclude non-essential personnel. Avoid breathing vapours. Refer to protective measures listed in sections 7 and 8. Contain and collect spillages with non-combustible absorbent materials e.g. sand, earth, vermiculite, diatomaceous earth and place in a suitable container for disposal in accordance with the waste regulations (see Section 13). Do not allow to enter drains or water courses. Clean preferably with a detergent; avoid the use of solvents. If the product enters drains or sewers, the local water company should be contacted immediately; in the case of contamination of streams, rivers or lakes, the relevant environment agency. 7. HANDLING AND STORAGE Handling Vapours are heavier than air and may spread along floors. They may form explosive mixtures with air. Prevent the creation of flammable or explosive concentrations of vapour in air and avoid concentrations higher than the occupational exposure limits. Additionally, the product should only be used in areas from which all naked lights and other sources of ignition have been excluded. Electrical equipment should be protected to the appropriate standard. Keep the container tightly closed. Exclude sources of heat, sparks and open flame. Non-sparking tools should be used. Required air quantity to 137 m3/ltr ventilate to 10% of the LEL The above figure is given as a guide only. Ventilation and extraction must be arranged so that all parts of the workplace are properly ventilated i.e. there are no recesses or pockets where high vapour concentrations are allowed to build up. If there is any doubt about the adequacy of the ventilation/extraction of solvent vapour, regular monitoring of confined workplaces should be carried out. Avoid skin and eye contact. Avoid inhalation of vapour and spray mist. Smoking, eating and drinking should be prohibited in areas of storage and use. For personal protection, see Section 8. Never use pressure to empty; the container is not a pressure vessel. cont’d 9804/9022 ISSUE 1, JANUARY 2002 The accumulation of contaminated rags and dry overspray, particularly in spray booth filters, may result in spontaneous combustion. Good housekeeping standards, regular safe removal of waste materials and regular maintenance of spray booth filters will minimise the risks of spontaneous combustion and other fire hazards. The Manual Handling Regulations may apply to the handling of containers/packages of this product. The following guide weight indicators are given to enable users to carry out assessments. Package Weight 1 litre can 1.3 - 1.4 kg Hand Protection When skin exposure may occur, advice should be sought from glove suppliers on appropriate types. Barrier creams may help to protect exposed areas of skin but are not substitutes for full physical protection. They should not be applied once exposure has occurred. Eye Protection Eye protection designed to protect against liquid splashes should be worn. Skin Protection Cotton or cotton/synthetic overalls or coveralls are normally suitable. Grossly contaminated clothing should be removed and the skin washed with soap and water or a proprietary skin cleanser. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Viscous liquid Odour: Characteristic odour Colour: Grey Density: 1.1 g/cm3 Viscosity: 1.8 - 2.4 poise. BS3900: Part A7 at 25 °C Flash Point: 39 °C Volatile Organic Content: 467 g/ltr Explosion limit - lower: 0.6% Water Solubility: Immiscible 10. STABILITY AND REACTIVITY Stable under the recommended storage and handling conditions (see Section 7). In a fire, hazardous decomposition products such as smoke, carbon monoxide, carbon dioxide and oxides of nitrogen may be produced. Keep away from oxidising agents and strongly alkaline and strongly acidic materials to prevent the possibility of exothermic reaction. 13. DISPOSAL CONSIDERATIONS Do not allow into drains or water courses or dispose of where ground or surface waters may be affected. Wastes, including emptied containers, are controlled wastes and should be disposed of in accordance with regulations made under the Control of Pollution Act and the Environmental Protection Act. Using information provided in this data sheet, should be obtained from the relevant environment agency whether the special waste regulations apply. 14. TRANSPORT INFORMATION Transport within the user’s premises Always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of accident or spillage. The product should not be used for purposes other than those shown in Section 1 without first referring to the supplier and obtaining written handling instructions. As the specific conditions of use are outside the supplier’s control, the user is responsible for ensuring that the requirements of relevant legislation are complied with. The information contained in this data sheet is based on the present state of knowledge and current national legislation. It provides guidance on health, safety and environmental aspects of the product and should not be construed as any guarantee of technical performance or suitability for particular applications. Further information and relevant advice can be found in:- The Chemicals (Hazard Information and Packaging for Supply) Regulations 1994 (SI 1994 : 3247) and amendments. Control of Substances Hazardous to Health Regulations 1999 (SI 1999 : 437) Manual Handling Operations Regulations 1992 (SI 1992 : 2793) Environmental Protection (Duty of Care) Regulations 1992 (SI 1992 : 2839) Occupational Exposure Limits, EH40 (revised annually) The storage of flammable liquids in containers, HS(G)51 Chemical warehousing: the storage of packaged dangerous substances, HS(G)71 The Approved Guide to the Classification and Labelling of Substances and Preparations Dangerous for Supply (Fourth Edition), L100 The Approved Supply List, L124 The Approved Code of Practice: Safety Data Sheets for Substances and Preparations Dangerous for Supply, L62 Special Waste Regulations 1996 (SI 1996:972) and amendments. The interpretation and use of flashpoint information, CS24. COSHH Essentials: easy steps to control chemicals, HS(G)193. Details of available Control Guidance Sheets, which may be relevant to the particular conditions of use, can also be found in HS(G)193. Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 Leigh’s/JCB Thinners No. 5/27/03/2001 9804/9028 ISSUE 1, JANUARY 2002 Emergency Contact : Emergency Telephone No.: +44 (0) 1889 590312 Description: Screenwash and De-icer 2. COMPOSITION/INFORMATION ON INGREDIENTS Declaration according to EC-Guideline (89/542/EEC): not applicable Information on dangerous substance(s) (89/379/EEC): Isopropylalcohol (isopropanol), CAS no. 67-63-0, F, Xi 11-36-67 conc. 14-19%, Ethylalcohol (ethanol), CAS no. 64-17-5, F 11 Conc. 25-32% Monoethyleneglycol, CAS no. 107-21-1, Xn 22 conc. < 24% Other substances: detergent, perfume, dye Flammable. May be absorbed by inhalation and/or ingestion. Keep out of the reach of children. Keep container in a well-ventilated place. 9804/9028 ISSUE 1, JANUARY 2002 4. FIRST-AID MEASURES General information: In case of ingestion always consult physician. First aid Inhalation: Fresh air, rest. Skin: Remove contaminated clothing. Rinse with water. Eye: Flush with water. In case of persistant irritation, consult physician. Ingestion: Rinse mouth with water. Let drink water. DO NOT induce vomiting. Consult physician. Advice to physician: May irritate respiratory system. May affect consciousness. 5. FIRE-FIGHTING MEASURES Extinguishing media: Carbon dioxide, powder, alcohol resistant foam, atomized water Vapour may build explosive mixtures with air Protective equipment: Self contained breathing apparatus 6. ACCIDENTAL RELEASE MEASURES Leaks and spills: Remove sources of ignition - no smoking. Avoid product from entering sewage. Rinse floor with water. Personal protection: Large quantities: boots, gloves, safety goggles. Ventilate well. 7. HANDLING AND STORAGE Handling: Use in ventilated area only. No smoking, open fire or welding. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Colour: Blue Odour: Characteristic Density (at 20°C.): appr. 930 kg/m3 pH (20°C.): n.b. Viscosity (at 20 C.): n.b. Solubility in water: in any ratio Boiling point/range: appr. 85 ºC. Explosion limits: 2-12% v/v Flashpoint: 21 < ºC. < 23 10. STABILITY AND REACTIVITY Stability: Stable under normal conditions Materials/conditions to avoid: Oxidizing substances, no smoking, no sparks or open fire Hazardous decomposition products: Carbon monoxyde, - dioxide 14. TRANSPORT INFORMATION ADR/RID Class: 3 Name: 1987 Alcohols, n.o.s. Packaging group II IMO UN no.: 1987 MFAG: 305 Class: 3.2 EmS: 3-06 Eye Contact: Contact lenses should be removed. Irrigate copiously with clean, fresh water for at least 10 mins. holding the eyelids apart, seek medical advice. Skin Contact: Remove contaminated clothing. Wash skin thoroughly with soap and water or use a proprietary skin cleaner. Do NOT use solvents or thinners. Ingestion: If accidentally swallowed obtain immediate medical attention. Keep at rest. Do NOT induce vomiting. 5. FIRE-FIGHTING MEASURES Extinguishing Media: Carbon dioxide, Dry Powder, Sand, Foam. NOT TO BE USED: WATER Special Instructions for Fire Fighting Personnel: Fire will produce dense black smoke containing hazardous products of combustion (see Section 10). Decomposition products may be a hazard to health. Appropriate self-contained breathing apparatus may be required. Cool closed containers exposed to fire with water spray. Do not allow run-off from fire fighting to enter drains or water courses. 6. ACCIDENTAL RELEASE MEASURES Exclude sources of ignition and ventilate the area. Exclude non-essential personnel. Avoid breathing vapours. Refer to protective measures listed in sections 7 and 8. Contain and collect spillages with non-combustible absorbent materials e.g. sand, earth and place in a suitable container for disposal in accordance with the waste regulations. Do not allow to enter drains or water courses. If it does the local water company should be contacted immediately, in case of contamination of streams, rivers or lakes the Environments Agency. Clean preferably with a detergent; avoid the use of solvents. 7. HANDLING AND STORAGE Do not use in areas where potential sources of ignition exist. Use non sparking tools and exclude sources of heat, sparks and flames. Keep container tightly closed. Never use pressure to empty, container is not a pressure vessel. Always keep in containers made of the same material as the supply container. Avoid skin & eye contact. For personal protection see Sect. 8. Good housekeeping, regular maintenance of spray booth filters, and regular removal of waste materials will minimise risks. Observe the label precautions. Store between 5 and 25 deg. C in a dry well ventilated place away from sources of heat, ignition and direct sunlight. No smoking. Prevent unauthorised access. Containers which are opened should be properly resealed and kept upright to prevent leakage. Store away from oxidising agents and strongly alkaline or acid materials. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Measures Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. If extraction methods are insufficient to maintain concentrations of particulates and/or solvent vapours below OEL’s, suitable respiratory protective equipment should be worn. Substance Name % Conc Notes: Notations = Sk - risk or absorption through skin Sen = respiratory sensitiser Notations = SK - Risk of absorption through skin SEN - Respiratory Sensitiser Bmgv - Biological Monitoring may be appropriate (see Biological Monitoring guidance Value in EH40 Table 3) OEL’s are from EH40 except where marked SUP which are assigned by the supplier of the substance. General Protection All ppe, including rpe, used to control exposure to hazardous substances must be selected to meet the requirements of the COSHH regulations. Respiratory Protection Air-fed respiratory equipment should be worn when spraying if levels cannot be controlled below OELs and engineering methods cannot be reasonably improved. Hand Protection Full physical protection is best. Seek relevant advice from glove manufacturers. Barrier cream may be of help but should not be applied after exposure has occurred. Eye Protection Eye protection designed to protect against liquid splashes should be worn. Skin Protection Cotton or cotton/synthetic overalls or coveralls are normally suitable. Grossly contaminated clothing should be removed and the skin washed with soap and water or a proprietary skin cleaner. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Flash Point: ≥ 21 ºC & ≤ 55 ºC Method Equilibrium Method to ISO 1516 & ISO 3680 Viscosity: Specific Gravity: .905 gms/cc Method Calculation Vapour Density: Heavier than Air Lower Explosion Limit: .8% Vol. Solubility in Water: Partially miscible 10. STABILITY AND REACTIVITY Stable under the recommended storage and handling conditions (see Section 7). In a fire, hazardous decomposition products such as smoke, carbon monoxide, carbon dioxide and oxides of nitrogen may be produced. Keep away from oxidising agents and strongly alkaline and acid materials to prevent the possibility of an exothermic reaction. HIGHER AROMATICS Eye Contact: Contact lenses should be removed. Irrigate copiously with clean, fresh water for at least 10 mins. holding the eyelids apart, seek medical advice. Skin Contact: Remove contaminated clothing. Wash skin thoroughly with soap and water or use a proprietary skin cleaner. Do NOT use solvents or thinners. Ingestion: If accidentally swallowed obtain immediate medical attention. Keep at rest. Do NOT induce vomiting. 5. FIRE-FIGHTING MEASURES Extinguishing Media: Carbon dioxide, Dry Powder, Sand, Foam. NOT TO BE USED: WATER Special Instructions for Fire Fighting Personnel: Fire will produce dense black smoke containing hazardous products of combustion (see Section 10). Decomposition products may be a hazard to health. Appropriate self-contained breathing apparatus may be required. Cool closed containers exposed to fire with water spray. Do not allow run-off from fire fighting to enter drains or water courses. 6. ACCIDENTAL RELEASE MEASURES Exclude sources of ignition and ventilate the area. Exclude non-essential personnel. Avoid breathing vapours. Refer to protective measures listed in sections 7 and 8. Contain and collect spillages with non-combustible absorbent materials e.g. sand, earth and place in a suitable container for disposal in accordance with the waste regulations. Do not allow to enter drains or water courses. If it does the local water company should be contacted immediately, in case of contamination of streams, rivers or lakes the Environments Agency. Clean preferably with a detergent; avoid the use of solvents. 7. HANDLING AND STORAGE Vapours are heavier than air and may spread along floors. They may form explosive mixtures with air. Prevent creation of explosive or flammable mixtures and avoid vapour concs higher then the OEL. Do not use in areas where potential sources of ignition exist. Electrical equipment should be protected to the appropriate standard. Use non sparking tools and exclude sources of heat, sparks and flames. Keep container tightly closed. Never use pressure to empty, container is not a pressure vessel. Always keep in containers made of the same material as the supply container. Avoid skin and eye contact. For personal protection see Section 8. Good housekeeping, regular maintenance of spray booth filters, and regular removal of waste materials will minimise risks. The product may charge electrostatically, use earthing leads when transferring from one container to another. Wear anti-static footwear and clothing, floors should be electrically conductive. Store in accordance with the HSE Guidance note ‘Storage of Flammable Liquids in Containers’ HS(G)51. Observe the label precautions. Store between 5 and 25 ºC in a dry well ventilated place away from sources of heat, ignition and direct sunlight. No smoking. Prevent unauthorised access. Containers which are opened should be properly resealed and kept upright to prevent leakage. Store away form oxidising agents and strongly alkaline or acid materials. The store room should be marked ‘Flashpoint below 32 ºC’ in accordance with ‘The Highly Flammable Liquids and Liquefied Petroleum Gases Regulations 1972 S.I. No 917 (1972) Sections 5 and 6. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Measures Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. If extraction methods are insufficient to maintain concentrations of particulates and/or solvent vapours below OEL’s, suitable respiratory protective equipment should be worn. cont’d 9804/9024 ISSUE 1, JANUARY 2002 Substance Name % Conc Splashes in the eyes may cause irritation and reversible local damage. Repeated or prolonged contact with the product may lead to removal of natural fats from the skin resulting in non-allergic contact dermatitis and absorption through the skin. Splashes in the eye may cause irritation and reversible local damage. HIGHER AROMATICS R36/37/38 Irritating to eyes, respiratory system and skin R37/38 Irritating to respiratory system and skin R41 Risk of serious damage to eyes R65 Harmful: may cause lung damage if swallowed R67 Date of last revision 12/02/97 The information in this safety data sheet is provided in accordance with the requirements of the Chemicals (Hazard Information and Packaging) Regulations. The product should not be used for purposes other than those shown in Section 1 without first referring to the supplier and obtaining written handling instructions. As the specific conditions of use are outside the supplier’s control, the user is responsible for ensuring that the requirements of relevant legislation are complied with. TP-02 The information contained in this Safety Data Sheet is based on the present state of knowledge and current national legislation. It provides guidance on health, safety and environmental aspects of the product and should not be construed as any guarantee of technical performance or suitability for particular applications. Further information and relevant advice can be found in:- The Control of Substances Hazardous to Health Regulations 1994 (SI 1994 : 3246) Manual Handling Operations Regulations 1992 (SI 1992 : 2793) Storage of Flammable Liquids in Containers, HS(G)51 Storage of Packaged Dangerous Substances, HS(G)71 The Environmental Protection (Duty of Care) Regulations 1992 (SI 1988: 2839) Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 9804/9026 ISSUE 1, JANUARY 2002 INGREDIENT NAME CAS No. HEALTH RISK (class) (R No.) XYLENE 1330-20-7 5-10 % Xn 20/21, 38 MESITYLENE 108-67-8 0-1 % Xi, N 37, 51/53 1,2,4-TRIMETHYLBENZENE 95-63-6 0-1 % Xn, N 20, 36/37/38, 51/53 SOLVENT NAPTHA(PETROLEUM)L/AROMATIC 64742-95-6 1-5 % Xi, Xn 37, 65, 51/53 2-METHOXY-1-METHYLETHYL ACETATE 108-65-6 1-5 % Xi 36 1-METHOXY-2-PROPANOL 107-98-2 5-10 % 2-BUTOXYETHANOL 111-76-2 1-5 % Xn 20/21/22, 37 BUTYL ACETATE 123-86-4 10-30 % NC 66, 67 4-HYDROXY-4-METHYLPENTAN-2-ONE 123-42-2 1-5 % Xi 36 DIMETHYL ETHER 115-10-6 30-60 % Extremely flammable 4. FIRST-AID MEASURES Inhalation: Move the exposed person to fresh air at once. Get medical attention if any discomfort continues. For breathing difficulties oxygen may be necessary. Ingestion: Ingestion is an unlikely event, but should this occur seek medical advice. cont’d 9804/9026 ISSUE 1, JANUARY 2002 Skin: Wash the skin immediately with soap and water. Get medical attention if any discomfort continues. Eyes: Spray in the eyes: Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues. 5. FIRE-FIGHTING MEASURES Extinguishing Media: Use: Powder. Dry chemicals, sand, dolomite etc. Water spray, fog or mist. Special Fire Fighting Procedures: Containers close to fire should be removed or cooled with water. Use water to keep fire exposed containers cool and disperse vapours. Unusual Fire and Explosion Hazards: Aerosol cans may explode in fires. Risk of explosion if heated. 6. ACCIDENTAL RELEASE MEASURES Spill Clean-up Methods: Extinguish all ignition sources. Avoid sparks, flames, heat and smoking. Ventilate. Wear necessary protective equipment. If leakage cannot be stopped, evacuate area. Ventilate well. Larger spill: Do not contaminate water sources or sewer. 7. HANDLING AND STORAGE Usage Precautions: Keep away from heat, sparks and open flame. Read and follow manufacturer's recommendations. Provide good ventilation. Protective Equipment: Use suitable goggles and gloves. Ventilation: Provide adequate general and local exhaust ventilation. Respirators: No specific recommendation made, but respiratory protection must be used if the general level exceeds the Occupational Exposure Level (OEL). Protective Gloves: For prolonged or repeated skin contact use suitable protective gloves. Eye Protection: Wear approved chemical safety goggles where eye exposure is reasonably probable. Other Protection: Wear appropriate clothing to prevent any possibility of liquid contact and repeated or prolonged vapour contact. Hygienic Work Routines: DO NOT SMOKE IN WORK AREA! Wash at the end of each work shift and before eating, smoking and using the toilet. Promptly remove any clothing that becomes contaminated. No eating or drinking while working with this material. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Aerosol Odour/Taste: Organic solvents Solubility Description: Insoluble in water. Flammability Limit (upper %): 18.6 Colour: Silver Flammability Limit (lower %): 1.1 10. STABILITY AND REACTIVITY Stability: Normally stable. Conditions to Avoid: Avoid heat, flames and other sources of ignition. Avoid contact with: Strong oxidising agents. Strong alkalis. Strong mineral acids. Hazardous Decomposition Products: Fire creates Vapours/gases/fumes of Carbon monoxide (CO). Carbon dioxide (CO2) Eyes: Spray and vapour in the eyes may cause irritation and smarting. May cause severe irritation to eyes. Substance Weight in Skin contact Remove contaminated clothing. Wash skin thoroughly with soap and water, or use a proprietary skin cleanser. Do NOT use solvents or thinners. Ingestion If accidentally swallowed obtain immediate medical attention. Keep at rest. Do NOT induce vomiting. 5. FIRE-FIGHTING MEASURES Extinguishing Media Use alcohol resistant foam, carbon dioxide, dry powder or water spray/mist. Do NOT use water jet. Recommendations Fire will produce dense black smoke containing hazardous products of combustion (see Section 10). Exposure to decomposition products may be a hazard to health. Appropriate self-contained breathing apparatus may be required. Cool closed containers exposed to fire with water spray. Do not allow run-off from fire-fighting to enter drains or water courses. 6. ACCIDENTAL RELEASE MEASURES Exclude sources of ignition and ventilate the area. Exclude non-essential personnel. Avoid breathing vapours. Refer to protective measures listed in Sections 7 and 8. Contain and collect spillage with non-combustible absorbent materials, e.g. sand, earth, vermiculite, diatomaceous earth and place in a suitable container. The contaminated area should be cleaned up immediately with a suitable decontaminant. One possible (flammable) decontaminant comprises water (45 parts by volume)/ ethanol or isopropanol (50 parts)/ concentrated (d 0.880) ammonia solution (5 parts). A non- flammable alternative is sodium carbonate (5 parts)/ water (95 parts). Add the same decontaminant to any residues and allow to stand for several days in a non-sealed container until no further reaction occurs. Once this stage is reached, close the container and dispose of in accordance with the waste regulations (see Section 13). Do not allow to enter drains or water courses. Clean preferably with a detergent; avoid the use of solvents. If the product enters drains or sewers the local water company should be contacted immediately; in the case of contamination of streams, rivers or lakes the relevant environment agency. 7. HANDLING AND STORAGE Handling Persons with a history of asthma, allergies or chronic or recurrent respiratory disease should only be employed in processes in which this product is used under appropriate medical supervision. Persons with a history of skin sensitisation problems should only be employed in processes in which this product is used under appropriate medical supervision. Persons with chronic eczema should not be engaged in any process which involves the use of paints containing isocyanates. For colours containing lead chromate (listed in Section 1), avoid the inhalation of dusts, particulates and spray mists arising from the use of these products. Vapours are heavier than air and may spread along floors. They may form explosive mixtures with air. Prevent the creation of flammable or explosive concentrations of vapour in air and avoid concentrations higher than the occupational exposure limits. Additionally the product should only be used in areas from which all naked lights and other sources of ignition have been excluded. Electrical equipment should be protected to the appropriate standard. Keep the container tightly closed. Exclude sources of heat, sparks and open flame. Non-sparking tools should be used. Required air quantity to 99 m³/ltr ventilate to 10% of the LEL. cont’d 9804/9027 ISSUE 1, JANUARY 2002 The above figure is given as a guide only. Ventilation and extraction must be arranged so that all parts of the workplace are properly ventilated i.e. there are no recesses or pockets where high vapour concentrations are allowed to build up. If there is any doubt about the adequacy of the ventilation/extraction of solvent vapour, regular monitoring of confined workplaces should be carried out. Avoid skin and eye contact. Avoid inhalation of vapour and spray mist. Smoking, eating and drinking should be prohibited in areas of storage and use. For personal protection, see Section 8. Never use pressure to empty; the container is not a pressure vessel. The accumulation of contaminated rags and dry overspray, particularly in spray booth filters, may result in spontaneous combustion. Good housekeeping standards, regular safe removal of waste materials and regular maintenance of spray booth filters will minimise the risks of spontaneous combustion and other fire hazards. Precautions should be taken to minimise the exposure to atmospheric humidity or water as carbon dioxide may be formed which, in closed containers can result in pressurisation. Care should be taken when re-opening partly used containers. The Manual Handling Regulations may apply to the handling of containers/packages of this product. The following guide weight indicators are given to enable users to carry out assessments. Package Base Additive Composite 5 litre can 5.2 - 6.4 kg 1.1 kg 6.3 - 7.5 kg Occupational Exposure Limits Substance 8 hr TWA¹ 15 min STEL² Notes 1-methoxypropyl acetate 50ppm(OES) 150ppm(OES) Ethylbenzene 100ppm(OES) 125ppm(OES) Isocyanates 0.02mg/m³(MEL) 0.07mg/m³(MEL) Lead Chromates 0.15mg/m³(MEL) Trimethylbenzenes 25ppm(OES) Xylene (mixture of isomers) 100ppm(OES) 150ppm(OES) Sk³ ¹ Long term exposure limit - 8 hour time weighted average ² Short term exposure limit - 15 minute reference period ³ There is a risk of absorption through unbroken skin OES Occupational exposure standard MEL Maximum exposure limit Further guidance on OES/MEL and the assessment of occupational exposure to harmful materials, including mixed exposures, is given in HSE Guidance Note EH40. Personal Protection All personal protective equipment, including respiratory protective equipment, used to control exposure to hazardous substances must be selected to meet requirements of the COSHH Regulations. Respiratory Protection Air-fed respiratory protective equipment should be worn when this product is sprayed. This should be in addition to other measures taken to reduce the exposure (e.g. in booth design and operation and process modifications). Non-essential and unprotected people should be excluded from the area if exposure is possible. When operators, whether spraying or not, have to work inside the spray booth, they should wear an air-fed respirator during the spraying process and until such time as the spray mist has cleared. To avoid the inhalation of dusts, operators should wear air line breathing apparatus when removing dry booth filters or removing or disposing of dry overspray deposits. Dry-sanding, flame cutting and/or welding of the dry paint film will give rise to dust and/or hazardous fumes. Wet sanding should be used wherever possible. If exposure cannot be avoided by the provision of local exhaust ventilation, suitable respiratory protective equipment should be used. Under cool, dry conditions, it is possible for the isocyanate to remain unreacted in the paint film for up to 30 hours after application. If dry flatting is unavoidable, air-fed respiratory protective equipment should be used. Hand Protection When skin exposure may occur, advice should be sought from glove suppliers on appropriate types. Barrier creams may help to protect exposed areas of skin but are not substitutes for full physical protection. They should not be applied once exposure has occurred. Eye Protection Eye protection designed to protect against liquid splashes should be worn. Skin Protection Cotton or cotton/synthetic overalls or coveralls are normally suitable. Grossly contaminated clothing should be removed and the skin washed with soap and water or a proprietary skin cleanser. 9. PHYSICAL AND CHEMICAL PROPERTIES The figures given below, unless otherwise stated, refer to the composite material. Physical State: Viscous liquid Odour: Characteristic odour Colour: Various Density: 1.3 g/cm³ cont’d 9804/9027 ISSUE 1, JANUARY 2002 Viscosity - base: 2.4 - 3.6 poise BS3900:Part A7 at 25°C Viscosity - additive: 47 - 57 seconds B2 cup at 20°C Flash Point - base: 26°C Flash Point - additive: 33°C Volatile Organic Content: 455 g/ltr Explosion Limit - lower: 1.0% Water Solubility: Immiscible 10. STABILITY AND REACTIVITY Stable under the recommended storage and handling conditions (see Section 7). In a fire, hazardous decomposition products such as smoke, carbon monoxide, carbon dioxide, oxides of nitrogen, hydrogen cyanide, amines and alcohols may be produced. Keep away from oxidising agents and strongly alkaline and strongly acidic materials. Uncontrolled exothermic reactions occur with amines and alcohols. The product reacts slowly with water resulting in evolution of carbon dioxide. In closed containers, pressure build up could result in distorting, blowing and in extreme cases bursting the container. Base (for colours containing lead chromate): Xylene (mixture of isomers) Lead Chromates TOXIC Contains lead. Should not be used on surfaces that are liable to be chewed or sucked by children Restricted to professional users. Flammable Danger of cumulative effects. Possible risk of irreversible effects May cause harm to the unborn child Possible risk of impaired fertility When using do not eat, drink or smoke Do not breathe vapour/spray. During spraying wear air-fed respiratory protective equipment. Additive: Aliphatic polyisocyanate HARMFUL Contains isocyanates. See information supplied by the manufacturer. Flammable Harmful by inhalation. May cause sensitisation by skin contact. Do not breathe vapour/spray. Wear suitable protective clothing and gloves In case of insufficient ventilation, wear suitable respiratory equipment. The information contained in this data sheet does not constitute the user's own assessment of workplace risks as required by other health and safety legislation. The provisions of the Health and Safety at Work etc. Act and the Control of Substances Hazardous to Health Regulations apply to the use of this product at work. R62 Possible risk of impaired fertility R65 Harmful: may cause lung damage if swallowed Full details of the hazard classifications are as follows:- Carc. Cat. 3 Carcinogenic Category 3 Repr. Cat. 1 Toxic for Reproduction Category 1 Repr. Cat. 3 Toxic for Reproduction Category 3 Further information about the hazard classification can be found in the Approved Guide to the Classification and Labelling of Substances and Preparations Dangerous for Supply. The information in this data sheet is provided in accordance with the requirements of the Chemicals (Hazard Information and Packaging for Supply) Regulations 1994. The product should not be used for purposes other than those shown in Section 1 without first referring to the supplier and obtaining written handling instructions. As the specific conditions of use are outside the supplier's control, the user is responsible for ensuring the requirements of relevant legislation are complied with. The information contained in this data sheet is based on the present state of knowledge and current national legislation. It provides guidance on health, safety and environmental aspects of the product and should not be construed as any guarantee of technical performance or suitability for particular applications. Further information and relevant advice can be found in: The Chemical (Hazard Information and Packaging for Supply) Regulations 1994 (SI 1994:3247) and amendments. Highly Flammable Liquids and Liquefied Petroleum Gases Regulations 1972 (SI 1972:917) Control of Lead at Work Regulations 1998 (SI 1998:543) Control of Substances Hazardous to Health Regulations 1999 (SI 1999:437) Manual Handling Operations Regulations 1992 (SI 1992:2793) Environmental Protection (Duty of Care) Regulations 1992 (SI 1992:2839) Isocyanates: health hazards and precautionary measures, EH16 Occupational Exposure Limits, EH40 (revised annually) Your Health and 2-pack Spray Paints, MS(B)8 Surveillance of People Exposed to Health Risks at Work (ISBN 0 11 8855743) The storage of flammable liquids in containers, HS(G)51 Chemical warehousing: the storage of packaged dangerous substances , HS(G)71 The Approved Guide to the Classification and Labelling of Substances and Preparations Dangerous for Supply (Fourth Edition), L100 The Approved Supply List, L124 The Approved Code of Practice: Safety Data Sheets for Substances and Preparations Dangerous for Supply, L62 Special Waste Regulations 1996 (SI 1996:972) and amendments Breathe Freely, IND(G)172 Respiratory Sensitisers and COSHH - a guide for employers, IND(G)95 The interpretation and use of flashpoint information, CS24 COSHH Essentials: easy steps to control chemicals, HS(G)193. Details of available Control Guidance Sheets, which may be relevant to the particular conditions of use, can also be found in HS(G)193. Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 9804/9030 ISSUE1, JANUARY 2002 Yellow Gloss (1 litre) Intended use: Stoving paint/lacquer for industrial use only. Application by spray when mixed with recommended thinner. Supplier: Emergency Contact : Emergency Telephone No.: +44 (0) 1889 590312 2. COMPOSITION/INFORMATION ON INGREDIENTS A mixture of resins, pigments, mineral extenders and organic solvents as required. For details of substances presenting a health hazard within the meaning of the Chemicals (Hazard Information & Packing) regulations 1994 see under Section 8 of this Safety Data Sheet. Inhalation of vapours from this product can cause narcosis and, with continued exposure above the OEL, possible long term effects. Flammable Danger of cumulative effects - Irritating to eyes, respiratory system and skin. Harmful Possible risk of irreversible effects through inhalation, in contact with skin and may cause lung damage if swallowed. 4. FIRST-AID MEASURES General In all cases of doubt or when symptoms persist seek medical attention. Never give anything by mouth to an unconscious person. cont’d 9804/9030 ISSUE1, JANUARY 2002 Inhalation: Remove to fresh air, keep warm and at rest. If breathing is irregular or stopped give artificial respiration. Give nothing by mouth. If unconscious place in recovery position and seek medical advice. Eye Contact: Contact lenses should be removed. Irrigate copiously with clean, fresh water for at least 10 mins. holding the eyelids apart, seek medical advice. Skin Contact: Remove contaminated clothing. Wash skin thoroughly with soap and water or use a proprietary skin cleaner. Do NOT use solvents or thinners. Ingestion: If accidentally swallowed obtain immediate medical attention. Keep at rest. Do NOT induce vomiting. 5. FIRE-FIGHTING MEASURES Extinguishing Media: Carbon dioxide, Dry Powder, Halogenated Hydrocarbons, Sand, Foam. NOT TO BE USED - Water Special Instructions for Fire Fighting Personnel Fire will produce dense black smoke containing hazardous products of combustion (see Section 10). Decomposition products may be a hazard to health. Appropriate self-contained breathing apparatus may be required. Cool closed containers exposed to fire with a water spray. Do not allow run off from fire fighting to enter drains or water courses. 6. ACCIDENTAL RELEASE MEASURES Exclude sources of ignition and ventilate the area. Exclude non-essential personnel. Avoid breathing vapours. Refer to protective measures listed in sect. 7 & 8. Contain and collect spillages with non-combustible absorbent materials e.g. sand, earth and place in suitable container for disposal in accordance with the waste regulations. Do not allow to enter drains or water courses. If it does the local water company should be contacted immediately, in case of contamination of streams, rivers or lakes the Environment Agency. Clean preferably with a detergent, avoid use of solvents. 7. STORAGE AND HANDLING Vapours are heavier than air and may spread along floors. They may form explosive mixtures with air. Prevent creation of explosive or flammable mixtures and avoid vapour concs higher than the OEL. Do not use in areas where potential sources of ignition exist. Electrical equipment should be protected to the appropriate standard. Use non sparking tools and exclude sources of heat, sparks and flames. Keep container tightly closed. Never use pressure to empty, container is not a pressure vessel. Always keep in containers made of the same material as the supply container. Avoid skin and eye contact. For personal protection see Section 8. Good housekeeping, regular maintenance of spray booth filters, and regular removal of waste materials will minimise risks. The product may charge electrostatically, Use earthing leads when transferring from one container to another. Wear anti-static footwear and clothing and floors should be electrically conductive. The accumulation of contaminated rags and dry overspray, particularly in spray booth filters may result in spontaneous combustion. Store in accordance with the HSE Guidance note ‘Storage of Flammable Liquids in Containers’ HS(G)51. Observe the label precautions. Store between 5 and 25 ºC in a dry well ventilated place away from sources of heat, ignition and direct sunlight. No smoking. Prevent unauthorised access. Containers which are opened should be properly resealed and kept upright to prevent leakage. Store away from oxidising agents and strongly alkaline or acid materials. The store room should be marked ‘Flashpoint below 32 ºC in accordance with ‘The Highly Flammable Liquids and Liquefied Petroleum Gases Regulations 1972 S.I. No. 917 (1972) Sections 5 and 6. 9804/9030 ISSUE1, JANUARY 2002 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Measures Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. If extraction methods are insufficient to maintain concentrations of particulates and /or solvent vapours below relevant OEL’s, suitable respiratory protective equipment should be worn. Substance Name % Conc XYLENE, MIXTURE OF ISOMERS SOLVESSO100/AROMATIC 100/SHELLSOLA/AROMASOLN LEAD CHROMATE Lead. Should not be used on surfaces that are liable to be chewed or sucked by children. FOR USE IN INDUSTRIAL INSTALLATIONS ONLY The information contained in this Safety Data Sheet does not constitute the user’s own assessment of the workplace risks as required by other health and safety legislation. The provisions of the Health and Safety at Work etc. Act and the Control of Substances Hazardous to Health Regulations apply to the use of this product at work. SOLVESSO100/AROMATIC 100/SHELLSOLA/AROMASOLN XYLENE, MIXTURE OF ISOMERS Substance Weight in 6. ACCIDENTAL RELEASE MEASURES Exclude sources of ignition and ventilate the area. Exclude non-essential personnel. Avoid breathing vapours. Refer to protective measures listed in sections 7 and 8. Contain and collect spillages with non-combustible absorbent materials e.g. sand, earth, vermiculite, diatomaceous earth and place in a suitable container for disposal in accordance with the waste regulations (see Section 13). Do not allow to enter drains or water courses. Clean preferably with a detergent; avoid the use of solvents. If the product enters drains or sewers, the local water company should be contacted immediately; in the case of contamination of streams, rivers or lakes, the relevant environment agency. 7. HANDLING AND STORAGE Handling Vapours are heavier than air and may spread along floors. They may form explosive mixtures with air. Prevent the creation of flammable or explosive concentrations of vapour in air and avoid concentrations higher than the occupational exposure limits. Additionally the product should only be used in areas from which all naked lights and other sources of ignition have been excluded. Electrical equipment should be protected to the appropriate standard. Keep the container tightly closed. Exclude sources of heat, sparks and open flame. Non-sparking tools should be used. Required air quantity to 130 m³/ltr ventilate to 10% of the LEL. The above figure is given as a guide only. Ventilation and extraction must be arranged so that all parts of the workplace are properly ventilated i.e. there are no recesses or pockets where high vapour concentrations are allowed to build up. If there is any doubt about the adequacy of the ventilation/extraction of solvent vapour, regular monitoring of confined workplaces should be carried out. Avoid skin and eye contact. Avoid inhalation of vapour and spray mist. Smoking, eating and drinking should be prohibited in areas of storage and use. For personal protection, see Section 8. Never use pressure to empty; the container is not a pressure vessel. The accumulation of contaminated rags and dry overspray, particularly in spray booth filters, may result in spontaneous combustion. Good housekeeping standards, regular safe removal of waste materials and regular maintenance of spray booth filters will minimise the risks of spontaneous combustion and other fire hazards. The Manual Handling Regulations may apply to the handling of containers/packages of this product. The following guide weight indicators are given to enable users to carry out assessments. Package Base Additive Composite 20 litre pail 24.0 kg 4.4 kg 28.4 kg 5 litre can 6.0 kg 1.1 kg 7.1 kg The principles contained in the HSE guidance note Storage of Packaged Dangerous Substances should be observed when storing this product. Store separately from oxidising agents and strongly alkaline and strongly acidic materials, 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Measures Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulates and/or solvent vapours below the relevant occupational exposure limits, suitable respiratory protective equipment should be worn (see ‘Personal Protection’ below). Exposure Limits Occupational Exposure Standards and/or Maximum Exposure Limits have been established by the Health and Safety Commission or recommended by the supplier for certain of the ingredients. OELs are taken from the current version of EH40 except those marked 'Sup', which are assigned by the supplier of the substance. Occupational Exposure Limits Substance 8 hr TWA¹ 15 min STEL² Notes 1-methoxypropan-2-ol 100ppm(OES) 300ppm(OES) Sk³ Trimethylbenzenes 25ppm(OES) Xylene (mixture of isomers) 100ppm(OES) 150ppm(OES) Sk³ ¹ Long term exposure limit - 8 hour time weighted average ² Short term exposure limit - 15 minute reference period ³ There is a risk of absorption through unbroken skin OES Occupational exposure standard Further guidance on OES/MEL and the assessment of occupational exposure to harmful materials, including mixed exposures, is given in HSE Guidance Note EH40. Personal Protection All personal protective equipment, including respiratory protective equipment, used to control exposure to hazardous substances must be selected to meet requirements of the COSHH Regulations. Respiratory Protection Air-fed respiratory protective equipment should be worn when this product is sprayed if the exposure of the sprayer or other people nearby cannot be controlled to below the Occupational Exposure limits and engineering controls and methods cannot reasonably be improved. To avoid the inhalation of dusts, operators should wear air line breathing apparatus when removing dry booth filters or removing or disposing of dry paint overspray deposits. Dry-sanding, flame cutting and/or welding of the dry paint film will give rise to dust and/or hazardous fumes. Wet sanding should be used wherever possible. If exposure cannot be avoided by the provision of local exhaust ventilation, suitable respiratory protective equipment should be used. Hand Protection When skin exposure may occur, advice should be sought from glove suppliers on appropriate types. Barrier creams may help to protect exposed areas of skin but are not substitutes for full physical protection. They should not be applied once exposure has occurred. Eye Protection Eye protection designed to protect against liquid splashes should be worn. Skin Protection Cotton or cotton/synthetic overalls or coveralls are normally suitable. Grossly contaminated clothing should be removed and the skin washed with soap and water or a proprietary skin cleanser. 9804/9033 ISSUE 1, JANUARY 2002 9. PHYSICAL AND CHEMICAL PROPERTIES The figures given below, unless otherwise stated, refer to the composite material. Physical State: Viscous liquid Odour: Characteristic odour Colour: Black Density: 1.2 g/cm³ Viscosity - base: 2.0 - 2.6 poise BS3900:Part A7 at 25°C Viscosity - additive: 40 - 50 seconds B2 cup at 20°C Flash Point - base: 25°C Flash Point - additive: 34°C Volatile Organic Content: 597 g/ltr Explosion Limit - lower: 1.0% Water Solubility: Immiscible 10. STABILITY AND REACTIVITY Stable under the recommended storage and handling conditions (see Section 7). In a fire, hazardous decomposition products such as smoke, carbon monoxide, carbon dioxide, oxides of nitrogen, hydrogen cyanide, amines and alcohols may be produced. Keep away from oxidising agents and strongly alkaline and strongly acidic materials to prevent the possibility of exothermic reaction. Using information provided in this data sheet, advice should be obtained from the relevant environment agency whether the special waste regulations apply. 14. TRANSPORT INFORMATION Transport within the user's premises Always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. Substance Weight in Base (for colours containing lead chromate): R10 Flammable Xn R20/21 Harmful by inhalation and in contact with skin. R33 Danger of cumulative effects. Carc. Cat. 3 R40 Possible risk of irreversible effects Repr. Cat. 1 R61 May cause harm to the unborn child Repr. Cat. 3 R62 Possible risk of impaired fertility Additive: R10 Flammable Xn R40 Possible risk of irreversible effects 4. FIRST-AID MEASURES In all cases of doubt, or where symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. Inhalation Remove to fresh air, keep patient warm and at rest. If breathing has stopped, administer artificial respiration. Give nothing by mouth. If unconscious, place in the recovery position and seek medical advice. Eye contact Contact lenses should be removed. Irrigate copiously with clean, fresh water for at least 10 minutes, holding the eyelids apart and seek medical advice. Skin contact Remove contaminated clothing. Wash skin thoroughly with soap and water, or use a proprietary skin cleanser. Do NOT use solvents or thinners. Ingestion If accidentally swallowed obtain immediate medical attention. Keep at rest. Do NOT induce vomiting. 5. FIRE-FIGHTING MEASURES Extinguishing Media Use alcohol resistant foam, carbon dioxide, dry powder or water spray/mist. Do NOT use water jet. Recommendations Fire will produce dense black smoke containing hazardous products of combustion (see Section 10). Exposure to decomposition products may be a hazard to health. Appropriate self-contained breathing apparatus may be required. Cool closed containers exposed to fire with water spray. Do not allow run-off from fire-fighting to enter drains or water courses. 6. ACCIDENTAL RELEASE MEASURES Exclude sources of ignition and ventilate the area. Exclude non-essential personnel. Avoid breathing vapours. Refer to protective measures listed in sections 7 and 8. Contain and collect spillages with non-combustible absorbent materials e.g. sand, earth, vermiculite, diatomaceous earth and place in a suitable container for disposal in accordance with the waste regulations (see Section 13). Do not allow to enter drains or water courses. Clean preferably with a detergent; avoid the use of solvents. If the product enters drains or sewers, the local water company should be contacted immediately; in the case of contamination of streams, rivers or lakes, the relevant environment agency. 7. HANDLING AND STORAGE Handling For colours containing lead chromate (listed in Section 1), avoid the inhalation of dusts, particulates and spray mists arising from the use of these products. cont’d 9804/9034 ISSUE 1, JANUARY 2002 Vapours are heavier than air and may spread along floors. They may form explosive mixtures with air. Prevent the creation of flammable or explosive concentrations of vapour in air and avoid concentrations higher than the occupational exposure limits. Additionally the product should only be used in areas from which all naked lights and other sources of ignition have been excluded. Electrical equipment should be protected to the appropriate standard. Keep the container tightly closed. Exclude sources of heat, sparks and open flame. Non-sparking tools should be used. Required air quantity to 134 m³/ltr ventilate to 10% of the LEL. The above figure is given as a guide only. Ventilation and extraction must be arranged so that all parts of the workplace are properly ventilated i.e. there are no recesses or pockets where high vapour concentrations are allowed to build up. If there is any doubt about the adequacy of the ventilation/extraction of solvent vapour, regular monitoring of confined workplaces should be carried out. Avoid skin and eye contact. Avoid inhalation of vapour and spray mist. Smoking, eating and drinking should be prohibited in areas of storage and use. For personal protection, see Section 8. Never use pressure to empty; the container is not a pressure vessel. The accumulation of contaminated rags and dry overspray, particularly in spray booth filters, may result in spontaneous combustion. Good housekeeping standards, regular safe removal of waste materials and regular maintenance of spray booth filters will minimise the risks of spontaneous combustion and other fire hazards. The Manual Handling Regulations may apply to the handling of containers/packages of this product. The following guide weight indicators are given to enable users to carry out assessments. Package Base Additive Composite 20 litre pail 17.6 - 20.8 kg 4.4 kg 22.0 - 25.2 kg 5 litre can 4.4 - 5.2 kg 1.1 kg 5.5 - 6.3 kg Exposure Limits Occupational Exposure Standards and/or Maximum Exposure Limits have been established by the Health and Safety Commission or recommended by the supplier for certain of the ingredients. OELs are taken from the current version of EH40 except those marked 'Sup', which are assigned by the supplier of the substance. Occupational Exposure Limits Substance 8 hr TWA¹ 15 min STEL² Notes 1-methoxypropan-2-ol 100ppm(OES) 300ppm(OES) Sk³ Lead Chromates 0.15mg/m³(MEL) Trimethylbenzenes 25ppm(OES) Xylene (mixture of isomers) 100ppm(OES) 150ppm(OES) Sk³ ¹ Long term exposure limit - 8 hour time weighted average ² Short term exposure limit - 15 minute reference period ³ There is a risk of absorption through unbroken skin OES Occupational exposure standard MEL Maximum exposure limit Further guidance on OES/MEL and the assessment of occupational exposure to harmful materials, including mixed exposures, is given in HSE Guidance Note EH40. Personal Protection All personal protective equipment, including respiratory protective equipment, used to control exposure to hazardous substances must be selected to meet requirements of the COSHH Regulations. Respiratory Protection Air-fed respiratory protective equipment should be worn when this product is sprayed if the exposure of the sprayer or other people nearby cannot be controlled to below the Occupational Exposure limits and engineering controls and methods cannot reasonably be improved. When spraying colours containing lead chromate (listed in Section 1), air-fed respiratory protective equipment must be worn. This should be in addition to other measures taken to reduce exposure (e.g. in booth design and operation, and process modifications). Non-essential personnel and unprotected people should be excluded from the area if exposure is possible. To avoid the inhalation of dusts, operators should wear air line breathing apparatus when removing dry booth filters or removing or disposing of dry overspray deposits. Dry-sanding, flame cutting and/or welding of the dry paint film will give rise to dust and/or hazardous fumes. Wet sanding should be used wherever possible. If exposure cannot be avoided by the provision of local exhaust ventilation, suitable respiratory protective equipment should be used. Hand Protection When skin exposure may occur, advice should be sought from glove suppliers on appropriate types. Barrier creams may help to protect exposed areas of skin but are not substitutes for full physical protection. They should not be applied once exposure has occurred. Eye Protection Eye protection designed to protect against liquid splashes should be worn. Skin Protection Cotton or cotton/synthetic overalls or coveralls are normally suitable. Grossly contaminated clothing should be removed and the skin washed with soap and water or a proprietary skin cleanser. 9804/9034 ISSUE 1, JANUARY 2002 9. PHYSICAL AND CHEMICAL PROPERTIES The figures given below, unless otherwise stated, refer to the composite material. Physical State: Viscous liquid Odour: Characteristic odour Colour: Yellow Density: 1.1 g/cm³ Viscosity - base: 1.8 - 2.2 poise BS3900:Part A7 at 25°C Viscosity - additive: 34 - 40 seconds B2 cup at 20°C Flash Point - base: 27°C Flash Point - additive: 33°C Volatile Organic Content: 594 g/ltr Explosion Limit - lower: 1.0% Water Solubility: Immiscible 10. STABILITY AND REACTIVITY Stable under the recommended storage and handling conditions (see Section 7). In a fire, hazardous decomposition products such as smoke, carbon monoxide, carbon dioxide and oxides of nitrogen may be produced. Keep away from oxidising agents and strongly alkaline and strongly acidic materials to prevent the possibility of exothermic reaction. Base (for colours containing lead chromate): Xylene (mixture of isomers) Lead Chromates TOXIC Contains lead. Should not be used on surfaces that are liable to be chewed or sucked by children Restricted to professional users. Flammable Danger of cumulative effects. Possible risk of irreversible effects May cause harm to the unborn child Possible risk of impaired fertility When using do not eat, drink or smoke Do not breathe vapour/spray. During spraying wear air-fed respiratory protective equipment. Additive: Aliphatic polyepoxide HARMFUL Flammable Possible risk of irreversible effects When using do not eat, drink or smoke Do not breathe vapour/spray. In case of insufficient ventilation, wear suitable respiratory equipment. The information contained in this data sheet does not constitute the user's own assessment of workplace risks as required by other health and safety legislation. The provisions of the Health and Safety at Work etc. Act and the Control of Substances Hazardous to Health Regulations apply to the use of this product at work. Full details of the hazard classifications are as follows:- Carc. Cat. 3 Carcinogenic Category 3 Repr. Cat. 1 Toxic for Reproduction Category 1 Repr. Cat. 3 Toxic for Reproduction Category 3 Further information about the hazard classification can be found in the Approved Guide to the Classification and Labelling of Substances and Preparations Dangerous for Supply. The information in this data sheet is provided in accordance with the requirements of the Chemicals (Hazard Information and Packaging for Supply) Regulations 1994. The product should not be used for purposes other than those shown in Section 1 without first referring to the supplier and obtaining written handling instructions. As the specific conditions of use are outside the supplier's control, the user is responsible for ensuring the requirements of relevant legislation are complied with. The information contained in this data sheet is based on the present state of knowledge and current national legislation. It provides guidance on health, safety and environmental aspects of the product and should not be construed as any guarantee of technical performance or suitability for particular applications. Further information and relevant advice can be found in: The Chemical (Hazard Information and Packaging for Supply) Regulations 1994 (SI 1994:3247) and amendments. Highly Flammable Liquids and Liquefied Petroleum Gases Regulations 1972 (SI 1972:917) Control of Lead at Work Regulations 1998 (SI 1998:543) Control of Substances Hazardous to Health Regulations 1999 (SI 1999:437) Manual Handling Operations Regulations 1992 (SI 1992:2793) Environmental Protection (Duty of Care) Regulations 1992 (SI 1992:2839) Occupational Exposure Limits, EH40 (revised annually) The storage of flammable liquids in containers, HS(G)51 Chemical warehousing: the storage of packaged dangerous substances , HS(G)71 The Approved Guide to the Classification and Labelling of Substances and Preparations Dangerous for Supply (Fourth Edition), L100 The Approved Supply List, L124 The Approved Code of Practice: Safety Data Sheets for Substances and Preparations Dangerous for Supply, L62 Special Waste Regulations 1996 (SI 1996:972) and amendments The interpretation and use of flashpoint information, CS24 COSHH Essentials: easy steps to control chemicals, HS(G)193. Details of available Control Guidance Sheets, which may be relevant to the particular conditions of use, can also be found in HS(G)193. Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 9804/9025 ISSUE 1, MARCH 2002 Adhesive Chemical Family: Formulated Epoxy Resin Component Cas Number Concentration EEC Symbol/ Ranges Ingestion: Low order of toxicity. No hazard in normal industrial use. Hardener No European Danger category (67/548/EEC and amendments). Eye: Contact with eyes causes redness and discomfort which is transient. Skin Contact: Low order of toxicity. Inhalation: No hazard in normal industrial use. Ingestion: Low order of toxicity. No hazard in normal industrial use. 4. FIRST-AID MEASURES Adhesive Eye: Flush eyes with large amounts of water until irritation subsides. If irritation persists, get medical attention. Skin Contact: Flush with large amounts of water; use soap if available. If irritation persists, get medical attention. Inhalation: Remove to fresh air. Ingestion: If swallowed, DO NOT induce vomiting. Keep at rest. Get prompt medical attention. Hardener Eye: Flush eyes with plenty of clean water. Skin Contact: Wash with soap and water. Inhalation: Remove to fresh air. Ingestion: Treat symptomatically and supportively. Get medical attention. 5. FIRE-FIGHTING MEASURES Adhesive Autoflammability: - C Flash Point: >100 ºC Extinguishing Media: CO2; Dry chemical; Foam; Water fog Special Firefighting Measures: Fire fighters should be equipped with self-contained breathing apparatus to protect against potentially toxic and irritating fumes. Fire & Explosion Hazards: Combustion may release noxious or toxic vapours - see below. Hazardous Combustion Products: Carbon monoxide, carbon dioxide, unknown hydrocarbons. Upper Explosion Limit (%): Not applicable Lower Explosion Limit (%): Not applicable Hardener Autoflammability: Not applicable Flash Point: >100 ºC (Tagliabue Closed Tester/Tag Closed Tester) Extinguishing Media: CO2; Dry chemical; Foam; Water fog Special Firefighting Measures: Fire fighters should be equipped with self-contained breathing apparatus to protect against potentially toxic and irritating fumes. Fire & Explosion Hazards: Combustion may release noxious or toxic vapours - see below. Hazardous Combustion Products: Carbon monoxide, carbon dioxide, unknown hydrocarbons. Upper Explosion Limit (%): Not applicable Lower Explosion Limit (%): Not applicable 9804/9025 ISSUE 1, MARCH 2002 6. ACCIDENTAL RELEASE MEASURES Spill and Leak Procedures Take up with sand or other absorbent material and place in container for later disposal. For safety and environmental precautions, please review entire Safety Data Sheet for necessary information. 7. HANDLING AND STORAGE Vapour pressure (mmHg): Adhesive: - (-) Hardener: Not Applicable Vapour density (air=1): Not applicable Viscosity: Adhesive: 60000 mPa.s Hardener: 12000 mPa.s Volatiles: None Volatile organic compounds: <5 g/l Autoflammability: Adhesive: - C Hardener: Not Applicable Flash point: Adhesive: >100 ºC Hardener: >100 ºC (Tagliabue Closed Tester/Tag Closed Tester) Oxidising properties: Not applicable 10. STABILITY AND REACTIVITY Adhesive Stability: Stable Materials to avoid: Bases; Amines; Acids; Oxidizers Hazardous decomposition products: Carbon monoxide, carbon dioxide, unknown hydrocarbons Hardener Stability: Stable Hazardous decomposition products: Carbon monoxide, carbon dioxide, unknown hydrocarbons 13. DISPOSAL CONSIDERATIONS Waste disposal methods: Waste disposal should be in accordance with existing Community, National and local regulations. Empty container warnings: Empty containers may contain product residue; follow SDS and label warnings even after they have been emptied. 14. TRANSPORT INFORMATION ADR/RID: Adhesive: Not restricted Hardener: Not applicable CEFIC Tremcard number: Not applicable HAZCHEM code: Not applicable KEMMLER code: Not applicable IMDG Classification: Not restricted Hardener Due to its isocyanate content this material is dangerous in use. Flammable - May cause sensitisation by inhalation - Harmful by inhalation and may cause lung damage if swallowed - irritating to eyes, respiratory system and skin. 4. FIRST-AID MEASURES General In all cases of doubt or when symptoms persist seek medical attention. Never give anything by mouth to an unconscious person. Inhalation Remove to fresh air, keep warm and at rest. If breathing is irregular or stopped give artificial respiration. Give nothing by mouth. If unconscious place in recovery position and seek medical advice. Eye contact Contact lenses should be removed. Irrigate copiously with clean, fresh water for at least 10 minutes, holding the eyelids apart and seek medical advice. Skin contact Remove contaminated clothing. Wash skin thoroughly with soap and water, or use a proprietary skin cleanser. Do NOT use solvents or thinners. Ingestion If accidentally swallowed obtain immediate medical attention. Keep at rest. Do NOT induce vomiting. 5. FIRE-FIGHTING MEASURES Extinguishing Media Carbon dioxide, Dry Powder, Halogenated Hydrocarbons, Sand, Foam. DO NOT USE WATER Special Instructions for Fire Fighting Personnel Fire will produce dense black smoke containing hazardous products of combustion (see Section 10). Decomposition products may be a hazard to health. Appropriate self-contained breathing apparatus may be required. Cool closed containers exposed to fire with water spray. Do not allow run-off from fire-fighting to enter drains or water courses. 6. ACCIDENTAL RELEASE MEASURES Paint Exclude sources of ignition and ventilate the area. Exclude non-essential personnel. Avoid breathing vapours. Refer to protective measures listed in sections 7 and 8. Contain and collect spillages with non-combustible absorbent materials e.g. sand, earth and place in a suitable container for disposal in accordance with the waste regulations. Do not allow to enter drains or water courses. Clean preferably with a detergent; avoid the use of solvents. If it does the local water company should be contacted immediately, in case of contamination of streams, rivers or lakes, the Environmental Agency. Clean preferably with a detergent, avoid use of solvents. Hardener Exclude sources of ignition and ventilate the area. Exclude non-essential personnel. Avoid breathing vapours. Refer to protective measures listed in sections 7 and 8. Contain and collect spillages with non-combustible absorbent materials e.g. sand, earth and place in a suitable container for disposal in accordance with the waste regulations. The contaminated area should be cleaned up immediately with a suitable decontaminant which should be allowed to stand for several days in a non sealed container until no further reaction occurs. One possible (flammable) decontaminant is water (45%) ethanol or isoproponol (50%), conc. (d:0.880) ammonia soln (5%). Non-flammable alternative is sodium carbonate (5%), water (95%). All %’s by Vol. Do not allow to enter drains or water courses. If it does the local water company should be contacted immediately, in case of contamination of streams, rivers or lakes the Environmental Agency. 9804/9035 ISSUE 1, MARCH 2002 7. HANDLING AND STORAGE General Vapours are heavier than air and may spread along floors. They may form explosive mixtures with air. Prevent creation of explosive or flammable mixtures and avoid vapour concs higher than the OEL. Do not use in areas where potential sources of ignition exist. Electrical equipment should be protected to the appropriate standard. Use non sparking tools and exclude sources of heat, sparks and flames. Keep container tightly closed. Never use pressure to empty, container is not a pressure vessel. Always keep in containers made of the same material as the supply container. Avoid skin and eye contact. For personal protection see Section 8. Good housekeeping, regular maintenance of spray booth filters, and regular removal of waste materials will minimise risks. The product may change electrostatically. Use earthing leads when transferring from one container to another. Wear anti-static footwear and clothing. Floors should be electrically conductive. Paint Store in accordance with the HSE Guidance note ‘Storage of Flammable Liquids in Containers’ HS(G)51. Observe the label precautions. Store between 5 and 25 °C in a dry well ventilated place away from sources of heat, ignition and direct sunlight. No smoking. Prevent unauthorised access. Containers which are opened should be properly resealed and kept upright to prevent leakage. Store away form oxidising agents and strongly alkaline or acid materials. The store room should be marked ‘Flashpoint below 32 ‘C’ in accordance with ‘The Highly Flammable Liquids and Liquified Petroleum Gases Regulations 1972 S.I. No 917 (1972) Sections 5 and 6. Hardener Subject to the Highly Flammable Liquids & Liquified Petroleum Gases Regulations. Up to 50 lts may be kept in workroom in a fireproof cupboard or bin, otherwise must be kept in a separate room. Observe the label precautions. Store between 5 and 25 °C in a dry well ventilated place away from sources of heat, ignition and direct sunlight. No. smoking. Prevent unauthorised access. Containers which re opened should be properly resealed and kept upright to prevent leakage. Store away from oxidising agents and strongly alkaline or acid materials. The store room should marked ‘Flashpoint below 32 ‘C’ in accordance with ‘The Highly Flammable Liquids and Liquified Petroleum Gases Regulations 1972 S.I. No 917 (1972) Sections 5 and 6. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Paint Engineering Measures Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. If extraction methods are insufficient to maintain concentrations of particulates and/or solvent vapours below relevant OEL’s, suitable respiratory protective equipment should be worn. Substance Name % Conc Respiratory Protection Air fed respiratory equipment should be worn when spraying if levels cannot be controlled below OELs and engineering methods cannot be reasonably improved. Hand Protection Full physical protection is best. Seek relevant advice from glove manufacturers. Barrier cream may be of help but should not be applied after exposure has occurred. Eye Protection Eye protection designed to protect against liquid splashes should be worn. Skin Protection Cotton or cotton/synthetic overalls or coveralls are normally suitable. Grossly contaminated clothing should be removed and the skin washed with soap and water or a proprietary skin cleaner. Hardener Engineering Measures Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. If extraction methods are insufficient to maintain concentrations of particulates and/or solvent vapours below relevant OEL’s, suitable respiratory protective equipment should be worn. Spraying of isocyanate products should be carried out in suitable spray booth or enclosures with effective exhaust ventilation to prevent spray mist entering the work area outside of the booth. Respiratory protective equipment should be worn by spray booth operatives (see Personal Protection below) Substance Name % Conc Skin Protection Cotton or cotton/synthetic overalls or coveralls are normally suitable. Grossly contaminated clothing should be removed and the skin washed with soap and water or a proprietary skin cleaner. 9. PHYSICAL AND CHEMICAL PROPERTIES Paint Physical State: Liquid Flash Point: ≥ 21 ºC & < 32 ºC Method. Equilibrium Method to ISO 1516 & ISO 3680 Viscosity Specific Gravity: 1.297 gms/cc Method Calculation Vapour Density: HEAVIER than Air Lower Explosion Limit: .8% Vol. Solubility in Water: Partially Miscible Hardener Physical State: Free flowing liquid Flash Point: Viscosity Specific Gravity: .976 gms/cc Method Hydrometer Vapour Density: HEAVIER than Air Lower Explosion Limit: .8% Vol. Solubility in Water: Partially Miscible 10. STABILITY AND REACTIVITY Paint Stable under the recommended storage and handling conditions (see Section 7). In a fire, hazardous decomposition products such as smoke, carbon monoxide, carbon dioxide and oxides of nitrogen may be produced. Keep away from oxidising agents and strongly alkaline and acid materials to prevent the possibility of exothermic reaction. Hardener In a fire, hazardous decomposition products such as smoke, carbon dioxide, and oxides of nitrogen, hydrogen cyanide, amines and alcohols may be produced. In a fire, hazardous decomposition products such as smoke, carbon monoxide, carbon dioxide, and oxides of nitrogen may be produced. Keep away from oxidising agents and strongly alkaline and acid materials to prevent the possibility of an exothermic reaction. Uncontrolled exothermic reactions occur with amines and alcohols. The product reacts slowly with water evolving carbon dioxide. In closed containers, pressure builds and can result in distortion, blowing and in extreme cases bursting of the container. International Packing Group...III Class...3.3 Road/Rail Item Number...31C UN Number...1263 Main Risk...FLAMMABLE Sub Risk...NARCOSIS Shipping Name...PAINT RELATED PRODUCT 15. REGULATORY INFORMATION Paint XYLENE, MIXTURE OF ISOMERS, LEAD CHROMATE, BUTYL ACAETATE BUTYL ACAETATE, METHOXY PROPYL ACETATE/PROPYLENE GLYCOL MONO- METHYL ETHER ACETATE, ARCOSOLV, PMA, ALIPHATIC PLY-ISOCYANATE Inhalation: Remove to fresh air, keep patient warm and at rest. If breathing has stopped, administer artificial respiration. Give nothing by mouth. If unconscious, place in the recovery position and seek medical advice. Eye Contact: Contact lenses should be removed. Irrigate copiously with clean, fresh water for at least 10 minutes, holding the eyelids apart and seek medical advice. Skin Contact: Remove contaminated clothing. Wash skin thoroughly with soap and water, or use a proprietary skin cleanser. Do NOT use solvents or thinners. Ingestion: If accidentally swallowed obtain immediate medical attention. Keep at rest. Do NOT induce vomiting. 5. FIRE-FIGHTING MEASURES Extinguishing Media: Use alcohol resistant foam, carbon dioxide, dry powder or water spray/mist. Do NOT use water jet. Recommendations: Fire will produce dense black smoke containing hazardous products of combustion (see Section 10). Exposure to decomposition products may be a hazard to health. Appropriate self-contained breathing apparatus may be required. Cool closed containers exposed to fire with water spray. Do not allow run-off from fire-fighting to enter drains or water courses. 6. ACCIDENTAL RELEASE MEASURES Exclude sources of ignition and ventilate the area. Exclude non-essential personnel. Avoid breathing vapours. Refer to protective measures listed in sections 7 and 8. Contain and collect spillages with non-combustible absorbent materials e.g. sand, earth, vermiculite, diatomaceous earth and place in a suitable container for disposal in accordance with the waste regulations (see Section 13). Do not allow to enter drains or water courses. Clean preferably with a detergent; avoid the use of solvents. If the product enters drains or sewers, the local water company should be contacted immediately; in the case of contamination of streams, rivers or lakes, the relevant environment agency. 7. HANDLING AND STORAGE Handling Vapours are heavier than air and may spread along floors. They may form explosive mixtures with air. Prevent the creation of flammable or explosive concentrations of vapour in air and avoid concentrations higher than the occupational exposure limits. Additionally, the product should only be used in areas from which all naked lights and other sources of ignition have been excluded. Electrical equipment should be protected to the appropriate standard. Keep the container tightly closed. Exclude sources of heat, sparks and open flame. Non-sparking tools should be used. Required air quantity to 137 m3/ltr ventilate to 10% of the LEL The above figure is given as a guide only. Ventilation and extraction must be arranged so that all parts of the workplace are properly ventilated i.e. there are no recesses or pockets where high vapour concentrations are allowed to build up. If there is any doubt about the adequacy of the ventilation/extraction of solvent vapour, regular monitoring of confined workplaces should be carried out. Avoid skin and eye contact. Avoid inhalation of vapour and spray mist. Smoking, eating and drinking should be prohibited in areas of storage and use. For personal protection, see Section 8. Never use pressure to empty; the container is not a pressure vessel. cont’d 9804/9022 ISSUE 2 (REV), JUNE 2002 The accumulation of contaminated rags and dry overspray, particularly in spray booth filters, may result in spontaneous combustion. Good housekeeping standards, regular safe removal of waste materials and regular maintenance of spray booth filters will minimise the risks of spontaneous combustion and other fire hazards. The Manual Handling Regulations may apply to the handling of containers/packages of this product. The following guide weight indicators are given to enable users to carry out assessments. Package Weight 1 litre can 1.3 - 1.4 kg Hand Protection When skin exposure may occur, advice should be sought from glove suppliers on appropriate types. Barrier creams may help to protect exposed areas of skin but are not substitutes for full physical protection. They should not be applied once exposure has occurred. Eye Protection Eye protection designed to protect against liquid splashes should be worn. Skin Protection Cotton or cotton/synthetic overalls or coveralls are normally suitable. Grossly contaminated clothing should be removed and the skin washed with soap and water or a proprietary skin cleanser. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Viscous liquid Odour: Characteristic odour Colour: Grey Density: 1.1 g/cm3 Viscosity: 1.8 - 2.4 poise. BS3900: Part A7 at 25 °C Flash Point: 39 °C Volatile Organic Content: 467 g/ltr Explosion limit - lower: 0.6% Water Solubility: Immiscible 10. STABILITY AND REACTIVITY Stable under the recommended storage and handling conditions (see Section 7). In a fire, hazardous decomposition products such as smoke, carbon monoxide, carbon dioxide and oxides of nitrogen may be produced. Keep away from oxidising agents and strongly alkaline and strongly acidic materials to prevent the possibility of exothermic reaction. 13. DISPOSAL CONSIDERATIONS Do not allow into drains or water courses or dispose of where ground or surface waters may be affected. Wastes, including emptied containers, are controlled wastes and should be disposed of in accordance with regulations made under the Control of Pollution Act and the Environmental Protection Act. Using information provided in this data sheet, should be obtained from the relevant environment agency whether the special waste regulations apply. 14. TRANSPORT INFORMATION Transport within the user’s premises Always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of accident or spillage. The product should not be used for purposes other than those shown in Section 1 without first referring to the supplier and obtaining written handling instructions. As the specific conditions of use are outside the supplier’s control, the user is responsible for ensuring that the requirements of relevant legislation are complied with. The information contained in this data sheet is based on the present state of knowledge and current national legislation. It provides guidance on health, safety and environmental aspects of the product and should not be construed as any guarantee of technical performance or suitability for particular applications. Further information and relevant advice can be found in:- The Chemicals (Hazard Information and Packaging for Supply) Regulations 1994 (SI 1994 : 3247) and amendments. Control of Substances Hazardous to Health Regulations 1999 (SI 1999 : 437) Manual Handling Operations Regulations 1992 (SI 1992 : 2793) Environmental Protection (Duty of Care) Regulations 1992 (SI 1992 : 2839) Occupational Exposure Limits, EH40 (revised annually) The storage of flammable liquids in containers, HS(G)51 Chemical warehousing: the storage of packaged dangerous substances, HS(G)71 The Approved Guide to the Classification and Labelling of Substances and Preparations Dangerous for Supply (Fourth Edition), L100 The Approved Supply List, L124 The Approved Code of Practice: Safety Data Sheets for Substances and Preparations Dangerous for Supply, L62 Special Waste Regulations 1996 (SI 1996:972) and amendments. The interpretation and use of flashpoint information, CS24. COSHH Essentials: easy steps to control chemicals, HS(G)193. Details of available Control Guidance Sheets, which may be relevant to the particular conditions of use, can also be found in HS(G)193. Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 Leigh’s/JCB Thinners No. 5/27/03/2001 9804/9019 ISSUE 2 (REV), JUNE 2002 * JCB Grey Paint Description: A sheen finish supplied in an aerosol dispenser. Based on an alkyd resin system with inorganic pigments and containing white spirit and acetone solvents and aerosol propellant. Supplier: Emergency Contact : Emergency Telephone No.: +44 (0) 1889 590312 2. COMPOSITION/INFORMATION ON INGREDIENTS The following ingredients have recognised health effects or exposure limits, and are present in concentrations above the limits laid down in the Chemicals (Hazard Information and Packaging for Supply) Regulations 1994 (CHIP 2). Substance Weight in ambient temperature. Ingestion: Unlikely to be hazardous if swallowed. No hazard in normal industrial use. Physio-chemical: No unusual hazards are expected. Environmental: Toxic to aquatic organisms. Not readily biodegradeable. Hardener Eye: Contact with eye causes redness and discomfort which is transient. Skin Contact: Unlikely to be hazardous by skin absorption. Inhalation: Unlikely to be hazardous by inhalation. Ingestion: Unlikely to be hazardous if swallowed. No hazard in normal industrial use. Physio-chemical: No unusual hazards are expected. Environmental: Unknown. *4. FIRST-AID MEASURES Resin and Hardener Eye: Immediate medical attention is not required. Irrigate with eyewash solution or clean water until pain is relieved. If symptoms develop, obtain medical attention. Skin Contact: Immediate medical attention is not required. Wash skin with soap and water. If symptoms develop, obtain medical attention. Inhalation: Immediate medical attention is not required. Remove patient from exposure. Ingestion: Immediate medical attention is not required. Treat symptomatically and supportively. *5. FIRE-FIGHTING MEASURES Resin and Hardener Extinguishing Media: CO2; Dry chemical; Foam; Water fog Special Firefighting Procedures: Fire fighters should be equipped with self-contained breathing apparatus to protect against potentially toxic and irritating fumes. Fire & Explosion Hazards: Combustion may release noxious or toxic vapours - see below. Hazardous Combustion Products: Carbon monoxide, carbon dioxide, unknown hydrocarbons. Flash Point: >100 ºC *6. ACCIDENTAL RELEASE MEASURES Resin and Hardener Spill and Leak Procedures Absorb spillages onto sand, earth or any suitable absorbent material. Scrape up and place in suitably labelled container for disposal. For safety and environmental precautions, please review entire Safety Data Sheet for necessary information. *7. HANDLING AND STORAGE Resin and Hardener Handling/Storage: Store in cool, dry place. Sensitivity to Static Electricity: No Sensitivity to Mechanical Impact: No *8. EXPOSURE CONTROLS/PERSONAL PROTECTION 9804/9025 ISSUE 2, SEPTEMBER 2002 Resin Ventilation Requirements: General Eye Protection Requirements: Safety glasses, goggles or face shield to protect against splashing. Personal eye protection should conform to EN 166. Glove Requirements: Employee must wear appropriate protective gloves to prevent contact with this substance. Nitrile rubber or Viton TM gloves are recommened. Cotton or other absorbent gloves should not be worn. Gloves should conform to EN 374. Clothing Requirements: Employee must wear appropriate protective clothing and equipment to prevent any possibility of skin contact with this substance. Wash Requirements: Wash before eating, drinking, or using toilet facilities. Respiratory Requirements: None required under normal handling conditions. Hardener Ventilation Requirements: General Eye Protection Requirements: Safety glasses, goggles or face shield to protect against splashing. Personal eye protection should conform to EN 166. Glove Requirements: Nitrile rubber or Viton TM gloves are recommened. Cotton or other absorbent gloves should not be worn. Gloves should conform to EN 374. Clothing Requirements: Uniforms, coveralls, or a lab coat should be worn. Wash Requirements: Wash before eating, drinking, or using toilet facilities. Respiratory Requirements: None required under normal handling conditions. *9. PHYSICAL AND CHEMICAL PROPERTIES (Refers to both resin and hardener unless stated otherwise) Pure substance or preparation: Preparation Physical form: Liquid Appearance/Odour: Resin: Colourless; slight odour Hardener: Colourless; sweet odour Boiling point: Not applicable Solubility in water: Insoluble Viscosity: Resin: Approximately 60000 mPa.s Hardener: Approximately 12000 mPa.s Relative density: Resin: 1.2 Hardener: 1.13 Volatile organic compounds: <5 g/litre Flash point: >100 ºC *10. STABILITY AND REACTIVITY Resin Stability: Stable Materials to avoid: Bases; Amines; Acids; Oxidizers Hazardous decomposition products: Carbon monoxide, carbon dioxide, unknown hydrocarbons Hardener Stability: Stable Materials to avoid: Acids, Oxidizers Hazardous decomposition products: Carbon monoxide, carbon dioxide, unknown hydrocarbons Resin Eye: May cause eye irritation. Skin: Irritating to the skin. Repeated and/or prolonged contact may cause skin sensitisation. Inhalation: Unlikely to be hazardous by inhalation because of the low vapour pressure of the material at ambient temperature. Ingestion: Unlikely to be hazardous if swallowed. No hazard in normal industrial use. Chronic (long term) effects of exposure Effects of Chronic Exposure: The toxicological properties of this product have not been fully evaluated. Use of good industrial hygiene practices is required. Avoid direct contact with skin or eyes. Do not ingest or inhale. Target Organs: Skin Respiratory Sensitisation: No Cardiac Sensitisation: No Skin Sensitisation: Sensitiser Possible Birth Defect Hazard: No Carcinogen: No Hardener Eye: Contact with eyes causes redness and discomfort which is transient. Skin: Unlikely to be hazardous by skin absorption. Inhalation: Unlikely to be hazardous by inhalation. Ingestion: Unlikely to be hazardous if swallowed. No hazard in normal industrial use. Chronic (long term) effects of exposure Effects of Chronic Exposure: The toxicological properties of this product have not been fully evaluated. Use of good industrial hygiene practices is required. Avoid direct contact with skin or eyes. Do not ingest or inhale. Target Organs: None known Respiratory Sensitisation: No Cardiac Sensitisation: No Skin Sensitisation: No Possible Birth Defect Hazard: No Carcinogen: No Resin Epoxy Resin Epoxy Resin Epoxy Resin S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S37 - Wear suitable gloves. Epoxy resin Trimethylolpropanetriglycidyl ether. Special Phrases: Contains epoxy constituents. See information supplied by the manufacturer. EINECS: All components of this product are listed in EINECS or ELINCS, or are otherwise exempt from EU notification requirements. Hardener Special Phrases: Safety data sheet available for professional user on request. EINECS: All components of this product are listed in EINECS or ELINCS, or are otherwise exempt from EU notification requirements. Skin contact Wash skin thoroughly with soap and water. Obtain medical attention if blistering occurs or redness persists. Ingestion Do not induce vomiting. Obtain medical attention urgently. Inhalation Remove from exposure. Obtain medical attention. 5. FIRE-FIGHTING MEASURES Extinguishing Media Use foam, dry chemical or carbon dioxide. Special Hazards of Product May form explosive mixtures with air. Vapours can travel a considerable distance to a source of ignition and flashback. Thermal decomposition or burning may release oxides of carbon, nitrogen and other toxic gasses and vapours. Protective Equipment for Fire-Fighting Wear self-contained breathing apparatus. 6. ACCIDENTAL RELEASE MEASURES Personal Precautions Wear appropriate protective clothing. Eliminate all sources of ignition. Ventilate the area to dispel any residual vapours. Environmental Precautions and Clean-Up Methods Try to prevent material from entering drains or water courses. Spillages Contain and absorb using earth, sand or other inert material. Transfer into suitable containers for recovery or disposal. 7. HANDLING AND STORAGE Handling Exposure by inhalation or skin contact should be minimised by good industrial hygiene practices. Avoid inhaling vapour. Avoid contact with eyes, skin and clothing. Use in a well-ventilated area. Keep container tightly closed when not in use. Respiratory Protection Adequate ventilation should be provided to maintain solvent concentrations in the workplace below exposure limits. Respiratory protection if there is a risk of exposure to high vapour concentrations. Hand Protection Wear suitable impervious gloves (Butyl/nitrile type) Eye Protection Chemical goggles if there is a risk of splashing. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Colour: Black Odour: Ester pH: Not applicable Flash Point (ºC): -4 Explosion Limits (%): Lower limit 1.8 - for component with the lowest explosion limit. Solubility in Water: Insoluble (reacts). Density (kg/m3) Approximately 1000 at 20 ºC Autoignition Temperature (ºC) Above 450 Viscosity (at 20 ºC) 70 at 20 ºC (measured as mPa.s) 10. STABILITY AND REACTIVITY Stability Stable under normal conditions. Contains volatile solvent. Conditions to Avoid Sources of ignition. Exposure to direct sunlight. High temperatures. Hazardous Decomposition Products Combustion will generate: oxides of carbon, oxides of nitrogen, toxic nitrogen compounds. Persistence/Degradability The product is partially or slowly biodegradable. Ecotoxicity The product may be harmful to aquatic organisms. Uses and Restrictions Customers are urged to ensure that the product is entirely suitable for their own purpose. It is the customer’s responsibility to ensure that a suitable and sufficient assessment of the risks created by the use of the product is undertaken. UK Legislation Health and Safety at Work etc Act 1974, and relevant Statutory Provisions. Chemicals (Hazard Information and Packaging) Regulations, 2002 SI 1999/437: The Control of Substances Hazardous to Health Regulations SI no. 972/1996: The Special Waste Regulations 1996 SI no. 2839 1991 Environmental Protection (Duty of Care) Regulations SI 1972/917: Highly Flammable Liquids and LPG Regulations. UK Guidance Publications EH40, Occupational Exposure Limits, HSE. Revised Annually. HS (G) 53, Respiratory Equipment - a Practical Guide for Users, HSE. General Approved Code of Practice to COSHH Regulations, HSE. Footnote The information contained in this SDS corresponds to our level of knowledge at the time of publication. All warranties are excluded. Our most current General Sales Conditions shall apply. Please consult the Technical Data Sheet prior to use. Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 9804/9037 ISSUE 1, AUGUST 2002 Emergency Contact : Emergency Telephone No.: +44 (0) 1889 590312 Description: One component moisture curing polyurethane based adhesive/sealant. 2. COMPOSITION/INFORMATION ON INGREDIENTS Substance Concentration Skin contact Wipe off as much as possible with a clean dry cloth. Wash skin thoroughly with soap and water. Solvents should not be used to clean skin because they may increase the penetration of the material. Contaminated clothing should be washed or dry-cleaned before re-use. Ingestion Do not induce vomiting. Wash out mouth with water. Obtain medical attention. Inhalation Unlikely to occur. However, provide symptomatic medical treatment if required. 5. FIRE-FIGHTING MEASURES Extinguishing Media Use water spray, foam, dry chemical or carbon dioxide. Special Hazards of Product Thermal decomposition or burning may release oxides of carbon, nitrogen and other toxic gasses and vapours. See also Section 10. Protective Equipment for Fire-Fighting Wear full protective clothing and self-contained breathing apparatus. 6. ACCIDENTAL RELEASE MEASURES Personal Precautions Wear appropriate protective clothing. Environmental Precautions and Clean-Up Methods Try to prevent material from entering drains or water courses. Spillages Remove spilled/leaked product by scraping from surfaces. Allow to solidify normally. Clean surfaces with a suitable solvent. 7. HANDLING AND STORAGE Handling Exposure by inhalation or skin contact should be minimised by good industrial hygiene practices. Avoid contact with eyes, skin and clothing. Use in a well-ventilated area. Respiratory Protection Respiratory protection not normally required. If limits are exceeded use an approved respirator suitable for the purpose. Hand Protection Wear suitable impervious gloves. Eye Protection Wear safety glasses if risks of accidental contamination are possible during application. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Paste Colour: Black Odour: Odourless pH: Not applicable Flash Point (ºC): Exceeds 100 Solubility in Water: Insoluble Vapour Pressure (kPa): Negligible vapour pressure at ambient conditions Density (kg/m3) Approximately 1.18 at 20 ºC Viscosity (at 20 ºC) Thixotropic paste 10. STABILITY AND REACTIVITY Stable Stable under normal conditions. Conditions to Avoid Exposure to water or moisture. Materials to avoid Amines. Alcohols. Hazardous Decomposition Products Reaction with water or moist air may produce: carbon dioxide formation resulting in pressure increase in bulk containers (risk of bursting). Combustion may also generate: oxides of carbon, oxides of nitrogen, toxic nitrogen compounds. Ecotoxicity The product Is expected to be non-hazardous to aquatic species. Footnote The information contained in this SDS corresponds to our level of knowledge at the time of publication. All warranties are excluded. Our most current General Sales Conditions shall apply. Please consult the Technical Data Sheet prior to use. Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 9804/8962 ISSUE 4, (REV) AUGUST 2002 Emergency Contact : Emergency Telephone No.: +44 (0) 1889 590312 * 2. COMPOSITION/INFORMATION ON INGREDIENTS Composition: Mixture of polydimethylsiloxanes, amorphous silica and crosslinker Reactive ingredient: Alkyltriacetoxysilanes < 5% Not regarded as a health hazard under current legislation. * 4. FIRST-AID MEASURES Inhalation: Remove affected personnel to fresh air, keep warm and at rest. If irritation persists, seek medical attention. Ingestion: Do not induce vomiting. Rinse mouth with clean water and then drink plenty of water. Seek medical attention. Skin Contact: Remove affected person from source of contamination. Wash thoroughly with soap and water. If irritation persists or a rash develops seek medical attention. Eye Contact: Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues. 9804/8962 ISSUE 4, (REV) AUGUST 2002 * 5. FIRE-FIGHTING MEASURES Extinguishing Media: Fire can be extinguished using: Carbon Dioxide (CO2), water spray. Hazardous Combustion Products: Fire creates: Toxic and highly flammable gasses are released. Protective Measures in Fire: Wear self-contained breathing apparatus. * 6. ACCIDENTAL RELEASE MEASURES Personal Precaution in Spill: Do not attempt to take action without suitable protective clothing - see section 8. Precautions to Protect Environment: Do not allow spillages to enter drains or watercourses. Spill Clean Up Methods: Stop leak if possible without risk. Absorb in vermiculite, dry sand or earth and place into containers. Flush with plenty of water to clean spillage area. Do not contaminate water sources or sewer. * 7. HANDLING AND STORAGE Usage Precautions: Handle in well ventilated areas. Avoid skin and eye contact. Hygienic Work Practices: Do not smoke in the work area. Wash at the end of each work shift and before eating, smoking and using the toilet. Wash promptly if skin becomes wet or contaminated. Promptly remove any clothing that becomes contaminated. Do not eat or drink whilst using this material. * 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Thixotropic paste. Colour: White. Aluminium Clear. Brown. Grey. Black. Odour: Vinegar. Density/Specific Gravity (g/ml) 1.039- - 1.040 Temperature (°C): 20 Decomposition Temp (°C): >200 Flash Point (°C): >150 Method: CC (Closed cup) * 10. STABILITY AND REACTIVITY Stability: Normally stable. Conditions to Avoid: Protect from frost. Hazardous Decomposition Products: During vulcanisation acetic acid is evolved. Air Transport Notes: Not Classified. * 15. REGULATORY INFORMATION 5. FIRE-FIGHTING MEASURES Extinguishing Media: Carbon dioxide, foam, dry chemical and water fog. Special Fire Fighting Procedures: Water or foam may cause frothing. Use water to keep fire exposed containers cool. Water spray may be used to flush spills away from exposures. Prevent runoff from fire control or dilution from entering waterways or drinking water supply. Special Protective Equipment: For fires in enclosed areas, firefighters MUST use self-contained breathing apparatus. Unusual Fire and Explosion Hazards: None. Flash Point > 226 °C (439 °F) (IP 36/ASTM D-92). Flammable Limits LEL NA, UEL NA NFPA Hazard ID: Health 0, Flammability 1, Reactivity 0 Hazardous Decomposition Products: Carbon Monoxide. Sulphur oxides. 6. ACCIDENTAL RELEASE MEASURES Notification Procedures: Report spills as required to appropriate authorities such as the local Environmental Health Officer or Fire Brigade. If spills are likely to enter any drain, waterway or groundwater, contact the Area Water Authority. Procedures if Material is Released or Spilled: Contain and absorb on fire retardant treated sawdust, diatomaceous earth, etc. Shovel up and dispose of at an appropriate licensed waste disposal site in accordance with current applicable laws and regulations and product characteristics at time of disposal. Environmental Precautions: Prevent spills from entering storm sewers or drains and contact with soil. Personal Precautions: See Section 8. 7. HANDLING AND STORAGE Handling: No special precautions are necessary beyond normal good hygiene practices. See Section 8 for additional personal protection advice when handling this product. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Ventilation: No special requirements under ordinary conditions of use and with adequate ventilation. Respiratory Protection: No special requirements under ordinary conditions of use and with adequate ventilation. Eye Protection: Normal industrial eye protection practices should be employed. Skin Protection: No special equipment required. However, good personal hygiene practices should always be followed. Exposure Limits: This product does not contain any components which have recognised exposure limits. 9. PHYSICAL AND CHEMICAL PROPERTIES Typical physical properties are given below. Consult Product Data Sheet for specific details. Physical State: Liquid Colour: Dark Amber Odour: Mild Odour Threshold: Not applicable pH: Not applicable Boiling Point: > 316 °C (600 °F) Drop Point: Not applicable Flash Point: > 226 °C (439 °F) (IP 36/ASTM D-92) Flammability: Not applicable Auto Flammability: Not established Explosive Properties: Not applicable Oxidising Properties: Not applicable Vapour Pressure: mmHg 20 °C: <0.1 Vapour Density: > 2.0 Evaporation Rate: Not applicable Relative Density: 15/4 °C: 0.888 Solubility in Water: Negligible Partition Coefficient: Not established Viscosity at 40 °C, cSt: 84.0 Viscosity at 100° C, cSt: 10.6 Pour Point: -27 °C (-17 °F) Freezing Point: Not established For further technical information, contact your marketing representative. 10. STABILITY AND REACTIVITY Stability (Thermal, Light, etc.): Stable Conditions to Avoid: Extreme heat Incompatibility (materials to avoid):Strong oxidisers Hazardous Decomposition Products: Carbon monoxide. Sulphur oxides Hazardous Polymerisation: Will not occur 9804/8906 ISSUE 4, (REV.) MARCH 2003 15. REGULATORY INFORMATION EU Labelling: EC Labelling not required The following product ingredients are cited on the lists below: Chemical Name CAS Number List Citations No reportable ingredients Regulatory Lists Searched 1=IARC 1 6=NO ALLERGI 11=DE TERAT B 16=DE CARC B 21=CH CARC 2=IARC 2A 7=SE ALLERGY 12=DE TERAT C 17=AT TERAT A 3=IARC 2B 8=SE CARC 13=DE TERAT D 18=AT TERAT B 4=NTP CARC 9=DK CARC 14=DE CARC A1 19=AT TERAT C 5=NTP SUS 10=DE TERAT A 15=DE CARC A2 20=AT TERAT D CARC=CARCINOGEN; SUS=SUSPECTED CARCINOGEN; TERAT=TERATOGENIC AT=Austria DE=Germany NO=Norway CH=Switzerland DK=Denmark SE=Sweden 4. FIRST-AID MEASURES Eyes: Flush the eye with copious amounts of water. No emergency measures are necessary but if adverse eye effects follow, refer for medical attention. Skin: Wash the contaminated skin thoroughly with soap and water. No emergency measures are necessary but if adverse skin effects follow, refer for medical attention. Inhalation: Remove the affected person to fresh air. If recovery is not rapid, obtain medical attention. Ingestion: DO NOT INDUCE VOMITING. No emergency measures are needed but if adverse health effects follow, refer for medical attention. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering measures: No special measures needed. Control parameters: TWA TLV (ACGIH): 5 mg/m3 for oil mist. However, in all circumstances exposure should be kept as low as reasonably possible by good ventilation and safe working practices. Respiratory protection: Inhalation of vapours, fumes or mists should be avoided by safe working practices and good ventilation. Eye protection: If there is a risk of splashing while handling product, eye protection should be worn (e.g. full face shield or goggles with side shields). Skin protection: Prolonged and repeated skin contact should be avoided by the use of clean gloves and clean overalls. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Oily liquid Colour: Light yellow R&S phrases: None 5. FIRE-FIGHTING MEASURES Extinguishing Media: Carbon dioxide, foam, dry chemical and water fog. Special Fire Fighting Procedures: Water or foam may cause frothing. Use water to keep fire exposed containers cool. Water spray may be used to flush spills away from exposures. Prevent runoff from fire control or dilution from entering waterways or drinking water supply. Special Protective Equipment: For fires in enclosed areas, firefighters MUST use self-contained breathing apparatus. Unusual Fire and Explosion Hazards Note Pressurised mists may form a flammable mixture Flash Point > 199 °C (390 °F) (IP 36/ASTM D-92). Flammable Limits LEL NA, UEL NA NFPA Hazard ID: Health 0, Flammability 1, Reactivity 0 Hazardous Decomposition Products: Carbon Monoxide, Metal Oxides, Elemental Oxides. 6. ACCIDENTAL RELEASE MEASURES Notification Procedures: Report spills as required to appropriate authorities such as the local Environmental Health Officer or Fire Brigade. If spills are likely to enter any drain, waterway or groundwater, contact the Area Water Authority. In case of accident or road spill, contact the Police and Fire Brigade and, if appropriate, the Area Water Authority. Procedures if Material is Released or Spilled: Contain and absorb on fire retardant treated sawdust, diatomaceous earth, etc. Shovel up and dispose of at an appropriate licensed waste disposal site in accordance with current applicable laws and regulations and product characteristics at time of disposal. Environmental Precautions: Prevent spills from entering storm sewers or drains and contact with soil. Personal Precautions: See Section 8. 7. HANDLING AND STORAGE Handling: High pressure injection under the skin may occur due to the rupture of pressurised lines. Always seek medical attention. Skin Protection: No special equipment required. However, good personal hygiene practices should always be followed. Exposure Limits: This product does not contain any components which have recognised exposure limits. However, a threshold limit value of 5.00 mg/m3 is suggested for oil mist. 9. PHYSICAL AND CHEMICAL PROPERTIES Typical physical properties are given below. Consult Product Data Sheet for specific details. Physical State: Liquid Colour: Amber Odour: Mild Odour Threshold: Not applicable pH: Not established Boiling Point: > 316 °C (600 °F) Melting Point: Not applicable * Flash Point: > 200 °C (392 °F) Flammability: Not applicable Auto Flammability: Not established Explosive Properties: Not applicable Oxidising Properties: Not applicable Vapour Pressure: mmHg 20 °C : < 0.1 Vapour Density: > 2.0 Evaporation Rate: Not applicable Relative Density: 15/4C : 0.88 Solubility in Water: Negligible Partition Coefficient: > 3.5 Viscosity at 40 °C, cSt: 82.8 Viscosity at 100° C, cSt: 10.3 Pour Point: -36 °C (-32.8 °F) Freezing Point: Not established For further technical information, contact your marketing representative. 10. STABILITY AND REACTIVITY Stability (Thermal, Light, etc.): Stable Conditions to Avoid: Extreme heat Incompatibility (materials to avoid):Strong oxidisers Hazardous Decomposition Products: Carbon monoxide, metal oxides, elemental oxides Hazardous Polymerisation: Will not occur Inhalation Toxicity: Not applicable. Harmful concentrations of mists and/or vapours are unlikely to be encountered through any customary or reasonably foreseeable handling, use, or misuse of this product. Eye Irritation: Practically non-irritating. (Draize score: greater than 6 but 15 or less.) Based on testing of similar products and/or the components. Skin Irritation: Practically non-irritating. (Primary Irritation Index: greater than 0.5 but less than 3). Based on testing of similar products and/or the components. Other Acute Toxicity Data: The acute toxicological results summarised above are based on testing of representative JCB products. Subchronic Toxicology (Summary) Representative JCB formulations have been tested by dermal applications 5 days/week for 90 days at doses significantly higher then those expected during normal industrial exposure. Extensive evaluations, including microscopic examination of internal organs and clinical chemistry of body fluids, showed no adverse effects. Reproductive Toxicology (Summary) Dermal exposure of pregnant rats to representative formulations did not cause adverse effects in either the mothers or their offspring. Chronic Toxicology (Summary) The base oils in this product are severely solvent refined and/or severely hydrotreated. Chronic skin painting studies of severely treated oils showed no evidence of carcinogenic effects. Sensitisation (Summary) Representative JCB formulations have not caused skin sensitisation in guinea pigs. 15. REGULATORY INFORMATION EU Labelling: EC Labelling not required The following product ingredients are cited on the lists below: Chemical Name CAS Number List Citations No reportable ingredients Regulatory Lists Searched 1=IARC 1 6=NO ALLERGI 11=DE TERAT B 16=DE CARC B 21=CH CARC 2=IARC 2A 7=SE ALLERGY 12=DE TERAT C 17=AT TERAT A 3=IARC 2B 8=SE CARC 13=DE TERAT D 18=AT TERAT B 4=NTP CARC 9=DK CARC 14=DE CARC A1 19=AT TERAT C 5=NTP SUS 10=DE TERAT A 15=DE CARC A2 20=AT TERAT D CARC=CARCINOGEN; SUS=SUSPECTED CARCINOGEN; TERAT=TERATOGENIC AT=Austria DE=Germany NO=Norway CH=Switzerland DK=Denmark SE=Sweden JCB Part Nos. 4000/2301, 4000/2302, 4000/2303 JCB HP Uni ATF 2002-07-17 1. PRODUCT AND COMPANY IDENTIFICATION JCB Universal ATF JCB HP Uni ATF Grades: Use: Lubricating oil for automotive transmissions Company: No Name CAS-No %-mass Use self-contained breathing equipment when fighting fire in confined spaces. 6. ACCIDENTAL RELEASE MEASURES Personal precautions: No special measures needed. Environmental precautions: Water may be used to flush spills away from sources of ignition. Do not allow the product to enter public drainage system or open water courses. Methods for cleaning up: Absorb and scrape up. Absorbent materials: Sand or active clay. 7. HANDLING AND STORAGE Handling: Avoid prolonged or repeated skin contact. Avoid inhalation of vapour, mist or fume. Do not wear contaminated clothing. animals. LD50 (rat) for base oils is above 5 g/kg . 12. JCB Product No. 4000/2501-5 lt, 4000/2502 -25 lt, 4000/2503 -200 lt 02-07 -17 1. PRODUCT AND COMPANY IDENTIFICATION JCB Transmission Fluid EP 10W JCB EP TransmissionP Part npumbers: Grades: SAE 10W, 30 Use: Lubricating oil for tractor transmissions Company: No Name CAS-No %-mass Use self-contained breathing equipment when fighting fire in confined spaces. 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Avoid prolonged or repeated skin contact. Environmental precautions: Water may be used to flush spills away from sources of ignition. Do not allow the product to enter public drainage system or open water courses. Methods for cleaning up: Absorb and scrape up. Absorbent materials: Sand or active clay. 7. HANDLING AND STORAGE Handling: Avoid prolonged or repeated skin contact. Avoid inhalation of vapour, mist or fume. Do not wear contaminated clothing. animals. LD50 (rat) for base oils is above 5 g/kg . 12. JCB Product No. 4000/2501-5 lt, 4000/2502 -25 lt, 4000/2503 -200 lt 4000/2601, 4000/2602, 4000/2603 02-07 -17 1. PRODUCT AND COMPANY IDENTIFICATION JCB Transmission Fluid EP SAE30 JCB EP TransmissionP Part npumbers: Grades: SAE 10W, 30 Use: Lubricating oil for tractor transmissions Company: No Name CAS-No %-mass Use self-contained breathing equipment when fighting fire in confined spaces. 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Avoid prolonged or repeated skin contact. Environmental precautions: Water may be used to flush spills away from sources of ignition. Do not allow the product to enter public drainage system or open water courses. Methods for cleaning up: Absorb and scrape up. Absorbent materials: Sand or active clay. 7. HANDLING AND STORAGE Handling: Avoid prolonged or repeated skin contact. Avoid inhalation of vapour, mist or fume. Do not wear contaminated clothing. animals. LD50 (rat) for base oils is above 5 g/kg . 12. 4. FIRST-AID MEASURES Eyes: Flush the eye with copious amounts of water. No emergency measures are necessary but if adverse eye effects follow, refer for medical attention. Skin: Wash the contaminated skin thoroughly with soap and water. No emergency measures are necessary but if adverse skin effects follow, refer for medical attention. Inhalation: Remove the affected person to fresh air. If recovery is not rapid, obtain medical attention. Ingestion: DO NOT INDUCE VOMITING. No emergency measures are needed but if adverse health effects follow, refer for medical attention. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering measures: No special measures needed. Control parameters: TWA TLV (ACGIH): 5 mg/m3 for oil mist. However, in all circumstances exposure should be kept as low as reasonably possible by good ventilation and safe working practices. Respiratory protection: Inhalation of vapours, fumes or mist should be avoided by safe working practices and good ventilation. Eye protection: If there is a risk of splashing while handling product, eye protection should be worn (e.g. full face shield or goggles with side shields). Skin protection: Prolonged and repeated skin contact should be avoided by the use of clean gloves and clean overalls. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Oily liquid Colour: Brown R&S phrases: None JCB Part Nos. 4001/1801, 4001/1802, 4001/1803 JCB EP Engine Oil 2002-07-17 1. PRODUCT AND COMPANY IDENTIFICATION JCB Engine Oil EP 15W40 JCB EP Engine Oil Grades: SAE 15W-40 Use: Lubricating oil for automotive engines Company: No Name CAS-No %-mass Slight flammability hazard when exposed to heat or flame. Special protective equipment for firefighters: Use self-contained breathing equipment when fighting fire in confined spaces. 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Avoid prolonged or repeated skin contact. Environmental precautions: Water may be used to flush spills away from sources of ignition. Do not allow the product to enter public drainage system or open water courses. Methods for cleaning up: Absorb and scrape up. Absorbent materials: Sand or active clay. 7. HANDLING AND STORAGE Handling: Avoid prolonged or repeated skin contact. Avoid inhalation of vapour, mist or fume. Do not wear contaminated clothing. If overheated, fumes and vapours are irritating to the breathing passages and lungs. Ingestion: Ingestion is unlikely to cause adverse systemic health effects. Other: The refined mineral base oils used in the formulation of this product are of a low order of toxicity in test animals. LD50 (rat) for base oils is above 5 g/kg . 12. 4. FIRST-AID MEASURES Eyes: Flush the eye with copious amounts of water. No emergency measures are necessary but if adverse eye effects follow, refer for medical attention. Skin: Wash the contaminated skin thoroughly with soap and water. No emergency measures are necessary but if adverse skin effects follow, refer for medical attention. Inhalation: Remove the affected person to fresh air. If recovery is not rapid, obtain medical attention. Ingestion: DO NOT INDUCE VOMITING. No emergency measures are needed but if adverse health effects follow, refer for medical attention. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering measures: No special measures needed. Control parameters: TWA TLV (ACGIH): 5 mg/m3 for oil mist. However, in all circumstances exposure should be kept as low as reasonably possible by good ventilation and safe working practices. Respiratory protection: Inhalation of vapours, fumes or mists should be avoided by safe working practices and good ventilation. Eye protection: If there is a risk of splashing while handling product, eye protection should be worn (e.g. full face shield or goggles with side shields). Skin protection: Prolonged and repeated skin contact should be avoided by the use of clean gloves and clean overalls. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Oily liquid Colour: Brown R&S phrases: None JCB Part Nos. 4002/1601, 4002/1602, 4002/1603 JCB EP Hydraulic 2002-07-17 1. PRODUCT AND COMPANY IDENTIFICATION JCB EP Hydraulic JCB Hydraulic Fluid EP 46 Grades: ISO VG 32, 46 Use: Lubricating oil for hydraulic equipment Company: No Name CAS-No %-mass Special protective equipment for firefighters: Use self-contained breathing equipment when fighting fire in confined spaces. 6. ACCIDENTAL RELEASE MEASURES Personal precautions: No special measures needed. Environmental precautions: Water may be used to flush spills away from sources of ignition. Do not allow the product to enter public drainage system or open water courses. Methods for cleaning up: Absorb and scrape up. Absorbent materials: Sand or active clay. 7. HANDLING AND STORAGE Handling: Avoid prolonged or repeated skin contact. Avoid inhalation of vapour, mist or fume. Do not wear contaminated clothing. Other: The refined mineral base oils used in the formulation of this product are of a low order of toxicity in test animals. LD50 (rat) for base oils is above 5 g/kg . 12. Eyes: Flush the eye with copious amounts of water. No emergency measures are necessary but if adverse eye effects follow, refer for medical attention. Skin: Wash the contaminated skin thoroughly with soap and water. No emergency measures are necessary but if adverse skin effects follow, refer for medical attention. Inhalation: Remove the affected person to fresh air. If recovery is not rapid, obtain medical attention. Ingestion: DO NOT INDUCE VOMITING. No emergency measures are needed but if adverse health effects follow, refer for medical attention. Physical state Oily liquid Colour Green UN-no: Not classified RID / ADR: Not classified IMO: Not classified IATA / ICAO: Not classified Other: - 15. REGULATORY INFORMATION EC Labelling / Classification Contains calcium sulphonate. May produce an allergic reaction. Eyes: Flush the eye with copious amounts of water. No emergency measures are necessary but if adverse eye effects follow, refer for medical attention. Skin: Wash the contaminated skin thoroughly with soap and water. No emergency measures are necessary but if adverse skin effects follow, refer for medical attention. Inhalation: Remove the affected person to fresh air. If recovery is not rapid, obtain medical attention. Ingestion: DO NOT INDUCE VOMITING. No emergency measures are needed but if adverse health effects follow, refer for medical attention. Physical state Oily liquid Colour Light yellow UN-no: Not classified RID / ADR: Not classified IMO: Not classified IATA / ICAO: Not classified Other: - 15. REGULATORY INFORMATION EC Labelling / Classification Eyes: Flush the eye with copious amounts of water. No emergency measures are necessary but if adverse eye effects follow, refer for medical attention. Skin: Wash the contaminated skin thoroughly with soap and water. No emergency measures are necessary but if adverse skin effects follow, refer for medical attention. Inhalation: Remove the affected person to fresh air. If recovery is not rapid, obtain medical attention. Ingestion: DO NOT INDUCE VOMITING. No emergency measures are needed but if adverse health effects follow, refer for medical attention. Physical state Oily liquid Colour Light yellow UN-no: Not classified RID / ADR: Not classified IMO: Not classified IATA / ICAO: Not classified Other: - 15. REGULATORY INFORMATION EC Labelling / Classification Eyes: Flush the eye with copious amounts of water. No emergency measures are necessary but if adverse eye effects follow, refer for medical attention. Skin: Wash the contaminated skin thoroughly with soap and water. No emergency measures are necessary but if adverse skin effects follow, refer for medical attention. Inhalation: Remove the affected person to fresh air. If recovery is not rapid, obtain medical attention. Ingestion: DO NOT INDUCE VOMITING. No emergency measures are needed but if adverse health effects follow, refer for medical attention. Physical state Oily liquid Colour : Brown UN-no: Not classified RID / ADR: Not classified IMO: Not classified IATA / ICAO: Not classified Other: - 15. REGULATORY INFORMATION EC Labelling / Classification 4. FIRST-AID MEASURES Eyes: Flush the eye with copious amounts of water. No emergency measures are necessary but if adverse eye effects follow, refer for medical attention. Skin: Wash the contaminated skin thoroughly with soap and water. No emergency measures are necessary but if adverse skin effects follow, refer for medical attention. Inhalation: Remove the affected person to fresh air. If recovery is not rapid, obtain medical attention. Ingestion: DO NOT INDUCE VOMITING. No emergency measures are needed but if adverse health effects follow, refer for medical attention. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering measures: No special measures needed. Control parameters: TWA TLV (ACGIH): 5 mg/m3 for oil mist. However, in all circumstances exposure should be kept as low as reasonably possible by good ventilation and safe working practices. Respiratory protection: Inhalation of vapours, fumes or mists should be avoided by safe working practices and good ventilation. Eye protection: If there is a risk of splashing while handling product, eye protection should be worn (e.g. full face shield or goggles with side shields). Skin protection: Prolonged and repeated skin contact should be avoided by the use of clean gloves and clean overalls. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Oily liquid Colour: Light yellow R&S phrases: None Ingestion: DO NOT INDUCE VOMITING. Wash mouth out with water. Obtain immediate treatment by a Doctor and provide a copy of this sheet. Pressure Injection: ALWAYS OBTAIN IMMEDIATE MEDICAL ATTENTION EVEN THOUGH THE INJURY MAY APPEAR MINOR. 5. FIRE-FIGHTING MEASURES Flammability: Combustible Flash point, (°CPMCC) > 150 Extinguishing media: Use foam, dry powder, CO2, Never use water. Products of combustion: Carbon dioxide, carbon monoxide together with dense smoke. 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Good standards of industrial hygiene together with the use of moisturising creams are recommended. Environmental precautions: Prevent liquid entering sewers, drains or water courses. Decontamination: Absorb in earth or sand or other suitable material. In case of spillage on water contain by a boom and collect by skimming or absorption. 7. HANDLING AND STORAGE Keep containers tightly closed. Store under cover. Keep away from food and drink. Compatible with most common metals; may soften certain rubbers - use resistant seals. Avoid sources of ignition. A bunded area may be required. Storage temperature: < 60 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits Substance LTEL STEL Source/other information Mineral oil (mist) 5 mg/m3 10mg/m3 EH40 (UK) Engineering Control Measures Local exhaust ventilation is recommended when excessive product misting occurs. Personal Protection Select PPE appropriate for the product properties/operations taking place. No eating, drinking or smoking in the work area. Wash before breaks and at end of shift/day. Do not keep contaminated cloths in pockets. Launder coveralls at regular intervals. 9804/9049 ISSUE 1, MARCH 2003 9. PHYSICAL AND CHEMICAL PROPERTIES

Storage

F 1M20&F0/801MFH10&E9 H7I&J0&4 3F1 770I&F &J0FQ003&A&M3I&!"&\(<& & 7. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Control Measures ;:&E804GKG4&/0MEH10E&3040EEM15<& Hand Protection XE0&M&2 I&PHM7GF5&JM11G01&410M/<& Eye Protection (90/G4M7&2 2270E&GK&F9010&GE&M&1GEU& K&050&4 3FM4F<& Body Protection ; 1/M7&Q 1U&Q0M1<& & 8. PHYSICAL AND CHEMICAL PROPERTIES Physical State: TG75&7GPHGI<& Colour: )7H0&L&)7M4U<& Odour: ]MG3F<& Flash Point (PMCC) (°C): +Z400IE&AC"<& Solubility in Water (kg/m 3 ) .3E 7HJ70<& Partition Coefficient (Log Pow) ;:F&I0F01/G30I<& Density (kg/m 3 ): "<B&?/0MEH10I&ME&U2 Keep containers tightly closed. 9804/8913 ISSUE 6, (REV.) MARCH 2003 d;;G'1643204;/<'305H37E'176<;RJ' ' 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering measures: I6'<G;1027'9;2<-/;<'4;;R;RJ' ' Control parameters: F*U'F,C'MU>aDYNK'Q'95$9')'86/'607'90<3J'Y6];:;/&'04'277'10/1-9<3241;<';SG6<-/;'<H6-7R'.;'W;G3'2<'76]'2<' /;2<642.7E'G6<<0.7;'.E'566R':;430723064'24R'<28;']6/W045'G/21301;<J' ' Respiratory protection: D4H2723064'68' 2G6-/<&'8-9;<'6/'90<3'<H6-7R'.;'2 60R;R'.E'<28;']6/W045'G/21301;<'24R'566R' ;430723064J' ' Eye protection: D8'3H;/;'0<'2'/0<W'68'<G72<H045']H07;'H24R7045'G/6R-13&';E;'G/63;13064'<H6-7R'.;']6/4'M;J5J'8-77'821;'<H0;7R'6/' 56557;<']03H'<0R;'<H0;7R<NJ' ' Skin protection: e/67645;R'24R'/;G;23;R'<W04'1643213'<H6-7R'.;'2 60R;R'.E'3H;'-<;'68'17;24'576 ;<'24R'17;24'6 ;/277<J' ' 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: _07E'70c-0R' Colour: ?/6]4' Appearance: ?/05H3'24R'17;2/' Odour: *;2W' pH: @705H37E'27W2704;' Boiling range, °C: D403027'.607045'G6043'M607'.2<;N'f')""J' Pour/melting point, °C: g'+)h' Flash point, °C (""'MU@F`'[P(&'>_>N' Autoflammability/ignition, °C f')""'M607'.2<;N' Upper explosion limit: I63'W46]4' Lower explosion limit: I63'W46]4' Vapour pressure, 20 °C, kPa: g'"J"#'M607'.2<;N' Viscosity, kinematic, 40 °C, mm 2 /s: %%' Relative density, 15 °C: "JO%P' Water solubility: I63'<67-.7;' Partition coefficient, n-octanol/water: I63'W46]4' Other data: 10. STABILITY AND REACTIVITY Conditions/materials to avoid: @32.7;J'`2E'/;213']03H'<3/645'6S0R0<045'25;43<J' ' Hazardous decomposition products: FH;/927'R;169G6<03064'6/'04169G7;3;'169.-<3064'92E'G/6R-1;'6S0R;<'68'12/.64'24R'0//0323045'8-9;<J' ' Do not store in open or unlabelled containers. Store away from strong oxidising agents or combustible material. Further advice: Used engine crankcase lubricants contain harmful contaminants. Because of the effects observed in laboratory tests (see Section 11), all persons who regularly handle used engine oil, such as engine mechanics and service station workers, should take precautions to minimise contact with the oil. Good personal hygiene practices MUST be followed. Wash thoroughly any skin contact areas with soap and water. Remove oil soaked clothing and discard oil-soaked shoes. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Eye Protection Normal industrial eye protection practices should be employed. Skin Protection No special equipment required. However, good personal hygiene practices should always be followed. cont’d 9804/8909 ISSUE 5 (REV.), MARCH 2003 Keep containers tightly closed. 9804/8969 ISSUE 6 (REV.), MARCH 2003 Keep containers tightly closed. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering measures: No special measures needed. Control parameters: TWA TLV (ACGIH): 5 mg/m3 for oil mist. However, in all circumstances exposure should be kept as low as reasonably possible by good ventilation and safe working practices. Respiratory protection: Inhalation of the vapours, fumes or mist should be avoided by safe working practices and good ventilation. Eye protection: If there is a risk of splashing while handling product, eye protection should be worn (e.g. full face shield or goggles with side shields). Skin protection: Prolonged and repeated skin contact should be avoided by the use of clean gloves and clean overalls. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Oily liquid Colour: Light yellow Keep containers tightly closed. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering measures: No special measures needed. Control parameters: TWA TLV (ACGIH): 5 mg/m3 for oil mist. However, in all circumstances exposure should be kept as low as reasonably possible by good ventilation and safe working practices. Respiratory protection: Inhalation of the vapours, fumes or mists should be avoided by safe working practices and good ventilation. Eye protection: If there is a risk of splashing while handling product, eye protection should be worn (e.g. full face shield or goggles with side shields). Skin protection: Prolonged and repeated skin contact should be avoided by the use of clean gloves and clean overalls. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Oily liquid Colour: Light yellow Keep containers tightly closed. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering measures: No special measures needed. Control parameters: TWA TLV (ACGIH): 5 mg/m3 for oil mist. However, in all circumstances exposure should be kept as low as reasonably possible by good ventilation and safe working practices. Respiratory protection: Inhalation of the vapours, fumes or mist should be avoided by safe working practices and good ventilation. Eye protection: If there is a risk of splashing while handling product, eye protection should be worn (e.g. full face shield or goggles with side shields). Skin protection: Prolonged and repeated skin contact should be avoided by the use of clean gloves and clean overalls. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Oily liquid Colour: Light yellow Drums should be stored on racks preferably under cover, out of direct sunlight, in well ventilated conditions. Other types of containers should be stored under cover out of direct sunlight in well ventilated conditions. Care should be taken to avoid over-stacking. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION As with all mineral oil based products keep skin contact to a minimum and ensure good hygiene standards. Avoid contact with used engine oil (see Section 16). Respiratory protection - Unlikely to be required in normal use. Note occupational exposure limits for Oil Mist (HSE Guidance Note EH 40/latest issue). Long term exposure limit - (8 hour TWA reference period) 5 milligrams per cubic metre. Short term exposure limit - (15 minute reference period) - 10 milligrams per cubic metre. Hand and skin protection - If contained or repeated exposure is likely PROTECTIVE CLOTHING SHOULD BE WORN including gloves (nitrile rubber or neoprene). Eye protection - Eye protection should be worn if splashing is likely. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Black semi-solid Density at 15 °C kg/l: 0.98 Flash Point (COC)C: >190 Penetration @ 25 °C: 320 9804/8945 ISSUE 2, (REV) FEBRUARY 1997 10. STABILITY AND REACTIVITY Conditions to avoid: Excess heat can lead to decomposition of the constituent additives with evolution of oxides of carbon, sulphur, nitrogen, phosphorous. Materials to avoid: May react with strong oxidising materials. Hazardous Decomposition Products: Oxides of carbon, sulphur, nitrogen, phosporous, particulate matter, unburnt hydrocarbons, polycyclic hydrocarbons and unidentified organic and inorganic compounds. With incomplete combustion - carbon monoxide. Do not store in open or unlabelled containers. Store away from strong oxidising agents or combustible material. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Eye Protection Normal industrial eye protection practices should be employed. Skin Protection No special equipment required. However good personal hygiene practices should always be followed. Respiratory Protection No special requirements under ordinary conditions of use and with adequate ventilation. cont’d 9804/8897 ISSUE 3 (REV.), NOVEMBER 1997 Ventilation No special requirements under ordinary conditions of use and with adequate ventilation. Exposure Limits This product does not contain any components which have recognised exposure limits. 9. PHYSICAL AND CHEMICAL PROPERTIES Typical physical properties are given below. Consult Product Data Sheet for specific details. Physical State: Grease Colour: Blue Grey Odour: Mild Odour Threshold: NA pH: NA Boiling Point °C (°F): >316 (600) Drop Point °C (°F): NA Flash Point °C (°F): >204 (400) (Estimated (Oil COC)) Flammability: NA Auto Flammability: NE Explosive Properties: NA Oxidising Properties: NA Vapour Pressure - mm Hg 20 °C: < 0.1 Vapour Density: NA Evaporation Rate: NA Relative Density: 15/4 C: 0.86 Solubility in Water: Negligible Partition Coefficient: NE Viscosity at 40°C, cSt: >300.0 Viscosity at 100°C, cSt: >15.0 Pour Point °C: NE Freezing Point °C (°F): NE Note: Most physical properties for oil component. NA = Not Applicable NE = Not Established D = Decomposes For further technical information contact JCB Service. 10. STABILITY AND REACTIVITY Stability (thermal, light etc.): Stable Conditions to avoid: Extreme heat Incompatibility (materials to avoid): Strong oxidisers Hazardous decomposition products: Carbon monoxide. Metal oxides. Hazardous polymerisation: Will not occur Do not store in open or unlabelled containers. Store away from strong oxidising agents or combustible material. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Eye Protection Generally eye contact is unlikely with this type of material. If eye contact is likely, safety glasses with side shields or chemical type goggles should be worn. Skin Protection If prolonged or repeated skin contact is likely, oil impervious gloves MUST be worn. Good personal hygiene practices should always be followed. Respiratory Protection No special requirements under ordinary conditions of use and with adequate ventilation. cont’d 9804/8944 ISSUE 3 (REV.), NOVEMBER 1997 Ventilation No special requirements under ordinary conditions of use and with adequate ventilation. Exposure Limits This product does not contain any components which have recognised exposure limits. 9. PHYSICAL AND CHEMICAL PROPERTIES Typical physical properties are given below. Consult Product Data Sheet for specific details. Physical State: Grease Colour: Grey Odour: Mild Odour Threshold: NA pH: NA Boiling Point °C (°F): >316 (600) Drop Point °C (°F): NA Flash Point °C (°F): >204 (400) (IP 34/ASTM D-93) Flammability: NA Auto Flammability: NE Explosive Properties: NA Oxidising Properties: NA Vapour Pressure - mm Hg 20 °C: < 0.1 Vapour Density: NE Evaporation Rate: NA Relative Density: 15/4 C: 0.867 Solubility in Water: Negligible Partition Coefficient: >3.5 Viscosity at 40°C, cSt: 150.0 Viscosity at 100°C, cSt: 11.8 Pour Point °C: NE Freezing Point °C (°F): NE Note: Most physical properties for oil component. NA = Not Applicable NE = Not Established D = Decomposes For further technical information contact JCB Service. 10. STABILITY AND REACTIVITY Stability (thermal, light etc.): Stable Conditions to avoid: Extreme heat Incompatibility (materials to avoid): Strong oxidisers Hazardous decomposition products: Carbon monoxide. Metal oxides. Elemental oxides. Hazardous polymerisation: Will not occur Do not store in open or unlabelled containers. Store away from strong oxidising agents or combustible material. 9804/8903 ISSUE 4, (REV.) NOVEMBER 1997 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Ventilation: No special requirements under ordinary conditions of use and with adequate ventilation. Respiratory Protection: No special requirements under ordinary conditions of use and with adequate ventilation. Eye Protection: Normal industrial eye protection practices should be employed. Skin Protection: If prolonged or repeated skin contact is likely, oil impervious gloves MUST be worn. Good personal hygience practices should always be followed. Exposure Limits: This product does not contain any components which have recognised exposure limits. 9. PHYSICAL AND CHEMICAL PROPERTIES Typical physical properties are given below. Consult Product Data Sheet for specific details. Physical State: Grease Colour: Brown Odour: Mild Odour Threshold: Not applicable pH: Not applicable Boiling Point: > 316 °C (600 °F) Drop Point: Not applicable Flash Point: > 204 °C (400 °F) (Estimated (Oil COC)) Flammability: Not applicable Auto Flammability: Not established Explosive Properties: Not applicable Oxidising Properties: Not applicable Vapour Pressure: mmHg 20 °C: <0.1 Vapour Density: > 2.0 Evaporation Rate: Not applicable Relative Density: 15/4 °C: 0.89 Solubility in Water: Negligible Partition Coefficient: Not established Viscosity at 40 °C, cSt: 150.0 Viscosity at 100° C, cSt: 13.0 Pour Point: Not established Freezing Point: Not established Note: Most physical properties for oil component. For further technical information, contact your marketing representative. 10. STABILITY AND REACTIVITY Stability (Thermal, Light, etc.): Stable Conditions to Avoid: Extreme heat Incompatibility (materials to avoid): Strong oxidisers Hazardous Decomposition Products: Carbon monoxide Hazardous Polymerisation: Will not occur 9804/8903 ISSUE 4, (REV.) NOVEMBER 1997 Storage temperature should be controlled to between 1 and 40°C. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering control measures: No specific measures necessary. Eye Protection No specific measures necessary. Hand Protection Use a good quality barrier cream. Body Protection Normal work wear. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Paste Colour: Dark Odour: Odourless Flash Point (PMCC) (°C): >200 Solubility in Water (kg/m3): Insoluble Density (kg/m3): 0.95 - 1.0 (typical) (measured as kg/litre) Auto Flammability (°C): Above 200 10. STABILITY AND REACTIVITY Stability (thermal, light etc.): Stable under normal conditions. Conditions to avoid: No specific measures necessary. Materials to avoid: Strong oxidising agents. Hazardous decomposition products: Combustion will generate: smoke, possibly thick and choking, resulting in zero visibility Do not store in open or unlabelled containers. Store away from strong oxidising agents or combustible material. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Ventilation: No special requirements under ordinary conditions of use and with adequate ventilation. Respiratory Protection: No special requirements under ordinary conditions of use and with adequate ventilation. Eye Protection: Generally eye contact is unlikely with this type material. If eye contact is likely, safety glasses with side shields or chemical type goggles should be worn. cont’d 9804/8970 ISSUE 3, (REV.) NOVEMBER 1997 Skin Protection: If prolonged or repeated skin contact is likely, oil impervious gloves MUST be worn. Good personal hygiene practices should always be followed. Exposure Limits: This product does not contain any components which have recognised exposure limits. 9. PHYSICAL AND CHEMICAL PROPERTIES Typical physical properties are given below. Consult Product Data Sheet for specific details. Physical State: Grease Colour: Dark Blue Odour: Mild Odour Threshold: Not applicable pH: Not applicable Boiling Point: Not established Drop Point: Not established Flash Point: > 204 °C (400 °F) (IP 34/ASTM D-93) Flammability: Not applicable Auto Flammability: Not established Explosive Properties: Not applicable Oxidising Properties: Not applicable Vapour Pressure: Not established Vapour Density: Not established Evaporation Rate: Not applicable Relative Density: 15/4C : 0.923 Solubility in Water: Negligible Partition Coefficient: > 3.5 Viscosity at 40 °C, cSt: Not established Viscosity at 100° C, cSt: Not established Pour Point: Not applicable Freezing Point: Not established Note: Most physical properties for oil component. For further technical information, contact your marketing representative. 10. STABILITY AND REACTIVITY Stability (Thermal, Light, etc.): Stable Conditions to Avoid: Extreme heat Incompatibility (materials to avoid): Strong oxidisers Hazardous Decomposition Products: Carbon monoxide, metal oxides, elemental oxides Hazardous Polymerisation: Will not occur Storage area should be: out of direct sunlight. Storage temperature should be kept below 50 °C. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Standards 1. Hydrogenated hydrocarbon An exposure limit of 300ppm is recommended. (<0.1% w/w benzene) 2. White spirit (<0.1% w/w benzene) UK EH40: OES 600 mg/m3 8h TWA. 3. Carbon Dioxide UK EH40 OES 5000 ppm (8000 mg/m3) 8h TWA. UK EH40 OES 15000 ppm (27000 mg/m3) 15 min TWA. Engineering Control Measurers Exposure to this material may be controlled in a number of ways. The measures appropriate for a particular worksite depend on how the material is used and on the potential for exposure. Use of the basic principles of Industrial Hygiene will enable this material to be used safely. Respiratory Protection Respiratory protection if there is a risk of exposure to high vapour concentrations. Hand Protection Use a good quality barrier cream. Eye Protection Chemical goggles if there is a risk of eye contact. Body Protection Normal work wear. Protection During Application During application, adequate ventilation must be provided. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State Liquid Colour Brown Odour Characteristic Boiling Range/Point (°C) Boils above 150. (based on major component). Flash Point (PMCC) (°C) 40 Explosion Limits (%) 0.6 to 7.0 (based on major component) cont’d 9804/8894 ISSUE 3 (REV.), NOVEMBER 1997 Solubility in Water (kg/m3) Insoluble Vapour Pressure (mm.Hg./20 °C) <2 Density (kg/m3) 0.85 (measured as kg/litre) Auto-flammability (°C) Above 200. Viscosity (cSt) Mobile liquid at ambient temperatures. Vapour Density (Air = 1) Heavier than air. Evaporation Rate <0.5 (referenced as n-butyl acetate = 1) 10. STABILITY AND REACTIVITY Stability Stable under normal conditions. Conditions to avoid Exposure to direct sunlight. Temperatures in excess of 50 °C. Materials to Avoid Strong oxidising agents. Hazardous Decomposition Combustion will generate: oxides of sulphur, smoke, possibly thick and choking, resulting in zero visibility. Keep containers tightly closed. 9804/8993 ISSUE 4, MARCH 2003 [;&C;D&>D;0/&2C&;A/C&;0&=C5@</55/?&3;CD@2C/0>N&*D;0/&@G@Q&K0;B&>D0;CI&;J2?2>2CI&@I/CD>&;0&3;B<=>D2<5/&B@D/02@5N& & 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Ventilation: f>/&2C&G/55&1/CD25@D/?&@0/@N& Respiratory Protection: PAA0;1/?&0/>A20@D;0Q&A0;D/3D21/&/F=2AB/CD&Mf*4&</&=>/?&2C&L2IL&1@A;=0&;0&B2>D&3;C3/CD0@D2;C>N&a;&>A/32@5& 0/F=20/B/CD>&=C?/0&;0?2C@0Q&3;C?2D2;C>&;K&=>/&@C?&G2DL&@?/F=@D/&1/CD25@D2;CN& Eye Protection: a;0B@5&2C?=>D02@5&/Q/&A0;D/3D2;C&A0@3D23/>&>L;=5?&</&/BA5;Q/?N& Skin Protection: .BA/012;=>&I5;1/>&Mf*4&</&G;0CN& Exposure Limits: 4L2>&A0;?=3D&?;/>&C;D&3;CD@2C&@CQ&3;BA;C/CD>&GL23L&L@1/&0/3;IC2>/?&/JA;>=0/&52B2D>N& & 9. PHYSICAL AND CHEMICAL PROPERTIES & 4QA23@5&ALQ>23@5&A0;A/0D2/>&@0/&I21/C&</5;GN&(;C>=5D&R0;?=3D&[@D@&*L//D&K;0&>A/32K23&?/D@25>N& Physical State: O2F=2?& Colour: O2ILD& Odour: M25?& Odour Threshold: a;D&@AA523@<5/& pH: a;D&/>D@<52>L/?& Boiling Point: a;D&/>D@<52>L/?& Melting Point: a;D&@AA523@<5/& Flash Point 9"&Z(&U!8 &Z_V&U.R&$! Keep containers tightly closed. 9804/8891 ISSUE 6, (REV.) MARCH 2003 Temperature < 5 °C Handling/Storage: Store in a cool, dry place. Sensitive to static Electricity: No Sensitivity to Mechanical Impact: No *8. EXPOSURE CONTROLS/PERSONAL PROTECTION COMPONENT EXPOSURE LIMITS Ethyl-2-cyanoacrylate UK EH40 OES 15-minute STEL: 0.3 ppm UK EH40 OES 15-minute STEL: 1.5 mg/m3 OCCUPATIONAL EXPOSURE CONTROLS Ventilation Requirements: Normal (mechanical) room ventilation should be adequate for small volumes. For higher volume activities, or if needed for worker comfort, local mechanical exhaust should be provided. Eye Protection requirements: Safety glasses, goggles or face shield to protect against splashing. Personal eye protection should conform to EN 166. Glove requirements: Nitrile rubber or Viton™ gloves are recommended. Cotton or other absorbent gloves should not be worn. Gloves should conform to EN 374. Clothing Requirements: Uniforms, coveralls, or a lab coat should be worn. Wash Requirements: Wash before eating, drinking, or using toilet facilities. Respiratory Requirements: None required under normal handling conditions. 9804/9003 ISSUE 2, (REV) SEPTEMBER 2002 Transport, handle and store in accordance with applicable local regulations and only in labelled containers designed for this product. * 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Respiratory protection: Airborne concentrations should be kept to lowest levels possible. If vapour, mist or dust is generated, use approved respirator as appropriate. Supplied air respiratory protection should be used for cleaning large spills or upon entry into tanks, vessels, or other confined spaces. See below for applicable permissible concentrations. Skin and hand protection: Avoid skin contact. When contamination has occured, workers should wash exposed skin with soap and water. Soiled clothing should be laundered or dry cleaned. Eye protection: Chemical type goggles or face shield recommended to prevent eye contact. Exposure limit for the Ethylene glycol: OSHA PEL-STEL 50 ppm; ACGIH TLV-STEL 50 ppm. * 9. PHYSICAL AND CHEMICAL PROPERTIES Store below 50 C in a dry, well ventilated place away from sources of heat, ignition and sunlight. NO SMOKING. Observe the label precautions. Store separately from strong oxidising agents and strongly alkaline and strongly acidic materials. 9. EXPOSURE CONTROLS/PERSONAL PROTECTION INGREDIENT NAME OES/MEL 8HR TWA 10 MIN stel Mineral Oils (Mist) OES 5mg/m3 10mg/m3 White Spirit OES 100ppm 125ppm Butane OES 600ppm 750ppm Engineering Measures: Provide adequate ventilation to maintain the flammable vapour concentration well below the lower explosion limit (LEL) and ensure the airborne concentration of substances to which an OES has been assigned is below that OES (Occupational Exposure Standard). Respiratory Protection: Under normal workshop conditions no respiratory equipment is required. Air-fed respiratory equipment should be worn when this product is sprayed if the exposure of the sprayer or other people nearby cannot be controlled to below the occupational exposure limit and engineering controls and measures cannot reasonably be improved. Hand Protection: Hand protection is not specified for product use in aerosol form. However, barrier creams may help to protect exposed areas of the skin but are not substitutes for full physical protection. They should not be applied once exposure has occurred. Eye Protection: Eye protection is not specified for product use in aerosol form. However, bulk application by spray gun or powered system should be carried out by operators wearing appropriate eye protection. Skin Protection: Cotton or cotton/synthetic overalls are normally suitable. Grossly contaminated clothing should be removed and the skin washed with soap and water or a proprietary skin cleaner. 10. PHYSICAL AND CHEMICAL PROPERTIES Typical physical properties are given below. Consult Product Data Sheet for specific details. Physical State: Aerosol Store below 50 C in a dry, well ventilated place away from sources of heat, ignition and sunlight. NO SMOKING. Observe the label precautions. Store separately from strong oxidising agents and strongly alkaline and strongly acidic materials. 9. EXPOSURE CONTROLS/PERSONAL PROTECTION INGREDIENT NAME OES/MEL 8HR TWA 10 MIN stel Mineral Oils (Mist) OES 5mg/m3 10mg/m3 White Spirit OES 100ppm 125ppm Butane OES 600ppm 750ppm Engineering Measures: Provide adequate ventilation to maintain the flammable vapour concentration well below the lower explosion limit (LEL) and ensure the airborne concentration of substances to which an OES has been assigned is below that OES (Occupational Exposure Standard). Respiratory Protection: Under normal workshop conditions no respiratory equipment is required. Air-fed respiratory equipment should be worn when this product is sprayed if the exposure of the sprayer or other people nearby cannot be controlled to below the occupational exposure limit and engineering controls and measures cannot reasonably be improved. Hand Protection: Hand protection is not specified for product use in aerosol form. However, barrier creams may help to protect exposed areas of the skin but are not substitutes for full physical protection. They should not be applied once exposure has occurred. Eye Protection: Eye protection is not specified for product use in aerosol form. However, bulk application by spray gun or powered system should be carried out by operators wearing appropriate eye protection. Skin Protection: Cotton or cotton/synthetic overalls are normally suitable. Grossly contaminated clothing should be removed and the skin washed with soap and water or a proprietary skin cleaner. 10. PHYSICAL AND CHEMICAL PROPERTIES Typical physical properties are given below. Consult Product Data Sheet for specific details. Physical State: Aerosol Store in containers as supplied - avoid moisture contamination. Recommended storage between 5 °C - 25 °C. 9804/8962 ISSUE 3, NOVEMBER 1997 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits (OEL’s) Substance 8 hr TWA 15 min STEL Acetic acid 10 ppm 15 ppm OES* *OES Occupations Exposure Standard. Ref HSE Guidance Note EH 40/94. Guidance Note EH40 is published by the Health and Safety Executive and is updated annually. OEL values are subject to periodical revision and users should check current edition. Personal Protection: Ventilation: Work area should be well ventilated to disperse traces of acetic acid. Requirements will be subject to working arrangements and quantities used. Gloves: Most types of non absorbent industrial glove will be suitable. Check manufacturer’s recommendations. Eyes: Wear safety spectacles/goggles as appropriate. Clothes: Normal protective clothing e.g. overalls/apron. Discard heavily contaminated clothing. Relevant Legislation Refs.2,3 9. PHYSICAL AND CHEMICAL PROPERTIES Storage area should be: cool, dry, well ventilated and out of direct sunlight. Store away from sources of heat or ignition. Storage temperature should be controlled to between 5 and 25 °C. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Standards: Isopropyl Alcohol UK EH40: OES 400 ppm (980 mg/m3) 8h TWA. UK EH40: OES 500 ppm (1225 mg/m3) 15min STEL. Respiratory Protection: Adequate ventilation should be provided to maintain solvent concentrations in the workplace below exposure limits. Respiratory protection if there is a risk of exposure to high vapour concentrations. Hand Protection: Wear suitable impervious gloves. Eye Protection: Chemical goggles if there is a risk of splashing. 9804/8976 ISSUE 3, (REV.) NOVEMBER 1997 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid. Colour: Clear. Odour: Characteristic. Alcoholic. pH: Not applicable. Boiling Range/Point (°C): 80 (based on major component). Flash Point (°C): 12. Explosion Limits (%): Lower Limit 2. Upper Limit 12. (based on major component). Solubility in Water (kg/m3): Miscible. Vapour Pressure (kPa): 4.8 at 20 °C (base on major component). Density (kg/m3): Approximately 0.78 at 20 °C. Auto-flammability (°C): Approximately 425. Viscosity: Approximately 2 at 20 °C (measured as mPa.s). 10. STABILITY AND REACTIVITY Stability: Stable under normal conditions. Contains volatile solvent. Conditions to Avoid: Sources of ignition. Exposure to direct sunlight. High temperatures. Materials to Avoid: Oxidising agents. Concentrated mineral acids. Alkalis. Halogens. Hazardous Decomposition Products: Combustion will generate: oxides of carbon. Temperature Ambient Handling/Storage: Store in a cool dry place Sensitive to static Electricity: Yes Special Sensitivity: Keep away from heat Sensitivity to Mechanical Impact: No *8. EXPOSURE CONTROLS/PERSONAL PROTECTION COMPONENT EXPOSURE LIMITS Butane UK EH40 OES 8-hour TWA: 600 ppm UK EH40 OES 8-hour TWA: 1450 mg/m3 UK EH40 OES 15-minute STEL: 750 ppm UK EH40 OES 15-minute STEL: 1810 mg/m3 Ethyl acetate UK EH40 OES 8-hour TWA: 200 ppm UK EH40 OES 15-minute STEL: 400 ppm OCCUPATIONAL EXPOSURE CONTROLS Ventilation Requirements: Local. Eye Protection Requirements: Safety glasses, goggles or face shield to protect against splashing. Personal eye protection should conform to EN 166. Glove Requirements: Nitrile rubber or Viton™ gloves are recommended. Cotton or other absorbent gloves should not be worn. Gloves should conform to EN 374. Clothing Requirements: Uniforms, coveralls, or a lab coat should be worn. Wash Requirements: Wash before eating, drinking, or using toilet facilities. Respiratory Requirements: None required under normal handling conditions. 9804/9004 ISSUE 2, (REV) SEPTEMBER 2002 Store below 50 °C in a dry, well ventilated place away from sources of heat, ignition and direct sunlight. No smoking. Observe the label precautions. Store separately from strong oxidising agents and strongly alkaline and strongly acidic materials. 9804/8951 ISSUE 2 (REV.), APRIL 1997 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Ingredient Name OES/MEL 8hr TWA 15 min STEL Xylene, mixture of isomers OES 100 ppm 150 ppm (Sk) Acetone OES 750 ppm 1500 ppm 1-Methoxy-2-propanol OES 100 ppm 300 ppm (Sk) Butane OES 600 ppm 750 ppm 1-Methoxy Propan-2-ol Acetate OES 100 ppm (Sup) Aromatic hydrocarbon solvent blend OES 50 ppm - (Sup) Engineering measures: Provide adequate ventilation to maintain the flammable vapour concentration well below the lower explosive limit (LEL) and ensure the airborne concentration of substances to which an OES has been assigned is below that OES (Occupational Exposure Standard). Respiratory Protection: Air-fed respiratory equipment should be worn when this product is sprayed if the exposure of the sprayer or other people nearby cannot be controlled to below the occupational exposure limit and engineering controls and measures cannot reasonably be improved. Hand protection: When skin exposure may occur, advice may be sought from the glove suppliers on appropriate types. Barrier creams may help to protect exposed areas of the skin but are not substitutes for full physical protection. They should not be applied once exposure has occurred. Eye protection: Eye protection designed to protect against liquid splashes should be worn. Skin protection: Cotton or cotton/synthetic overalls are normally suitable. Grossly contaminated clothing should be removed and the skin washed with soap and water or a proprietary skin cleaner. (Sk) denotes product can be absorbed through skin. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Aerosol Store below 50 °C in a dry, well ventilated place away from sources of heat, ignition and direct sunlight. No smoking. Observe the label precautions. Store separately from strong oxidising agents and strongly alkaline and strongly acidic materials. 9804/8952 ISSUE 2 (REV.), APRIL 1997 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Ingredient Name OES/MEL 8hr TWA 15 min STEL Xylene, mixture of isomers OES 100 ppm 150 ppm (Sk) Acetone OES 750 ppm 1500 ppm 1-Methoxy Propan-2-ol Acetate OES 100 ppm (Sup) Aromatic hydrocarbon solvent blend OES 50 ppm - (Sup) Butane OES 600 ppm 750 ppm Engineering measures: Provide adequate ventilation to maintain the flammable vapour concentration well below the lower explosive limit (LEL) and ensure the airborne concentration of substances to which an OES has been assigned is below that OES (Occupational Exposure Standard). Respiratory Protection: Air-fed respiratory equipment should be worn when this product is sprayed if the exposure of the sprayer or other people nearby cannot be controlled to below the occupational exposure limit and engineering controls and measures cannot reasonably be improved. Hand protection: When skin exposure may occur, advice may be sought from the glove suppliers on appropriate types. Barrier creams may help to protect exposed areas of the skin but are not substitutes for full physical protection. They should not be applied once exposure has occurred. Eye protection: Eye protection designed to protect against liquid splashes should be worn. Skin protection: Cotton or cotton/synthetic overalls are normally suitable. Grossly contaminated clothing should be removed and the skin washed with soap and water or a proprietary skin cleaner. (Sk) denotes product can be absorbed through skin. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Aerosol Store below 50 °C in a dry, well ventilated place away from sources of heat, ignition and direct sunlight. No smoking. Observe the label precautions. Store separately from strong oxidising agents and strongly alkaline and strongly acidic materials. 9804/8953 ISSUE 2 (REV.), APRIL 1997 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Ingredient Name OES/MEL 8hr TWA 15 min STEL Xylene, mixture of isomers OES 100 ppm 150 ppm (Sk) Acetone OES 750 ppm 1500 ppm 1-Methoxy-2-propanol OES 100 ppm 300 ppm (Sk) Butane OES 600 ppm 750 ppm 1-Methoxy Propan-2-ol Acetate OES 100 ppm (Sup) Aromatic hydrocarbon solvent blend OES 50 ppm - (Sup) Engineering measures: Provide adequate ventilation to maintain the flammable vapour concentration well below the lower explosive limit (LEL) and ensure the airborne concentration of substances to which an OES has been assigned is below that OES (Occupational Exposure Standard). Respiratory Protection: Air-fed respiratory equipment should be worn when this product is sprayed if the exposure of the sprayer or other people nearby cannot be controlled to below the occupational exposure limit and engineering controls and measures cannot reasonably be improved. Hand protection: When skin exposure may occur, advice may be sought from the glove suppliers on appropriate types. Barrier creams may help to protect exposed areas of the skin but are not substitutes for full physical protection. They should not be applied once exposure has occurred. Eye protection: Eye protection designed to protect against liquid splashes should be worn. Skin protection: Cotton or cotton/synthetic overalls are normally suitable. Grossly contaminated clothing should be removed and the skin washed with soap and water or a proprietary skin cleaner. (Sk) denotes product can be absorbed through skin. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Aerosol Store below 50 °C in a dry, well ventilated place away from sources of heat, ignition and direct sunlight. No smoking. Observe the label precautions. Store separately from strong oxidising agents and strongly alkaline and strongly acidic materials. 9804/8954 ISSUE 2 (REV.), APRIL 1997 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Ingredient Name OES/MEL 8hr TWA 15 min STEL Xylene, mixture of isomers OES 100 ppm 150 ppm (Sk) Acetone OES 750 ppm 1500 ppm 1-Methoxy-2-propanol OES 100 ppm 300 ppm (Sk) Butane OES 600 ppm 750 ppm 1-Methoxy Propan-2-ol Acetate OES 100 ppm (Sup) Aromatic hydrocarbon solvent blend OES 50 ppm - (Sup) Engineering measures: Provide adequate ventilation to maintain the flammable vapour concentration well below the lower explosive limit (LEL) and ensure the airborne concentration of substances to which an OES has been assigned is below that OES (Occupational Exposure Standard). Respiratory Protection: Air-fed respiratory equipment should be worn when this product is sprayed if the exposure of the sprayer or other people nearby cannot be controlled to below the occupational exposure limit and engineering controls and measures cannot reasonably be improved. Hand protection: When skin exposure may occur, advice may be sought from the glove suppliers on appropriate types. Barrier creams may help to protect exposed areas of the skin but are not substitutes for full physical protection. They should not be applied once exposure has occurred. Eye protection: Eye protection designed to protect against liquid splashes should be worn. Skin protection: Cotton or cotton/synthetic overalls are normally suitable. Grossly contaminated clothing should be removed and the skin washed with soap and water or a proprietary skin cleaner. (Sk) denotes product can be absorbed through skin. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Aerosol Store below 50 °C in a dry, well ventilated place away from sources of heat, ignition and direct sunlight. No smoking. Observe the label precautions. Store separately from strong oxidising agents and strongly alkaline and strongly acidic materials. 9804/8955 ISSUE 2 (REV.), APRIL 1997 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Ingredient Name OES/MEL 8hr TWA 15 min STEL Xylene, mixture of isomers OES 100 ppm 150 ppm (Sk) Acetone OES 750 ppm 1500 ppm 1-Methoxy-2-propanol OES 100 ppm 300 ppm (Sk) Butane OES 600 ppm 750 ppm 1-Methoxy Propan-2-ol Acetate OES 100 ppm (Sup) Aromatic hydrocarbon solvent blend OES 50 ppm - (Sup) Engineering measures: Provide adequate ventilation to maintain the flammable vapour concentration well below the lower explosive limit (LEL) and ensure the airborne concentration of substances to which an OES has been assigned is below that OES (Occupational Exposure Standard). Respiratory Protection: Air-fed respiratory equipment should be worn when this product is sprayed if the exposure of the sprayer or other people nearby cannot be controlled to below the occupational exposure limit and engineering controls and measures cannot reasonably be improved. Hand protection: When skin exposure may occur, advice may be sought from the glove suppliers on appropriate types. Barrier creams may help to protect exposed areas of the skin but are not substitutes for full physical protection. They should not be applied once exposure has occurred. Eye protection: Eye protection designed to protect against liquid splashes should be worn. Skin protection: Cotton or cotton/synthetic overalls are normally suitable. Grossly contaminated clothing should be removed and the skin washed with soap and water or a proprietary skin cleaner. (Sk) denotes product can be absorbed through skin. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Aerosol Although the storage of this product is not subject to specific statutory requirements, the principles contained in the HSE guidance note Storage of Flammable Liquids in Containers, should be observed. Observe the label precautions. Store between 5 °C and 25 °C in a dry, well ventilated place away from sources of heat, ignition and direct sunlight. No smoking. Prevent unauthorised access. Containers which are opened should be properly resealed and kept upright to prevent leakage. The principles contained in the HSE guidance note Storage of Packaged Dangerous Substances, should be observed when storing this product. Store separately from oxidising agents and strongly alkaline and strongly acidic materials. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Measures Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulates and/or solvent vapours below the relevant occupational exposure limits, suitable respiratory protective equipment should be worn (see ‘Personal Protection’ below). Cont..... 9804/8926 ISSUE 5 (REV.), MARCH 2002 Observe the label precautions. Store between 5 °C and 25 °C in a dry, well ventilated place away from sources of heat, ignition and direct sunlight. Prevent unauthorised access. Containers which are open should be properly resealed and kept upright to prevent leakage. Store separately from oxidising agents and strongly alkaline materials. No smoking. Although the storage of this product is not subject to specific statutory requirements, the principles of the HSE Guidance Note HS(G)51 Storage of Flammable Liquids in Containers should be observed. The principles contained in the HSE Guidance Note Storage of Packaged Dangerous Substances, should be observed. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Measures Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust and good general ventilation. If these are insufficient to maintain concentrations of particulates and/or solvent vapours to below the relevant occupational exposure limits, then suitable respiratory protection should be worn (see 8 ‘Personal Protection’). Exposure Limits Occupational exposure limits Substance 8 hr TWA (1) 15 min STEL (2) Notations (3) ppm (4) mgm/m3 (4) ppm (4) mgm/m3 (4) White spirit 100 575 125 720 Lead - 0.15 Chromium - 0.5 NOTES: 1 Long term exposure limit - 8 hour time weighted average. 2 Short term exposure limit - 15 minute reference period. 3 ‘Sk’ indicates risks of absorbtion through the skin. ‘Sen’ indicates a respiratory sensitiser. 4 ‘OES’ indicates an occupational exposure standard. ‘MEL’ indicates a maximum exposure limit. OELs are taken from the current version of EH40 except those marked ‘SUP’ which are assigned by the supplier of the substance. G.V indicates Guidance Value (see EH40/95) Personal Protection All ppe, including rpe, used to control exposure to hazardous substances must be selected to meet the requirements of the COSHH Regulations. Respiratory Protection [Applicable to sprayed coatings containing solvents but not isocyanates.] Air fed respiratory protection should be worn when this product is sprayed if the exposure of the sprayer or other people nearby cannot be controlled to below the OES and Engineering Controls and other methods cannot be reasonably improved. Hand Protection Where skin exposure may occur, advice should be sought from glove suppliers on appropriate types. Barrier creams may help to protect exposed areas of skin but are not substitutes for full physical protection. They should not be applied once exposure has commenced. Eye Protection Eye protection designed to protect against liquid splashes should be worn. Skin Protection Cotton or cotton/synthetic overalls are normally suitable. Disposables offer protection during short periods of high exposure i.e. spraying. 9804/8919 ISSUE 3 (REV.), APRIL 1997 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Flash Point (closed cup): 38°C Viscosity: Mobile liquid Specific Gravity: 1.2 kg/litre Vapour Density: Heavier than air Lower Explosion Limit: 0.8% Solubility in Water: Immiscible 10. STABILITY AND REACTIVITY Stable under the recommended storage and handling conditions (see Section 7). In a fire, hazardous decomposition products such as smoke, carbon monoxide, carbon dioxide, nitrogen oxides may be produced. Keep away from oxidising agents and strongly alkaline or acidic materials to prevent the possibility of exothermic reactions occurring. Observe the label precautions. Store between 5 °C and 25 °C in a dry, well ventilated place away from sources of heat, ignition and direct sunlight. Prevent unauthorised access. Containers which are open should be properly resealed and kept upright to prevent leakage. Store separately from oxidising agents and strongly alkaline materials. No smoking. Although the storage of this product is not subject to specific statutory requirements, the principles of the HSE Guidance Note HS(G)51 Storage of Flammable Liquids in Containers should be observed. The principles contained in the HSE Guidance Note Storage of Packaged Dangerous Substances, should be observed. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Measures Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust and good general ventilation. If these are insufficient to maintain concentrations of particulates and/or solvent vapours to below the relevant occupational exposure limits, then suitable respiratory protection should be worn (see 8 ‘Personal Protection’). Exposure Limits Occupational exposure limits Substance 8 hr TWA (1) 15 min STEL (2) Notations (3) ppm (4) mgm/m3 (4) ppm (4) mgm/m3 (4) White spirit 100 575 125 720 Lead - 0.15 Chromium - 0.5 NOTES: 1 Long term exposure limit - 8 hour time weighted average. 2 Short term exposure limit - 15 minute reference period. 3 ‘Sk’ indicates risks of absorbtion through the skin. ‘Sen’ indicates a respiratory sensitiser. 4 ‘OES’ indicates an occupational exposure standard. ‘MEL’ indicates a maximum exposure limit. OELs are taken from the current version of EH40 except those marked ‘SUP’ which are assigned by the supplier of the substance. G.V indicates Guidance Value (see EH40/95) Personal Protection All ppe, including rpe, used to control exposure to hazardous substances must be selected to meet the requirements of the COSHH Regulations. Respiratory Protection [Applicable to sprayed coatings containing solvents but not isocyanates.] Air fed respiratory protection should be worn when this product is sprayed if the exposure of the sprayer or other people nearby cannot be controlled to below the OES and Engineering Controls and other methods cannot be reasonably improved. Hand Protection Where skin exposure may occur, advice should be sought from glove suppliers on appropriate types. Barrier creams may help to protect exposed areas of skin but are not substitutes for full physical protection. They should not be applied once exposure has commenced. Eye Protection Eye protection designed to protect against liquid splashes should be worn. Skin Protection Cotton or cotton/synthetic overalls are normally suitable. Disposables offer protection during short periods of high exposure i.e. spraying. 9804/8918 ISSUE 4 (REV.), NOVEMBER 1997 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Flash Point (closed cup): 38°C Viscosity: Mobile liquid Specific Gravity: 1.2 kg/litre Vapour Density: Heavier than air Lower Explosion Limit: 0.8% Solubility in Water: Immiscible 10. STABILITY AND REACTIVITY Stable under the recommended storage and handling conditions (see Section 7). In a fire, hazardous decomposition products such as smoke, carbon monoxide, carbon dioxide, nitrogen oxides may be produced. Keep away from oxidising agents and strongly alkaline or acidic materials to prevent the possibility of exothermic reactions occurring. Observe the label precautions. Store between 5 °C and 25 °C in a dry, well ventilated place away from sources of heat, ignition and direct sunlight. Prevent unauthorised access. Containers which are open should be properly resealed and kept upright to prevent leakage. Store separately from oxidising agents and strongly alkaline materials. No smoking. Although the storage of this product is not subject to specific statutory requirements, the principles of the HSE Guidance Note HS(G)51 Storage of Flammable Liquids in Containers should be observed. The principles contained in the HSE Guidance Note Storage of Packaged Dangerous Substances, should be observed. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Measures Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust and good general ventilation. If these are insufficient to maintain concentrations of particulates and/or solvent vapours to below the relevant occupational exposure limits, then suitable respiratory protection should be worn (see 8 ‘Personal Protection’). Exposure Limits Occupational exposure limits Substance 8 hr TWA (1) 15 min STEL (2) Notations (3) ppm (4) mgm/m3 (4) ppm (4) mgm/m3 (4) White spirit 100 575 125 720 Lead - 0.15 Chromium - 0.5 NOTES: 1 Long term exposure limit - 8 hour time weighted average. 2 Short term exposure limit - 15 minute reference period. 3 ‘Sk’ indicates risks of absorbtion through the skin. ‘Sen’ indicates a respiratory sensitiser. 4 ‘OES’ indicates an occupational exposure standard. ‘MEL’ indicates a maximum exposure limit. OELs are taken from the current version of EH40 except those marked ‘SUP’ which are assigned by the supplier of the substance. G.V indicates Guidance Value (see EH40/95) Personal Protection All ppe, including rpe, used to control exposure to hazardous substances must be selected to meet the requirements of the COSHH Regulations. Respiratory Protection [Applicable to sprayed coatings containing solvents but not isocyanates.] Air fed respiratory protection should be worn when this product is sprayed if the exposure of the sprayer or other people nearby cannot be controlled to below the OES and Engineering Controls and other methods cannot be reasonably improved. Hand Protection Where skin exposure may occur, advice should be sought from glove suppliers on appropriate types. Barrier creams may help to protect exposed areas of skin but are not substitutes for full physical protection. They should not be applied once exposure has commenced. Eye Protection Eye protection designed to protect against liquid splashes should be worn. Skin Protection Cotton or cotton/synthetic overalls are normally suitable. Disposables offer protection during short periods of high exposure i.e. spraying. 9804/8917 ISSUE 4 (REV.), NOVEMBER 1997 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Flash Point (closed cup): 38°C Viscosity: Mobile liquid Specific Gravity: 1.2 kg/litre Vapour Density: Heavier than air Lower Explosion Limit: 0.8% Solubility in Water: Immiscible 10. STABILITY AND REACTIVITY Stable under the recommended storage and handling conditions (see Section 7). In a fire, hazardous decomposition products such as smoke, carbon monoxide, carbon dioxide, nitrogen oxides may be produced. Keep away from oxidising agents and strongly alkaline or acidic materials to prevent the possibility of exothermic reactions occurring. Although the storage of this product is not subject to specific statutory requirements, the principles contained in the HSE guidance note Storage of Flammable Liquids in Containers, should be observed. Observe the label precautions. Store between 5 °C and 25 °C in a dry, well ventilated place away from sources of heat, ignition and direct sunlight. No smoking. Prevent unauthorised access. Containers which are opened should be properly resealed and kept upright to prevent leakage. The principles contained in the HSE guidance note Storage of Packaged Dangerous Substances, should be observed when storing this product. Store separately from oxidising agents and strongly alkaline and strongly acidic materials. * 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Measures Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulates and/or solvent vapours below the relevant occupational exposure limits, suitable respiratory protective equipment should be worn (see ‘Personal Protection’ below). Exposure Limits Occupational Exposure Standards and/or Maximum Exposure Limits have been established by the Health and Safety Commission or recommended by the supplier for certain of the ingredients. OELs are taken from the current versions of EH40 except those marked ‘Sup’, which are assigned by the supplier of the substance. Occupational exposure limits Substance 8 hr TWA (†) 15 min STEL(‡) Notes White spirit 600.0 mg/m3 (OELsol) (†) Long term exposure limit - 8 hour time weighted average. (‡) Short term exposure limit - 15 minute reference period. (OELsol) Occupational exposure limit of the hydrocarbon solvent mixture (set by supplier) Further guidance on OES/MEL and the assessment of occupational exposure to harmful materials, including mixed exposures, is given in HSE Guidance Note EH40. Personal Protection All personal protective equipment, including respiratory protective equipment, used to control exposure to hazardous substances must be selected to meet the requirements of the COSHH Regulations. Respiratory Protection If exposure to hazardous substances identified above cannot be controlled by the provision of local exhaust ventilation and good general extraction, suitable respiratory protective equipment should be worn. cont’d 9804/8958 ISSUE 3 (REV.), FEB 2002 Observe the label precautions. Store between 5 °C and 25 °C in a dry, well ventilated place away from sources of heat, ignition and direct sunlight. Prevent unauthorised access. Containers which are open should be properly resealed and kept upright to prevent leakage. Store separately from oxidising agents and strongly alkaline materials. No smoking. Although the storage of this product is not subject to specific statutory requirements, the principles of the HSE Guidance Note HS(G)51 Storage of Flammable Liquids in Containers should be observed. The principles of the HSE Guidance Note Storage of Packaged Dangerous Substances should be observed. 9804/8920 ISSUE 5 (REV.), JUNE 2002 Although the storage of this product is not subject to specific statutory requirements, the principles contained in the HSE guidance note Storage of Flammable Liquids in Containers, should be observed. Observe the label precautions. Store between 5 °C and 25 °C in a dry, well ventilated place away from sources of heat, ignition and direct sunlight. No smoking. Prevent unauthorised access. Containers which are opened should be properly resealed and kept upright to prevent leakage. The principles contained in the HSE guidance note Storage of Packaged Dangerous Substances, should be observed when storing this product. Store separately from oxidising agents and strongly alkaline and strongly acidic materials. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Measures Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulates and/or solvent vapours below the relevant occupational exposure limits, suitable respiratory protective equipment should be worn (see ‘Personal Protection’ below). Exposure Limits Occupational Exposure Standards and/or Maximum Exposure Limits have been established by the Health and Safety Commission or recommended by the supplier for certain of the ingredients. OELs are taken from the current versions of EH40 except those marked ‘Sup’, which are assigned by the supplier of the substance. Occupational exposure limits Substance 8 hr TWA (†) 15 min STEL(‡) Notes White spirit 100 ppm (OES) 125 ppm (OES) (†) Long term exposure limit - 8 hour time weighted average. (‡) Short term exposure limit - 15 minute reference period. (OES) Occupational exposure standard. Further guidance on OES/MEL and the assessment of occupational exposure to harmful materials, including mixed exposures, is given in HSE Guidance Note EH40. Personal Protection All personal protective equipment, including respiratory protective equipment, used to control exposure to hazardous substances must be selected to meet the requirements of the COSHH Regulations. cont’d 9804/8914 ISSUE 2 (REV.), MARCH 1997 Respiratory Protection Air-fed respiratory protective equipment should be worn when this product is sprayed if the exposure of the sprayer or other people nearby cannot be controlled to below the Occupational Exposure Limit and engineering controls and methods cannot reasonably be improved. Dry sanding, flame cutting and/or welding of the dry paint film will give rise to dust and/or hazardous fumes. Wet sanding should be used wherever possible. If exposure cannot be avoided by the provision of local exhaust ventilation, suitable respiratory protective equipment should be used. Hand Protection When skin exposure may occur, advice should be sought from glove suppliers on appropriate types. Barrier creams may help to protect exposed areas of skin but are not substitutes for full physical protection. They should not be applied once exposure has occurred. Eye Protection Eye protection designed to protect against liquid splashes should be worn. Skin Protection Cotton or cotton/synthetic overalls or coveralls are normally suitable. Grossly contaminated clothing should be removed and the skin washed with soap and water or a proprietary skin cleaner. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Viscous liquid Odour: Characteristic odour Colour: Various Specific Gravity: 0.9 g/cm3 Viscosity: 1.5 - 2.5 poise BS3900 : Part A7 at 25 °C Flash Point: 36 °C Volatile Organic Content: 489 g/ltr Explosion limit - lower: 0.6% Water Solubility: Immiscible 10. STABILITY AND REACTIVITY Stable under the recommended storage and handling conditions (see Section 7). In a fire, hazardous decomposition products such as smoke, carbon monoxide, carbon dioxide and oxides of nitrogen may be produced. Keep away from oxidising agents and strongly alkaline and strongly acidic materials to prevent the possibility of exothermic reaction. Although the storage of this product is not subject to specific statutory requirements, the principles contained in the HSE guidance note Storage of Flammable Liquids in Containers, should be observed. Observe the label precautions. Store between 5 °C and 25 °C in a dry, well ventilated place away from sources of heat, ignition and direct sunlight. No smoking. Prevent unauthorised access. Containers which are opened should be properly resealed and kept upright to prevent leakage. The principles contained in the HSE guidance note Storage of Packaged Dangerous Substances, should be observed when storing this product. Store separately from oxidising agents and strongly alkaline and strongly acidic materials. 9804/8927 ISSUE 3 (REV.), MARCH 1997 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Measures Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulates and/or solvent vapours below the relevant occupational exposure limits, suitable respiratory protective equipment should be worn (see ‘Personal Protection’ below). Exposure Limits Occupational Exposure Standards and/or Maximum Exposure Limits have been established by the Health and Safety Commission or recommended by the supplier for certain of the ingredients. OELs are taken from the current versions of EH40 except those marked ‘Sup’, which are assigned by the supplier of the substance. Occupational exposure limits Substance 8 hr TWA (†) 15 min STEL(‡) Notes Lead compounds 0.15 mg/m3 (MEL) White spirit 100 ppm (OES) 125 ppm (OES) (†) Long term exposure limit - 8 hour time weighted average. (‡) Short term exposure limit - 15 minute reference period. (OES) Occupational exposure standard. (MEL) Maximum exposure limit. Further guidance on OES/MEL and the assessment of occupational exposure to harmful materials, including mixed exposures, is given in HSE Guidance Note EH40. Personal Protection All personal protective equipment, including respiratory protective equipment, used to control exposure to hazardous substances must be selected to meet the requirements of the COSHH Regulations. Respiratory Protection Air-fed respiratory protective equipment should be worn when this product is sprayed if the exposure of the sprayer or other people nearby cannot be controlled to below the Occupational Exposure Limit and engineering controls and methods cannot reasonably be improved. When spraying colours containing lead chromate (listed in Section 1), air-fed respiratory protective equipment must be worn. This should be in addition to other measures taken to reduce exposure (e.g. in booth design and operation, and process modifications). Non- essential and unprotected people should be excluded from the area if exposure is possible. Dry sanding, flame cutting and/or welding of the dry paint film will give rise to dust and/or hazardous fumes. Wet sanding should be used wherever possible. If exposure cannot be avoided by the provision of local exhaust ventilation, suitable respiratory protective equipment should be used. Hand Protection When skin exposure may occur, advice should be sought from glove suppliers on appropriate types. Barrier creams may help to protect exposed areas of skin but are not substitutes for full physical protection. They should not be applied once exposure has occurred. Eye Protection Eye protection designed to protect against liquid splashes should be worn. Skin Protection Cotton or cotton/synthetic overalls or coveralls are normally suitable. Grossly contaminated clothing should be removed and the skin washed with soap and water or a proprietary skin cleaner. 9804/8927 ISSUE 3 (REV.), MARCH 1997 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Viscous liquid Odour: Characteristic odour Colour: Various Specific Gravity: 1.1 g/cm3 Viscosity: 1.8 - 2.2 poise BS3900 : Part A7 at 25 °C Flash Point: 39 °C Volatile Organic Content: 474 g/ltr Explosion limit - lower: 0.6% Water Solubility: Immiscible 10. STABILITY AND REACTIVITY Stable under the recommended storage and handling conditions (see Section 7). In a fire, hazardous decomposition products such as smoke, carbon monoxide, carbon dioxide and oxides of nitrogen may be produced. Keep away from oxidising agents and strongly alkaline and strongly acidic materials to prevent the possibility of exothermic reaction. Although the storage of this product is not subject to specific statutory requirements, the principles contained in the HSE guidance note Storage of Flammable Liquids in Containers, should be observed. Observe the label precautions. Store between 5 °C and 25 °C in a dry, well ventilated place away from sources of heat, ignition and direct sunlight. No smoking. Prevent unauthorised access. Containers which are opened should be properly resealed and kept upright to prevent leakage. The principles contained in the HSE guidance note Storage of Packaged Dangerous Substances, should be observed when storing this product. Store separately from oxidising agents and strongly alkaline and strongly acidic materials. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Measures Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulates and/or solvent vapours below the relevant occupational exposure limits, suitable respiratory protective equipment should be worn (see ‘Personal Protection’ below). Exposure Limits Occupational Exposure Standards and/or Maximum Exposure Limits have been established by the Health and Safety Commission or recommended by the supplier for certain of the ingredients. OELs are taken from the current versions of EH40 except those marked ‘Sup’, which are assigned by the supplier of the substance. Occupational exposure limits Substance 8 hr TWA (†) 15 min STEL(‡) Notes Lead compounds 0.15 mg/m3 (MEL) White spirit 100 ppm (OES) 125 ppm (OES) (†) Long term exposure limit - 8 hour time weighted average. (‡) Short term exposure limit - 15 minute reference period. (OES) Occupational exposure standard. (MEL) Maximum exposure limit. Further guidance on OES/MEL and the assessment of occupational exposure to harmful materials, including mixed exposures, is given in HSE Guidance Note EH40. cont’d 9804/8957 ISSUE 4 (REV.), JUNE 2002 Although the storage of this product is not subject to specific statutory requirements, the principles contained in the HSE guidance note Storage of Flammable Liquids in Containers, should be observed. Observe the label precautions. Store between 5 °C and 25 °C in a dry, well ventilated place away from sources of heat, ignition and direct sunlight. No smoking. Prevent unauthorised access. Containers which are opened should be properly resealed and kept upright to prevent leakage. The principles contained in the HSE guidance note Storage of Packaged Dangerous Substances, should be observed when storing this product. Store separately from oxidising agents and strongly alkaline and strongly acidic materials. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Measures Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulates and/or solvent vapours below the relevant occupational exposure limits, suitable respiratory protective equipment should be worn (see ‘Personal Protection’ below). Exposure Limits Occupational Exposure Standards and/or Maximum Exposure Limits have been established by the Health and Safety Commission or recommended by the supplier for certain of the ingredients. OELs are taken from the current versions of EH40 except those marked ‘Sup’, which are assigned by the supplier of the substance. Occupational exposure limits Substance 8 hr TWA (†) 15 min STEL(‡) Notes White spirit 600.0 mg/m3 (OELsol) (†) Long term exposure limit - 8 hour time weighted average. (‡) Short term exposure limit - 15 minute reference period. (OELsol) Occupational exposure limit of the hydrocarbon solvent mixture (set by supplier) Further guidance on OES/MEL and the assessment of occupational exposure to harmful materials, including mixed exposures, is given in HSE Guidance Note EH40. Personal Protection All personal protective equipment, including respiratory protective equipment, used to control exposure to hazardous substances must be selected to meet the requirements of the COSHH Regulations. cont’d 9804/8916 ISSUE 5 (REV.), JUNE 2002 Although the storage of this product is not subject to specific statutory requirements, the principles contained in the HSE guidance note Storage of Flammable Liquids in Containers, should be observed. Observe the label precautions. Store between 5 °C and 25 °C in a dry, well ventilated place away from sources of heat, ignition and direct sunlight. No smoking. Prevent unauthorised access. Containers which are opened should be properly resealed and kept upright to prevent leakage. The principles contained in the HSE guidance note Storage of Packaged Dangerous Substances, should be observed when storing this product. Store separately from oxidising agents and strongly alkaline and strongly acidic materials. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Measures Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulates and/or solvent vapours below the relevant occupational exposure limits, suitable respiratory protective equipment should be worn (see ‘Personal Protection’ below). Exposure Limits Occupational Exposure Standards and/or Maximum Exposure Limits have been established by the Health and Safety Commission or recommended by the supplier for certain of the ingredients. OELs are taken from the current versions of EH40 except those marked ‘Sup’, which are assigned by the supplier of the substance. Occupational exposure limits Substance 8 hr TWA (†) 15 min STEL(‡) Notes White spirit 100 ppm (OES) 125 ppm (OES) (†) Long term exposure limit - 8 hour time weighted average. (‡) Short term exposure limit - 15 minute reference period. (OES) Occupational exposure standard. Further guidance on OES/MEL and the assessment of occupational exposure to harmful materials, including mixed exposures, is given in HSE Guidance Note EH40. Personal Protection All personal protective equipment, including respiratory protective equipment, used to control exposure to hazardous substances must be selected to meet the requirements of the COSHH Regulations. Respiratory Protection Air-fed respiratory protective equipment should be worn when this product is sprayed if the exposure of the sprayer or other people nearby cannot be controlled to below the Occupational Exposure Limit and engineering controls and methods cannot reasonably be improved. Dry sanding, flame cutting and/or welding of the dry paint film will give rise to dust and/or hazardous fumes. Wet sanding should be used wherever possible. If exposure cannot be avoided by the provision of local exhaust ventilation, suitable respiratory protective equipment should be used. Hand Protection When skin exposure may occur, advice should be sought from glove suppliers on appropriate types. cont’d 9804/8923 ISSUE 5 (REV.), JUNE 2002 Although the storage of this product is not subject to specific statutory requirements, the principles contained in the HSE guidance note Storage of Flammable Liquids in Containers, should be observed. Observe the label precautions. Store between 5 °C and 25 °C in a dry, well ventilated place away from sources of heat, ignition and direct sunlight. No smoking. Prevent unauthorised access. Containers which are opened should be properly resealed and kept upright to prevent leakage. The principles contained in the HSE guidance note Storage of Packaged Dangerous Substances, should be observed when storing this product. Store separately from oxidising agents and strongly alkaline and strongly acidic materials. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Measures Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulars and/or solvent vapours below the relevant occupational exposure limits, suitable respiratory protective equipment should be worn (see ‘Personal Protection’ below). Exposure Limits Occupational Exposure Standards and/or Maximum Exposure Limits have been established by the Health and Safety Commission or recommended by the supplier for certain of the ingredients. OELs are taken from the current versions of EH40 except those marked ‘Sup’, which are assigned by the supplier of the substance. Occupational exposure limits Substance 8 hr TWA (†) 15 min STEL(‡) Notes Lead compounds 0.15 mg/m3 (MEL) White spirit 100ppm (OES) 125 ppm (OES) (†) Long term exposure limit - 8 hour time weighted average. (‡) Short term exposure limit - 15 minute reference period. (OES) Occupational exposure standard. (MEL) Maximum exposure limit. Further guidance on OES/MEL and the assessment of occupational exposure to harmful materials, including mixed exposures, is given in HSE Guidance Note EH40. Personal Protection All personal protective equipment, including respiratory protective equipment, used to control exposure to hazardous substances must be selected to meet the requirements of the COSHH Regulations. cont’d 9804/8915 ISSUE 4 (REV.), NOVEMBER 1997 Respiratory Protection Air-fed respiratory protective equipment should be worn when this product is sprayed. This should be in addition to other measures taken to reduce exposure (e.g. in booth design and operation and process modifications). Non-essential and unprotected people should be excluded from the area if exposure is possible. When operators, whether spraying or not, have to work inside the spray booth, they should wear an air-fed respirator during the spraying process and until such time as the spray mist has cleared. However, persons entering the spray booths or enclosures for short periods (less than 15 minutes) when spraying is taking place may be protected from inhaling the spray mist by wearing suitable respirators with charcoal canisters. Care should be taken to ensure that filters are changed in accordance with the supplier’s instructions. The use of a canister respirator is considered very much a second choice to air-fed respiratory protective equipment. Dry sanding, flame cutting and/or welding of the dry paint film will give rise to dust and/or hazardous fumes. Wet sanding should be used wherever possible. If exposure cannot be avoided by the provision of local exhaust ventilation, suitable respiratory protective equipment should be used. Hand Protection When skin exposure may occur, advice should be sought from glove suppliers on appropriate types. Barrier creams may help to protect exposed areas of skin but are not substitutes for full physical protection. They should not be applied once exposure has occurred. Eye Protection Eye protection designed to protect against liquid splashes should be worn. Skin Protection Cotton or cotton/synthetic overalls or coveralls are normally suitable. Grossly contaminated clothing should be removed and the skin washed with soap and water or a proprietary skin cleaner. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Viscous liquid Odour: Characteristic odour Colour: Yellow Specific Gravity: 1.4 g/cm3 Viscosity: 0.8-1.3 poise BS3900: Part A7 at 25°C Flash Point: 46 °C Volatile Organic Content: 437 g/ltr Explosion limit - lower: 0.6% Water Solubility: Immiscible 10. STABILITY AND REACTIVITY Stable under the recommended storage and handling conditions (see Section 7). In a fire, hazardous decomposition products such as smoke, carbon monoxide, carbon dioxide and oxides of nitrogen may be produced. Keep away from oxidising agents and strongly alkaline and strongly acidic materials to prevent the possibility of exothermic reaction. Although the storage of this product is not subject to specific statutory requirements, the principles contained in the HSE guidance note Storage of Flammable Liquids in Containers, should be observed. Observe the label precautions. Store between 5 °C and 25 °C in a dry, well ventilated place away from sources of heat, ignition and direct sunlight. No smoking. Prevent unauthorised access. Containers which are opened should be properly resealed and kept upright to prevent leakage. The principles contained in the HSE guidance note Storage of Packaged Dangerous Substances, should be observed when storing this product. Store separately from oxidising agents and strongly alkaline and strongly acidic materials. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Measures Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulates and/or solvent vapours below the relevant occupational exposure limits, suitable respiratory protective equipment should be worn (see ‘Personal Protection’ below). Exposure Limits Occupational Exposure Standards and/or Maximum Exposure Limits have been established by the Health and Safety Commission or recommended by the supplier for certain of the ingredients. OELs are taken from the current versions of EH40 except those marked ‘Sup’, which are assigned by the supplier of the substance. Occupational exposure limits Substance 8 hr TWA (†) 15 min STEL(‡) Notes Lead compounds 0.15 mg/m3 (MEL) White spirit 100ppm (OES) 125 ppm (OES) (†) Long term exposure limit - 8 hour time weighted average. (‡) Short term exposure limit - 15 minute reference period. (OES) Occupational exposure standard. (MEL) Maximum exposure limit. Further guidance on OES/MEL and the assessment of occupational exposure to harmful materials, including mixed exposures, is given in HSE Guidance Note EH40. cont’d 9804/8922 ISSUE 5 (REV.), JUNE 2002 Observe the label precautions. Store between 5 °C and 25 °C in a dry, well ventilated place away from sources of heat, ignition and direct sunlight. Prevent unauthorised access. Containers which are open should be properly resealed and kept upright to prevent leakage. Store separately from oxidising agents and strongly acidic and alkaline materials. No smoking. Although the storage of this product is not subject to specific statutory requirements, the principles of the HSE Guidance Note HS(G)51 Storage of Flammable Liquids in Containers should be observed. The principles of the HSE Guidance Note Storage of Packed Dangerous Substances should be observed. 9804/8929 ISSUE 4 (REV.), JUNE 2002 Although the storage of this product is not subject to specific statutory requirements, the principles contained in the HSE guidance note Storage of Flammable Liquids in Containers, should be observed. Observe the label precautions. Store between 5 °C and 25 °C in a dry, well ventilated place away from sources of heat, ignition and direct sunlight. No smoking. Prevent unauthorised access. Containers which are opened should be properly resealed and kept upright to prevent leakage. The principles contained in the HSE guidance note Storage of Packaged Dangerous Substances, should be observed when storing this product. Store separately from oxidising agents and strongly alkaline and strongly acidic materials. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Measures Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulates and/or solvent vapours below the relevant occupational exposure limits, suitable respiratory protective equipment should be worn (see ‘Personal Protection’ below). Exposure Limits Occupational Exposure Standards and/or Maximum Exposure Limits have been established by the Health and Safety Commission or recommended by the supplier for certain of the ingredients. OELs are taken from the current versions of EH40 except those marked ‘Sup’, which are assigned by the supplier of the substance. Occupational exposure limits Substance 8 hr TWA (†) 15 min STEL(‡) Notes 1-methoxypropan-2-ol 100 ppm (OES) 300 ppm (OES) Skin Mesitylene 25 ppm (OES) Xylene (mixture of isomers) 100 ppm (OES) 150 ppm (OES) Skin (†) Long term exposure limit - 8 hour time weighted average. (‡) Short term exposure limit - 15 minute reference period. (OES) Occupational exposure standard. (Skin) There is a risk of absorption through unbroken skin. Further guidance on OES/MEL and the assessment of occupational exposure to harmful materials, including mixed exposures, is given in HSE Guidance Note EH40. Personal Protection All personal protective equipment, including respiratory protective equipment, used to control exposure to hazardous substances must be selected to meet the requirements of the COSHH Regulations. Respiratory Protection If exposure to hazardous substances identified above cannot be controlled by the provision of local exhaust ventilation and good general extraction, suitable respiratory protective equipment should be worn. Dry sanding, flame cutting and/or welding of the dry paint film will give rise to dust and/or hazardous fumes. Wet sanding should be used wherever possible. If exposure cannot be avoided by the provision of local exhaust ventilation, suitable respiratory protective equipment should be used. cont’d 9804/8964 ISSUE 3 (REV.), JUNE 2002 The storage and use of this product is subject to the requirements of the Highly Flammable Liquids and Liquefied Petroleum Gases Regulations. Up to 50 litres of such highly flammable liquids may be kept in a work room provided they are kept in a fire-proof cupboard or bin. Larger quantities must be kept in a separate storeroom conforming to the structural requirements of the regulations. Further guidance is contained in the HSE guidance note Storage of Flammable Liquids in Containers. Observe the label precautions. Store between 5 °C and 25 °C in a dry, well ventilated place away from sources of heat, ignition and direct sunlight. No smoking. Prevent unauthorised access. Containers which are opened should be properly resealed and kept upright to prevent leakage. The principles contained in the HSE guidance note Storage of Packaged Dangerous Substances, should be observed when storing this product. Store separately from oxidising agents and strongly alkaline and strongly acidic materials. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Measures Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulates and/or solvent vapours below the relevant occupational exposure limits, suitable respiratory protective equipment should be worn (see ‘Personal Protection’ below). Exposure Limits Occupational Exposure Standards and/or Maximum Exposure Limits have been established by the Health and Safety Commission or recommended by the supplier for certain of the ingredients. OELs are taken from the current versions of EH40 except those marked ‘Sup’, which are assigned by the supplier of the substance. Occupational exposure limits Substance 8 hr TWA (†) 15 min STEL(‡) Notes 1-methoxypropan-2-ol 100 ppm (OES) 300 ppm (OES) Skin Mesitylene 25 ppm (OES) Xylene (mixture of isomers) 100 ppm (OES) 150 ppm (OES) Skin 9804/8965 ISSUE 3 (REV.), NOVEMBER 1997 8. EXPOSURE CONTROLS/PERSONAL PROTECTION continued (†) Long term exposure limit - 8 hour time weighted average. (‡) Short term exposure limit - 15 minute reference period. (OES) Occupational exposure standard. (Skin) There is a risk of absorption through unbroken skin. Further guidance on OES/MEL and the assessment of occupational exposure to harmful materials, including mixed exposures, is given in HSE Guidance Note EH40. Personal Protection All personal protective equipment, including respiratory protective equipment, used to control exposure to hazardous substances must be selected to meet the requirements of the COSHH Regulations. * Respiratory Protection Air-fed respiratory protective equipment should be worn when this product is sprayed. This should be in addition to other measures taken to reduce exposure (e.g. in booth design and operation and process modifications). Non-essential and unprotected people should be excluded from the area if exposure is possible When operators, whether spraying or not, have to work inside the spray booth, they should wear an air-fed respirator during the spraying process and until such time as the spray mist has cleared. However, persons entering the spray booths or enclosures for short periods (less than 15 minutes) when spraying is taking place may be protected from inhaling the spray mist by wearing suitable respirators with charcoal canisters. Care should be taken to ensure that filters are changed in accordance with the supplier’s instructions. The use of a canistor respirator is considered very much a second choice to air-fed respiratory protective equipment. When spraying colours containing lead chromate (listed in Section 1), air-fed respiratory protective equipment must be worn. This should be in addition to other measures taken to reduce exposure (e.g. in booth design and operation, and process modifications). Non- essential and unprotected people should be excluded from the area if exposure is possible. Dry sanding, flame cutting and/or welding of the dry paint film will give rise to dust and/or hazardous fumes. Wet sanding should be used wherever possible. If exposure cannot be avoided by the provision of local exhaust ventilation, suitable respiratory protective equipment should be used. Hand Protection When skin exposure may occur, advice should be sought from glove suppliers on appropriate types. Barrier creams may help to protect exposed areas of skin but are not substitutes for full physical protection. They should not be applied once exposure has occurred. Eye Protection Eye protection designed to protect against liquid splashes should be worn. Skin Protection Cotton or cotton/synthetic overalls or coveralls are normally suitable. Grossly contaminated clothing should be removed and the skin washed with soap and water or a proprietary skin cleaner. 9. PHYSICAL AND CHEMICAL PROPERTIES The figures given below, unless otherwise stated, refer to the composite material. Physical State: Viscous liquid Odour: Characteristic odour Colour: Various * Specific Gravity: 1.2 g/cm3 * Viscosity - base: 2.0-2.6 poise BS3900: Part A7 at 25°C * Viscosity - additive: 34-42 seconds B2 cup at 20°C * Flash Point - base: 25°C * Flash Point - additive: 32 °C * Volatile Organic Content: 591 g/ltr Explosion limit - lower: 0.8% Water Solubility: Immiscible 9804/8965 ISSUE 3 (REV.), NOVEMBER 1997 10. STABILITY AND REACTIVITY Stable under the recommended storage and handling conditions (see Section 7). In a fire, hazardous decomposition products such as smoke, carbon monoxide, carbon dioxide and oxides of nitrogen may be produced. Keep away from oxidising agents and strongly alkaline and strongly acidic materials to prevent the possibility of exothermic reaction. The storage and use of this product is subject to the requirements of the Highly Flammable Liquids and Liquefied Petroleum Gases Regulations. Up to 50 litres of such highly flammable liquids may be kept in a work room provided they are kept in a fire-proof cupboard or bin. Larger quantities must be kept in a separate storeroom conforming to the structural requirements of the regulations. Further guidance is contained in the HSE guidance note Storage of Flammable Liquids in Containers. Observe the label precautions. Store between 5 °C and 25 °C in a dry, well ventilated place away from sources of heat, ignition and direct sunlight. No smoking. Prevent unauthorised access. Containers which are opened should be properly resealed and kept upright to prevent leakage. The principles contained in the HSE guidance note Storage of Packaged Dangerous Substances, should be observed when storing this product. Store separately from oxidising agents and strongly alkaline and strongly acidic materials. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Measures Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulates and/or solvent vapours below the relevant occupational exposure limits, suitable respiratory protective equipment should be worn (see ‘Personal Protection’ below). Exposure Limits Occupational Exposure Standards and/or Maximum Exposure Limits have been established by the Health and Safety Commission or recommended by the supplier for certain of the ingredients. OELs are taken from the current versions of EH40 except those marked ‘Sup’, which are assigned by the supplier of the substance. Occupational exposure limits Substance 8 hr TWA (†) 15 min STEL(‡) Notes 1-methoxypropan-2-ol 100 ppm (OES) 300 ppm (OES) Skin Mesitylene 25 ppm (OES) (†) Long term exposure limit - 8 hour time weighted average. (‡) Short term exposure limit - 15 minute reference period. (OES) Occupational exposure standard. (Skin) There is a risk of absorption through unbroken skin. Further guidance on OES/MEL and the assessment of occupational exposure to harmful materials, including mixed exposures, is given in HSE Guidance Note EH40. Personal Protection All personal protective equipment, including respiratory protective equipment, used to control exposure to hazardous substances must be selected to meet the requirements of the COSHH Regulations. Respiratory Protection Air-fed respiratory protective equipment should be worn when this product is sprayed if the exposure of the sprayer or other people nearby cannot be controlled to below the Occupational Exposure Limit and engineering controls and methods cannot reasonably be improved. Dry sanding, flame cutting and/or welding of the dry paint film will give rise to dust and/or hazardous fumes. Wet sanding should be used wherever possible. If exposure cannot be avoided by the provision of local exhaust ventilation, suitable respiratory protective equipment should be used. cont’d 9804/8966 ISSUE 3 (REV.), JUNE 2002 Storage area should be: cool, dry. Storage temperature should be controlled to between 5 and 25 °C. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Standards: Diphenylmethandiisocyanate UK EH40 MEL .02 mg/m3 8h TWA. UK EH40 MEL .07 mg/m3 15 min STEL Isophorondiisocyanate UK EH40 MEL .02 mg/m3 8h TWA. UK EH40 MEL .07 mg/m3 15 min STEL Xylene UK EH40: OES 100 ppm (435 mg/m3) 8h TWA. UK EH40: OES 150 ppm (650 mg/m3) 15min STEL. Respiratory Protection: Respiratory protection not normally required. Hand Protection: PVC or rubber gloves. Eye Protection: Wear safety glasses if risks of accidental contamination are possible during application. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Paste. Colour: Black or white. Odour: Characteristic. pH: Not applicable. Flash Point (°C): Exceeds 65. Explosion Limits (%): Lower limit .6. (measured as V/V) based on solvent component. Solubility in Water (kg/m3): Insoluble. Vapour Pressure (kPa): Negligible vapour pressure at ambient conditions. Density (kg/m3): 1.2 at 20 °C. Auto-flammability (°C): 240-525 for the solvent. Not determined for the product. Viscosity: Thixotropic paste. Decomposition Temperature (°C): > 150. 9804/8974 ISSUE 4, (REV.) NOVEMBER 1997 10. STABILITY AND REACTIVITY Stability: Stable under normal conditions. Conditions to Avoid: Exposure to water or moisture. Materials to Avoid: Amines. Alcohols. Hazardous Decomposition Products: Reaction with water or moist air may produce: carbon dioxide formation resulting in pressure increase in bulk containers (risk of bursting). Storage area should be: cool, dry. Storage temperature should be controlled to between 5 and 25 ¡C. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Standards: Diphenylmethandiisocyanate UK EH40 MEL .02 mg/m3 8h TWA. UK EH40 MEL .07 mg/m3 15 min STEL Isophorondiisocyanate UK EH40 MEL .02 mg/m3 8h TWA. UK EH40 MEL .07 mg/m3 15 min STEL Xylene UK EH40: OES 100 ppm (435 mg/m3) 8h TWA. UK EH40: OES 150 ppm (650 mg/m3) 15min STEL. Respiratory Protection: Respiratory protection not normally required. Hand Protection: PVC or rubber gloves. Eye Protection: Wear safety glasses if risks of accidental contamination are possible during application. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Paste. Colour: Black. Odour: Characteristic. pH: Not applicable. Flash Point (¡C): Exceeds 65. Explosion Limits (%): Lower limit .6. (measured as V/V) based on solvent component. Solubility in Water (kg/m3): Insoluble. Vapour Pressure (kPa): Negligible vapour pressure at ambient conditions. Density (kg/m3): 1.13 at 20 ¡C. Auto-flammability (¡C): 240-525 for the solvent. Not determined for the product. Viscosity: Thixotropic paste. Decomposition Temperature (¡C): > 150. 9804/8989 ISSUE 3, (REV.) NOVEMBER 1996 10. STABILITY AND REACTIVITY Stability: Stable under normal conditions. Conditions to Avoid: Exposure to water or moisture. Materials to Avoid: Amines. Alcohols. Hazardous Decomposition Products: Reaction with water or moist air may produce: carbon dioxide formation resulting in pressure increase in bulk containers (risk of bursting). Store in original containers at 5°C-28°C and do not return residual materials to containers as contamination may reduce the shelf life of the bulk product. 8. EXPOSURE CONTROLS - PERSONAL PROTECTION In circumstances where there is potential for prolonged or repeated skin contact, the use of disposable gloves (polyethylene, natural rubber or equivalent ester-resistant material) is recommended. 9804/8984 ISSUE 2, SEPTEMBER 1995 Page 2 of 4 9804/8984 ISSUE 2, SEPTEMBER 1995 SDS 128249 9. PHYSICAL & CHEMICAL PROPERTIES Appearance: Smooth dark yellow paste Odour: Mild characteristic pH: 3-6 (aqueous acetone extraction) (The following properties are to be interpreted within the meaning of Directive 67/548/EEC) Boiling point : --- °C Flash Point (Closed cup) : >100°C Specific Gravity : 1.15 - 1.2g/ml @ 20°C Solubility in Water : immiscible Solubility in Acetone : Vapour Pressure : <0.5 mmHg @ 20°C Other properties : --- 10. STABILITY & REACTIVITY Non reactive to water. Non reactive to oxidising agents except for peroxides. Destabilised by reducing agents. Temperature Ambient Special Sensitivity: Keep away from heat Handling/Storage: Store in cool, dry place Ventilation Requirements: General Sensitive to static Electricity?: No Sensitivity to Mechanical Impact: No 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Ventilation Requirements: General Eye Protection Requirements: Avoid contact with eyes. Wear goggles if there is likelihood of contact with eyes. Glove Requirements: The use of chemically resistant gloves is recommended. Clothing Requirements: Overalls or lab coat should be worn. Respiratory Requirements: None required under normal handling conditions. 9. PHYSICAL AND CHEMICAL PROPERTIES Pure Substance or Preparation: Preparation Physical Form: Liquid Appearance/Odour: Red; Acrylic odour Odour Threshold: Not available pH as is: Not applicable Boiling Point: Not applicable Melting/Freezing Point: Not applicable Solubility in Water: Insoluble Partition Coefficient (n-octanol/water): Not applicable Relative Density: 1.060 Evaporation Rate: Not applicable Vapour Pressure (mmHg): Not applicable Vapour Density (air=1): Not applicable Viscosity: 500 mPa.s Volatiles: None Volatile Organic Compounds: <5 g/l Autoflammability: Not applicable Flash Point: >100 ¡C (Pensky-Martens Closed Tester) Oxidizing Properties: Not applicable 10. STABILITY AND REACTIVITY Stability: Stable Materials to Avoid: Acids; Bases; Peroxides Hazardous Decomposition Products: Thermal decomposition could produce carbon monoxide, carbon dioxide, and unidentified organic compounds. Hazardous Polymerization Conditions: An oxygen-free atmosphere may cause hazardous polymerization. Temperature Ambient Special Sensitivity: Keep away from heat Handling/Storage: Store in cool, dry place Ventilation Requirements: General Sensitive to static Electricity?: No Sensitivity to Mechanical Impact: No 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Ventilation Requirements: General Eye Protection Requirements: Safety glasses, goggles or face shield to protect against splashing. Glove Requirements: The use of chemically resistant gloves is recommended. Clothing Requirements: Overalls or lab coat should be worn. Respiratory Requirements: None required under normal handling conditions. 9804/8999 ISSUE 2 (REV), JUNE 2002 Temperature Ambient Special Sensitivity: Keep away from heat Handling/Storage: Store in cool, dry place Ventilation Requirements: General Sensitive to static Electricity?: No Sensitivity to Mechanical Impact: No 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Ventilation Requirements: General Eye Protection Requirements: Avoid contact with eyes. Wear goggles if there is likelihood of contact with eyes. Glove Requirements: The use of chemically resistant gloves is recommended. Clothing Requirements: Overalls or lab coat should be worn. Respiratory Requirements: None required under normal handling conditions. 9. PHYSICAL AND CHEMICAL PROPERTIES Pure Substance or Preparation: Preparation Physical Form: Liquid Appearance/Odour: Green; Acrylic odour Odour Threshold: Not available pH as is: Not applicable Boiling Point: Not applicable Melting/Freezing Point: Not applicable Solubility in Water: Insoluble Partition Coefficient (n-octanol/water): Not applicable Relative Density: 1.070 Evaporation Rate: Not applicable Vapour Pressure (mmHg): Not applicable Vapour Density (air=1): Not applicable Viscosity: 500 mPa.s Volatiles: None Volatile Organic Compounds: <5 g/l Autoflammability: Not applicable Flash Point: >100 ¡C (Pensky-Martens Closed Tester) Oxidizing Properties: Not applicable 10. STABILITY AND REACTIVITY Stability: Stable Materials to Avoid: Acids; Bases; Peroxides Hazardous Decomposition Products: Thermal decomposition could produce carbon monoxide, carbon dioxide, and unidentified organic compounds. Hazardous Polymerization Conditions: An oxygen-free atmosphere may cause hazardous polymerization. Temperature 5 - 25 ¡C Special Sensitivity: Keep away from heat Handling/Storage: Store in cool, dry place Ventilation Requirements: General Sensitive to static Electricity?: No Sensitivity to Mechanical Impact: No 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Component : Hydroxypropyl methacrylate Exposure Limits: 20 ppm (Manufacturer) Ventilation Requirements: General Eye Protection Requirements: Avoid contact with eyes. Wear goggles if there is likelihood of contact with eyes. Glove Requirements: The use of chemically resistant gloves is recommended. Clothing Requirements: Overalls or lab coat should be worn. Respiratory Requirements: None required under normal handling conditions. 9. PHYSICAL AND CHEMICAL PROPERTIES Pure Substance or Preparation: Preparation Physical Form: Liquid Appearance/Odour: Green; Acrylic odour Odour Threshold: Not available pH as is: Not applicable Boiling Point: Not applicable Melting/Freezing Point: Not applicable Solubility in Water: Insoluble Partition Coefficient (n-octanol/water): Not applicable Relative Density: 1.060 Evaporation Rate: Not applicable Vapour Pressure (mmHg): Not applicable Vapour Density (air=1): Not applicable Viscosity: 37 000 mPa.s Volatiles: None Volatile Organic Compounds: - Autoflammability: Not applicable Flash Point: >100 ¡C Oxidizing Properties: Not applicable 10. STABILITY AND REACTIVITY Stability: Stable Materials to Avoid: Acids; Bases; Peroxides Hazardous Decomposition Products: Thermal decomposition could produce carbon monoxide, carbon dioxide, and unidentified organic compounds. Hazardous Polymerization Conditions: An oxygen-free atmosphere may cause hazardous polymerization. Temperature <5 ¡C Handling/Storage: Store in a cool, dry area away from heat, sparks or fire. Ventilation Requirements: Normal (mechanical) room ventilation should be adequate for small volumes. For higher volume activities, or if needed for worker comfort, local mechanical exhaust should be provided. Sensitive to static Electricity?: No Sensitivity to Mechanical Impact: No 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Component: Ethyl 2-cyanoacrylate Exposure Limits: 2 ppm (Manufacturer) Ventilation Requirements: Normal (mechanical) room ventilation should be adequare for small volumes. For higher volume activities, or if needed for worker comfort, local mechanical exhaust should be provided. Eye Protection requirements: Avoid contact with eyes. Wear chemical goggles if there is likelihood of contact with eyes. Glove Requirements: Wear polyethylene gloves. DO NOT wear rubber of cloth gloves. Clothing Requirements: Overalls or lab coat should be worn. Respiratory Requirements: None required under normal handling conditions. 9. PHYSICAL AND CHEMICAL PROPERTIES Pure Substance or Preparation: Preparation Physical Form: Liquid Appearance/Odour: Colourless; Pungnet odour Odour Threshold: Not available pH as is: Not applicable Boiling Point: Not applicable Melting/Freezing Point: Not applicable Solubility in Water: Insoluble Partition Coefficient (n-octanol/water): Not applicable Relative Density: 1.050 Evaporation Rate: Not applicable Vapour Pressure (mmHg): 0.3 (20 ¡C) Vapour Density (air=1): >1 Viscosity: 100 mPa.s Volatiles: None Volatile Organic Compounds: - Autoflammability: Not applicable Flash Point: 75 ¡C (Setaflash Closed Tester) Oxidizing Properties: Not applicable 10. STABILITY AND REACTIVITY Stability: Stable Materials to Avoid: Amines; Bases; Peroxides; Water Hazardous Decomposition Products: Decomposes upon heating to release toxic fumes of nitrogen oxides, carbon monoxide and carbon dioxide. Hazardous Polymerization Conditions: Contamination of adhesive with alkaline materials, peroxides or water can result in rapid polymerization. In large quantities, this could lead to an uncontrollable rise in temperature and a build-up of pressure in closed containers. Store in original containers at 5°C-28°C and do not return residual materials to containers as contamination may reduce the shelf life of the bulk product. Keep away from sources of ignition. Store away from heat in a cool, well-ventilated area. 8. EXPOSURE CONTROLS - PERSONAL PROTECTION In circumstanes where there is potential for prolonged or repeated skin contact, the use of polyvinyl alcohol, polyethylene or nitrile rubber gauntlets or equivalent resistant gloves is recommended. TLV (ACGIH) is calculated to be approx. 813ppm. 9804/8982 ISSUE 2, SEPTEMBER 1995 Page 2 of 4 9804/8982 ISSUE 2, SEPTEMBER 1995 SDS 178061 9. PHYSICAL & CHEMICAL PROPERTIES Appearance: Clear colourless liquid Odour: pungent pH: - - (The following properties are to be interpreted within the meaning of Directive 67/548/EEC) Boiling point : - - °C Flash Point (Closed cup) : - 18°C Specific Gravity : 0.8g/ml @ 20°C Solubility in Water : miscible Solubility in Acetone : Vapour Pressure : approx. 230mbar mmHg @ 20°C Other properties : - - 10. STABILITY & REACTIVITY The product is relatively stable under normal conditions of use. Non reactive to oxidising agents except for peroxides. Store in original containers at 5 °C - 28 °C and do not return residual materials to containers as contamination may reduce the shelf life of the bulk product. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Use of Loctite applicator equipment is recommended. 9804/8934* ISSUE 4, (REV.) MAY 1997 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Red Liquid Odour: Characteristic pH: 3-6 (The following properties are to be interpreted within the meaning of Directive 67/548/EEC) Boiling Point: - - - °C Flash Point (Closed cup): >100 CC Specific Gravity: 1.08 gimI @ 20 °C Solubility in Water: immiscible Solubility in Chloroform: - - - Vapour Pressure: <0.1 mmHg @ 20 °C Other Properties: - - - 10. STABILITY AND REACTIVITY The product is relatively stable under normal conditions of use. Temperature Ambient Special Sensitivity: Keep away from heat Handling/Storage: Store in a cool, dry area away from heat, sparks or fire. Store at room temperature. Ventilation Requirements: Sufficient to keep vapours below TLV exposure limits. Sensitive to static Electricity?: Yes Sensitivity to Mechanical Impact: No 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Component: n-Hexane Exposure Limits: 50 ppm (ACGIH-TWA) 50 ppm (MAK) Recommended Test Methods: 3M organic vapour monitor Ventilation Requirements: Sufficient to keep vapours below TLV exposure limits. Eye Protection Requirements: Wear chemical goggles. Glove Requirements: Employee must wear appropriate protective gloves to prevent contact with this substance. 9804/9006 ISSUE 1, FEBRUARY 1997 Clothing Requirements: Uniforms, coveralls, or a lab coat should be worn. Respiratory Requirements: Avoid prolonged or repeated breathing of vapour or mists. If exposure may or does exceed occupational exposure limits, use a NIOSH approved respirator to prevent overexposure. 9. PHYSICAL AND CHEMICAL PROPERTIES Pure Substance or Preparation: Preparation Physical Form: Liquid Appearance/Odour: Green; Hydrocarbon odour Odour Threshold: Not available pH as is: Not applicable Boiling Point: 63 °C Melting/Freezing Point: <-20 °C Solubility in Water: Insoluble Partition Coefficient (n-octanol/water): Not applicable Relative Density: 0.700 Evaporation Rate: 7.7 (Butyl Acetate) Vapour Pressure (mmHg): 187 (20 °C) Vapour Density (air=1): >1.0 Viscosity 0.55 cSt Volatiles: None Volatile Organic Compounds: 98% Autoflammability: >200 °C Flash Point: -26 °C (Tagliabue Closed Tester/Tag Closed Tester) Oxidizing Properties: Not applicable 10. STABILITY AND REACTIVITY Stability: Stable Hazardous Decomposition Products: Because of the presence of flammable organic solvents, avoid exposure to fire, sparks, open flames, excessive heat. Storage area should be: cool, dry, well ventilated, out of direct sunlight. Store away from sources of heat or ignition. Storage temperature should be controlled to between 5 and 25°C. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Standards Ethyl acetate: UK EH40: OES 400ppm (1400mg/m3) 8h TWA. Ethyl benzene: UK EH40: OES 100ppm (435mg/m3) 8h TWA. UK EH40: OES 125ppm (545mg/m3) 15min STEL Xylene: UK EH40: OES 100ppm (435mg/m3) 8h TWA. UK EH40: OES 150ppm (650mg/m3) 15min STEL Respiratory Protection: Adequate ventilation should be provided to maintain solvent concentrations in the workplace below exposure limits. Respiratory protection if there is a risk of exposure to high vapour concentrations. Hand Protection: Wear suitable impervious gloves. Eye Protection: Chemical goggles if there is a risk of splashing. 9804/8990 ISSUE 4, NOVEMBER 1997 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Colour: Black Odour: Characteristic. Fragrant pH: Not applicable Boiling Range/Point (°C): 77 (based on major component) Flash Point (°C): -4 Explosion Limits (%): Lower limit 2.2. Upper limit 10 (based on major component) Solubility in Water (kg/m3): Partially soluble Vapour Pressure (kPa) 12.6 at 25°C. (based on major component) Density (kg/m3) 1 at 20°C. Approx. Auto-flammability (deg C) Above 425. Viscosity Mobile liquid at ambient temperatures. 10. STABILITY AND REACTIVITY Stability: Stable under normal conditions. Contains volatile solvent. Conditions to Avoid: Sources of ignition. Exposure to direct sunlight. High temperatures. Materials to Avoid: Oxidising agents. Concentrated mineral acids. Alkalis. Hazardous Decomposition Products: Combustion will generate: oxides of carbon. Keep containers closed when not in use. Store at ambient temperatures. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Respiratory Protection Airborne concentrations should be kept to lowest levels possible. If vapour, mist of dust is generated, use approved respirator as appropriate. Supplied air respiratory protection should be used for cleaning large spills or upon entry into tanks, vessels, or other confined spaces. Hand and Skin Protection: Exposed employees should exercise reasonable personal cleanliness This includes cleansing exposed skin areas several times daily with soap and water, and laundering or dry cleaning soiled work clothing. Eye Protection: Chemical type goggles or face shield recommended to prevent eye contact. Exposure LImit for the Product None established for product 9. PHYSICAL AND CHEMICAL PROPERTIES Do not store in open or unlabelled containers. Store away from strong oxidising agents or combustible material. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Ventilation: No special requirements under ordinary conditions of use and with adequate ventilation. Respiratory Protection: No special requirements under ordinary conditions of use and with adequate ventilation. Eye Protection: Normal industrial eye protection practices should be employed. Cont’d 9804/8868 ISSUE 2 (REV.), MARCH 1997 Skin Protection: Gloves suitable for handling hot materials should be worn. Exposure Limits: This product does not contain any components which have recognised exposure limits. However, a threshold limit value of 2.00 mg/m3 is suggested for wax fumes. 9. PHYSICAL AND CHEMICAL PROPERTIES Typical physical properties are given below. Consult Product Data Sheet for specific details. Physical State: Liquid Colour: Light Amber Odour: Mild Odour Threshold: NA pH: NA Boiling Point °C (°F): > 316 (600) Melting Point °C (°F): 57 (135) Flash Point °C (°F): > 176 (349) (IP 36/ASTM D-92) Flammability: NA Auto Flammability: NE Explosive Properties: NA Oxidising Properties: NA Vapour Pressure-mmHg 20 °C: < 0.1 Vapour Density: > 2.0 Evaporation Rate: NA Relative Density, 15/4 °C: 0.855 Solubility in Water: Negligible Partition Coefficient: NE Viscosity at 40 °C, cSt: NA Viscosity at 100 °C, cSt: 12.0 Pour Point °C: NA Freezing Point °C (°F): NE NA = Not Applicable NE = Not Established D = Decomposes For further technical information contact JCB Service. 10. STABILITY AND REACTIVITY Stability (thermal, light etc.): Stable Conditions to avoid: Extreme heat Incompatibility (materials to avoid): Strong oxidisers Hazardous decomposition products: Carbon monoxide. Hazardous polymerisation: Will not occur Do not store in open or unlabelled containers. Store away from strong oxidising agents or combustible material. 9804/8961 ISSUE 2 (REV.), MARCH 1997 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Ventilation: No special requirements under ordinary conditions of use and with adequate ventilation. Respiratory Protection: No special requirements under ordinary conditions of use and with adequate ventilation. Eye Protection: Normal industrial eye protection practices should be employed. Skin Protection: No special equipment required. However, good personal hygiene practices should always be followed. Exposure Limits: This product does not contain any components which have recognised exposure limits. 9. PHYSICAL AND CHEMICAL PROPERTIES Typical physical properties are given below. Consult Product Data Sheet for specific details. Physical State: Grease Colour: Blue Grey Odour: Mild Odour Threshold: NA pH: NA Boiling Point °C (°F): >316 (600) Drop Point °C (°F): NA Flash Point °C (°F): >204 (400) (Estimated (Oil COC)) Flammability: NA Auto Flammability: NE Explosive Properties: NA Oxidising Properties: NA Vapour Pressure-mmHg 20 °C: < 0.1 Vapour Density: NA Evaporation Rate: NA Relative Density, 15/4 °C: 0.86 Solubility in Water: Negligible Partition coefficient: NE Viscosity at 40° C, cSt: > 300.0 Viscosity at 100° C, cSt: > 15.0 Pour Point °C (°F): NE Freezing Point °C (°F): NE Note: Most physical properties for oil component. NA = Not Applicable NE = Not Established D = Decomposes For further technical information contact JCB Service. 10. STABILITY AND REACTIVITY Stability (thermal, light etc.): Stable Conditions to avoid: Extreme heat Incompatibility (materials to avoid): Strong oxidisers Hazardous decomposition products: Metal oxides. Carbon monoxide. Hazardous polymerisation: Will not occur 9804/8961 ISSUE 2 (REV.), MARCH 1997 The storage and use of this product is subject to the requirements of the Highly Flammable Liquids and Liquefied Petroleum Gases Regulations. Up to 50 litres of such highly flammable liquids may be kept in a work room provided they are kept in a fire-proof cupboard or bin. Larger quantities must be kept in a separate storeroom conforming to the structural requirements of the regulations. Further guidance is contained in the HSE guidance note Storage of Flammable Liquids in Containers. Observe the label precautions. Store between 5 °C and 25 °C in a dry, well ventilated place away from sources of heat, ignition and direct sunlight. No smoking. Prevent unauthorised access. Containers which are opened should be properly resealed and kept upright to prevent leakage. The principles contained in the HSE guidance note Storage of Packaged Dangerous Substances, should be observed when storing this product. Store separately from oxidising agents and strongly alkaline and strongly acidic materials. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Measures Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulates and/or solvent vapours below the relevant occupational exposure limits, suitable respiratory protective equipment should be worn (see ‘Personal Protection’ below). Exposure Limits Occupational Exposure Standards and/or Maximum Exposure Limits have been established by the Health and Safety Commission or recommended by the supplier for certain of the ingredients. OELs are taken from the current versions of EH40 except those marked ‘Sup’, which are assigned by the supplier of the substance. Occupational exposure limits Substance 8 hr TWA (†) 15 min STEL(‡) Notes Acetone 750 ppm (OES) 1500 ppm (OES) Butane 600 ppm (OES) 750 ppm (OES) Lead compounds 0.15 mg/m3 (MEL) White spirit 100ppm (OES) 125 ppm (OES) cont’d 9804/9010 ISSUE 1, MAY 1997 (†) Long term exposure limit - 8 hour time weighted average. (‡) Short term exposure limit - 15 minute reference period. (OES) Occupational exposure standard. (MEL) Maximum exposure limit. Further guidance on OES/MEL and the assessment of occupational exposure to harmful materials, including mixed exposures, is given in HSE Guidance Note EH40. Personal Protection All personal protective equipment, including respiratory protective equipment, used to control exposure to hazardous substances must be selected to meet the requirements of the COSHH Regulations. Respiratory Protection Air-fed respiratory protective equipment should be worn when this product is sprayed. This should be in addition to other measures taken to reduce exposure (e.g. in booth design and operation and process modifications). Non-essential and unprotected people should be excluded from the area if exposure is possible. When operators, whether spraying or not, have to work inside the spray booth, they should wear an air-fed respirator during the spraying process and until such time as the spray mist has cleared. However, persons entering the spray booths or enclosures for short periods (less than 15 minutes) when spraying is taking place may be protected from inhaling the spray mist by wearing suitable respirators with charcoal canisters. Care should be taken to ensure that filters are changed in accordance with the supplier’s instructions. The use of a canister respirator is considered very much a second choice to air-fed respiratory protective equipment. Dry sanding, flame cutting and/or welding of the dry paint film will give rise to dust and/or hazardous fumes. Wet sanding should be used wherever possible. If exposure cannot be avoided by the provision of local exhaust ventilation, suitable respiratory protective equipment should be used. Hand Protection When skin exposure may occur, advice should be sought from glove suppliers on appropriate types. Barrier creams may help to protect exposed areas of skin but are not substitutes for full physical protection. They should not be applied once exposure has occurred. Eye Protection Eye protection designed to protect against liquid splashes should be worn. Skin Protection Cotton or cotton/synthetic overalls or coveralls are normally suitable. Grossly contaminated clothing should be removed and the skin washed with soap and water or a proprietary skin cleaner. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Odour: Characteristic odour Colour: Yellow Specific Gravity: 0.7 g/cm3 Flash Point: -18 °C Volatile Organic Content: 588 g/ltr Explosion limit - lower: 0.6% Water Solubility: Immiscible 10. STABILITY AND REACTIVITY Stable under the recommended storage and handling conditions (see Section 7). In a fire, hazardous decomposition products such as smoke, carbon monoxide, carbon dioxide and oxides of nitrogen may be produced. cont’d 9804/9010 ISSUE 1, MAY 1997 Keep away from oxidising agents and strongly alkaline and strongly acidic materials to prevent the possibility of exothermic reaction. The storage and use of this product is subject to the requirements of the Highly Flammable Liquids and Liquefied Petroleum Gases Regulations. Up to 50 litres of such highly flammable liquids may be kept in a work room provided they are kept in a fire-proof cupboard or bin. Larger quantities must be kept in a separate storeroom conforming to the structural requirements of the regulations. Further guidance is contained in the HSE guidance note Storage of Flammable Liquids in Containers. Observe the label precautions. Store between 5 °C and 25 °C in a dry, well ventilated place away from sources of heat, ignition and direct sunlight. No smoking. Prevent unauthorised access. Containers which are opened should be properly resealed and kept upright to prevent leakage. The principles contained in the HSE guidance note Storage of Packaged Dangerous Substances, should be observed when storing this product. Store separately from oxidising agents and strongly alkaline and strongly acidic materials. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Measures Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulates and/or solvent vapours below the relevant occupational exposure limits, suitable respiratory protective equipment should be worn (see ‘Personal Protection’ below). Exposure Limits Occupational Exposure Standards and/or Maximum Exposure Limits have been established by the Health and Safety Commission or recommended by the supplier for certain of the ingredients. OELs are taken from the current versions of EH40 except those marked ‘Sup’, which are assigned by the supplier of the substance. Occupational exposure limits Substance 8 hr TWA (†) 15 min STEL(‡) Notes Acetone 750 ppm (OES) 1500 ppm (OES) Butane 600 ppm (OES) 750 ppm (OES) Lead compounds 0.15 mg/m3 (MEL) White spirit 100ppm (OES) 125 ppm (OES) cont’d 9804/9009 ISSUE 1, MARCH 1997 (†) Long term exposure limit - 8 hour time weighted average. (‡) Short term exposure limit - 15 minute reference period. (OES) Occupational exposure standard. (MEL) Maximum exposure limit. Further guidance on OES/MEL and the assessment of occupational exposure to harmful materials, including mixed exposures, is given in HSE Guidance Note EH40. Personal Protection All personal protective equipment, including respiratory protective equipment, used to control exposure to hazardous substances must be selected to meet the requirements of the COSHH Regulations. Respiratory Protection Air-fed respiratory protective equipment should be worn when this product is sprayed. This should be in addition to other measures taken to reduce exposure (e.g. in booth design and operation and process modifications). Non-essential and unprotected people should be excluded from the area if exposure is possible. When operators, whether spraying or not, have to work inside the spray booth, they should wear an air-fed respirator during the spraying process and until such time as the spray mist has cleared. However, persons entering the spray booths or enclosures for short periods (less than 15 minutes) when spraying is taking place may be protected from inhaling the spray mist by wearing suitable respirators with charcoal canisters. Care should be taken to ensure that filters are changed in accordance with the supplier’s instructions. The use of a canister respirator is considered very much a second choice to air-fed respiratory protective equipment. Dry sanding, flame cutting and/or welding of the dry paint film will give rise to dust and/or hazardous fumes. Wet sanding should be used wherever possible. If exposure cannot be avoided by the provision of local exhaust ventilation, suitable respiratory protective equipment should be used. Hand Protection When skin exposure may occur, advice should be sought from glove suppliers on appropriate types. Barrier creams may help to protect exposed areas of skin but are not substitutes for full physical protection. They should not be applied once exposure has occurred. Eye Protection Eye protection designed to protect against liquid splashes should be worn. Skin Protection Cotton or cotton/synthetic overalls or coveralls are normally suitable. Grossly contaminated clothing should be removed and the skin washed with soap and water or a proprietary skin cleaner. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Odour: Characteristic odour Colour: Yellow Specific Gravity: 0.7 g/cm3 Flash Point: -18 °C Volatile Organic Content: 587 g/ltr Explosion limit - lower: 0.6% Water Solubility: Immiscible 10. STABILITY AND REACTIVITY Stable under the recommended storage and handling conditions (see Section 7). In a fire, hazardous decomposition products such as smoke, carbon monoxide, carbon dioxide and oxides of nitrogen may be produced. Keep away from oxidising agents and strongly alkaline and strongly acidic materials to prevent the possibility of exothermic reaction. 9804/9009 ISSUE 1, MARCH 1997 The storage and use of this product is subject to the requirements of the Highly Flammable Liquids and Liquefied Petroleum Gases Regulations. Up to 50 litres of such highly flammable liquids may be kept in a work room provided they are kept in a fire-proof cupboard or bin. Larger quantities must be kept in a separate storeroom conforming to the structural requirements of the regulations. Further guidance is contained in the HSE guidance note Storage of Flammable Liquids in Containers. Observe the label precautions. Store between 5 °C and 25 °C in a dry, well ventilated place away from sources of heat, ignition and direct sunlight. No smoking. Prevent unauthorised access. Containers which are opened should be properly resealed and kept upright to prevent leakage. The principles contained in the HSE guidance note Storage of Packaged Dangerous Substances, should be observed when storing this product. Store separately from oxidising agents and strongly alkaline and strongly acidic materials. 9804/9012 ISSUE 2, NOVEMBER 1997 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Measures Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulates and/or solvent vapours below the relevant occupational exposure limits, suitable respiratory protective equipment should be worn (see ‘Personal Protection’ below). Exposure Limits Occupational Exposure Standards and/or Maximum Exposure Limits have been established by the Health and Safety Commission or recommended by the supplier for certain of the ingredients. OELs are taken from the current versions of EH40 except those marked ‘Sup’, which are assigned by the supplier of the substance. Occupational exposure limits Substance 8 hr TWA (†) 15 min STEL(‡) Notes 1-methoxypropan-2-ol 100 ppm (OES) 300 ppm (OES) Skin Lead compounds 0.15 mg/m3 (MEL) Mesitylene 25 ppm (OES) Xylene (mixture of isomers) 100 ppm (OES) 150 ppm (OES) Skin (†) Long term exposure limit - 8 hour time weighted average. (‡) Short term exposure limit - 15 minute reference period. (OES) Occupational exposure standard. (MEL) Maximum exposure limit (Skin) There is a risk of absorption through unbroken skin. Further guidance on OES/MEL and the assessment of occupational exposure to harmful materials, including mixed exposures, is given in HSE Guidance Note EH40. Personal Protection All personal protective equipment, including respiratory protective equipment, used to control exposure to hazardous substances must be selected to meet the requirements of the COSHH Regulations. Respiratory Protection Air-fed respiratory protective equipment should be worn when this product is sprayed if the exposure of the sprayer or other people nearby cannot be controlled to below the Occupational Exposure Limit and engineering controls and methods cannot reasonably be improved. When spraying colours containing lead chromate (listed in Section 1), air-fed respiratory protective equipment must be worn. This should be in addition to other measures taken to reduce exposure (e.g. in booth design and operation, and process modifications). Non- essential and unprotected people should be excluded from the area if exposure is possible. Dry sanding, flame cutting and/or welding of the dry paint film will give rise to dust and/or hazardous fumes. Wet sanding should be used wherever possible. If exposure cannot be avoided by the provision of local exhaust ventilation, suitable respiratory protective equipment should be used. Hand Protection When skin exposure may occur, advice should be sought from glove suppliers on appropriate types. Barrier creams may help to protect exposed areas of skin but are not substitutes for full physical protection. They should not be applied once exposure has occurred. Eye Protection Eye protection designed to protect against liquid splashes should be worn. Skin Protection Cotton or cotton/synthetic overalls or coveralls are normally suitable. Grossly contaminated clothing should be removed and the skin washed with soap and water or a proprietary skin cleaner. 9804/9012 ISSUE 2, NOVEMBER 1997 9. PHYSICAL AND CHEMICAL PROPERTIES The figures given below, unless otherwise stated, refer to the composite material. Physical State: Viscous liquid Odour: Characteristic odour Colour: Various Specific Gravity: 1.1 g/cm3 Viscosity - base: 1.8-2.2 poise BS3900: Part A7 at 25°C Viscosity - additive: 34-38 seconds B2 cup at 20°C Flash Point - base: 27 °C Flash Point - additive: 33 °C Volatile Organic Content: 613 g/ltr Explosion limit - lower: 1.0% Water Solubility: Immiscible 10. STABILITY AND REACTIVITY Stable under the recommended storage and handling conditions (see Section 7). In a fire, hazardous decomposition products such as smoke, carbon monoxide, carbon dioxide and oxides of nitrogen may be produced. Keep away from oxidising agents and strongly alkaline and strongly acidic materials to prevent the possibility of exothermic reaction. Do not store in open or unlabelled containers. Store under cover, out of direct sunlight and away from strong oxidising agents or combustible material. 9804/9014 ISSUE 1, AUGUST 1999 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Ventilation: No special requirements under ordinary conditions of use and with adequate ventilation. Respiratory Protection: No special requirements under ordinary conditions of use and with adequate ventilation. Eye Protection: Normal industrial eye protection practices should be employed. Skin Protection: If prolonged or repeated skin contact is likely, protective clothing including oil impervious gloves MUST be worn. Good personal hygience practices should always be followed. Exposure Limits: This product does not contain any components which have recognised exposure limits. 9. PHYSICAL AND CHEMICAL PROPERTIES Typical physical properties are given below. Consult Product Data Sheet for specific details. Physical State: Grease Colour: Brown Odour: Mild Odour Threshold: Not applicable pH: Not applicable Boiling Point: > 316 °C (600 °F) Drop Point: 180 °C (IP Method 132) Flash Point: > 190 °C (374 °F) (Estimated (Oil COC)) Flammability: Not applicable Auto Flammability: Not established Explosive Properties: Not applicable Oxidising Properties: Not applicable Vapour Pressure: mmHg 20 °C: <0.1 Vapour Density: > 2.0 Evaporation Rate: Not applicable Relative Density: 15/4 °C: 0.89 Solubility in Water: Negligible Partition Coefficient: Not established Viscosity at 40 °C, cSt: 150.0 Viscosity at 100° C, cSt: 13.0 Pour Point: Not established Freezing Point: Not established Note: Most physical properties for oil component. For further technical information, contact your marketing representative. 10. STABILITY AND REACTIVITY Stability (Thermal, Light, etc.): Stable Conditions to Avoid: Extreme heat Incompatibility (materials to avoid): Strong oxidisers Hazardous Decomposition Products: Carbon monoxide Hazardous Polymerisation: Will not occur 9804/9014 ISSUE 1, AUGUST 1999 e@@J'6;98759@4A'85:K8<H'6<;A@SM' ' 9804/9015 ISSUE 1, JULY 2000 eAAC(6;98759A4T(85:>8<?(6<;TA@L( ( •••• 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering measures: K;(TCA657<(DA7T24AT(9AA@A@L( Control parameters: JaW(J1/(OWF0,fPM(*(D:$D()(=;4(;5<(D5T8L(f;^ASA4'(59(7<<(65462DT8796AT(AUC;T24A(T>;2<@(3A(ZAC8(7T(<;^(7T( 4A7T;973<?(C;TT53<A(3?( ;;@(SA985<785;9(79@(T7=A(^;4Z59 (C476856ATL( Respiratory protection: 9>7<785;9(;=(8>A(S7C;24T'(=2DAT(;4(D5T8T(T>;2<@(3A(7S;5@A@(3?(T7=A(^;4Z59 (C476856AT(79@( ;;@(SA985<785;9L( Eye protection: =(8>A4A(5T(7(45TZ(;=(TC<7T>59 (^>5<A(>79@<59 (C4;@268'(A?A(C4;8A685;9(T>;2<@(3A(^;49(OAL L(=2<<(=76A(T>5A<@(;4( ; <AT( ^58>(T5@A(T>5A<@TPL( Skin protection: 4;<;9 A@(79@(4ACA78A@(TZ59(6;98768(T>;2<@(3A(7S;5@A@(3?(8>A(2TA(;=(6<A79( <;SAT(79@(6<A79(;SA47<<TL( ( * 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: .5<?(<5B25@( Colour 15 >8(?A<<;^( Appearance G45 >8(79@(6<A74( Odour: F>74768A45T856( pH: KA2847<( Boiling range, ¡C ,95857<(3;5<59 (C;598(O;5<(37TAP(g()""L( Pour/melting point, ¡C: h(d#!( Flash point, ¡C: g(%&"(OW-Jb(+R#'(F.FP( Autoflammability/ignition, ¡C: g()""(O;5<(37TAP( Upper explosion limit: K;8(Z9;^9( Lower explosion limit: K;8(Z9;^9( Vapour pressure, 20 ¡C, kPa: h("L"%(O;5<(37TAP( Viscosity, kinematic, 40 ¡C, mm 2 /s ,9@5678A@(3?( 47@A(@AT5 9785;9( Relative density, 15 ¡C: "LQ*(d("LQR( Water solubility: K;8(T;<23<A( Partition coefficient, n-octanol/water: K;8(Z9;^9( Other data: •••• 10. STABILITY AND REACTIVITY Conditions/materials to avoid: 873<AL(b7?(4A768(^58>(T84;9 (;U5@5T59 (7 A98TL( Hazardous decomposition products: J>A4D7<(@A6;DC;T585;9(;4(596;DC<A8A(6;D32T85;9(D7?(C4;@26A(;U5@AT(;=(6743;9(79@(544587859:(=2DATL( ( •••• 11. TOXICOLOGICAL INFORMATION J>A(4A=59A@(D59A47<(37TA(;5<T(2TA@(59(8>A(=;4D2<785;9(;=(8>5T(C4;@268(74A(;=(7(<;^(;4@A4(;=(8;U5658?(59(8AT8(795D7<TL( 1+*"(O478P(5T(73;SA(%"( $Z L(W<8>;2 >(5965@A987<(6;98768(^58>(8>A(TZ59(@;AT(9;8(672TA(5DDA@578A(54458785;9'( C4;<;9:A@(79@(4ACA78A@(6;98768(D7?(@A=78(8>A(TZ59(79@(ASA9827<<?(672TA(@A4D78585TL( 9804/9016 ISSUE 1, JULY 2000 Temperature Ambient Handling/Storage: Store in a cool, dry area away from heat, sparks or fire. Store at room temperature. Sensitive to static Electricity?: Yes Special Sensitivity: Keep away from heat Sensitivity to Mechanical Impact: No *8. EXPOSURE CONTROLS/PERSONAL PROTECTION Component: Alkanes, C7-10-iso- Propane Butane Exposure Limits: ACGIH-TWA : 2500 ppm ACGIH-TWA : 800 PPM Ventilation Requirements: Sufficient to keep vapours below TLV exposure limits. Eye Protection Requirements: Wear chemical goggles. Glove Requirements: Employee must wear appropriate protective gloves to prevent contact with this substance. Clothing Requirements: Uniforms, coveralls, or a lab coat should be worn. 9804/9007 ISSUE 2, SEPTEMBER 2001 Store in accordance with conditions of the licence which is necessary under the Petroleum (Consolidation) Act. Further guidance is contained in the HSE guidance note Storage of Flammable Liquids in Containers. Observe the label precautions. Store between 5°C and 25°C in a dry, well ventilated place away from sources of heat, ignition and direct sunlight. No smoking. Prevent unauthorised access. Containers which are open should be properly re-sealed and kept upright to prevent leakage. The principles contained in the HSE guidance note Storage of Packaged Dangerous Substances should be observed when storing this product. Store separately from oxidising agents and strongly alkaline and strongly acidic materials. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Measures Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulates and/or solvent vapours below the relevant occupational exposure limits, suitable respiratory protective equipment should be worn (see 'Personal Protection' below). Exposure Limits Occupational Exposure Standards and/or Maximum Exposure Limits have been established by the Health and Safety Commission or recommended by the supplier for certain of the ingredients. OELs are taken from the current version of EH40 except those marked 'Sup', which are assigned by the supplier of the substance. Occupational Exposure Limits Substance 8 hr TWA¹ 15 min STEL² Notes Acetone 750ppm(OES) 1500ppm(OES) Butane 600ppm(OES) 750ppm(OES) White spirit 600.0mg/m³(OELsol) ¹ Long term exposure limit - 8 hour time weighted average ² Short term exposure limit - 15 minute reference period OES Occupational exposure standard OELsol Occupational exposure limit for the hydrocarbon solvent mixture (set by supplier) Further guidance on OES/MEL and the assessment of occupational exposure to harmful materials, including mixed exposures, is given in HSE Guidance Note EH40. Cont’d 9804/9019 ISSUE1, JANUARY 2002 Personal Protection All personal protective equipment, including respiratory protective equipment, used to control exposure to hazardous substances must be selected to meet requirements of the COSHH Regulations. Respiratory Protection Air-fed respiratory protective equipment should be worn when this product is sprayed if the exposure of the sprayer or other people nearby cannot be controlled to below the Occupational Exposure limits and engineering controls and methods cannot reasonably be improved. Dry-sanding, flame cutting and/or welding of the dry paint film will give rise to dust and/or hazardous fumes. Wet sanding should be used wherever possible. If exposure cannot be avoided by the provision of local exhaust ventilation, suitable respiratory protective equipment should be used. Hand Protection When skin exposure may occur, advice should be sought from glove suppliers on appropriate types. Barrier creams may help to protect exposed areas of skin but are not substitutes for full physical protection. They should not be applied once exposure has occurred. Eye Protection Eye protection designed to protect against liquid splashes should be worn. Skin Protection Cotton or cotton/synthetic overalls or coveralls are normally suitable. Grossly contaminated clothing should be removed and the skin washed with soap and water or a proprietary skin cleanser. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State Liquid Odour Characteristic odour Colour Grey Density 0.8 g/cm³ Flash Point -18°C Volatile Organic Content 596 g/ltr Explosion Limit - lower 0.6% Water Solubility Immiscible 10. STABILITY AND REACTIVITY Stable under the recommended storage and handling conditions (see Section 7). In a fire, hazardous decomposition products such as smoke, carbon monoxide, carbon dioxide and oxides of nitrogen may be produced. Keep away from oxidising agents and strongly alkaline and strongly acidic materials to prevent the possibility of exothermic reaction. Although the storage of this product is not subject to specific statutory requirements, the principles contained in the HSE guidance note Storage of Flammable Liquids in Containers, should be observed. Observe the label precautions. Store between 5 °C and 25 °C in a dry, well ventilated place away from sources of heat, ignition and direct sunlight. No smoking. Prevent unauthorised access. Containers which are open should be properly resealed and kept upright to prevent leakage. The principles contained in the HSE guidance note Storage of Packaged Dangerous Substances should be observed when storing this product. Store separately from oxidising agents and strongly alkaline and strongly acidic materials. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Measures Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulates and/or solvent vapours below the relevant occupational exposure limits, suitable respiratory protective equipment should be worn (see ‘Personal Protection’ below). Exposure Limits Occupational Exposure Standards and/or Maximum Exposure Limits have been established by the Health and Safety Commission or recommended by the supplier for certain of the ingredients. OELs are taken from the current version of EH40 except those marked ‘Sup’, which are assigned by the supplier of the substance. Occupational exposure limits Substance 8 hr TWA (†) 15 min STEL(‡) Notes White spirit 600.0 mg/m3 (OELsol) (†) Long term exposure limit - 8 hour time weighted average. (‡) Short term exposure limit - 15 minute reference period. (OELsol) Occupational exposure limit of the hydrocarbon solvent mixture (set by supplier) Further guidance on OES/MEL and the assessment of occupational exposure to harmful materials, including mixed exposures, is given in HSE Guidance Note EH40. Personal Protection All personal protective equipment, including respiratory protective equipment, used to control exposure to hazardous substances must be selected to meet requirements of the COSHH Regulations. Respiratory Protection Air-fed respiratory protective equipment should be worn when this product is sprayed if the exposure of the sprayer or other people nearby cannot be controlled to below the Occupational Exposure limits and engineering controls and methods cannot reasonably be improved. Dry-sanding, flame cutting and/or welding of the dry paint film will give rise to dust and/or hazardous fumes. Wet sanding should be used wherever possible. If exposure cannot be avoided by the provision of local exhaust ventilation, suitable respiratory protective equipment should be used. cont’d 9804/9022 ISSUE 1, JANUARY 2002 Store in cool, ventilated area. Keep container tightly closed. Highly flammable liquid. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure controls: Ventilate area. Avoid inhalation of vapours. Substance MAC VLE 15 min. Ethanol 5000 ppm 9500 mg/m3 Isopropanol 400 ppm 980 mg/m3 Glycol 50 ppm 125 mg/m3 Personal protection Respiratory: Hand: Under normal conditions not applicable. Maintain usual care when handling chemicals. Eye: Skin: 9804/9028 ISSUE 1, JANUARY 2002 Do not store in open or unlabelled containers. Store away from strong oxidising agents or combustible material. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Eye Protection Generally eye contact is unlikely with this type of material. If eye contact is likely, safety glasses with side shields or chemical type goggles should be worn. Skin Protection If prolonged or repeated skin contact is likely, oil impervious gloves MUST be worn. Good personal hygiene practices should always be followed. Respiratory Protection No special requirements under ordinary conditions of use and with adequate ventilation. cont’d 9804/9032 ISSUE1, JANUARY 2002 Ventilation No special requirements under ordinary conditions of use and with adequate ventilation. Exposure Limits This product does not contain any components which have recognised exposure limits. 9. PHYSICAL AND CHEMICAL PROPERTIES Typical physical properties are given below. Consult Product Data Sheet for specific details. Physical State: Grease Colour: Grey Odour: Mild Odour Threshold: NA pH: NA Boiling Point °C (°F): >316 (600) Drop Point °C (°F): NA Flash Point °C (°F): >204 (400) (IP 34/ASTM D-93) Flammability: NA Auto Flammability: NE Explosive Properties: NA Oxidising Properties: NA Vapour Pressure - mm Hg 20 °C: < 0.1 Vapour Density: NE Evaporation Rate: NA Relative Density: 15/4 C: 0.867 Solubility in Water: Negligible Partition Coefficient: >3.5 Viscosity at 40°C, cSt: 150.0 Viscosity at 100°C, cSt: 11.8 Pour Point °C: NE Freezing Point °C (°F): NE Note: Most physical properties for oil component. NA = Not Applicable NE = Not Established D = Decomposes For further technical information contact JCB Service. 10. STABILITY AND REACTIVITY Stability (thermal, light etc.): Stable Conditions to avoid: Extreme heat Incompatibility (materials to avoid): Strong oxidisers Hazardous decomposition products: Carbon monoxide. Metal oxides. Elemental oxides. Hazardous polymerisation: Will not occur Precautions Aerosol cans: Must not be exposed for direct sunlight or temperatures above 50°C. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION INGREDIENT NAME CAS No STD LT EXP ST EXP (8 hrs) (15 min) XYLENE 1330-20-7 OES. 100 ppm(Sk) 150 ppm(Sk) SOLVENT NAPTHA(PETROLEUM)L/AROMATIC 64742-95-6 SUP. 200 mg/m3 No std. 2-METHOXY-1-METHYLETHYL ACETATE 108-65-6 SUP. 50 ppm 100 ppm 1-METHOXY-2-PROPANOL 107-98-2 OES. 100 ppm(Sk) 300 ppm(Sk) 2-BUTOXYETHANOL 111-76-2 OES. 25 ppm(Sk) No std. BUTYL ACETATE 123-86-4 OES. 150 ppm 200 ppm 4-HYDROXY-4-METHYLPENTAN-2-ONE 123-42-2 OES. 50 ppm 75 ppm DIMETHYL ETHER 115-10-6 OES. 400 ppm 500 ppm Ingredient Comments: OES = Occupational Exposure Standard. SUP = Supplier's recommendation. Sk = Can be absorbed through skin. cont’d 9804/9026 ISSUE 1, JANUARY 2002 The storage and use of this product is subject to the requirements of the Highly Flammable Liquids and Liquefied Petroleum Gases Regulations. Up to 50 litres of such highly flammable liquids may be kept in a work room provided they are kept in a fire-proof cupboard or bin. Larger quantities must be kept in a separate storeroom conforming to the structural requirements of the regulations. Further guidance is contained in the HSE guidance note Storage of Flammable Liquids in Containers. Observe the label precautions. Store between 5°C and 25°C in a dry, well ventilated place away from sources of heat, ignition and direct sunlight. No smoking. Prevent unauthorised access. Containers which are open should be properly re-sealed and kept upright to prevent leakage. The principles contained in the HSE guidance note Storage of Packaged Dangerous Substances should be observed when storing this product. Store separately from oxidising agents and strongly acidic materials, amines, alcohols and water. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Measures Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. Spraying of isocyanate containing products should only be carried out in suitable spray booths or enclosures equipped with effective exhaust ventilation to prevent spray mist escaping into the work area outside the spray booth. Respiratory protective equipment should be worn by spray booth operators (see 'Personal Protection' below). Exposure Limits Occupational Exposure Standards and/or Maximum Exposure Limits have been established by the Health and Safety Commission or recommended by the supplier for certain of the ingredients. OELs are taken from the current version of EH40 except those marked 'Sup', which are assigned by the supplier of the substance. cont’d 9804/9027 ISSUE 1, JANUARY 2002 The storage and use of this product is subject to the requirements of the Highly Flammable Liquids and Liquefied Petroleum Gases Regulations. Up to 50 litres of such highly flammable liquids may be kept in a work room provided they are kept in a fire-proof cupboard or bin. Larger quantities must be kept in a separate storeroom conforming to the structural requirements of the regulations. Further guidance is contained in the HSE guidance note Storage of Flammable Liquids in Containers. Observe the label precautions. Store between 5°C and 25°C in a dry, well ventilated place away from sources of heat, ignition and direct sunlight. No smoking. Prevent unauthorised access. Containers which are open should be properly re-sealed and kept upright to prevent leakage. cont’d 9804/9033 ISSUE 1, JANUARY 2002 The storage and use of this product is subject to the requirements of the Highly Flammable Liquids and Liquefied Petroleum Gases Regulations. Up to 50 litres of such highly flammable liquids may be kept in a work room provided they are kept in a fire-proof cupboard or bin. Larger quantities must be kept in a separate storeroom conforming to the structural requirements of the regulations. Further guidance is contained in the HSE guidance note Storage of Flammable Liquids in Containers. Observe the label precautions. Store between 5°C and 25°C in a dry, well ventilated place away from sources of heat, ignition and direct sunlight. No smoking. Prevent unauthorised access. Containers which are open should be properly re-sealed and kept upright to prevent leakage. The principles contained in the HSE guidance note Storage of Packaged Dangerous Substances should be observed when storing this product. Store separately from oxidising agents and strongly alkaline and strongly acidic materials. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Measures Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. Spraying of isocyanate containing products should only be carried out in suitable spray booths or enclosures equipped with effective exhaust ventilation to prevent spray mist escaping into the work area outside the spray booth. Respiratory protective equipment should be worn by spray booth operators (see 'Personal Protection' below). cont’d 9804/9034 ISSUE 1, JANUARY 2002 Temperature Ambient Handling/Storage: Store in cool, dry place Ventilation Requirements: General Sensitivity to Static Electricity: No Sensitivity to to Mechanical Impact: No 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Adhesive Ventilation Requirements: General Eye Protection Requirements: Avoid contact with eyes. Wear chemical goggles if there is likelihood of contact with eyes. Glove Requirements: Employee must wear appropriate protective gloves to prevent contact with this substance. Clothing Requirements: Employee must wear appropriate protective clothing and equipment to prevent any possibility of skin contact with this substance. Respiratory Requirements: None required under normal handling conditions. Hardener Ventilation Requirements: General Eye Protection Requirements: Safety glasses, goggles or face shield to protect against splashing. Glove Requirements: The use of chemically resistant gloves is recommended. Clothing Requirements: Overalls or lab coat should be worn. Respiratory Requirements: None required under normal handling conditions. 9. PHYSICAL AND CHEMICAL PROPERTIES Pure substance or preparation: Preparation Physical form: Liquid Appearance/Odour: Adhesive: Colourless; slight odour Hardener: Colourless; sweet odour Odour threshold: Not available pH as is: Not applicable Boiling point: Not applicable Melting/freezing point: Not applicable Solubility in water: Insoluble Partition coefficient (n-octanol/water) Not applicable Relative density: Adhesive: 1.200 Hardener: 1.130 Evaporation rate: Not applicable Cont’d..... 9804/9025 ISSUE 1, MARCH 2002 Technical Measures: Not applicable Conditions -suitable: Store at room temperature, protected against contact with water and moisture, and away from any source of ignition. Keep container clearly labelled and closed when not is use. Make the necessary arrangements and take all measures to prevent water and ground pollution. -to be Avoided: Do not store exposed to the elements. Incompatible products: Dangerous reaction with strong oxidising agents. Packaging materials: - recommended Use only hydrocarbon-resistant containers, joints, pipes, etc. Keep in original container if possible. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Personal protective equipment: - Hand protection: Impermeable hydrocarbon-proof gloves. Cont’d 9804/9021 ISSUE1, MARCH 2002 - Eye protection: Goggles, in case of splashing. - Skin and body protection As required, wear a face mask, hydrocarbon-proof clothing, and safety boots (when handling drums). Industrial hygiene: Avoid prolonged and repeated contact with the skin. If the product comes into contact with the skin, wash the affected area immediately and repeatedly with soap and water. Use no abrasives, solvents or petroleum spirit. If the product comes into contact with the eyes, keep eyes open and rinse immediately and repeatedly with water for at least 15 minutes and consult a specialist. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: - physical state: semi-smooth running - colour: Grey-black Odour: Characteristic pH: Not applicable Specific temperatures of change in state: - drop point: >=@ 230 ºC (ISO 2176) Flash point: Not applicable Auto-ignition temperature: > 250 ºC (ASTM E 659). This temperature may be significantly lower under particular conditions (oxidation on high surface areas) Explosion limits: Not applicable Vapour pressure: Negligible at normal temperatures of storage, handling and use Density: About 900 kg/m3 at 15 ºC Solubility: - in water: Insoluble and immiscible - in organic solvents: Soluble in many common solvents Other: - penetration: (60 cycles - 25 ºC): about 280 (1/10 mm) under ISO 2137 10. STABILITY AND REACTIVITY Stability: The product is stable under normal temperatures of storage, handling and use. Dangerous reactions: - Conditions to avoid: Heat, sparks, ignition, points, flames..... - Materials to avoid: Strong oxidising agents. Dangerous decomposition products: Incomplete combustions and thermalysis produce more or else toxic gases such as CO, CO2, various hydrocarbons, alderhydes and soot. Although the storage of this product is not subject to specific statutory requirements, the principles contained in the HSE guidance note Storage of Flammable Liquids in Containers, should be observed. Observe the label precautions. Store between 5 °C and 25 °C in a dry, well ventilated place away from sources of heat, ignition and direct sunlight. No smoking. Prevent unauthorised access. Containers which are open should be properly resealed and kept upright to prevent leakage. The principles contained in the HSE guidance note Storage of Packaged Dangerous Substances should be observed when storing this product. Store separately from oxidising agents and strongly alkaline and strongly acidic materials. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Measures Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulates and/or solvent vapours below the relevant occupational exposure limits, suitable respiratory protective equipment should be worn (see ‘Personal Protection’ below). Exposure Limits Occupational Exposure Standards and/or Maximum Exposure Limits have been established by the Health and Safety Commission or recommended by the supplier for certain of the ingredients. OELs are taken from the current version of EH40 except those marked ‘Sup’, which are assigned by the supplier of the substance. Occupational exposure limits Substance 8 hr TWA (†) 15 min STEL(‡) Notes White spirit 600.0 mg/m3 (OELsol) (†) Long term exposure limit - 8 hour time weighted average. (‡) Short term exposure limit - 15 minute reference period. (OELsol) Occupational exposure limit of the hydrocarbon solvent mixture (set by supplier) Further guidance on OES/MEL and the assessment of occupational exposure to harmful materials, including mixed exposures, is given in HSE Guidance Note EH40. Personal Protection All personal protective equipment, including respiratory protective equipment, used to control exposure to hazardous substances must be selected to meet requirements of the COSHH Regulations. Respiratory Protection Air-fed respiratory protective equipment should be worn when this product is sprayed if the exposure of the sprayer or other people nearby cannot be controlled to below the Occupational Exposure limits and engineering controls and methods cannot reasonably be improved. Dry-sanding, flame cutting and/or welding of the dry paint film will give rise to dust and/or hazardous fumes. Wet sanding should be used wherever possible. If exposure cannot be avoided by the provision of local exhaust ventilation, suitable respiratory protective equipment should be used. cont’d 9804/9022 ISSUE 2 (REV), JUNE 2002 Store in accordance with conditions of the licence which is necessary under the Petroleum (Consolidation) Act. Further guidance is contained in the HSE guidance note Storage of Flammable Liquids in Containers. Observe the label precautions. Store between 5°C and 25°C in a dry, well ventilated place away from sources of heat, ignition and direct sunlight. No smoking. Prevent unauthorised access. Containers which are open should be properly re-sealed and kept upright to prevent leakage. The principles contained in the HSE guidance note Storage of Packaged Dangerous Substances should be observed when storing this product. Store separately from oxidising agents and strongly alkaline and strongly acidic materials. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Measures Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulates and/or solvent vapours below the relevant occupational exposure limits, suitable respiratory protective equipment should be worn (see 'Personal Protection' below). Exposure Limits Occupational Exposure Standards and/or Maximum Exposure Limits have been established by the Health and Safety Commission or recommended by the supplier for certain of the ingredients. OELs are taken from the current version of EH40 except those marked 'Sup', which are assigned by the supplier of the substance. Occupational Exposure Limits Substance 8 hr TWA¹ 15 min STEL² Notes Acetone 750ppm(OES) 1500ppm(OES) Butane 600ppm(OES) 750ppm(OES) White spirit 600.0mg/m³(OELsol) ¹ Long term exposure limit - 8 hour time weighted average ² Short term exposure limit - 15 minute reference period OES Occupational exposure standard OELsol Occupational exposure limit for the hydrocarbon solvent mixture (set by supplier) Further guidance on OES/MEL and the assessment of occupational exposure to harmful materials, including mixed exposures, is given in HSE Guidance Note EH40. Cont’d 9804/9019 ISSUE 2 (REV), JUNE 2002 Personal Protection All personal protective equipment, including respiratory protective equipment, used to control exposure to hazardous substances must be selected to meet requirements of the COSHH Regulations. Respiratory Protection Air-fed respiratory protective equipment should be worn when this product is sprayed if the exposure of the sprayer or other people nearby cannot be controlled to below the Occupational Exposure limits and engineering controls and methods cannot reasonably be improved. Dry-sanding, flame cutting and/or welding of the dry paint film will give rise to dust and/or hazardous fumes. Wet sanding should be used wherever possible. If exposure cannot be avoided by the provision of local exhaust ventilation, suitable respiratory protective equipment should be used. Hand Protection When skin exposure may occur, advice should be sought from glove suppliers on appropriate types. Barrier creams may help to protect exposed areas of skin but are not substitutes for full physical protection. They should not be applied once exposure has occurred. Eye Protection Eye protection designed to protect against liquid splashes should be worn. Skin Protection Cotton or cotton/synthetic overalls or coveralls are normally suitable. Grossly contaminated clothing should be removed and the skin washed with soap and water or a proprietary skin cleanser. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State Liquid Odour Characteristic odour Colour Grey Density 0.8 g/cm³ Flash Point -18°C Volatile Organic Content 596 g/ltr Explosion Limit - lower 0.6% Water Solubility Immiscible 10. STABILITY AND REACTIVITY Stable under the recommended storage and handling conditions (see Section 7). In a fire, hazardous decomposition products such as smoke, carbon monoxide, carbon dioxide and oxides of nitrogen may be produced. Keep away from oxidising agents and strongly alkaline and strongly acidic materials to prevent the possibility of exothermic reaction. Storage area should be: cool, dry, well ventilated, out of direct sunlight. Store away from sources of heat or ignition. Storage temperature should be controlled to between 5 and 25 ºC. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits Butan-2-one UK EH40: OES 200 ppm (600 mg/m3) 8h TWA. UK EH40: OES 300 ppm (899 mg/m3) 15min STEL. Ethyl Acetate UK EH40: OES 200 ppm 8h TWA. UK EH40: OES 400 ppm 15min STEL. Butyl Acetate UK EH40: OES 150 ppm (724 mg/m3) 8h TWA. UK EH40: OES 200 ppm (966 mg/m3) 15min STEL. Diphenylmethandiisocyanate UK EH40: MEL 0.07 mg/m3 15min STEL. UK EH40: MEL 0.02 mg/m3 8h TWA. Engineering Control Measures Use of the basic principles of industrial hygiene will enable this material to be used safely. cont’d 9804/9036 ISSUE 1, AUGUST 2002 Storage area should be: cool, dry. Storage temperature should be controlled to between 5 and 25 ºC. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits 1,2-Benzenedicarboxylic acid UK EH40: OES 5 mg/m3 8h TWA. diisodecyl ester Isophorondiisocyanate UK EH40: MEL 0.02 mg/m3 8h TWA. UK EH40: MEL 0.07 mg/m3 15min STEL. Diphenylmethandiisocyanate UK EH40: MEL 0.07 mg/m3 15min STEL. UK EH40: MEL 0.02 mg/m3 8h TWA. Engineering Control Measures Use of the basic principles of industrial hygiene will enable this material to be used safely. cont’d 9804/9037 ISSUE 1, AUGUST 2002 Precautions Keep in cool, dry, ventilated storage and closed containers. Keep in original container. * 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Ingredient Comments: OES = Occupational Exposure Standard. MEL = Maximum Exposure Limit. Protective Equipment: Process Conditions: ACETIC ACID 10 ppm: 8 hr TWA 15 ppm 15 min STEL 15 ppm 15 min STEL Ventilation: Provide adequate general and local exhaust ventilation. Protective Gloves: Use suitable protective gloves if risk of skin contact. Eye Protection: Goggles giving complete protection to eyes and eyewash bottle with clean water. Other Protection: Wear appropriate clothing to prevent any possibility of skin contact. Continued.................... 9804/8962 ISSUE 4, (REV) AUGUST 2002 Do not store in open or unlabelled containers. Store away from strong oxidising agents or combustible material. 9804/8906 ISSUE 4, (REV.) MARCH 2003 Keep containers tightly closed. 9804/8912 ISSUE 5, (REV.) MARCH 2003 Do not store in open or unlabelled containers. Store away from strong oxidising agents or combustible material. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Ventilation: No special requirements under ordinary conditions of use and with adequate ventilation. Respiratory Protection: No special requirements under ordinary conditions of use and with adequate ventilation. Eye Protection: Normal industrial eye protection practices should be employed. cont’d 9804/8905 ISSUE 5, (REV.) MARCH 2003 Keep containers tightly closed. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering measures: No special measures needed. Control parameters: TWA TLV (ACGIH) : 5 mg/m³ for oil mist. However, in all circumstances exposure should be kept as low as reasonably possible by good ventilation and safe working practices. Respiratory protection: Inhalation of the vapours, fumes or mists should be avoided by safe working practices and good ventilation. Eye protection: If there is a risk of splashing while handling product, eye protection should be worn (e.g. full face shield or goggles with side shields). Skin protection: Prolonged and repeated skin contact should be avoided by the use of clean gloves and clean overalls. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state Oily liquid Colour Red Keep containers tightly closed. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering measures: No special measures needed. Control parameters: TWA TLV (ACGIH) : 5 mg/m³ for oil mist. However, in all circumstances exposure should be kept as low as reasonably possible by good ventilation and safe working practices. Respiratory protection: Inhalation of the vapours, fumes or mists should be avoided by safe working practices and good ventilation. Eye protection: If there is a risk of splashing while handling product, eye protection should be worn (e.g. full face shield or goggles with side shields). Skin protection: Prolonged and repeated skin contact should be avoided by the use of clean gloves and clean overalls. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state Oily liquid Colour Brown Keep containers tightly closed. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering measures: No special measures needed. Control parameters: TWA TLV (ACGIH) : 5 mg/m³ for oil mist. However, in all circumstances exposure should be kept as low as reasonably possible by good ventilation and safe working practices. Respiratory protection: Inhalation of the vapours, fumes or mists should be avoided by safe working practices and good ventilation. Eye protection: If there is a risk of splashing while handling product, eye protection should be worn (e.g. full face shield or goggles with side shields). Skin protection: Prolonged and repeated skin contact should be avoided by the use of clean gloves and clean overalls. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state Oily liquid Colour Brown Keep containers tightly closed. 9804/8910 ISSUE 5, (REV.) MARCH 2003 Keep containers tightly closed. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering measures: No special measures needed. Control parameters: TWA TLV (ACGIH) : 5 mg/m³ for oil mist. However, in all circumstances exposure should be kept as low as reasonably possible by good ventilation and safe working practices. Respiratory protection: Inhalation of the vapours, fumes or mists should be avoided by safe working practices and good ventilation. Eye protection: If there is a risk of splashing while handling product, eye protection should be worn (e.g. full face shield or goggles with side shields). Skin protection: Prolonged and repeated skin contact should be avoided by the use of clean gloves and clean overalls. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state 9 Colour Brown Keep containers tightly closed. 9804/9047 ISSUE 1, MARCH 2003 Keep containers tightly closed. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering measures: No special measures needed. Control parameters: TWA TLV (ACGIH) : 5 mg/m³ for oil mist. However, in all circumstances exposure should be kept as low as reasonably possible by good ventilation and safe working practices. Respiratory protection: Inhalation of the vapours, fumes or mists should be avoided by safe working practices and good ventilation. Eye protection: If there is a risk of splashing while handling product, eye protection should be worn (e.g. full face shield or goggles with side shields). Skin protection: Prolonged and repeated skin contact should be avoided by the use of clean gloves and clean overalls. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state Oily liquid Colour Light yellow Keep containers tightly closed. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering measures:No special measures needed. Control parameters TWA TLV (ACGIH) 5 mg/m³ for oil mist. However, in all circumstances exposure should be kept as low as reasonably possible by good ventilation and safe working practices. Respiratory protection:Inhalation of the vapours, fumes or mists should be avoided by safe working practices and good ventilation. Eye protection: If there is a risk of splashing while handling product, eye protection should be worn (e.g. full face shield or goggles with side shields). Hand/skin protection: Prolonged and repeated skin contact should be avoided by the use of clean gloves and clean overalls. PVC or nitrile gloves may be suitable. 9. PHYSICAL AND CHEMICAL PROPERTIES file://C:\My Documents\Oils\5670_JCBTwoStrokeOil_E.htm 3/4/03 JCB Two Stroke Oil 9804/9042 ISSUE 1, MARCH 2003 Keep containers tightly closed. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering measures:No special measures needed. Control parameters TWA TLV (ACGIH) 5 mg/m³ for oil mist. However, in all circumstances exposure should be kept as low as reasonably possible by good ventilation and safe working practices. Respiratory protection:Inhalation of the vapours, fumes or mists should be avoided by safe working practices and good ventilation. Eye protection: If there is a risk of splashing while handling product, eye protection should be worn (e.g. full face shield or goggles with side shields). Hand/skin protection: Prolonged and repeated skin contact should be avoided by the use of clean gloves and clean overalls. B2-PVCNI 9. PHYSICAL AND CHEMICAL PROPERTIES file://C:\My Documents\Oils\5667_JCBChainOil_E.htm 3/4/03 JCB Chain Oil 9804/9044 ISSUE 1, MARCH 2003 Keep containers tightly closed. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering measures:No special measures needed. Control parameters TWA TLV (ACGIH) 5 mg/m³ for oil mist. However, in all circumstances exposure should be kept as low as reasonably possible by good ventilation and safe working practices. Respiratory protection:Inhalation of the vapours, fumes or mists should be avoided by safe working practices and good ventilation. Eye protection: If there is a risk of splashing while handling product, eye protection should be worn (e.g. full face shield or goggles with side shields). Hand/skin protection: Prolonged and repeated skin contact should be avoided by the use of clean gloves and clean overalls. PVC or nitrile gloves may be suitable. 9. PHYSICAL AND CHEMICAL PROPERTIES file://C:\My Documents\Oils\5668_JCBMilkingMachine_E.htm 3/4/03 JCB Milking Machine 9804/9043 ISSUE 1, MARCH 2003 Keep containers tightly closed. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering measures:No special measures needed. Control parameters TWA TLV (ACGIH) 5 mg/m³ for oil mist. However, in all circumstances exposure should be kept as low as reasonably possible by good ventilation and safe working practices. Respiratory protection:Inhalation of the vapours, fumes or mists should be avoided by safe working practices and good ventilation. Eye protection: If there is a risk of splashing while handling product, eye protection should be worn (e.g. full face shield or goggles with side shields). Hand/skin protection: Prolonged and repeated skin contact should be avoided by the use of clean gloves and clean overalls. PVC or nitrile gloves may be suitable. 9. PHYSICAL AND CHEMICAL PROPERTIES file://C:\My Documents\Oils\5666_JCBGardenOil_E.htm 3/4/03 JCB Garden Oil 9804/9041 ISSUE 1, MARCH 2003 Keep containers tightly closed. 9804/9046 ISSUE 1, MARCH 2003

TOXICOLOGICAL INFORMATION

Acute Toxicity O Q& 1I01& K&M4HF0&F ZG4GF5<& & The refined mineral base oils used in the formulation of this product are of a low order of toxicity in test animals. LD50 (rat) is above 10 g/kg. Although incidental contact with the skin does not cause immediate irritation, prolonged and repeated contact may defat the skin and eventually cause dermatitis. 9804/8913 ISSUE 6, (REV.) MARCH 2003 FH;'/;804;R'904;/27'.2<;'607<'-<;R'04'3H;'86/9-723064'68'3H0<'G/6R-13'2/;'68'2'76]'6/R;/'68'36S0103E'04'3;<3'240927<J' ,[Q"'M/23N'0<'2.6:;'#"'5$W5J'U73H6-5H'0410R;4327'1643213']03H'3H;'<W04'R6;<'463'12-<;'099;R023;'0//0323064&' G/67645;R'24R'/;G;23;R'1643213'92E'R;823'3H;'<W04'24R';:;43-277E'12-<;'R;/923030<J' ' Acute toxicology: Oral toxicity: Practically non-toxic (LD50: greater than 2000 mg/kg) Based on testing of similar products and/or the components. Dermal toxicity: Practically non-toxic (LD50: greater than 2000 mg/kg) Based on testing of similar products and/or the components. Inhalation toxicity Practically non-toxic (LC50 greater than 5 mg/1) Based on testing of similar products and/or the components. Eye irritation: Practically non-irritating. (Draize score: greater than 6 but 15 or less). Based on testing of similar products and/or the components. cont’d 9804/8909 ISSUE 5 (REV.), MARCH 2003 LD50 (oral, rat) > 5000 mg/kg. LD50 (dermal) > 2000 mg/kg 9804/8969 ISSUE 6 (REV.), MARCH 2003 The refined mineral base oils used in the formulation of this product are of a low order of toxicity in test animals. LD50 (rat) is above 10 g/kg. Although incidental contact with the skin does not cause immediate irritation, prolonged and repeated contact may defat the skin and eventually cause dermatitis. The refined mineral base oils used in the formulation of this product are of a low order of toxicity in test animals. LD50 (rat) is above 10 g/kg. Although incidental contact with the skin does not cause immediate irritation, prolonged and repeated contact may defat the skin and eventually cause dermatitis. The refined mineral base oils used in the formulation of this product are of a low order of toxicity in test animals. LD50 (rat) is above 10 g/kg. Although incidental contact with the skin does not cause immediate irritation, prolonged and repeated contact may defat the skin and eventually cause dermatitis. The mineral oils and other components of this Lubricating Grease may be considered not to be essentially toxic in normal handling. Acute toxicology: Oral toxicity: Practically non-toxic (LD50: greater than 2000 mg/kg) Based on testing of similar products and/or the components. Dermal toxicity: Practically non-toxic (LD50: greater than 2000 mg/kg) Based on testing of similar products and/or the components. Inhalation toxicity: Not applicable. Harmful concentrations of mists and/or vapours are unlikely to be encountered through any customary or reasonably foreseeable handling, use, or misuse of this product. Eye irritation: Practically non-irritating. (Draize score: greater than 6 but 15 or less). Based on testing of similar products and/or the components. Skin irritation: Practically non-irritating. (Primary Irritation Index: greater than 0.5 but less than 3). Based on testing of similar products and/or the components. cont’d 9804/8897 ISSUE 3 (REV.), NOVEMBER 1997 Subchronic Toxicology (summary): Severely solvent refined and severely hydrotreated mineral base oils have been tested at doses significantly higher than those expected during normal industrial exposure. Extensive evaluations showed no adverse effects. Chronic Toxicology (summary): The base oils in this product are severely solvent refined and/or severely hydrotreated. Chronic skin painting studies of severely treated oils showed no evidence of carcinogenic effects. Acute toxicology: Oral toxicity: Practically non-toxic (LD50: greater than 2000 mg/kg) Based on testing of similar products and/or the components. Dermal toxicity: Practically non-toxic (LD50: greater than 2000 mg/kg) Based on testing of similar products and/or the components. Inhalation toxicity: Not applicable. Harmful concentrations of mists and/or vapours are unlikely to be encountered through any customary or reasonably foreseeable handling, use, or misuse of this product. Eye irritation: Practically non-irritating. (Draize score: greater than 6 but 15 or less). Based on testing of similar products and/or the components. Skin irritation: Practically non-irritating. (Primary Irritation Index: greater than 0.5 but less than 3). Based on testing of similar products and/or the components. cont’d 9804/8944 ISSUE 3 (REV.), NOVEMBER 1997 Other Acute Toxicity Data: The acute toxicological results summarsed previously are based on testing of representative products. Subchronic Toxicology (summary): Representative formulations have been tested by dermal applications 5 days/week for 90 days at doses significantly higher than those expected during normal industrial exposure. Extensive evaluations, including microscopic examination of internal organs and clinical chemistry of body fluids, showed no adverse effects. Reproductive Toxicology (summary): Dermal exposure of pregnant rats to representative formulations did not cause adverse effects in either the mothers or their offspring. Chronic Toxicology (summary): The base oils in this product are severely solvent refined and/or severely hydrotreated. Chronic skin painting studies of severely treated oils showed no evidence of carcinogenic effects. These results are confirmed on a continuing basis. Sensitisation (summary): Representative formulations have not caused skin sensitisation in guinea pigs. Acute Toxicology Oral Toxicity: Practically non-toxic (LD50: greater than 2,000 mg/kg). Based on testing of similar products and/or the components. Dermal Toxicity: Practically non-toxic (LD50: greater than 2,000 mg/kg). Based on testing of similar products and/or the components. Inhalation Toxicity: Not applicable. Harmful concentrations of mists and/or vapours are unlikely to be encountered through any customary or reasonably foreseeable handling, use, or misuse of this product. Eye Irritation: Practically non-irritating. Skin Irritation: Practically non-irritating. (Primary Irritation Index: greater than 0.5 but less than 3). Based on testing of similar products and/or the components. Subchronic Toxicology (Summary) Severely solvent refined and severely hydrotreated mineral base oils have been tested at doses significantly higher than those expected during normal industrial exposure. Extensive evaluations showed no adverse effects. Chronic Toxicology (Summary) The base oils in this product are severely solvent refined and/or severely hydrotreated. Chronic skin painting studies of severely treated oils showed no evidence of carcinogenic effects. Acute toxicity: Low order of acute toxicity. Acute Toxicology Oral Toxicity: Practically non-toxic (LD50: greater than 2,000 mg/kg). Based on testing of similar products and/or the components. Dermal Toxicity: Practically non-toxic (LD50: greater than 2,000 mg/kg). Based on testing of similar products and/or the components. cont’d 9804/8970 ISSUE 3, (REV.) NOVEMBER 1997 Inhalation Toxicity: Not applicable. Harmful concentrations of mists and/or vapours are unlikely to be encountered through any customary or reasonably foreseeable handling, use, or misuse of this product. Eye Irritation: Practically non-irritating. (Draize score: greater than 6 but 15 or less.) Based on testing of similar products and/or the components. Skin Irritation: Practically non-irritating. (Primary Irritation Index: greater than 0.5 but less than 3). Based on testing of similar products and/or the components. Other Acute Toxicity Data: The acute toxicological results summarised above are based on testing of representative JCB products. Subchronic Toxicology (Summary) Representative JCB formulations have been tested by dermal applications 5 days/week for 90 days at doses significantly higher than those expected during normal industrial exposure. Extensive evaluations, including microscopic examination of internal organs and clinical chemistry of body fluids, showed no adverse effects. Reproductive Toxicology (Summary) Dermal exposure of pregnant rats to representative formulations did not cause adverse effects in either the mothers or their offspring. Chronic Toxicology (Summary) The base oils in this product are severely solvent refined and/or severely hydrotreated. Chronic skin painting studies of severely treated oils showed no evidence of carcinogenic effects. Sensitisation (Summary) Representative JCB formulations have not caused skin sensitisation in guinea pigs. Acute Toxicity Low order of acute toxicity. The refined mineral base oils used in the formulation of this product are of a low order of toxicity in test animals. LD50 (rat) is above 10 g/kg. Although incidental contact with the skin does not cause immediate irritation, prolonged and repeated contact may defat the skin and eventually cause dermatitis. 9804/8993 ISSUE 4, MARCH 2003 Acute Toxicology Oral Toxicity: O[9"6&g&9&I Toxic dose 1 - LD50: 5000 mg/kg (oral rat) The refined mineral base oils used in the formulation of this product are of a low order of toxicity in test animals. LD50 (rat) is above 10 g/kg. Although incidental contact with the skin does not cause immediate irritation, prolonged and repeated contact may defat the skin and eventually cause dermatitis. 9804/8891 ISSUE 6, (REV.) MARCH 2003 Eye: Contact with eyes causes redness and discomfort which is transient. Skin: Unlikely to be hazardous by skin absorption. Inhalation: Vapour may be irritant to the respiratory tract. Ingestion: Unlikely to be hazardous if swallowed. No hazard in normal industrial use. CHRONIC (LONG TERM) EFFECTS OF EXPOSURE Effects of Chronic Exposure: The toxicological properties of this product have not been fully evaluated. Use of good industrial hygiene practices is required. Avoid direct contact with skin or eyes. Do not ingest or inhale. Target Organs: None known. Respiratory Sensitisation: No. Cardiac Sensitisation: No. Skin Sensitisation: No. Possible Birth Defect Hazard: No. Carcinogen: No. Eye: On contact, will bond eyelids together. Vapours are lachrymatory. Will cause eye irritation. Skin: On contact, immediate bonding of the skin will occur. Irritating to the skin. Inhalation: Vapour may be irritant to the respiratory tract. Ingestion: On contact, immediate bonding of mouth could occur. CHRONIC (LONG TERM) EFFECTS OF EXPOSURE Effects of Chronic Exposure: Under EU legislation the cyanoacrylates do not require classification as sensitisers and the rapid polymerisation caused on contact with moisture makes this unlikely. However the American Conference of Governmental Industrial Hygienists (ACGIH) has reported some limited evidence of skin and respiratory sensitisation. Target Organs: Respiratory system, Skin Respiratory Sensitisation: May cause allergic reaction. Cardiac Sensitisation: No. Skin Sensitisation: May cause allergic reaction. Possible Birth Defect Hazard: No. Carcinogen: No. Acute Inhalation: High concentrations of vapours or mist are likely to be irritating to the respiratory tract and may cause nausea, dizziness, headaches and drowsiness. Skin contact: Slightly irritating to the skin. Continued..... 9804/8892 ISSUE 4*, OCTOBER 2001 Acute Toxicology INGREDIENT: LD50 (Animal/Oral) White Spirit: >5g/kg (Rat) There is no data available on the specific product itself. Exposure to organic solvent vapours may result in adverse health effects on the renal and central nervous systems. Symptoms can include: headache, dizziness, fatigue, muscular weakness, drowsiness or, in extreme cases, loss of consciousness. Splashes in the eyes may cause irritation and reversible local damage. White spirit vapour in high concentrations can cause intoxification, headache, nausea, and, in extreme cases, coma. Ingestion may cause irritation of mouth, throat and digestive tract causing vomiting and abdominal pain. Significant absorbtion can cause sleepiness and pulmonary oedema. Mineral oil, when in frequent or prolonged contact with the skin can cause defatting leading to skin disorders such as ‘oil acne’ and warts or ulcers which may undergo malignant changes. Inhalation of high concentrations of oil mist may produce local irritation of the respiratory tract or systemic effects from absorption into the bloodstream. Ingestion may produce irritation of the mouth, the intestinal tract or systemic effects from absorption into the bloodstream. Eye contact will cause soreness and interferes with the eye’s protective fluid causing irritation of eye tissue and possibility of some damage to the outer layer if exposure is not dealt with promptly. The preparation is considered to be of relatively low order or toxicity. However ingestion will cause stomach ache, interfere with the biological balance in the stomach, irritate the trachea and may cause diarrhoea. Inhalation of mist or spray will cause irritation and if severe could cause discomfort in breathing. As with all chemicals individuals with lung disorders or breathing disorders may experience more severe reactions. Contact with skin will cause irritation. Degrees of severity will depend on the dilution rate. Preparation may damage outer layers of skin if unattended to. Repeated skin contact with diluted material can cause dryness and soreness of skin. Acute Toxicology INGREDIENT: LD50 (Animal/Oral) White Spirit: >5g/kg (Rat) There is no data available on the specific product itself. Exposure to organic solvent vapours may result in adverse health effects on the renal and central nervous systems. Symptoms can include: headache, dizziness, fatigue, muscular weakness, drowsiness or, in extreme cases, loss of consciousness. Splashes in the eyes may cause irritation and reversible local damage. White spirit vapour in high concentrations can cause intoxification, headache, nausea, and, in extreme cases, coma. Ingestion may cause irritation of mouth, throat and digestive tract causing vomiting and abdominal pain. Significant absorbtion can cause sleepiness and pulmonary oedema. Mineral oil, when in frequent or prolonged contact with the skin can cause defatting leading to skin disorders such as ‘oil acne’ and warts or ulcers which may undergo malignant changes. Inhalation of high concentrations of oil mist may produce local irritation of the respiratory tract or systemic effects from absorption into the bloodstream. Ingestion may produce irritation of the mouth, the intestinal tract or systemic effects from absorption into the bloodstream. There is no evidence of serious acute or long term chronic effects associated with the use of this product under normal controlled conditions. Acute Toxicity: Low order of acute toxicity. Oral LD50 (rat) 5045 mg/kg (based on major component). Excessive exposure may produce anaesthetic or narcotic effects. Irritancy - Eyes: Liquid and vapour can cause irritation on contact and at high concentrations. Irritancy - Skin: Frequent skin contact may cause irritation and defatting due to the solvent content. - Eye: May cause eye irritation. Skin: Repeated or prolonged contact may cause defatting of the skin resulting in dryness, cracking and dermatitis. Inhalation: Vapours may cause drowsiness and dizziness. Ingestion: Aspiration of the product into the lungs following ingestion may cause pulmonary injury leading to pneumonitis. CHRONIC (LONG TERM) EFFECTS OF EXPOSURE Effects of Chronic Exposure: The toxicological properties of this product have not been fully evaluated. Use of good industrial hygiene practices is required. Avoid direct contact with skin or eyes. Do not ingest or inhale. Target Organs: Not applicable. Respiratory Sensitisation: No. Cardiac Sensitisation: No. Skin Sensitisation: No. Possible Birth Defect Hazard: No. Carcinogen: No. Ingredient LD50 (Animal/oral) Acetone 9.75 g/kg (Rat) 1-Methoxy-2-Propanol 7.5 g/kg (Rat) Xylene, mixture of isomers 4.3 g/kg (Rat) 1-Methoxy Propan-2-ol Acetate 8.5 g/kg (Rat) There is no data available on the product itself. Exposure to organic solvent vapours may result in adverse health effects on the renal and central nervous systems. Symptoms can include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases, loss of consciousness. Splashes in the eyes may cause irritation and reversible local damage. Acetone may produce conjunctival irritation and corneal damage. Skin is unlikely to be irritated on brief or occasional exposure; prolonged contact may produce irritation and dermatitis. High vapour concentrations irritate the respiratory tract, are anaesthetic, and may cause headaches and dizziness, and depress the central nervous system leading to unconsciousness. Ingestion may cause gastro-intestinal irritation and CNS depression leading to unconsciousness. Xylene vapour and liquid is irritating to the eyes. Liquid is a skin irritant; prolonged contact may cause dermatitis. High vapour concentrations irritate the respiratory tract, are anaesthetic, may cause drowsiness, nausea, dizziness and eventually unconsciousness. Ingestion of xylene may cause narcosis, vomiting and unconsciousness. Ingredient LD50 (Animal/oral) Xylene, mixture of isomers 4.3 g/kg (Rat) Acetone 9.75 g/kg (Rat) 1-Methoxy Propan-2-ol Acetate 8.5 g/kg (Rat) There is no data available on the product itself. Exposure to organic solvent vapours may result in adverse health effects on the renal and central nervous systems. Symptoms can include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases, loss of consciousness. Splashes in the eyes may cause irritation and reversible local damage. Xylene vapour and liquid is irritating to the eyes. Liquid is a skin irritant; prolonged contact may cause dermatitis. High vapour concentrations irritate the respiratory tract, are anaesthetic, may cause drowsiness, nausea, dizziness and eventually unconsciousness. Ingestion of xylene may cause narcosis, vomiting and unconsciousness. Acetone may produce conjunctival irritation and corneal damage. Skin is unlikely to be irritated on brief or occasional exposure; prolonged contact may produce irritation and dermatitis. High vapour concentrations irritate the respiratory tract, are anaesthetic, and may cause headaches and dizziness, and depress the central nervous system leading to unconsciousness. Ingestion may cause gastro-intestinal irritation and CNS depression leading to unconsciousness. Ingredient LD50 (Animal/oral) Acetone 9.75 g/kg (Rat) 1-Methoxy-2-Propanel 7.5 g/kg (Rat) Xylene, mixture of isomers 4.3 g/kg (Rat) 1-Methoxy Propan-2-ol Acetate 8.5 g/kg (Rat) There is no data available on the product itself. Exposure to organic solvent vapours may result in adverse health effects on the renal and central nervous systems. Symptoms can include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases, loss of consciousness. Splashes in the eyes may cause irritation and reversible local damage. Acetone may produce conjunctival irritation and corneal damage. Skin is unlikely to be irritated on brief or occasional exposure; prolonged contact may produce irritation and dermatitis. High vapour concentrations irritate the respiratory tract, are anaesthetic, and may cause headaches and dizziness, and depress the central nervous system leading to unconsciousness. Ingestion may cause gastro-intestinal irritation and CNS depression leading to unconsciousness. Xylene vapour and liquid is irritating to the eyes. Liquid is a skin irritant; prolonged contact may cause dermatitis. High vapour concentrations irritate the respiratory tract, are anaesthetic, may cause drowsiness, nausea, dizziness and eventually unconsciousness. Ingestion of xylene may cause narcosis, vomiting and unconsciousness. Ingredient LD50 (Animal/oral) Acetone 9.75 g/kg (Rat) 1-Methoxy-2-Propanol 7.5 g/kg (Rat) Xylene, mixture of isomers 4.3 g/kg (Rat) 1-Methoxy Propan-2-ol Acetate 8.5 g/kg (Rat) There is no data available on the product itself. Exposure to organic solvent vapours may result in adverse health effects on the renal and central nervous systems. Symptoms can include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases, loss of consciousness. Splashes in the eyes may cause irritation and reversible local damage. Acetone may produce conjunctival irritation and corneal damage. Skin is unlikely to be irritated on brief or occasional exposure; prolonged contact may produce irritation and dermatitis. High vapour concentrations irritate the respiratory tract, are anaesthetic, and may cause headaches and dizziness, and depress the central nervous system leading to unconsciousness. Ingestion may cause gastro-intestinal irritation and CNS depression leading to unconsciousness. Xylene vapour and liquid is irritating to the eyes. Liquid is a skin irritant; prolonged contact may cause dermatitis. High vapour concentrations irritate the respiratory tract, are anaesthetic, may cause drowsiness, nausea, dizziness and eventually unconsciousness. Ingestion of xylene may cause narcosis, vomiting and unconsciousness. There is no data available on the product itself. Exposure to organic solvent vapours may result in adverse health effects such as irritation of the mucous membrane and respiratory system and adverse effects on the renal and central nervous systems. Symptoms include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases unconsciousness. Splashes in the eyes may cause irritation and irreversible local damage. Repeated or prolonged contact with the product may lead to removal of natural fats from the skin resulting in non-allergic contact dermatitis and absorption through the skin. There is no data available on the product itself. Exposure to organic solvent vapours may result in adverse health effects such as irritation of the mucous membrane and respiratory system and adverse effects on the renal and central nervous systems. Symptoms include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases unconsciousness. Splashes in the eyes may cause irritation and reversible local damage. Repeated or prolonged contact with the product may lead to removal of natural fats from the skin resulting in non-allergic contact dermatitis and absorption through the skin. There is no data available on the product itself. Exposure to organic solvent vapours may result in adverse health effects such as irritation of the mucous membrane and respiratory system and adverse effects on the renal and central nervous systems. Symptoms include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases unconsciousness. Splashes in the eyes may cause irritation and reversible local damage. Repeated or prolonged contact with the product may lead to removal of natural fats from the skin resulting in non-allergic contact dermatitis and absorption through the skin. Splashes in the eye may cause irritation and reversible local damage. There is no data available on the product itself. Exposure to organic solvent vapours may result in adverse health effects such as irritation of the mucous membrane and respiratory system and adverse effects on the renal and central nervous systems. Symptoms include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases unconsciousness. Splashes in the eyes may cause irritation and reversible local damage. Repeated or prolonged contact with the product may lead to removal of natural fats from the skin resulting in non-allergic contact dermatitis and absorption through the skin. Splashes in the eye might cause irritation and reversible local damage. Ingredient LD50 (Animal/oral) Acetone 9.75 g/kg (Rat) 1-Methoxy-2-Propanel 7.5 g/kg (Rat) Xylene, mixture of isomers 4.3 g/kg (Rat) 1-Methoxy Propan-2-ol Acetate 8.5 g/kg (Rat) There is no data available on the product itself. Exposure to organic solvent vapours may result in adverse health effects on the renal and central nervous systems. Symptoms can include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases, loss of consciousness. Splashes in the eyes may cause irritation and reversible local damage. Acetone may produce conjunctival irritation and corneal damage. Skin is unlikely to be irritated on brief or occasional exposure; prolonged contact may produce irritation and dermatitis. High vapour concentrations irritate the respiratory tract, are anaesthetic, and may cause headaches and dizziness, and depress the central nervous system leading to unconsciousness. Ingestion may cause gastro-intestinal irritation and CNS depression leading to unconsciousness. Xylene vapour and liquid is irritating to the eyes. Liquid is a skin irritant; prolonged contact may cause dermatitis. High vapour concentrations irritate the respiratory tract, are anaesthetic, may cause drowsiness, nausea, dizziness and eventually unconsciousness. Ingestion of xylene may cause narcosis, vomiting and unconsciousness. There is no data available on the product itself. Exposure to organic solvent vapours may result in adverse health effects such as irritation of the mucous membrane and the respiratory system and adverse effects on the renal and central nervous systems. Symptoms include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases loss of consciousness. Repeated or prolonged contact with the product may lead to removal of natural fats from the skin resulting in non- allergic contact dermatitis and absorption through the skin. Splashes in the eyes may cause irritation and reversible local damage. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea. Other effects may be as described for exposure to vapours. Increased incidences of lung cancer have been identified in the chromate manufacturing industry. Epidemiological studies have shown that where lead chromates alone were manufactured there were no cancer excesses. Animal studies have shown that some insoluble chromates are carcinogenic but the data does not extend to lead chromate pigments. There is no evidence of a risk of lung cancer arising from the use of lead chromate containing products. Epidemiological data shows an association between elevated maternal blood lead levels and developmental effects in the offspring. Following the introduction of the criteria for Toxic For Reproduction hazard classification the EC has classified all lead compounds as causing developmental toxicity in humans. Lead chromate, although of relatively low solubility and bioavailablity, is included in this classification. There is no data available on the product itself. Exposure to organic solvent vapours may result in adverse health effects such as irritation of the mucous membrane and the respiratory system and adverse effects on the renal and central nervous system. Symptoms include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases loss of consciousness. Repeated or prolonged contact with the product may lead to removal of natural fats from the skin, resulting in non-allergic contact dermatitis and absorption through the skin. Splashes in the eyes may cause irritation and reversible local damage. Ingestion may result in the following effects:- sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea. Other effects may be as described for exposure to vapours. Increased occurrences of lung cancer have been identified in the chromate pigment manufacturing industry. Epidemiological studies have shown that where lead chromates alone were manufactured there were no cancer excesses. Animal studies have shown that some insoluble chromates are carcinogenic but the data does not extend to lead chromate pigments. There is no evidence of a risk of lung cancer arising from the use of lead chromate containing products. Epidemiological data shows an association between elevated maternal blood levels and development effects in the offspring. Following the introduction of the criteria for “Toxic to reproduction” hazard classification the E.C. has classified all lead compounds as causing development toxicity in humans. Lead Chromate, although of relatively low solubility and bio availability is included in this classification. There is no data available on the product itself. Exposure to organic solvent vapours may result in adverse health effects such as irritation of the mucous membrane and the respiratory system and adverse effects on the renal and central nervous system. Symptoms include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases loss of consciousness. Repeated or prolonged contact with the product may lead to removal of natural fats from the skin, resulting in non-allergic contact dermatitis and absorption through the skin. Splashes in the eyes may cause irritation and reversible local damage. Ingestion may result in the following effects:- sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea. Other effects may be as described for exposure to vapours. Increased occurrences of lung cancer have been identified in the chromate pigment manufacturing industry. Epidemiological studies have shown that where lead chromates alone were manufactured there were no cancer excesses. Animal studies have shown that some insoluble chromates are carcinogenic but the data does not extend to lead chromate pigments. There is no evidence of a risk of lung cancer arising from the use of lead chromate containing products. Epidemiological data shows an association between elevated maternal blood levels and development effects in the offspring. Following the introduction of the criteria for “Toxic to reproduction” hazard classification the E.C. has classified all lead compounds as causing development toxicity in humans. Lead Chromate, although of relatively low solubility and bio availability is included in this classification. There is no data available on the product itself. Exposure to organic solvent vapours may result in adverse health effects such as irritation of the mucous membrane and the respiratory system and adverse effects on the renal and central nervous system. Symptoms include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases loss of consciousness. Repeated or prolonged contact with the product may lead to removal of natural fats from the skin, resulting in non-allergic contact dermatitis and absorption through the skin. Splashes in the eyes may cause irritation and reversible local damage. Ingestion may result in the following effects:- sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea. Other effects may be as described for exposure to vapours. Increased occurrences of lung cancer have been identified in the chromate pigment manufacturing industry. Epidemiological studies have shown that where lead chromates alone were manufactured there were no cancer excesses. Animal studies have shown that some insoluble chromates are carcinogenic but the data does not extend to lead chromate pigments. There is no evidence of a risk of lung cancer arising from the use of lead chromate containing products. Epidemiological data shows an association between elevated maternal blood levels and development effects in the offspring. Following the introduction of the criteria for “Toxic to reproduction” hazard classification the E.C. has classified all lead compounds as causing development toxicity in humans. Lead Chromate, although of relatively low solubility and bio availability is included in this classification. There is no data available on the product itself. Exposure to organic solvent vapours may result in adverse health effects such as irritation of the mucous membrane and the respiratory system and adverse effects on the renal and central nervous systems. Symptoms include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases loss of consciousness. Repeated or prolonged contact with the product may lead to removal of natural fats from the skin resulting in non- allergic contact dermatitis and absorption through the skin. Splashes in the eyes may cause irritation and reversible local damage. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea. Other effects may be as described for exposure to vapours. There is no data available on the product itself. Exposure to organic solvent vapours may result in adverse health effects such as irritation of the mucous membrane and the respiratory system and adverse effects on the renal and central nervous system. Symptoms include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases loss of consciousness. Repeated or prolonged contact with the product may lead to removal of natural fats from the skin, resulting in non- allergic contact dermatitis and absorption through the skin. Splashes in the eyes may cause irritation and reversible local damage. Ingestion may result in the following effects:- sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea. Other effects may be as described for exposure to vapours. There is no data available on the product itself. Exposure to organic solvent vapours may result in adverse health effects such as irritation of the mucous membrane and the respiratory system and adverse effects on the renal and central nervous systems. Symptoms include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases loss of consciousness. Repeated or prolonged contact with the product may lead to removal of natural fats from the skin resulting in non-allergic contact dermatitis and absorption through the skin. Splashes in the eyes may cause irritation and reversible local damage. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea. Other effects may be as described for exposure to vapours. 9804/8914 ISSUE 2 (REV.), MARCH 1997 There is no data available on the product itself. Exposure to organic solvent vapours may result in adverse health effects such as irritation of the mucous membrane and the respiratory system and adverse effects on the renal and central nervous systems. Symptoms include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases loss of consciousness. Repeated or prolonged contact with the product may lead to removal of natural fats from the skin resulting in non-allergic contact dermatitis and absorption through the skin. Splashes in the eyes may cause irritation and reversible local damage. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea. Other effects may be as described for exposure to vapours. Increased incidences of lung cancer have been identified in the chromate manufacturing industry. Epidemiological studies have shown that where lead chromates alone were manufactured there were no cancer excesses. Animal studies have shown that some insoluble chromates are carcinogenic but the data does not extend to lead chromate pigments. There is no evidence of a risk of lung cancer arising from the use of lead chromate containing products. Epidemiological data shows an association between elevated maternal blood lead levels and developmental effects in the offspring. Following the introduction of the criteria for Toxic to Reproduction hazard classification the EC has classified all lead compounds as causing developmental toxicity in humans. Lead chromate, although of relatively low solubility and bioavailablity, is included in this classification. 9804/8927 ISSUE 3 (REV.), MARCH 1997 There is no data available on the product itself. Exposure to organic solvent vapours may result in adverse health effects such as irritation of the mucous membrane and the respiratory system and adverse effects on the renal and central nervous systems. Symptoms include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases loss of consciousness. Repeated or prolonged contact with the product may lead to removal of natural fats from the skin resulting in non- allergic contact dermatitis and absorption through the skin. Splashes in the eyes may cause irritation and reversible local damage. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea. Other effects may be as described for exposure to vapours. Increased incidences of lung cancer have been identified in the chromate manufacturing industry. Epidemiological studies have shown that where lead chromates alone were manufactured there were no cancer excesses. Animal studies have shown that some insoluble chromates are carcinogenic but the data does not extend to lead chromate pigments. There is no evidence of a risk of lung cancer arising from the use of lead chromate containing Epidemiological data shows an association between elevated maternal blood lead levels and developmental effects in the offspring. Following the introduction of the criteria for Toxic to Reproduction hazard classification the EC has classified all lead compounds as causing developmental toxicity in humans. Lead chromate, although of relatively low solubility and bioavailablity; is included in this classification. There is no data available on the product itself. Exposure to organic solvent vapours may result in adverse health effects such as irritation of the mucous membrane and the respiratory system and adverse effects on the renal and central nervous systems. Symptoms include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases loss of consciousness. Repeated or prolonged contact with the product may lead to removal of natural fats from the skin resulting in non-allergic contact dermatitis and absorption through the skin. Splashes in the eyes may cause irritation and reversible local damage. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea. Other effects may be as described for exposure to vapours. 9804/8916 ISSUE 5 (REV.), JUNE 2002 There is no data available on the product itself. Exposure to organic solvent vapours may result in adverse health effects such as irritation of the mucous membrane and the respiratory system and adverse effects on the renal and central nervous systems. Symptoms include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases loss of consciousness. Repeated or prolonged contact with the product may lead to removal of natural fats from the skin resulting in non- allergic contact dermatitis and absorption through the skin. Splashes in the eyes may cause irritation and reversible local damage. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea. Other effects may be as described for exposure to vapours. There is no data available on the product itself. Exposure to organic solvent vapours may result in adverse health effects such as irritation of the mucous membrane and the respiratory system and adverse effects on the renal and central nervous systems. Symptoms include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases loss of consciousness. cont’d 9804/8915 ISSUE 4 (REV.), NOVEMBER 1997 Repeated or prolonged contact with the product may lead to removal of natural fats from the skin resulting in non-allergic contact dermatitis and absorption through the skin. Splashes in the eyes may cause irritation and reversible local damage. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea. Other effects may be as described for exposure to vapours. Increased incidences of lung cancer have been identified in the chromate manufacturing industry. Epidemiological studies have shown that where lead chromates alone were manufactured there were no cancer excesses. Animal studies have shown that some insoluble chromates are carcinogenic but the data does not extend to lead chromate pigments. There is no evidence of a risk of lung cancer arising from the use of lead chromate containing Epidemiological data shows an association between elevated maternal blood lead levels and developmental effects in the offspring. Following the introduction of the criteria for Toxic to Reproduction hazard classification the EC has classified all lead compounds as causing developmental toxicity in humans. Lead chromate, although of a relatively low solubility and bioavailability, is included in this classification. There is no data available on the product itself. cont’d 9804/8922 ISSUE 5 (REV.), JUNE 2002 There is no data available on the product itself. Exposure to organic solvent vapours may result in adverse health effects such as irritation of the mucous membrane and the respiratory system and adverse effects on the renal and central nervous system. Symptoms include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases loss of consciousness. Repeated or prolonged contact with the product may lead to removal of natural fats from the skin, resulting in non- allergic contact dermatitis and absorption through the skin. Splashes in the eyes may cause irritation and reversible local damage. There is no data available on the product itself. Exposure to organic solvent vapours may result in adverse health effects such as irritation of the mucous membrane and the respiratory system and adverse effects on the renal and central nervous systems. Symptoms include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases loss of consciousness. Repeated or prolonged contact with the product may lead to removal of natural fats from the skin resulting in non- allergic contact dermatitis and absorption through the skin. Splashes in the eyes may cause irritation and reversible local damage. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea. Other effects may be as described for exposure to vapours. There is no data available on the product itself. Exposure to organic solvent vapours may result in adverse health effects such as irritation of the mucous membrane and the respiratory system and adverse effects on the renal and central nervous systems. Symptoms include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases loss of consciousness. Repeated or prolonged contact with the product may lead to removal of natural fats from the skin resulting in non-allergic contact dermatitis and absorption through the skin. Splashes in the eyes may cause irritation and reversible local damage. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea. Other effects may be as described for exposure to vapours. There is no data available on the product itself. Exposure to organic solvent vapours may result in adverse health effects such as irritation of the mucous membrane and the respiratory system and adverse effects on the renal and central nervous systems. Symptoms include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases loss of consciousness. Repeated or prolonged contact with the product may lead to removal of natural fats from the skin resulting in non- allergic contact dermatitis and absorption through the skin. Splashes in the eyes may cause irritation and reversible local damage. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea. Other effects may be as described for exposure to vapours. 9804/8966 ISSUE 3 (REV.), JUNE 2002 Eye: Contact with eyes causes redness and discomfort which is transient. Skin: Unlikely to be hazardous by skin absorption. Inhalation: Harmful if inhaled.Vapour may be irritant to the respiratory tract. Ingestion: Unlikely to be hazardous if swallowed. No hazard in normal industrial use. CHRONIC (LONG TERM) EFFECTS OF EXPOSURE Effects of Chronic Exposure: The toxicological properties of this product have not been fully evaluated. Use of good industrial hygiene practices is required. Avoid direct contact with skin or eyes. Do not ingest or inhale. Target Organs: None known. Respiratory Sensitisation: No. Cardiac Sensitisation: No. Skin Sensitisation: No. Possible Birth defect Hazard: No. Carcinogen: No. Acute Toxicity: Low order of acute toxicity. Skin Sensitisation: The possibility of allergic sensitisation should be considered. Human Data: Hypersensitive persons may develop asthmatic symptoms and should refrain from working with the product. Acute Toxicity: Low order of acute toxicity. Skin Sensitisation: The possibility of allergic sensitisation should be considered. Human Data: Hypersensitive persons may develop asthmatic symptoms and should refrain from working with the product. Inhalation: Due to the low volatility of the product there are no hazards associated with inhalation under normal conditions of use. Skin: Acute dermal LD50 is estimated to be greater than 2000mg/kg. Although it is not a common sensitizer there may be a risk of sensitization on prolonged or repeated exposure with damaged skin. Eye: Not considered to be an eye irritant. Ingestion: This product is considered to be of low toxicity having an acute oral LD50 (rat) >5000mg/kg by analogy to other similar products. Product Toxicology Eye Irritation: Transient Product Toxicology Eye Irritation: Transient Product Toxicology Eye Irritation: Transient Product Toxicology Eye Irritation: Transient Eye: Contact with eyes causes redness and discomfort which is transient. Skin: Unlikely to be hazardous by skin absorption. Inhalation: Vapour may be irritant to the respiratory tract. Ingestion: Unlikely to be hazardous if swallowed. No hazard in normal industrial use. CHRONIC (LONG TERM) EFFECTS OF EXPOSURE Effects of Chronic Exposure: The toxicological properties of this product have not been fully evaluated. Use of good industrial hygiene practices is required. Avoid direct contact with skin or eyes. Do not ingest or inhale. Target Organs: None known. Respiratory Sensitisation: No. Cardiac Sensitisation: No. Skin Sensitisation: No. Possible Birth Defect Hazard: No. Carcinogen: No. Inhalation: Inhalation of vapours may cause headaches or dizziness. Skin: Solvent may remove essential oils from the skin making it susceptible to attack from other chemicals. Accute dermal LD50 is estimated to be greater than 2000mg/kg. Eye: May cause irritation to eyes. Ingestion: This product is considered to be of low toxicity having an acute oral LD50 (rat) >2000mg/kg by analogy to other similar products. Ingestion of large quantities may cause liver or kidney damage. Inhalation: Due to the low volatility of the product there are no hazards associated with inhalation under normal conditions of use. Skin: This Product is of low toxicity and is not easily absorbed through the skin. Eye: Not considered to be an eye irritant. Ingestion: This product is considered to be of low toxicity having an acute oral LD5O (rat) >5000 mg/kg by analogy to other similar products. Eye: Contact with eyes causes redness and discomfort which is transient. Skin: Unlikely to be hazardous by skin absorption. Inhalation: Vapour may be irritant to the respiratory tract. Ingestion: Unlikely to be hazardous if swallowed. No hazard in normal industrial use. CHRONIC (LONG TERM) EFFECTS OF EXPOSURE Effects of Chronic Exposure: The toxicological properties of this product have not been fully evaluated. Use of good industrial hygiene practices is required. Avoid direct contact with skin or eyes. Do not ingest or inhale. Target Organs: None known. Respiratory Sensitisation: No. Cardiac Sensitisation: No. Skin Sensitisation: No. Possible Birth Defect Hazard: No. Carcinogen: No. Acute Toxicity: Low order of acute toxicity. Excessive exposure may produce anaesthetic or narcotic effects. Irritancy - Eyes: Liquid and vapour can cause irritation on contact and at high concentrations. Irritancy - Skin: Frequent skin contact may cause irritation and defatting due to the solvent content. Acute Inhalation High concentrations of vapours or mist are likely to be irritating to the respiratory tract and may cause nausea, dizziness, headaches and drowsiness. Skin contact Slightly irritating to the skin. Believed not to be a skin sensitiser. Eye Contact Unlikely to cause more than transient stinging or redness if accidental eye contact occurs. Contact..... 9804/9011 ISSUE 4, (REV) MARCH 2003 Acute toxicology: Oral toxicity: Practically non-toxic (LD50: greater than 2000 mg/kg). Based on testing of similar products and/or the components. Dermal toxicity: Practically non-toxic (LD50: greater than 2000 mg/kg). Based on testing of similar products and/or the components. Inhalation toxicity: Not applicable. Harmful concentrations of mists and/or vapours are unlikely to be encountered through any customary or reasonably foreseeable handling, use, or misuse of this product. Eye irritation: Practically non-irritating. (Draize score: 0 or greater but 6 or less). Based on testing of similar products and/or the components. cont’d 9804/8868 ISSUE 2 (REV.), MARCH 1997 Skin irritation: Practically non-irritating. (Primary Irritation Index: 0.5 or less). Based on testing of similar products and/or the components. Subchronic Toxicology (summary): Severely solvent refined and severely hydrotreated mineral base oils have been tested at doses significantly higher than those expected during normal industrial exposure. Extensive evaluations showed no adverse effects. Chronic Toxicology (summary): The base oils in this product are severely solvent refined and/or severely hydrotreated. Chronic skin painting studies of severely treated oils showed no evidence of carcinogenic effects. Acute toxicology: Oral toxicity: Practically non-toxic (LD50: greater than 2000 mg/kg). Based on testing of similar products and/or the components. Dermal toxicity: Practically non-toxic (LD50: greater than 2000 mg/kg). Based on testing of similar products and/or the components. Inhalation toxicity: Not applicable. Harmful concentrations of mists and/or vapours are unlikely to be encountered through any customary or reasonably foreseeable handling, use, or misuse of this product. Eye irritation: Practically non-irritating. (Draize score: greater than 6 but 15 or less). Based on testing of similar products and/or the components. Skin irritation: Practically non-irritating. (Primary Irritation Index: greater than 0.5 but less than 3). Based on testing of similar products and/or the components. Subchronic Toxicology (summary): Severely solvent refined and severely hydrotreated mineral base oils have been tested at doses significantly higher than those expected during normal industrial exposure. Extensive evaluations showed no adverse effects. Chronic Toxicology (summary): The base oils in this product are severely solvent refined and/or severely hydrotreated. Chronic skin painting studies of severely treated oils showed no evidence of carcinogenic effects. There is no data available on the product itself. Exposure to organic solvent vapours may result in adverse health effects such as irritation of the mucous membrane and the respiratory system and adverse effects on the renal and central nervous systems. Symptoms include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases loss of consciousness. Repeated or prolonged contact with the product may lead to removal of natural fats from the skin resulting in non-allergic contact dermatitis and absorption through the skin. Splashes in the eyes may cause irritation and reversible local damage. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea. Other effects may be as described for exposure to vapours. Increased incidences of lung cancer have been identified in the chromate manufacturing industry. Epidemiological studies have shown that where lead chromates alone were manufactured there were no cancer excesses. Animal studies have shown that some insoluble chromates are carcinogenic but the data does not extend to lead chromate pigments. There is no evidence of a risk of lung cancer arising from the use of lead chromate containing Epidemiological data shows an association between elevated maternal blood lead levels and developmental effects in the offspring. Following the introduction of the criteria for Toxic to Reproduction hazard classification the EC has classified all lead compounds as causing developmental toxicity in humans. Lead chromate, although of a relatively low solubility and bioavailability, is included in this classification. There is no data available on the product itself. Exposure to organic solvent vapours may result in adverse health effects such as irritation of the mucous membrane and the respiratory system and adverse effects on the renal and central nervous systems. Symptoms include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases loss of consciousness. Repeated or prolonged contact with the product may lead to removal of natural fats from the skin resulting in non-allergic contact dermatitis and absorption through the skin. Splashes in the eyes may cause irritation and reversible local damage. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea. Other effects may be as described for exposure to vapours. Increased incidences of lung cancer have been identified in the chromate manufacturing industry. Epidemiological studies have shown that where lead chromates alone were manufactured there were no cancer excesses. Animal studies have shown that some insoluble chromates are carcinogenic but the data does not extend to lead chromate pigments. There is no evidence of a risk of lung cancer arising from the use of lead chromate containing Epidemiological data shows an association between elevated maternal blood lead levels and developmental effects in the offspring. Following the introduction of the criteria for Toxic to Reproduction hazard classification the EC has classified all lead compounds as causing developmental toxicity in humans. Lead chromate, although of a relatively low solubility and bioavailability, is included in this classification. There is no data available on the product itself. Exposure to organic solvent vapours may result in adverse health effects such as irritation of the mucous membrane and the respiratory system and adverse effects on the renal and central nervous systems. Symptoms include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases loss of consciousness. Repeated or prolonged contact with the product may lead to removal of natural fats from the skin resulting in non-allergic contact dermatitis and absorption through the skin. Splashes in the eyes may cause irritation and reversible local damage. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea. Other effects may be as described for exposure to vapours. Increased incidences of lung cancer have been identified in the chromate manufacturing industry. Epidemiological studies have shown that where lead chromates alone were manufactured there were no cancer excesses. Animal studies have shown that some insoluble chromates are carcinogenic but the data does not extend to lead chromate pigments. There is no evidence of a risk of lung cancer arising from the use of lead chromate containing products. Epidemiological data shows an association between elevated maternal blood lead levels and developmental effects in the offspring. Following the introduction of the criteria for Toxic to Reproduction hazard classification the EC has classified all lead compounds as causing developmental toxicity in humans. Lead chromate, although of a relatively low solubility and bioavailability, is included in this classification. Skin Contact: Sulphuric acid causes severe burns and tissue destruction. Eye Contact: Sulphuric acid causes severe burns and tissue destruction. Ingestion: Sulphuric acid causes severe corrosion of the mouth, throat and digestive tract. Lead and lead compounds are harmful if ingested. Inhalation: Sulphuric acid mist generated during charging can irritate the nose, throat and upper respiratory tract. Lead can only be inhaled if released from the battery container and then reduced to a dry airborne dust. Prompt disposal of waste will prevent exposure by this route. See DISPOSAL CONSIDERATIONS. Acute Toxicology Oral Toxicity: Practically non-toxic (LD50: greater than 2,000 mg/kg). Based on testing of similar products and/or the components. Dermal Toxicity: Practically non-toxic (LD50: greater than 2,000 mg/kg). Based on testing of similar products and/or the components. Inhalation Toxicity: Not applicable. Harmful concentrations of mists and/or vapours are unlikely to be encountered through any customary or reasonably foreseeable handling, use, or misuse of this product. Eye Irritation: Practically non-irritating. Skin Irritation: Practically non-irritating. (Primary Irritation Index: greater than 0.5 but less than 3). Based on testing of similar products and/or the components. Subchronic Toxicology (Summary) Severely solvent refined and severely hydrotreated mineral base oils have been tested at doses significantly higher than those expected during normal industrial exposure. Extensive evaluations showed no adverse effects. Chronic Toxicology (Summary) The base oils in this product are severely solvent refined and/or severely hydrotreated. Chronic skin painting studies of severely treated oils showed no evidence of carcinogenic effects. IK@'4@=59@S'>59@47<'37A@';5<A'2A@S'59'8K@'=;4>2<785;9';='8K5A'J4;S268'74@';='7'<;]';4S@4';='8;\5658H'59'8@A8'795>7<AM'1+*"' P478Q'5A'73;?@'#"' $V M'-<8K;2 K'5965S@987<'6;98768']58K'8K@'AV59'S;@A'9;8'672A@'5>>@S578@'54458785;9&'J4;<;9 @S'79S' 4@J@78@S'6;98768'>7H'S@=78'8K@'AV59'79S'@?@9827<<H'672A@'S@4>78585AM' ' 9804/9015 ISSUE 1, JULY 2000 Eye: Slight /mild irritant Skin: Repeated or prolonged contact may cause deatting of the skin resulting in dryness, cracking and dematits. Inhalation: The vapour has anaesthetic properties and when inhaled at concentrations above the occupational exposure limit, it may cause respiatory irratation, headache, fatigue, dizziness and incoordination. Ingestion: Low oral toxicity There is no data available on the product itself. Exposure to organic solvent vapours may result in adverse health effects such as irritation of the mucous membrane and the respiratory system and adverse effects on the renal and central nervous systems. Symptoms include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases loss of consciousness. Cont’d 9804/9019 ISSUE1, JANUARY 2002 Repeated or prolonged contact with the product may lead to removal of natural fats from the skin resulting in non- allergic contact dermatitis and absorption through the skin. Splashes in the eye may cause irritation and reversible local damage. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea. Other effects may be as described for exposure to vapours. The preparation is considered to be low order of toxicity and, used in accordance with instructions, presents low chemical hazard. Inhalation of mist or spray will cause irritation and if severe could cause discomfort in breathing. As with all chemicals, individuals with lung disorders or breathing disorders may experience more severe reactions. Ingestion will irritate trachea and cause pain and sickness. Prolonged exposure is likely to cause inflammation and can damage tissue. Ingestion can cause risk of asphyxia if preparation is aspired into lungs. Aspiration into lungs is serious and may prevent breathing (asphyxia). Medical attention is urgent. Trachea/mouth will also be irritated. There is no data available on the product itself. Exposure to organic solvent vapours may result in adverse health effects such as irritation of the mucous membrane and the respiratory system and adverse effects on the renal and central nervous systems. Symptoms include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases loss of consciousness. Repeated or prolonged contact with the product may lead to removal of natural fats from the skin resulting in non- allergic contact dermatitis and absorption through the skin. Splashes in the eyes may cause irritation and reversible local damage. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea. Other effects may be as described for exposure to vapours. Acute toxicity: LD50, rat, oral: > 2000 mg/kg LC50, rabbit, dermal: > 5000 mg/kg Chronic toxicity ethanol: Possible risk of impaired fertility Other toxicological effects: Inhalation: Coughing, sore throat, headache, closeness Eyes: Redness, pain Ingestion: Sore throat, stomach ache, sickness Acute toxicology: Oral toxicity: Practically non-toxic (LD50: greater than 2000 mg/kg) Based on testing of similar products and/or the components. Dermal toxicity: Practically non-toxic (LD50: greater than 2000 mg/kg) Based on testing of similar products and/or the components. Inhalation toxicity: Not applicable. Harmful concentrations of mists and/or vapours are unlikely to be encountered through any customary or reasonably foreseeable handling, use, or misuse of this product. Eye irritation: Practically non-irritating. (Draize score: greater than 6 but 15 or less). Based on testing of similar products and/or the components. Skin irritation: Practically non-irritating. (Primary Irritation Index: greater than 0.5 but less than 3). Based on testing of similar products and/or the components. cont’d 9804/9032 ISSUE1, JANUARY 2002 Other Acute Toxicity Data: The acute toxicological results summarsed previously are based on testing of representative products. Subchronic Toxicology (summary): Representative formulations have been tested by dermal applications 5 days/week for 90 days at doses significantly higher than those expected during normal industrial exposure. Extensive evaluations, including microscopic examination of internal organs and clinical chemistry of body fluids, showed no adverse effects. Reproductive Toxicology (summary): Dermal exposure of pregnant rats to representative formulations did not cause adverse effects in either the mothers or their offspring. Chronic Toxicology (summary): The base oils in this product are severely solvent refined and/or severely hydrotreated. Chronic skin painting studies of severely treated oils showed no evidence of carcinogenic effects. These results are confirmed on a continuing basis. Sensitisation (summary): Representative formulations have not caused skin sensitisation in guinea pigs. There is no data available on the product itself. Exposure to organic solvent vapours may result in adverse health effects such as irritation of the mucous membrane and the respiratory system and adverse effects on the renal and central nervous systems. Symptoms include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases loss of consciousness. Splashes in the eyes may cause irritation and reversible local damage. Repeated or prolonged contact with the product may lead to removal of natural fats from the skin resulting in non-allergic contact dermatitis and absorption through the skin. Splashes in the eye may cause irritation and reversible local damage. 9804/9023 ISSUE 1, JANUARY 2002 There is no data available on the product itself. Exposure to organic solvent vapours may result in adverse health effects such as irritation of the mucous membrane and the respiratory system and adverse effects on the renal and central nervous systems. Symptoms include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases loss of consciousness. cont’d 9804/9024 ISSUE 1, JANUARY 2002 Health Hazards, General: Prolonged and repeated contact with solvents over a long period may lead to permanent health problems. Inhalation: Gas or vapour in high concentrations may irritate respiratory system. Gas or vapour displaces oxygen available for breathing (asphyxiant). Skin: Product has a defatting effect on skin. Prolonged or repeated exposure may cause severe irritation. cont’d 9804/9026 ISSUE 1, JANUARY 2002 There is no data available on the product itself. Exposure to organic solvent vapours may result in adverse health effects such as irritation of the mucous membrane and the respiratory system and adverse effects on the renal and central nervous systems. Symptoms include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases loss of consciousness. Repeated or prolonged contact with the product may lead to removal of natural fats from the skin resulting in non- allergic contact dermatitis and absorption through the skin. Splashes in the eye may cause irritation and reversible local damage. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea. Other effects may be as described for exposure to vapours. Based on the properties of the isocyanate content of this product, respiratory exposure may cause acute irritation and/or sensitisation of the respiratory system, resulting in asthmatic symptoms, wheezing and a tightness of the chest. Sensitised persons may subsequently show asthmatic symptoms when exposed to airborne concentrations of isocyanates well below the occupational exposure limit. Repeated exposure may lead to permanent respiratory disability. COSHH requires that persons exposed to products containing isocyanates, which are respiratory sensitisers, are subject to appropriate health surveillance. Publications giving guidance on health surveillance are listed in Section 16. Employees should be provided with a copy of the HSE pocket card containing information on isocyanate 2-pack spray paints. Increased incidences of lung cancer have been identified in the chromate manufacturing industry. Epidemiological studies have shown that where lead chromates alone were manufactured, there were no cancer excesses. Animal studies have shown that some insoluble chromates are carcinogenic but the data does not extend to lead chromate pigments. There is no evidence of a risk of lung cancer arising from the use of lead chromate containing products. Epidemiological data shows an association between elevated maternal blood lead levels and development effects in the offspring. Following the introduction of the criteria for 'Toxic For Reproduction' hazard classification, the EC has classified all lead compounds as causing developmental toxicity in humans. Lead chromate, although of relatively low solubility and bioavailability, is included in this classification. 9804/9027 ISSUE 1, JANUARY 2002 There is no data available on the product itself. Exposure to organic solvent vapours may result in adverse health effects such as irritation of the mucous membrane and respiratory system and adverse effects on the renal and central nervous systems. Symptoms include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases unconsciousness. Splashes in the eyes may cause irritation and reversible local damage. Repeated or prolonged contact with the product may lead to removal of natural fats from the skin resulting in non-allergic contact dermatitis and absorption through the skin. Splashes in the eye may cause irritation and reversible local damage. There is no data available on the product itself. Exposure to organic solvent vapours may result in adverse health effects such as irritation of the mucous membrane and respiratory system and adverse effects on the renal and central nervous systems. Symptoms include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases unconsciousness. Splashes in the eyes may cause irritation and reversible local damage. Repeated or prolonged contact with the product may lead to removal of natural fats from the skin resulting in non-allergic contact dermatitis and absorption through the skin. Splashes in the eye may cause irritation and reversible local damage. There is no data available on the product itself. Exposure to organic solvent vapours may result in adverse health effects such as irritation of the mucous membrane and the respiratory system and adverse effects on the renal and central nervous systems. Symptoms include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases loss of consciousness. Repeated or prolonged contact with the product may lead to removal of natural fats from the skin resulting in non- allergic contact dermatitis and absorption through the skin. Splashes in the eye may cause irritation and reversible local damage. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea. Other effects may be as described for exposure to vapours. There is no data available on the product itself. Exposure to organic solvent vapours may result in adverse health effects such as irritation of the mucous membrane and the respiratory system and adverse effects on the renal and central nervous systems. Symptoms include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases loss of consciousness. Repeated or prolonged contact with the product may lead to removal of natural fats from the skin resulting in non- allergic contact dermatitis and absorption through the skin. Splashes in the eye may cause irritation and reversible local damage. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea. Other effects may be as described for exposure to vapours. Increased incidences of lung cancer have been identified in the chromate manufacturing industry. Epidemiological studies have shown that where lead chromates alone were manufactured, there were no cancer excesses. Animal studies have shown that some insoluble chromates are carcinogenic but the data does not extend to lead chromate pigments. There is no evidence of a risk of lung cancer arising from the use of lead chromate containing products. Epidemiological data shows an association between elevated maternal blood lead levels and development effects in the offspring. Following the introduction of the criteria for 'Toxic For Reproduction' hazard classification, the EC has classified all lead compounds as causing developmental toxicity in humans. Lead chromate, although of relatively low solubility and bioavailability, is included in this classification. 9804/9034 ISSUE 1, JANUARY 2002 Chronic (long term) effects of Exposure Adhesive These indications are based on the toxicological data for product constituents, evaluated in accordance with current regulations. Acute Toxicity Inhalation Risk is improbable under normal conditions of use Contact with the skin: Harmless Ingestion: Harmless Local Effects Inhalation: Risk is improbable under normal conditions Contact with skin: Not irritating Contact with the eyes: Not irritating Cont’d 9804/9021 ISSUE1, MARCH 2002 Sensitisation Contact with the skin: Not allergenic Chronic Toxicity or Long-term Toxicity Inhalation: Risk is improbable under normal conditions o use Contact with the skin: Characteristic skin affections (oil blisters) may develop following prolonged and repeated exposure through contact with stained clothing. Specific Effects Carcinogenecity: Not carcinogenic This product is formulated from refined mineral oils and other ingredients considered to be non-carcinogenic. Paint There is no data available on the product itself. Exposure to organic solvent vapours may result in adverse health effects such as irritation of the mucous membrane and respiratory system and adverse effects on the renal and central nervous systems. Symptoms include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases unconsciousness. Splashes in the eyes may cause irritation and reversible local damage. Repeated or prolonged contact with the product may lead to removal of natural fats from the skin resulting in non-allergic contact dermatitis and absorption through the skin. Splashes in the eye may cause irritation and reversible local damage. Hardener There is no data available on the product itself. Respiratory exposure may cause acute irritation &/or sensitisation of the respiratory system resulting in asthmatic symptoms. Repeated exposure may lead to permanent respiratory disability. Exposure to organic solvent vapours may result in adverse health effects such as irritation of the mucous membrane and respiratory system and adverse effects on the renal and central nervous systems. Symptoms include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases unconsciousness. Splashes in the eyes may cause irritation and reversible local damage. Repeated or prolonged contact with the product may lead to removal of natural fats from the skin resulting in non-allergic contact dermatitis and absorption through the skin. 9804/9035 ISSUE 1, MARCH 2002 There is no data available on the product itself. Exposure to organic solvent vapours may result in adverse health effects such as irritation of the mucous membrane and the respiratory system and adverse effects on the renal and central nervous systems. Symptoms include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases loss of consciousness. Repeated or prolonged contact with the product may lead to removal of natural fats from the skin resulting in non- allergic contact dermatitis and absorption through the skin. Splashes in the eyes may cause irritation and reversible local damage. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea. Other effects may be as described for exposure to vapours. There is no data available on the product itself. Exposure to organic solvent vapours may result in adverse health effects such as irritation of the mucous membrane and the respiratory system and adverse effects on the renal and central nervous systems. Symptoms include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases loss of consciousness. Cont’d 9804/9019 ISSUE 2 (REV), JUNE 2002 Repeated or prolonged contact with the product may lead to removal of natural fats from the skin resulting in non- allergic contact dermatitis and absorption through the skin. Splashes in the eye may cause irritation and reversible local damage. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea. Other effects may be as described for exposure to vapours. 9804/9025 ISSUE 2, SEPTEMBER 2002 Acute Toxicity Low order of acute toxicity. Excessive exposure may produce anaesthetic or narcotic effects. Eye Irritation Liquid and vapours can cause irritation on contact and at high concentrations. Skin Irritation Frequent or prolonged skin contact may cause some local short term skin irritation. Sensitisation - Skin The possibility of allergic sensitisation should be considered. Human Data Inhalation causes respiratory sensitisation. Hypersensitive persons may develop asthmatic symptoms and should refrain from working with the product. Acute Toxicity Low order of acute toxicity. Skin Irritation Frequent or prolonged skin contact may cause some local short term skin irritation. Sensitisation - Skin The possibility of allergic sensitisation should be considered. Human Data Hypersensitive persons may develop asthmatic symptoms and should refrain from working with the product. Health Warnings: No specific health warnings noted. Acute Toxicology Oral Toxicity: Practically non-toxic (LD50: greater than 2,000 mg/kg). Based on testing of similar products and/or the components. Dermal Toxicity: Practically non-toxic (LD50: greater than 2,000 mg/kg). Based on testing of similar products and/or the components. Inhalation Toxicity: Not applicable. Harmful concentrations of mists and/or vapours are unlikely to be encountered through any customary or reasonably foreseeable handling, use, or misuse of this product. Eye Irritation: Practically non-irritating. (Draize score: 0 or greater but 6 or less). Based on testing of similar products and/or the components. Skin Irritation: Practically non-irritating. (Primary Irritation Index: 0.5 but less). Based on testing of similar products and/or the components. Subchronic Toxicology (Summary) Severely solvent refined and severely hydrotreated mineral base oils have been tested at doses significantly higher than those expected during normal industrial exposure. Extensive evaluations showed no adverse effects. Chronic Toxicology (Summary) The base oils in this product are severely solvent refined and/or severely hydrotreated. Chronic skin painting studies of severely treated oils showed no evidence of carcinogenic effects. The refined mineral base oils used in the formulation of this product are of a low order of toxicity in test animals. LD50 (rat) is above 10 g/kg. Although incidental contact with the skin does not cause immediate irritation, prolonged and repeated contact may defat the skin and eventually cause dermatitis. 9804/8912 ISSUE 5, (REV.) MARCH 2003 Acute Toxicology Oral Toxicity: Practically non-toxic (LD50: greater than 2,000 mg/kg). Based on testing of similar products and/or the components. Dermal Toxicity: Practically non-toxic (LD50: greater than 2,000 mg/kg). Based on testing of similar products and/or the components. cont’d 9804/8905 ISSUE 5, (REV.) MARCH 2003 Eyes: Unlikely to cause eye irritation. Skin: Although incidental contact with the skin does not cause immediate irritation, prolonged and repeated contact may defat the skin and eventually cause dermatitis. Inhalation: Not volatile. It is not likely to be an inhalation hazard at normal ambient temperatures. If overheated, fumes and vapours are irritating to the breathing passages and lungs. Ingestion: Ingestion is unlikely to cause adverse systemic health effects. Other: The refined mineral base oils used in the formulation of this product are of a low order of toxicity in test JCB HP Uni ATF Page 2 of 3 9804/9038 ISSUE 1, MARCH 2003 Eyes: Unlikely to cause eye irritation. Skin: Although incidental contact with the skin does not cause immediate irritation, prolonged and repeated contact may defat the skin and eventually cause dermatitis. Inhalation: Not volatile. It is not likely to be an inhalation hazard at normal ambient temperatures. If overheated, fumes and vapours are irritating to the breathing passages and lungs. Ingestion: Ingestion is unlikely to cause adverse systemic health effects. Other: The refined mineral base oils used in the formulation of this product are of a low order of toxicity in test JCB EP Transmission Page 2 of 3 9804/9040 ISSUE 1, MARCH 2003 Eyes: Unlikely to cause eye irritation. Skin: Although incidental contact with the skin does not cause immediate irritation, prolonged and repeated contact may defat the skin and eventually cause dermatitis. Inhalation: Not volatile. It is not likely to be an inhalation hazard at normal ambient temperatures. If overheated, fumes and vapours are irritating to the breathing passages and lungs. Ingestion: Ingestion is unlikely to cause adverse systemic health effects. Other: The refined mineral base oils used in the formulation of this product are of a low order of toxicity in test JCB EP Transmission Page 2 of 3 9804/9045 ISSUE 1, MARCH 2003 The refined mineral base oils used in the formulation of this product are of a low order of toxicity in test animals. LD50 (rat) is above 10 g/kg. Although incidental contact with the skin does not cause immediate irritation, prolonged and repeated contact may defat the skin and eventually cause dermatitis. 9804/8910 ISSUE 5, (REV.) MARCH 2003 Eyes: Unlikely to cause eye irritation. Skin: Although incidental contact with the skin does not cause immediate irritation, prolonged and repeated contact may defat the skin and eventually cause dermatitis. Inhalation: Not volatile. It is not likely to be an inhalation hazard at normal ambient temperatures. JCB EP Engine Oil Page 2 of 3 9804/9039 ISSUE 1, MARCH 2003 The refined mineral base oils used in the formulation of this product are of a low order of toxicity in test animals. LD50 (rat) is above 10 g/kg. Although incidental contact with the skin does not cause immediate irritation, prolonged and repeated contact may defat the skin and eventually cause dermatitis. 9804/9047 ISSUE 1, MARCH 2003 Eyes: Unlikely to cause eye irritation. Skin: Although incidental contact with the skin does not cause immediate irritation, prolonged and repeated contact may defat the skin and eventually cause dermatitis. Inhalation: Not volatile. It is not likely to be an inhalation hazard at normal ambient temperatures. If overheated, fumes and vapours are irritating to the breathing passages and lungs. Ingestion: Ingestion is unlikely to cause adverse systemic health effects. JCB EP Hydraulic Page 2 of 3 9804/9048 ISSUE 1, MARCH 2003 Eyes: Unlikely to cause eye irritation. Skin: Although incidental contact with the skin does not cause immediate irritation, prolonged and repeated contact may defat the skin and eventually cause dermatitis. Inhalation: Not volatile. It is not likely to be an inhalation hazard at normal ambient temperatures. If overheated, fumes and vapours are slightly irritating to the breathing passages and lungs. Ingestion: Ingestion is unlikely to cause adverse systemic health effects. Other: The refined mineral base oils used in the formulation of this product are of a low order of toxicity in test animals. LD50 (rat) for base oils is above 5 g/kg . 12. Eyes: Unlikely to cause eye irritation. Skin: Although incidental contact with the skin does not cause immediate irritation, prolonged and repeated contact may defat the skin and eventually cause dermatitis. Inhalation: Not volatile. It is not likely to be an inhalation hazard at normal ambient temperatures. If overheated, fumes and vapours are irritating to the breathing passages and lungs. Ingestion: Ingestion is unlikely to cause adverse systemic health effects. Other: The refined mineral base oils used in the formulation of this product are of a low order of toxicity in test animals. LD50 (rat) for base oils is above 5 g/kg . 12. Eyes: Unlikely to cause eye irritation. Skin: Although incidental contact with the skin does not cause immediate irritation, prolonged and repeated contact may defat the skin and eventually cause dermatitis. Inhalation: Not volatile. It is not likely to be an inhalation hazard at normal ambient temperatures. If overheated, fumes and vapours are slightly irritating to the breathing passages and lungs. Ingestion: Ingestion is unlikely to cause adverse systemic health effects. Other: The refined mineral base oils used in the formulation of this product are of a low order of toxicity in test animals. LD50 (rat) for base oils is above 5 g/kg . 12. Eyes: Slightly irritating to the eye. Skin: Although incidental contact with the skin does not cause immediate irritation, prolonged and repeated contact may defat the skin and eventually cause dermatitis. Inhalation: Not volatile. It is not likely to be an inhalation hazard at normal ambient temperatures. If overheated, fumes and vapours are irritating to the breathing passages and lungs. Ingestion: Ingestion is unlikely to cause adverse systemic health effects. Other: The refined mineral base oils used in the formulation of this product are of a low order of toxicity in test animals. LD50 (rat) for base oils is above 5 g/kg . 12. The refined mineral base oils used in the formulation of this product are of a low order of toxicity in test animals. LD50 (rat) is above 10 g/kg. Although incidental contact with the skin does not cause immediate irritation, prolonged and repeated contact may defat the skin and eventually cause dermatitis. 9804/9046 ISSUE 1, MARCH 2003 The following toxicological assessment is based on a knowledge of the toxicity of the product’s components Estimated oral LD50 Rat, > 2000mg/kg

ECOLOGICAL INFORMATION

Mobility 690&81 IH4F&GE&G3R 7MFG70&M3I&G3E 7HJ70&M3I&QG77&M44H/H7MF0&G3&F90&21 H3I<&.K& 1070ME0I&F &QMF01&F90&81 IH4F&QG77&K7 MF<& Persistence/Degradability 690&81 IH4F&GE&0Z804F0I&F &J0&10EGEFM3F&F &JG I021MIMFG 3<& Bio-accumulation `1 IH4F&GE&3 F&0Z804F0I&F &JG M44H/H7MF0<& The base oil components are not expected to be dangerous to the aquatic environment. Not readily biodegradable. 13. DISPOSAL CONSIDERATIONS Transport to authorised waste location, or incineration under controlled conditions. 14. TRANSPORT INFORMATION UN-No: Not classified IATA/ICAO: Not classified RID/ADR: Not classified Other: IMO: Not classified 15. REGULATORY INFORMATION No EC exposure limit established. EC Labelling/Classification: I63';SG;13;R'36'.;'36S01'36'2c-2301';4:0/649;43J'I63'/;2R07E'.06R;5/2R2.7;J' ' 13. DISPOSAL CONSIDERATIONS F/24<G6/3'36'2-3H6/0<;R']2<3;'76123064&'6/'04104;/23064'-4R;/'1643/677;R'164R03064<J' ' 14. TRANSPORT INFORMATION UN-No I63'172<<080;R'IATA/ICAO I63'172<<080;R' RID/ADR: I63'172<<080;R'Other: IMO: I63'172<<080;R' ' 15. REGULATORY INFORMATION I6'A>';SG6<-/;'70903';<32.70<H;RJ' EC Labelling/Classification: Environmental Fate and Effects: Acute LC/EC50 Fish Juvenile Rainbow Trout Practically non-toxic. Based on testing of similar products Environmental precautions: Prevent spills from entering storm sewers or drains and contact with soil. 13. DISPOSAL CONSIDERATIONS Waste Disposal Product is suitable for burning in an enclosed, controlled burner for fuel value or disposal by supervised incineration. Such burning may be limited by the controlling authority. In addition, the product is suitable for processing by an approved recycling facility or can be disposed of at any licensed waste disposal site. Use of these methods is subject to user compliance with applicable laws and regulations and consideration of product characteristics at time of disposal. 14. TRANSPORT INFORMATION USA DOT: Not regulated by USA DOT RID/ADR: Not regulated by RID/ADR IMO: Not regulated by IMO IATA: Not regulated by IATA 9804/8909 ISSUE 5 (REV.), MARCH 2003 Not expected to be dangerous for the aquatic environment. LC50 fish (96 h): >500 mg/l. 13. DISPOSAL CONSIDERATIONS Transport to authorised waste location, or incineration under controlled conditions. 14. TRANSPORT INFORMATION UN-No: Not classified IATA/ICAO: Not classified RID/ADR: Not classified Other: IMO: Not classified 15. REGULATORY INFORMATION No EC exposure limit established. EC Labelling/Classification: The base oil components are not expected to be dangerous to the aquatic environment. Not readily biodegradable. 13. DISPOSAL CONSIDERATIONS Transport to authorised waste location, or incineration under controlled conditions. 14. TRANSPORT INFORMATION UN-No: Not classified IATA/ICAO: Not classified RID/ADR: Not classified Other: IMO: Not classified 15. REGULATORY INFORMATION No EC exposure limit established. EC Labelling/Classification: The base oil components are not expected to be dangerous to the aquatic environment. Not readily biodegradable. 13. DISPOSAL CONSIDERATIONS Transport to authorised waste location, or incineration under controlled conditions. 14. TRANSPORT INFORMATION UN-No: Not classified IATA/ICAO: Not classified RID/ADR: Not classified Other: IMO: Not classified 15. REGULATORY INFORMATION No EC exposure limit established. EC Labelling/Classification: The base oil components are not expected to be dangerous to the aquatic environment. Not readily biodegradable. 13. DISPOSAL CONSIDERATIONS Transport to authorised waste location, or incineration under controlled conditions. 14. TRANSPORT INFORMATION UN-No: Not classified IATA/ICAO: Not classified RID/ADR: Not classified Other: IMO: Not classified 15. REGULATORY INFORMATION No EC exposure limit established. EC Labelling/Classification: No information available but can be expected to biodegrade slowly. 13. DISPOSAL CONSIDERATIONS Environmental Fate and Effects: Not established. Environmental precautions: Prevent spills from entering storm sewers or drains and contact with soil. 13. DISPOSAL CONSIDERATIONS Waste Disposal Product is suitable for burning in an enclosed, controlled burner for fuel value or disposal by supervised incineration. Such burning may be limited by the controlling authority. In addition, the product is suitable for processing by an approved recycling facility or can be disposed of at any licensed waste disposal site. Use of these methods is subject to user compliance with applicable laws and regulations and consideration of product characteristics at time of disposal. 14. TRANSPORT INFORMATION USA DOT: Not regulated by USA DOT RID/ADR: Not regulated by RID/ADR IMO: Not regulated by IMO IATA: Not regulated by IATA 15. REGULATORY INFORMATION Environmental Fate and Effects: Acute LC/EC50 Fish Juvenile Rainbow Trout practically non-toxic. Based on testing of similar products Environmental precautions: Prevent spills from entering storm sewers or drains and contact with soil. 13. DISPOSAL CONSIDERATIONS Waste Disposal Product is suitable for burning in an enclosed, controlled burner for fuel value or disposal by supervised incineration. Such burning may be limited by the controlling authority. In addition, the product is suitable for processing by an approved recycling facility or can be disposed of at any licensed waste disposal site. Use of these methods is subject to user compliance with applicable laws and regulations and consideration of product characteristics at time of disposal. 14. TRANSPORT INFORMATION USA DOT: Not regulated by USA DOT RID/ADR: Not regulated by RID/ADR IMO: Not regulated by IMO IATA: Not regulated by IATA 15. REGULATORY INFORMATION Environmental Fate and Effects: Not established. 13. DISPOSAL CONSIDERATIONS Waste Disposal: Product is suitable for burning in an enclosed, controlled burner for fuel value or disposal by supervised incineration. Such burning may be limited by the controlling authority. In addition, the product is suitable for processing by an approved recycling facility or can be disposed of at any licensed waste disposal site. Use of these methods is subject to user compliance with applicable laws and regulations and consideration of product characteristics at time of disposal. 14. TRANSPORT INFORMATION USA DOT: Not regulated by USA DOT. RID/ADR: Not regulated by RID/ADR. IMO: Not regulated by IMO. IATA: Not regulated by IATA. 9804/8903 ISSUE 4, (REV.) NOVEMBER 1997 15. REGULATORY INFORMATION EU Labelling: EC Labelling not required The following product ingredients are cited on the lists below: Chemical Name CAS Number List Citations No reportable ingredients Regulatory Lists Searched 1=IARC 1 6=NO ALLERGI 11=DE TERAT B 16=DE CARC B 21=CH CARC 2=IARC 2A 7=SE ALLERGY 12=DE TERAT C 17=AT TERAT A 3=IARC 2B 8=SE CARC 13=DE TERAT D 18=AT TERAT B 4=NTP CARC 9=DK CARC 14=DE CARC A1 19=AT TERAT C 5=NTP SUS 10=DE TERAT A 15=DE CARC A2 20=AT TERAT D CARC=CARCINOGEN; SUS=SUSPECTED CARCINOGEN; TERAT=TERATOGENIC AT=Austria DE=Germany NO=Norway CH=Switzerland DK=Denmark SE=Sweden Mobility: The product is insoluble in water. The product is poorly absorbed onto soils or sediments. cont’d 9804/8931 ISSUE 3 (REV.), JUNE 2002 Environmental Fate and Effects Acute LC/EC50 Fish Juvenile Rainbow Trout Practically non-toxic. Based on testing of similar products. 13. DISPOSAL CONSIDERATIONS Waste Disposal: Product is suitable for burning in an enclosed, controlled burner for fuel value or disposal by supervised incineration. Such burning may be limited by the controlling authority. In addition, the product is suitable for processing by an approved recycling facility or can be disposed of at any licensed waste disposal site. Use of these methods is subject to user compliance with applicable laws and regulations and consideration of product characteristics at time of disposal. 14. TRANSPORT INFORMATION USA DOT: Not regulated by USA DOT. RID/ADR: Not regulated by RID/ADR. IMO: Not regulated by IMO. IATA: Not regulated by IATA. 9804/8970 ISSUE 3, (REV.) NOVEMBER 1997 15. REGULATORY INFORMATION EU Labelling: EC Labelling not required The following product ingredients are cited on the lists below: Chemical Name CAS Number List Citations No reportable ingredients Regulatory Lists Searched 1=IARC 1 6=NO ALLERGI 11=DE TERAT B 16=DE CARC B 21=CH CARC 2=IARC 2A 7=SE ALLERGY 12=DE TERAT C 17=AT TERAT A 3=IARC 2B 8=SE CARC 13=DE TERAT D 18=AT TERAT B 4=NTP CARC 9=DK CARC 14=DE CARC A1 19=AT TERAT C 5=NTP SUS 10=DE TERAT A 15=DE CARC A2 20=AT TERAT D CARC=CARCINOGEN; SUS=SUSPECTED CARCINOGEN; TERAT=TERATOGENIC AT=Austria DE=Germany NO=Norway CH=Switzerland DK=Denmark SE=Sweden Mobility The product will leach into soil. If released into water the product will float. Persistence/Degradability The product is expected to be resistant to biodegradation. Bio-accumulation Product is not expected to bioaccumulate. 13. DISPOSAL CONSIDERATIONS Container Disposal Plastic caps and empty aerosols may be recycled via appropriate routes. Empty aerosols may be disposed of by authorised landfill. Do not incinerate closed containers. 14. TRANSPORT INFORMATION The base oil components are not expected to be dangerous to the aquatic environment. Not readily biodegradable. 13. DISPOSAL CONSIDERATIONS Transport to authorised waste location, or incineration under controlled conditions. 14. TRANSPORT INFORMATION UN-No: Not classified IATA/ICAO: Not classified RID/ADR: Not classified Other: IMO: Not classified 15. REGULATORY INFORMATION No EC exposure limit established. EC Labelling/Classification: Environmental Fate and Effects: a;D&/>D@<52>L/?N& & 13. DISPOSAL CONSIDERATIONS Waste Disposal: R0;?=3D&2>&>=2D@<5/&K;0&<=0C2CI&2C&@C&/C35;>/?\&3;CD0;55/?&<=0C/0&K;0&K=/5&1@5=/&;0&?2>A;>@5&<Q&>=A/012>/?& 2C32C/0@D2;CN& *=3L&<=0C2CI&B@Q&</&52B2D/?&<Q&DL/&3;CD0;552CI&@=DL;02DQN&.C&@??2D2;C\&DL/&A0;?=3D&2>&>=2D@<5/&K;0&A0;3/>>2CI&<Q&@C& @AA0;1/?&0/3Q352CI&K@3252DQ&;0&3@C&</&?2>A;>/?&;K&@D&@CQ&523/C>/?&G@>D/&?2>A;>@5&>2D/N&f>/&;K&DL/>/&B/DL;?>&2>& >=<h/3D&D;&=>/0&3;BA52@C3/&G2DL&@AA523@<5/&5@G>&@C?&0/I=5@D2;C>&@C?&3;C>2?/0@D2;C&;K&A0;?=3D&3L@0@3D/02>D23>&@D& D2B/&;K&?2>A;>@5N& & 14. TRANSPORT INFORMATION USA DOT: a;D&0/I=5@D/?&<Q&f*P&[c4N& IMO: a;D&0/I=5@D/?&<Q&.McN& IATA: a;D&0/I=5@D/?&<Q&.P4PN& 9804/8994 ISSUE 2, JULY 2000 Degradability: No data available Acute fish toxicity: No data available Water hazard classification: No data available. However see disposal considerations. 13. DISPOSAL CONSIDERATIONS The base oil components are not expected to be dangerous to the aquatic environment. Not readily biodegradable. 13. DISPOSAL CONSIDERATIONS Transport to authorised waste location, or incineration under controlled conditions. 14. TRANSPORT INFORMATION UN-No: Not classified IATA/ICAO: Not classified RID/ADR: Not classified Other: IMO: Not classified 15. REGULATORY INFORMATION No EC exposure limit established. EC Labelling/Classification: Potential Effect on Environment: Unknown 13. DISPOSAL CONSIDERATIONS Waste Disposal Methods: Waste disposal should be in accordance with existing Community, National and and local regulations. Empty Container Warnings: Empty containers may contain product residue; follow SDS and label warnings even after they have been emptied. 9804/9000 ISSUE 2, (REV) SEPTEMBER 2002 Potential Effect on Environment: Unknown 13. DISPOSAL CONSIDERATIONS Waste Disposal Methods: Waste disposal should be in accordance with existing Community, National and and local regulations. Empty Container Warnings: Empty containers may contain product residue; follow SDS and label warnings even after they have been emptied. 9804/9003 ISSUE 2, (REV) SEPTEMBER 2002 Mobility: Not determined. Persistence and degradability: According to EC criteria: Expected to be readily biodegradable. Potential to bioaccumulate: This product is estimated to have a low potential to bioconcentrate. Aquatic toxicity: Believed not to be toxic to aquatic species. There is no data on the product itself. The product should not be allowed to enter drains or water courses or be deposited where it can affect ground or surface waters. The Air Pollution Control requirements of regulations made under the Environmental Protection Act may apply to the use of this product. White spirit has a high potential to bio-accumulate, is practically non-toxic to aquatic organisms and has good bio- degradability. 14. DISPOSAL CONSIDERATIONS Waste Disposal: Do not allow into drains or water courses or dispose of where ground or surface waters may be affected. Wastes, including emptied containers, are controlled wastes and should be disposed of in accordance with regulations made under the Control of Pollution Act. 9804/9018 ISSUE 1, March 2001 Using the information provided in this data sheet, advice should be obtained from the Waste Regulation Authority as to whether the special waste regulations apply. 15. TRANSPORT INFORMATION CCCN: 3403 99 10 UN NO: 1950 AEROSOL: CLASS 2 ADR ITEM: 5 F PACKINGGROUP: 2 DANGEROUSGOODS INLIMITED QUANTITIES: EEC TARIFF NO. 340399-10-0 16. REGULATORY INFORMATION LABEL FOR SUPPLY: CAUTIONFLAMMABLE Aquatic Toxicity: Toxic to marine organisms due to pH effects. Degradability: Surfacants greater than 80% primary biodegradability. Mobility: Data not yet available. Bioaccumulative Potential: Not known 13. DISPOSAL CONSIDERATIONS Refer to section 6. If local regulations permit run to waste, diluting greatly with running water. Rinse out empty packaging. Damage packaging to prevent reuse if via local waste disposal. 9804/8941 ISSUE 4, (REV.) SEPTEMBER 2001 There is no data on the product itself. The product should not be allowed to enter drains or water courses or be deposited where it can affect ground or surface waters. The Air Pollution Control requirements of regulations made under the Environmental Protection Act may apply to the use of this product. White spirit has a high potential to bio-accumulate, is practically non-toxic to aquatic organisms and has good bio- degradability. 14. DISPOSAL CONSIDERATIONS Waste Disposal: Do not allow into drains or water courses or dispose of where ground or surface waters may be affected. Wastes, including emptied containers, are controlled wastes and should be disposed of in accordance with regulations made under the Control of Pollution Act. 9804/9018 ISSUE 1, March 2001 Cured product is inert and not readily biodegradable. 9804/8962 ISSUE 3, NOVEMBER 1997 13. DISPOSAL CONSIDERATIONS Disposal of waste product and containers is subject to the Duty of Care* and conditions set by local authorities. Waste must only be transported and disposed of by authorised or registered contractors. *The duty of Care - A Code of Practice. Published by HMSO Dec. 1991 Relevant Legislation Ref.4 14. TRANSPORT INFORMATION The product is not classified hazardous for transport. 15. REGULATORY INFORMATION The product is not classified as hazardous according to the CHIP Regulations1. References to Legislation 1: Chemicals (Hazard Information and Packaging) Regulations 1993 (CHIP). 2: Control of Substances Hazardous to Health Regulations 1988 (COSHH). 3: Personal Protective Equipment at Work Regulations 1992. 4: The environmental Protection Act 1990. Mobility: The product is volatile/gaseous and will partition to the air phase. The product will dissolve rapidly in water. Hydrolysis will release a minor quantity of butyl alcohol which has a limited solubility. Persistence/Degradability: The product is expected to be readily biodegradable. BOD5 = 60% of ThOD (based on major component). Bio-accumulation: Product is not expected to bioaccumulate. Ecotoxicity: The product is expected to be non-hazardous to aquatic species. 13. DISPOSAL CONSIDERATIONS Product Disposal: Dispose of as Special Waste. Container Disposal: Empty containers may contain hazardous residues. Do not incinerate closed containers. 9804/8976 ISSUE 3, (REV.) NOVEMBER 1997 14. TRANSPORT INFORMATION - 13. DISPOSAL CONSIDERATIONS - 14. TRANSPORT INFORMATION - 15. REGULATORY INFORMATION - Potential Effect on Environment: Harmful to aquatic organisms. Not readily biodegradable. 13. DISPOSAL CONSIDERATIONS Waste Disposal Methods: Waste disposal should be in accordance with existing Community, National and and local regulations. Empty Container Warnings: Empty containers may contain product residue; follow SDS and label warnings even after they have been emptied. 9804/9004 ISSUE 2, (REV) SEPTEMBER 2002 There is no data available on the product itself. The product should not be allowed to enter drains or water courses or be deposited where it can affect ground or surface waters. The Air Pollution Control requirements of regulations made under the Environmental Protection Act may apply to the use of this product. Acetone has no bio-accumulation potential, it is not acutely toxic to aquatic organisms and has good biodegradability. Xylene is likely to bio-accumulate, but with short retention with the order of a week or less. It is likely to be moderately toxic to aquatic organisms and it will biodegrade although it will float on water and evaporate slowly. 13. DISPOSAL CONSIDERATIONS Do not allow into drains or water courses or dispose of where ground or surface waters may be affected. Wastes, including emptied containers, are controlled wastes and should be disposed of in accordance with regulations made under the Control of Pollution Act. Using the information provided in this data sheet, advice should be obtained from the Waste Regulations Authority whether the special waste regulations apply. 14. TRANSPORT INFORMATION CCCN: 3208 20 90 UN no.: 1950 IMDG: 2102 Class: 2 ICAO/IATA: 2.1 RID/ADR: 2,5’F 9804/8951 ISSUE 2 (REV.), APRIL 1997 15. REGULATORY INFORMATION Label for supply: EXTREMELY FLAMMABLE There is no data available on the product itself. The product should not be allowed to enter drains or water courses or be deposited where it can affect ground or surface waters. Xylene is likely to bio-accumulate, but with short retention with the order of a week or less. It is likely to be moderately toxic to aquatic organisms and it will biodegrade although it will float on water and evaporate slowly. Acetone has no bio-accumulation potential, it is not acutely toxic to aquatic organisms and has good biodegradability. 13. DISPOSAL CONSIDERATIONS Do not allow into drains or water courses or dispose of where ground or surface waters may be affected. Wastes, including emptied containers, are controlled wastes and should be disposed of in accordance with regulations made under the Control of Pollution Act. Using the information provided in this data sheet, advice should be obtained from the Waste Regulation Authority whether the special waste regulations apply. 14. TRANSPORT INFORMATION CCCN: 3208 20 90 UN no.: 1950 IMDG: 2102 Class: 2 ICAO/IATA: 2.1,6.1 RID/ADR: 2,5’TF 9804/8952 ISSUE 2 (REV.), APRIL 1997 15. REGULATORY INFORMATION Label for supply: EXTREMELY FLAMMABLE HARMFUL There is no data available on the product itself. The product should not be allowed to enter drains or water courses or be deposited where it can affect ground or surface waters. The Air Pollution Control requirements of regulations made under the Environmental Protection Act may apply to the use of this product. Acetone has no bio-accumulation potential, it is not acutely toxic to aquatic organisms and has good biodegradability. Xylene is likely to bio-accumulate, but with short retention with the order of a week or less. It is likely to be moderately toxic to aquatic organisms and it will biodegrade although it will float on water and evaporate slowly. 13. DISPOSAL CONSIDERATIONS Do not allow into drains or water courses or dispose of where ground or surface waters may be affected. Wastes, including emptied containers, are controlled wastes and should be disposed of in accordance with regulations made under the Control of Pollution Act. Using the information provided in this data sheet, advice should be obtained from the Waste Regulations Authority whether the special waste regulations apply. 14. TRANSPORT INFORMATION CCCN: 3208 20 90 UN no.: 1950 IMDG: 2102 Class: 2 ICAO/IATA: 2.1 RID/ADR: 2,5’F 9804/8953 ISSUE 2 (REV.), APRIL 1997 15. REGULATORY INFORMATION Label for supply: EXTREMELY FLAMMABLE There is no data available on the product itself. The product should not be allowed to enter drains or water courses or be deposited where it can affect ground or surface waters. The Air Pollution Control requirements of regulations made under the Environmental Protection Act may apply to the use of this product. Acetone has no bio-accumulation potential, it is not acutely toxic to aquatic organisms and has good biodegradability. Xylene is likely to bio-accumulate, but with short retention with the order of a week or less. It is likely to be moderately toxic to aquatic organisms and it will biodegrade although it will float on water and evaporate slowly. 13. DISPOSAL CONSIDERATIONS Do not allow into drains or water courses or dispose of where ground or surface waters may be affected. Wastes, including emptied containers, are controlled wastes and should be disposed of in accordance with regulations made under the Control of Pollution Act. Using the information provided in this data sheet, advice should be obtained from the Waste Regulation Authority whether the special waste regulations apply. 14. TRANSPORT INFORMATION CCCN: 3208 20 90 UN no.: 1950 IMDG: 2102 Class: 2 ICAO/IATA: 2.1 RID/ADR: 2,5’F 9804/8954 ISSUE 2 (REV.), APRIL 1997 15. REGULATORY INFORMATION Label for supply: EXTREMELY FLAMMABLE There is no data available on the product itself. The product should not be allowed to enter drains or water courses or be deposited where it can affect ground or surface waters. The Air Pollution Control requirements of regulations made under the Environmental Protection Act may apply to the use of this product. 9804/8978 ISSUE 2, (REV.) MARCH 1997 13. DISPOSAL CONSIDERATIONS Do not allow into drains or water courses or dispose of where ground or surface waters may be affected. Wastes, including emptied containers, are controlled wastes and should be disposed of in accordance with regulations made under the Control of Pollution and Environmental Protection Acts. 14. TRANSPORT INFORMATION Road/Rail SI Number: 1263 Packing Group: II Class: 3 15. REGULATORY INFORMATION The product is classified and labelled for supply in accordance with the Chemicals (Hazard Information & Packaging) Regulations as follows. There is no data available on the product itself. The product should not be allowed to enter drains or water courses or be deposited where it can affect ground or surface waters. The Air Pollution Control requirements of regulations made under the Environmental Protection Act may apply to the use of this product. 13. DISPOSAL CONSIDERATIONS Do not allow into drains or water courses or dispose of where ground or surface waters may be affected. Wastes, including emptied containers, are controlled wastes and should be disposed of in accordance with regulations made under the Control of Pollution and Environmental Protection Acts. 9804/8979 ISSUE 2, (REV.) MARCH 1997 14. TRANSPORT INFORMATION Road/Rail SI Number: 1263 Packing Group: III Class: 3 Designation: PAINT PRODUCT Sea Packing Grp.: < = 30lts III Packing Grp.: > 30lts III Class: 3 Marine Pollutant: No There is no data available on the product itself. The product should not be allowed to enter drains or water courses or be deposited where it can affect ground or surface waters. The Air Pollution Control requirements of regulations made under the Environmental Protection Act may apply to the use of this product. 13. DISPOSAL CONSIDERATIONS Do not allow into drains or water courses or dispose of where ground or surface waters may be affected. Wastes, including emptied containers, are controlled wastes and should be disposed of in accordance with regulations made under the Control of Pollution and Environmental Protection Acts. 9804/8980 ISSUE 2, (REV.) MARCH 1997 14. TRANSPORT INFORMATION Road/Rail SI Number: 1263 Packing Group: III Class: 3 Designation: PAINT PRODUCT Sea Packing Grp.: < = 30lts III Packing Grp.: > 30lts III Class: 3 Marine Pollutant: No There is no data available on the product itself. The product should not be allowed to enter drains or water courses or be deposited where it can affect ground or surface waters. The Air Pollution Control requirements of regulations made under the Environmental Protection Act may apply to the use of this product. 9804/8981 ISSUE 2, (REV.) MARCH 1997 13. DISPOSAL CONSIDERATIONS Do not allow into drains or water courses or dispose of where ground or surface waters may be affected. Wastes, including emptied containers, are controlled wastes and should be disposed of in accordance with regulations made under the Control of Pollution and Environmental Protection Acts. 14. TRANSPORT INFORMATION Road/Rail SI Number: 1263 Packing Group: III Class: 3.3 Designation: Flammable Liquid Sea Packing Grp.: < = 30lts III Packing Grp.: > 30lts III Class: 3.3 Marine Pollutant: No There is no data available on the product itself. The product should not be allowed to enter drains or water courses or be deposited where it can affect ground or surface waters. The Air Pollution Control requirements of regulations made under the Environmental Protection Act may apply to the use of this product. Acetone has no bio-accumulation potential, it is not acutely toxic to aquatic organisms and has good biodegradability. Xylene is likely to bio-accumulate, but with short retention with the order of a week or less. It is likely to be moderately toxic to aquatic organisms and it will biodegrade although it will float on water and evaporate slowly. 13. DISPOSAL CONSIDERATIONS Do not allow into drains or water courses or dispose of where ground or surface waters may be affected. Wastes, including emptied containers, are controlled wastes and should be disposed of in accordance with regulations made under the Control of Pollution Act. Using the information provided in this data sheet, advice should be obtained from the Waste Regulation Authority whether the special waste regulations apply. 14. TRANSPORT INFORMATION CCCN: 3208 20 90 UN no.: 1950 IMDG: 2102 Class: 2 ICAO/IATA: 2.1 RID/ADR: 2,5’F 9804/8955 ISSUE 2 (REV.), APRIL 1997 15. REGULATORY INFORMATION Label for supply: EXTREMELY FLAMMABLE There is no data available on the product itself. The product should not be allowed to enter drains or water courses or be deposited where it can affect ground or surface waters. The Air Pollution Control requirements of regulations made under the Environmental Protection Act may apply to the use of this product. * 13. DISPOSAL CONSIDERATIONS Do not allow to enter drains or water courses or dispose of where ground or surface waters may be affected. Wastes, including emptied containers, are controlled wastes and should be disposed of in accordance with regulations made under the Control of Pollution Act and the Environmental Protection Act. Cont..... 9804/8926 ISSUE 5 (REV.), MARCH 2002 There is no data available on this product. The Air Pollution Control requirements of Regulations made under the Environmental Protection Act may apply to the use of this product. See also Sections 5, 6 and 13. This product contains White Spirit which is classified as marine pollutant. 9804/8919 ISSUE 3 (REV.), APRIL 1997 13. DISPOSAL CONSIDERATIONS Do not allow into drains or water courses or dispose of where ground or surface waters may be affected. Wastes, including emptied containers, are controlled wastes and should be disposed of in accordance with Regulations made under the Control of Pollution and the Environmental Protection Acts. Using the information provided in this safety data sheet, advice should be obtained from the local Waste Disposal Authority as to whether the Special Waste regulations apply. 14. TRANSPORT INFORMATION Transport Details Class : 3 Proper Shipping Name : Paint Sub Hazard : None There is no data available on this product. The Air Pollution Control requirements of Regulations made under the Environmental Protection Act may apply to the use of this product. See also Sections 5, 6 and 13. This product contains White Spirit which is classified as marine pollutant. 9804/8918 ISSUE 4 (REV.), NOVEMBER 1997 13. DISPOSAL CONSIDERATIONS Do not allow into drains or water courses or dispose of where ground or surface waters may be affected. Wastes, including emptied containers, are controlled wastes and should be disposed of in accordance with Regulations made under the Control of Pollution and the Environmental Protection Acts. Using the information provided in this safety data sheet, advice should be obtained from the local Waste Disposal Authority as to whether the Special Waste regulations apply. 14. TRANSPORT INFORMATION Transport Details Class : 3 Proper Shipping Name : Paint Sub Hazard : None There is no data available on this product. The Air Pollution Control requirements of Regulations made under the Environmental Protection Act may apply to the use of this product. See also Sections 5, 6 and 13. This product contains White Spirit which is classified as marine pollutant. 9804/8917 ISSUE 4 (REV.), NOVEMBER 1997 13. DISPOSAL CONSIDERATIONS Do not allow into drains or water courses or dispose of where ground or surface waters may be affected. Wastes, including emptied containers, are controlled wastes and should be disposed of in accordance with Regulations made under the Control of Pollution and the Environmental Protection Acts. Using the information provided in this safety data sheet, advice should be obtained from the local Waste Disposal Authority as to whether the Special Waste regulations apply. 14. TRANSPORT INFORMATION Transport Details Class : 3 Proper Shipping Name : Paint Sub Hazard : None There is no data available on the product itself. The product should not be allowed to enter drains or water courses or be deposited where it can affect ground or surface waters. The Air Pollution Control requirements of regulations made under the Environmental Protection Act may apply to the use of this product. 9804/8958 ISSUE 3 (REV.), FEB 2002 There is no data available on the product itself. The Air Pollution Control requirements of Regulations made under the Environmental Protection Act may apply to the use of this product. See also Sections 5, 6 and 13. This product contains White Spirit which is classified as marine pollutant. 13. DISPOSAL CONSIDERATIONS Do not allow into drains or water courses or dispose of where ground or surface waters may be affected. Wastes, including emptied containers, are controlled wastes and should be disposed of in accordance with Regulations made under the Control of Pollution and the Environmental Protection Acts. 14. TRANSPORT INFORMATION Transport Details Class : 3 Proper Shipping Name : Paint Sub Hazard : None There is no data available on the product itself. The product should not be allowed to enter drains or water courses or be deposited where it can affect ground or surface waters. The Air Pollution Control requirements of regulations made under the Environmental Protection Act may apply to the use of this product. 13. DISPOSAL CONSIDERATIONS Do not allow into drains or water courses or dispose of where ground or surface waters may be affected. Wastes, including emptied containers, are controlled wastes and should be disposed of in accordance with regulations made under the Control of Pollution Act and the Environmental Protection Act. Using information provided in this data sheet, advice should be obtained from the Waste Regulation Authority whether the special waste regulations apply. 14. TRANSPORT INFORMATION Transport within the user’s premises Always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of accident or spillage. Transport Details Class : 3 Proper Shipping Name : Paint Sub Hazard : - There is no data available on the product itself. The product should not be allowed to enter drains or water courses or be deposited where it can affect ground or surface waters. The Air Pollution Control requirements of regulations made under the Environmental Protection Act may apply to the use of this product. 13. DISPOSAL CONSIDERATIONS Do not allow into drains or water courses or dispose of where ground or surface waters may be affected. Wastes, including emptied containers, are controlled wastes and should be disposed of in accordance with regulations made under the Control of Pollution Act and the Environmental Protection Act. Using information provided in this data sheet, should be obtained from the Waste Regulation Authority whether the special waste regulations apply. 14. TRANSPORT INFORMATION Transport within the user’s premises Always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of accident or spillage. Transport Details Class : 3 Proper Shipping Name : Paint Sub Hazard : - There is no data available on the product itself. The product should not be allowed to enter drains or water courses or be deposited where it can affect ground or surface waters. The Air Pollution Control requirements of regulations made under the Environmental Protection Act may apply to the use of this product. 13. DISPOSAL CONSIDERATIONS Do not allow into drains or water courses or dispose of where ground or surface waters may be affected. Wastes, including emptied containers, are controlled wastes and should be disposed of in accordance with regulations made under the Control of Pollution Act and the Environmental Protection Act. Using information provided in this data sheet, advice should be obtained from the Waste Regulation Authority whether the special waste regulations apply. 14. TRANSPORT INFORMATION Transport within the user’s premises Always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of accident or spillage. Transport Details Class : 3 Proper Shipping Name : Paint Sub Hazard : - There is no data available on the product itself. The product should not be allowed to enter drains or water courses or be deposited where it can affect ground or surface waters. The Air Pollution Control requirements of regulations made under the Environmental Protection Act may apply to the use of this product. 13. DISPOSAL CONSIDERATIONS Do not allow to enter drains or water courses or dispose of where ground or surface waters may be affected. Wastes, including emptied containers, are controlled wastes and should be disposed of in accordance with regulations made under the Control of Pollution Act and the Environmental Protection Act. Using information provided in this data sheet, advice should be obtained from the relevant environment agency whether the special waste regulations apply. 14. TRANSPORT INFORMATION Transport within the user’s premises Always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of accident or spillage. There is no data available on the product itself. The product should not be allowed to enter drains or water courses or be deposited where it can affect ground or surface waters. The Air Pollution Control requirements of regulations made under the Environmental Protection Act may apply to the use of this product. 9804/8923 ISSUE 5 (REV.), JUNE 2002 There is no data available on the product itself. The product should not be allowed to enter drains or water courses or be deposited where it can affect ground or surface waters. The Air Pollution Control requirements of regulations made under the Environmental Protection Act may apply to the use of this product. 13. DISPOSAL CONSIDERATIONS Do not allow into drains or water courses or dispose of where ground or surface waters may be affected. Wastes, including emptied containers, are controlled wastes and should be disposed of in accordance with regulations made under the Control of Pollution Act and the Environmental Protection Act. Using information provided in this data sheet, advice should be obtained from the Waste Regulation Authority whether the special waste regulations apply. 14. TRANSPORT INFORMATION Transport within the user’s premises Always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of accident or spillage. Transport Details Class : 3 Proper Shipping Name : Paint Sub Hazard : - There is no data available on the product itself. The product should not be allowed to enter drains or water courses or be deposited where it can affect ground or surface waters. The Air Pollution Control requirements of regulations made under the Environmental Protection Act may apply to the use of this product. 13. DISPOSAL CONSIDERATIONS Do not allow into drains or water courses or dispose of where ground or surface waters may be affected. Wastes, including emptied containers, are controlled wastes and should be disposed of in accordance with regulations made under the Control of Pollution Act and the Environmental Protection Act. Using information provided in this data sheet, advice should be obtained from the Waste Regulation Authority whether the special waste regulations apply. 14. TRANSPORT INFORMATION Transport within the user’s premises Always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of accident or spillage. Transport Details Class : 3 Proper Shipping Name : Paint Sub Hazard : - There is no data available on the product itself. The Air Pollution Control requirements of Regulations made under the Environmental Protection Act may apply to the use of this product. 13. DISPOSAL CONSIDERATIONS Do not allow into drains or water courses or dispose of where ground or surface waters may be affected. Wastes, including emptied containers, are controlled wastes and should be disposed of in accordance with Regulations made under the Control of Pollution and the Environmental Protection Acts. 14. TRANSPORT INFORMATION Trade Designation Paint Product Packing Group III U.N. Number : UN 1263 Class Number (RID/ADR) : 3 I.M.C.O. Code 3.3 Flash Point : Above 32°C Hazardous Property Flammable Liquid with Heavy Flammable Vapour Subsidiary Risk : None 15. REGULATORY INFORMATION This product is classified and labelled for supplying in accordance with the Chemicals (Hazard Information and Packaging) Regulations as follows:- R10 Flammable R20/21 Harmful by inhalation and in contact with skin. Xn Harmful. S23 Do not breathe vapour or spray. S38 In case of insufficient ventilation, wear suitable respiratory equipment. cont’d 9804/8929 ISSUE 4 (REV.), JUNE 2002 There is no data available on the product itself. The product should not be allowed to enter drains or water courses or be deposited where it can affect ground or surface waters. The Air Pollution Control requirements of regulations made under the Environmental Protection Act may apply to the use of this product. 9804/8964 ISSUE 3 (REV.), JUNE 2002 There is no data available on the product itself. The product should not be allowed to enter drains or water courses or be deposited where it can affect ground or surface waters. The Air Pollution Control requirements of regulations made under the Environmental Protection Act may apply to the use of this product. 13. DISPOSAL CONSIDERATIONS Do not allow into drains or water courses or dispose of where ground or surface waters may be affected. Wastes, including emptied containers, are controlled wastes and should be disposed of in accordance with regulations made under the Control of Pollution Act and the Environmental Protection Act. Using information provided in this data sheet, advice should be obtained from the Environmental Agency whether the special waste regulations apply. 14. TRANSPORT INFORMATION Transport within the user’s premises Always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of accident or spillage. Base: Transport Details Class : 3 Proper Shipping Name : Paint Sub Hazard : - There is no data available on the product itself. The product should not be allowed to enter drains or water courses or be deposited where it can affect ground or surface waters. The Air Pollution Control requirements of regulations made under the Environmental Protection Act may apply to the use of this product. 13. DISPOSAL CONSIDERATIONS Do not allow into drains or water courses or dispose of where ground or surface waters may be affected. Wastes, including emptied containers, are controlled wastes and should be disposed of in accordance with regulations made under the Control of Pollution Act and the Environmental Protection Act. Using information provided in this data sheet, advice should be obtained from the Waste Regulation Authority whether the special waste regulations apply. 14. TRANSPORT INFORMATION Transport within the user’s premises Always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of accident or spillage. Base: Transport Details Class : 3 Proper Shipping Name : Paint Sub Hazard : - Potential Effect on Environment: Unknown 13. DISPOSAL CONSIDERATIONS Waste Disposal Methods: Waste disposal should be in accordance with existing Community, National and and local regulations. Empty Container Warnings: Empty containers may contain product residue; follow SDS and label warnings even after they have been emptied. 9804/8997 ISSUE 2, (REV) SEPTEMBER 2002 Mobility: Because of its high viscosity, low water solubility and low degree of toxicity, this material should not present any environmental problems. Ecotoxicity: The product is expected to be non-hazardous to aquatic species. 13. DISPOSAL CONSIDERATIONS Product Disposal: If possible allow the product to cure naturally in open air. When cured the product may be landfilled. Disposal of bulk quantities and/or containers should be made through an authorised waste contractor. 14. TRANSPORT INFORMATION Mobility: Because of its high viscosity, low water solubility and low degree of toxicity, this material should not present any environmental problems. Ecotoxicity: The product is expected to be non-hazardous to aquatic species. 13. DISPOSAL CONSIDERATIONS Product Disposal: If possible allow the product to cure naturally in open air. When cured the product may be landfilled. Disposal of bulk quantities and/or containers should be made through an authorised waste contractor. 14. TRANSPORT INFORMATION Does not contain substances listed on the Montreal protocol. Potential Effect on Environment: Unknown Mobility: Unknown Persistence and Degradability: Unknown Potential to Bioaccumulate: Unknown Ecotoxicity: Unknown Aquatic Toxicity: None established 13. DISPOSAL CONSIDERATIONS Waste Disposal Methods: Waste disposal should be in accordance with existing Community, National and and local regulations. Empty Container Warnings: Empty containers may contain product residue; follow SDS and label warnings even after they have been emptied. 14. TRANSPORT INFORMATION (See also section 9) ADR/RID: Not applicable CEFIC Tremcard Number: Not applicable Hazchem Code: Not applicable Kemmler Code: Not applicable IMDG Classification: Not applicable Potential Effect on Environment: Unknown Mobility: Unknown Persistence and Degradability: Unknown Potential to Bioaccumulate: Unknown Ecotoxicity: Unknown Aquatic Toxicity: None established 13. DISPOSAL CONSIDERATIONS Waste Disposal Methods: Waste disposal should be in accordance with existing Community, National and and local regulations. Empty Container Warnings: Empty containers may contain product residue; follow SDS and label warnings even after they have been emptied. 14. TRANSPORT INFORMATION (See also section 9) ADR/RID: Not applicable CEFIC Tremcard Number: Not applicable Hazchem Code: Not applicable Kemmler Code: Not applicable IMDG Classification: Not applicable Potential Effect on Environment: Unknown Mobility: Unknown Persistence and Degradability: Unknown Potential to Bioaccumulate: Unknown Ecotoxicity: Unknown Aquatic Toxicity: None established 13. DISPOSAL CONSIDERATIONS Waste Disposal Methods: Waste disposal should be in accordance with existing Community, National and and local regulations. Empty Container Warnings: Empty containers may contain product residue; follow SDS and label warnings even after they have been emptied. 14. TRANSPORT INFORMATION (See also section 9) ADR/RID: Not applicable CEFIC Tremcard Number: Not applicable Hazchem Code: Not applicable Kemmler Code: Not applicable IMDG Classification: Not applicable Potential Effect on Environment: Unknown Mobility: Unknown Persistence and Degradability: Unknown Potential to Bioaccumulate: Unknown Ecotoxicity: Unknown Aquatic Toxicity: None established 13. DISPOSAL CONSIDERATIONS Waste Disposal Methods: Waste disposal should be in accordance with existing Community, National and and local regulations. Empty Container Warnings: Empty containers may contain product residue; follow SDS and label warnings even after they have been emptied. 14. TRANSPORT INFORMATION (See also section 9) ADR/RID: Not applicable CEFIC Tremcard Number: Not applicable Hazchem Code: Not applicable Kemmler Code: Not applicable IMDG Classification: Not applicable Potential Effect on Environment: Unknown 13. DISPOSAL CONSIDERATIONS Waste Disposal Methods: Waste disposal should be in accordance with existing Community, National and and local regulations. Empty Container Warnings: Empty containers may contain product residue; follow SDS and label warnings even after they have been emptied. 9804/9002 ISSUE 2, (REV) SEPTEMBER 2002 Potential Effect on Environment: Low order of risk Mobility: Unknown Persistence and Degradability: Unknown Potential to Bioaccumulate: Unknown Ecotoxicity: Unknown Aquatic Toxicity: None established 13. DISPOSAL CONSIDERATIONS Waste Disposal Methods: Waste disposal should be in accordance with existing Community, National and and local regulations. Empty Container Warnings: Empty containers may contain product residue; follow SDS and label warnings even after they have been emptied. 14. TRANSPORT INFORMATION (See also section 9) ADR/RID: Not applicable CEFIC Tremcard Number: Not applicable Hazchem Code: Not applicable Kemmler Code: Not applicable IMDG Classification: Not applicable Does not contain substances listed on the Montreal protocol. Aerosol contains hydrocarbon propellant. No information available. 13. DISPOSAL CONSIDERATIONS Dispose of in accordance with local and national regulations. 14. TRANSPORT INFORMATION UN No.: None Air (IATA): Not classified Sea (IMO): Not classified RoadiRail (ADR/RID): Not classified 9804/8934* ISSUE 4, (REV.) MAY 1997 15. REGULATORY INFORMATION Hazard Label: None Potential Effect on Environment: Unknown Mobility: Unknown Persistence and Degradability: Unknown Potential to Bioaccumulate: Unknown Ecotoxicity: Unknown Aquatic Toxicity: None established 9804/9006 ISSUE 1, FEBRUARY 1997 13. DISPOSAL CONSIDERATIONS Waste Disposal Methods: Waste disposal should be in accordance with existing Community, National and and local regulations. Empty Container Warnings: Empty containers may contain product residue; follow instructions in this docu- ment and label warnings even after they have been emptied. 14. TRANSPORT INFORMATION (See also section 9) ADR/RID: 3, 3b CEFIC Tremcard Number: - Hazchem Code: - Kemmler Code: - IMDG Classification: 3.1 Potential Effect on Environment: Unknown 13. DISPOSAL CONSIDERATIONS Waste Disposal Methods: Waste disposal should be in accordance with existing Community, National and and local regulations. Empty Container Warnings: Empty containers may contain product residue; follow SDS and label warnings even after they have been emptied. 9804/9005 ISSUE 2, (REV) SEPTEMBER 2002 Mobility: The product is volatile/gaseous and will partition to the air phase. The product is sparingly soluble in water. Persistence/Degradability: The product is partially or slowly biodegradable. BOD5 = 16% of ThOD. (based on major component) Bio-accumulation: Product is not expected to bioaccumulate. Ecotoxicity: Product is expected to be non-hazardous to aquatic species. Mobility Spillages may penetrate the soil causing ground water contamination. Persistence and Degradability According to EC criteria: Expected to be readily biodegradable. Potential to Bioaccumulate Considered unlikely to bioaccumulate. Aquatic Toxicity Not classified as toxic. Environmental Fate and Effects: Not established. 13. DISPOSAL CONSIDERATIONS Waste Disposal: Product is suitable for burning in an enclosed, controlled burner for fuel value or disposal by supervised incineration. Such burning may be limited by the controlling authority. In addition, the product is suitable for processing by an approved recycling facility or can be disposed of at any licensed waste disposal site. Use of these methods is subject to user compliance with applicable laws and regulations and consideration of product characteristics at time of disposal. 14. TRANSPORT INFORMATION USA DOT: Not regulated by USA DOT. RID/ADR: Not regulated by RID/ADR. IMO: Not regulated by IMO. IATA: Not regulated by IATA. 15. REGULATORY INFORMATION EC Classification and Labelling: EC labelling not required. The following product ingredients are cited on the lists below: Chemical Name CAS Number List Citations No reportable ingredients Regulatory Lists Searched 1 = IARC 1 6 = NO ALLERGI 11 = DE TERAT B 16 = DE CARC B 21 = CH CARC 2 = IARC 2A 7 = SE ALLERGY 12 = DE TERAT C 17 = AT TERAT A 3 = IARC 2B 8 = SE CARC 13 = DE TERAT D 18 = AT TERAT B 4 = NTP CARC 9 = DK CARC 14 = DE CARC A1 19 = AT TERAT C 5 = NTP SUS 10 = DE TERAT A 15 = DE CARC A2 20 = AT TERAT D CARC = CARCINOGEN; SUS = SUSPECTED CARCINOGEN; TERAT = TERATOGENIC AT = Austria DE = Germany NO = Norway CH = Switzerland DK = Denmark SE = Sweden 9804/8868 ISSUE 2 (REV.), MARCH 1997 Environmental Fate and Effects: Not established. 13. DISPOSAL CONSIDERATIONS Waste Disposal: Product is suitable for burning in an enclosed, controlled burner for fuel value or disposal by supervised incineration. Such burning may be limited by the controlling authority. In addition, the product is suitable for processing by an approved recycling facility or can be disposed of at any licensed waste disposal site. Use of these methods is subject to user compliance with applicable laws and regulations and consideration of product characteristics at time of disposal. 14. TRANSPORT INFORMATION USA DOT: Not regulated by USA DOT. RID/ADR: Not regulated by RID/ADR. IMO: Not regulated by IMO. IATA: Not regulated by IATA. 15. REGULATORY INFORMATION EC Classification and Labelling: EC labelling not required. cont’d 9804/8961 ISSUE 2 (REV.), MARCH 1997 The following product ingredients are cited on the lists below: Chemical Name CAS Number List Citations No reportable ingredients Regulatory Lists Searched 1 = IARC 1 6 = NO ALLERGI 11 = DE TERAT B 16 = DE CARC B 21 = CH CARC 2 = IARC 2A 7 = SE ALLERGY 12 = DE TERAT C 17 = AT TERAT A 3 = IARC 2B 8 = SE CARC 13 = DE TERAT D 18 = AT TERAT B 4 = NTP CARC 9 = DK CARC 14 = DE CARC A1 19 = AT TERAT C 5 = NTP SUS 10 = DE TERAT A 15 = DE CARC A2 20 = AT TERAT D CARC = CARCINOGEN; SUS = SUSPECTED CARCINOGEN; TERAT = TERATOGENIC AT = Austria DE = Germany NO = Norway CH = Switzerland DK = Denmark SE = Sweden There is no data available on the product itself. The product should not be allowed to enter drains or water courses or be deposited where it can affect ground or surface waters. The Air Pollution Control requirements of regulations made under the Environmental Protection Act may apply to the use of this product. 13. DISPOSAL CONSIDERATIONS Do not allow into drains or water courses or dispose of where ground or surface waters may be affected. Wastes, including emptied containers, are controlled wastes and should be disposed of in accordance with regulations made under the Control of Pollution Act and the Environmental Protection Act. Using information provided in this data sheet, advice should be obtained from the Waste Regulation Authority whether the special waste regulations apply. 14. TRANSPORT INFORMATION Transport within the user’s premises Always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of accident or spillage. Transport Details Class : 2 Proper Shipping Name : Flammable gas Sub Hazard : - There is no data available on the product itself. The product should not be allowed to enter drains or water courses or be deposited where it can affect ground or surface waters. The Air Pollution Control requirements of regulations made under the Environmental Protection Act may apply to the use of this product. 13. DISPOSAL CONSIDERATIONS Do not allow into drains or water courses or dispose of where ground or surface waters may be affected. Wastes, including emptied containers, are controlled wastes and should be disposed of in accordance with regulations made under the Control of Pollution Act and the Environmental Protection Act. Using information provided in this data sheet, advice should be obtained from the Waste Regulation Authority whether the special waste regulations apply. 14. TRANSPORT INFORMATION Transport within the user’s premises Always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of accident or spillage. Transport Details Class : 2 Proper Shipping Name : Flammable gas Sub Hazard : - There is no data available on the product itself. The product should not be allowed to enter drains or water courses or be deposited where it can affect ground or surface waters. The Air Pollution Control requirements of regulations made under the Environmental Protection Act may apply to the use of this product. 9804/9012 ISSUE 2, NOVEMBER 1997 13. DISPOSAL CONSIDERATIONS Do not allow into drains or water courses or dispose of where ground or surface waters may be affected. Wastes, including emptied containers, are controlled wastes and should be disposed of in accordance with regulations made under the Control of Pollution Act and the Environmental Protection Act. Using information provided in this data sheet, advice should be obtained from the Environmental Agency whether the special waste regulations apply. 14. TRANSPORT INFORMATION Transport within the user’s premises Always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of accident or spillage. Base: Transport Details Class : 3 Proper Shipping Name : Paint Sub Hazard : - Lead compounds and sulphuric acid will cause “harm” as defined in S29(5) of the Environmental Protection Act 1990. *13. DISPOSAL CONSIDERATIONS Damaged or spent batteries or residue from fires and spillages should be contained in closed acid proof receptacles, to prevent escape to the environment and disposed of as Special Waste. See REGULATORY INFORMATION. *14. TRANSPORT INFORMATION Road: Substance Identification Number 2794 ADR labelling CORROSIVE SUBSTANCE UK labelling for conveyance CORROSIVE SUBSTANCE Sea: Environmental Fate and Effects: Not established, but can be expected to biodegrade slowly. 13. DISPOSAL CONSIDERATIONS Waste Disposal: Product is suitable for burning in an enclosed, controlled burner for fuel value or disposal by supervised incineration. Such burning may be limited by the controlling authority. In addition, the product is suitable for processing by an approved recycling facility or can be disposed of at any licensed waste disposal site. Use of these methods is subject to user compliance with applicable laws and regulations and consideration of product characteristics at time of disposal. 14. TRANSPORT INFORMATION USA DOT: Not regulated by USA DOT. RID/ADR: Not regulated by RID/ADR. IMO: Not regulated by IMO. IATA: Not regulated by IATA. 9804/9014 ISSUE 1, AUGUST 1999 15. REGULATORY INFORMATION EU Labelling: EC Labelling not required The following product ingredients are cited on the lists below: Chemical Name CAS Number List Citations No reportable ingredients Regulatory Lists Searched 1=IARC 1 6=NO ALLERGI 11=DE TERAT B 16=DE CARC B 21=CH CARC 2=IARC 2A 7=SE ALLERGY 12=DE TERAT C 17=AT TERAT A 3=IARC 2B 8=SE CARC 13=DE TERAT D 18=AT TERAT B 4=NTP CARC 9=DK CARC 14=DE CARC A1 19=AT TERAT C 5=NTP SUS 10=DE TERAT A 15=DE CARC A2 20=AT TERAT D CARC=CARCINOGEN; SUS=SUSPECTED CARCINOGEN; TERAT=TERATOGENIC AT=Austria DE=Germany NO=Norway CH=Switzerland DK=Denmark SE=Sweden IK@'37A@';5<'6;>J;9@98A'74@'9;8'@\J@68@S'8;'3@'S79 @4;2A'8;'8K@'7d27856'@9?54;9>@98M'L;8'4@7S5<H'35;S@ 47S73<@M' ' • 13. DISPOSAL CONSIDERATIONS I479AJ;48'8;'728K;45A@S']7A8@'<;6785;9&';4'59659@4785;9'29S@4'6;984;<<@S'6;9S585;9AM' ' • 14. TRANSPORT INFORMATION UN-No L;8'6<7AA5=5@S'IATA/ICAO L;8'6<7AA5=5@S' RID/ADR: L;8'6<7AA5=5@S'Other: IMO: L;8'6<7AA5=5@S' ' • 15. REGULATORY INFORMATION L;'.C'@\J;A24@'<5>58'@A873<5AK@SM' EC Labelling/Classification: Potential Effect on Environment: Unknown Mobility: Unknown Persistence and Degradability: Unknown Potential to Bioaccumulate: Unknown Ecotoxicity: Very toxic to fish Aquatic Toxicity: None established 13. DISPOSAL CONSIDERATIONS Waste Disposal Methods: Waste disposal should be in accordance with existing Community, National and and local regulations. Empty Container Warnings: Empty containers may contain product residue; follow instructions in this docu- ment and label warnings even after they have been emptied. *14. TRANSPORT INFORMATION (See also section 9) IATA Classification proper shipping name: Aerosols, Flammable. There is no data available on the product itself. The product should not be allowed to enter drains or water courses or be deposited where it can affect ground or surface waters. The Air Pollution Control requirements of regulations made under the Environmental Protection Act may apply to the use of this product. 13. DISPOSAL CONSIDERATIONS Do not allow to enter drains or water courses, or dispose of where ground or surface waters may be affected. Wastes, including emptied containers, are controlled wastes and should be disposed of in accordance with regulations made under the Control of Pollution Act and the Environmental Protection Act. Using information provided in this data sheet, advice should be obtained from the relevant environment agency whether the special waste regulations apply. 14. TRANSPORT INFORMATION Transport within the user's premises Always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. Aquatic toxicity: Not known. Degradability: Not known. Mobility: Not expected to be persistent in the environment. Bioaccumulative Potential: No data available. 13. DISPOSAL CONSIDERATIONS Refer to section 6. Rinse out empty packaging. Damage packaging to prevent re-use if disposed of via local waste. Observe all local and national waste disposal regulations. 14. TRANSPORT INFORMATION JCB PDI Enhancer: This preparation is not classified as hazardous for transportation. UN No. UN Description Transport Class No. Transport Category N/A Not applicable 15. REGULATORY INFORMATION JCB PDI Enhancer: Preparation is classified for supply by CHIP regulations as Harmful. (Aspiration Risk if swallowed). Harmful: May cause lung damage if swallowed. Avoid eye contact and minimise skin contact. Wear suitable gloves. In case of fire, use sand, earth, foam or water fog. Use only in well ventilated areas. If swallowed, do not induce vomiting, seek medical advice immediately and show this container or label. Note: The information contained in this product safety datasheet and/or product label and/or other user information does not constitute an assessment of workplace risks as required by other Health and Safety Regulations. (e.g. Control of Substances Hazardous to Health Regulations (COSHH). Individual countries may have other appropriate legislation for assessing risk and establishing safe working practices. There is no data available on the product itself. The product should not be allowed to enter drains or water courses or be deposited where it can affect ground or surface waters. 9804/9022 ISSUE 1, JANUARY 2002 Acute toxicity: Isopropanol 9640 mg/l pimephales promelas Ethanol 13000 mg/l salmo gairdneri/oncorh.mykiss Glycol 40761 mg/l salmo gairdneri/oncorh.mykiss 13. DISPOSAL CONSIDERATIONS Environmental Fate and Effects: Acute LC/EC50 Fish Juvenile Rainbow Trout practically non-toxic. Based on testing of similar products Environmental precautions: Prevent spills from entering storm sewers or drains and contact with soil. 13. DISPOSAL CONSIDERATIONS Waste Disposal Product is suitable for burning in an enclosed, controlled burner for fuel value or disposal by supervised incineration. Such burning may be limited by the controlling authority. In addition, the product is suitable for processing by an approved recycling facility or can be disposed of at any licensed waste disposal site. Use of these methods is subject to user compliance with applicable laws and regulations and consideration of product characteristics at time of disposal. 14. TRANSPORT INFORMATION USA DOT: Not regulated by USA DOT RID/ADR: Not regulated by RID/ADR IMO: Not regulated by IMO IATA: Not regulated by IATA 15. REGULATORY INFORMATION EC Classification and Labelling: EC labelling not required. The following product ingredients are cited on the lists below: Chemical Name: CAS Number: List Citations: No reportable ingredients Regulatory Lists Searched: 1 = IARC 1 6 = NO ALLERGI 11 = DE TERAT B 16 = DE CARC B 21 = CH CARC 2 = IARC 2A 7 = SE ALLERGY 12 = DE TERAT C 17 = AT TERAT A 3 = IARC 2B 8 = SE CARC 13 = DE TERAT D 18 = AT TERAT B 4 = NTP CARC 9 = DK CARC 14 = DE CARC A1 19 = AT TERAT C 5 = NTP SUS 10 = DE TERAT A 15 = DE CARC A2 20 = AT TERAT D cont’d 9804/9032 ISSUE1, JANUARY 2002 CARC = Carcinogen SUS = Suspected Carcinogen TERAT = Teratogenic AT = Austria DE = Germany NO = Norway CH = Switzerland DK = Denmark SE = Sweden There is no data available on the product itself. The product should not be allowed to enter drains or water courses or be deposited where it can affect ground or surface waters. The Air Pollution Control requirements of regulations made under the Environmental Protection Act may apply to the use of this product. 13. DISPOSAL CONSIDERATIONS Do not allow into drains or water courses or dispose of where ground or surface waters may be affected. Wastes, including emptied containers, are controlled wastes and should be disposed of in accordance with regulations made under the Control of Pollution Act and the Environmental Protection Acts. 14. TRANSPORT INFORMATION Road/Rail SI Number.....1263 Packing Group.....III Class.....3 Designation.....PAINT PRODUCT Sea Packing Grp. <=30lts...III Packing Grp.>30lts.....III Class.....3 Marine Pollutant.....No UN Number.....1263 Main Risk.....FLAMMABILITY Sub Risk.....NARCOSIS Shipping Name.....PAINT PRODUCT Air Packing Grp.<=30lts.....III Packing Grp.>30lts.....III Un Number.....1263 Main Risk.....FLAMMABILITY Sub Risk.....NARCOSIS Shipping Name.....PAINT PRODUCT International Packing Group.....III Class.....3 Road/Rail Item Number.....31C UN Number.....1263 Main Risk.....FLAMMABILITY Sub Risk.....NARCOSIS Shipping Name.....PAINT PRODUCT 15. REGULATORY INFORMATION The product is classified and labelled for supply in accordance with the Chemicals (Hazard Information & Packaging) Regulations as follows: There is no data available on the product itself. The product should not be allowed to enter drains or water courses or be deposited where it can affect ground or surface waters. The Air Pollution Control requirements of regulations made under the Environmental Protection Act may apply to the use of this product. 13. DISPOSAL CONSIDERATIONS Do not allow into drains or water courses or dispose of where ground or surface waters may be affected. Wastes, including emptied containers, are controlled wastes and should be disposed of in accordance with regulations made under the Control of Pollution and Environmental Protection Acts. 14. TRANSPORT INFORMATION Road/Rail SI Number.....1263 Packing Group.....III Class.....3 15. REGULATORY INFORMATION The product is classified and labelled for supply in accordance with the Chemicals (Hazard Information & Packaging) Regulations as follows: There is no data available on the product itself. The product should not be allowed to enter drains or water courses or be deposited where it can affect ground or surface waters. The Air Pollution Control requirements of regulations made under the Environmental Protection Act may apply to the use of this product. 13. DISPOSAL CONSIDERATIONS Do not allow to enter drains or water courses, or dispose of where ground or surface waters may be affected. Wastes, including emptied containers, are controlled wastes and should be disposed of in accordance with regulations made under the Control of Pollution Act and the Environmental Protection Act. Using information provided in this data sheet, advice should be obtained from the relevant environment agency whether the special waste regulations apply. 14. TRANSPORT INFORMATION Transport within the user's premises Always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. There is no data available on the product itself. The product should not be allowed to enter drains or water courses or be deposited where it can affect ground or surface waters. The Air Pollution Control requirements of regulations made under the Environment Protection Act may apply to the use of this product. 13. DISPOSAL CONSIDERATIONS Do not allow into drains or water courses or dispose of where ground or surface waters may be affected. Wastes, including emptied containers, are controlled wastes and should be disposed of in accordance with regulations made under the Control of Pollution & Environmental Protection Acts. 14. TRANSPORT INFORMATION Road/Rail SI Number.....1263 Packing Group.....III Class.....3.3 Designation.....PAINT Sea Packing Grp. <=30lts....III Packing Grp.>30lts.....III Class.....3.3 Marine Pollutant.....No UN Number.....1263 Main Risk.....Flammability Sub Risk.....Narcosis Shipping Name.....PAINT Air Packing Grp.<=30lts.....III Packing Grp.>30lts.....III Class.....3.3 Un Number.....1263 Main Risk.....Flammability Sub Risk.....Narcosis Shipping Name.....PAINT International Packing Group.....III Class.....3 Road/Rail Item Number.....31C UN Number.....1263 Main Risk.....Flammability Sub Risk.....Narcosis Shipping Name.....PAINT 9804/9030 ISSUE1, JANUARY 2002 15. REGULATORY INFORMATION This product is classified and labelled for supply in accordance with the Chemicals (Hazard Information & Packaging) Regulations as follows: There is no data available on the product itself. The product should not be allowed to enter drains or water courses or be deposited where it can affect ground or surface waters. The Air Pollution Control requirements of regulations made under the Environment Protection Act may apply to the use of this product. 9804/9031 ISSUE1, JANUARY 2002 13. DISPOSAL CONSIDERATIONS Do not allow into drains or water courses or dispose of where ground or surface waters may be affected. Wastes, including emptied containers, are controlled wastes and should be disposed of in accordance with regulations made under the Control of Pollution & Environmental Protection Acts. 14. TRANSPORT INFORMATION Road/Rail SI Number.....1263 Packing Group.....III Class.....3 Designation.....PAINT PRODUCT Sea Packing Grp. <=30lts...III Packing Grp.>30lts.....III Class.....3 Marine Pollutant.....No UN Number.....1263 Main Risk.....FLAMMABILITY Sub Risk.....NARCOSIS Shipping Name.....PAINT PRODUCT Air Packing Grp.<=30lts.....III Packing Grp.>30lts.....III Un Number.....1263 Main Risk.....FLAMMABILITY Sub Risk.....NARCOSIS Shipping Name.....PAINT PRODUCT International Packing Group.....III Class.....3 Road/Rail Item Number.....31C UN Number.....1263 Main Risk.....FLAMMABILITY Sub Risk.....NARCOSIS Shipping Name.....PAINT PRODUCT 15. REGULATORY INFORMATION This product is classified and labelled for supply in accordance with the Chemicals (Hazard Information & Packaging) Regulations as follows: There is no data available on the product itself. The product should not be allowed to enter drains or water courses or be deposited where it can affect ground or surface waters. The Air Pollution Control requirements of regulations made under the Environmental Protection Act may apply to the use of this product. 13. DISPOSAL CONSIDERATIONS Do not allow to enter drains or water courses, or dispose of where ground or surface waters may be affected. Wastes, including emptied containers, are controlled wastes and should be disposed of in accordance with regulations made under the Control of Pollution Act and the Environmental Protection Act. cont’d 9804/9033 ISSUE 1, JANUARY 2002 There is no data available on the product itself. The product should not be allowed to enter drains or water courses or be deposited where it can affect ground or surface waters. The Air Pollution Control requirements of regulations made under the Environmental Protection Act may apply to the use of this product. 13. DISPOSAL CONSIDERATIONS Do not allow to enter drains or water courses, or dispose of where ground or surface waters may be affected. Wastes, including emptied containers, are controlled wastes and should be disposed of in accordance with regulations made under the Control of Pollution Act and the Environmental Protection Act. Using information provided in this data sheet, advice should be obtained from the relevant environment agency whether the special waste regulations apply. 14. TRANSPORT INFORMATION Transport within the user's premises Always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. Potential effect on environment: Unknown Mobility: Unknown Persistence and degradability: Unknown Potential to bioaccumulate: Unknown Ecotoxicity: Unknown Aquatic toxicity: Non established 9804/9025 ISSUE 1, MARCH 2002 Mobility: - Ground: Given its physical and chemical characteristics, the product generally shows little mobility in the ground. - Water: The product is insoluble, it floats on water. Persistence and degradability: Experimental data on the finished product is not available. However, the ‘mineral oil’ portion of the virgin product is intrinsically biodegrabable. Particular ingredients may not be biodegradable. Ecotoxicity: The virgin product is considered to present no danger for land-growing organisms and little danger for aquatic life. No data is currently available for the used 13. DISPOSAL CONSIDERATIONS Waste: There is no data available on the product itself. The product should not be allowed to enter drains or water courses or be deposited where it can affect ground or surface waters. The Air Pollution Control requirements of regulations made under the Environmental Protection Acts may apply to the use of this product. 13. DISPOSAL CONSIDERATIONS Paint Do not allow into drains or water courses or dispose of where ground or surface waters may be affected. Wastes, including emptied containers, are controlled wastes and should be be disposed of in accordance with regulations made under the Control of Pollution & Environmental Protection Acts. Hardener Residues in emptied containers should be neutralised with decontaminant (see sect. 6). Do not allow into drains or water courses or dispose of where ground or surface waters may be affected. Wastes, including emptied containers, are controlled wastes and should be disposed of in accordance with regulations made under the Control of Pollution and Environmental Protection Acts. 14. TRANSPORT INFORMATION Paint Road/Rail SI Number.....1263 Packing Group...III Class...3.3 Designation...Flammable Liquid Sea Packing Grp. <=30lts...III Packing Grp. >30lts...III Class...3.3 Marine Pollutant...No UN Number...1263 Main Risk...Flammability Sub Risk...Narcosis Shipping Name...Flammable Liquid Air Packing Grp.<=30lts...III Packing Grp.>30lts...III Class...3.3 UN Number...1263 Main Risk...Flammability Sub Risk...Narcosis Shipping Name...Flammable Liquid International Packing Group...III Class...3.3 Road/Rail UN Number...1263 Main Risk...Flammability Sub Risk...Narcosis Shipping Name...Flammable Liquid Hardener Road/Rail SI Number.....1263 Packing Group...III Class...3.3 Designation...PAINT RELATED PRODUCT Sea Packing Grp. <=30lts...III Packing Grp. >30lts...III Class...3.3 Marine Pollutant...No UN Number...1263 Main risk...FLAMMABLE Sub Risk...NARCOSIS Shipping Name...PAINT RELATED PRODUCT Air Packing Grp.<=30lts...III Packing Grp.>30lts...III Class...3.3 UN Number...1263 Main Risk...FLAMMABLE Sub Risk...NARCOSIS Shipping Name...PAINT RELATED PRODUCT cont’d 9804/9035 ISSUE 1, MARCH 2002 There is no data available on the product itself. The product should not be allowed to enter drains or water courses or be deposited where it can affect ground or surface waters. 9804/9022 ISSUE 2 (REV), JUNE 2002 There is no data available on the product itself. The product should not be allowed to enter drains or water courses or be deposited where it can affect ground or surface waters. The Air Pollution Control requirements of regulations made under the Environmental Protection Act may apply to the use of this product. 13. DISPOSAL CONSIDERATIONS Do not allow to enter drains or water courses, or dispose of where ground or surface waters may be affected. Wastes, including emptied containers, are controlled wastes and should be disposed of in accordance with regulations made under the Control of Pollution Act and the Environmental Protection Act. Using information provided in this data sheet, advice should be obtained from the relevant environment agency whether the special waste regulations apply. 14. TRANSPORT INFORMATION Transport within the user's premises Always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. Resin Potential Effect on Environment: Toxic to aquatic organisms. Not readily biodegradeable. Hardener Potential Effect on Environment: Unknown. 13. DISPOSAL CONSIDERATIONS Waste disposal methods: Waste disposal should be in accordance with existing Community, National and local regulations. Empty container warnings: Empty containers may contain product residue; follow SDS and label warnings even after they have been emptied. *14. TRANSPORT INFORMATION (see also section 9) 9804/9025 ISSUE 2, SEPTEMBER 2002 Mobility The product is volatile/gaseous and will partition to the air phase. The product is insoluble in water. cont’d 9804/9036 ISSUE 1, AUGUST 2002 Mobility Because of its high viscosity, low water solubility and low degree of toxicity, this material should not present any environmental problems. cont’d 9804/9037 ISSUE 1, AUGUST 2002 LC 50, 96 HRS, FISH mg/l: 88 EC 50, 48 HRS, DAPHNIA, mg/l: 150 Mobility: Slightly soluble product, readily forms deposits. Bio Accumulation: Does not bioaccumulate significantly. Degradability: Not readily biodegradable. * 13. DISPOSAL CONSIDERATIONS Environmental Fate and Effects: Not established. 13. DISPOSAL CONSIDERATIONS Waste Disposal: Product is suitable for burning in an enclosed, controlled burner for fuel value or disposal by supervised incineration. Such burning may be limited by the controlling authority. In addition, the product is suitable for processing by an approved recycling facility or can be disposed of at any licensed waste disposal site. Use of these methods is subject to user compliance with applicable laws and regulations and consideration of product characteristics at time of disposal. 14. TRANSPORT INFORMATION USA DOT: Not regulated by USA DOT. RID/ADR: Not regulated by RID/ADR. IMO: Not regulated by IMO. IATA: Not regulated by IATA. 9804/8906 ISSUE 4, (REV.) MARCH 2003 Not expected to be toxic to aquatic environment. Not readily biodegradeable. 13. DISPOSAL CONSIDERATIONS Transport to authorised waste location, or incineration under controlled conditions. 14. TRANSPORT INFORMATION UN-No: Not classified IATA/ICAO: Not classified RID/ADR: Not classified Other: IMO: Not classified 15. REGULATORY INFORMATION No EC exposure limit established. EC Labelling/Classification: Environmental Fate and Effects: Not established. 13. DISPOSAL CONSIDERATIONS Waste Disposal: Product is suitable for burning in an enclosed, controlled burner for fuel value or disposal by supervised incineration. Such burning may be limited by the controlling authority. In addition, the product is suitable for processing by an approved recycling facility or can be disposed of at any licensed waste disposal site. Use of these methods is subject to user compliance with applicable laws and regulations and consideration of product characteristics at time of disposal. 14. TRANSPORT INFORMATION USA DOT:Not regulated by USA DOT. RID/ADR: Not regulated by RID/ADR. IMO: Not regulated by IMO. IATA: Not regulated by IATA. 9804/8905 ISSUE 5, (REV.) MARCH 2003 Mobility: Little mobility in soil. Some components may penetrate the soil causing ground water pollution. Will spread on the water surface. A small portion may be dispersed in water. Degradability: Not readily biodegradable. Ecotoxicity/bioaccumulation:The base oil components are not expected to be dangerous to the aquatic environment. 13. DISPOSAL CONSIDERATIONS Transport to authorized waste location, or incinerate under controlled conditions. European Waste Catalogue No. 130205. 14. TRANSPORT INFORMATION UN-no: Not classified RID / ADR: Not classified IMO: Not classified IATA / ICAO: Not classified Other: - 15. REGULATORY INFORMATION EC Labelling / Classification Mobility: Little mobility in soil. Some components may penetrate the soil causing ground water pollution. Will spread on the water surface. A small portion may be dispersed in water. Degradability: Not readily biodegradable. Ecotoxicity/bioaccumulation:The base oil components are not expected to be dangerous to the aquatic environment. 13. DISPOSAL CONSIDERATIONS Transport to authorized waste location, or incinerate under controlled conditions. European Waste Catalogue No. 130202. 14. TRANSPORT INFORMATION UN-no: Not classified RID / ADR: Not classified IMO: Not classified IATA / ICAO: Not classified Other: - 15. REGULATORY INFORMATION EC Labelling / Classification Mobility: Little mobility in soil. Some components may penetrate the soil causing ground water pollution. Will spread on the water surface. A small portion may be dispersed in water. Degradability: Not readily biodegradable. Ecotoxicity/bioaccumulation:The base oil components are not expected to be dangerous to the aquatic environment. 13. DISPOSAL CONSIDERATIONS Transport to authorized waste location, or incinerate under controlled conditions. European Waste Catalogue No. 130202. 14. TRANSPORT INFORMATION UN-no: Not classified RID / ADR: Not classified IMO: Not classified IATA / ICAO: Not classified Other: - 15. REGULATORY INFORMATION EC Labelling / Classification Not expected to be toxic to aquatic environment. Not readily biodegradable. 13. DISPOSAL CONSIDERATIONS Transport to authorised waste location, or incineration under controlled conditions. 14. TRANSPORT INFORMATION UN-No: Not classified IATA/ICAO: Not classified RID/ADR: Not classified Other: IMO: Not classified 15. REGULATORY INFORMATION No EC exposure limit established. EC Labelling/Classification: Mobility: Little mobility in soil. Some components may penetrate the soil causing ground water pollution. Will spread on the water surface. A small portion may be dispersed in water. Degradability: Not readily biodegradable. Ecotoxicity/bioaccumulation:The base oil components are not expected to be dangerous to the aquatic environment. 13. DISPOSAL CONSIDERATIONS Transport to authorized waste location, or incinerate under controlled conditions. European Waste Catalogue No. 130205. 14. TRANSPORT INFORMATION UN-no: Not classified RID / ADR: Not classified IMO: Not classified IATA / ICAO: Not classified Other: - 15. REGULATORY INFORMATION EC Labelling / Classification The base oil components are not expected to be dangerous to the aquatic environment. Not readily biodegradable. 13. DISPOSAL CONSIDERATIONS Transport to authorised waste location, or incineration under controlled conditions. 14. TRANSPORT INFORMATION UN-No: Not classified IATA/ICAO: Not classified RID/ADR: Not classified Other: IMO: Not classified 15. REGULATORY INFORMATION No EC exposure limit established. EC Labelling/Classification: Mobility: Little mobility in soil. Some components may penetrate the soil causing ground water pollution. Will spread on the water surface. A small portion may be dispersed in water. Degradability: Not readily biodegradable. Ecotoxicity/bioaccumulation:The base oil components are not expected to be dangerous to the aquatic environment. 13. DISPOSAL CONSIDERATIONS Transport to authorized waste location, or incinerate under controlled conditions. European Waste Catalogue No. 130106. 14. TRANSPORT INFORMATION UN-no: Not classified RID / ADR: Not classified IMO: Not classified IATA / ICAO: Not classified Other: - 15. REGULATORY INFORMATION EC Labelling / Classification Mobility: Little mobility in soil. Some components may penetrate the soil causing ground water pollution. Will spread on the water surface. A small portion may be dispersed in water. Degradability: Not readily biodegradable. Ecotoxicity/bioaccumulation:The base oil components are not expected to be dangerous to the aquatic environment. 13. DISPOSAL CONSIDERATIONS Transport to authorized waste location, or incinerate under controlled conditions (EU Directives 2000/76/EC and 1999/31/EC apply). European Waste Catalogue Code 13 02 05: mineral-based non-chlorinated engine, gear and lubricating oils 14. TRANSPORT INFORMATION file://C:\My Documents\Oils\5670_JCBTwoStrokeOil_E.htm 3/4/03 JCB Two Stroke Oil 9804/9042 ISSUE 1, MARCH 2003 Mobility: Little mobility in soil. Some components may penetrate the soil causing ground water pollution. Will spread on the water surface. A small portion may be dispersed in water. Degradability: Not readily biodegradable. Ecotoxicity/bioaccumulation:The base oil components are not expected to be dangerous to the aquatic environment. 13. DISPOSAL CONSIDERATIONS Transport to authorized waste location, or incinerate under controlled conditions (EU Directives 2000/76/EC and 1999/31/EC apply). European Waste Catalogue Code 13 02 05: mineral-based non-chlorinated engine, gear and lubricating oils 14. TRANSPORT INFORMATION file://C:\My Documents\Oils\5667_JCBChainOil_E.htm 3/4/03 JCB Chain Oil 9804/9044 ISSUE 1, MARCH 2003 Mobility: Little mobility in soil. Some components may penetrate the soil causing ground water pollution. Will spread on the water surface. A small portion may be dispersed in water. Degradability: Not readily biodegradable. Ecotoxicity/bioaccumulation:The base oil components are not expected to be dangerous to the aquatic environment. 13. DISPOSAL CONSIDERATIONS Transport to authorized waste location, or incinerate under controlled conditions (EU Directives 2000/76/EC and 1999/31/EC apply). European Waste Catalogue Code 13 02 05: mineral-based non-chlorinated engine, gear and lubricating oils 14. TRANSPORT INFORMATION file://C:\My Documents\Oils\5668_JCBMilkingMachine_E.htm 3/4/03 JCB Milking Machine 9804/9043 ISSUE 1, MARCH 2003 Mobility: Little mobility in soil. Some components may penetrate the soil causing ground water pollution. Will spread on the water surface. A small portion may be dispersed in water. Degradability: Not readily biodegradable. Ecotoxicity/bioaccumulation:The base oil components are not expected to be dangerous to the aquatic environment. Contains a small amount of additive components classified as dangerous to the aquatic environment. 13. DISPOSAL CONSIDERATIONS Transport to authorized waste location, or incinerate under controlled conditions (EU Directives 2000/76/EC and 1999/31/EC apply). European Waste Catalogue Code 13 02 05: mineral-based non-chlorinated engine, gear and lubricating oils 14. TRANSPORT INFORMATION file://C:\My Documents\Oils\5666_JCBGardenOil_E.htm 3/4/03 JCB Garden Oil 9804/9041 ISSUE 1, MARCH 2003 Not expected to be toxic to aquatic environment. Not readily biodegradeable. 13. DISPOSAL CONSIDERATIONS Transport to authorised waste location, or incineration under controlled conditions. 14. TRANSPORT INFORMATION UN-No: Not classified IATA/ICAO: Not classified RID/ADR: Not classified Other: IMO: Not classified 15. REGULATORY INFORMATION No EC exposure limit established. EC Labelling/Classification: Biodegradability: < 50% (CEC L-33-T082) Chemical oxygen demand (mg02/l): Not determined Not readily biodegradable but inherently biodegradable. Leaching and penetration through surface soils is generally regarded as resulting in long term persistence. Fresh or used product may be harmful to aquatic life. 13. DISPOSAL CONSIDERATIONS Used, degraded or contaminated product may be classified as special waste. Anyone classifying hazardous waste and determining its fate must be qualified in accordance with state and international regulations. 14. TRANSPORT INFORMATION Classification for transport: Not classified for transport Shipping name: NA

R-phrase(s)

30<& None. Flammable Highly Flammable. Lead chromate - T R61, R33, R40 Repr. Cat.1 Carc. Cat. 3 as Chromium (CR) <15% as Lead (Pb) <25% (*) for full text see Section 16. R61 May cause harm to the unborn child. R10 Flammable R40 Possible risk of irreversible effects. R33 Danger of cumulative effects P90 Contains lead. Should not be used on surfaces that are liable to be chewed or sucked by children. 9804/8919 ISSUE 3 (REV.), APRIL 1997 4. FIRST-AID MEASURES General: In all cases of doubt, or if symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. Inhalation: Remove casualty to fresh air and keep warm and at rest. If breathing has stopped administer artificial respiration. If unconscious place in the recovery position and seek medical help. Give nothing by mouth. Eye Contact: Remove contact lenses and keep in a safe place. Irrigate copiously with clean water for at least 10 minutes holding eye lids apart and seek medical advice. Skin Contact: Remove contaminated clothing (including footwear). Wash skin thoroughly with soap and water or a proprietary skin cleanser. Do not use solvents or thinners. Ingestion: If accidentally swallowed obtain immediate medical attention. Keep at rest. Do not induce vomiting. 5. FIRE-FIGHTING MEASURES Extinguishing Media: Recommended: Alcohol resistant foam, CO2, dry powder or water spray/mist. Not to be used: Water jet. Recommendations: Fire will produce dense black smoke containing hazardous products of combustion (see Section 11). Decomposition products may be a hazard to health. Appropriate self-contained breathing apparatus may be required. Cool closed containers with water spray. Do not allow run-off from fire fighting to enter drains or water courses. 6. ACCIDENTAL RELEASE MEASURES Exclude sources of ignition and ventilate the area. Exclude non essential personnel. Avoid breathing vapours. Refer to protective measures listed in Section 7 and 8. Contain and collect spillages with non combustible absorbent material i.e. sand, earth, vermiculite or diatomaceous earth. Place in a suitable container for disposal in accordance with Waste Regulations (see Section 13). Do not allow to enter drains or water courses. Clean, preferably with a detergent. Avoid the use of solvents. If the product enters drains or sewers, contact the local water company immediately. In the case of contamination of streams, lakes or canals, the National Rivers Authority. 7. HANDLING AND STORAGE Handling Vapours are heavier than air and may spread along floors. They may form explosive mixtures with air. Prevent the creation of flammable or explosive concentrations of vapour and avoid vapour concentrations higher than the occupational exposure limits. The product should only be used in areas from which all naked lights and other sources of ignition have been excluded. Electrical equipment should be protected to the appropriate standard. Keep container tightly closed. Exclude sources of heat, sparks and open flame. Non sparking tools should be used. Avoid skin and eye contact. Avoid the inhalation of vapour and spray mist. Smoking, eating and drinking should be prohibited in areas of storage and use. For personal protection see Section 8. Never use pressure to empty. The container is not a pressure vessel. Always keep in containers the same material as the supply container. Good housekeeping standards and regular safe removal of waste material will minimise the risks of spontaneous combustion and other fire hazards. The Manual Handling Operations Regulations will apply to the handling of containers of this product. Refer to the guide weight indicated on the container when carrying out assessments. Avoid the handling of dusts, particulates and spray mists arising from the use of this lead chromate containing paint. cont’d 9804/8919 ISSUE 3 (REV.), APRIL 1997 Lead chromate - T R61, R33, R40 Repr. Cat.1 Carc. Cat. 3 as Chromium (CR) <15% as Lead (Pb) <25% (*) for full text see Section 16. R61 May cause harm to the unborn child. R10 Flammable R40 Possible risk of irreversible effects. R33 Danger of cumulative effects P90 Contains lead. Should not be used on surfaces that are liable to be chewed or sucked by children. 9804/8918 ISSUE 4 (REV.), NOVEMBER 1997 4. FIRST-AID MEASURES General: In all cases of doubt, or if symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. Inhalation: Remove casualty to fresh air and keep warm and at rest. If breathing has stopped administer artificial respiration. If unconscious place in the recovery position and seek medical help. Give nothing by mouth. Eye Contact: Remove contact lenses and keep in a safe place. Irrigate copiously with clean water for at least 10 minutes holding eye lids apart and seek medical advice. Skin Contact: Remove contaminated clothing (including footwear). Wash skin thoroughly with soap and water or a proprietary skin cleanser. Do not use solvents or thinners. Ingestion: If accidentally swallowed obtain immediate medical attention. Keep at rest. Do not induce vomiting. 5. FIRE-FIGHTING MEASURES Extinguishing Media: Recommended: Alcohol resistant foam, CO2, dry powder or water spray/mist. Not to be used: Water jet. Recommendations: Fire will produce dense black smoke containing hazardous products of combustion (see Section 11). Decomposition products may be a hazard to health. Appropriate self-contained breathing apparatus may be required. Cool closed containers with water spray. Do not allow run-off from fire fighting to enter drains or water courses. 6. ACCIDENTAL RELEASE MEASURES Exclude sources of ignition and ventilate the area. Exclude non essential personnel. Avoid breathing vapours. Refer to protective measures listed in Section 7 and 8. Contain and collect spillages with non combustible absorbent material i.e. sand, earth, vermiculite or diatomaceous earth. Place in a suitable container for disposal in accordance with Waste Regulations (see Section 13). Do not allow to enter drains or water courses. Clean, preferably with a detergent. Avoid the use of solvents. If the product enters drains or sewers, contact the local water company immediately. In the case of contamination of streams, lakes or canals, the National Rivers Authority. 7. HANDLING AND STORAGE Handling Vapours are heavier than air and may spread along floors. They may form explosive mixtures with air. Prevent the creation of flammable or explosive concentrations of vapour and avoid vapour concentrations higher than the occupational exposure limits. The product should only be used in areas from which all naked lights and other sources of ignition have been excluded. Electrical equipment should be protected to the appropriate standard. Keep container tightly closed. Exclude sources of heat, sparks and open flame. Non sparking tools should be used. Avoid skin and eye contact. Avoid the inhalation of vapour and spray mist. Smoking, eating and drinking should be prohibited in areas of storage and use. For personal protection see Section 8. Never use pressure to empty. The container is not a pressure vessel. Always keep in containers the same material as the supply container. Good housekeeping standards and regular safe removal of waste material will minimise the risks of spontaneous combustion and other fire hazards. The Manual Handling Operations Regulations will apply to the handling of containers of this product. Refer to the guide weight indicated on the container when carrying out assessments. Avoid the handling of dusts, particulates and spray mists arising from the use of this lead chromate containing paint. cont’d 9804/8918 ISSUE 4 (REV.), NOVEMBER 1997 Lead chromate - T R61, R33, R40 Repr. Cat.1 Carc. Cat. 3 as Chromium (CR) <15% as Lead (Pb) <25% (*) for full text see Section 16. R61 May cause harm to the unborn child. R10 Flammable R40 Possible risk of irreversible effects. R33 Danger of cumulative effects P90 Contains lead. Should not be used on surfaces that are liable to be chewed or sucked by children. 9804/8917 ISSUE 4 (REV.), NOVEMBER 1997 4. FIRST-AID MEASURES General: In all cases of doubt, or if symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. Inhalation: Remove casualty to fresh air and keep warm and at rest. If breathing has stopped administer artificial respiration. If unconscious place in the recovery position and seek medical help. Give nothing by mouth. Eye Contact: Remove contact lenses and keep in a safe place. Irrigate copiously with clean water for at least 10 minutes holding eye lids apart and seek medical advice. Skin Contact: Remove contaminated clothing (including footwear). Wash skin thoroughly with soap and water or a proprietary skin cleanser. Do not use solvents or thinners. Ingestion: If accidentally swallowed obtain immediate medical attention. Keep at rest. Do not induce vomiting. 5. FIRE-FIGHTING MEASURES Extinguishing Media: Recommended: Alcohol resistant foam, CO2, dry powder or water spray/mist. Not to be used: Water jet. Recommendations: Fire will produce dense black smoke containing hazardous products of combustion (see Section 11). Decomposition products may be a hazard to health. Appropriate self-contained breathing apparatus may be required. Cool closed containers with water spray. Do not allow run-off from fire fighting to enter drains or water courses. 6. ACCIDENTAL RELEASE MEASURES Exclude sources of ignition and ventilate the area. Exclude non essential personnel. Avoid breathing vapours. Refer to protective measures listed in Section 7 and 8. Contain and collect spillages with non combustible absorbent material i.e. sand, earth, vermiculite or diatomaceous earth. Place in a suitable container for disposal in accordance with Waste Regulations (see Section 13). Do not allow to enter drains or water courses. Clean, preferably with a detergent. Avoid the use of solvents. If the product enters drains or sewers, contact the local water company immediately. In the case of contamination of streams, lakes or canals, the National Rivers Authority. 7. HANDLING AND STORAGE Handling Vapours are heavier than air and may spread along floors. They may form explosive mixtures with air. Prevent the creation of flammable or explosive concentrations of vapour and avoid vapour concentrations higher than the occupational exposure limits. The product should only be used in areas from which all naked lights and other sources of ignition have been excluded. Electrical equipment should be protected to the appropriate standard. Keep container tightly closed. Exclude sources of heat, sparks and open flame. Non sparking tools should be used. Avoid skin and eye contact. Avoid the inhalation of vapour and spray mist. Smoking, eating and drinking should be prohibited in areas of storage and use. For personal protection see Section 8. Never use pressure to empty. The container is not a pressure vessel. Always keep in containers the same material as the supply container. Good housekeeping standards and regular safe removal of waste material will minimise the risks of spontaneous combustion and other fire hazards. The Manual Handling Operations Regulations will apply to the handling of containers of this product. Refer to the guide weight indicated on the container when carrying out assessments. Avoid the handling of dusts, particulates and spray mists arising from the use of this lead chromate containing paint. cont’d 9804/8917 ISSUE 4 (REV.), NOVEMBER 1997 NONE (*) for full text see Section 16. R10 Flammable P90 Contains lead. Should not be used on surfaces that are liable to be chewed or sucked by children. 4. FIRST-AID MEASURES General: In all cases of doubt, or if symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. Inhalation: Remove casualty to fresh air and keep warm and at rest. If breathing has stopped administer artificial respiration. If unconscious place in the recovery position and seek medical help. Give nothing by mouth. cont’d 9804/8920 ISSUE 5 (REV.), JUNE 2002 Aromatic Hydrocarbon >95 <100% Xn R20/21 (*) for full text see Section 16. R10 R20/21 4. FIRST-AID MEASURES General: In all cases of doubt, or if symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. Inhalation: Remove casualty to fresh air and keep warm and at rest. If breathing is irregular or stopped administer artificial respiration. If unconscious place in the recovery position and seek medical help. cont’d 9804/8929 ISSUE 4 (REV.), JUNE 2002 None assigned. None assigned. Highly flammable. Harmful by inhalation and in contact with skin. Irritating to skin. None 1 Severely solvent refined mineral oil (IP346 ± 93 - DMSO extract < 3 %) 2 Poly alkylmethacrylate - 3 Polyolefin 1-5 Xn R20 No substances are present in concentrations regarded to present a health or environmental hazard (article 3 of Directive 1999/45/EC). 3. Health: Unlikely to cause eye irritation. Unlikely to cause immediate irritation but prolonged and repeated contact may be harmful to the skin. Not volatile. It is not likely to be an inhalation hazard at normal ambient temperatures. If overheated, fumes and vapours are irritating to the breathing passages and lungs. Ingestion is unlikely to cause adverse systemic health effects. Environmental: Although no specific ecological hazards are expected and bioaccumulation is unlikely, spillage into the environment should always be avoided. Physical / Chemical: Not applicable None 1 Severely solvent refined mineral oil (IP346 ± 94 DMSO extract < 3 %) 2 Calcium alkylphenate 3-4 Xi R38,R53 3 Zinc alkyldithiophosphate < 1.5 Xi R41 4 Calcium sulphonates - No substances are present in concentrations regarded to present health hazards (article 3 of Directive 88/379/EEC). 3. Health: Unlikely to cause eye irritation. Unlikely to cause immediate irritation but prolonged and repeated contact may be harmful to the skin. Not volatile. It is not likely to be an inhalation hazard at normal ambient temperatures. If overheated, fumes and vapours are irritating to the breathing passages and lungs. Ingestion is unlikely to cause adverse systemic health effects. Environmental: Although no specific ecological hazards are expected and bioaccumulation is unlikely, spillage into the environment should always be avoided. Physical / Chemical: Not applicable None 1 Severely solvent refined mineral oil (IP346 ± 94 DMSO extract < 3 %) 2 Calcium alkylphenate 3-4 Xi R38,R53 3 Zinc alkyldithiophosphate < 1.5 Xi R41 4 Calcium sulphonates - No substances are present in concentrations regarded to present health hazards (article 3 of Directive 88/379/EEC). 3. Health: Unlikely to cause eye irritation. Unlikely to cause immediate irritation but prolonged and repeated contact may be harmful to the skin. Not volatile. It is not likely to be an inhalation hazard at normal ambient temperatures. If overheated, fumes and vapours are irritating to the breathing passages and lungs. Ingestion is unlikely to cause adverse systemic health effects. Environmental: Although no specific ecological hazards are expected and bioaccumulation is unlikely, spillage into the environment should always be avoided. Physical / Chemical: Not applicable None 1 Severely solvent refined mineral oil (IP346 ± 91 - DMSO extract < 3 %) 2 Zinc alkyldithiophosphate < 2 Xi R38,R41 3 Calcium/magnesium sulphonates & phenates - 4 Polyolefins - No substances are present in concentrations regarded to present health hazards (article 3 of Directive 88/379/EEC). 3. Health: Unlikely to cause eye irritation. Unlikely to cause immediate irritation but prolonged and repeated contact may be harmful to the skin. Not volatile. It is not likely to be an inhalation hazard at normal ambient temperatures. If overheated, fumes and vapours are irritating to the breathing passages and lungs. Ingestion is unlikely to cause adverse systemic health effects. Environmental: Although no specific ecological hazards are expected and bioaccumulation is unlikely, spillage into the environment should always be avoided. Physical / Chemical: Not applicable None 1 Severely solvent refined mineral oil (IP346 ± 93 - DMSO extract < 3 %) 2 Zinc alkyldithiophosphate < 0.5 Xi R38 3 Poly alkyl methacrylate - 4 Antioxidants & Rust inhibitors < 0.5 Xi R38 No substances are present in concentrations regarded to present health hazards (article 3 of Directive 88/379/EEC). 3. Health: Unlikely to cause eye irritation. Unlikely to cause immediate irritation but prolonged and repeated contact may be harmful to the skin. Not volatile. It is not likely to be an inhalation hazard at normal ambient temperatures. If overheated, fumes and vapours are irritating to the breathing passages and lungs. Ingestion is unlikely to cause adverse systemic health effects. Environmental: Although no specific ecological hazards are expected and bioaccumulation is unlikely, spillage into the environment should always be avoided. Physical / Chemical: Not applicable None None None None None

S-phrase(s)

30<& & None. Keep away from sources of Ignition - No Smoking. Use only in well ventilated areas. Do not breathe gas/fumes/vapour/spray. Keep out of reach of children. Avoid contact with skin and eyes. Use only in well ventilated areas. Take precautionary measures against static discharges. Keep away from sources of ignition - No Smoking. Keep out of reach of children. Keep container tightly closed. Do no empty into drains. Avoid contact with skin and eyes. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves. Do not empty into drains. Contains isocyanates. See information supplied by the manufacturer. 9804/8974 ISSUE 4, (REV.) NOVEMBER 1997 Avoid contact with skin and eyes. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves. Do not empty into drains. Contains isocyanates. See information supplied by the manufacturer. 9804/8989 ISSUE 3, (REV.) NOVEMBER 1996 Avoid contact with skin and eyes. Do not breathe gas/fumes/vapour/spray. Use only in well ventilated areas. Take precautionary measures against static discharges. Keep away from sources of ignition - No Smoking. Keep out of reach of children Keep container tightly closed Do not empty into drains None 9804/9021 ISSUE1, MARCH 2002 Other regulations:No EC exposure limit established. 16. Other regulations:No EC exposure limit established. 16. Other regulations:No EC exposure limit established. 16. Other regulations:No EC exposure limit established. 16. Other regulations:No EC exposure limit established. 16. None Other Safety data sheet available for professional user on request. regulations: 16. None Other - regulations: 16. None Other - regulations: 16. None Other Safety data sheet available for professional user on request. regulations: 16.

Further information

Product Use ] 1&G3IHEF1GM7&HE0& 375<&OHJ1G4M3F<& MSDS first Issued: Aa&'H30&ABBb& Revision Date: cM149&ABBa<& National Legislation EC Legislation +(&WG104FGR0E&BA CONCAWE report no. 5/87 ‘health aspect of lubricants’. It is believed that all the information given in this bulletin (which supersedes all previous issues) is accurate at the time of printing. Such information is offered in good faith but without guarantee and without any representation that the product concerned is suitable for any use or application. Without limitation of the foregoing, nothing herein shall be construed as a recommendation for uses which infringe valid patents or as extending any license under valid patents. JCB pursues a policy of constant research and development aimed at product improvement and, therefore, reserves the right to change formulation, specification and characteristics of its products without notice. User should verify current specifications with JCB and ascertain that products are suitable for intended uses and applications. Where the information provided herein discloses a potential hazard or hazardous ingredient, adequate warning must be provided to employees and users and appropriate precautions taken, including the practice of good industrial hygiene. contact JCB SERVICE WORLD PARTS CENTRE UTTOXETER STAFFORDSHIRE ST14 5BS TEL: + 44 (0) 1889 590312 FAX: + 44 * Note: Items marked with an asterisk (*) have been amended since last issue. Q8 T 45/1995-06-14 >_I>U*A'/;G6/3'46J'Q$O%'iH;273H'2<G;13'68'7-./01243<j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c-23;']2/4045' 9-<3'.;'G/6:0R;R'36';9G76E;;<'24R'-<;/<'24R'2GG/6G/023;'G/;12-3064<'32W;4&'0417-R045'3H;'G/21301;'68'566R' 04R-<3/027'HE50;4;J' ' ^-/3H;/'D486/923064'1643213K' JCB SERVICE WORLD PARTS CENTRE UTTOXETER STAFFORDSHIRE ST14 5BS TEL: + 44 (0) 1889 590 312 FAX: + 44 (0) 1889 593 624 9804/8909 ISSUE 5 (REV.), MARCH 2003 Ingredients considered hazardous to health This product is not hazardous to health as defined by the EC Dangerous Substances/Preparations Directives. See Section 15 for a regulatory analysis of the ingredients. Effects of overexposure: No significant effects expected. 4. FIRST-AID MEASURES Eye Contact: Flush thoroughly with water. If irritation occurs, call a doctor. Skin Contact: Wash contact areas with soap and water. Inhalation: Not expected to be a problem. Ingestion: Not expected to be a problem. However, if greater than 1/2 litre (pint) is ingested or if feeling uncomfortable, give 1 to 2 glasses of water and obtain medical attention or call an ambulance for assistance. DO NOT INDUCE VOMITING or give anything by mouth to an unconscious person. 5. FIRE-FIGHTING MEASURES Extinguishing Media: Carbon dioxide, foam, dry chemical, and water fog. cont’d 9804/8909 ISSUE 5 (REV.), MARCH 2003 Chemical Names and Synonyms: Severe treat min. oils and additives Use: Automotive engine oil; lubricant for selected compressors Note: This product should not be used for any other purpose without expert advice. COSHH Regulations: Product reviewed and no action under COSHH considered necessary. Note: JCB Lubricant products are not formulated to contain PCBS. Any sections of this Material Safety Data Bulletin which are printed in bold text highlights recent significant changes which have been made to the advice or information given. It is believed that all the information given in this bulletin (which supersedes all previous issues) is accurate at the time of printing. Such information is offered in good faith but without guarantee and without any representation that the product concerned is suitable for any particular use or application. Without limitation of the foregoing, nothing herein shall be construed as a recommendation for uses which infringe valid patents or as extending any licence under valid patents. JCB pursues a policy of constant research and development aimed at product improvement and, therefore, reserves the right to change formulation, specification and characteristics of its products without notice. User should verify current specifications with JCB and ascertain that products are suitable for intended uses and applications. Where the information provided herein discloses a potential hazard or hazardous ingredient, adequate warning must be provided to employees and users and appropriate precautions taken, including the practice of good industrial hygiene. contact JCB SERVICE WORLD PARTS CENTRE UTTOXETER STAFFORDSHIRE ST14 5BS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 593624 440727-63/02.08.95 9804/8969 ISSUE 6 (REV.), MARCH 2003 JCB Brake Fluid Grades: Use: Brake fluid for automobiles Supplier: Emergency Contact : Emergency Telephone No.: +44 (0) 1889 590312 2. COMPOSITION/INFORMATION ON INGREDIENTS Glycol ethers, glycol ether esters, polyglycol and inhibitors (100%). It is believed that all the information given in this bulletin (which supersedes all previous issues) is accurate at the time of printing. Such information is offered in good faith but without guarantee and without any representation that the product concerned is suitable for any use or application. Without limitation of the foregoing, nothing herein shall be construed as a recommendation for uses which infringe valid patents or as extending any license under valid patents. JCB pursues a policy of constant research and development aimed at product improvement and, therefore, reserves the right to change formulation, specification and characteristics of its products without notice. User should verify current specifications with JCB and ascertain that products are suitable for intended uses and applications. Where the information provided herein discloses a potential hazard or hazardous ingredient, adequate warning must be provided to employees and users and appropriate precautions taken, including the practice of good industrial hygiene. contact JCB SERVICE WORLD PARTS CENTRE UTTOXETER STAFFORDSHIRE ST14 5BS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 593624 * Note: Items marked with an asterisk (*) have been amended since last issue. Q8 Brake Fluid/1996-05-23 9804/8899 ISSUE 5 (REV.), MARCH 2003 JCB Hydraulic Fluid HP 15 Grades: ISO VG 15 Use: Lubricating oil for hydraulic equipment Supplier: Severely solvent refined mineral oil (appr. 95%) Additives (appr. 5%), mainly: Zinc alkyldithiophosphate Poly alkyl methacrylate CONCAWE report no. 5/87 ‘health aspect of lubricants’. It is believed that all the information given in this bulletin (which supersedes all previous issues) is accurate at the time of printing. Such information is offered in good faith but without guarantee and without any representation that the product concerned is suitable for any use or application. Without limitation of the foregoing, nothing herein shall be construed as a recommendation for uses which infringe valid patents or as extending any license under valid patents. JCB pursues a policy of constant research and development aimed at product improvement and, therefore, reserves the right to change formulation, specification and characteristics of its products without notice. User should verify current specifications with JCB and ascertain that products are suitable for intended uses and applications. Where the information provided herein discloses a potential hazard or hazardous ingredient, adequate warning must be provided to employees and users and appropriate precautions taken, including the practice of good industrial hygiene. contact JCB SERVICE WORLD PARTS CETNRE UTTOXETER STAFFORDSHIRE ST14 5BS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 593624 * Note: Items marked with an asterisk (*) have been amended since last issue. Q8 Heller 15/1997-06-13 9804/8971 ISSUE 5, (REV.) MARCH 2003 JCB Hydraulic Fluid HP 46 Grades: ISO VG 22, 32, 46, 68, 100, 150, 460 Use: Lubricating oil for hydraulic equipment Severely solvent refined mineral oil (> 98%). Additives (< 2%), mainly: Zinc alkyldithiophosphate Antioxidants Rust inhibitors CONCAWE report no. 5/87 ‘health aspects of lubricants’. It is believed that all the information given in this bulletin (which supersedes all previous issues) is accurate at the time of printing. Such information is offered in good faith but without guarantee and without any representation that the product concerned is suitable for any use or application. Without limitation of the foregoing, nothing herein shall be construed as a recommendation for uses which infringe valid patents or as extending any license under valid patents. JCB pursues a policy of constant research and development aimed at product improvement and, therefore, reserves the right to change formulation, specification and characteristics of its products without notice. User should verify current specifications with JCB and ascertain that products are suitable for intended uses and applications. Where the information provided herein discloses a potential hazard or hazardous ingredient, adequate warning must be provided to employees and users and appropriate precautions taken, including the practice of good industrial hygiene. contact JCB SERVICE WORLD PARTS CENTRE UTTOXETER STAFFORDSHIRE ST14 5BS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 593624 * Note: Items marked with an asterisk (*) have been amended since last issue. Q8 Haydn (22-460) 1995-04-04 9804/8972 ISSUE 5, (REV.) MARCH 2003 JCB Hydraulic Fluid HP 32 Grades: ISO VG 22, 32, 46, 68, 100, 150, 460 Use: Lubricating oil for hydraulic equipment Severely solvent refined mineral oil (> 98%). Additives (< 2%), mainly: Zinc alkyldithiophosphate Antioxidants Rust inhibitors CONCAWE report no. 5/87 ‘health aspect of lubricants’. It is believed that all the information given in this bulletin (which supersedes all previous issues) is accurate at the time of printing. Such information is offered in good faith but without guarantee and without any representation that the product concerned is suitable for any use or application. Without limitation of the foregoing, nothing herein shall be construed as a recommendation for uses which infringe valid patents or as extending any license under valid patents. JCB pursues a policy of constant research and development aimed at product improvement and, therefore, reserves the right to change formulation, specification and characteristics of its products without notice. User should verify current specifications with JCB and ascertain that products are suitable for intended uses and applications. Where the information provided herein discloses a potential hazard or hazardous ingredient, adequate warning must be provided to employees and users and appropriate precautions taken, including the practice of good industrial hygiene. contact JCB SERVICE WORLD PARTS CENTRE UTTOEXTER STAFFORDSHIRE ST14 5BS TEL: + 44 (0) 1889 590312 FAX: +44 (0) 1889 593624 * Note: Items marked with an asterisk (*) have been amended since last issue. Q8 Haydn (22-460) 1995-04-04 9804/8945 ISSUE 2, (REV) FEBRUARY 1997 JCB Extra Dig Dipper Lubricant is an alkali metal soap lubricating grease containing laminar solid lubricants, polymers and additives. On the basis or our knowledge of the highly refined mineral oils and on the recommendations of the manufacturers of the additives used in this lubricating grease this product is unlikely to be hazardous to man in normal use. In the environment these greases are likely to biodegrade slowly. 4. FIRST-AID MEASURES Type of Exposure First Aid Measures Ingestion Harmless if swallowed in small amounts - larger Wash mouth out with water. Do not induce vomiting quantities may cause nausea and diarrhoea. because of the danger of aspiration. If aspiration occurs or is expected get immediate medical advice. Skin Unlikely to cause irritation, but prolonged or frequent Wash skin as soon as possible with soap and water. contact may cause irritation which could result in Change contaminated clothing and launder before reuse. dermatitis. Eyes May cause minor irritation with short-term redness Wash out thoroughly with water. If redness and/or irritation and stinging. continues get medical advice. cont’d 9804/8945 ISSUE 2, (REV) FEBRUARY 1997 Inhalation Unlikely to be irritant. If inhalation of fumes irritates the nose or throat or causes coughing remove to fresh air. Get medical advice if irritation continues. 5. FIRE-FIGHTING MEASURES Extinguish with dry powder, foam, sand or earth. For small fires use CO2. Do not tackle fires with water. Water may be used to cool the surrounding area. Fires in closed or confined spaces should be tackled by trained personnel who should wear breathing apparatus. 6. ACCIDENTAL RELEASE MEASURES May cause slippery surfaces. Contain spillage - do not wash spillage down drain. Absorb using absorbent clay, sand or other suitable absorbent. Report any escape to public drainage or water courses to Local Authority and Fire Brigade. 7. HANDLING AND STORAGE 7.1 Handling Skin contact should be kept to a minimum and good hygiene standards maintained. If prolonged or repeated contact is likely PROTECTIVE CLOTHING, as detailed in Section 8 SHOULD BE WORN when handling this product. 7.2 Liability - The information contained in this data sheet is accurate to the best of JCB’s knowledge. It applies only to the products designated herein and supplied by JCB or its distributors. The customer is strongly advised to observe and ensure that its employees and customers observe all directions contained herein, however neither JCB or its distributors accepts any liability whatsoever (other than liability in respect of matters referred to in Section 2 Unfair Contract Terms Act 1977 and in Section 7 Customer Protection Act 1987) arising out of the use of the information or the use adaptation or processing of the products designated herein. Where third party products are used in conjunction with or instead of products produced or supplied by JCB or its distributors the customer should himself obtain all necessary technical, health and safety information about such products from the third party. can be found in Health and Safety Executive Publications a list of which may be made available on request. JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 LT-DS-862-01 9804/8897 ISSUE 3 (REV.), NOVEMBER 1997 Ingredients considered hazardous to health This product is not hazardous to health as defined by the EC Dangerous Substances/Preparations Directives. See Section 15 for a regulatory analysis of the ingredients. Effects of overexposure: No significant effects expected. 4. FIRST-AID MEASURES Eye Contact: Flush thoroughly with water. If irritation occurs, call a doctor. Skin Contact: Wash contact areas with soap and water. High pressure accidental injection through the skin requires IMMEDIATE medical attention for possible incision, irrigation and/or debridement. Inhalation: Not expected to be a problem. Ingestion: Not expected to be a problem. However, if greater than 1/2 litre (pint) is ingested or if feeling uncomfortable, give 1 or 2 glasses of water and obtain medical attention or call an ambulance for assistance. DO NOT INDUCE VOMITING or give anything by mouth to an unconscious person. 9804/8897 ISSUE 3 (REV.), NOVEMBER 1997 5. FIRE-FIGHTING MEASURES Extinguishing Media: Carbon dioxide, foam, dry chemical and water fog. Special fire fighting procedures: Water or foam may cause frothing. Use water to keep fire exposed containers cool. Water spray may be used to flush spills away from exposures. Prevent runoff from fire control or dilution from entering waterways or drinking water supply. Special Protective Equipment: For fires in enclosed areas, firefighters MUST use self-contained breathing apparatus. Unusual fire and explosion hazards: None. Flash Point °C(°F): >204 (400) (Estimated (Oil COC)) Flammable Limits: LEL NA UEL NA. NFPA Hazard ID: Health: 0 Flammability: 1 Reactivity: 0 Hazardous decomposition products: Metal oxides. Carbon monoxide. 6. ACCIDENTAL RELEASE MEASURES Notification procedures: Report spills as required to appropriate authorities such as the local Environmental Health Officer or Fire Brigade. If spills are likely to enter any drain, waterway or groundwater, contact the Area Water Authority. Procedures if material is released or spilled: Contain and absorb on fire retardant treated sawdust, diatomaceous earth, etc. Shovel up and dispose of at an appropriate licensed waste disposal site in accordance with current applicable laws and regulations and product characteristics at time of disposal. Environmental precautions: Prevent spills from entering storm sewers or drains and contact with soil. Personal precautions: See Section 8. 7. HANDLING AND STORAGE Handling: No special precautions are necessary beyond normal good hygiene practices. See Section 8 for additional personal protection advice when handling this product. Chemical Names and Synonyms: Pet. Hydrocarbons and Additives Use: Open gear and slide lubricant. Note: This product should not be used for any other purpose without expert advice. COSHH Regulations: Product reviewed and no action under COSHH considered necessary. Note: JCB Lubricant products are not formulated to contain PCBS. It is believed that all the information given in this bulletin (which supersedes all previous issues) is accurate at the time of printing. Such information is offered in good faith but without guarantee and without any representation that the product concerned is suitable for any particular use or application. Without limitation of the foregoing, nothing herein shall be construed as a recommendation for uses which infringe valid patents or as extending any licence under valid patents. JCB pursues a policy of constant research and development aimed at product improvement and, therefore, reserves the right to change formulation, specification and characteristics of its products without notice. User should verify current specifications with JCB and ascertain that products are suitable for intended uses or applications. Where the information provided herein discloses a potential hazard or hazardous ingredient, adequate warning must be provided to employees and users and appropriate precautions taken, including the practice of good industrial hygiene. contact JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 * Note: Items marked with an asterisk (*) have been amended since last issue. 619122-63/08.08.95` 9804/8944 ISSUE 3 (REV.), NOVEMBER 1997 Ingredients considered hazardous to health This product is not hazardous to health as defined by the EC Dangerous Substances/Preparations Directives. See Section 15 for a regulatory analysis of the ingredients. Effects of overexposure: No significant effects expected. 4. FIRST-AID MEASURES Eye Contact: Flush thoroughly with water. If irritation occurs, call a doctor. Skin Contact: Wash contact areas with soap and water. High pressure accidental injection through the skin requires IMMEDIATE medical attention for possible incision, irrigation and/or debridement. Inhalation: Not expected to be a problem. Ingestion: Not expected to be a problem. However, if greater than 1/2 litre (pint) is ingested or if feeling uncomfortable, give 1 or 2 glasses of water and obtain medical attention or call an ambulance for assistance. DO NOT INDUCE VOMITING or give anything by mouth to an unconscious person. 9804/8944 ISSUE 3 (REV.), NOVEMBER 1997 5. FIRE-FIGHTING MEASURES Extinguishing Media: Carbon dioxide, foam, dry chemical and water fog. Special fire fighting procedures: Water or foam may cause frothing. Use water to keep fire exposed containers cool. Water spray may be used to flush spills away from exposures. Prevent runoff from fire control or dilution from entering waterways or drinking water supply. Special Protective Equipment: For fires in enclosed areas, firefighters MUST use self-contained breathing apparatus. Unusual fire and explosion hazards: None. Flash Point °C(°F): >204 (400) (IP 34/ASTM D-93) Flammable Limits: LEL NA. UEL NA. NFPA Hazard ID: Health: 0 Flammability: 1 Reactivity: 0 Hazardous decomposition products: Carbon monoxide. Metal oxides. Elemental oxides. 6. ACCIDENTAL RELEASE MEASURES Notification procedures: Report spills as required to appropriate authorities such as the local Environmental Health Officer or Fire Brigade. If spills are likely to enter any drain, waterway or groundwater, contact the Area Water Authority. In case of accident or road spill, contact the Police and Fire Brigade and, if appropriate, the Area Water Authority. Procedures if material is released or spilled: Shovel up and dispose of at an appropriate licensed waste disposal site in accordance with current applicable laws and regulations and product characteristics at time of disposal. Environmental Precautions Prevent spills from entering storm sewers or drains and contact with soil. Personal precautions: See Section 8. 7. HANDLING AND STORAGE Handling: High pressure injection under the skin may occur due to the rupture of pressurised lines. Always seek medical attention. Chemical Names and Synonyms: Severe Treat Min. Oils & Additives Use: Extreme pressure grease. Note: This product should not be used for any other purpose without expert advice. COSHH Regulations: Product reviewed and no action under COSHH considered necessary. Note: JCB Lubricant products are not formulated to contain PCBS. It is believed that all the information given in this bulletin (which supersedes all previous issues) is accurate at the time of printing. Such information is offered in good faith but without guarantee and without any representation that the product concerned is suitable for any particular use or application. Without limitation of the foregoing, nothing herein shall be construed as a recommendation for uses which infringe valid patents or as extending any licence under valid patents. JCB pursues a policy of constant research and development aimed at product improvement and, therefore, reserves the right to change formulation, specification and characteristics of its products without notice. User should verify current specifications with JCB and ascertain that products are suitable for intended uses or applications. Where the information provided herein discloses a potential hazard or hazardous ingredient, adequate warning must be provided to employees and users and appropriate precautions taken, including the practice of good industrial hygiene. contact JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 * Note: Items marked with an asterisk (*) have been amended since last issue. 539130-63/03.08.95 9804/8903 ISSUE 4, (REV.) NOVEMBER 1997 Ingredients considered Hazardous to Health: This product is not hazardous to health as defined by the EC Dangerous Substances/Preparations Directives. See Section 15 for a regulatory analysis of the ingredients. Effects of Overexposure: No Significant effects expected. 4. FIRST-AID MEASURES Eye Contact: Flush thoroughly with water. If irritation occurs, call a doctor. Skin Contact: Wash contact areas with soap and water. High pressure accidental injection through the skin requires IMMEDIATE medical attention for possible incision, irrigation and/or debridement. Inhalation: Not expected to be a problem. Ingestion: Not expected to be a problem. However, if greater than 1/2 litre (pint) is ingested or if feeling uncomfortable, give 1 to 2 glasses of water and obtain medical attention or call an ambulance for assistance. DO NOT INDUCE VOMITING or give anything by mouth to an unconscious person. 9804/8903 ISSUE 4, (REV.) NOVEMBER 1997 5. FIRE-FIGHTING MEASURES Extinguising Media: Carbon dioxide, foam, dry chemical and water fog. Special Fire Fighting Procedures: Water or foam may cause frothing. Use water to keep fire exposed containers cool. Water spray may be used to flush spills away from exposures. Prevent runoff from fire control or dilution from entering waterways or drinking water supply. Special Protective Equipment: For fires in enclosed areas, firefighters MUST use self-contained breathing apparatus. Unusual Fire and Explosion Hazards: None. Flash Point > 204 °C (400 °F) (Estimated (Oil COC)). Flammable Limits LEL NA, UEL NA NFPA Hazard ID: Health 0, Flammability 1, Reactivity 0 Hazardous Decomposition Products: Carbon Monoxide. 6. ACCIDENTAL RELEASE MEASURES Notification Procedures: Report spills as required to appropriate authorities such as the local Environmental Health Officer or Fire Brigade. If spills are likely to enter any drain, waterway or groundwater, contact the Area Water Authority. In case of accident or road spill, contact the Police and Fire Brigade and, if appropriate, the Area Water Authority. Procedures if Material is Released or Spilled: Shovel up and dispose of at an appropriate licensed waste dispostal site in accordance with current applicable laws and regulations and product characteristics at time of disposal. Environmental Precautions: Prevent spills from entering storm sewers or drains and contact with soil. Personal Precautions: See Section 8. 7. HANDLING AND STORAGE Handling: No special precautions are necessary beyond normal good hygiene practices. See Section 8 for additional personal protection advice when handling this product. Chemical Names and Synonyms: Severe treat min. oils & additives. Use: Automotive grease. Note: This product should not be used for any other purpose without expert advice. COSHH Regulations: Product reviewed and no action under COSHH considered necessary. Note: JCB products are not formulated to contain PCBS. It is believed that all the information given in this bulletin (which supersedes all previous issues) is accurate at the time of printing. Such information is offered in good faith but without guarantee and without any representation that the product concerned is suitable for any use or application. Without limitation of the foregoing, nothing herein shall be construed as a recommendation for uses which infringe valid patents or as extending any licence under valid patents. JCB pursues a policy of constant research and development aimed at product improvement and, therefore, reserves the right to change formulation, specification and characteristics of its products without notice. User should verify current specifications with JCB and ascertain that products are suitable for intended uses and applications. Where the information provided herein discloses a potential hazard or hazardous ingredient, adequate warning must be provided to employees and users and appropriate precautions taken, including the practice of good industrial hygiene. contact JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 * Note: Items marked with an asterisk (*) have been amended since last issue. MOBIL/539064-63/15.06.95 9804/8931 ISSUE 3 (REV.), JUNE 2002 Preparation: Hazardous Components Component: Min % Max % EEC Classification 0.00100.00 No constituents need to be specified Main Hazards: Not classified as hazardous. Product Use: For industrial use only. Lubricant. MSDS first issued: 06.05.96 Revision Date: National legislation EC Legislation: EC Directive 91/155/EEC defining the laying down and detailed arrangements for the system of specific information relating to dangerous preparations. EC Directive 88/397/EEC relating to the classification, packaging and labelling of dangerous preparations. contact JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 9804/8970 ISSUE 3, (REV.) NOVEMBER 1997 Ingredients considered Hazardous to Health: This product is not hazardous to health as defined by the EC Dangerous Substances/Preparations Directives. See Section 15 for a regulatory analysis of the ingredients. Effects of Overexposure: No Significant effects expected. 4. FIRST-AID MEASURES Eye Contact: Flush thoroughly with water. If irritation occurs, call a doctor. Skin Contact: Wash contact areas with soap and water. High pressure accidental injection through the skin requires IMMEDIATE medical attention for possible incision, irrigation and/or debridement. Inhalation: Not expected to be a problem. Ingestion: Not expected to be a problem. However, if greater than 1/2 litre (pint) is ingested or if feeling uncomfortable, give 1 to 2 glasses of water and obtain medical attention or call an ambulance for assistance. DO NOT INDUCE VOMITING or give anything by mouth to an unconscious person. 9804/8970 ISSUE 3, (REV.) NOVEMBER 1997 5. FIRE-FIGHTING MEASURES Extinguishing Media: Carbon dioxide, foam, dry chemical and water fog. Special Fire Fighting Procedures: Water or foam may cause frothing. Use water to keep fire exposed containers cool. Water spray may be used to flush spills away from exposures. Prevent runoff from fire control or dilution from entering waterways or drinking water supply. Special Protective Equipment: For fires in enclosed areas, firefighters MUST use self-contained breathing apparatus. Unusual Fire and Explosion Hazards: None. Flash Point > 204 °C (400 °F) (IP 34/ASTM D-93). Flammable Limits LEL NA, UEL NA NFPA Hazard ID: Health 0, Flammability 1, Reactivity 0 Hazardous Decomposition Products: Carbon Monoxide, Metal Oxides, Elemental Oxides. 6. ACCIDENTAL RELEASE MEASURES Notification Procedures: Report spills as required to appropriate authorities such as the local Environmental Health Officer or Fire Brigade. If spills are likely to enter any drain, waterway or groundwater, contact the Area Water Authority. In case of accident or road spill, contact the Police and Fire Brigade and, if appropriate, the Area Water Authority. Procedures if Material is Released or Spilled: Shovel up and dispose of at an appropriate licensed waste disposal site in accordance with current applicable laws and regulations and product characteristics at time of disposal. Environmental Precautions: Prevent spills from entering storm sewers or drains and contact with soil. Personal Precautions: See Section 8. 7. HANDLING AND STORAGE Handling: High pressure injection under the skin may occur due to the rupture of pressurised lines. Always seek medical attention. Chemical Names and Synonyms: Pet hydrocarbons and additives. Use: General purpose grease. Note: This product should not be used for any other purpose without expert advice. COSHH Regulations: Product reviewed and no action under COSHH considered necessary. Note: JCB products are not formulated to contain PCBS. It is believed that all the information given in this bulletin (which supersedes all previous issues) is accurate at the time of printing. Such information is offered in good faith but without guarantee and without any representation that the product concerned is suitable for any use or application. Without limitation of the foregoing, nothing herein shall be construed as a recommendation for uses which infringe valid patents or as extending any licence under valid patents. JCB pursues a policy of constant research and development aimed at product improvement and, therefore, reserves the right to change formulation, specification and characteristics of its products without notice. User should verify current specifications with JCB and ascertain that products are suitable for intended uses and applications. Where the information provided herein discloses a potential hazard or hazardous ingredient, adequate warning must be provided to employees and users and appropriate precautions taken, including the practice of good industrial hygiene. contact JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 * Note: Items marked with an asterisk (*) have been amended since last issue. MOBIL/28.08.94 9804/8894 ISSUE 3 (REV.), NOVEMBER 1997 Hazardous Components in Product for EC Component Name Concentration Product Use For industrial use only. Lubricant. MSDS first issued 18 June 1996 Revision Date: 24 February 1997 National Legislation EC Legislation EC Directive 88/379/EEC relating to the classification, packaging and labelling of dangerous preparations. EC Directive 91/155/EEC defining the laying down and detailed arrangements for the system of specific information relating to dangerous preparations. EC Directive 94/1/EC adapting some technicalities of Council Directive 75/324/EEC on the approximation of the laws of Member States relating to aerosol dispensers. UK Guidance Publications EH40, Occupational Exposure Limits, HSE. Revised Annually. CHIP 96 page (xvi) Note 4 para 3 - reference application of the aspiration hazard (R65) to aerosols. To the best of our knowledge, the information contained herein is accurate. Although certain hazards may be described we cannot predict that these are the only hazards, or combination of hazards, that may exist in a workplace. This MSDS, therefore, forms a component only of a risk assessment carried out by, or on behalf of, the user. Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 * Note: Items marked with an asterisk (*) have been amended since last issue. 22001 5.00 GB Current/24.02.97 9804/8993 ISSUE 4, MARCH 2003 JCB Engine Oil HP 15W40 Grades: SAE 10W-30, 15W-40 Use: Lubricating oil for automotive engines Severely solvent refined mineral oil (appr. 92%) Additives (appr. 8%), mainly: Zinc alkyldithiophosphate Calcium/magnesium sulphonates & phenates Hydrocarbon polymers CONCAWE report no. 5/87 ‘health aspect of lubricants’. It is believed that all the information given in this bulletin (which supersedes all previous issues) is accurate at the time of printing. Such information is offered in good faith but without guarantee and without any representation that the product concerned is suitable for any use or application. Without limitation of the foregoing, nothing herein shall be construed as a recommendation for uses which infringe valid patents or as extending any license under valid patents. JCB pursues a policy of constant research and development aimed at product improvement and, therefore, reserves the right to change formulation, specification and characteristics of its products without notice. User should verify current specifications with JCB and ascertain that products are suitable for intended uses and applications. Where the information provided herein discloses a potential hazard or hazardous ingredient, adequate warning must be provided to employees and users and appropriate precautions taken, including the practice of good industrial hygiene. Further Information contact: JCB SERVICE WORLD PARTS CENTRE UTTOXETER STAFFORDSHIRE ST14 5BS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 593624 * Note: Items marked with an asterisk (*) have been amended since last issue. Q8 T 500/1995-04-27 9804/8994 ISSUE 2, JULY 2000 regulation 6 of the Chemicals (Hazard Information and Packaging for Supply) Regulations 1994 (CHIP 2) (and other related directives) and provides information relating to the safe handling and use of the product. This leaflet must be read in conjunction with the Product Safety Notice (9804/8889). Ensure your dealer provides you with a copy of the Notice with this leaflet. Health Emergency and Customer Service Telephone: Contact '()&*/0123/&4/56&"788%&9%"$7 & Application: 4;&</&=>/?&@>&@&>=AA5/B/CD@5&@CD2E>F=@GH&@I/CD&2C&'()&G/D&<0@H/&@J5/>&K255/?&G2DL&M;<25K5=2?& !::& ;0&M;<25K5=2?&!:!N& & Ingredients considered Hazardous to Health: Substance Name Wt% EU Classification O;CI&(L@2C&P5H/CQ5&RL;>AL2D/&7""&S2T,$8& Notes: +(&*QB<;5U>VT&S2&.002D@CDN& Characteristics: Physical Description Test Method Typical Result *A/32K23&W0@12DQ&X&79NY&Z(&P*4M&[7:%8&"N%7& (;5;=0&P*4M&[79""&:N"& 2>3;>2DQ&X&!"&Z(\&3*D&P*4M&[!!9& N"& -2>3;>2DQ&X&7""&Z(\&3*D&P*4M&[!!9&9N!& ]@D/0\&^&P*4M&[%9&"N7&B@J& _5@>L&R;2CD\&Z(&P*4M&[%$&7Y9& R;=0&R;2CD\&Z(&P*4M&[%`&"& 4;D@5&P32?&a=B</0\&BI&bcd Chemical Names and Synonyms: O;CI&3L@2C&@5H/CQ5&AL;>AL2D/N& Use: 40@3D;0&;25&@??2D21/N& Note: 4L2>&A0;?=3D&>L;=5?&C;D&</&=>/?&K;0&@CQ&;DL/0&A=0A;>/&G2DL;=D&/JA/0D&@?123/N& Note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f>/0& >L;=5?&1/02KQ&3=00/CD&>A/32K23@D2;C>&G2DL&'()&@C?&@>3/0D@2C&DL@D&A0;?=3D>&@0/&>=2D@<5/&K;0&2CD/C?/?&=>/>&@C?& @AA523@D2;C>N& ]L/0/&DL/&2CK;0B@D2;C&A0;12?/?&L/0/2C&?2>35;>/>&@&A;D/CD2@5&L@e@0?&;0&L@e@0?;=>&2CI0/?2/CD\&@?/F=@D/&G@0C2CI& B=>D&</&A0;12?/?&D;&/BA5;Q//>&@C?&=>/0>&@C?&@AA0;A02@D/&A0/3@=D2;C>&D@H/C\&2C35=?2CI&DL/&A0@3D23/&;K&I;;?& 2C?=>D02@5&LQI2/C/N& & _=0DL/0&.CK;0B@D2;C&3;CD@3D6& JCB SERVICE WORLD PARTS CENTRE UTTOXETER STAFFORDSHIRE ST14 5BS TEL: + 44 (0) 1889 590 312 FAX: + 44 (0) 1889 593 624 9804/8895 ISSUE 3 (REV.), NOVEMBER 1997 Ingredient Name: White spirit Cas No. 64742-88-7 User notes: Disclaimer: The information given in this document has been completed on the basis of the best available knowledge. It does not imply that the information is complete or accurate in all cases. It is the user’s responsibility to satisfy themselves to the application of the information and/or recommendations given for their own particular use. This Material Safety Data Sheet has been prepared in accordance with EEC Directive 91/155/EEC. NA = Not Applicable. N/D = Not Determined. Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 * Note: Items marked with an asterisk (*) have been amended since last issue. DD-MM-YY/04.07.98 9804/8963 ISS. 1 SEPT. 89 your dealer provides you with a copy of the Notice with this leaflet. PRODUCT – ROCOL J166 ANTI SEIZE Part No(s) : 4003/0211 Supplier : ROCOL Ltd. Chemical names & synonyms : Organically modified clay thickened solvent refined mineral oil containing blend of solid lubricants imparting anti-seize properties. Intended use : Prevention of seizure of threaded components. NOTE: THIS PRODUCT SHOULD NOT BE USED FOR OTHER PURPOSES WITHOUT EXPERT ADVICE. PHYSICAL PROPERTIES Appearance : Dark copper grease Melting point : NA Odour : Little or none Pour point : NA pH : NA Boiling point : NA Viscosity : NA Relative density : 1.3 Flash point : >200 °C Solubility : Insoluble Vapour pressure : NA HEALTH HAZARD DATA Effects of over exposure : Causes irritation to eyes. Excessive contact with skin may lead to dermatitis. If swal- lowed may cause nausea. Occupational exposure limit : NA SPECIAL PROTECTION INFORMATION Eye protection : Avoid contact with eyes, wear safety glasses if eye contact may occur. Skin protection : Use barrier cream if skin contact cannot be avoided. Respiratory protection : No special equipment, adequate ventilation required. Ventilation : Adequate ventilation required. EMERGENCY & FIRST AID PROCEDURES Eye contact : Rinse immediately with plenty of water. SEEK MEDICAL ADVICE. Skin contact : Wash contact area with soap and water, apply moisturising hand cream. Inhalation : Remove to fresh air. Ingestion : Do not indice vomiting. SEEK MEDICAL ADVICE. FIRE & EXPLOSION HAZARD DATA Flash point : >200 °C IP Classification : Unclassified Flammable limits : LEL NA UEL NA Extinguishing media : CO2, Powder, Foam Special fire fighting procedures: None. 9804/8963 9804/8963 ISS. 1 SEPT. 89 REACTIVITY DATA Stability (thermal, light, etc.) : Stable. Conditions to avoid : Extreme heat. Incompatibility (materials to avoid) : Strong oxidising agents. Hazardous decomposition products : Carbon and oxides of carbon. Copper compounds. Hazard polymerisation : NA SPILLAGE LEAKAGE AND WASTE DISPOSAL PROCEDURES Environmental impact : Report spills as required to appropriate authorities. Procedures if material is released or spilled : Wipe up with rags. Remove residue with a detergent cleaner immediately. Waste disposal : Product can be disposed of at licensed site. Users must comply with current applicable laws and regulations. ADDITIONAL HANDLING AND STORAGE INFORMATION Recommended storage temperatures between 0 °C - 40 °C. TOXICOLOGICAL DATA Oral toxicity : May cause nausea. Dermal toxicity : May cause dematitis if excessive contact. Inhalation toxicity : NA Eye irritation : Causes irritation. Skin irritation : Causes irritation. SUBCHRONIC TOXICOLOGY (SUMMARY) : NA CHRONIC TOXICOLOGY (SUMMARY) : NA OTHER TOXICOLOGY DATA : NA REGULATORY INFORMATION CONCAWE report no. 5/87 ‘health aspect of lubricants’. It is believed that all the information given in this bulletin (which supersedes all previous issues) is accurate at the time of printing. Such information is offered in good faith but without guarantee and without any representation that the product concerned is suitable for any use or application. Without limitation of the foregoing, nothing herein shall be construed as a recommendation for uses which infringe valid patents or as extending any license under valid patents. JCB pursues a policy of constant research and development aimed at product improvement and, therefore, reserves the right to change formulation, specification and characteristics of its products without notice. User should verify current specifications with JCB and ascertain that products are suitable for intended uses and applications. Where the information provided herein discloses a potential hazard or hazardous ingredient, adequate warning must be provided to employees and users and appropriate precautions taken, including the practice of good industrial hygiene. Further Information contact: JCB SERVICE WORLD PARTS CENTRE UTTOXETER STAFFORDSHIRE ST14 5BS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 593624 * Note: Items marked with an asterisk (*) have been amended since last issue. Q8 T 1000/1995-05-01 9804/9000 ISSUE 2, (REV) SEPTEMBER 2002 COMPONENT EC NUMBER CONCENTRATION EC SYMBOL FULL TEXT OF RISK PHRASES FOR INGREDIENTS INDICATED IN SECTION 2: Methacrylic acid R35 - Causes severe burns. R21/22 - Harmful in contact with skin and if swallowed. Cumene hydroperoxide R7 - May cause fire. R21/22 - Harmful in contact with skin and if swallowed. R48/20/22 - Harmful: danger of serious damage to health by prolonged exposure through inhalation and if swallowed. R23 - Toxic by inhalation. R34 - Causes burns. R37 - Irritating to respiratory system. R51/53 - Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. N,N-Dimethyl-p-toluidine R23/24/25 - Toxic by inhalation, in contact with skin and if swallowed. R33 - Danger of cumulative effects. R52/53 - Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Directives 1999/45/EC and 91/155/EEC have been considered when compiling this SDS; the information is provided for health and safety assessment by an industrial user. Reference should be made to any relevant local or national health, safety, and environmental legislation. This information does not constitute indication of suitability for specific uses. Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 Note: Items marked with an asterisk (*) have been amended since last issue. 9804/9003 ISSUE 2, (REV) SEPTEMBER 2002 Component EC Number Concentration EEC Symbol/Risk Phrases Ethyl 2-cyanoacrylate 230-391-5 >50% XI R36/37/38 For full text of risk phrases, please refer to section 16. Emergency Overview: IRRITANT Eye: On contact, will bond eyelids together. Vapours are lachrymatory. Will cause eye irritation. Skin Contact: On contact, immediate bonding of the skin will occur. Irritating to the skin. Inhalation: Vapour may be irritant to the respiratory tract. Ingestion: On contact, immediate bonding of mouth could occur. Physico-Chemical: No unusual hazards are expected. Environmental: Unknown. *4. FIRST-AID MEASURES Eye: Get medical attention immediately. Flush with large amounts of water while holding eyelids open. Cured adhesive will not bond well to surface of eye, but corneal damage from abrasion may result. Skin Contact: Immediate medical attention is not required. No attempt should be made tom remove material from skin or to remove contaminated clothing, as the bonded skin can be easily torn. If symptoms develop, obtain medical attention. Inhalation: Immediate medical attention is not required. Remove to fresh air. Get medical attention if irritation persists. Ingestion: Obtain immediate medical attention. Treat symptomatically and supportively. 9804/9003 ISSUE 2, (REV) SEPTEMBER 2002 FULL TEXT OF RISK PHRASES FOR INGREDIENTS INDICATED IN SECTION 2: Ethyl-2-cyanoacrylate R36/37/38 - Irritating to eyes, respiratory system and skin. Directives 1999/45/EC and 91/155/EEC have been considered when compiling this SDS; the information is provided for health and safety assessment by an industrial user. Reference should be made to any relevant local or national health, safety, and environmental legislation. This information does not constitute indication of suitability for specific uses. Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 Note: Items marked with an asterisk (*) have been amended since last issue. 9804/8892 ISSUE 4*, OCTOBER 2001 JCB Four Seasons Antifreeze and Summer Coolant Supplier: JCB SERVICE, ROCESTER, STAFFS. ST14 5LS Tel: +44 (0) 1889 590312 Chemical Name and/or family or description: Antifreeze and coolant for engines Name % Wt CAS NO. EC No. Ethylene glycol 90 - 97 107-21-1 203-473-3 Xn R22 Harmful is swallowed Water and additives 3 - 10 CBI * Warning Statement HARMFUL IS SWALLOWED. MAY ENTER AND CAUSE DAMAGE IF SWALLOWED. MAY CAUSE DIZZINESS AND DROWSINESS. Acute Effects of Exposure to Man Inhalation: Vapours or mist, in excess of permissible concentrations, or in unusually high concentrations generated from spraying, heating the material or from exposure in poorly ventilated areas or confined spaces, may cause irritation of the nose and throat, headache, nausea, and drowsiness. Skin contact: Brief contact may cause slight irritation. Prolonged contact, as with clothing wetted with material, may cause more severe irritation and discomfort, seen as local redness and swelling. Eye contact: May cause irritation, experienced as mild discomfort and seen as slight excess redness of the eye. Continued............ 9804/8892 ISSUE 4*, OCTOBER 2001 Acute or chronic oral consumption of products containing ethylene glycol can produce significant adverse health effects, including death, in humans and animals. Keep out of reach of children. Such products should not be used in potable (drinking) water systems or other systems where contamination or potable water supplies is possible (e.g. recreational vehicles, winterising potable water systems). Do not decant into unlabelled containers. The information given in the document has been compiled on the basis of best available knowledge in accordance with the requirements of the Chemical Hazards Information and Pack Regulations 1993. It does not imply that the information is complete or accurate in all cases. It is the users responsibility to satisfy themselves as to the application of the information and/or the recommendations given for their own use. Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 * Note: Items marked with an asterisk (*) have been amended since last issue. 9804/9018 ISSUE 1, March 2001 1. IDENTIFICATION OF SUBSTANCE/COMPANY: JCB Part No(s): 993/99166 PRODUCT NAME: LIQUID MAINTENANCE INTENDED USE: Multi-Purpose Lubricant which will penetrate and release rusty/jammed fixings. Displaces water and moisture from vehicle ignition systems and aids starting and smoothrunning. Cleans all metals and removes bloom from enamel surfaces. Degreases and leaves an anti-rust protective film. Does not conduct electricity within the normal range found in home or industry. Does not contain Silicone or CFC’s. Perfect formulation for all around the workshop /garage/factory. Formulation approved by Jaguar Cars Limited, JCB, Audi Volkswagen, British Gas. 2. MANUFACTURER: SUPPLIER: Action Can Ltd., Dixon Close, Old Boston Trading Estate, Haydock, St. Helens, Merseyside, WA11 9SF. Tel 01942 713667. Fax 01942 716235 Emergency Tel: 01704 821314 3. INFORMATION ON INGREDIENTS/COMPOSITION AC-90 ALL VARIANTS: INGREDIENTS: CAS NO. HEALTH RISK (Class) (R No) Mineral Oils None White Spirit 64742-88-7 None Butane 106-97-8 None Propane 74-98-6 None Eye Contact:Product may cause eye irritation if product comes into physical contact with eyes. Skin Contact:Slight skin irritant. Prolonged or repeated contact may cause drying or defatting of skin. 9804/9018 ISSUE 1, March 2001 Inhalation: High levels of vapour/mist may cause dizziness. Can cause irritation of the respiratory tract. Ingestion: Accidental ingestion is an unlikely event. 5. FIRST-AID MEASURES Eye Contact: Contact lenses should be removed. Irrigate copiously with clean, fresh water for at least 10 minutes, holding the eyelids apart. Seek medical advice. Skin Contact: Remove contaminated clothing. Wash skin thoroughly with soap and water or use a proprietary skin cleaner Inhalation: Remove to fresh air, keep the patient warm and at rest. If breathing is irregular or hasstopped, administer artificial respiration. Give nothing by mouth. If unconscious, place in the recovery position and seek medical advice. Ingestion: If accidentally swallowed, obtain immediate medical attention. Keep at rest. DONOT INDUCE VOMITTING. 6. FIRE-FIGHTING MEASURES Extinguising Media: Alcohol resistant foam/CO2/powder/water spray/mist.DONOT USE WATER JET. Special Fire Fighting Procedures: Fire exposed containers should be sprayed with water to lessen risk of explosion. Unusual Fire and Explosion Hazards: Fire will produce dense black smoke containing combustion products which may be a health hazard. Appropriate self-contained breathing apparatus may be required. RUN OFF FROM FIRE MUST NOT ENTER DRAINS. 7. ACCIDENTAL RELEASE MEASURES Procedures for leaks or spillage: Exclude sources of ignition and ventilate the area. Exclude non-essential personnel. Avoid breathing vapours. Refer to protective measures listed in Sections 7 and 8. Contain and collect spillages with non-combustible absorbent materials e.g. sand, earth, vermiculite, diatomaceous earth and place in a suitable container for disposal in accordance with waste regulations (see Section 3). DO NOT ALLOW TO ENTER DRAINS OR WATER COURSES. Clean preferably with a detergent; avoid the use of solvents.If the product enters drains or sewers, the local water company should be contacted immediately, or in the case of contamination of streams, rivers or lakes, the National Rivers Authority. 8. HANDLING AND STORAGE Handling: Vapours are heavier than air and may spread along floors. They may form explosive mixtures with air. Prevent the creation of flammable or explosive concentrations of vapour in air and avoid vapour concentrations higher than the occupational exposure limits. DO NOT USE ON AN ENGINE WHILST IT IS RUNNING. Use only in areas from which all sources of heat, sparks and open flame have been excluded. Avoid skin and eye contact. 9804/9018 ISSUE 1, March 2001 Avoid inhalation of vapour and spray mist. Smoking, eating and drinking should be prohihited in areas of use and storage. READ DIRECTIONS FOR USE PRINTED ON EACH UNIT OF USE. The information contained in this data sheet is provided in accordance with the requirements of the Chemicals (Hazard Information and Packaging)Regulations. It does not constitute the users own assessment of work-place risks as required by other health and safety legislation. The provisions of the Health and Safety at Work, etc. Act and the Control of Substances Hazardous toHealth Regulations apply to the use of this product at work. The product should not be used purposes other than those shown in Section 1 wihout first referring to the supplier and obtaining written handling instructions. As the specific conditions of the product are outside the suppliers control, the user is responsible for ensuring that the requirements of the relevant legilation are complied with. OES/MEL values are obtained from the current issue of EH40 unless indicated thus (Sup) when a value has been obtained from the supplier. FURTHER INFORMATION AND ADVICE CAN BE FOUND IN THE FOLLOWING PUBLICATIONS: THE CONTROL OF SUBSTANCES HAZARDOUS TO HEALTH REGULATIONS 1988(SI 1988: 1657) STORAGE OF PACKAGED DANGEROUS SUBSTANCES HS(G)71 THE ENVIRONMENTAL PROTECTION (DUTY OF CARE) REGULATIONS 1992 (SI 1992 : 2839) THE HIGHLY FLAMMABLE LIQUIDS AND LIQUIFIED PETROLEUM GASES REGULATIONS 1972 (SI 1972 : 917) STORAGE OF FLAMMABLE LIQUIDS IN CONTAINERS HS(G)51 THIS PRODUCT SHOULD BE STORED, HANDLED AND USED IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE PRACTICES AND IN CONFORMITY WITH LEGAL REGULATIONS. THE INFORMATION CONTAINED HEREIN IS BASED ON THE CURRENT STATE OF OUR KNOWLEDGE AND IS INTENDED TO DESCRIBE PRODUCTS FROM THE POINT OF VIEW OF SAFETY REQUIREMENTS ANDTHUS SHOULD NOT BE CONSTRUED AS GUARANTEEING SPECIFIC PROPERTIES.FOR FURTHER INFORMATION CONTACT THE OFFICE, TELEPHONE 01942 713667. Action Can Ltd. 9804/8941 ISSUE 4, (REV.) SEPTEMBER 2001 Emergency Contact : Emergency Telephone No.: +44 (0) 1922 745845 2. COMPOSITION/INFORMATION ON INGREDIENTS Contents amongst other ingredients. Substance Index No. % w/w Hazard Class.tn Sodium hydroxide 011 002 00 6 0.1-0.5 C, R35 NTA not listed 1.0-5.0 Xi, R36 Amphoteric detergent not listed 1.0-5.0 Xi, R36, 38 Cationic detergent not listed 1.0-5.0 Xi, R36, 53 Nonionic detergent not listed 1.0-5.0 Xn, R22, 36/38 1-methoxy-2-propanol not listed 0.5-2.0 F, R10 Preparation is alkaline. It is considered to be of relatively low hazard provided that good standards of industrial hygiene and working practice are maintained. Repeated contact can cause irritation to eyes and skin. 9804/8941 ISSUE 4, (REV.) SEPTEMBER 2001 This product is not designed to be used in its neat form. No other usage is recommended unless advised in writing by JCB Services. This safety data sheet is distributed solely of the purpose of the Health and Safety at Work Act 1974; included under this heading is article 10 of Directive 88/379/EEC. It does not constitute any warranty or guarantee as to the quality properties condition or otherwise of the product. It has been prepared from the best knowledge available to us and we shall not be liable for any insufficiency or inaccuracy in such information in any case whatsoever. Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 TECHTRON/TEM689/30.01.96 9804/9018 ISSUE 1, March 2001 1. IDENTIFICATION OF SUBSTANCE/COMPANY: JCB Part No(s): 993/99166 PRODUCT NAME: LIQUID MAINTENANCE INTENDED USE: Multi-Purpose Lubricant which will penetrate and release rusty/jammed fixings. Displaces water and moisture from vehicle ignition systems and aids starting and smoothrunning. Cleans all metals and removes bloom from enamel surfaces. Degreases and leaves an anti-rust protective film. Does not conduct electricity within the normal range found in home or industry. Does not contain Silicone or CFC’s. Perfect formulation for all around the workshop /garage/factory. Formulation approved by Jaguar Cars Limited, JCB, Audi Volkswagen, British Gas. 2. MANUFACTURER: SUPPLIER: Action Can Ltd., Dixon Close, Old Boston Trading Estate, Haydock, St. Helens, Merseyside, WA11 9SF. Tel 01942 713667. Fax 01942 716235 Emergency Tel: 01704 821314 3. INFORMATION ON INGREDIENTS/COMPOSITION AC-90 ALL VARIANTS: INGREDIENTS: CAS NO. HEALTH RISK (Class) (R No) Mineral Oils None White Spirit 64742-88-7 None Butane 106-97-8 None Propane 74-98-6 None Eye Contact:Product may cause eye irritation if product comes into physical contact with eyes. Skin Contact:Slight skin irritant. Prolonged or repeated contact may cause drying or defatting of skin. 9804/9018 ISSUE 1, March 2001 The information contained in this data sheet is provided in accordance with the requirements of the Chemicals (Hazard Information and Packaging) Regulations. It does not constitute the users own assessment of work-place risks as required by other health and safety legislation. The provisions of the Health and Safety at Work, etc. Act and the Control of Substances Hazardous toHealth Regulations apply to the use of this product at work. The product should not be used purposes other than those shown in Section 1 wihout first referring to the supplier and obtaining written handling instructions. As the specific conditions of the product are outside the suppliers control, the user is responsible for ensuring that the requirements of the relevant legilation are complied with. OES/MEL values are obtained from the current issue of EH40 unless indicated thus (Sup) when a value has been obtained from the supplier. FURTHER INFORMATION AND ADVICE CAN BE FOUND IN THE FOLLOWING PUBLICATIONS: THE CONTROL OF SUBSTANCES HAZARDOUS TO HEALTH REGULATIONS 1988(SI 1988: 1657) STORAGE OF PACKAGED DANGEROUS SUBSTANCES HS(G)71 THE ENVIRONMENTAL PROTECTION (DUTY OF CARE) REGULATIONS 1992 (SI 1992 : 2839) THE HIGHLY FLAMMABLE LIQUIDS AND LIQUIFIED PETROLEUM GASES REGULATIONS 1972 (SI 1972 : 917) STORAGE OF FLAMMABLE LIQUIDS IN CONTAINERS HS(G)51 THIS PRODUCT SHOULD BE STORED, HANDLED AND USED IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE PRACTICES AND IN CONFORMITY WITH LEGAL REGULATIONS. THE INFORMATION CONTAINED HEREIN IS BASED ON THE CURRENT STATE OF OUR KNOWLEDGE AND IS INTENDED TO DESCRIBE PRODUCTS FROM THE POINT OF VIEW OF SAFETY REQUIREMENTS ANDTHUS SHOULD NOT BE CONSTRUED AS GUARANTEEING SPECIFIC PROPERTIES.FOR FURTHER INFORMATION CONTACT THE OFFICE, TELEPHONE 01942 713667. Action Can Ltd. 9804/8962 ISSUE 3, NOVEMBER 1997 Emergency Contact : Emergency Telephone No.: +44 (0) 1889 590312 2. COMPOSITION/INFORMATION ON INGREDIENTS Composition: Mixture silicones, silica filler and cross-linking agents. Reactive ingredient: methyl tri-acetoxysilane <5% Small quantities of acetic acid are released during the cure reaction with atmospheric moisture. Uncured product may irritate skin and eyes. DP 2205 is not classified hazardous according to the CHIP Regulations1. Inhalation: Exposure to acetic acid fumes may cause slight irritation of eyes and upper respiratory tract. Skin: Frequent/prolonged contact with uncured product may cause irritation or dermatitis. Eyes: Uncured product is moderately irritating to eyes. Ingestion: Possible irritation of mouth and throat. Product will solidify internally on reaction with moisture. 9804/8962 ISSUE 3, NOVEMBER 1997 4. FIRST-AID MEASURES Inhalation: Move to fresh air. Seek medical advice if symptoms persist. Skin Contact: Wash from skin with soap and water. Obtain medical advice if skin irritation persists. Eye Contact: Flush immediately with plenty of water or saline eye wash solution and continue rinsing for ten minutes. Obtain medical attention if irritation persists. Ingestion: Clear material from mouth and throat and slowly drink glass water. Do not induce vomiting. Obtain immediate medical advice. 5. FIRE-FIGHTING MEASURES Extinguishing Media: No restrictions if product is involved in a fire. Special Precautions: Wear breathing equipment if large stocks are involved in a fire. Combustion Products: Silica released during combustion. 6. ACCIDENTAL RELEASE MEASURES Scrape up or absorb with sand and transfer to container for disposal. See also Section 13. 7. HANDLING AND STORAGE Personal Precautions: Respiratory: Ensure work area is well ventilated to disperse traces of acetic acid which are released as product cures. Skin: Avoid skin contact with uncured product - wear gloves if necessary. Eyes: Avoid contact. Wear safety spectacles as standard precaution. See Section 8: Exposure Controls/Personal Protection. Fire Precautions: Use: No special precautions. This information is accurate to the best of knowledge of Dunlop Adhesives and is given on the understanding that the product will be used in accordance with any instructions given with the product. Should any use be contemplated outside these instructions then appropriate advice should be sought. Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 * Note: Items marked with an asterisk (*) have been amended since last issue. DUNLOP/DP 2205 Sealant/October 1994 9804/8976 ISSUE 3, (REV.) NOVEMBER 1997 JCB Active Wipe MSDS first issued: 17.11.94 Revision Date: Revisions Highlighted: Future revisions will incorporate such information as is required but which is not available at this time. Footnote: This information is given in good faith and based on information believed to be reliable. This document is not a specification and properties shown are not guaranteed. National Legislation UK Legislation: Health and Safety at Work etc. Act, 1974, and relevant Statutory Provisions. SI 1993/1746: Chemicals (Hazard Information and Packaging) Regulations, 1993. SI 1972/917: Highly Flammable Liquids & LPG Regs. SI No 2839 1991 Environmental Protection (Duty of Care) Regulations. Petroleum (Consolidation) Act, 1928 and associated legislation. SI 1988/1657: The Control of Substances Hazardous to Health Regulations. UK Guidance Publications: EH40, Occupational Exposure Limits, HSE. Revised Annually. HS(G) 53, Respiratory Protective Equipment - a Practical Guide for Users, HSE. Guide to Highly Flammable Liquids & LPG Regulations - H&SE. Hydrocarbon Solvents - A Guide to Safe Handling (Solvent Industries Association). cont’d 9804/8976 ISSUE 3, (REV.) NOVEMBER 1997 Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 * Note: Items marked with an asterisk (*) have been amended since last issue. SIKA/SKP205 1.00 GB/17.11.94 9804/8977 ISSUE 2, (REV.) NOVEMBER 1996 Telephone: 0115 944 0129 2. COMPOSITION/INFORMATION ON INGREDIENTS Ingredient Listing: JCB Pure Hand Cleaner is a proprietary blend of Citrus Oil (CAS 5989-27-5), water, blended organic emulsifiers and surfacants and pumice (CAS 1332-09-8). Those components for which there is no CAS reference are proprietary to the raw material manufacturer. Letters of assurance are on file from these manufacturers stating that their components are listed in the U.S. EPA TSCA inventory. Index No known hazards 4. FIRST-AID MEASURES Eye Contact: Direct eye contact will result in irritation, flush with water. If irritation persists, consult a doctor. Ingestion: While this material is non-toxic, ingestion of excessive amounts may cause stomach upset. Drink large amounts of milk or other mild liquid. Consult a doctor should complications arise. 9804/8977 ISSUE 2, (REV.) NOVEMBER 1996 5. FIRE-FIGHTING MEASURES Flammable Limits: Not determined, considered a minimal hazard. Extinguishing Media: Dry chemical, CO2, Universal Foam or water. Unusual Fire and Explosion Hazards: None - difficult to ignite. 6. ACCIDENTAL RELEASE MEASURES Small Spills: Wipe up product, rinse soiled area with water down the drain. 7. HANDLING AND STORAGE Precaution to be taken in handling and storage to extend shelf life: Always store unused portion in original container with cap secure. Avoid temperature extremes. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Respiratory Protection: Not required. Ventilation: Not required. Protective Gloves: Not required. Eye Protection: Avoid direct contact. Other Protective Equipment. Not required. 9. PHYSICAL AND CHEMICAL PROPERTIES Approximate Boiling Point: 200 - 300 ¡F. Vapour Pressure: 41 mm of Hg @ 25 ¡C. Vapour Density (Air = 1): 0.8 Solubility in Water: Emulsifies Specific Gravity (H2O = 1): 0.84 at 25 ¡C Percent Volatile by Volume: 75% Evaporation Rate (H2O = 1): 1 pH: 8.0 - 8.7 The purpose of this statement is to assure all users and distributors of P & K Industries Citrus based products that the hazards of all ÔchemicalsÕ (products) used in the manufacturing of these products have been evaluated and that no known hazards have been found to exist. Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 P&K Industries 9804/9004 ISSUE 2, (REV) SEPTEMBER 2002 Chemical Family: Methacrylate Ester Component EC Number Concentration Ranges EEC Symbol/Risk Phrases Isopropanol 200-661-7 20 - 35 F XI R11 R36 R67 Ethyl acetate 205-500-4 20 - 35 F XI R11 R36 R66 R67 Pentane 203-692-4 20 - 35 F+ N T R12 R51 R53 R45 R65 For full text of risk phrases, please refer to Section 16. EMERGENCY OVERVIEW IRRITANT HARMFUL EXTREMELY FLAMMABLE DANGEROUS FOR THE ENVIRONMENT Eye: May cause eye irritation. Skin Contact: Repeated or prolonged contact may cause defatting of the skin resulting in dryness, cracking and dermatitis. Inhalation: Vapours may cause drowsiness and dizziness. Ingestion: Aspiration of the product into the lungs following ingestion may cause pulmonary injury leading to pneumonitis. Physico-Chemical: May readily catch fire after brief contact with source of ignition. Environmental: Harmful to aquatic organisms. Not readily biodegradable. 9804/9004 ISSUE 2, (REV) SEPTEMBER 2002 FULL TEXT OF RISK PHRASES FOR INGREDIENTS INDICATED IN SECTION 2: Isopropanol R11 - Highly flammable. R36 - Irritating to eyes. R67 - Vapours may cause drowsiness and dizziness. Ethyl acetate R11 - Highly flammable. R36 - Irritating to eyes. R66 - Repeated exposure may cause skin dryness or cracking. R67 - Vapours may cause drowsiness and dizziness. Pentane R12 - Extremely flammable. R51 - Toxic to aquatic organisms. R53 - May cause long-term adverse effects in the aquatic environment. R45 - May cause cancer. R65 - Harmful: may cause lung damage if swallowed. Directives 1999/45/EC and 91/155/EEC have been considered when compiling this SDS; the information is provided for health and safety assessment by an industrial user. Reference should be made to any relevant local or national health, safety, and environmental legislation. This information does not constitute indication of suitability for specific uses. Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 Note: Items marked with an asterisk (*) have been amended since last issue. 9804/8951 ISSUE 2 (REV.), APRIL 1997 Emergency Contact : Emergency Telephone No.: +44 (0) 1889 590312 2. COMPOSITION/INFORMATION ON INGREDIENTS Ingredient Name CAS No. Health Risk The information in this data sheet is provided in accordance with the requirements of the Chemicals (Hazard Information and Packaging) Regulations. It does not constitute the user’s own assessment of workplace risks as required by other health and safety legislation. The provisions of the Health & Safety at Work etc. Act and the Control of Substances Hazardous to Health Regulations apply to the use of this product at work. The product should not be used for purposes other than those shown in Section 1 without first referring to the supplier and obtaining written handling instructions. As the specific conditions of the product are outside the supplier’s control, the user is responsible for ensuring that the requirements of relevant legislation are complied with. OES/MEL values are obtained from the current issue of EH40 unless indicated thus (Sup) when a value has been obtained from the supplier. Further information and advice can be found in the following publications:- The Control of Substances Hazardous to Health Regulations 1988 (SI 1988 : 1657) Storage of Packaged Dangerous Substances, HS(G)71 The Environmental Protection (Duty of Care) Regulations 1992 (SI 1992 : 2839) The Highly Flammable Liquids and Liquified Petroleum Gases Regulations 1972 (SI 1972:917) Storage of Flammable Liquids in Containers, HS(G)51 This product should be stored, handled and used in accordance with good industrial hygiene practices and in conformity with legal regulations. The information contained herein is based on the current state of our knowledge and is intended to describe products from the point of view of safety requirements and thus should not be construed as guaranteeing specific properties. Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 SDS:01010000/4/27.01.97 9804/8952 ISSUE 2 (REV.), APRIL 1997 Emergency Contact : Emergency Telephone No.: +44 (0) 1889 590312 2. COMPOSITION/INFORMATION ON INGREDIENTS Ingredient Name CAS No. Health Risk The information contained in this data sheet is provided in accordance with the requirements of the Chemicals (Hazard Information and Packaging) Regulations. It does not constitute the user’s own assessment of workplace risks as required by other health and safety legislation. The provisions of the Health & Safety at Work etc. Act and the Control of Substances Hazardous to Health Regulations apply to the use of this product at work. The product should not be used for purposes other than those shown in Section 1 without first referring to the supplier and obtaining written handling instructions. As the specific conditions of the product are outside the supplier’s control, the user is responsible for ensuring that the requirements of relevant legislation are complied with. OES/MEL values are obtained from the current issue of EH40 unless indicated thus (Sup) when a value has been obtained from the supplier. Further information and advice can be found in the following publications:- The Control of Substances Hazardous to Health Regulations 1988 (SI 1988 : 1657) The Environmental Protection (Duty of Care) Regulations 1992 (SI 1992 : 2839) Storage of Packaged Dangerous Substances, HS(G)71 The Highly Flammable Liquids and Liquified Petroleum Gases Regulations 1972 (SI 1972:917) Storage of Flammable Liquids in Containers, HS(G)51 This product should be stored, handled and used in accordance with good industrial hygiene practices and in conformity with legal regulations. The information contained herein is based on the current state of our knowledge and is intended to describe products from the point of view of safety requirements and thus should not be construed as guaranteeing specific properties. Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 SDS:01020000/2/29.01.97 9804/8953 ISSUE 2 (REV.), APRIL 1997 Emergency Contact : Emergency Telephone No.: +44 (0) 1889 590312 2. COMPOSITION/INFORMATION ON INGREDIENTS Ingredient Name CAS No. Health Risk The information contained in this data sheet is provided in accordance with the requirements of the Chemicals (Hazard Information and Packaging) Regulations. It does not constitute the user’s own assessment of workplace risks as required by other health and safety legislation. The provisions of the Health & Safety at Work etc. Act and the Control of Substances Hazardous to Health Regulations apply to the use of this product at work. The product should not be used for purposes other than those shown in Section 1 without first referring to the supplier and obtaining written handling instructions. As the specific conditions of the product are outside the supplier’s control, the user is responsible for ensuring that the requirements of relevant legislation are complied with. OES/MEL values are obtained from the current issue of EH40 unless indicated thus (Sup) when a value has been obtained from the supplier. Further information and advice can be found in the following publications:- The Control of Substances Hazardous to Health Regulations 1988 (SI 1988 : 1657) Storage of Packaged Dangerous Substances, HS(G)71 The Environmental Protection (Duty of Care) Regulations 1992 (SI 1992 : 2839) The Highly Flammable Liquids and Liquified Petroleum Gases Regulations 1972 (SI 1972:917) Storage of Flammable Liquids in Containers, HS(G)51 This product should be stored, handled and used in accordance with good industrial hygiene practices and in conformity with legal regulations. The information contained herein is based on the current state of our knowledge and is intended to describe products from the point of view of safety requirements and thus should not be construed as guaranteeing specific properties. Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 SDS:01010000/4/27.01.97 9804/8954 ISSUE 2 (REV.), APRIL 1997 Emergency Contact : Emergency Telephone No.: +44 (0) 1889 590312 2. COMPOSITION/INFORMATION ON INGREDIENTS Ingredient Name CAS No. Health Risk The information contained in this data sheet is provided in accordance with the requirements of the Chemicals (Hazard Information and Packaging) Regulations. It does not constitute the user’s own assessment of workplace risks as required by other health and safety legislation. The provisions of the Health & Safety at Work etc. Act and the Control of Substances Hazardous to Health Regulations apply to the use of this product at work. The product should not be used for purposes other than those shown in Section 1 without first referring to the supplier and obtaining written handling instructions. As the specific conditions of the product are outside the supplier’s control, the user is responsible for ensuring that the requirements of relevant legislation are complied with. OES/MEL values are obtained from the current issue of EH40 unless indicated thus (Sup) when a value has been obtained from the supplier). Further information and advice can be found in the following publications:- The Control of Substances Hazardous to Health Regulations 1988 (SI 1988 : 1657) Storage of Packaged Dangerous Substances, HS(G)71 The Environmental Protection (Duty of Care) Regulations 1992 (SI 1992 : 2839) The Highly Flammable Liquids and Liquified Petroleum Gases Regulations 1972 (SI 1972:917) Storage of Flammable Liquids in Containers, HS(G)51 This product should be stored, handled and used in accordance with good industrial hygiene practices and in conformity with legal regulations. The information contained herein is based on the current state of our knowledge and is intended to describe products from the point of view of safety requirements and thus should not be construed as guaranteeing specific properties. Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 SDS:01010000/4/27.01.97 9804/8978 ISSUE 2, (REV.) MARCH 1997 SUMITOMO YELLOW TOPCOAT Intended Use: Air drying paint/lacquer for industrial use only. Application by spray when mixed with recommended thinner. Emergency Telephone No.: +44 (0) 1889 590312 2. COMPOSITION/INFORMATION ON INGREDIENTS A mixture of resins, pigments, mineral extenders and organic solvents as required. For details of substances presenting a health hazard within the meaning of the Chemicals (Hazard Information & Packing) regulations 1994 see under Section 8 of this Safety Data Sheet. Inhalation of vapours from this product can cause narcosis and, with continued exposure above the OEL, possible long term effects. Highly flammable - Harmful by inhalation, in contact with skin and may cause lung damage if swallowed - Irritating to eyes, respiratory system and skin. 4. FIRST-AID MEASURES General: In all cases of doubt or when symptoms persist seek medical attention. Never give anything by mouth to an unconscious person. Inhalation: Remove to fresh air, keep warm and at rest. If breathing is irregular or stopped give artificial respiration. Give nothing by mouth. If unconscious place in recovery position and seek medical advice. Eye Contact: Contact lenses should be removed. Irrigate copiously with clean, fresh water for at least 10 mins. holding the eyelids apart, seek medical advice. Skin Contact: Remove contaminated clothing. Wash skin thoroughly with soap and water or use a proprietary skin cleaner. Do NOT use solvents or thinners. Ingestion If accidentally swallowed obtain immediate medical attention. Keep at rest. Do NOT induce vomiting. 9804/8978 ISSUE 2, (REV.) MARCH 1997 5. FIRE-FIGHTING MEASURES Extinguishing Media: Carbon dioxide, Dry Powder, Sand, Foam. Not to be used: Water Special instructions for Fire Fighting Personnel: Fire will produce dense black smoke containing hazardous products of combustion (see Section 10). Decomposition products may be a hazard to health. Appropriate self-contained breathing apparatus may be required. Cool closed containers exposed to fire with a water spray. Do not allow run off from fire fighting to enter drains or water courses. 6. ACCIDENTAL RELEASE MEASURES Exclude sources of ignition and ventilate the area. Exclude non-essential personnel. Avoid breathing vapours. Refer to protective measures listed in sect. 7&8. Contain and collect spillages with non-combustible absorbent materials e.g. sand, earth and place in suitable container for disposal in accordance with the waste regulations. Do not allow to enter drains or water courses. If it does the local water company should be contacted immediately, in case of contamination of streams, rivers or lakes the Environmental Agency. Clean preferably with a detergent, avoid use of solvents. 7. HANDLING AND STORAGE Vapours are heavier than air and may spread along floors. They may form explosive mixtures with air. Prevent creation of explosive or flammable mixtures and avoid vapour concs higher than the OEL. Do not use in areas where potential sources of ignition exist. Electrical equipment should be protected to the appropriate standard. Use non sparking tools and exclude sources of heat, sparks and flames. Keep container tightly closed. Never use pressure to empty, container is not a pressure vessel. Always keep in containers made of the same material as the supply container. Avoid skin and eye contact. For personal protection see Sect. 8. Good housekeeping and regular removal of waste materials will minimise risks. The product may charge electrostatically. Use earthing leads when transferring from one container to another. Wear anti-static footwear and clothing and floors should be electrically conductive. Store in accordance with the conditions of the licence which is necessary under the Petroleum (Consolidation) Act. See the HSE guidance note Storage of Flammable Liquids in Containers. Observe the label precautions. Store between 5 and 25°C in a dry well ventilated place away from sources of heat, ignition and direct sunlight. No smoking. Prevent unauthorised access. Containers which are opened should be properly resealed and kept upright to prevent leakage. Store away from oxidising agents and strongly alkaline or acid materials.The principles contained in the HSE’s guidance note Storage of Packaged Dangerous substances should be observed when storing this product. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering measures Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. If extraction methods are insufficient to maintain concentrations of particulates and/or solvent vapours below relevant OEL’s, suitable respiratory protective equipment should be worn. Substance Name % Conc Range Symbol OES 8hr ppm OES 15min ppm Text of any Risk Phrases listed in Section 8 R10 Flammable R11 Highly flammable R20 Harmful by inhalation R20/21 Harmful by inhalation and in contact with skin R36 Irritating to the eyes R36/37/38 Irritating to eyes, respiratory system and skin. R65 Harmful: may cause lung damage if swallowed The information contained in this safety data sheet is provided in accordance with the requirements of the Chemicals (Hazard Information & Packaging) Regulations. The product should not be used for purposes other than those shown in Section 1 without first referring to the supplier and obtaining written handling instructions. As the specific conditions of use of the product are outside the supplier’s control the user is responsible for ensuring that requirements of the relevant legislation are complied with. TP-02 cont’d 9804/8978 ISSUE 2, (REV.) MARCH 1997 The information contained in this Safety Data Sheet is based on the present state of knowledge and current national legislation. It provides guidance on health, safety and environmental aspects of the product and should not be construed as any guarantee of technical performance or suitability for particular applications. Further information and relevant advice can be found in:- The Control Of Substances Hazardous to Health Regulations 1988 (SI 1988: 1657) The Manual Handling Operations Regulations 1992 (SI 1992: 2793) Storage of Flammable Liquids in Containers. HS(G)51 Storage of Packaged Dangerous Substances. HS(G)71 The Environmental Protection (Duty of Care) Regulations 1992 (SI 1988: 2839) Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 CARRS/E9265/28.02.97 9804/8979 ISSUE 2, (REV.) MARCH 1997 No relevant information. For details of substances presenting a health hazard within the meaning of the Chemicals (Hazard Information & Packing) regulations 1994 see under Section 8 of this Safety Data Sheet. Inhalation of vapours from this product can cause narcosis and, with continued exposure above the OEL, possible long term effects. Flammable - Harmful by inhalation and in contact with skin - Irritating to eyes, respiratory system and skin. - Harmful: may cause lung damage if swallowed. 4. FIRST-AID MEASURES General: In all cases of doubt or when symptoms persist seek medical attention. Never give anything by mouth to an unconscious person. Inhalation: Remove to fresh air, keep warm and at rest. If breathing is irregular or stopped give artificial respiration. Give nothing by mouth. If unconscious place in recovery position and seek medical advice. Eye Contact: Contact lenses should be removed. Irrigate copiously with clean, fresh water for at least 10 mins. holding the eyelids apart, seek medical advice. Skin Contact: Remove contaminated clothing. Wash skin thoroughly with soap and water or use a proprietary skin cleaner. Do NOT use solvents or thinners. Ingestion If accidentally swallowed obtain immediate medical attention. Keep at rest. Do NOT induce vomiting. 9804/8979 ISSUE 2, (REV.) MARCH 1997 5. FIRE-FIGHTING MEASURES Extinguishing Media: Carbon dioxide, Dry Powder, Sand, Foam. Not to be used: Water Special instructions for Fire Fighting Personnel: Fire will produce dense black smoke containing hazardous products of combustion (see Section 10). Decomposition products may be a hazard to health. Appropriate self-contained breathing apparatus may be required. Cool closed containers exposed to fire with a water spray. Do not allow run off from fire fighting to enter drains or water courses. 6. ACCIDENTAL RELEASE MEASURES Exclude sources of ignition and ventilate the area. Exclude non-essential personnel. Avoid breathing vapours. Refer to protective measures listed in sect. 7&8. Contain and collect spillages with non-combustible absorbent materials e.g. sand, earth and place in suitable container for disposal in accordance with the waste regulations. Do not allow to enter drains or water courses. If it does the local water company should be contacted immediately, in case of contamination of streams, rivers or lakes the Environmental Agency. Clean preferably with a detergent, avoid use of solvents. 7. HANDLING AND STORAGE Do not use in areas where potential sources of ignition exist. Use non sparking tools and exclude sources of heat, sparks and flames. Keep container tightly closed. Never use pressure to empty, container is not a pressure vessel. Always keep in containers made of the same material as the supply container. Avoid skin and eye contact. For personal protection see Sect.8. Good housekeeping and regular removal of waste materials will minimise risks. Observe the label precautions. Store between 5 and 25°C in a dry well ventilated place away from sources of heat, ignition and direct sunlight. No smoking. Prevent unauthorised access. Containers which are opened should be properly resealed and kept upright to prevent leakage. Store away from oxidising agents and strongly alkaline or acid materials. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering measures Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. If extraction methods are insufficient to maintain concentrations of particulates and/or solvent vapours below relevant OEL’s, suitable respiratory protective equipment should be worn. Substance Name % Conc Range Symbol OES 8hr ppm OES 15min ppm Text of any Risk Phrases listed in Section 8 R10 Flammable R11 Highly flammable R20 Harmful by inhalation R20/21 Harmful by inhalation and in contact with skin R36 Irritating to the eyes R36/37/38 Irritating to eyes, respiratory system and skin. R65 Harmful: may cause lung damage if swallowed cont’d 9804/8979 ISSUE 2, (REV.) MARCH 1997 The information contained in this safety data sheet is provided in accordance with the requirements of the Chemicals (Hazard Information & Packaging) Regulations. The product should not be used for purposes other than those shown in Section 1 without first referring to the supplier and obtaining written handling instructions. As the specific conditions of use of the product are outside the supplier’s control the user is responsible for ensuring that requirements of relevant legislation are complied with. The information contained in this Safety Data Sheet is based on the present state of knowledge and current national legislation. It provides guidance on health, safety and environmental aspects of the product and should not be construed as any guarantee of technical performance or suitability for particular applications. Further information and relevant advice can be found in:- The Control Of Substances Hazardous to Health Regulations 1988 (SI 1988: 1657) The Manual Handling Operations Regulations 1992 (SI 1992: 2793) Storage of Flammable Liquids in Containers. HS(G)51 Storage of Packaged Dangerous Substances. HS(G)71 The Environmental Protection (Duty of Care) Regulations 1992 (SI 1988: 2839) Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 CARRS/E9277/28.02.97 9804/8980 ISSUE 2, (REV.) MARCH 1997 No relevant information. For details of substances presenting a health hazard within the meaning of the Chemicals (Hazard Information & Packing) regulations 1994 see under Section 8 of this Safety Data Sheet. Inhalation of vapours from this product can cause narcosis and, with continued exposure above the OEL, possible long term effects. Flammable - Harmful by inhalation and in contact with skin - Irritating to eyes, respiratory system and skin. - Harmful: may cause lung damage if swallowed. 4. FIRST-AID MEASURES General: In all cases of doubt or when symptoms persist seek medical attention. Never give anything by mouth to an unconscious person. Inhalation: Remove to fresh air, keep warm and at rest. If breathing is irregular or stopped give artificial respiration. Give nothing by mouth. If unconscious place in recovery position and seek medical advice. Eye Contact: Contact lenses should be removed. Irrigate copiously with clean, fresh water for at least 10 mins. holding the eyelids apart, seek medical advice. Skin Contact: Remove contaminated clothing. Wash skin thoroughly with soap and water or use a proprietary skin cleaner. Do NOT use solvents or thinners. Ingestion If accidentally swallowed obtain immediate medical attention. Keep at rest. Do NOT induce vomiting. 9804/8980 ISSUE 2, (REV.) MARCH 1997 5. FIRE-FIGHTING MEASURES Extinguishing Media: Carbon dioxide, Dry Powder, Sand, Foam. Not to be used: Water Special instructions for Fire Fighting Personnel: Fire will produce dense black smoke containing hazardous products of combustion (see Section 10). Decomposition products may be a hazard to health. Appropriate self-contained breathing apparatus may be required. Cool closed containers exposed to fire with a water spray. Do not allow run off from fire fighting to enter drains or water courses. 6. ACCIDENTAL RELEASE MEASURES Exclude sources of ignition and ventilate the area. Exclude non-essential personnel. Avoid breathing vapours. Refer to protective measures listed in sect. 7&8. Contain and collect spillages with non-combustible absorbent materials e.g. sand, earth and place in suitable container for disposal in accordance with the waste regulations. Do not allow to enter drains or water courses. If it does the local water company should be contacted immediately, in case of contamination of streams, rivers or lakes the Environmental Agency. Clean preferably with a detergent, avoid use of solvents. 7. HANDLING AND STORAGE Do not use in areas where potential sources of ignition exist. Use non sparking tools and exclude sources of heat, sparks and flames. Keep container tightly closed. Never use pressure to empty, container is not a pressure vessel. Always keep in containers made of the same material as the supply container. Avoid skin and eye contact. For personal protection see Sect.8. Good housekeeping and regular removal of waste materials will minimise risks. Observe the label precautions. Store between 5 and 25°C in a dry well ventilated place away from sources of heat, ignition and direct sunlight. No smoking. Prevent unauthorised access. Containers which are opened should be properly resealed and kept upright to prevent leakage. Store away from oxidising agents and strongly alkaline or acid materials. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering measures Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. If extraction methods are insufficient to maintain concentrations of particulates and/or solvent vapours below relevant OEL’s, suitable respiratory protective equipment should be worn. Substance Name % Conc Range Symbol OES 8hr ppm OES 15min ppm Risk Phrases Notation Higher Aromatics >30% & = <40% Xn,, 50.00 20/21-36/37/38-65-10 OES Shella, Solvesso 100 Solvesso 100/Aromatic >1% & = <5% Xn, 50.00 36/37/38-20/21/65-10 OES 100/Shellsola/Aromasoln P-mentha-1, 8(9)-Diene >1% & = <5% Xi, 38-10 Notes Notations = Sk - risk of absorption through skin Sen - respiratory sensitiser. OES = Occupational Exposure Standard MEL = Maximum Exposure Limit OEL’s are from EH40 except where marked SUP which are assigned by the supplier of the substance. General Protection All ppe, including rpe, used to control exposure to hazardous substances must be selected to meet the requirements of the COSHH regulations. cont’d 9804/8980 ISSUE 2, (REV.) MARCH 1997 Respiratory Protection Air fed respiratory equipment should be worn when spraying if levels cannot be controlled below OELs and engineering methods cannot be reasonably improved. Hand Protection Full physical protection is best. Seek relevant advice from glove manufacturers. Barrier cream may be of help but should not be applied after exposure has occurred. Eye Protection Eye protection designed to protect against liquid splashes should be worn. Skin Protection Cotton or cotton/synthetic overalls or coveralls are normally suitable. Grossly contaminated clothing should be removed and the skin washed with soap and water or a proprietary skin cleaner. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Flash Point: ≥ 21°C & ≤ 55°C Method Equilibrium Method to ISO 1516 & ISO 3680. Viscosity: Specific Gravity: 1.233 gms/cc Method Calculation Vapour Density: HEAVIER than Air Lower Explosion Limit: .8% Vol. Solubility In Water: PARTIALLY MISCIBLE 10. STABILITY AND REACTIVITY Stable under the recommended storage and handling conditions (see Sect.7). In a fire, hazardous decomposition products such as smoke, carbon monoxide, carbon dioxide, and oxides of nitrogen may be produced. Keep away from oxidising agents and strongly alkaline and acid materials to prevent the possibility of an exothermic reaction. Text of any Risk Phrases listed in Section 8 R10 Flammable R20/21 Harmful by inhalation and in contact with skin R20/21/65 Harmful by inhalation, in contact with skin and may cause lung damage if swallowed R36/37/38 Irritating to eyes, respiratory system and skin. R38 Irritating to the skin R65 Harmful: may cause lung damage if swallowed 9804/8980 ISSUE 2, (REV.) MARCH 1997 The information contained in this safety data sheet is provided in accordance with the requirements of the Chemicals (Hazard Information & Packaging) Regulations. The product should not be used for purposes other than those shown in Section 1 without first referring to the supplier and obtaining written handling instructions. As the specific conditions of use of the product are outside the supplier’s control the user is responsible for ensuring that requirements of relevant legislation are complied with. The information contained in this Safety Data Sheet is based on the present state of knowledge and current national legislation. It provides guidance on health, safety and environmental aspects of the product and should not be construed as any guarantee of technical performance or suitability for particular applications. Further information and relevant advice can be found in:- The Control Of Substances Hazardous to Health Regulations 1988 (SI 1988: 1657) The Manual Handling Operations Regulations 1992 (SI 1992: 2793) Storage of Flammable Liquids in Containers. HS(G)51 Storage of Packaged Dangerous Substances. HS(G)71 The Environmental Protection (Duty of Care) Regulations 1992 (SI 1988: 2839) Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 CARRS/E9234/28.02.97 9804/8981 ISSUE 2, (REV.) MARCH 1997 A mixture of organic solvents. For details of substances presenting a health hazard within the meaning of the Chemicals (Hazard Information & Packing) regulations 1994 see under Section 8 of this Safety Data Sheet. Inhalation of vapours from this product can cause narcosis and, with continued exposure above the OEL, possible long term effects. Flammable - Harmful by inhalation and in contact with skin - Irritating to eyes, respiratory system and skin. - Harmful: may cause lung damage if swallowed. 4. FIRST-AID MEASURES General: In all cases of doubt or when symptoms persist seek medical attention. Never give anything by mouth to an unconscious person. Inhalation: Remove to fresh air, keep warm and at rest. If breathing is irregular or stopped give artificial respiration. Give nothing by mouth. If unconscious place in recovery position and seek medical advice. Eye Contact: Contact lenses should be removed. Irrigate copiously with clean, fresh water for at least 10 mins. holding the eyelids apart, seek medical advice. Skin Contact: Remove contaminated clothing. Wash skin thoroughly with soap and water or use a proprietary skin cleaner. Do NOT use solvents or thinners. Ingestion If accidentally swallowed obtain immediate medical attention. Keep at rest. Do NOT induce vomiting. 9804/8981 ISSUE 2, (REV.) MARCH 1997 5. FIRE-FIGHTING MEASURES Extinguishing Media: Carbon dioxide, Dry Powder, Sand, Foam. Not to be used: Water Special instructions for Fire Fighting Personnel: Fire will produce dense black smoke containing hazardous products of combustion (see Section 10). Decomposition products may be a hazard to health. Appropriate self-contained breathing apparatus may be required. Cool closed containers exposed to fire with a water spray. Do not allow run off from fire fighting to enter drains or water courses. 6. ACCIDENTAL RELEASE MEASURES Exclude sources of ignition and ventilate the area. Exclude non-essential personnel. Avoid breathing vapours. Refer to protective measures listed in sect. 7&8. Contain and collect spillages with non-combustible absorbent materials e.g. sand, earth and place in suitable container for disposal in accordance with the waste regulations. Do not allow to enter drains or water courses. If it does the local water company should be contacted immediately, in case of contamination of streams, rivers or lakes the Environmental Agency. Clean preferably with a detergent, avoid use of solvents. 7. HANDLING AND STORAGE Vapours are heavier than air and may spread along floors. They may form explosive mixtures with air. Prevent creation of explosive or flammable mixtures and avoid vapour concs higher than the OEL. Do not use in areas where potential sources of ignition exist. Electrical equipment should be protected to the appropriate standard. Use non sparking tools and exclude sources of heat, sparks and flames. Keep container tightly closed. Never use pressure to empty, container is not a pressure vessel. Always keep in containers made of the same material as the supply container. Avoid skin and eye contact. For personal protection see Sect.8. Good housekeeping and regular removal of waste materials will minimise risks. The product may charge electrostatically, use earthing leads when transferring from one container to another. Wear anti-static footwear and clothing and floors should be electrically conductive. Store in accordance with the conditions of the licence which is necessary under the Petroleum (Consolidation) Act. See the HSE guidance note Storage of Flammable Liquids in Containers. Observe the label precautions. Store between 5 and 25°C in a dry well ventilated place away from sources of heat, ignition and direct sunlight. No smoking. Prevent unauthorised access. Containers which are opened should be properly resealed and kept upright to prevent leakage. Store away from oxidising agents and strongly alkaline or acid materials. The principles contained in the HSE’s guidance note Storage of Packaged Dangerous Substances should be observed when storing this product. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering measures Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. If extraction methods are insufficient to maintain concentrations of particulates and/or solvent vapours below relevant OEL’s, suitable respiratory protective equipment should be worn. Substance Name % Conc Range Text of any Risk Phrases listed in Section 8 R10 Flammable R20/21 Harmful by inhalation and in contact with skin R38 Irritating to the skin R65 Harmful: may cause lung damage if swallowed The information contained in this Safety Data Sheet is provided in accordance with the requirements of the Chemicals (Hazard Information & Packaging) Regulations. The product should not be used for purposes other than those shown in Section 1 without first referring to the supplier and obtaining written handling instructions. As the specific conditions of use of the product are outside the supplier’s control the user is responsible for ensuring that requirements of relevant legislation are complied with. The information contained in this Safety Data Sheet is based on the present state of knowledge and current national legislation. It provides guidance on health, safety and environmental aspects of the product and should not be construed as any guarantee of technical performance or suitability for particular applications. Further information and relevant advice can be found in:- The Control Of Substances Hazardous to Health Regulations 1988 (SI 1988: 1657) The Manual Handling Operations Regulations 1992 (SI 1992: 2793) Storage of Flammable Liquids in Containers. HS(G)51 Storage of Packaged Dangerous Substances. HS(G)71 The Environmental Protection (Duty of Care) Regulations 1992 (SI 1988: 2839) Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 CARRS/016/28.02.97 9804/8955 ISSUE 2 (REV.), APRIL 1997 Emergency Contact : Emergency Telephone No.: +44 (0) 1889 590312 2. COMPOSITION/INFORMATION ON INGREDIENTS Ingredient Name CAS No. Health Risk The information contained in this data sheet is provided in accordance with the requirements of the Chemicals (Hazard Information and Packaging) Regulations. It does not constitute the user’s own assessment of workplace risks as required by other health and safety legislation. The provisions of the Health & Safety at Work etc. Act and the Control of Substances Hazardous to Health Regulations apply to the use of this product at work. The product should not be used for purposes other than those shown in Section 1 without first referring to the supplier and obtaining written handling instructions. As the specific conditions of the product are outside the supplier’s control, the user is responsible for ensuring that the requirements of relevant legislation are complied with. OES/MEL values are obtained from the current issue of EH40 unless indicated thus (Sup) when a value has been obtained from the supplier). Further information and advice can be found in the following publications:- The Control of Substances Hazardous to Health Regulations 1988 (SI 1988 : 1657) Storage of Packaged Dangerous Substances, HS(G)71 The Environmental Protection (Duty of Care) Regulations 1992 (SI 1992 : 2839) The Highly Flammable Liquids and Liquified Petroleum Gases Regulations 1972 (SI 1972:917) Storage of Flammable Liquids in Containers, HS(G)51 This product should be stored, handled and used in accordance with good industrial hygiene practices and in conformity with legal regulations. The information contained herein is based on the current state of our knowledge and is intended to describe products from the point of view of safety requirements and thus should not be construed as guaranteeing specific properties. Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 SDS:01010000/4/27.01.97 9804/8926 ISSUE 5 (REV.), MARCH 2002 Emergency Contact : Emergency Telephone No.: +44 (0) 1889 590312 Description: A gloss finish for application by brush or spray. Based on an alkyd resin system with inorganic and/or organic pigments and containing white spirit solvent. Also, the following colours contain lead chromate pigment:- BS4800 04E53 - Red BS4800 14E53 - Emerald Green Yellow - R5007 Orange - R4961 RAL 2000 - Yellow Orange RAL 6018 - Yellow Green RAL 6029 - Mint Green Yellow - R4622 Yellow - R4806 * 2. COMPOSITION/INFORMATION ON INGREDIENTS The following ingredients have recognised health effects or exposure limits and are present in concentrations above the limits laid down in the Chemicals (Hazard Information and Packaging for Supply) Regulations 1994 (CHIP 2). For all colours except those listed in Section 1 as containing lead chromate:- Weight Risk CAS Substance in paint Full details of R-phrases are as follows:- R33 Danger of cumulative effects. R40 Possible risk of irreversible effects R61 May cause harm to the unborn child R62 Possible risk of impaired fertility R65 Harmful: may cause lung damage if swallowed Full details of the hazard classifications are as follows:- Carc. Cat. 3 Carcinogenic - Category 3 Repr. Cat. 1 Toxic for reproduction Category 1 Repr. Cat. 3 Toxic for reproduction Category 3 Further information about hazard classifications can be found in the Approved Guide to the Classification and Labelling of Substances and Preparations Dangerous for Supply. The information in this data sheet is provided in accordance with the requirements of the Chemicals (Hazard Information and Packaging for Supply) Regulations 1994. The product should not be used for purposes other than those shown in Section 1 without first referring to the supplier and obtaining written handling instructions. As the specific conditions of use are outside the supplier’s control, the user is responsible for ensuring that the requirements of relevant legislation are complied with. The information contained in this data sheet is based on the present state of knowledge and current national legislation. It provides guidance on health, safety and environmental aspects of the product and should not be construed as any guarantee of technical performance or suitability for particular applications. Further information and relevant advice can be found in:- The Chemicals (Hazard Information and Packaging for Supply) Regulations 1994 (SI 1994 : 3247) and amendments. Control of Lead at Work Regulations 1980 (SI 1998:543) Control of Substances Hazardous to Health Regulations 1999 (SI 1999 :437) Manual Handling Operations Regulations 1992 (SI 1992: 2793) Environmental Protection (Duty of Care) Regulations 1992 (SI 1992 : 2839) Occupational Exposure Limits, EH40 (revised annually) The storage of flammable liquids in containers, HS(G)51 Chemical warehousing: the Storage of Packaged Dangerous Substances, HS(G)71 The Approved Guide to the Classification and Labelling of Substances and Preparations Dangerous for Supply (Second Edition), L63 The Approved Supply List, L115 The Approved Code of Practice: Safety Data Sheets for Substances and Preparations Dangerous for Supply, L62 Special Waste Regulations 1996 (SI 1996:972) and amendments Cont..... 9804/8926 ISSUE 5 (REV.), MARCH 2002 Text of R Phrases listed in Section 2:- R No. Phrase T Toxic. R61 May cause harm to the unborn child. R40 Possible risk of irreversible effects. R33 Danger of cumulative effects. Repr. Cat. 1 Toxic to Reproduction Category 1 (see Section 2). Carc. Cat. 3 Carcinogen Category 3 (see Section 2). This product should not be used for purposes other than those shown in Section 1 without first referring to the supplier. The information contained in this Safety Data Sheet is based on the present state of knowledge and current national legislation. It provides guidance on health, safety and environmental aspects of the product and should not be construed as any guarantee of technical performance or suitability for particular applications. Further information and relevant advice can be found in:- The Control of Substances Hazardous to Health Regulations 1988 (SI 1988: 1657) The Highly Flammable Liquids & Liquified Petroleum Gases Regulations 1972 (SI 1972 917) The Manual Handling Operations Regulations 1992 (SI 1992: 2739) The Storage of Flammable Liquids in Containers HS(G)51 The Storage of Packaged Dangerous Substances HS(G)71 The Environmental Protection (Duty of Care) Regulations 1992 (SI 1992 : 283G) Surveillance of people exposed to Health Risks at Work (ISBN 0118833745) H.M.S.O. Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 ???? 9804/8918 ISSUE 4 (REV.), NOVEMBER 1997 Emergency Contact : Emergency Telephone No.: +44 (0) 1889 590312 Intended Use: Paint product for the decoration and protection of surfaces in the Commercial Vehicle, Plant and Building Industries. 2. COMPOSITION/INFORMATION ON INGREDIENTS Substances presenting a health hazard within the meaning of the Chemicals (Hazard Information and Packaging) Regulations 1993. Name Conc. range (%) Symbol Letter Text of R Phrases listed in Section 2:- R No. Phrase T Toxic. R61 May cause harm to the unborn child. R40 Possible risk of irreversible effects. R33 Danger of cumulative effects. Repr. Cat. 1 Toxic to Reproduction Category 1 (see Section 2). Carc. Cat. 3 Carcinogen Category 3 (see Section 2). This product should not be used for purposes other than those shown in Section 1 without first referring to the supplier. The information contained in this Safety Data Sheet is based on the present state of knowledge and current national legislation. It provides guidance on health, safety and environmental aspects of the product and should not be construed as any guarantee of technical performance or suitability for particular applications. Further information and relevant advice can be found in:- The Control of Substances Hazardous to Health Regulations 1988 (SI 1988: 1657) The Highly Flammable Liquids & Liquified Petroleum Gases Regulations 1972 (SI 1972 917) The Manual Handling Operations Regulations 1992 (SI 1992: 2739) The Storage of Flammable Liquids in Containers HS(G)51 The Storage of Packaged Dangerous Substances HS(G)71 The Environmental Protection (Duty of Care) Regulations 1992 (SI 1992 : 283G) Surveillance of people exposed to Health Risks at Work (ISBN 0118833745) H.M.S.O. Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 * Note: Items marked with an asterisk (*) have been amended since last issue. ???? 9804/8917 ISSUE 4 (REV.), NOVEMBER 1997 Emergency Contact : Emergency Telephone No.: +44 (0) 1889 590312 Intended Use: Paint product for the decoration and protection of surfaces in the Commercial Vehicle, Plant and Building Industries. 2. COMPOSITION/INFORMATION ON INGREDIENTS Substances presenting a health hazard within the meaning of the Chemicals (Hazard Information and Packaging) Regulations 1993. Name Conc. range (%) Symbol Letter Text of R Phrases listed in Section 2:- R No. Phrase T Toxic. R61 May cause harm to the unborn child. R40 Possible risk of irreversible effects. R33 Danger of cumulative effects. Repr. Cat. 1 Toxic to Reproduction Category 1 (see Section 2). Carc. Cat. 3 Carcinogen Category 3 (see Section 2). This product should not be used for purposes other than those shown in Section 1 without first referring to the supplier. The information contained in this Safety Data Sheet is based on the present state of knowledge and current national legislation. It provides guidance on health, safety and environmental aspects of the product and should not be construed as any guarantee of technical performance or suitability for particular applications. Further information and relevant advice can be found in:- The Control of Substances Hazardous to Health Regulations 1988 (SI 1988: 1657) The Highly Flammable Liquids & Liquified Petroleum Gases Regulations 1972 (SI 1972 917) The Manual Handling Operations Regulations 1992 (SI 1992: 2739) The Storage of Flammable Liquids in Containers HS(G)51 The Storage of Packaged Dangerous Substances HS(G)71 The Environmental Protection (Duty of Care) Regulations 1992 (SI 1992 : 283G) Surveillance of people exposed to Health Risks at Work (ISBN 0118833745) H.M.S.O. Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 * Note: Items marked with an asterisk (*) have been amended since last issue. 9804/8958 ISSUE 3 (REV.), FEB 2002 Emergency Contact : Emergency Telephone No.: +44 (0) 1889 590312 Description: A solvent cleanser/thinner based on white spirit. * 2. COMPOSITION/INFORMATION ON INGREDIENTS The following ingredients have recognised health effects or exposure limits, and are present in concentrations above the limits laid down in the Chemicals (Hazard Information and Packaging for Supply) Regulations 1994 (CHIP 2). Weight Risk CAS Substance in paint Full details of R-phrases are as follows:- R65 Harmful: may cause lung damage if swallowed The information in this data sheet is provided in accordance with the requirements of the Chemicals (Hazard Information and Packaging for Supply) Regulations 1994. The product should not be used for purposes other than those shown in Section 1 without first referring to the supplier and obtaining written handling instructions. As the specific conditions of use are outside the supplier’s control, the user is responsible for ensuring that the requirements of relevant legislation are complied with. The information contained in this data sheet is based on the present state of knowledge and current national legislation. It provides guidance on health, safety and environmental aspects of the product and should not be construed as any guarantee of technical performance or suitability for particular applications. Further information and relevant advice can be found in:- The Chemical (Hazard Information and Packaging for Supply) Regulations 1994 (SI 1994 : 3247) and amendments. Control of Substances Hazardous to Health Regulations 1999 (SI 1999 : 437) Manual Handling Operations Regulations 1992 (SI 1992 : 2793) Environmental Protection (Duty of Care) Regulations 1992 (SI 1992 : 2839) Occupational Exposure Limits, EH40 (revised annually) The storage of flammable liquids in containers, HS(G)51 Chemical warehousing: the storage of packaged dangerous substances, HS(G)71 The Approved Guide to the Classification and Labelling of Substances and Preparations Dangerous for Supply (Fourth Edition), L100 The Approved Supply List, L124 The Approved Code of Practice: Safety Data Sheets for Substances and Preparations Dangerous for Supply, L62 Special Waste Regulations 1996 (SI 1996:972) and amendments. The interpretation and use of flashpoint information, CS24. COSHH Essentials: easy steps to control chemicals, HS(G)193. Details of available Control Guidance Sheets, which may be relevant to the particular conditions of use, can also be found in HS(G)193. Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 Leigh’s/JCB Thinners No. 5/27/03/2001 9804/8920 ISSUE 5 (REV.), JUNE 2002 Emergency Contact : Emergency Telephone No.: +44 (0) 1889 590312 Intended Use: Paint product for the decoration and protection of surfaces in the Commercial Vehicle, Plant and Building Industries. 2. COMPOSITION/INFORMATION ON INGREDIENTS Substances presenting a health hazard within the meaning of the Chemicals (Hazard Information and Packaging) Regulations 1993. Name Conc. range (%) Symbol Letter Text of R Phrases listed in Section 2:- R No. Phrase NONE This product should not be used for purposes other than those shown in Section 1 without first referring to the supplier. The information contained in this Safety Data Sheet is based on the present state of knowledge and current national legislation. It provides guidance on health, safety and environmental aspects of the product and should not be construed as any guarantee of technical performance or suitability for particular applications. Further information can be found in:- The Highly Flammable Liquids & Liquified Petroleum Gases Regulations 1972 (SI 1972 917) The Manual Handling Operations Regulations 1992 (SI 1992 2739) The Storage of Flammable Liquids in Containers HS(G)51 The Storage of Packed Dangerous Substances HS(G)71 The Environmental Protection (Duty of Care) Regulations 1992 (SI 1992 283G) Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 * Note: Items marked with an asterisk (*) have been amended since last issue. E800/JULY 95 9804/8914 ISSUE 2 (REV.), MARCH 1997 Emergency Contact : Emergency Telephone No.: +44 (0) 1889 590312 Description: An infra red reflecting matt finish for brush or spray application onto Defence Equipment. Based on an alkyd resin system with inorganic pigments and containing white spirit solvent. 2. COMPOSITION/INFORMATION ON INGREDIENTS The following ingredients have recognised health effects and are present in concentrations above the limits laid down in the Chemicals (Hazard Information and Packaging for Supply) Regulations 1994 (CHIP 2). Weight Risk CAS Substance in paint Full details of R-phrases are as follows:- R22 Harmful if swallowed. Further information about hazard classifications can be found in the Approved Guide to the Classification and Labelling of Substances and Preparations Dangerous for Supply. The information in this data sheet is provided in accordance with the requirements of the Chemicals (Hazard Information and Packaging for Supply) Regulations 1994. The product should not be used for purposes other than those shown in Section 1 without first referring to the supplier and obtaining written handling instructions. As the specific conditions of use are outside the supplier’s control, the user is responsible for ensuring that the requirements of relevant legislation are complied with. The information contained in this data sheet is based on the present state of knowledge and current national legislation. It provides guidance on health, safety and environmental aspects of the product and should not be construed as any guarantee of technical performance or suitability for particular applications. Further information and relevant advice can be found in:- The Chemicals (Hazard Information and Packaging for Supply) Regulations 1994 (SI 1994 : 3247) Control of Substances Hazardous to Health Regulations 1988 (SI 1988 : 1657) Manual Handling Operations Regulations 1992 (SI 1992: 2793) Environmental Protection (Duty of Care) Regulations 1992 (SI 1992 : 2839) Occupational Exposure Limits, EH40 The storage of flammable liquids in containers, HS(G)51 Storage of Packaged Dangerous Substances, HS(G)71 The Approved Guide to the Classification and Labelling of Substances and Preparations Dangerous for Supply (Second Edition), L63 The Approved Supply List, L61 The Approved Code of Practice: Safety Data Sheets for Substances and Preparations Dangerous for Supply, L62 cont’d 9804/8914 ISSUE 2 (REV.), MARCH 1997 Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 Def Stan 80-41 Finish/10/09/96 9804/8927 ISSUE 3 (REV.), MARCH 1997 Emergency Contact : Emergency Telephone No.: +44 (0) 1889 590312 Description: A sheen finish for spray, brush or roller application to suitably primed surfaces. Based on an alkyd resin system with inorganic and/or organic pigments and containing white spirit solvent. Also, the following colours contain lead chromate pigment:- BS2660 6-074 BS381C 216 Gloss - Eau-De-Nil BS381C 221 Gloss - Brilliant Green BS381C 225 Gloss - Light Brunswick Green BS381C 226 Gloss - Middle Brunswick Green BS381C 227 Gloss - Deep Brunswick Green BS4800 04D45 - Crimson BS4800 04E53 - Red BS4800 06C39 - Tobacco BS4800 06E51 - Nasturtium BS4800 08E51 - Golden Yellow BS4800 10C31 - Buttermilk BS4800 10C33 - Pollen BS4800 10C39 - Seaweed BS4800 10E53 - Canary Yellow BS4800 12B29 - Black Forest BS4800 12D45 - Avocado BS4800 14E51 - April Green BS4800 14E53 - Emerald BS5252 04E56 BS5252 08E53 BS5252 10D44 BS5252 10E55 Mid Brunswick Green - R4358 Orange - R4860 RAL 1007 - Chrome Yellow RAL 1018 - Zinc Yellow RAL 3000 - Fire Red Red - R4816 Yellow - R4726 Yellow - R4775 2. COMPOSITION/INFORMATION ON INGREDIENTS The following ingredients have recognised health effects and are present in concentrations above the limits laid down in the Chemicals (Hazard Information and Packaging for Supply) Regulations 1994 (CHIP 2). cont’d 9804/8927 ISSUE 3 (REV.), MARCH 1997 Weight Risk CAS Substance in paint Full details of R-phrases are as follows:- R22 Harmful if swallowed. R33 Danger of cumulative effects. R40 Possible risk of irreversible effects R61 May cause harm to the unborn child R62 Possible risk of impaired fertility Full details of the hazard classifications are as follows:- Repr. Cat. 1 Toxic for reproduction - Category 1 Repr. Cat. 1 Toxic for reproduction - Category 3 Carc. Cat. 3 Carcinogenic - Category 3 Further information about hazard classifications can be found in the Approved Guide to the Classification and Labelling of Substances and Preparations Dangerous for Supply. The information in this data sheet is provided in accordance with the requirements of the Chemicals (Hazard Information and Packaging for Supply) Regulations 1994. The product should not be used for purposes other than those shown in Section 1 without first referring to the supplier and obtaining written handling instructions. As the specific conditions of use are outside the supplier’s control, the user is responsible for ensuring that the requirements of relevant legislation are complied with. The information contained in this data sheet is based on the present state of knowledge and current national legislation. It provides guidance on health, safety and environmental aspects of the product and should not be construed as any guarantee of technical performance or suitability for particular applications. Further information and relevant advice can be found in:- The Chemicals (Hazard Information and Packaging for Supply) Regulations 1994 (SI 1994 : 3247) Control of Lead at Work Regulations 1980 (SI 1980 : 1248) Control of Substances Hazardous to Health Regulations 1988 (SI 1988 : 1657) Manual Handling Operations Regulations 1992 (SI 1992: 2793) Environmental Protection (Duty of Care) Regulations 1992 (SI 1992 : 2839) Occupational Exposure Limits, EH40 The storage of flammable liquids in containers, HS(G)51 Storage of Packaged Dangerous Substances, HS(G)71 The Approved Guide to the Classification and Labelling of Substances and Preparations Dangerous for Supply (Second Edition), L63 The Approved Supply List, L61 The Approved Code of Practice: Safety Data Sheets for Substances and Preparations Dangerous for Supply, L62 Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 M415/30/08/96 9804/8957 ISSUE 4 (REV.), JUNE 2002 Emergency Contact : Emergency Telephone No.: +44 (0) 1889 590312 Description: A gloss finish for application by brush or spray. Based on an alkyd resin system with lead chromate and other pigments and containing white spirit solvent. 2. COMPOSITION/INFORMATION ON INGREDIENTS The following ingredients have recognised health effects and are present in concentrations above the limits laid down in the Chemicals (Hazard Information and Packaging for Supply) Regulations 1994 (CHIP 2). Weight Risk CAS Substance in paint Full details of R-phrases are as follows:- R22 Harmful if swallowed. R33 Danger of cumulative effects. R40 Possible risk of irreversible effects R61 May cause harm to the unborn child R62 Possible risk of impaired fertility cont’d 9804/8957 ISSUE 4 (REV.), JUNE 2002 Full details of R-phrases are as follows:- R65 Harmful: may cause lung damage if swallowed The information in this data sheet is provided in accordance with the requirements of the Chemicals (Hazard Information and Packaging for Supply) Regulations 1994. The product should not be used for purposes other than those shown in Section 1 without first referring to the supplier and obtaining written handling instructions. As the specific conditions of use are outside the supplier’s control, the user is responsible for ensuring that the requirements of relevant legislation are complied with. The information contained in this data sheet is based on the present state of knowledge and current national legislation. It provides guidance on health, safety and environmental aspects of the product and should not be construed as any guarantee of technical performance or suitability for particular applications. Further information and relevant advice can be found in:- The Chemicals (Hazard Information and Packaging for Supply) Regulations 1994 (SI 1994 : 3247) and amendments Control of Substances Hazardous to Health Regulations 1999 (SI 1999 : 437) Manual Handling Operations Regulations 1992 (SI 1992: 2793) Environmental Protection (Duty of Care) Regulations 1992 (SI 1992 : 2839) Occupational Exposure Limits, EH40 (revised annually) The storage of flammable liquids in containers, HS(G)51 Chemical warehousing: the storage of packaged dangerous substances, HS(G)71 The Approved Guide to the Classification and Labelling of Substances and Preparations Dangerous for Supply (Fourth Edition), L100 The Approved Supply List, L124 The Approved Code of Practice: Safety Data Sheets for Substances and Preparations Dangerous for Supply, L62 Special Waste Regulations 1996 (SI 1996:972) and amendments The interpretation and use of flashpoint information, CS24 COSHH Essentials: easy steps to control chemicals, HS(G)193, Details of available Control Guidance Sheets, which may be relevant to the particular conditions of use, can also be found in HS(G)193. Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 * Note: Items marked with an asterisk (*) have been amended since last issue. 9804/8923 ISSUE 5 (REV.), JUNE 2002 Emergency Contact : Emergency Telephone No.: +44 (0) 1889 590312 Description: A gloss finish for brush or spray application. Based on an alkyd resin system with inorganic pigments and containing white spirit solvent. The following ingredients have recognised health effects and are present in concentrations above the limits laid down in the Chemicals (Hazard Information and Packaging for Supply) Regulations 1994 (CHIP 2). Weight Risk CAS Substance in paint Full details of R-phrases are as follows:- R22 Harmful if swallowed. Further information about hazard classifications can be found in the Approved Guide to the Classification and Labelling of Substances and Preparations Dangerous for Supply. The information in this data sheet is provided in accordance with the requirements of the Chemicals (Hazard Information and Packaging for Supply) Regulations 1994. The product should not be used for purposes other than those shown in Section 1 without first referring to the supplier and obtaining written handling instructions. As the specific conditions of use are outside the supplier’s control, the user is responsible for ensuring that the requirements of relevant legislation are complied with. The information contained in this data sheet is based on the present state of knowledge and current national legislation. It provides guidance on health, safety and environmental aspects of the product and should not be construed as any guarantee of technical performance or suitability for particular applications. Further information and relevant advice can be found in:- The Chemicals (Hazard Information and Packaging for Supply) Regulations 1994 (SI 1994 : 3247) Control of Substances Hazardous to Health Regulations 1988 (SI 1988 : 1657) Manual Handling Operations Regulations 1992 (SI 1992: 2793) Environmental Protection (Duty of Care) Regulations 1992 (SI 1992 : 2839) Occupational Exposure Limits, EH40 The storage of flammable liquids in containers, HS(G)51 Storage of Packaged Dangerous Substances, HS(G)71 The Approved Guide to the Classification and Labelling of Substances and Preparations Dangerous for Supply (Second Edition), L63 The Approved Supply List, L61 The Approved Code of Practice: Safety Data Sheets for Substances and Preparations Dangerous for Supply, L62 Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 * Note: Items marked with an asterisk (*) have been amended since last issue. 11.09.96/Rev. 3 9804/8915 ISSUE 4 (REV.), NOVEMBER 1997 Emergency Contact : Emergency Telephone No.: +44 (0) 1889 590312 Description: An anticorrosive primer for spray application to blast cleaned surfaces. Based on an alkyd resin system with zinc phosphate and other inorganic pigments and containing white spirit solvent. 2. COMPOSITION/INFORMATION ON INGREDIENTS The following ingredients have recognised health effects and are present in concentrations above the limits laid down in the Chemicals (Hazard Information and Packaging for Supply) Regulations 1994 (CHIP 2). Weight Risk CAS Substance in paint Full details of R-phrases are as follows:- R22 Harmful if swallowed R33 Danger of cumulative effects R40 Possible risk of irreversible effects R61 May cause harm to the unborn child R62 Possible risk of impaired fertility Full details of the hazard classifications are as follows:- Repr. Cat. 1 Toxic for reproduction - Category 1 Repr. Cat. 3 Toxic for reproduction - Category 3 Carc. Cat. 3 Carcinogenic - Category 3 Further information about hazard classifications can be found in the Approved Guide to the Classification and Labelling of Substances and Preparations Dangerous for Supply. The information in this data sheet is provided in accordance with the requirements of the Chemicals (Hazard Information and Packaging for Supply) Regulations 1994. The product should not be used for purposes other than those shown in Section 1 without first referring to the supplier and obtaining written handling instructions. As the specific conditions of use are outside the supplier’s control, the user is responsible for ensuring that the requirements of relevant legislation are complied with. cont’d 9804/8915 ISSUE 4 (REV.), NOVEMBER 1997 The information contained in this data sheet is based on the present state of knowledge and current national legislation. It provides guidance on health, safety and environmental aspects of the product and should not be construed as any guarantee of technical performance or suitability for particular applications. Further information and relevant advice can be found in:- The Chemicals (Hazard Information and Packaging for Supply) Regulations 1994 (SI 1994 : 3247) Control of Lead at Work Regulations 1980 (SI 1980 : 1248) Control of Substances Hazardous to Health Regulations 1988 (SI 1988 : 1657) Manual Handling Operations Regulations 1992 (SI 1992: 2793) Environmental Protection (Duty of Care) Regulations 1992 (SI 1992 : 2839) Occupational Exposure Limits, EH40 The storage of flammable liquids in containers, HS(G)51 Storage of Packaged Dangerous Substances, HS(G)71 Approved Guide to the Classification and Labelling of Substances and Preparations Dangerous for Supply (Second Edition), L63 The Approved Supply List, L61 The Approved Code of Practice: Safety Data Sheets for Substances and Preparations Dangerous for Supply, L62 Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 * Note: Items marked with an asterisk (*) have been amended since last issue. 4200/5900/11.09.96 9804/8922 ISSUE 5 (REV.), JUNE 2002 Emergency Contact : Emergency Telephone No.: +44 (0) 1889 590312 Description: A gloss finish for brush or spray application. Based on an alkyd resin system with lead chromate and other pigments and containing white spirit solvent. 2. COMPOSITION/INFORMATION ON INGREDIENTS The following ingredients have recognised health effects and are present in concentrations above the limits laid down in the Chemicals (Hazard Information and Packaging for Supply) Regulations 1994 (CHIP 2). Weight Risk CAS Substance in paint Full details of R-phrases are as follows:- R22 Harmful if swallowed R33 Danger of cumulative effects R40 Possible risk of irreversible effects R61 May cause harm to the unborn child R62 Possible risk of impaired fertility Full details of the hazard classifications are as follows:- Repr. Cat. 1 Toxic for reproduction - Category 1 Repr. Cat. 3 Toxic for reproduction - Category 3 Carc. Cat. 3 Carcinogenic - Category 3 cont’d 9804/8922 ISSUE 5 (REV.), JUNE 2002 Text of R Phrases listed in Section 2:- R No. Phrase Xn Harmful. R20/21 Harmful by inhalation and in contact with skin. This product should not be used for purposes other than those shown in Section 1 without first referring to the supplier. The information contained in this Data Sheet is based on the present state of knowledge and current national legislation. It provides guidance on health, safety and environmental aspects of the product and should not be construed as any guarantee of technical performance or suitability for particular applications. Further information can be found in:- The Control of Substances Hazardous to Health Regulations 1988 (SI 1988 : 1657) The Manual Handling Operations Regulations 1992 (SI 1992 2739) The Storage of Flammable Liquids in Containers HS(G)51 The Storage of Packed Dangerous Substances HS(G)71 The Environmental Protection (Duty of Care) Regulations 1992 (SI 1992 283G) Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 * Note: Items marked with an asterisk (*) have been amended since last issue. M571/JULY 1994 9804/8929 ISSUE 1, SEPTEMBER 1989 your dealer provides you with a copy of the Notice with this leaflet. PRODUCT – MASOPAR SYNTHETIC THINNER M 571 JCB Part No(s) : 4200/8103 Supplier : Joseph Mason Paints Chemical names & synonyms : Aromatic hydrocarbon fraction. Intended use : Thinner for industrial and commercial paints. NOTE: THIS PRODUCT SHOULD NOT BE USED FOR OTHER PURPOSES WITHOUT EXPERT ADVICE. PHYSICAL PROPERTIES Appearance : Lliquid Melting point : NA Odour : NA Pour point : NA pH : NA Boiling point : NA Viscosity : NA Relative density : NA Flash point : 32 °C Solubility : Insoluble Vapour pressure : NA HEALTH HAZARD DATA Effects of over exposure : Excessive concentrations may produce effects on the central nervous system including drowsiness. In extreme cases loss of consciousness may occur. Irritating to eyes and res- piratory system. Prolonged skin contact may lead to dermatitis. Occupational exposure limit : ppm 33 (long 8 hrs) SPECIAL PROTECTION INFORMATION Eye protection : Wear eye/face protection when using this product. Skin protection : Wear protective clothing when using this product. Respiratory protection : Use only in well ventilated area, wear respiratory protection equipment if required. Ventilation : Good ventilation required. EMERGENCY & FIRST AID PROCEDURES Eye contact : Flush with water for at least 10 mins holding eyelids apart. Skin contact : Remove contaminated clothing. Wash well with soap and water or a proprietary cleanser. DO NOT USE SOLVENTS OR THINNERS. Inhalation : Remove patient to fresh air, keep warm and at rest. If breathing irregular or stopped, give artificial respiration. GIVE NOTHING BY MOUTH. Ingestion : Not expected to be a problem. If accidentially swallowed, DO NOT INDUCE VOMITING, keep warm an at rest and obtain medical aid. FIRE & EXPLOSION HAZARD DATA Flash point : <32 °C IP Classification : Unclassified Flammable limits : LEL : UEL : Extinguishing media : Foam, dry powder Special fire fighting procedures: Do not use water jets. Wear breathing apparatus when fighting fire. Fire will produce dense black harmful smoke. 9804/8929 ISSUE 1, SEPTEMBER 1989 Page 1 of 2 9804/8929 ISSUE 1, SEPTEMBER 1989 REACTIVITY DATA Stability (thermal, light, etc.) : Stable Conditions to avoid : Sources of ignition. Extreme heat. Incompatibility (materials to avoid) : NA Hazardous decomposition products : NA Hazard polymerisation : Will not occur. SPILLAGE LEAKAGE AND WASTE DISPOSAL PROCEDURES Environmental impact : Report spills as required to appropriate authorities. Do not allow to enter drains, water courses/water sup- plies/ponds/rivers etc. Procedures if material is released or spilled : Remove sources of ignition. Contain and absorb on fire retardant treated sawdust, diatomaceous earth etc. Shovel up and dispose of at licensed waste site in accordance with current regulations. Waste disposal : Waste material and spillages must be treated as a fire hazard and disposed of in accordance with Control of Pollu- tion Act 1974. Contact Local Authority prior to disposal. ADDITIONAL HANDLING AND STORAGE INFORMATION The product is flammable - flammable concentrations of vapour should be avoided by providing adequate ventilation. Keep in well ventilated, cool, dry place away from sources of ignition. Keep all tins tightly closed. Paint residues are liable to spontaneous com- bustion. Remove soiled cloths and masking etc from the working area daily. Damp residues with water and store in closed metal TOXICOLOGICAL DATA Oral toxicity : Toxic Dermal toxicity : Toxic - may cause dermatitis. Inhalation toxicity : May cause drowsiness. In extreme cases loss of consciousness can occur. Eye irritation : Causes irritation and possible damage. Skin irritation : Causes irritation and possible damage. SUBCHRONIC TOXICOLOGY (SUMMARY) : NA CHRONIC TOXICOLOGY (SUMMARY) : NA OTHER TOXICOLOGY DATA : NA REGULATORY INFORMATION Full details of R-phrases are as follows:- R20/21 Harmful by inhalation and in contact with skin. R37 Irritating to respiratory system. R38 Irritating to skin. Further information about hazard classifications can be found in the Approved Guide to the Classification and Labelling of Substances and Preparations Dangerous for Supply. The information in this data sheet is provided in accordance with the requirements of the Chemicals (Hazard Information and Packaging for Supply) Regulations 1994. The product should not be used for purposes other than those shown in Section 1 without first referring to the supplier and obtaining written handling instructions. As the specific conditions of use are outside the supplier’s control, the user is responsible for ensuring that the requirements of relevant legislation are complied with. The information contained in this data sheet is based on the present state of knowledge and current national legislation. It provides guidance on health, safety and environmental aspects of the product and should not be construed as any guarantee of technical performance or suitability for particular applications. Further information and relevant advice can be found in:- The Chemicals (Hazard Information and Packaging for Supply) Regulations 1994 (SI 1994 : 3247) Control of Substances Hazardous to Health Regulations 1988 (SI 1988 : 1657) Manual Handling Operations Regulations 1992 (SI 1992: 2793) Environmental Protection (Duty of Care) Regulations 1992 (SI 1992 : 2839) Occupational Exposure Limits, EH40 The storage of flammable liquids in containers, HS(G)51 Storage of Packaged Dangerous Substances, HS(G)71 The Approved Guide to the Classification and Labelling of Substances and Preparations Dangerous for Supply (Second Edition), L63 The Approved Supply List, L61 The Approved Code of Practice: Safety Data Sheets for Substances and Preparations Dangerous for Supply, L62 Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 01.06.95/Rev. 2 9804/8965 ISSUE 3 (REV.), NOVEMBER 1997 Emergency Contact : Emergency Telephone No.: +44 (0) 1889 590312 * Description: A semi-gloss finish for spray application to suitably primed components. Based on a 2-pack isocyanate free acrylic epoxy resin system with inorganic pigments and containing naphtha, 1-methoxypropan-2-ol and xylene solvents. 2. COMPOSITION/INFORMATION ON INGREDIENTS The following ingredients have recognised health effects and are present in concentrations above the limits laid down in the Chemicals (Hazard Information and Packaging for Supply) Regulations 1994 (CHIP 2). Weight Risk CAS Substance in paint Full details of R-phrases are as follows:- R20/21 Harmful by inhalation and in contact with skin. R36/38 Irritating to eyes and skin. R37 Irritating to respiratory system. R38 Irritating to skin. R40 Possible risk of irreversible effects. The information in this data sheet is provided in accordance with the requirements of the Chemicals (Hazard Information and Packaging for Supply) Regulations 1994. The product should not be used for purposes other than those shown in Section 1 without first referring to the supplier and obtaining written handling instructions. As the specific conditions of use are outside the supplier’s control, the user is responsible for ensuring that the requirements of relevant legislation are complied with. The information contained in this data sheet is based on the present state of knowledge and current national legislation. It provides guidance on health, safety and environmental aspects of the product and should not be construed as any guarantee of technical performance or suitability for particular applications. Further information and relevant advice can be found in:- The Chemicals (Hazard Information and Packaging for Supply) Regulations 1994 (SI 1994 : 3247) Highly Flammable Liquids and Liquefied Petroleum Gases Regulations 1972 (SI 1972 : 917) Control of Substances Hazardous to Health Regulations 1988 (SI 1988 : 1657) Manual Handling Operations Regulations 1992 (SI 1992: 2793) Environmental Protection (Duty of Care) Regulations 1992 (SI 1992 : 2839) Occupational Exposure Limits, EH40 The storage of flammable liquids in containers, HS(G)51 Storage of Packaged Dangerous Substances, HS(G)71 The Approved Guide to the Classification and Labelling of Substances and Preparations Dangerous for Supply (Second Edition), L63 The Approved Supply List, L76 The Approved Code of Practice: Safety Data Sheets for Substances and Preparations Dangerous for Supply, L62 cont’d 9804/8965 ISSUE 3 (REV.), NOVEMBER 1997 Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 Note: Items marked with an asterisk (*) have been ammended since last issue. cont’d 9804/8966 ISSUE 3 (REV.), JUNE 2002 Emergency Contact : Emergency Telephone No.: +44 (0) 1889 590312 Description: An anticorrosive primer for application by spray. Based on a two pack epoxy resin system with zinc phosphate and other inorganic pigments and containing aromatic hydrocarbon and 1-methoxypropan-2-ol solvents. 2. COMPOSITION/INFORMATION ON INGREDIENTS The following ingredients have recognised health effects and are present in concentrations above the limits laid down in the Chemicals (Hazard Information and Packaging for Supply) Regulations 1994 (CHIP 2). Weight Risk CAS Substance in paint Full details of R-phrases are as follows:- R36/38 Irritating to eyes and skin R37 Irritating to respiratory system R40 Possible risk of irreversible effects Further information about hazard classifications can be found in the Approved Guide to the Classification and Labelling of Substances and Preparations Dangerous for Supply. The information in this data sheet is provided in accordance with the requirements of the Chemicals (Hazard Information and Packaging for Supply) Regulations 1994. The product should not be used for purposes other than those shown in Section 1 without first referring to the supplier and obtaining written handling instructions. As the specific conditions of use are outside the supplier’s control, the user is responsible for ensuring that the requirements of relevant legislation are complied with. cont’d 9804/8966 ISSUE 3 (REV.), JUNE 2002 FULL TEXT OF RISK PHRASES FOR INGREDIENTS INDICATED IN SECTION 2: Cumene hydroperoxide R7 - May cause fire. R21/22 - Harmful in contact with skin and if swallowed. R48/20/22 - Harmful: danger of serious damage to health by prolonged exposure through inhalation and if swallowed. R23 - Toxic by inhalation. R34 - Causes burns. R37 - Irritating to respiratory system. R51/53 - Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. N,N-Dimethyl-p-toluidine R23/24/25 - Toxic by inhalation, in contact with skin and if swallowed. R33 - Danger of cumulative effects. R52/53 - Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Directives 1999/45/EC and 91/155/EEC have been considered when compiling this SDS; the information is provided for health and safety assessment by an industrial user. Reference should be made to any relevant local or national health, safety, and environmental legislation. This information does not constitute indication of suitability for specific uses. Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 Note: Items marked with an asterisk (*) have been amended since last issue. 9804/8974 ISSUE 4, (REV.) NOVEMBER 1997 JCB Polyurethane Sealant MSDS first issued: 11.10.94 Revision Date: 11.10.94 Uses and Restrictions: Customers are urged to ensure that the product is entirely suitable for their own purpose. It is the customer’s responsibility to ensure that a suitable and sufficient assessment of the risks created by the use of the product is undertaken. Footnote: This information is given in good faith and based on information believed to be reliable. This document is not a specification and properties shown are not guaranteed. National Legislation UK Legislation: Health and Safety at Work etc. Act, 1974, and relevant Statutory Provisions. SI 1993/1746: Chemicals (Hazard Information and Packaging) Regulations, 1993. SI 1988/1657: The Control of Substances Hazardous to Health Regulations. Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 Note: Items marked with an asterisk (*) have been ammended since last issue. SIKA/SKFX252 2.00 GB/11.10.94 9804/8989 ISSUE 3, (REV.) NOVEMBER 1996 JCB Ultrafast Adhesive MSDS first issued: 11.10.94 Revision Date: Uses and Restrictions: Customers are urged to ensure that the product is entirely suitable for their own purpose. It is the customerÕs responsibility to ensure that a suitable and sufficient assessment of the risks created by the use of the product is undertaken. Footnote: This information is given in good faith and based on information believed to be reliable. This document is not a specification and properties shown are not guaranteed. National Legislation UK Legislation: Health and Safety at Work etc. Act, 1974, and relevant Statutory Provisions. SI 1993/1746: Chemicals (Hazard Information and Packaging) Regulations, 1993. SI 1988/1657: The Control of Substances Hazardous to Health Regulations. Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 SIKA/SIKTKUF 1.00 GB/11.10.94 9804/8889 ISS.1 SEPT.89 PRODUCT SAFETY NOTICE To be read in conjunction with Product Safety Information (COSHH) leaflets. It is believed that all the information given in the accompanying leaflet is accurate at the time of printing. Such information is offered in good faith but without guarantee and without any representation that the product concerned is suitable for any particular use or application. Without limitation of the foregoing, nothing herein shall be construed as a recommendation for uses which infringe valid patents or as extending any licence under valid patents. JCB Service pursues a policy of constant development aimed at product improvement and, therefore, reserves the right to change formulation, specification and characteristics of its products without notice. Users should verify current specifications with JCB Service or their authorised distributors, and ascertain that products are suitable for intended uses or applications. Where the information provided herein discloses a potential hazard or hazardous ingredients, adequate warning must be provided to employees and users and appropriate precautions taken, including the practice of good industrial hygiene. PREPARED BY : JCB SERVICE FOR FURTHER INFORMATION CONTACT : JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TELEPHONE 01889 590312 9804/8934 ISSUE 2, SEPTEMBER 1995 your dealer provides you with a copy of the Notice with this leaflet. PRODUCT – HIGH STRENGTH THREAD LOCKER JCB Part No(s) : 4101/0502 Supplier : Loctite Chemical names & synonyms : Polyetheleneglycol dimethacrylate based sealant. Intended use : Locking sealant. COMPOSITIONAL INFORMATION Component % by Weight* Further Information may be obtained from the Health & Regulatory Affairs Department at the following address :- Loctite (International) NBD Tallaght Business Park, Whitestown, Dublin 24, Ireland Tel: +353-1-510433 or +353-1-519466. Fax: +353-1-519073 Prepared by : Dr. Yvonne Traynor Health & Regulatory Affairs Officer. Internal formula ref.: EG-725, 90/03 Formerly Development Product: LI-249 HRA Ref.: 44-E Supercedes Safety Data Sheet No: 44-E of 05/06/85 The information in this safety data sheet was obtained from reputable sources and to the best of our knowledge, is accurate and current at the mentioned date. Neither Loctite nor its subsidiary companies accept any liability arising out of the use of the information provided here or the use, application or processing of the product(s) described herein. Attention of users is drawn to the possible hazards from improper use of the product(s). 9804/8984 ISSUE 2, SEPTEMBER 1995 Page 4 of 4 Methacrylate Ester No components which pose a risk. No European Danger category (67/548/EEC and amendments) Eye: Slightly irritating but does not injure eye tissue. Skin Contact: Low order of toxicity. Inhalation: No hazard in normal industrial use. Ingestion: Low order of toxicity. No hazard in normal industrial use. 4. FIRST-AID MEASURES Eye: Flush eyes with plenty of clean water Skin Contact: Wash with soap and water. Inhalation: Remove to fresh air. Ingestion: DO NOT induce vomiting. If individual is conscious, give milk or water to dilute stomach contents. Keep warm and quiet. Get prompt medical attention. 5. FIRE-FIGHTING MEASURES Autoflammability: Not applicable Flash Point: >100 ¡C (Pensky-Martens Closed Tester) Extinguishing Media: CO2; Dry chemical; Foam; Water fog Special Firefighting Procedures: Fire fighters should be equipped with self-contained breathing apparatus to protect against potentially toxic and irritating fumes. Fire & Explosion Hazards: Combustion may release noxious or toxic vapours. See below. Hazardous Combustion Products: Thermal decomposition could produce carbon monoxide, carbon dioxide, and unidentified organic compounds. Upper Explosion Limit (%): Not applicable Lower Explosion Limit (%): Not applicable 6. ACCIDENTAL RELEASE MEASURES Spill and Leak Procedures: Take up with sand or other absorbent material and place in container for later disposal. This material should not be spilled, dumped, or flushed into sewers or public waterways. For safety and environmental precautions, please review entire Safety Data Sheet for necessary information. 7. HANDLING AND STORAGE Revision Date: 14 August, 1995 Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 14.8.95 9804/8999 ISSUE 2 (REV), JUNE 2002 Methacrylate Ester No components which pose a risk. No European Danger category (67/548/EEC and amendments) Eye: Slightly irritating but does not injure eye tissue. Skin Contact: Low order of toxicity. Inhalation: No hazard in normal industrial use. Ingestion: Low order of toxicity. No hazard in normal industrial use. 4. FIRST-AID MEASURES Eye: Flush eyes with plenty of clean water Skin Contact: Wash with soap and water. Inhalation: Remove to fresh air. Ingestion: DO NOT induce vomiting. If individual is conscious, give milk or water to dilute stomach contents. Keep warm and quiet. Get prompt medical attention. 9804/8999 ISSUE 2 (REV), JUNE 2002 Revision Date: 20 November 1996 Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 20.11.96 Methacrylate Ester No components which pose a risk. No European Danger category (67/548/EEC and amendments). Eye: Slightly irritating but does not injure eye tissue. Skin Contact: Low order of toxicity. Inhalation: No hazard in normal industrial use. Ingestion: Low order of toxicity. No hazard in normal industrial use. 4. FIRST-AID MEASURES Eye: Flush eyes with plenty of water. Skin Contact: Wash with soap and water. Inhalation: Remove to fresh air. Ingestion: DO NOT induce vomiting. If individual is conscious, give milk or water to dilute stomach contents. Keep warm and quiet. Get prompt medical attention. 5. FIRE-FIGHTING MEASURES Autoflammability: Not applicable Flash Point: >100 ¡C (Pensky-Martens Closed Tester) Extinguishing Media: CO2; Dry chemical; Foam; Water fog Special Firefighting Procedures: Fire fighters should be equipped with self-contained breathing apparatus to protect against potentially toxic and irritating fumes. Fire & Explosion Hazards: Combustion may release noxious or toxic vapours. See below. Hazardous Combustion Products: Thermal decomposition could produce carbon monoxide, carbon dioxide, and unidentified organic compounds. Upper Explosion Limit (%): Not applicable Lower Explosion Limit (%): Not applicable 6. ACCIDENTAL RELEASE MEASURES Spill and Leak Procedures: Take up with sand or other absorbent material and place in container for later disposal. This material should not be spilled, dumped, or flushed into sewers or public waterways. For safety and environmental precautions, please review entire Safety Data Sheet for necessary information. 7. HANDLING AND STORAGE Revision Date: 10 April 1996 Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 10.4.96 Methacrylate Ester Component CAS Number Concentration Ranges EEC Symbol/Risk Phrases Hydroxypropy methacrylate 127813-02-1 10-<20% Xi R36/38 Irritant Eye: Slightly irritating but does not injure eye tissue. Skin Contact: Frequent of prolonged contact may irritate the skin. Inhalation: No hazard in normal industrial use. Ingestion: Low order of toxicity. No hazard in normal industrial use. 4. FIRST-AID MEASURES Eye: Flush eyes with large amounts of water until irritation subsides. If irritation persists, get medical attention. Skin Contact: Flush with large amounts of water; use soap if available. If irritation persists, get medical attention. Inhalation: Remove to fresh air. Ingestion: DO NOT induce vomiting. If individual is conscious, give milk or water to dilute stomach contents. Keep warm and quiet. Get prompt medical attention. 5. FIRE-FIGHTING MEASURES Autoflammability: Not applicable Flash Point: >100 ¡C (Pensky-Martens Closed Tester) Extinguishing Media: CO2; Dry chemical; Foam; Water fog Special Firefighting Procedures: Fire fighters should be equipped with self-contained breathing apparatus to protect against potentially toxic and irritating fumes. Fire & Explosion Hazards: Combustion may release noxious or toxic vapours. See below. Hazardous Combustion Products: Thermal decomposition could produce carbon monoxide, carbon dioxide, and unidentified organic compounds. Upper Explosion Limit (%): Not applicable Lower Explosion Limit (%): Not applicable 6. ACCIDENTAL RELEASE MEASURES Spill and Leak Procedures: Take up with sand or other absorbent material and place in container for later disposal. This material should not be spilled, dumped, or flushed into sewers or public waterways. For safety and environmental precautions, please review entire Safety Data Sheet for necessary information. 7. HANDLING AND STORAGE Revision Date: 21 November 1996 Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 21.11.96 9804/9002 ISSUE 2, (REV) SEPTEMBER 2002 COMPONENT EC NUMBER CONCENTRATION EC SYMBOL FULL TEXT OF RISK PHRASES FOR INGREDIENTS INDICATED IN SECTION 2: Methacrylic acid R35 - Causes severe burns. R21/22 - Harmful in contact with skin and if swallowed. Cumene hydroperoxide R7 - May cause fire. R21/22 - Harmful in contact with skin and if swallowed. R48/20/22 - Harmful: danger of serious damage to health by prolonged exposure through inhalation and if swallowed. R23 - Toxic by inhalation. R34 - Causes burns. R37 - Irritating to respiratory system. R51/53 - Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. N,N-Dimethyl-p-toluidine R23/24/25 - Toxic by inhalation, in contact with skin and if swallowed. R33 - Danger of cumulative effects. R52/53 - Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Directives 1999/45/EC and 91/155/EEC have been considered when compiling this SDS; the information is provided for health and safety assessment by an industrial user. Reference should be made to any relevant local or national health, safety, and environmental legislation. This information does not constitute indication of suitability for specific uses. Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 Note: Items marked with an asterisk (*) have been amended since last issue. Chemical Family: Methacrylate Ester Component CAS Number Concentration Ranges EEC Symbol/Risk Phrases Ethyl 7085-85-0 >50% 2-cyanoacrylate No European Danger category (67/548/EEC and amendments). Eye: On contact, will bond eyelids together. Vapours are lachrymatory. Skin Contact: On contact, immediate bonding of the skin will occur. Inhalation: Vapours may be irritating to respiratory system and nasal passages. Ingestion: On contact, immediate bonding of mouth could occur. 4. FIRST-AID MEASURES Eye: Flush with large amounts of water while hodling eyelids open. Get medical attention immediately. Cured adhesive will not bond well to surface of eye, but corneal damage from abrasion may result. DO NOT wear contact lenses when working with this material. Skin Contact: No attempt should be made to remove mterial from skin or to remove contaminated clothing, as the bonded skin can be easily torn. Wash with large volumes of soap and water while flexing bonded skin parts. This procedure will slowly release bonded areas. DO NOT remove cured adhesive mechanically or attempt to separate bonded skin. Inhalation: Remove to fresh air. If breathing is difficult, give oxygen. If breathing has stopped, give artificial respiration. Get medical attention. Ingestion: Immediate bonding of mouth will occur. Get medical attention. 5. FIRE-FIGHTING MEASURES Autoflammability: Not applicable Flash Point: 75 ¡C (Setaflash Closed Tester) Extinguishing Media: CO2; Dry chemical; Foam Special Firefighting Procedures: Fire fighters should be equipped with self-contained breathing apparatus to protect against potentially toxic and irritating fumes. Fire & Explosion Hazards: Cloths used to wipe up spills may cause rapid polymerization that could generate sufficient heat to ignite the cloth. Combustion may release noxious or toxic vapours. See Reactivity. Hazardous Combustion Products: Decomposes upon heating to release toxic fumes of nitrogen oxides, carbon monoxide and carbon dioxide. Upper Explosion Limit (%): Not applicable Lower Explosion Limit (%): Not applicable 6. ACCIDENTAL RELEASE MEASURES Spill and Leak Procedures Small Spills: Wipe up with cloth. Immediately soak cloth with water to polymerize the adhesive. CAUTION! Cloth containing adhesive may undergo auto ignition if not soaked with water. Large Spills: Flood area with water. When cured, remove film with a scraper. Wear approved respirator for organic vapours if needed, and protective clothing. For safety and environmental precautions, please review entire Safety Data Sheet for necessary information. 7. HANDLING AND STORAGE Further Information may be obtained from the Health & Regulatory Affairs Department at the following address :- Loctite (International) NBD Tallaght Business Park, Whitestown, Dublin 24, Ireland Tel: +353-1-510433 or +353-1-519466. Fax: +353-1-519073 Prepared by : Dr. Yvonne Traynor Health & Regulatory Affairs Officer. Internal formula ref.: EO 91/35 Formerly Development Product: LID-1403 HRA Ref.: 338-E Supercedes Safety Data Sheet No: 338-E of 05.02.92 The information in this safety data sheet was obtained from reputable sources and to the best of our knowledge, is accurate and current at the mentioned date. Neither Loctite nor its subsidiary companies accept any liability arising out of the use of the information provided here or the use, application or processing of the product(s) described herein. Attention of users is drawn to the possible hazards from improper use of the product(s). 9804/8982 ISSUE 2, SEPTEMBER 1995 Page 4 of 4 9804/8973 ISSUE 5 (REV), JUNE 2002 your dealer provides you with a copy of the Notice with this leaflet. PRODUCT – TURBO INSULATION BLANKET, TURBO EXHAUST BLANKET JCB Part No(s) : *158/30406 Supplier : Chemical names & synonyms : 'E' Glass Needle Mat Intended use : Sound and Heat Insulation NOTE: THIS PRODUCT SHOULD NOT BE USED FOR OTHER PURPOSES WITHOUT EXPERT ADVICE. The (UK) Health & Safety Executive enforce an occupational exposure limit as a Maximum Exposure Limit of 5mg m3 as measured by personal (breathing zone) monitoring. (For microfine fibres the HSE enforce a standard of 1 fibre/ml of air as an Occupational Exposure Standard.) COMPOSITION A typical composition of A' Glass is as follows: Si02 (Silicon Dioxide) 54.2% A1203 (Aluminium Oxide) 15.2% Ca0 (Calcium Oxide) 17.3% Mg0 (Magnesium Oxide) 4.7% Na20 (Aluminium Oxide) 0.6% B203 (Boron Oxide) 8.0% PROPERTIES Needle Mat comprises selected long filament E' Glass fibres, consolidated by a well established mechanical process to form a felt material which contains no organic or resinous binding agents. The average diameter of the fibre ranges from 6-15 microns. The information in this safety data sheet was obtained from reputable sources and to the best of our knowledge,is accurate and current at the mentioned date. Neither the manufacturer, its subsidiary companies of JCB Service accept any liability arising out of the use of the information provided here or the use, application or processing of the product(s) described herein. Attention of users is drawn to the possible hazards from improper use of the product(s). For Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 * * Note: Items marked with an asterisk (*) have been amended since last issue. LOC/SDS128932/3.6.93 9804/9006 ISSUE 1, FEBRUARY 1997 Surface Primer Component CAS Number Concentration Ranges EEC Symbol/Risk Phrases n-Hexane 110-54-3 1-<5% Xn F R11 R48/20 Highly Flammable. Eye: Slightly irritating but does not injure eye tissue. Skin Contact: Repeated of prolonged contact may cause defatting of the skin, which may lead to skin irritation and/or dryness. Inhalation: Avoid breathing vapours or mists. High vapour concentrations are irritating to the eyes and the respiratory tract. Vapours cause headaches and dizziness, are anaesthetic and may have other effects on the central nervous system. Ingestion: Low order of toxicity. 4. FIRST-AID MEASURES Eye: Flush eyes with large amounts of water until irritation subsides. If irritation persists, get medical attention. Skin Contact: Flush with large amounts of water; use soap if available. Inhalation: Remove to fresh air. Ingestion: If swallowed, DO NOT induce vomiting. Keep at rest. Get prompt medical attention. 9804/9006 ISSUE 1, FEBRUARY 1997 5. FIRE-FIGHTING MEASURES Autoflammability: >200 °C Flash Point: -26 °C (Tagliabue Closed Tester/Tag Closed Tester) Extinguishing Media: Dry chemical; Foam Special Firefighting Procedures: Fire fighters should be equipped with self-contained breathing apparatus to protect against potentially toxic and irritating fumes. Water or water foam can cause frothing which can be violent, especially if sprayed into container of hot burning liquid, and can possibly endanger fire fighter. Fire & Explosion Hazards: Dangerous fire hazard when exposed to heat or flame. Hazardous Combustion Products: Thermal decomposition may release toxic and/or hazardous gases. Upper Explosion Limit (%): 7.4 Lower Explosion Limit (%): 1.1 6. ACCIDENTAL RELEASE MEASURES Spill and Leak Procedures: Shut off ignition sources. Stop leak if you can do it without risk. For small liquid spills, take up with sand or other absorbent material. For larger spills, dam far ahead of spill for later disposal. No smoking, flames or flares in hazard area. Keep unnecessary people away. For safety and environmental precautions, please review entire Safety Data Sheet for necessary information. 7. HANDLING AND STORAGE Recommended Uses: Accelerator Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 PG905/14/2/96 9804/9005 ISSUE 2, (REV) SEPTEMBER 2002 COMPONENT EC NUMBER CONCENTRATION EC SYMBOL FULL TEXT OF RISK PHRASES FOR INGREDIENTS INDICATED IN SECTION 2: Methacrylic acid R35 - Causes severe burns. R21/22 - Harmful in contact with skin and if swallowed. Cumene hydroperoxide R7 - May cause fire. R21/22 - Harmful in contact with skin and if swallowed. R48/20/22 - Harmful: danger of serious damage to health by prolonged exposure through inhalation and if swallowed. R23 - Toxic by inhalation. R34 - Causes burns. R37 - Irritating to respiratory system. R51/53 - Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. N,N-Dimethyl-p-toluidine R23/24/25 - Toxic by inhalation, in contact with skin and if swallowed. R33 - Danger of cumulative effects. R52/53 - Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Directives 1999/45/EC and 91/155/EEC have been considered when compiling this SDS; the information is provided for health and safety assessment by an industrial user. Reference should be made to any relevant local or national health, safety, and environmental legislation. This information does not constitute indication of suitability for specific uses. Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 Note: Items marked with an asterisk (*) have been amended since last issue. 9804/8990 ISSUE 4, NOVEMBER 1997 Preparation – Hazardous Components Component Min% Max% Future revisions will incorporate such information as is required but which is not available at this time. This information is given in good faith and based on information believed to be reliable. This document is not a specification and properties shown are not guaranteed. Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 * Note: Items marked with an asterisk (*) have been amended since last issue. SKP206 1.00 GB 17/11/96 9804/9011 ISSUE 4, (REV) MARCH 2003 JCB Biodegradable Hydraulic Fluid International Product code & Name: 32082 HYDRA 46 Description: Hydraulic Oil Name % Wt CAS No. EC No. Fatty acid ester 95 - 99.99 CBI Additive 1 - 2.99 CBI Warning statement None considered necessary. Acute effects of exposure to man Inhalation Vapours or mist in unusually high concentrations, as from exposure in poorly ventilated areas or confined spaces, may cause irritation of the nose and throat, headache, nausea and drowsiness. Skin Contact Brief contact is not irritating. Prolonged contact, as with clothing wetted with material, may cause defatting of skin or irritation, seen as local redness with possible mild discomfort. Eye Contact May cause minimal irritation, experienced as temporary discomfort. Ingestion No adverse effects expected. If more than several mouthfuls are swallowed, abdominal discomfort, nausea, and diarrhoea may occur. Continued..... 9804/9011 ISSUE 4, (REV) MARCH 2003 None All information contained in this Material Safety Data Sheet and, in particular, the health and safety and environmental information is accurate to the best of our knowledge and belief as at the date of issue specified. However, the Company makes no warranty or representation, express or implied, as to the accuracy or completeness of such information. The provision of this Material Safety Data Sheet is not intended, of itself, to obviate the need for all users to satisfy themselves that the product described is suitable for their individual purposes and that the safety precautions and environmental advice are adequate for their individual purposes and situation. Further, it is the user’s obligation to use this product safely and to comply with all applicable laws and regulations concerning the use of the product. continued.... 9804/9011 ISSUE 4, (REV) MARCH 2003 Chemical Names and Synonyms: Petroleum Hydrocarbons Use: Rust preventative. Note: This product should not be used for any other purpose without expert advice. COSHH Regulations: Product reviewed and no action under COSHH considered necessary. Note: JCB products are not formulated to contain PCBS. It is believed that all the information given in this bulletin (which supersedes all previous issues) is accurate at the time of printing. Such information is offered in good faith but without guarantee and without any representation that the product concerned is suitable for any particular use or application. Without limitation of the foregoing, nothing herein shall be construed as a recommendation for uses which infringe valid patents or as extending any license under valid patents. JCB pursues a policy of constant research and development aimed at product improvement and, therefore, reserves the right to change formulation, specification and characteristics of its products without notice. User should verify current specifications with JCB and ascertain that products are suitable for intended uses or applications. Where the information provided herein discloses a potential hazard or hazardous ingredient, adequate warning must be provided to employees and users and appropriate precautions taken, including the practice of good industrial hygiene. Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 667089-63/08.08.95 9804/8961 ISSUE 2 (REV.), MARCH 1997 Emergency Contact : Emergency Telephone No.: +44 (0) 1889 590312 2. COMPOSITION/INFORMATION ON INGREDIENTS Ingredients considered hazardous to health: This product is not hazardous to health as defined by the EC Dangerous Substances/Preparations Directives. See Section 15 for a regulatory analysis of the ingredients. Effects of overexposure: No significant effects expected. 4. FIRST-AID MEASURES Eye Contact: Flush thoroughly with water. If irritation occurs, call a doctor. Skin Contact: Wash contact areas with soap and water. High pressure accidental injection through the skin requires IMMEDIATE medical attention for possible incision, irrigation and/or debridement. Inhalation: Not expected to be a problem. Ingestion: Not expected to be a problem. However, if greater than 1/2 litre (pint) is ingested or if feeling uncomfortable, give 1 to 2 glasses of water and obtain medical attention or call an ambulance for assistance. DO NOT INDUCE VOMITING or give anything by mouth to an unconscious person. 9804/8961 ISSUE 2 (REV.), MARCH 1997 5. FIRE-FIGHTING MEASURES Extinguishing Media: Carbon dioxide, foam, dry chemical and water fog. Special fire fighting procedures: Water or foam may cause frothing. Use water to keep fire exposed containers cool. Water spray may be used to flush spills away from exposures. Prevent runoff from fire control or dilution from entering waterways or drinking water supply. Special protective equipment: For fires in enclosed areas, firefighters MUST use self-contained breathing apparatus. Unusual fire and explosion hazards: None. Flash Point °C (°F): >204 (400) (Estimated (Oil COC)). Flammable limits - LEL NA, UEL NA. NFPA Hazard ID: Health: 0 Flammability: 1 Reactivity: 0 Hazardous decomposition products: Metal oxides. Carbon monoxide. 6. ACCIDENTAL RELEASE MEASURES Notification Procedures: Report spills as required to appropriate authorities such as the local Environmental Health Officer or Fire Brigade. If spills are likely to enter any drain, waterway or groundwater, contact the Area Water Authority. Procedures if Material is Released or Spilled: Contain and absorb on fire retardant treated sawdust, diatomaceous earth, etc. Shovel up and dispose of at an appropriate licensed waste disposal site in accordance with current applicable laws and regulations and product characteristics at time of disposal. Environmental Precautions: Prevent spills from entering storm sewers or drains and contact with soil. Personal Precautions: See Section 8. 7. HANDLING AND STORAGE Handling: No special precautions are necessary beyond normal good hygiene practices. See Section 8 for additional personal protection advice when handling this product. Chemical Names and Synonyms: Pet. hydrocarbons and additives Use: Extreme pressure grease. Note: This product should not be used for any other purpose without expert advice. COSHH Regulations: Product reviewed and no action under COSHH considered necessary. Note: JCB lubricant products are not formulated to contain PCBS. It is believed that all the information given in this bulletin (which supersedes all previous issues) is accurate at the time of printing. Such information is offered in good faith but without guarantee and without any representation that the product concerned is suitable for any particular use or application. Without limitation of the foregoing, nothing herein shall be construed as a recommendation for uses which infringe valid patents or as extending any license under valid patents. JCB pursues a policy of constant research and development aimed at product improvement and, therefore, reserves the right to change formulation, specification and characteristics of its products without notice. User should verify current specifications with JCB and ascertain that products are suitable for intended uses and applications. Where the information provided herein discloses a potential hazard or hazardous ingredient, adequate warning must be provided to employees and users and appropriate precautions taken, including the practice of good industrial hygiene. Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 619262-63/08.08.95 9804/9010 ISSUE 1, MAY 1997 Emergency Contact : Emergency Telephone No.: +44 (0) 1889 590312 Description: A gloss finish supplied in an aerosol dispenser. Based on an alkyd resin system with lead chromate pigments and containing white spirit and acetone solvents and aerosol propellant. 2. COMPOSITION/INFORMATION ON INGREDIENTS The following ingredients have recognised health effects and are present in concentrations above the limits laid down in the Chemicals (Hazard Information and Packaging for Supply) Regulations 1994 (CHIP 2). Weight Risk CAS Substance in paint Full details of R-phrases are as follows:- R22 Harmful if swallowed R33 Danger of cumulative effects R40 Possible risk of irreversible effects R61 May cause harm to the unborn child R62 Possible risk of impaired fertility cont’d 9804/9010 ISSUE 1, MAY 1997 Full details of the hazard classifications are as follows:- Repr. Cat. 1 Toxic for reproduction - Category 1 Repr. Cat. 3 Toxic for reproduction - Category 3 Carc. Cat. 3 Carcinogenic - Category 3 Further information about hazard classifications can be found in the Approved Guide to the Classification and Labelling of Substances and Preparations Dangerous for Supply. The information in this data sheet is provided in accordance with the requirements of the Chemicals (Hazard Information and Packaging for Supply) Regulations 1994. The product should not be used for purposes other than those shown in Section 1 without first referring to the supplier and obtaining written handling instructions. As the specific conditions of use are outside the supplier’s control, the user is responsible for ensuring that the requirements of relevant legislation are complied with. The information contained in this data sheet is based on the present state of knowledge and current national legislation. It provides guidance on health, safety and environmental aspects of the product and should not be construed as any guarantee of technical performance or suitability for particular applications. Further information and relevant advice can be found in:- The Chemicals (Hazard Information and Packaging for Supply) Regulations 1994 (SI 1994 : 3247) Highly Flammable Liquids and Liquefied Petroleum Gases Regulations 1972 (SI 1972 : 917) Control of Lead at Work Regulations 1980 (SI 1980 : 1248) Control of Substances Hazardous to Health Regulations 1988 (SI 1988 : 1657) Manual Handling Operations Regulations 1992 (SI 1992: 2793) Environmental Protection (Duty of Care) Regulations 1992 (SI 1992 : 2839) Occupational Exposure Limits, EH40 The storage of flammable liquids in containers, HS(G)51 Storage of Packaged Dangerous Substances, HS(G)71 Approved Guide to the Classification and Labelling of Substances and Preparations Dangerous for Supply (Second Edition), L63 The Approved Supply List, L61 The Approved Code of Practice: Safety Data Sheets for Substances and Preparations Dangerous for Supply, L62 Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 4200/5305/11.09.96 9804/9009 ISSUE 1, MARCH 1997 Emergency Contact : Emergency Telephone No.: +44 (0) 1889 590312 Description: A gloss finish supplied in an aerosol dispenser. Based on an alkyd resin system with lead chromate pigments and containing white spirit and acetone solvents and aerosol propellant. 2. COMPOSITION/INFORMATION ON INGREDIENTS The following ingredients have recognised health effects and are present in concentrations above the limits laid down in the Chemicals (Hazard Information and Packaging for Supply) Regulations 1994 (CHIP 2). Weight Risk CAS Substance in paint Full details of R-phrases are as follows:- R22 Harmful if swallowed R33 Danger of cumulative effects R40 Possible risk of irreversible effects R61 May cause harm to the unborn child R62 Possible risk of impaired fertility cont’d 9804/9009 ISSUE 1, MARCH 1997 Full details of the hazard classifications are as follows:- Repr. Cat. 1 Toxic for reproduction - Category 1 Repr. Cat. 3 Toxic for reproduction - Category 3 Carc. Cat. 3 Carcinogenic - Category 3 Further information about hazard classifications can be found in the Approved Guide to the Classification and Labelling of Substances and Preparations Dangerous for Supply. The information in this data sheet is provided in accordance with the requirements of the Chemicals (Hazard Information and Packaging for Supply) Regulations 1994. The product should not be used for purposes other than those shown in Section 1 without first referring to the supplier and obtaining written handling instructions. As the specific conditions of use are outside the supplier’s control, the user is responsible for ensuring that the requirements of relevant legislation are complied with. The information contained in this data sheet is based on the present state of knowledge and current national legislation. It provides guidance on health, safety and environmental aspects of the product and should not be construed as any guarantee of technical performance or suitability for particular applications. Further information and relevant advice can be found in:- The Chemical (Hazard Information and Packaging for Supply) Regulations 1994 (SI 1994 : 3247) Highly Flammable Liquids and Liquefied Petroleum Gases Regulations 1972 (SI 1972 : 917) Control of Lead at Work Regulations 1980 (SI 1980 : 1248) Control of Substances Hazardous to Health Regulations 1988 (SI 1988 : 1657) Manual Handling Operations Regulations 1992 (SI 1992: 2793) Environmental Protection (Duty of Care) Regulations 1992 (SI 1992 : 2839) Occupational Exposure Limits, EH40 The storage of flammable liquids in containers, HS(G)51 Storage of Packaged Dangerous Substances, HS(G)71 The Approved Guide to the Classification and Labelling of Substances and Preparations Dangerous for Supply (Second Edition), L63 Approved Supply List, L61 The Approved Code of Practice: Safety Data Sheets for Substances and Preparations Dangerous for Supply, L62 Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 4200/6005/11.09.96 9804/9012 ISSUE 2, NOVEMBER 1997 Emergency Contact : Emergency Telephone No.: +44 (0) 1889 590312 Description: Based on a 2-pack isocyanate free acrylic epoxy resin system with inorganic pigments and containing naphtha, xylene and 1-methoxypropan-2-ol solvents. 2. COMPOSITION/INFORMATION ON INGREDIENTS The following ingredients have recognised health effects and are present in concentrations above the limits laid down in the Chemicals (Hazard Information and Packaging for Supply) Regulations 1994 (CHIP 2). Weight Risk CAS Substance in paint Full details of R-phrases are as follows:- R20/21 Harmful by inhalation and in contact with skin. R33 Danger of cumulative effects R36/38 Irritating to eyes and skin R37 Irritating to respiratory system R38 Irritating to skin R40 Possible risk of irreversible effects R61 May cause harm to the unborn child R62 Possible risk of impaired fertility Full details of the hazard classifications are as follows:- Repr. Cat. 1 Toxic for reproduction - Category 1 Repr. Cat. 3 Toxic for reproduction - Category 3 Carc. Cat. 3 Carcinogenic - Category 3 Further information about hazard classifications can be found in the Approved Guide to the Classification and Labelling of Substances and Preparations Dangerous for Supply. The information in this data sheet is provided in accordance with the requirements of the Chemicals (Hazard Information and Packaging for Supply) Regulations 1994. The product should not be used for purposes other than those shown in Section 1 without first referring to the supplier and obtaining written handling instructions. As the specific conditions of use are outside the supplier’s control, the user is responsible for ensuring that the requirements of relevant legislation are complied with. The information contained in this data sheet is based on the present state of knowledge and current national legislation. It provides guidance on health, safety and environmental aspects of the product and should not be construed as any guarantee of technical performance or suitability for particular applications. Further information and relevant advice can be found in:- The Chemicals (Hazard Information and Packaging for Supply) Regulations 1994 (SI 1994 : 3247) Control of Lead at Work Regulations 1980 (SI 1980 : 1248) Control of Substances Hazardous to Health Regulations 1988 (SI 1988 : 1657) Manual Handling Operations Regulations 1992 (SI 1992: 2793) Environmental Protection (Duty of Care) Regulations 1992 (SI 1992 : 2839) Occupational Exposure Limits, EH40 The storage of flammable liquids in containers, HS(G)51 Storage of Packaged Dangerous Substances, HS(G)71 Approved Guide to the Classification and Labelling of Substances and Preparations Dangerous for Supply (Second Edition), L63 The Approved Supply List, L76 The Approved Code of Practice: Safety Data Sheets for Substances and Preparations Dangerous for Supply, L62 cont’d 9804/9012 ISSUE 2, NOVEMBER 1997 Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 * Note: Items marked with an asterisk (*) have been amended since last issue. 06.03.97/Rev. 6 9804/8942 ISSUE 2, FEBRUARY 1998 Lead, lead compounds and <35% sulphuric acid in a polypropylene or hard rubber case. - Sulphuric acid is corrosive. It will cause burns and irritation to skin, eyes and respiratory tract. - An explosive mixture of hydrogen and oxygen is given off during charging. - Conductive objects in contact with live battery terminals can become hot enough to burn the skin. Sparks and molten metal may be ejected and could result in fire or explosion. *4. FIRST-AID MEASURES Inhalation: Remove to fresh air, seek medical attention. Skin Contact: Immediately drench the affected area with clean water and remove any contaminated clothing. If any soreness or irritation persists seek medical advice. Eye Contact: Immediately wash out the eyes with clean water for at least 10 minutes and always seek medical attention. Ingestion: Do NOT induce vomiting. Make the patient drink as much water as possible and seek medical attention. Burns: Apply a sterile dressing and seek medical attention. 9804/8942 ISSUE 2, FEBRUARY 1998 *5. FIRE-FIGHTING MEASURES Extinguishing Media: Dry powder, CO2, water spray. Special Hazards: Burning batteries will produce toxic fumes from the lead, acid and case material. Protective Equipment: Self contained respiratory equipment must be worn when dealing with fires. *6. ACCIDENTAL RELEASE MEASURES - Evacuate people from the affected area. Stop all smoking, eliminate sources of ignition and wear full protective clothing and chemical grade eye protection before dealing with the situation. - Use sand dams to confine the spread of liquid and to prevent entry into drains not intended for corrosive liquids. Cover spillage liberally with soda ash or sodium bicarbonate until neutralised. Mop up cautiously using plenty of water. See DISPOSAL CONSIDERATIONS for information on disposal of residue from fire and spillages. *7. HANDLING AND STORAGE - Do not wear nylon clothing, use insulated tools and remove or cover rings and bracelets with insulating material when working on or handling batteries. - Keep all sources of ignition away from batteries. - NEVER short circuit the terminals to establish whether or not a battery is charged. - Keep the electrolyte topped up to the correct level. - Recharge batteries at the rate recommended by the manufacturer in a well ventilated area. - Disconnect the battery before working on or near any exposed part of the vehicle electrical system. - Store batteries upright in single layers in a well ventilated area, never obstruct the cell vents. - Batteries are heavy; correct lifting techniques should be employed when lifting and handling. *8. EXPOSURE CONTROLS/PERSONAL PROTECTION When there is a risk from acid splashes wear chemical goggles or a full face screen and acid proof protective clothing including gloves and boots. Exposure to sulphuric acid mist generated during charging should be controlled by good natural ventilation or by local exhaust ventilation down to the current Occupational Exposure Standard given in the UK HSE Guidance Note EH40. Contact with lead is restricted to the battery terminals unless the case is damaged. Always wash your hands with soap and warm water after handling batteries. *9. PHYSICAL AND CHEMICAL PROPERTIES The lead and lead compounds are in the form of solids which can only be exposed if the battery case is damaged. Sulphuric acid is a corrosive liquid which can escape through the cell vents if the battery is tipped over. 9804/8942 ISSUE 2, FEBRUARY 1998 *10. STABILITY AND REACTIVITY Sulphuric acid will react violently with other acids, alkalis and oxidising agents. In some cases toxic fumes may be evolved. Chlorine gas is given off when sea water enters a lead-acid battery, top up with pure fresh water only. JCB Powermaster Batteries - safe charging and use, refer to JCB Publication No. 9804/9008. For instructions for commissioning JCB Dry Charged Batteries refer to JCB Publication No. 9804/9013 and manufacturers recommendations which may be attached to dry charged batteries. A copy of these two publications can be found on the JCB Service Technical Information for Parts and Service (T.I.P.S.) CD ROM in a folder called ‘Battery’. Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 * Note: Items marked with an asterisk (*) have been amended since last issue. 9804/9014 ISSUE 1, AUGUST 1999 Ingredients considered Hazardous to Health: This product is not hazardous to health as defined by the EC Dangerous Substances/Preparations Directives. See Section 15 for a regulatory analysis of the ingredients. Effects of Overexposure: No Significant effects expected. 4. FIRST-AID MEASURES Eye Contact: Flush thoroughly with water. If irritation occurs, call a doctor. Skin Contact: Wash contact areas with soap and water. High pressure accidental injection through the skin requires IMMEDIATE medical attention for possible incision, irrigation and/or debridement. Inhalation: If inhalation of fumes irritates the nose or throat or causes coughing, remove to fresh air. If irritation continues call a doctor. Ingestion: Not expected to be a problem. However, if greater than 1/2 litre (1 pint) is ingested or if feeling uncomfortable, give 1 to 2 glasses of water and obtain medical attention or call an ambulance for assistance. DO NOT INDUCE VOMITING or give anything by mouth to an unconscious person. 9804/9014 ISSUE 1, AUGUST 1999 5. FIRE-FIGHTING MEASURES Extinguising Media: Carbon dioxide, foam, dry chemical and water fog. Special Fire Fighting Procedures: Water or foam may cause frothing. Use water to keep fire exposed containers cool. Water spray may be used to flush spills away from exposures. Prevent runoff from fire control or dilution from entering waterways or drinking water supply. Special Protective Equipment: For fires in enclosed areas, firefighters MUST use self-contained breathing apparatus. Unusual Fire and Explosion Hazards: None. Flash Point > 204 °C (400 °F) (Estimated (Oil COC)). Flammable Limits LEL NA, UEL NA NFPA Hazard ID: Health 0, Flammability 1, Reactivity 0 Hazardous Decomposition Products: Carbon Monoxide. 6. ACCIDENTAL RELEASE MEASURES Notification Procedures: Report spills as required to appropriate authorities such as the local Environmental Health Officer or Fire Brigade. If spills are likely to enter any drain, waterway or groundwater, contact the Area Water Authority. In case of accident or road spill, contact the Police and Fire Brigade and, if appropriate, the Area Water Authority. Procedures if Material is Released or Spilled: Absorb using absorbent clay, sand or other suitable absorbent. Shovel up and dispose of at an appropriate licensed waste dispostal site in accordance with current applicable laws and regulations and product characteristics at time of disposal. Environmental Precautions: Prevent spills from entering storm sewers or drains and contact with soil. Personal Precautions: See Section 8. 7. HANDLING AND STORAGE Handling: No special precautions are necessary beyond normal good hygiene practices. See Section 8 for additional personal protection advice when handling this product. Chemical Names and Synonyms: Severe treat min. oils & additives. Use: Automotive grease. Note: This product should not be used for any other purpose without expert advice. COSHH Regulations: Product reviewed and no action under COSHH considered necessary. Note: JCB products are not formulated to contain PCBS. It is believed that all the information given in this bulletin (which supersedes all previous issues) is accurate at the time of printing. Such information is offered in good faith but without guarantee and without any representation that the product concerned is suitable for any use or application. Without limitation of the foregoing, nothing herein shall be construed as a recommendation for uses which infringe valid patents or as extending any licence under valid patents. JCB pursues a policy of constant research and development aimed at product improvement and, therefore, reserves the right to change formulation, specification and characteristics of its products without notice. User should verify current specifications with JCB and ascertain that products are suitable for intended uses and applications. Where the information provided herein discloses a potential hazard or hazardous ingredient, adequate warning must be provided to employees and users and appropriate precautions taken, including the practice of good industrial hygiene. Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 9804/9015 ISSUE 1, JULY 2000 ' Product Name: JCB Extreme Performance Multigrade Engine Oil 15W40 * Grades: ,-.'#"/0)"&'#*/0!"' ' * Use: 1234567859 ';5<'=;4'728;>;85?@'@9 59@A' ' Distributor: BCD',.EFGC.' ' * Emergency Contact : .>@4:@96H'I@<@JK;9@'L;MN'O!!'P"Q'#%%R'*R")#(' ' ,@?@4@<H'A;<?@98'4@=59@S'>59@47<';5<'P7JJ4M'R(TQ' -SS585?@A'P7JJ4M'%TQ&'>759<HN' U596'7<VH<S58K5;JK;AJK78@' C7<652>$>7:9@A52>'A2<JK;978@A'W'JK@978@A' XHS4;6743;9'J;<H>@4A' C_LC-/.'4@J;48'9;M'*$%Z'iK@7<8K'7AJ@68';='<23456798Aj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d278@']74959 '>2A8' 3@'J4;?5S@S'8;'@>J<;H@@A'79S'2A@4A'79S'7JJ4;J4578@'J4@67285;9A'87V@9&'596<2S59 '8K@'J476856@';=' ;;S'59S2A8457<' KH:5@9@M' ' ^248K@4'G9=;4>785;9'6;98768N' ' JCB SERVICE WORLD PARTS CENTRE UTTOXTER STAFFORDSHIRE ST14 7BS TEL: + 44 (0) 1889 590312 • Note: G8@>A'>74V@S']58K'79'7A8@45AV'P*Q'K7?@'3@@9'7>@9S@S'A596@'<7A8'5AA2@M' ' 9804/9015 ISSUE 1, JULY 2000 9804/9016 ISSUE 1, JULY 2000 ( Product Name: JCB Extreme Performance Multigrade Hydraulic Fluid ( •••• Grades: ,-.(/0()#'(!&( •••• Use 1234567859 (;5<(=;4(>?@472<56(AB25CDA98( ( Distributor: EFG(-HI/,FH( ( Emergency Contact HDA4 A96?(JA<AC>;9A(K;LM(N!!(O"P(%QQR(*R")%#( ( -ASA4A<?(T;<SA98(4A=59A@(D59A47<(;5<(O7CC4;UL(R)VPL( W@@585SAT(O7CC4;UL(XVP'(D759<?M( Y596(7<Z?<@58>5;C>;TC>78A( [;<?(7<Z?<(DA8>764?<78A( W985;U5@798T( I2T8(59>5358;4T( Recommended Uses: Accelerator Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 PB950A/14/2/96 9804/9019 ISSUE1, JANUARY 2002 JCB Service Sheen Aerosol Description: A sheen finish supplied in an aerosol dispenser. Based on an alkyd resin system with inorganic pigments and containing white spirit and acetone solvents and aerosol propellant. Supplier: Emergency Contact : Emergency Telephone No.: +44 (0) 1889 590312 2. COMPOSITION/INFORMATION ON INGREDIENTS The following ingredients have recognised health effects or exposure limits, and are present in concentrations above the limits laid down in the Chemicals (Hazard Information and Packaging for Supply) Regulations 1994 (CHIP 2). Substance Weight in Full details of R-phrases are as follows:- R36 Irritating to eyes R65 Harmful: may cause lung damage if swallowed R66 Repeated exposure may cause skin dryness or cracking The information in this data sheet is provided in accordance with the requirements of the Chemicals (Hazard Information and Packaging for Supply) Regulations 1994. The product should not be used for purposes other than those shown in Section 1 without first referring to the supplier and obtaining written handling instructions. As the specific conditions of use are outside the supplier's control, the user is responsible for ensuring the requirements of relevant legislation are complied with. The information contained in this data sheet is based on the present state of knowledge and current national legislation. It provides guidance on health, safety and environmental aspects of the product and should not be construed as any guarantee of technical performance or suitability for particular applications. Further information and relevant advice can be found in: The Chemical (Hazard Information and Packaging for Supply) Regulations 1994 (SI 1994:3247) and amendments. Petroleum (Consolidation) Act 1928 Control of Substances Hazardous to Health Regulations 1999 (SI 1999:437) Manual Handling Operations Regulations 1992 (SI 1992:2793) Environmental Protection (Duty of Care) Regulations 1992 (SI 1992:2839) Occupational Exposure Limits, EH40 (revised annually) The storage of flammable liquids in containers, HS(G)51 Chemical warehousing: the storage of packaged dangerous substances , HS(G)71 The Approved Guide to the Classification and Labelling of Substances and Preparations Dangerous for Supply (Fourth Edition), L100 The Approved Supply List, L124 The Approved Code of Practice: Safety Data Sheets for Substances and Preparations Dangerous for Supply, L62 Special Waste Regulations 1996 (SI 1996:972) and amendments The interpretation and use of flashpoint information, CS24 COSHH Essentials: easy steps to control chemicals, HS(G)193. Details of available Control Guidance Sheets, which may be relevant to the particular conditions of use, can also be found in HS(G)193. Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 Leigh’s 4/08/05/2001 9804/9020 ISSUE1, JANUARY 2002 JCB PDI Enhancer (25 litres) Tem No: Supplier: Emergency Contact : Emergency Telephone No.: +44 (0) 1889 590312 2. COMPOSITION/INFORMATION ON INGREDIENTS Contents amongst other ingredients: Raw Name Chip Index No. % W/W in Preparation Haz. Class.tn Non aromatic hydrocarbon >70% Xn, R65 Harmful: May cause lung damage if swallowed. Preparation is combustible. Hydrocarbon exposure can also cause drowsiness in confined areas. 4. FIRST-AID MEASURES No other usage is recommended unless advised in writing. OEL (vapour) 600 ppm OEL (mist) 5 ppm. The information is this datasheet is based on the present state of our knowledge of the product at the time of publication. It is given in good faith, no warranty is implied with respect to the quality or the specification of the product. The user must satisfy himself that the product is entirely suitable for his purpose. Cont’d 9804/9020 ISSUE1, JANUARY 2002 Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 9804/9022 ISSUE 1, JANUARY 2002 Emergency Contact : Emergency Telephone No.: +44 (0) 1889 590312 Description: A sheen finish for brush or spray application. Based on an alkyd resin system with inorganic and/or organis pigments and containing white spirit solvent. 2. COMPOSITION/INFORMATION ON INGREDIENTS The following ingredients have recognised health effects or exposure limits, and are present in concentrations above the limits laid down in the Chemicals (Hazard Information and Packaging for Supply) Regulations 1994 (CHIP 2). Weight Risk CAS Substance in paint Full details of R-phrases are as follows:- R65 Harmful: may cause lung damage if swallowed The information in this data sheet is provided in accordance with the requirements of the Chemicals (Hazard Information and Packaging for Supply) Regulations 1994. cont’d 9804/9022 ISSUE 1, JANUARY 2002 None Screenclear is a concentrated product for windscreen wiper systems only. For economic use: dilute with water according to the frost protection table, as given on label. All information is related to the product as supplied and is provided on the understanding that it will be used in the way and for purposes as indicated and that user has taken all necessary precautions. Information contained in the publication is true and accurate to the best of our knowledge. SDS distribution It is recommended that the handling and safety information presented in this safety data sheet be passed on, in an appropriate form, to your customers and handlers. Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 9804/9032 ISSUE1, JANUARY 2002 Ingredients considered hazardous to health This product is not hazardous to health as defined by the EC Dangerous Substances/Preparations Directives. See Section 15 for a regulatory analysis of the ingredients. Effects of overexposure: No significant effects expected. 4. FIRST-AID MEASURES Eye Contact: Flush thoroughly with water. If irritation occurs, call a doctor. Skin Contact: Wash contact areas with soap and water. High pressure accidental injection through the skin requires IMMEDIATE medical attention for possible incision, irrigation and/or debridement. Inhalation: Not expected to be a problem. Ingestion: Not expected to be a problem. However, if greater than 1/2 litre (pint) is ingested or if feeling uncomfortable, give 1 or 2 glasses of water and obtain medical attention or call an ambulance for assistance. DO NOT INDUCE VOMITING or give anything by mouth to an unconscious person. 9804/9032 ISSUE1, JANUARY 2002 5. FIRE-FIGHTING MEASURES Extinguishing Media: Carbon dioxide, foam, dry chemical and water fog. Special fire fighting procedures: Water or foam may cause frothing. Use water to keep fire exposed containers cool. Water spray may be used to flush spills away from exposures. Prevent runoff from fire control or dilution from entering waterways or drinking water supply. Special Protective Equipment: For fires in enclosed areas, firefighters MUST use self-contained breathing apparatus. Unusual fire and explosion hazards: None. Flash Point °C(°F): >204 (400) (IP 34/ASTM D-93) Flammable Limits: LEL NA. UEL NA. NFPA Hazard ID: Health: 0 Flammability: 1 Reactivity: 0 Hazardous decomposition products: Carbon monoxide. Metal oxides. Elemental oxides. 6. ACCIDENTAL RELEASE MEASURES Notification procedures: Report spills as required to appropriate authorities such as the local Environmental Health Officer or Fire Brigade. If spills are likely to enter any drain, waterway or groundwater, contact the Area Water Authority. In case of accident or road spill, contact the Police and Fire Brigade and, if appropriate, the Area Water Authority. Procedures if material is released or spilled: Shovel up and dispose of at an appropriate licensed waste disposal site in accordance with current applicable laws and regulations and product characteristics at time of disposal. Environmental Precautions Prevent spills from entering storm sewers or drains and contact with soil. Personal precautions: See Section 8. 7. HANDLING AND STORAGE Handling: High pressure injection under the skin may occur due to the rupture of pressurised lines. Always seek medical attention. Chemical Names and Synonyms: Severe Treat Min. Oils & Additives Use: Extreme pressure grease. Note: This product should not be used for any other purpose without expert advice. COSHH Regulations: Product reviewed and no action under COSHH considered necessary. Note: JCB Lubricant products are not formulated to contain PCBS. It is believed that all the information given in this bulletin (which supersedes all previous issues) is accurate at the time of printing. Such information is offered in good faith but without guarantee and without any representation that the product concerned is suitable for any particular use or application. Without limitation of the foregoing, nothing herein shall be construed as a recommendation for uses which infringe valid patents or as extending any licence under valid patents. JCB pursues a policy of constant research and development aimed at product improvement and, therefore, reserves the right to change formulation, specification and characteristics of its products without notice. User should verify current specifications with JCB and ascertain that products are suitable for intended uses or applications. Where the information provided herein discloses a potential hazard or hazardous ingredient, adequate warning must be provided to employees and users and appropriate precautions taken, including the practice of good industrial hygiene. Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 9804/9023 ISSUE 1, JANUARY 2002 Emergency Contact : Emergency Telephone No.: +44 (0) 1889 590312 Intended Use: For application by brush or low volume spray. 2. COMPOSITION/INFORMATION ON INGREDIENTS No relevant information. For details of substances presenting a health hazard within the meaning of the Chemicals (Hazard Information & Packing) regulations 1994 see under Section 8 of this Safety Data Sheet. Inhalation of vapours from this product can cause narcosis and, with continued exposure above the OEL, possible long term effects. Flammable - Harmful by inhalation and in contact with skin - Irritating to eyes, respiratory system and skin. Harmful: may cause lung damage if swallowed. 4. FIRST-AID MEASURES General: In all cases of doubt or when symptoms persist seek medical attention. Never give anything by mouth to an unconscious person. Inhalation: Remove to fresh air, keep warm and at rest. If breathing is irregular or stopped give artificial respiration. Give nothing by mouth. If unconscious place in recovery position and seek medical advice. cont’d 9804/9023 ISSUE 1, JANUARY 2002 Text of any Risk Phrases listed in Section 8 R10 Flammable R20/21 Harmful by inhalation and in contact with skin R22 Harmful if swallowed R36 Irritating to the eyes R36/37/38 Irritating to eyes, respiratory system and skin R37/38 Irritating to respiratory system and skin R41 Risk of serious damage to eyes R65 Harmful: may cause lung damage if swallowed R67 Date of last revision 23/12/96 The information in this data sheet is provided in accordance with the requirements of the Chemicals (Hazard Information and Packaging for Supply). The product should not be used for purposes other than those shown in Section 1 without first referring to the supplier and obtaining written handling instructions. As the specific conditions of use are outside the supplier’s control, the user is responsible for ensuring that the requirements of relevant legislation are complied with. The information contained in this data sheet is based on the present state of knowledge and current national legislation. It provides guidance on health, safety and environmental aspects of the product and should not be construed as any guarantee of technical performance or suitability for particular applications. Further information and relevant advice can be found in:- The Control of Substances Hazardous to Health Regulations 1994 (SI 1994 : 3246) Manual Handling Operations Regulations 1992 (SI 1992 : 2793) Storage of Flammable Liquids in Containers, HS(G)51 Storage of Packaged Dangerous Substances, HS(G)71 The Environmental Protection (Duty of Care) Regulations 1992 (SI 1988: 2839) Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 9804/9024 ISSUE 1, JANUARY 2002 Emergency Contact : Emergency Telephone No.: +44 (0) 1889 590312 Intended Use: Air drying paint/lacquer for industrial use only. Application by spray when mixed with recommended thinner. 2. COMPOSITION/INFORMATION ON INGREDIENTS A mixture of resins, pigments, mineral extenders and organic solvents as required. For details of substances presenting a health hazard within the meaning of the Chemicals (Hazard Information & Packing) regulations 1994 see under Section 8 of this Safety Data Sheet. Inhalation of vapours from this product can cause narcosis and, with continued exposure above the OEL, possible long term effects. Highly Flammable - Harmful by inhalation, in contact with skin and may cause lung damage if swallowed - Irritating to eyes, respiratory system and skin. 4. FIRST-AID MEASURES General: In all cases of doubt or when symptoms persist seek medical attention. Never give anything by mouth to an unconscious person. Inhalation: Remove to fresh air, keep warm and at rest. If breathing is irregular or stopped give artificial respiration. Give nothing by mouth. If unconscious place in recovery position and seek medical advice. cont’d 9804/9024 ISSUE 1, JANUARY 2002 Text of any Risk Phrases listed in Section 8 R10 Flammable R20/21 Harmful by inhalation and in contact with skin R22 Harmful if swallowed R36 Irritating to the eyes 9804/9024 ISSUE 1, JANUARY 2002 Information Sources: Dangerous Properties of Industrial Materials Report, N.Sax et.al. Revision Date: 11-00 Safety Data Sheet Status: Approved. This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company’s knowledge and belief, accurate and reliable as of the date indicated. However, no warranty, guarantee or representation is made as to its accuracy, reliability or completeness. It is the user’s responsibility to satisfy himself as to the suitability of such information for his own particular use. Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 9804/9027 ISSUE 1, JANUARY 2002 Emergency Contact : Emergency Telephone No.: +44 (0) 1889 590312 Description: A high performance polyurethane gloss finish application by spray or brush. Based on a two pack acrylic urethane resin system with inorganic and/or organic pigments and containing xylene, aromatic hydrocarbon and 1-methoxy-2-propyl acetate solvents. 2. COMPOSITION/INFORMATION ON INGREDIENTS The following ingredients have recognised health effects or exposure limits, and are present in concentrations above the limits laid down in the Chemicals (Hazard Information and Packaging for Supply) Regulations 1994 (CHIP 2). Substance Weight in Full details of R-phrases are as follows:- R20 Harmful by inhalation. R20/21 Harmful by inhalation and in contact with skin. R23 Toxic by inhalation R33 Danger of cumulative effects. R36 Irritating to eyes R36/37/38 Irritating to eyes, respiratory system and skin. R37 Irritating to respiratory system R38 Irritating to the skin R40 Possible risk of irreversible effects R42/43 May cause sensitisation by inhalation and skin contact. R43 May cause sensitisation by skin contact. R50 Very toxic to aquatic organisms R51 Toxic to aquatic organisms R53 May cause long-term adverse effects in the aquatic environment R61 May cause harm to the unborn child cont’d 9804/9027 ISSUE 1, JANUARY 2002 Text of any Risk Phrases listed in Section 8. R20/21 Harmful by inhalation and in contact with skin R20/21/65 Harmful by inhalation, in contact with skin and may cause lung damage if swallowed R33 Danger of cumulative effects R36/37/38 Irritating to eyes, respiratory system and skin R38 Irritating to the skin. R61 May cause harm to the unborn child Date of last revision 31/10/00 The information contained in this safety data sheet is provided in accordance with the requirements of the Chemicals (Hazard Information & Packaging) Regulations. The product should not be used for purposes other than those shown in Section 1 without first referring to the supplier and obtaining written handling instructions. As the specific conditions of use of the product are outside the supplier’s control the user is responsible for ensuring that the requirements of relevant legislation are complied with. TP-19 The information contained in this Safety Data Sheet is based on the present state of knowledge and current national legislation. It provides guidance on health, safety and environmental aspects of the product and should not be construed as any guarantee of technical performance or suitability for particular applications. Further information and relevant advice can be found in:- The Control of Substances Hazardous to Health Regulations 1994 (SI 1994: 3246) The Manual Handling Operations Regulations 1992 (SI 1992: 2793) Storage of Flammable Liquids in Containers. HS(G)51 Storage of Packaged Dangerous Substances HS(G)71 The Environmental Protection (Duty of Care) Regulations 1992 (SI 1988: 2839) Cont’d 9804/9030 ISSUE1, JANUARY 2002 Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 Carrs E8613 6/13/11/2001 9804/9031 ISSUE1, JANUARY 2002 Emergency Contact : Emergency Telephone No.: +44 (0) 1889 590312 Intended Use: For application by brush or low volume spray. 2. COMPOSITION/INFORMATION ON INGREDIENTS No relevant information. For details of substances presenting a health hazard within the meaning of the Chemicals (Hazard Information & Packing) regulations 1994 see Under Section 8 of the Safety Data Sheet. Inhalation of vapours from this product can cause narcosis and, with continued exposure above the OEL, possible long term effects. Flammable Harmful by inhalation and in contact with skin - Irritating to eyes, respiratory system and skin. Harmful May cause lung damage if swallowed. 4. FIRST-AID MEASURES General In all cases of doubt or when symptoms persist seek medical attention. Never give anything by mouth to an unconscious person. Inhalation: Remove to fresh air, keep warm and at rest. If breathing is irregular or stopped give artificial respiration. Give nothing by mouth. If unconscious place in recovery position and seek medical advice. cont’d 9804/9031 ISSUE1, JANUARY 2002 Eye Contact: Contact lenses should be removed. Irrigate copiously with clean, fresh water for at least 10 mins. holding the eyelids apart, seek medical advice. Skin Contact: Remove contaminated clothing. Wash skin thoroughly with soap and water or use a proprietary skin cleaner. Do NOT use solvents or thinners. Ingestion: If accidentally swallowed obtain immediate medical attention. Keep at rest. Do NOT induce vomiting. 5. FIRE-FIGHTING MEASURES Extinguishing Media: Carbon dioxide, Dry Powder, Sand, Foam. NOT TO BE USED - Water Special Instructions for Fire Fighting Personnel Fire will produce dense black smoke containing hazardous products of combustion (see Section 10). Decomposition products may be a hazard to health. Appropriate self-contained breathing apparatus may be required. Cool closed containers exposed to fire with a water spray. Do not allow run off from fire fighting to enter drains or water courses. 6. ACCIDENTAL RELEASE MEASURES Exclude sources of ignition and ventilate the area. Exclude non-essential personnel. Avoid breathing vapours. Refer to protective measures listed in sect. 7 & 8. Contain and collect spillages with non-combustible absorbent materials e.g. sand, earth and place in suitable container for disposal in accordance with the waste regulations. Do not allow to enter drains or water courses. If it does the local water company should be contacted immediately, in case of contamination of streams, rivers or lakes the Environment Agency. Clean preferably with a detergent, avoid use of solvents. 7. STORAGE AND HANDLING Do not use in areas where potential sources of ignition exist. Use non sparking tools and exclude sources of heat, sparks and flames. Keep container tightly closed. Never use pressure to empty, container is not a pressure vessel. Always keep in containers made of the same material as the supply container. Avoid skin and eye contact. For personal protection see Sect. 8. Good housekeeping, regular maintenance of spray booth filters, and regular removal of waste materials will minimise risks. Observe the label precautions. Store between 5 and 25 ºC in a dry well ventilated place away from sources of heat, ignition and direct sunlight. No smoking. Prevent unauthorised access. Containers which a re opened should be properly resealed and kept upright to prevent leakage. Store away from oxidising agents and strongly alkaline or acid materials. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Measures Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. If extraction methods are insufficient to maintain concentrations of particulates and /or solvent vapours below relevant OEL’s , suitable respiratory protective equipment should be worn. Substance Name % Conc Text of any Risk Phrases listed in Section 8. R20/21 Harmful by inhalation and in contact with skin R20/21/65 Harmful by inhalation, in contact with skin and may cause lung damage if swallowed R36/37/38 Irritating to eyes, respiratory system and skin R38 Irritating to the skin. The information contained in this safety data sheet is provided in accordance with the requirements of the Chemicals (Hazard Information & Packaging) Regulations. The product should not be used for purposes other than those shown in Section 1 without first referring to the supplier and obtaining written handling instructions. As the specific conditions of use of the product are outside the supplier’s control the user is responsible for ensuring that the requirements of relevant legislation are complied with. The information contained in this Safety Data Sheet is based on the present state of knowledge and current national legislation. It provides guidance on health, safety and environmental aspects of the product and should not be construed as any guarantee of technical performance or suitability for particular applications. Further information and relevant advice can be found in:- The Control of Substances Hazardous to Health Regulations 1994 (SI 1994: 3246) The Manual Handling Operations Regulations 1992 (SI 1992: 2793) Storage of Flammable Liquids in Containers. HS(G)51 Storage of Packaged Dangerous Substances HS(G)71 The Environmental Protection (Duty of Care) Regulations 1992 (SI 1988: 2839) Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 9804/9033 ISSUE 1, JANUARY 2002 Emergency Contact : Emergency Telephone No.: +44 (0) 1889 590312 Description: A sheen finish fOR spray application to suitably primed components. Based on a two pack epoxy resin system with inorganic pigments and containing aromatic hydrocarbon, 1-methoxpropan-2-ol and xylene solvents. 2. COMPOSITION/INFORMATION ON INGREDIENTS The following ingredients have recognised health effects or exposure limits, and are present in concentrations above the limits laid down in the Chemicals (Hazard Information and Packaging for Supply) Regulations 1994 (CHIP 2). Substance Weight in Full details of R-phrases are as follows:- R20/21 Harmful by inhalation and in contact with skin. R36/38 Irritating to eyes and skin R37 Irritating to respiratory system R38 Irritating to the skin R40 Possible risk of irreversible effects R51 Toxic to aquatic organisms R53 May cause long-term adverse effects in the aquatic environment R65 Harmful: may cause lung damage if swallowed The information in this data sheet is provided in accordance with the requirements of the Chemicals (Hazard Information and Packaging for Supply) Regulations 1994. The product should not be used for purposes other than those shown in Section 1 without first referring to the supplier and obtaining written handling instructions. As the specific conditions of use are outside the supplier's control, the user is responsible for ensuring the requirements of relevant legislation are complied with. The information contained in this data sheet is based on the present state of knowledge and current national legislation. It provides guidance on health, safety and environmental aspects of the product and should not be construed as any guarantee of technical performance or suitability for particular applications. Further information and relevant advice can be found in: The Chemical (Hazard Information and Packaging for Supply) Regulations 1994 (SI 1994:3247) and amendments. Highly Flammable Liquids and Liquefied Petroleum Gases Regulations 1972 (SI 1972:917) Control of Substances Hazardous to Health Regulations 1999 (SI 1999:437) Manual Handling Operations Regulations 1992 (SI 1992:2793) Environmental Protection (Duty of Care) Regulations 1992 (SI 1992:2839) Occupational Exposure Limits, EH40 (revised annually) The storage of flammable liquids in containers, HS(G)51 Chemical warehousing: the storage of packaged dangerous substances , HS(G)71 The Approved Guide to the Classification and Labelling of Substances and Preparations Dangerous for Supply (Fourth Edition), L100 The Approved Supply List, L124 The Approved Code of Practice: Safety Data Sheets for Substances and Preparations Dangerous for Supply, L62 Special Waste Regulations 1996 (SI 1996:972) and amendments The interpretation and use of flashpoint information, CS24 COSHH Essentials: easy steps to control chemicals, HS(G)193. Details of available Control Guidance Sheets, which may be relevant to the particular conditions of use, can also be found in HS(G)193. Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 9804/9034 ISSUE 1, JANUARY 2002 Emergency Contact : Emergency Telephone No.: +44 (0) 1889 590312 Description: A gloss finish for spray application to pre-painted components. Based on an isocyanate free acrylic epoxy resin system with inorganic and/or organic pigments and containing aromatic hydrocarbon, xylene and 1-methoxypropan-2-ol solvent. Also contains lead chromate pigment. 2. COMPOSITION/INFORMATION ON INGREDIENTS The following ingredients have recognised health effects or exposure limits, and are present in concentrations above the limits laid down in the Chemicals (Hazard Information and Packaging for Supply) Regulations 1994 (CHIP 2). Substance Weight in Full details of R-phrases are as follows:- R20/21 Harmful by inhalation and in contact with skin. R33 Danger of cumulative effects. R36/38 Irritating to eyes and skin R37 Irritating to respiratory system R38 Irritating to the skin R40 Possible risk of irreversible effects R50 Very toxic to aquatic organisms R51 Toxic to aquatic organisms R53 May cause long-term adverse effects in the aquatic environment R61 May cause harm to the unborn child R62 Possible risk of impaired fertility R65 Harmful: may cause lung damage if swallowed cont’d 9804/9034 ISSUE 1, JANUARY 2002 Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 9804/9021 ISSUE1, MARCH 2002 Emergency Contact : Emergency Telephone No.: +44 (0) 1889 590312 Commercial Application: Multi-purpose grease High-temperature extreme-pressure grease 2. COMPOSITION/INFORMATION ON INGREDIENTS Preparation Chemical Nature: Grease containing molybdenum sulphide, without heavy metals. Ingredients contributing to hazards: Benzoic acid cas 65-85-0 (Xi - R36/37)...............................about 2.4% Zinc alkyl di-thiophosphate (Xi, R38 - R41).........................about 1.4% Alyklated diphenylamines case 68411-46-1 (N : R51/53)...about 1.5% Inpurities contributing to hazards: None to our knowledge, in normal use The information contained in this data sheet is given in good faith and is accurate to the best of our knowledge at the date indicated above. It is understood by the user that any use of the product for purposes other than those for which it was designed entails potential risk. The information given herein in no way dispenses the user from knowing and applying all provision regulating his or her activity. The user bears sole liability for the precautions required when using the product. The regulatory texts indicated herein are intended to aid the user to fulfill his obligations. This list is not to be considered complete and exhaustive. It is the user’s responsibility to ensure that he is subject to no other obligations than those mentioned. Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 9804/9035 ISSUE 1, MARCH 2002 Emergency Contact : Emergency Telephone No.: +44 (0) 1889 590312 Description: Stoving paint/lacquer for industrial use only. Application by spray when mixed with recommended thinner. Polyisocyanate Hardener for admixture with appropriate paint product. For application by spray application. 2. COMPOSITION/INFORMATION ON INGREDIENTS Paint A mixture of resins, pigments, mineral extenders and organic solvents as required. Hardener A mixture of resins and Isocyanate Prepolymer with flammable organic solvents. For details of substances presenting a health hazard within the meaning of the Chemicals (Hazard Information & Packing) regulations 1994 see under Section 8 of this Safety Data Sheet. Paint Inhalation of vapours from this product can cause narcosis and, with continued exposure above the OEL, possible long term effects. Harmful: possible risk of irreversible effects through inhalation, in contact with skin and may cause lung damage if swallowed - Irritating to eyes, respiratory system and skin. Flammable - Danger of cumulative effects. cont’d 9804/9035 ISSUE 1, MARCH 2002 Text of any Risk Phrases used in Section 8. Paint R10 Flammable R20/21 Harmful by inhalation and in contact with skin R33 Danger of cumulative effects R38 Irritating to the skin R61 May cause harm to the unborn child Hardener R10 Flammable R20 Harmful by inhalation R20/21 Harmful by inhalation and in contact with skin. R20/21/22 Toxic by inhalation R36/37/38 Irritating to eyes, respiratory system and skin R38 Irritating to the skin R42 May cause sensitisation by inhalation R42/43 May cause sensitisation by inhalation and skin contact R43 May cause sensitisation by skin contact The information contained in this data sheet is provided in accordance with the requirements of the Chemicals (Hazard Information & Packaging) Regulations. The product should not be used for purposes other than those shown in Section 1 without first referring to the supplier and obtaining written handling instructions. As the specific conditions of use of the product are outside the supplier’s control the user is responsible for ensuring that the requirements of relevant legislation are complied with. TP-05 The information contained in this data sheet is based on the present state of knowledge and current national legislation. It provides guidance on health, safety and environmental aspects of the product and should not be construed as any guarantee of technical performance or suitability for particular applications. Further information and relevant advice can be found in: The Control of Substances Hazardous to Health Regulations 1994 (SI 1994: 3246) The Manual Handling Operations Regulations 1992 (SI 1992:2793) Storage of Flammable Liquids in Containers, HS(G)51 Storage of Packaged Dangerous Substances HS(G)71 The Environmental Protection (Duty of Care) Regulations 1992 (SI 1988:2839) Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 9804/9022 ISSUE 2 (REV), JUNE 2002 Emergency Contact : Emergency Telephone No.: +44 (0) 1889 590312 Description: A sheen finish for brush or spray application. Based on an alkyd resin system with inorganic and/or organis pigments and containing white spirit solvent. 2. COMPOSITION/INFORMATION ON INGREDIENTS The following ingredients have recognised health effects or exposure limits, and are present in concentrations above the limits laid down in the Chemicals (Hazard Information and Packaging for Supply) Regulations 1994 (CHIP 2). Weight Risk CAS Substance in paint Full details of R-phrases are as follows:- R65 Harmful: may cause lung damage if swallowed The information in this data sheet is provided in accordance with the requirements of the Chemicals (Hazard Information and Packaging for Supply) Regulations 1994. cont’d 9804/9022 ISSUE 2 (REV), JUNE 2002 Full details of R-phrases are as follows:- R36 Irritating to eyes R65 Harmful: may cause lung damage if swallowed R66 Repeated exposure may cause skin dryness or cracking The information in this data sheet is provided in accordance with the requirements of the Chemicals (Hazard Information and Packaging for Supply) Regulations 1994. The product should not be used for purposes other than those shown in Section 1 without first referring to the supplier and obtaining written handling instructions. As the specific conditions of use are outside the supplier's control, the user is responsible for ensuring the requirements of relevant legislation are complied with. The information contained in this data sheet is based on the present state of knowledge and current national legislation. It provides guidance on health, safety and environmental aspects of the product and should not be construed as any guarantee of technical performance or suitability for particular applications. Further information and relevant advice can be found in: The Chemical (Hazard Information and Packaging for Supply) Regulations 1994 (SI 1994:3247) and amendments. Petroleum (Consolidation) Act 1928 Control of Substances Hazardous to Health Regulations 1999 (SI 1999:437) Manual Handling Operations Regulations 1992 (SI 1992:2793) Environmental Protection (Duty of Care) Regulations 1992 (SI 1992:2839) Occupational Exposure Limits, EH40 (revised annually) The storage of flammable liquids in containers, HS(G)51 Chemical warehousing: the storage of packaged dangerous substances , HS(G)71 The Approved Guide to the Classification and Labelling of Substances and Preparations Dangerous for Supply (Fourth Edition), L100 The Approved Supply List, L124 The Approved Code of Practice: Safety Data Sheets for Substances and Preparations Dangerous for Supply, L62 Special Waste Regulations 1996 (SI 1996:972) and amendments The interpretation and use of flashpoint information, CS24 COSHH Essentials: easy steps to control chemicals, HS(G)193. Details of available Control Guidance Sheets, which may be relevant to the particular conditions of use, can also be found in HS(G)193. Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 Leigh’s 4/08/05/2001 9804/9025 ISSUE 2, SEPTEMBER 2002 Resin Chemical Family: Formulated Epoxy Resin Component EC Number Concentration EEC Symbol/Risk Phrases Epoxy resin >50% XI N R36/38 R43 R51/53 Trimethylolpropane 20- 35 XI R43 R36/38 R52/53 triglycidyl ether Hardener Component EC Number Concentration EEC Symbol/Risk Phrases Phenol derivative 5 - 10 XN XI R22 R36/38 For full text of risk phrases, please refer to Section 16. Resin Emergency Overview Irritant. Sensitiser. Dangerous for the environment. Eye: May cause eye irritation. Skin Contact: Irritating to the skin. Repeated and/or prolonged contact may cause skin sensitisation. Inhalation: Unlikely to be hazardous by inhalation because of the low vapour pressure of the material at Cont’d..... 9804/9025 ISSUE 2, SEPTEMBER 2002 Full text of phrases for ingredients indicated in section 2: Epoxy resin: R36/38 - Irritating to eyes and skin. R43 - May cause sensitisation by skin contact. R51/53 - Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Trimethylolpropanetriglycidyl ether: R43 - May cause sensitisation by skin contact. R36/38 - Irritating to eyes and skin. R52/53 - Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Phenol derivative: R22 - Harmful if swallowed R36/38 - Irritating to eyes and skin. Directives 1999/45/EC and 91/155/EEC have been considered when compiling this SDS; the information is provided for health and safety assessment by an industrial user. Reference should be made to any relevant local or national health, safety, and environmental legislation. This information does not constitute indication of suitability for specific uses. Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 Note: Items marked with an asterisk (*) have been amended since last issue. 9804/9036 ISSUE 1, AUGUST 2002 Emergency Contact : Emergency Telephone No.: +44 (0) 1889 590312 Description: Primer for paint and plastic surfaces for use with sealants/adhesives. 2. COMPOSITION/INFORMATION ON INGREDIENTS Substance Concentration Revisions Highlighted Main Hazards. R Phrases. Exposure controls. Personal protection. cont’d 9804/9036 ISSUE 1, AUGUST 2002 First Issue Date 20/01/1997 Revisions Highlighted Composition/Information on the Components. Main Hazards. Toxicological information. Labelling information. R Phrases. S Phrases. Uses and Restrictions Customers are urged to ensure that the product is entirely suitable for their own purpose. It is the customer’s responsibility to ensure that a suitable and sufficient assessment of the risks created by the use of the product is undertaken. UK Legislation Health and Safety at Work etc Act 1974, and relevant Statutory Provisions. Chemicals (Hazard Information and Packaging) Regulations, 2002 SI 1999/437: The Control of Substances Hazardous to Health Regulations SI no. 972/1996: The Special Waste Regulations 1996 SI no. 2839 1991 Environmental Protection (Duty of Care) Regulations UK Guidance Publications EH40, Occupational Exposure Limits, HSE. Revised Annually. General Approved Code of Practice to COSHH Regulations, HSE. cont’d 9804/9037 ISSUE 1, AUGUST 2002 Disclaimer: The information contained in this data sheet is based on the present state of knowledge and current national legislation. It provides guidance on health, safety and environmental aspects of the product and should not be construed as any guarantee of technical performance or suitability for particular applications. Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 * Note: Items marked with an asterisk (*) have been amended since last issue. 9804/8906 ISSUE 4, (REV.) MARCH 2003 Ingredients considered Hazardous to Health: This product is not hazardous to health as defined by the EC Dangerous Substances/Preparations Directives. See Section 15 for a regulatory analysis of the ingredients. Effects of Overexposure: No Significant effects expected. 4. FIRST-AID MEASURES Eye Contact: Flush thoroughly with water. If irritation occurs, call a doctor. Skin Contact: Wash contact areas with soap and water. Inhalation: Not expected to be a problem. Ingestion: Not expected to be a problem. However, if greater than 1/2 litre (pint) is ingested or if feeling uncomfortable, give 1 to 2 glasses of water and obtain medical attention or call an ambulance for assistance. DO NOT INDUCE VOMITING or give anything by mouth to an unconscious person. 9804/8906 ISSUE 4, (REV.) MARCH 2003 Chemical Names and Synonyms: Pet. Hydrocarbons and Additives Use: Automotive gear oil. Note: This product should not be used for any other purpose without expert advice. COSHH Regulations: Product reviewed and no action under COSHH considered necessary. Note: JCB products are not formulated to contain PCBS. It is believed that all the information given in this bulletin (which supersedes all previous issues) is accurate at the time of printing. Such information is offered in good faith but without guarantee and without any representation that the product concerned is suitable for any use or application. Without limitation of the foregoing, nothing herein shall be construed as a recommendation for uses which infringe valid patents or as extending any licence under valid patents. JCB pursues a policy of constant research and development aimed at product improvement and, therefore, reserves the right to change formulation, specification and characteristics of its products without notice. User should verify current specifications with JCB and ascertain that products are suitable for intended uses and applications. Where the information provided herein discloses a potential hazard or hazardous ingredient, adequate warning must be provided to employees and users and appropriate precautions taken, including the practice of good industrial hygiene. Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 593624 MOBIL/559047-63/30.05.93 9804/8912 ISSUE 5, (REV.) MARCH 2003 JCB Gear Oil EP 85W140 Grades: SAE 75W, 80W-90, 85W-140, 90 Use: Lubricating oil for automotive gears Emergency Contact : Emergency Telephone No.: +44 (0) 1889 590312 2. COMPOSITION/INFORMATION ON INGREDIENTS Severely solvent refined mineral oil (appr. 93%) Additives (appr. 7%), mainly: Organic sulphur and phosphorus containing compounds Poly alkyl methacrylate CONCAWE report no. 5/87 ‘health aspect of lubricants’. It is believed that all the information given in this bulletin (which supersedes all previous issues) is accurate at the time of printing. Such information is offered in good faith but without guarantee and without any representation that the product concerned is suitable for any use or application. Without limitation of the foregoing, nothing herein shall be construed as a recommendation for uses which infringe valid patents or as extending any license under valid patents. JCB pursues a policy of constant research and development aimed at product improvement and, therefore, reserves the right to change formulation, specification and characteristics of its products without notice. User should verify current specifications with JCB and ascertain that products are suitable for intended uses and applications. Where the information provided herein discloses a potential hazard or hazardous ingredient, adequate warning must be provided to employees and users and appropriate precautions taken, including the practice of good industrial hygiene. Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 * Note: Items marked with an asterisk (*) have been amended since last issue. Q8 T 55/1995-05-01 9804/8905 ISSUE 5, (REV.) MARCH 2003 Ingredients considered Hazardous to Health: This product is not hazardous to health as defined by the EC Dangerous Substances/Preparations Directives. See Section 15 for a regulatory analysis of the ingredients. Effects of Overexposure: No Significant effects expected. 4. FIRST-AID MEASURES Eye Contact: Flush thoroughly with water. If irritation occurs, call a doctor. Skin Contact: Wash contact areas with soap and water. High pressure accidental injection through the skin requires IMMEDIATE medical attention for possible incision, irrigation and/or debridement. Inhalation: Not expected to be a problem. Ingestion: Not expected to be a problem. However, if greater than 1/2 litre (1 pint) is ingested or if feeling uncomfortable, give 1 to 2 glasses of water and obtain medical attention or call an ambulance for assistance. DO NOT INDUCE VOMITING or give anything by mouth to an unconscious person. 9804/8905 ISSUE 5, (REV.) MARCH 2003 Chemical Names and Synonyms: Severe treat min oils & additives. Use: Transmission/hydraulic oil. Note: This product should not be used for any other purpose without expert advice. COSHH Regulations: Product reviewed and no action under COSHH considered necessary. Note: JCB products are not formulated to contain PCBS. It is believed that all the information given in this bulletin (which supersedes all previous issues) is accurate at the time of printing. Such information is offered in good faith but without guarantee and without any representation that the product concerned is suitable for any use or application. Without limitation of the foregoing, nothing herein shall be construed as a recommendation for uses which infringe valid patents or as extending any licence under valid patents. JCB pursues a policy of constant research and development aimed at product improvement and, therefore, reserves the right to change formulation, specification and characteristics of its products without notice. User should verify current specifications with JCB and ascertain that products are suitable for intended uses and applications. Where the information provided herein discloses a potential hazard or hazardous ingredient, adequate warning must be provided to employees and users and appropriate precautions taken, including the practice of good industrial hygiene. Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 MOBIL/559054-63/24.10.94 9804/9038 ISSUE 1, MARCH 2003 Text of R-phrases indicated in section 2: R 20: Harmful by inhalation. Footnote The information in this sheet has been compiled by Kuwait Petroleum Research & Technology B.V. of Rotterdam, Netherlands, on the basis of data available to them at the date stated above. The information contained in this MSDS corresponds to our level of knowledge at the time of publication. All warranties The information is for the guidance of customers of the Kuwait Petroleum group of companies (being all companies controlled directly or indirectly by Kuwait are excluded. Our most current General Sales Conditions shall apply. Please consult the Technical Data Sheet prior to Petroleum Corporation of Safat, Kuwait) but is not intended as an exhaustive description of the health and safety aspects of the use of the product and in particular the information takes no account of possible abnormal reactions of individuals. use. Customers are responsible for the proper storage, use and handling of the product and for determining whether the product is fit for the use to which it is put. The information does not describe health and safety aspects of the product once it has been misused or mishandled or when it is mixed with any other product. Further Information contact: This document is in accordance with 91/155/EEC, 93/112/EC and ISO 11014-1. JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 JCB HP Uni ATF Page 3 of 3 9804/9040 ISSUE 1, MARCH 2003 CONCAWE report no. 5/87 "health aspects of lubricants". The information in this sheet has been compiled by Kuwait Petroleum Research & Technology B.V. of Rotterdam, Netherlands, on the basis of data available to them at the date stated above. The information is for the guidance of customers of the Kuwait Petroleum group of companies (being all companies controlled directly or indirectly by Kuwait Petroleum Corporation of Safat, Kuwait) but is not intended as an exhaustive description of the health and safety aspects of the use of the product and in particular the information takes no account of possible abnormal reactions of individuals. Customers are responsible for the proper storage, use and handling of the product and for determining whether the product is fit for the use to which it is put. The information does not describe health and safety aspects of the product once it has been misused or mishandled or when it is mixed with any other product. This document is in accordance with 91/155/EEC, 93/112/EC and ISO 11014-1. Footnote The information contained in this MSDS corresponds to our level of knowledge at the time of publication. All warranties are excluded. Our most current General Sales Conditions shall apply. Please consult the Technical Data Sheet prior to use. Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 JCB EP Transmission Page 3 of 3 9804/9045 ISSUE 1, MARCH 2003 CONCAWE report no. 5/87 "health aspects of lubricants". The information in this sheet has been compiled by Kuwait Petroleum Research & Technology B.V. of Rotterdam, Netherlands, on the basis of data available to them at the date stated above. The information is for the guidance of customers of the Kuwait Petroleum group of companies (being all companies controlled directly or indirectly by Kuwait Petroleum Corporation of Safat, Kuwait) but is not intended as an exhaustive description of the health and safety aspects of the use of the product and in particular the information takes no account of possible abnormal reactions of individuals. Customers are responsible for the proper storage, use and handling of the product and for determining whether the product is fit for the use to which it is put. The information does not describe health and safety aspects of the product once it has been misused or mishandled or when it is mixed with any other product. This document is in accordance with 91/155/EEC, 93/112/EC and ISO 11014-1. Footnote The information contained in this MSDS corresponds to our level of knowledge at the time of publication. All warranties are excluded. Our most current General Sales Conditions shall apply. Please consult the Technical Data Sheet prior to use. Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 JCB EP Transmission Page 3 of 3 9804/8910 ISSUE 5, (REV.) MARCH 2003 JCB Engine Oil HP 10W30 Grade: 10W-30 Use: Lubricating oil for automotive engines Severely solvent refined mineral oil (approx. 95%). Additives (appr. 5%), mainly: Zinc alkyldithiophosphate Calcium/magnesium sulphonates & phenates Hydrocarbon polymers CONCAWE report no. 5/87 ‘health aspect of lubricants’. It is believed that all the information given in this bulletin (which supersedes all previous issues) is accurate at the time of printing. Such information is offered in good faith but without guarantee and without any representation that the product concerned is suitable for any use or application. Without limitation of the foregoing, nothing herein shall be construed as a recommendation for uses which infringe valid patents or as extending any license under valid patents. JCB pursues a policy of constant research and development aimed at product improvement and, therefore, reserves the right to change formulation, specification and characteristics of its products without notice. User should verify current specifications with JCB and ascertain that products are suitable for intended uses and applications. Where the information provided herein discloses a potential hazard or hazardous ingredient, adequate warning must be provided to employees and users and appropriate precautions taken, including the practice of good industrial hygiene. Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 * Note: Items marked with an asterisk (*) have been amended since last issue. SHP 10w-30 API CC.SF/1997-11-12 9804/9039 ISSUE 1, MARCH 2003 CONCAWE report no. 5/87 "health aspects of lubricants". The information in this sheet has been compiled by Kuwait Petroleum Research & Technology B.V. of Rotterdam, Netherlands, on the basis of data available to them at the date stated above. The information is for the guidance of customers of the Kuwait Petroleum group of companies (being all companies controlled directly or indirectly by Kuwait Petroleum Corporation of Safat, Kuwait) but is not intended as an exhaustive description of the health and safety aspects of the use of the product and in particular the information takes no account of possible abnormal reactions of individuals. Customers are responsible for the proper storage, use and handling of the product and for determining whether the product is fit for the use to which it is put. The information does not describe health and safety aspects of the product once it has been misused or mishandled or when it is mixed with any other product. This document is in accordance with 91/155/EEC, 93/112/EC and ISO 11014-1. Footnote The information contained in this MSDS corresponds to our level of knowledge at the time of publication. All warranties are excluded. Our most current General Sales Conditions shall apply. Please consult the Technical Data Sheet prior to use. Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 JCB EP Engine Oil Page 3 of 3 9804/9047 ISSUE 1, MARCH 2003 JCB Engine Oil HP 20W50 Grades: SAE 10W-30, 15W-40 Use: Lubricating oil for automotive engines Severely solvent refined mineral oil (appr. 92%) Additives (appr. 8%), mainly: Zinc alkyldithiophosphate Calcium/magnesium sulphonates & phenates Hydrocarbon polymers CONCAWE report no. 5/87 ‘health aspect of lubricants’. It is believed that all the information given in this bulletin (which supersedes all previous issues) is accurate at the time of printing. Such information is offered in good faith but without guarantee and without any representation that the product concerned is suitable for any use or application. Without limitation of the foregoing, nothing herein shall be construed as a recommendation for uses which infringe valid patents or as extending any license under valid patents. JCB pursues a policy of constant research and development aimed at product improvement and, therefore, reserves the right to change formulation, specification and characteristics of its products without notice. User should verify current specifications with JCB and ascertain that products are suitable for intended uses and applications. Where the information provided herein discloses a potential hazard or hazardous ingredient, adequate warning must be provided to employees and users and appropriate precautions taken, including the practice of good industrial hygiene. Further Information contact: JCB SERVICE WORLD PARTS CENTRE UTTOXETER STAFFORDSHIRE ST14 5BS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 593624 9804/9048 ISSUE 1, MARCH 2003 CONCAWE report no. 5/87 "health aspects of lubricants". The information in this sheet has been compiled by Kuwait Petroleum Research & Technology B.V. of Rotterdam, Netherlands, on the basis of data available to them at the date stated above. The information is for the guidance of customers of the Kuwait Petroleum group of companies (being all companies controlled directly or indirectly by Kuwait Petroleum Corporation of Safat, Kuwait) but is not intended as an exhaustive description of the health and safety aspects of the use of the product and in particular the information takes no account of possible abnormal reactions of individuals. Customers are responsible for the proper storage, use and handling of the product and for determining whether the product is fit for the use to which it is put. The information does not describe health and safety aspects of the product once it has been misused or mishandled or when it is mixed with any other product. This document is in accordance with 91/155/EEC, 93/112/EC and ISO 11014-1. Footnote The information contained in this MSDS corresponds to our level of knowledge at the time of publication. All warranties are excluded. Our most current General Sales Conditions shall apply. Please consult the Technical Data Sheet prior to use. Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 JCB EP Hydraulic Page 3 of 3 JCB Two Stroke Oil 9804/9042 ISSUE 1, MARCH 2003 JCB Part Nos. 4004/4701, 4004/4702, 4004/4704 JCB Two Stroke Oil 2003-02-11 1. PRODUCT AND COMPANY IDENTIFICATION JCB Two Stroke Oil (Hazard Information and Packaging for Supply) Regulations (CHIP3) (and other related directives) and provides Grades: Use: Lubricating oil for two-stroke engines information relating to the safe handling and use of the product. Company: No Name EC-No. CAS-No. %-mass The information in this sheet has been compiled by Kuwait Petroleum Research & Technology B.V. of Rotterdam, Netherlands, on the basis of data available to them at the date stated above. The information is for the guidance of customers of the Kuwait Petroleum group of companies (being all companies controlled directly or indirectly by Kuwait Petroleum Corporation of Safat, Kuwait) but is not intended as an exhaustive description of the health and safety aspects of the use of the product and in particular the information takes no account of possible abnormal reactions of individuals. Customers are responsible for the proper storage, use and handling of the product and for determining whether the product is fit for the use to which it is put. The information does not describe health and safety aspects of the product once it has been misused or mishandled or when it is mixed with any other product. This document is in accordance with 2001/58/EC and ISO 11014-1. Footnote The information contained in this MSDS corresponds to our level of knowledge at the time of publication. All warranties are excluded. Our most current General Sales Conditions shall apply. Please consult the Technical Data Sheet prior to use. Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 file://C:\My Documents\Oils\5670_JCBTwoStrokeOil_E.htm 3/4/03 JCB Chain Oil 9804/9044 ISSUE 1, MARCH 2003 JCB Part Nos. 4004/4801, 4004/4802, 4004/4804 JCB Chain Oil 2003-02-07 1. PRODUCT AND COMPANY IDENTIFICATION JCB Chain Oil JCB Chainsaw Oil (Hazard Information and Packaging for Supply) Regulations (CHIP3) (and other related directives) and provides Grades: ISO VG 150 Use: Lubricating oil for chainsaws information relating to the safe handling and use of the product. Company: No Name EC-No. CAS-No. %-mass The information in this sheet has been compiled by Kuwait Petroleum Research & Technology B.V. of Rotterdam, Netherlands, on the basis of data available to them at the date stated above. The information is for the guidance of customers of the Kuwait Petroleum group of companies (being all companies controlled directly or indirectly by Kuwait Petroleum Corporation of Safat, Kuwait) but is not intended as an exhaustive description of the health and safety aspects of the use of the product and in particular the information takes no account of possible abnormal reactions of individuals. Customers are responsible for the proper storage, use and handling of the product and for determining whether the product is fit for the use to which it is put. The information does not describe health and safety aspects of the product once it has been misused or mishandled or when it is mixed with any other product. This document is in accordance with 2001/58/EC and ISO 11014-1. Footnote The information contained in this MSDS corresponds to our level of knowledge at the time of publication. All warranties are excluded. Our most current General Sales Conditions shall apply. Please consult the Technical Data Sheet prior to use. Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 file://C:\My Documents\Oils\5667_JCBChainOil_E.htm 3/4/03 JCB Milking Machine 9804/9043 ISSUE 1, MARCH 2003 JCB Part Nos. 4004/4901, 9004/4902 JCB Milking Machine 2003-02-07 1. PRODUCT AND COMPANY IDENTIFICATION JCB Milking Machine JCB Milking Machine Oil (Hazard Information and Packaging for Supply) Regulations (CHIP3) (and other related directives) and provides Grades: ISO 68 Use: Vacuum oil for milk machines information relating to the safe handling and use of the product. Company: No Name EC-No. CAS-No. %-mass Text of R-phrases indicated for the ingredients in section 2: R 36/38: Irritating to eyes and skin. R 51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. The information in this sheet has been compiled by Kuwait Petroleum Research & Technology B.V. of Rotterdam, Netherlands, on the basis of data available to them at the date stated above. The information is for the guidance of customers of the Kuwait Petroleum group of companies (being all companies controlled directly or indirectly by Kuwait Petroleum Corporation of Safat, Kuwait) but is not intended as an exhaustive description of the health and safety aspects of the use of the product and in particular the information takes no account of possible abnormal reactions of individuals. Customers are responsible for the proper storage, use and handling of the product and for determining whether the product is fit for the use to which it is put. The information does not describe health and safety aspects of the product once it has been misused or mishandled or when it is mixed with any other product. This document is in accordance with 2001/58/EC and ISO 11014-1. Footnote The information contained in this MSDS corresponds to our level of knowledge at the time of publication. All warranties are excluded. Our most current General Sales Conditions shall apply. Please consult the Technical Data Sheet prior to use. Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 file://C:\My Documents\Oils\5668_JCBMilkingMachine_E.htm 3/4/03 JCB Garden Oil 9804/9041 ISSUE 1, MARCH 2003 JCB Part Nos. 4004/5001, 4004/5002, 4004/5004 JCB Garden Oil 2003-02-07 1. PRODUCT AND COMPANY IDENTIFICATION JCB Garden Machinery Oil JCB Garden Oil (Hazard Information and Packaging for Supply) Regulations (CHIP3) (and other related directives) and provides Grades: SAE 30 Use: Lubricating oil for lawnmower motors information relating to the safe handling and use of the product. Company: No Name EC-No. CAS-No. %-mass Text of R-phrases indicated for the ingredients in section 2: R 38: Irritating to skin. R 41: Risk of serious damage to eyes. R 51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. The information in this sheet has been compiled by Kuwait Petroleum Research & Technology B.V. of Rotterdam, Netherlands, on the basis of data available to them at the date stated above. The information is for the guidance of customers of the Kuwait Petroleum group of companies (being all companies controlled directly or indirectly by Kuwait Petroleum Corporation of Safat, Kuwait) but is not intended as an exhaustive description of the health and safety aspects of the use of the product and in particular the information takes no account of possible abnormal reactions of individuals. Customers are responsible for the proper storage, use and handling of the product and for determining whether the product is fit for the use to which it is put. The information does not describe health and safety aspects of the product once it has been misused or mishandled or when it is mixed with any other product. This document is in accordance with 2001/58/EC and ISO 11014-1. Footnote The information contained in this MSDS corresponds to our level of knowledge at the time of publication. All warranties are excluded. Our most current General Sales Conditions shall apply. Please consult the Technical Data Sheet prior to use. Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 FAX: + 44 (0) 1889 590546 file://C:\My Documents\Oils\5666_JCBGardenOil_E.htm 3/4/03 9804/9046 ISSUE 1, MARCH 2003 JCB Gear Oil EP 80W90 Grades: SAE 75W, 80W-90, 85W-140, 90 Use: Lubricating oil for automotive gears Emergency Contact : Emergency Telephone No.: +44 (0) 1889 590312 2. COMPOSITION/INFORMATION ON INGREDIENTS Severely solvent refined mineral oil (appr. 93%) Additives (appr. 7%), mainly: Organic sulphur and phosphorus containing compounds Poly alkyl methacrylate CONCAWE report no. 5/87 ‘health aspect of lubricants’. It is believed that all the information given in this bulletin (which supersedes all previous issues) is accurate at the time of printing. Such information is offered in good faith but without guarantee and without any representation that the product concerned is suitable for any use or application. Without limitation of the foregoing, nothing herein shall be construed as a recommendation for uses which infringe valid patents or as extending any license under valid patents. JCB pursues a policy of constant research and development aimed at product improvement and, therefore, reserves the right to change formulation, specification and characteristics of its products without notice. User should verify current specifications with JCB and ascertain that products are suitable for intended uses and applications. Where the information provided herein discloses a potential hazard or hazardous ingredient, adequate warning must be provided to employees and users and appropriate precautions taken, including the practice of good industrial hygiene. Further Information contact: JCB SERVICE - PARTS DIVISION ROCESTER STAFFORDSHIRE ST14 5LS TEL: + 44 (0) 1889 590312 9804/9049 ISSUE 1, MARCH 2003 Comprises a blend of highly refined mineral oils and multifunctional additives. The data and advice given apply when the product is sold for the stated application(s). The product is not sold as suitable for any other application. Use of the product for applications wother than as stated in his sheet may give rise to risks not mentioned in this sheet. You should not use the product other than for the stated application or applications without seeking advice from us. If you have purchased the product for supply to a third party for use at wor, it is your duty to take all necessary steps to secure that any person handling or using the product is provided with the information in this sheet. If you are an employer, it is your duty to tell your employees and others who may be affected of any hazards described in this sheet and of any precautions which should be taken. Further Information contact: JCB SERVICE WORLD PARTS CENTRE UTTOXETER STAFFORDSHIRE ST14 5BS TEL: + 44 (0) 1889 590312

Hazardous Ingredients

No substances are present in concentrations regarded to present health hazards (article 3 of Directive 88/379/EEC). Health: Unlikely to cause eye irritation. Unlikely to cause immediate irritation but prolonged and repeated contact may be harmful to the skin. Not volatile. It is not likely to be an inhalation hazard at normal ambient temperatures. If overheated, fumes and vapours are irritating to the breathing passages and lungs. Ingestion is unlikely to cause adverse systemic health effects. Environmental: Although no specific ecological hazards are expected and bioaccumulation is unlikely, spillage into the environment should always be avoided. Physical/Chemical: Not applicable. I6'<-.<3241;<'2/;'G/;<;43'04'1641;43/23064<'/;52/R;R'36'G/;<;43'H;273H'H2Z2/R<'M2/3017;')'68'[0/;130:;' OO$)%P$AA>NJ' ' Health: \470W;7E'36'12-<;';E;'0//0323064J' \470W;7E'36'12-<;'099;R023;'0//0323064'.-3'G/67645;R'24R'/;G;23;R'1643213'92E'.;'H2/98-7'36'3H;'<W04J' I63' 672307;J'D3'0<'463'70W;7E'36'.;'24'04H2723064'H2Z2/R'23'46/927'29.0;43'3;9G;/23-/;<J'D8'6 ;/H;23;R&'8-9;<'24R' :2G6-/<'2/;'<705H37E'0//0323045'36'3H;'./;23H045'G2<<25;<'24R'7-45<J' D45;<3064'0<'-470W;7E'36'12-<;'2R:;/<;'<E<3;901'H;273H';88;13<J' ' Environmental: U73H6-5H'46'<G;10801';167650127'H2Z2/R<'2/;';SG;13;R'24R'.06211-9-723064'0<'-470W;7E&'<G07725;'0436'3H;' 4 0/649;43'<H6-7R'.;'2 60R;RJ' ' Physical/Chemical: I63'2GG7012.7;J' ' $164304-;R' No substances are present in concentrations regarded to present health hazards (article 3 of Directive 88/379/EEC). Health: Slightly irritating to the eye. Slightly irritating to the skin. Not volatile. It is not likely to be an inhalation hazard at normal ambient temperatures. Ingestion in large quantities may cause damage to the kidneys, nervous system and blood. Environmental: Although no specific ecological hazards are expected and bioaccumulation is unlikely, spillage into the environment should always be avoided. Physical/Chemical: Not applicable. No substances are present in concentrations regarded to present health hazards (article 3 of Directive 88/379/EEC). Health: Unlikely to cause eye irritation. Unlikely to cause immediate irritation but prolonged and repeated contact may be harmful to the skin. Not volatile. It is not likely to be an inhalation hazard at normal ambient temperatures. If overheated, fumes and vapours are slightly irritating to the breathing passages and lungs. Ingestion is unlikely to cause adverse systemic health effects. Environmental: Although no specific ecological hazards are expcted and bioaccumulation is unlikely, spillage into the environment should always be avoided. Physical/Chemical: Not applicable. No substances are present in concentrations regarded to present health hazards (article 3 of Directive 88/379/EEC). Health: Unlikely to cause eye irritation. Unlikely to cause immediate irritation but prolonged and repeated contact may be harmful to the skin. Not volatile. It is not likely to be an inhalation hazard at normal ambient temperatures. If overheated, fumes and vapours are slightly irritating to the breathing passages and lungs. Ingestion is unlikely to cause adverse systemic health effects. Environmental: Although no specific ecological hazards are expected and bioaccumulation is unlikely, spillage into the environment should always be avoided. Physical/Chemical: Not applicable. No substances are present in concentrations regarded to present health hazards (article 3 of Directive 88/379/EEC). Health: Unlikely to cause eye irritation. Unlikely to cause immediate irritation but prolonged and repeated contact may be harmful to the skin. Not volatile. It is not likely to be an inhalation hazard at normal ambient temperatures. If overheated, fumes and vapours are slightly irritating to the breathing passages and lungs. Ingestion is unlikely to cause adverse systemic health effects. Environmental: Although no specific ecological hazards are expected and bioaccumulation is unlikely, spillage into the environment should always be avoided. Physical/Chemical: Not applicable. No substances are present in concentrations regarded to present health hazards (article 3 of Directive 88/379/EEC). Health: Unlikely to cause eye irritation. Unlikely to cause immediate irritation but prolonged and repeated contact may be harmful to the skin. Not volatile. It is not likely to be an inhalation hazard at normal ambient temperatures. If overheated, fumes and vapours are slightly irritating to the breathing passages and lungs. Ingestion is unlikely to cause adverse systemic health effects. Environmental: Although no specific ecological hazards are expected and bioaccumulation is unlikely, spillage into the environment should always be avoided. Physical/Chemical: Not applicable. No substances are present in concentrations regarded to present health hazards (article 3 of Directive 88/379/EEC). Health: Unlikely to cause eye irritation. Unlikely to cause immediate irritation but prolonged and repeated contact may be harmful to the skin. Not volatile. It is not likely to be an inhalation hazard at normal ambient temperatures. If overheated, fumes and vapours are slightly irritating to the breathing passages and lungs. Ingestion is unlikely to cause adverse systemic health effects. Environmental: Although no specific ecological hazards are expected and bioaccumulation is unlikely, spillage into the environment should always be avoided. Physical/Chemical: Not applicable. Ethylene clycol Xn R22 Harmful if swallowed. L;'A23A8796@A'74@'J4@A@98'59'6;96@984785;9A'4@:74S@S'8;'J4@A@98'K@7<8K'K7Y74SA'P74856<@')';='+54@685?@'%%$)ZR$..CQM' ' Health: [9<5V@<H'8;'672A@'@H@'54458785;9M' [9<5V@<H'8;'672A@'5>>@S578@'54458785;9'328'J4;<;9:@S'79S'4@J@78@S'6;98768'>7H'3@'K74>=2<'8;'8K@'AV59M' L;8'?;<785<@M'G8'5A'9;8'<5V@<H'8;'3@'79'59K7<785;9'K7Y74S'78'9;4>7<'7>35@98'8@>J@47824@AM'G=';?@4K@78@S&'=2>@A'79S' 7J;24A'74@'A<5 K8<H'544587859 '8;'8K@'34@78K59 'J7AA7 @A'79S'<29 AM' G9:@A85;9'5A'29<5V@<H'8;'672A@'7S?@4A@'AHA8@>56'K@7<8K'@==@68AM' Environmental: 8K;2 K'9;'AJ@65=56'@6;<; 567<'K7Y74SA'74@'@\J@68@S'79S'35;7662>2<785;9'5A'29<5V@<H&'AJ5<<7 @'598;'8K@'@9?54;9>@98' AK;2<S'7<]7HA'3@'7?;5S@SM' Physical/Chemical: L;8'7JJ<5673<@M' K;(T23T8796AT(74A(C4ATA98(59(6;96A984785;9T(4A:74@A@(8;(C4ATA98(>A7<8>(>7\74@T(O74856<A()(;=(+54A685SA( QQ$)XR$HHFPL( ( Health: ]9<5ZA<?(8;(672TA(A?A(54458785;9L( ]9<5ZA<?(8;(672TA(5DDA@578A(54458785;9(328(C4;<;9:A@(79@(4ACA78A@(6;98768(D7?(3A(>74D=2<(8;(8>A(TZ59L( K;8(S;<785<AL(,8(5T(9;8(<5ZA<?(8;(3A(79(59>7<785;9(>7\74@(78(9;4D7<(7D35A98(8ADCA47824ATL(,=(;SA4>A78A@'(=2DAT(79@( S7C;24T(74A(T<5 >8<?(544587859 (8;(8>A(34A78>59 (C7TT7 AT(79@(<29 TL( ,9:AT85;9(5T(29<5ZA<?(8;(672TA(7@SA4TA(T?T8AD56(>A7<8>(A==A68TL( Environmental: W<8>;2 >(9;(TCA65=56(A6;<; 567<(>7\74@T(74A(AUCA68A@(79@(35;7662D2<785;9(5T(29<5ZA<?'(TC5<<7 A(598;(8>A(A9S54;9DA98( T>;2<@(7<^7?T(3A(7S;5@A@L( Physical/Chemical: K;8(7CC<5673<AL( No substances are present in concentrations regarded to present health hazards (article 3 of Directive 88/379/EEC). Health: Unlikely to cause eye irritation. Unlikely to cause immediate irritation but prolonged and repeated contact may be harmful to the skin. Not volatile. It is not likely to be an inhalation hazard at normal ambient temperatures. If overheated, fumes and vapours are irritating to the breathing passages and lungs. Ingestion is unlikely to cause adverse systemic health effects. Environmental: Although no specific ecological hazards are expected and bioaccumulation is unlikely, spillage into the environment should always be avoided. Physical/Chemical: Not applicable. No substances are present in concentrations regarded to present health hazards (article 3 of Directive 88/379/EEC). Health: Unlikely to cause eye irritation. Unlikely to cause immediate irritation but prolonged and repeated contact may be harmful to the skin. Not volatile. It is not likely to be an inhalation hazard at normal ambient temperatures. If overheated, fumes and vapours are slightly irritating to the breathing passages and lungs. Ingestion is unlikely to cause adverse systemic health effects. Environmental: Although no specific ecological hazards are expected and bioaccumulation is unlikely, spillage into the environment should be avoided. Physical/Chemical: Not applicable. No substances are present in concentrations regarded to present health hazards (article 3 of Directive 88/379/EEC). Health: Unlikely to cause eye irritation. Unlikely to cause immediate irritation but prolonged and repeated contact may be harmful to the skin. Not volatile. It is not likely to be an inhalation hazard at normal ambient temperatures. If overheated, fumes and vapours are slightly irritating to the breathing passages and lungs. Ingestion is unlikely to cause adverse systemic health effects. Environmental: Although no specific ecological hazards are expected and bioaccumulation is unlikely, spillage into the environment should always be avoided. Physical/Chemical: Not applicable. No substances are present in concentrations regarded to present health hazards (article 3 of Directive 88/379/EEC). Health: Unlikely to cause eye irritation. Unlikely to cause immediate irritation but prolonged and repeated contact may be harmful to the skin. Not volatile. It is not likely to be an inhalation hazard at normal ambient temperatures. If overheated, fumes and vapours are irritating to the breathing passages and lungs. Ingestion is unlikely to cause adverse systemic health effects. Environmental: Although no specific ecological hazards are expected and bioaccumulation is unlikely, spillage into the environment should always be avoided. Physical/Chemical: Not applicable. Risk Codes CAS Number EEC Number % range Highly refined material oil OEL assigned This product is not dangerous when handled with care and according to its determined use. Skin irritation is possible, however, due to prolonged direct exposure. Special hazards of product after use: Engine oils may generate potential carcinogens during use or by contamination. Avoid prolonged or repeated contact with used oils. 4. FIRST-AID MEASURES Eyes: Wash immediately with copious of water/eyewash, holding the eyelids open. Obtain treatment by a Doctor if symptoms persist. Skin: Contact with the neat product should be washed off promptly with soap and water. Contact with treated symptoms should be washed as directed with good standards of industrial hygiene. Inhalation: Remove to fresh air. If symptoms persist seek treatment by a Doctor. Cont..... 9804/9049 ISSUE 1, MARCH 2003

Additional information

None 9804/8913 ISSUE 6, (REV.) MARCH 2003 None 5. FIRE-FIGHTING MEASURES Extinguishing Media: Recommended: Dry chemical, foam CO2, water mist. Not to be used: Direct water jet. Use water ONLY to keep fire exposed containers cool. Specific exposure hazards: Slight flammability hazard when exposed to heat or flame. Special protective equipment for firefighters: Use self-contained breathing equipment when fighting fire in confined spaces. 6. ACCIDENTAL RELEASE MEASURES Personal precautions: No special measures needed. Environmental precautions: Water may be used to flush spills away from sources of ignition. Do not allow the product to enter public drainage system or open water courses. Methods for cleaning up: Absorb and scrape up. Absorbent materials: Sand or active clay. 7. HANDLING AND STORAGE Handling: Avoid prolonged or repeated skin contact. Avoid inhalation of vapour, mist or fumes. Do not wear contaminated clothing. Used ;4504;'1/24W12<;'607'1643204<'H2/98-7'16432904243<J'D4'72.6/236/E'3;<3<&'G/67645;R'24R'/;G;23;R' 2GG70123064'68'used 1/24W12<;'607'36'3H;'<W04'68'901;&'H2:;'12-<;R'<W04'1241;/J'FH;/;86/;';S3/2'12/;'<H6-7R'.;' 32W;4&'.E'3H;'-<;'68'G/63;130 ;'1763H045'24R'566R'G;/<6427'HE50;4;&'36'2 60R'G/67645;R&';S1;<<0 ;'6/'/;G;23;R' <W04'1643213']03H'used ;4504;'607J' 4. FIRST-AID MEASURES Eyes: ^7-<H'3H;';E;']03H'16G06-<'296-43<'68']23;/J'I6';9;/5;41E'9;2<-/;<'2/;'4;1;<<2/E'.-3'08'2R:;/<;';E;';88;13<' 86776]&'/;8;/'86/'9;R0127'233;43064J' ' Skin: *2<H'3H;'1643290423;R'<W04'3H6/6-5H7E']03H'<62G'24R']23;/J'I6';9;/5;41E'9;2<-/;<'2/;'4;1;<<2/E'.-3'08' 2R:;/<;'<W04';88;13<'86776]&'/;8;/'86/'9;R0127'233;43064J' ' Inhalation: B;96 ;'3H;'288;13;R'G;/<64'36'8/;<H'20/J'D8'/;16 ;/E'0<'463'/2G0R&'6.3204'9;R0127'233;43064J' ' Ingestion: [_'I_F'DI[\>A'C_`DFDIaJ'I6';9;/5;41E'9;2<-/;<'2/;'4;;R;R'.-3'08'2R:;/<;'H;273H';88;13<'86776]&'/;8;/'86/' 9;R0127'233;43064J' ' I64;' ' 5. FIRE-FIGHTING MEASURES Extinguishing Media Recommended [/E'1H;90127&'8629'>_'('&']23;/'90<3J' ' Not to be used: [0/;13']23;/'b;3J'\<;']23;/'647E'36'W;;G'80/;';SG6<;R'1643204;/<'1667J' ' Specific exposure hazards: @705H3'872992.0703E'H2Z2/R']H;4';SG6<;R'36'H;23'6/'8729;J' ' Special protective equipment for fire-fighters: \<;'<;78+1643204;R'./;23H045';c-0G9;43']H;4'805H3045'80/;'04'164804;R'<G21;<J' ' 6. ACCIDENTAL RELEASE MEASURES Personal precautions: U:60R'G/67645;R'6/'/;G;23;R'<W04'1643213J' ' Environmental precautions: *23;/'92E'.;'-<;R'36'87-<H'<G077<'2]2E'8/69'<6-/1;<'68'05403064J'[6'463'2776]'3H;'G/6R-13'36';43;/'G-.701'R/20425;' <E<3;9'6/'6G;4']23;/'16-/<;<J' ' Methods for cleaning up: U.<6/.'24R'<1/2G;'-GJ' ' Absorbent materials: @24R'6/'2130:;'172EJ' ' None. 9804/8969 ISSUE 6 (REV.), MARCH 2003 None 5. FIRE-FIGHTING MEASURES Extinguishing Media: Recommended: Dry chemical, foam CO2, water mist. Not to be used: Direct water jet. Use water ONLY to keep fire exposed containers cool. Specific exposure hazards: Slight flammability hazard when exposed to heat or flame. Special protective equipment for firefighters: Use self-contained breathing equipment when fighting fire in confined spaces. 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Avoid prolonged or repeated skin contact. Environmental precautions: Do not allow the product to enter public drainage system or open water courses. Methods for cleaning up: Absorb and scrape up. Absorbent materials: Sand or active clay. 7. HANDLING AND STORAGE Handling: Avoid prolonged or repeated skin contact. Avoid inhalation of vapour, mist or fumes. Do not wear contaminated clothing. The main hazard following ingestion is aspiration into the lungs and subsequent chemical pneumonitis. Therefore emptying of the stomach by any method is not recommended except under experienced medical supervision. Cont’d 9804/8899 ISSUE 5 (REV.), MARCH 2003 Injection under the skin of mineral oil or grease under very high pressure is a serious emergency requiring IMMEDIATE medical attention and hospitalisation, even if initially there may be very little in the way of symptoms or signs to suggest this seriousness. Surgical exploration of the affected site with wide incision(s), careful debridement and irrigation of the damaged area should be undertaken at the slightest sign of actual presence of the oil under the skin. A conservative approach will inevitably lead to extensive necrosis of the subcutaneous tissues and structures. Especially vulnerable are the myelin sheaths of the nerves as these are rapidly dissolved by the hydrocarbon leading to extensive and irreversible impairment. 5. FIRE-FIGHTING MEASURES Extinguishing Media: Recommended: Dry chemical, foam CO2, water mist. Not to be used: Direct water jet. Use water ONLY to keep fire exposed containers cool. Specific exposure hazards: Slight flammability hazard when exposed to heat or flame. Special protective equipment for firefighters: Use self-contained breathing equipment when fighting fire in confined spaces. 6. ACCIDENTAL RELEASE MEASURES Personal precautions: No special measures needed. Environmental precautions: Water may be used to flush spills away from sources of ignition. Do not allow the product to enter public drainage system or open water courses. Methods for cleaning up: Absorb and scrape up. Absorbent materials: Sand or active clay. 9804/8899 ISSUE 5 (REV.), MARCH 2003 Injection under the skin of oil or grease under very high pressure is a serious emergency which should immediately be referred to hospital. A copy of this data sheet should accompany the casualty to hospital for the information of the medical staff. 9804/8971 ISSUE 5, (REV.) MARCH 2003 Injection under the skin of mineral oil or grease under very high pressure is a serious emergency requiring IMMEDIATE medical attention and hospitalisation, even if initially there may be very little in the way of symptoms or signs to suggest this seriousness. Surgical exploration of the affected site with wide incision(s), careful debridement and irrigation of the damaged area should be undertaken at the slightest sign of actual presence of the oil under the skin. A conservative approach will inevitably lead to extensive necrosis of the subcutaneous tissues and structures. Especially vulnerable are the myelin sheaths of the nerves as these are rapidly dissolved by the hydrocarbon leading to extensive and irreversible impairment. 5. FIRE-FIGHTING MEASURES Extinguishing Media: Recommended: Dry chemical, foam CO2, water mist. Not to be used: Direct water jet. Use water ONLY to keep fire exposed containers cool. Specific exposure hazards: Slight flammability hazard when exposed to heat or flame. Special protective equipment for firefighters: Use self-contained breathing equipment when fighting fire in confined spaces. 6. ACCIDENTAL RELEASE MEASURES Personal precautions: No special measures needed. Environmental precautions: Water may be used to flush spills away from sources of ignition. Do not allow the product to enter public drainage system or open water courses. Methods for cleaning up: Absorb and scrape up. Absorbent materials: Sand or active clay. 9804/8971 ISSUE 5, (REV.) MARCH 2003 Injection under the skin of oil or grease under very high pressure is a serious emergency which should immediately be referred to hospital. A copy of this data sheet should accompany the casualty to hospital for the information of the medical staff. 9804/8972 ISSUE 5, (REV.) MARCH 2003 Injection under the skin of mineral oil or grease under very high pressure is a serious emergency requiring IMMEDIATE medical attention and hospitalisation, even if initially there may be very little in the way of symptoms or signs to suggest this seriousness. Surgical exploration of the affected site with wide incision(s), careful debridement and irrigation of the damaged area should be undertaken at the slightest sign of actual presences of the oil under the skin. A conservative approach will inevitably lead to extensive necrosis of the subcutaneous tissues and structures. Especially vulnerable are the myelin sheaths of the nerves as these are rapidly dissolved by the hydrocarbon leading to extensive and irreversible impairment. 5. FIRE-FIGHTING MEASURES Extinguishing Media: Recommended: Dry chemical, foam CO2, water mist. Not to be used: Direct water jet. Use water ONLY to keep fire exposed containers cool. Specific exposure hazards: Slight flammability hazard when exposed to heat or flame. Special protective equipment for firefighters: Use self-contained breathing equipment when fighting fire in confined spaces. 6. ACCIDENTAL RELEASE MEASURES Personal precautions: No special measures needed. Environmental precautions: Water may be used to flush spills away from sources of ignition. Do not allow the product to enter public drainage system or open water courses. Methods for cleaning up: Absorb and scrape up. Absorbent materials: Sand or active clay. 9804/8972 ISSUE 5, (REV.) MARCH 2003 Used engine crankcase oil contains harmful contaminants. In laboratory tests, prolonged and repeated applications of used crankcase oil to the skin of mice, have caused skin cancer. Therefore extra care should be taken, by the use of protective clothing and good personal hygiene, to avoid prolonged, excessive or repeated skin contact with used engine oil. 9804/8993 ISSUE 4, MARCH 2003 None 5. FIRE-FIGHTING MEASURES Extinguishing Media: Recommended: Dry chemical, foam CO2, water mist. Not to be used: Direct water jet. Use water ONLY to keep fire exposed containers cool. Specific exposure hazards: Slight flammability hazard when exposed to heat or flame. Special protective equipment for firefighters: Use self-contained breathing equipment when fighting fire in confined spaces. 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Avoid prolonged or repeated skin contact. Environmental precautions: Water may be used to flush spills away from sources of ignition. Do not allow the product to enter public drainage system or open water courses. Methods for cleaning up: Absorb and scrape up. Absorbent materials: Sand or active clay. 7. HANDLING AND STORAGE Handling: Avoid prolonged or repeated skin contact. Avoid inhalation of vapour, mist or fumes. Do not wear contaminated clothing. Used engine crankcase oil contains harmful contaminants. In laboratory tests, prolonged and repeated applications of used crankcase oil to the skin of mice, have caused skin cancer. Therefore extra care should be taken, by the use of protective clothing and good personal hygiene, to avoid prolonged, excessive or repeated skin contact with used engine oil. 9804/8891 ISSUE 6, (REV.) MARCH 2003 None 5. FIRE-FIGHTING MEASURES Extinguishing Media: Recommended: Dry chemical, foam CO2, water mist. Not to be used: Direct water jet. Use water ONLY to keep fire exposed containers cool. Specific exposure hazards: Slight flammability hazard when exposed to heat or flame. Special protective equipment for firefighters: Use self-contained breathing equipment when fighting fire in confined spaces. 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Avoid prolonged or repeated skin contact. Environmental precautions: Water may be used to flush spills away from sources of ignition. Do not allow the product to enter public drainage system or open water courses. Methods for cleaning up: Absorb and scrape up. Absorbent materials: Sand or active clay. 7. HANDLING AND STORAGE Handling: Avoid prolonged or repeated skin contact. Avoid inhalation of vapours, mist or fumes. Do not wear contaminated clothing. Refer to any national measures that may be relevant. 1997-02-20 9804/8892 ISSUE 4*, OCTOBER 2001 Used @9 59@'6479V67A@';5<'6;98759A'K74>=2<'6;987>59798AM'G9'<73;478;4H'8@A8A&'J4;<;9 @S'79S'4@J@78@S'7JJ<56785;9A' ;=' used 6479V67A@';5<'8;'8K@'AV59';='>56@&'K7?@'672A@S'AV59'6796@4M'IK@4@=;4@'@\847'674@'AK;2<S'3@'87V@9&'3H'8K@'2A@' ;=' J4;8@685?@'6<;8K59 '79S' ;;S'J@4A;97<'KH 5@9@&'8;'7?;5S'J4;<;9 @S&'@\6@AA5?@';4'4@J@78@S'AV59'6;98768']58K'used e9:59@';5<M' 9804/9015 ISSUE 1, JULY 2000 L;9@' • 5. FIRE-FIGHTING MEASURES Extinguishing Media Recommended +4H'6K@>567<&'=;7>'C_'('&']78@4'>5A8M' Not to be used: +54@68']78@4'b@8M'[A@']78@4'_L1c'8;'V@@J'=54@'@\J;A@S'6;98759@4A'6;;<M' Specific exposure hazards: ,<5:K8'=<7>>735<58H'K7Y74S']K@9'@\J;A@S'8;'K@78';4'=<7>@M' Special protective equipment for firefighters: A@'A@<=06;98759@S'34@78K59 '@d25J>@98']K@9'=5 K859 '=54@'59'6;9=59@S'AJ76@AM' ' • 6. ACCIDENTAL RELEASE MEASURES Personal precautions: -?;5S'J4;<;9:@S';4'4@J@78@S'AV59'6;98768M' Environmental precautions: 78@4'>7H'3@'2A@S'8;'=<2AK'AJ5<<A'7]7H'=4;>'A;246@A';='5 9585;9M'+;'9;8'7<<;]'8K@'J4;S268'8;'@98@4'J23<56'S47597 @' AHA8@>';4';J@9']78@4'6;24A@AM' Methods for cleaning up: -3A;43'79S'A647J@'2JM' Absorbent materials: ,79S';4'7685?@'6<7HM' ' • 7. HANDLING AND STORAGE Handling: ;5S'J4;<;9 @S';4'4@J@78@S'AV59'6;98768M'-?;5S'59K7<785;9';='?7J;24&'>5A8';4'=2>@AM'+;'9;8']@74'6;987>5978@S'6<;8K59 M' 9_A685;9(29@A4(8>A(TZ59(;=(;5<(;4( 4A7TA(29@A4(SA4?(>5 >(C4ATT24A(5T(7(TA45;2T(ADA4 A96?(^>56>(T>;2<@(5DDA@578A<?( 3A(4A=A44A@(8;(>;TC587<L(W(6;C?(;=(8>5T(@787(T>AA8(T>;2<@(766;DC79?(8>A(67T27<8?(8;(>;TC587<(=;4(8>A(59=;4D785;9(;=( 8>A(DA@567<(T87==L( 9804/9016 ISSUE 1, JULY 2000 9_A685;9(29@A4(8>A(TZ59(;=(D59A47<(;5<(;4( 4A7TA(29@A4(SA4?(>5 >(C4ATT24A(5T(7(TA45;2T(ADA4 A96?(4AB25459 ( ,bbH+,WJH(DA@567<(788A985;9(79@(>;TC587<5T785;9'(ASA9(5=(595857<<?(8>A4A(D7?(3A(SA4?(<588<A(59(8>A(^7?(;=(T?DC8;DT(;4( T5 9T(8;(T2 AT8(8>5T(TA45;2T9ATTL( 24 567<(AUC<;4785;9(;=(8>A(7==A68A@(T58A(^58>(^5@A(5965T5;9OTP'(674A=2<(@A345@ADA98(79@(5445 785;9(;=(8>A(@7D7 A@( 74A7(T>;2<@(3A(29@A487ZA9(78(8>A(T<5 >8AT8(T5 9(;=(76827<(C4ATA96A(;=(8>A(;5<(29@A4(8>A(TZ59L(W(6;9TA4S785SA( 7CC4;76>(^5<<(59AS5873<?(<A7@(8;(AU8A9T5SA(9A64;T5T(;=(8>A(T2362879A;2T(85TT2AT(79@(T8426824ATL(HTCA657<<?( S2<9A473<A(74A(8>A(D?A<59(T>A78>T(;=(8>A(9A4SAT(7T(8>ATA(74A(47C5@<?(@5TT;<SA@(3?(8>A(>?@4;6743;9(<A7@59:(8;( AU8A9T5SA(79@(544ASA4T53<A(5DC754DA98L( ( •••• 5. FIRE-FIGHTING MEASURES Extinguishing Media Recommended +4?(6>AD567<'(=;7D(F.(#('(^78A4(D5T8L( Not to be used: +54A68(^78A4(_A8L(]TA(^78A4(.K1c(8;(ZAAC(=54A(AUC;TA@(6;98759A4T(6;;<L( Specific exposure hazards: -<5:>8(=<7DD735<58?(>7\74@(^>A9(AUC;TA@(8;(>A78(;4(=<7DAL( Special protective equipment for firefighters: TA(TA<=d6;98759A@(34A78>59 (AB25CDA98(^>A9(=5 >859 (=54A(59(6;9=59A@(TC76ATL( ( •••• 6. ACCIDENTAL RELEASE MEASURES Personal precautions: K;(TCA657<(DA7T24AT(9AA@A@L( Environmental precautions: a78A4(D7?(3A(2TA@(8;(=<2T>(TC5<<T(7^7?(=4;D(T;246AT(;=(5 9585;9L(+;(9;8(7<<;^(8>A(C4;@268(8;(A98A4(C23<56(@47597 A( T?T8AD( ;4(;CA9(^78A4(6;24TATL( Methods for cleaning up: W3T;43(79@(T647CA(2CL( Absorbent materials: -79@(;4(7685SA(6<7?L( ( 9804/9016 ISSUE 1, JULY 2000 None 9804/8912 ISSUE 5, (REV.) MARCH 2003 None 5. FIRE-FIGHTING MEASURES Extinguishing Media: Recommended: Dry chemical, foam CO2, water mist. Not to be used: Direct water jet. Use water ONLY to keep fire exposed containers cool. Specific exposure hazards: Slight flammability hazard when exposed to heat or flame. Special protective equipment for firefighters: Use self-contained breathing equipment when fighting fire in confined spaces. 6. ACCIDENTAL RELEASE MEASURES Personal precautions: No special measures needed. Environmental precautions: Water may be used to flush spills away from sources of ignition. Do not allow the product to enter public drainage system or open water courses. Methods for cleaning up: Absorb and scrape up. Absorbent materials: Sand or active clay. 7. HANDLING AND STORAGE Handling: Avoid prolonged or repeated skin contact. Avoid inhalation of vapour, mist or fumes. Do not wear contaminated clothing. None 4. FIRST AID MEASURES Eyes: Flush the eye with copious amounts of water. No emergency measures are necessary but if adverse eye effects follow, refer for medical attention. Skin: Wash the contaminated skin thoroughly with soap and water. No emergency measures are necessary but if adverse skin effects follow, refer for medical attention. Inhalation: Remove the affected person to fresh air. If recovery is not rapid, obtain medical attention. Ingestion: DO NOT INDUCE VOMITING. No emergency measures are needed but if adverse health effects follow, refer for medical attention. 5. FIREFIGHTING MEASURES Extinguishing media Recommended Dry chemical, foam, CO2, water mist Not to be used: Direct water jet. Use water ONLY to keep fire-exposed containers cool. Specific exposure hazards: Slight flammability hazard when exposed to heat or flame. Special protective equipment for firefighters: JCB HP Uni ATF Page 1 of 3 9804/9038 ISSUE 1, MARCH 2003 None 4. FIRST AID MEASURES Eyes: Flush the eye with copious amounts of water. No emergency measures are necessary but if adverse eye effects follow, refer for medical attention. Skin: Wash the contaminated skin thoroughly with soap and water. No emergency measures are necessary but if adverse skin effects follow, refer for medical attention. Inhalation: Remove the affected person to fresh air. If recovery is not rapid, obtain medical attention. Ingestion: DO NOT INDUCE VOMITING. No emergency measures are needed but if adverse health effects follow, refer for medical attention. 5. FIREFIGHTING MEASURES Extinguishing media Recommended Dry chemical, foam, CO2, water mist Not to be used: Direct water jet. Use water ONLY to keep fire-exposed containers cool. Specific exposure hazards: Slight flammability hazard when exposed to heat or flame. Special protective equipment for firefighters: JCB EP Transmission Page 1 of 3 9804/9040 ISSUE 1, MARCH 2003 None 4. FIRST AID MEASURES Eyes: Flush the eye with copious amounts of water. No emergency measures are necessary but if adverse eye effects follow, refer for medical attention. Skin: Wash the contaminated skin thoroughly with soap and water. No emergency measures are necessary but if adverse skin effects follow, refer for medical attention. Inhalation: Remove the affected person to fresh air. If recovery is not rapid, obtain medical attention. Ingestion: DO NOT INDUCE VOMITING. No emergency measures are needed but if adverse health effects follow, refer for medical attention. 5. FIREFIGHTING MEASURES Extinguishing media Recommended Dry chemical, foam, CO2, water mist Not to be used: Direct water jet. Use water ONLY to keep fire-exposed containers cool. Specific exposure hazards: Slight flammability hazard when exposed to heat or flame. Special protective equipment for firefighters: JCB EP Transmission Page 1 of 3 9804/9045 ISSUE 1, MARCH 2003 Used engine crankcase oil contains harmful contaminants. In laboratory tests, prolonged and repeated application of used crankcase oil to the skin of mice, have caused skin cancer. Therefore extra care should be taken, by the use of protective clothing and good personal hygiene, to avoid prolonged, excessive or repeated skin contact with used engine oil. 9804/8910 ISSUE 5, (REV.) MARCH 2003 None 5. FIRE-FIGHTING MEASURES Extinguishing Media: Recommended: Dry chemical, foam CO2, water mist. Not to be used: Direct water jet. Use water only to keep fire exposed containers cool. Specific exposure hazards: Slight flammability hazard when exposed to heat or flame. Special protective equipment for firefighters: Use self-contained breathing equipment when fighting fire in confined spaces. 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Avoid prolonged or repeated skin contact. Environmental precautions: Water may be used to flush spills away from sources of ignition. Do not allow the product to enter public drainage system or open water courses. Methods for cleaning up: Absorb and scrape up. Absorbent materials: Sand or active clay. 7. HANDLING AND STORAGE Handling: Avoid prolonged or repeated skin contact. Avoid inhalation of vapours, mists or fumes. Do not wear contaminated clothing. USED engine crankcase oil contains harmful contaminants. In laboratory tests, prolonged and repeated applications of USED crankcase oil to the skin of mice, have caused skin cancer. Therefore extra care should be taken, by the use of protective clothing and good personal hygiene, to avoid prolonged, excessive or repeated skin contact with USED engine oil. 4. FIRST AID MEASURES Eyes: Flush the eye with copious amounts of water. No emergency measures are necessary but if adverse eye effects follow, refer for medical attention. Skin: Wash the contaminated skin thoroughly with soap and water. No emergency measures are necessary but if adverse skin effects follow, refer for medical attention. Inhalation: Remove the affected person to fresh air. If recovery is not rapid, obtain medical attention. Ingestion: DO NOT INDUCE VOMITING. No emergency measures are needed but if adverse health effects follow, refer for medical attention. 5. FIREFIGHTING MEASURES Extinguishing media Recommended Dry chemical, foam, CO2, water mist Not to be used: Direct water jet. Use water ONLY to keep fire-exposed containers cool. Specific exposure hazards: JCB EP Engine Oil Page 1 of 3 9804/9039 ISSUE 1, MARCH 2003 Used engine crankcase oil contains harmful contaminants. In laboratory tests, prolonged and repeated applications of used crankcase oil to the skin of mice, have caused skin cancer. Therefore extra care should be taken, by the use of protective clothing and good personal hygiene, to avoid prolonged, excessive or repeated skin contact with used engine oil. 9804/9047 ISSUE 1, MARCH 2003 None 5. FIRE-FIGHTING MEASURES Extinguishing Media: Recommended: Dry chemical, foam CO2, water mist. Not to be used: Direct water jet. Use water ONLY to keep fire exposed containers cool. Specific exposure hazards: Slight flammability hazard when exposed to heat or flame. Special protective equipment for firefighters: Use self-contained breathing equipment when fighting fire in confined spaces. 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Avoid prolonged or repeated skin contact. Environmental precautions: Water may be used to flush spills away from sources of ignition. Do not allow the product to enter public drainage system or open water courses. Methods for cleaning up: Absorb and scrape up. Absorbent materials: Sand or active clay. 7. HANDLING AND STORAGE Handling: Avoid prolonged or repeated skin contact. Avoid inhalation of vapour, mist or fumes. Do not wear contaminated clothing. Injection under the skin of oil or grease under very high pressure is a serious emergency which should immediately be referred to hospital. A copy of this data sheet should accompany the casualty to hospital for the information of the medical staff. 4. FIRST AID MEASURES Eyes: Flush the eye with copious amounts of water. No emergency measures are necessary but if adverse eye effects follow, refer for medical attention. Skin: Wash the contaminated skin thoroughly with soap and water. No emergency measures are necessary but if adverse skin effects follow, refer for medical attention. Inhalation: Remove the affected person to fresh air. If recovery is not rapid, obtain medical attention. Ingestion: DO NOT INDUCE VOMITING. No emergency measures are needed but if adverse health effects follow, refer for medical attention. 5. FIREFIGHTING MEASURES Extinguishing media Recommended Dry chemical, foam, CO2, water mist Not to be used: Direct water jet. Use water ONLY to keep fire-exposed containers cool. Specific exposure hazards: Slight flammability hazard when exposed to heat or flame. JCB EP Hydraulic Page 1 of 3 9804/9048 ISSUE 1, MARCH 2003 5. FIREFIGHTING MEASURES Extinguishing media Recommended Dry chemical, foam, CO2, water mist Not to be used: Direct water jet. Use water ONLY to keep fire-exposed containers cool. Specific exposure hazards: Slight flammability hazard when exposed to heat or flame. Special protective equipment for firefighters: Use self-contained breathing equipment when fighting fire in confined spaces. 6. ACCIDENTAL RELEASE MEASURES Personal precautions: No special measures needed. Environmental precautions: Water may be used to flush spills away from sources of ignition. Do not allow the product to enter public drainage system or open water courses. Methods for cleaning up: Absorb and scrape up. Absorbent materials: Sand or active clay. 7. HANDLING AND STORAGE Handling: Avoid prolonged or repeated skin contact. Avoid inhalation of vapour, mist or fume. Do not wear contaminated clothing. None 4. FIRST AID MEASURES Warning statement None considered necessary. Acute effects of exposure to man Inhalation Vapours or mist in unusually high concentrations, as from exposure in poorly ventilated areas or confined spaces, may cause irritation of the nose and throat, headache, nausea and drowsiness. Skin Contact file://C:\My Documents\Oils\5667_JCBChainOil_E.htm Brief contact is not irritating. Prolonged contact, as with clothing wetted with material, may cause defatting of skin or 3/4/03 irritation, seen as local redness with possible mild discomfort. Eye Contact May cause minimal irritation, experienced as temporary discomfort. Ingestion No adverse effects expected. If more than several mouthfuls are swallowed, abdominal discomfort, nausea, and diarrhoea may occur. Continued..... JCB Chain Oil 9804/9044 ISSUE 1, MARCH 2003 5. FIREFIGHTING MEASURES Extinguishing media Recommended Dry chemical, foam, CO2, water mist Not to be used: Direct water jet. Use water ONLY to keep fire-exposed containers cool. Specific exposure hazards: Slight flammability hazard when exposed to heat or flame. Special protective equipment for firefighters: Use self-contained breathing equipment when fighting fire in confined spaces. 6. ACCIDENTAL RELEASE MEASURES Personal precautions: No special measures needed. Environmental precautions: Water may be used to flush spills away from sources of ignition. Do not allow the product to enter public drainage system or open water courses. Methods for cleaning up: Absorb and scrape up. Absorbent materials: Sand or active clay. 7. HANDLING AND STORAGE Handling: Avoid prolonged or repeated skin contact. Avoid inhalation of vapour, mist or fume. Do not wear contaminated clothing. Injection under the skin of oil or grease under very high pressure is a serious emergency which should immediately be referred to hospital. A copy of this data sheet should accompany the casualty to hospital for the information of the medical staff. 4. FIRST AID MEASURES Warning statement None considered necessary. Acute effects of exposure to man Inhalation Vapours or mist in unusually high concentrations, as from exposure in poorly ventilated areas or confined spaces, may cause irritation of the nose and throat, headache, nausea and drowsiness. Skin Contact file://C:\My Documents\Oils\5668_JCBMilkingMachine_E.htm Brief contact is not irritating. Prolonged contact, as with clothing wetted with material, may cause defatting of skin or 3/4/03 irritation, seen as local redness with possible mild discomfort. Eye Contact May cause minimal irritation, experienced as temporary discomfort. Ingestion No adverse effects expected. If more than several mouthfuls are swallowed, abdominal discomfort, nausea, and diarrhoea may occur. Continued..... JCB Milking Machine 9804/9043 ISSUE 1, MARCH 2003 5. FIREFIGHTING MEASURES Extinguishing media Recommended Dry chemical, foam, CO2, water mist Not to be used: Direct water jet. Use water ONLY to keep fire-exposed containers cool. Specific exposure hazards: Slight flammability hazard when exposed to heat or flame. Special protective equipment for firefighters: Use self-contained breathing equipment when fighting fire in confined spaces. 6. ACCIDENTAL RELEASE MEASURES Personal precautions: No special measures needed. Environmental precautions: Water may be used to flush spills away from sources of ignition. Do not allow the product to enter public drainage system or open water courses. Methods for cleaning up: Absorb and scrape up. Absorbent materials: Sand or active clay. 7. HANDLING AND STORAGE Handling: Avoid prolonged or repeated skin contact. Avoid inhalation of vapour, mist or fume. Do not wear contaminated clothing. USED engine crankcase oil contains harmful contaminants. In laboratory tests, prolonged and repeated applications of USED crankcase oil to the skin of mice, have caused skin cancer. Therefore extra care should be taken, by the use of protective clothing and good Warning statement personal hygiene, to avoid prolonged, excessive or repeated skin contact with USED engine oil. None considered necessary. 4. FIRST AID MEASURES Acute effects of exposure to man Inhalation Vapours or mist in unusually high concentrations, as from exposure in poorly ventilated areas or confined spaces, may cause irritation of the nose and throat, headache, nausea and drowsiness. Skin Contact file://C:\My Documents\Oils\5666_JCBGardenOil_E.htm Brief contact is not irritating. Prolonged contact, as with clothing wetted with material, may cause defatting of skin or 3/4/03 irritation, seen as local redness with possible mild discomfort. Eye Contact May cause minimal irritation, experienced as temporary discomfort. Ingestion No adverse effects expected. If more than several mouthfuls are swallowed, abdominal discomfort, nausea, and diarrhoea may occur. Continued..... JCB Garden Oil 9804/9041 ISSUE 1, MARCH 2003 5. FIREFIGHTING MEASURES Extinguishing media Recommended Dry chemical, foam, CO2, water mist Not to be used: Direct water jet. Use water ONLY to keep fire-exposed containers cool. Specific exposure hazards: Slight flammability hazard when exposed to heat or flame. Special protective equipment for firefighters: Use self-contained breathing equipment when fighting fire in confined spaces. 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Avoid prolonged or repeated skin contact. Environmental precautions: Water may be used to flush spills away from sources of ignition. Do not allow the product to enter public drainage system or open water courses. Methods for cleaning up: Absorb and scrape up. Absorbent materials: Sand or active clay. 7. HANDLING AND STORAGE Handling: Avoid prolonged or repeated skin contact. Avoid inhalation of vapour, mist or fume. Do not wear contaminated clothing. None 9804/9046 ISSUE 1, MARCH 2003 None 5. FIRE-FIGHTING MEASURES Extinguishing Media: Recommended: Dry chemical, foam CO2, water mist. Not to be used: Direct water jet. Use water ONLY to keep fire exposed containers cool. Specific exposure hazards: Slight flammability hazard when exposed to heat or flame. Special protective equipment for firefighters: Use self-contained breathing equipment when fighting fire in confined spaces. 6. ACCIDENTAL RELEASE MEASURES Personal precautions: No special measures needed. Environmental precautions: Water may be used to flush spills away from sources of ignition. Do not allow the product to enter public drainage system or open water courses. Methods for cleaning up: Absorb and scrape up. Absorbent materials: Sand or active clay. 7. HANDLING AND STORAGE Handling: Avoid prolonged or repeated skin contact. Avoid inhalation of vapour, mist or fumes. Do not wear contaminated clothing.

Appearance/Odor

Bright and clear Characteristic pH: Neutral Boiling range, °C: Initial boiling point (oil base) > 300 Pour/melting point, °C: < -24 Flash point, °C: > 172 (ASTM D92, COC) Autoflammability/ignition, °C: > 300 (oil base) Upper explosion limit: Not known Lower explosion limit: Not known Vapour pressure, 20 °C, kPa: < 0.01 (oil base) Viscosity, kinematic, 40 °C, mm2/s: 71 (SAE 80W); 174 (SAE 90) Relative density, 15 °C: 0.90 Water solubility: Not soluble Partition coefficient, n-octanol/water: Not known Other data: 10. STABILITY AND REACTIVITY Conditions/materials to avoid: Stable. May react with strong oxidising agents. Hazardous decomposition products: Thermal decomposition or incomplete combustion may produce oxides of carbon and irritating fumes. Bright and clear Sweet pH: Neutral Boiling range, °C: > 260 Pour/melting point, °C: < -50 Flash point, °C: 152 (ASTM D92, COC) Autoflammability/ignition, °C: > 300 (oil base) Upper explosion limit: Not known Lower explosion limit: Not known Vapour pressure, 20 °C, kPa: < 0.3 Viscosity, kinematic, 40 °C, mm2/s: 11 Relative density, 15 °C: 1.00 Water solubility: Soluble Partition coefficient, n-octanol/water: Not known Other data: 10. STABILITY AND REACTIVITY Conditions/materials to avoid: Stable. May react with strong oxidising agents. Hazardous decomposition products: Thermal decomposition or incomplete combustion may produce oxides of carbon and irritating fumes. Bright and clear Characteristic pH: Neutral Boiling range, °C: Initial boiling point (oil base) > 260. Pour/melting point, °C: < -42 Flash point, °C: > 160 (ASTM D92, COC) Autoflammability/ignition, °C: > 230 (oil base) Upper explosion limit: Not known Lower explosion limit: Not known Vapour pressure, 20 °C, kPa: < 0.01 (oil base) Viscosity, kinematic, 40 °C, mm2/s: 15 Relative density, 15 °C: 0.86 Water solubility: Not soluble Partition coefficient, n-octanol/water: Not known Other data: 10. STABILITY AND REACTIVITY Conditions/materials to avoid: Stable. May react with strong oxidising agents. Hazardous decomposition products: Thermal decomposition or incomplete combustion may produce oxides of carbon and irritating fumes. 9804/8899 ISSUE 5 (REV.), MARCH 2003 Bright and clear Characteristic pH: Neutral Boiling range, °C: Initial boiling point (oil base) > 300. Pour/melting point, °C: < -12 Flash point, °C: > 190 (ASTM D92, COC) Autoflammability/ignition, °C: > 300 (oil base) Upper explosion limit: Not known Lower explosion limit: Not known Vapour pressure, 20 °C, kPa: < 0.01 (oil base) Viscosity, kinematic, 40 °C, mm2/s: Indicated by grade designation Relative density, 15 °C: 0.87 - 0.90 Water solubility: Not soluble Partition coefficient, n-octanol/water: Not known Other data: 10. STABILITY AND REACTIVITY Conditions/materials to avoid: Stable. May react with strong oxidising agents. Hazardous decomposition products: Thermal decomposition or incomplete combustion may produce oxides of carbon and irritating fumes. 9804/8971 ISSUE 5, (REV.) MARCH 2003 Bright and clear Characteristic pH: Neutral Boiling range, °C: Initial boiling point (oil base) > 300. Pour/melting point, °C: < -12 Flash point, °C: > 190 (ASTM D92, COC) Autoflammability/ignition, °C: > 300 (oil base) Upper explosion limit: Not known Lower explosion limit: Not known Vapour pressure, 20 °C, kPa: < 0.01 (oil base) Viscosity, kinematic, 40 °C, mm2/s: Indicated by grade designation Relative density, 15 °C: 0.87 - 0.90 Water solubility: Not soluble Partition coefficient, n-octanol/water: Not known Other data: 10. STABILITY AND REACTIVITY Conditions/materials to avoid: Stable. May react with strong oxidising agents. Hazardous decomposition products: Thermal decomposition or incomplete combustion may produce oxides of carbon and irritating fumes. 9804/8972 ISSUE 5, (REV.) MARCH 2003 Bright and clear Weak pH: Slightly alkaline Boiling range, °C: Initial boiling point (oil base) > 300 Pour/melting point, °C: < -27 Flash point, °C: > 200 (ASTM D92, COC) Autoflammability/ignition, °C: > 300 (oil base) Upper explosion limit: Not known Lower explosion limit: Not known Vapour pressure, 20 °C, kPa: < 0.01 (oil base) Viscosity, kinematic, 40 °C, mm2/s: > 70 Relative density, 15 °C: 0.88 Water solubility: Not soluble Partition coefficient, n-octanol/water: Not known Other data: 10. STABILITY AND REACTIVITY Conditions/materials to avoid: Stable. May react with strong oxidising agents. Hazardous decomposition products: Thermal decomposition or incomplete combustion may produce oxides of carbon and irritating fumes. Bright and clear Weak pH: Slightly alkaline Boiling range, °C: Initial boiling point (oil base) > 300. Pour/melting point, °C: < -30 Flash point, °C: > 190 (ASTM D92, COC) Autoflammability/ignition, °C: > 300 (oil base) Upper explosion limit: Not known Lower explosion limit: Not known Vapour pressure, 20 °C, kPa: < 0.01 (oil base) Viscosity, kinematic, 40 °C, mm2/s: > 70 Relative density, 15 °C: 0.88 - 0.89 Water solubility: Not soluble Partition coefficient, n-octanol/water: Not known Other data: 10. STABILITY AND REACTIVITY Conditions/materials to avoid: Stable. May react with strong oxidising agents. Hazardous decomposition products: Thermal decomposition or incomplete combustion may produce oxides of carbon and irritating fumes. Green Acrylic odour Boiling Point: Not applicable Solubility in Water: Insoluble Viscosity: Approximately 500 mPa.s Relative Density: 1.07 Volatile Organic Compounds: < 5 g/litre Flash Point: >100 °C *10. STABILITY AND REACTIVITY Stability: Stable Conditions to Avoid: Avoid the absence of air, and metal contamination. Materials to Avoid: Metals and their salts., Reducing agents., Oxidizers., Free radical initiators Hazardous Decomposition Products: Thermal decomposition could produce carbon monoxide, carbon dioxide, and unidentified organic compounds. Green liquid Mild odour Flash Point (PMCC), deg C: 115 min Relative density: 1.119 @ 20 deg C Viscosity: 20 mm2/s @ 20 deg C pH: 8.2 @ 33% Solubility in water: 100% * 10. STABILITY AND REACTIVITY Conditions to avoid: Sources of ignition such as naked flames, sparks, hot surfaces. Materials to avoid: Avoid contact with strong oxidising agents. Hazardous decomposition products: Oxides of carbon, aldehydes and ketones. * Brown liquid Hydrocarbon pH: Not applicable Boiling Point/Range > 140 °C Melting point/Range > 0 °C Flammability: LEL 0.8 (% volume in air 25 °C) UEL 9.0 Auto Flammability: > 230 °C Explosive Properties: None Oxidising Properties: None Can Pressure: 2.41 bar Voc Content: 65g/100ml Relative Density: Not applicable Solubility (Water): Insoluble 9804/9018 ISSUE 1, March 2001 Solubility (Solvent): Soluble in aliphatic hydrocarbons 11. STABILITY AND REACTIVITY Stability: Stable Conditions to Avoid: Naked flames, red hot surfaces, other high temperature sources that may induce thermal decomposition. Incompatibility (materials to avoid): Oxidising agents, strong acids, strong alkalis. Hazardous Decomposition Products: In a fire hazardous decomposition products such as smoke, carbon monoxide, carbon dioxide and oxides of nitrogen may be produced. Clear orange mobile liquid Bland Relative Density: 1.03 @ 20 °C (Typical) pH Neat: 13.0 (approx) pH (1%): 8 (approx) Solubility (water): Miscible in all proportions. 10. STABILITY AND REACTIVITY Stable under normal conditions. Contact with light metal alloys can release hydrogen. Thermal decomposition will produce oxides of carbon and nitrogen (trace). Hazardous reactions:- strong oxidising agents. Brown liquid Hydrocarbon pH: Not applicable Boiling Point/Range > 140 °C Melting point/Range > 0 °C Flammability: LEL 0.8 (% volume in air 25 °C) UEL 9.0 Auto Flammability: > 230 °C Explosive Properties: None Oxidising Properties: None Can Pressure: 2.41 bar Voc Content: 65g/100ml Relative Density: Not applicable Solubility (Water): Insoluble 9804/9018 ISSUE 1, March 2001 Supplied in a variety of colours including white and translucent. Sharp acetic acid. Solubility in Water: Insoluble. pH: Not applicable. Relative Density (SG): 1.0 approx. Viscosity: No data. Flash Point : 100 °C - 150 °C. Boiling Point: Not applicable. 10. STABILITY AND REACTIVITY No hazardous instability. White to off white creamy paste with citrus scent. Flash Point (Method Used): > 240 ¡F (Cleveland Open Cup) 9804/8977 ISSUE 2, (REV.) NOVEMBER 1996 10. STABILITY AND REACTIVITY Stability: Stable Incompatibility: Some plastics. Keep covered. Avoid strong oxidising agents. Hazardous Decomposition Products: None known. Material is biodegradable. Coloured paint Ketone solvent pH: N/A Boiling point/boiling range: 55 °C Melting point/melting range: <0 °C Flash point: -40 °C Flammability: LEL 0.8 (% vol in air @ 25 °C) UEL 13.0 Autoflammability: >250 °C Explosive properties: None Oxidising properties: None Can pressure: 2.75 bar Relative density: VOC content: 63 g/100 ml Solubility-Water: Insoluble Solubility-Solvent: Soluble in ketones/esters Other data: 10. STABILITY AND REACTIVITY Stability: Stable Conditions to avoid: Avoid naked flames, red hot surfaces, other high temperature sources that may induce thermal decomposition. Incompatibility (Materials to avoid): Oxidising agents, strong acids, strong alkalis. Hazardous decomposition products: In a fire, hazardous decomposition products such as smoke, carbon monoxide, carbon dioxide and oxides of nitrogen may be produced. 9804/8951 ISSUE 2 (REV.), APRIL 1997 Coloured paint Ketone solvent pH: N/A Boiling point/boiling range: 55 °C Melting point/melting range: °C Flash point: -40 °C Flammability: LEL 0.8 (% vol in air @ 25 °C) UEL 13.0 Autoflammability: >250 °C Explosive properties: None Oxidising properties: None Can pressure: 2.75 bar Relative density: N/A VOC content: 62 g/100 ml Solubility-Water: Insoluble Solubility-Solvent: Soluble in ketones/esters Other data: 10. STABILITY AND REACTIVITY Stability: Stable Conditions to avoid: Avoid naked flames, red hot surfaces, other high temperature sources that may induce thermal decomposition. Incompatibility (Materials to avoid): Oxidising agents, strong acids, strong alkalis. Hazardous decomposition products: In a fire, hazardous decomposition products such as smoke, carbon monoxide, carbon dioxide and oxides of nitrogen may be produced. 9804/8952 ISSUE 2 (REV.), APRIL 1997 Coloured paint Ketone solvent pH: N/A Boiling point/boiling range: 55 °C Melting point/melting range: <0 °C Flash point: -40 °C Flammability: LEL 0.8 (% vol in air @ 25 °C) UEL 13.0 Autoflammability: >250 °C Explosive properties: None Oxidising properties: None Can pressure: 2.75 bar Relative density: VOC content: 63 g/100 ml Solubility-Water: Insoluble Solubility-Solvent: Soluble in ketones/esters Other data: 10. STABILITY AND REACTIVITY Stability: Stable Conditions to avoid: Avoid naked flames, red hot surfaces, other high temperature sources that may induce thermal decomposition. Incompatibility (Materials to avoid): Oxidising agents, strong acids, strong alkalis. Hazardous decomposition products: In a fire, hazardous decomposition products such as smoke, carbon monoxide, carbon dioxide and oxides of nitrogen may be produced. 9804/8953 ISSUE 2 (REV.), APRIL 1997 Coloured paint Ketone solvent pH: N/A Boiling point/boiling range: 55 °C Melting point/melting range: <0 °C Flash point: -40 °C Flammability: LEL 0.8 (% vol in air @ 25 °C) UEL 13.0 Autoflammability: >250 °C Explosive properties: None Oxidising properties: None Can pressure: 2.75 bar Relative density: VOC content: 63 g/100 ml Solubility-Water: Insoluble Solubility-Solvent: Soluble in ketones/esters Other data: 10. STABILITY AND REACTIVITY Stability: Stable Conditions to avoid: Avoid naked flames, red hot surfaces, other high temperature sources that may induce thermal decomposition. Incompatibility (Materials to avoid): Oxidising agents, strong acids, strong alkalis. Hazardous decomposition products: In a fire, hazardous decomposition products such as smoke, carbon monoxide, carbon dioxide and oxides of nitrogen may be produced. 9804/8954 ISSUE 2 (REV.), APRIL 1997 Coloured paint Ketone solvent pH: N/A Boiling point/boiling range: 55 °C Melting point/melting range: <0 °C Flash point: -40 °C Flammability: LEL 0.8 (% vol in air @ 25 °C) UEL 13.0 Autoflammability: >250 °C Explosive properties: None Oxidising properties: None Can pressure: 2.75 bar Relative density: VOC content: 63 g/100 ml Solubility-Water: Insoluble Solubility-Solvent: Soluble in ketones/esters Other data: 10. STABILITY AND REACTIVITY Stability: Stable Conditions to avoid: Avoid naked flames, red hot surfaces, other high temperature sources that may induce thermal decomposition. Incompatibility (Materials to avoid): Oxidising agents, strong acids, strong alkalis. Hazardous decomposition products: In a fire, hazardous decomposition products such as smoke, carbon monoxide, carbon dioxide and oxides of nitrogen may be produced. 9804/8955 ISSUE 2 (REV.), APRIL 1997 Red Acrylic odour Boiling Point: Not applicable Solubility in Water: Insoluble Viscosity: Approximately 75000 mPa.s Relative Density: 1.1 Volatile Organic Compounds: <5 g/l Flash Point: >100 °C *10. STABILITY AND REACTIVITY Stability: Stable Conditions to Avoid: Avoid the absence of air, and metal contamination. Materials to Avoid: Metals and their salts., Reducing agents., Oxidizers., Free radical initiators Hazardous Decomposition Products: Thermal decomposition could produce carbon monoxide, carbon dioxide, and unidentified organic compounds. Clear liquid Mild odour Flash point (ASTM D92), °C: > 200 Relative Density: 0.91 - 0.93 @ 15 °C Viscosity: 32 - 68 @ 40 °C 10. STABILITY AND REACTIVITY Materials to avoid Strong Oxidising agents Green petrol-like Oxidizing Properties: Not applicable Boiling Point: 63 °C Melting/Freezing Point: <-20 °C Solubility in Water: Insoluble Viscosity: 0.55 cSt Relative Density: 0.700 Evaporation Rate: 7.7 (Butyl Acetate) Vapour Pressure (mmHg): 187 (20 °C) Vapour Density (air=1): >1.0 Volatile Organic Compounds: 98% Autoflammability: >200 °C Flash Point: -26 °C (Tagliabue Closed Tester/Tag Closed Tester) *10. STABILITY AND REACTIVITY Stability: Stable Bright and clear Characteristic pH: Neutral Boiling range, °C: Initial boiling point (oil base) > 300 Pour/melting point, °C: < -39 - < -12 Flash point, °C: > 166 (ASTM D92, COC) Autoflammability/ignition, °C: > 300 (oil base) Upper explosion limit: Not known Lower explosion limit: Not known Vapour pressure, 20 °C, kPa: < 0.01 (oil base) Viscosity, kinematic, 40 °C, mm2/s: 25 - 431 Relative density, 15 °C: 0.88 - 0.91 Water solubility: Not soluble Partition coefficient, n-octanol/water: Not known Other data: 10. STABILITY AND REACTIVITY Conditions/materials to avoid: Stable. May react with strong oxidising agents. Hazardous decomposition products: Thermal decomposition or incomplete combustion may produce oxides of carbon and irritating fumes. Bright & clear Mineral oil pH Neutral Boiling range, °C Initial boiling point (oil base) appr. 300 Melting Point. °C < - 42 Flash Point, °C 176 (ASTM D93, P-M) Autoflammability/ ignition, °C > 300 (oil base) Upper explosion limit Not known Lower explosion limit Not known Vapour pressure, 20 °C, kPa < 0.01 (oil base) Viscosity, kinematic, 40 °C, mm²/s 35 Relative density, 15 °C 0.86 Water solubility Not soluble Partition coefficient, n-octanol/water Not known Other data - 10. STABILITY AND REACTIVITY Conditions / materials to avoid: Stable. May react with strong oxidizing agents. Hazardous decomposition products: Thermal decomposition or incomplete combustion may produce oxides of carbon and irritating fumes. 11. Bright & clear Weak pH Slightly alkaline Boiling range, °C Initial boiling point (oil base) > 300 Melting Point. °C < -15 Flash Point, °C > 190 (ASTM D92, COC) Autoflammability/ ignition, °C > 300 (oil base) Upper explosion limit Not known Lower explosion limit Not known Vapour pressure, 20 °C, kPa < 0.01 (oil base) Viscosity, kinematic, 40 °C, mm²/s > 40 Relative density, 15 °C 0.88 - 0.91 Water solubility Not soluble Partition coefficient, n-octanol/water Not known Other data - 10. STABILITY AND REACTIVITY Conditions / materials to avoid: Stable. May react with strong oxidizing agents. Hazardous decomposition products: Thermal decomposition or incomplete combustion may produce oxides of carbon and irritating fumes. 11. Bright & clear Weak pH Slightly alkaline Boiling range, °C Initial boiling point (oil base) > 300 Melting Point. °C < -15 Flash Point, °C > 190 (ASTM D92, COC) Autoflammability/ ignition, °C > 300 (oil base) Upper explosion limit Not known Lower explosion limit Not known Vapour pressure, 20 °C, kPa < 0.01 (oil base) Viscosity, kinematic, 40 °C, mm²/s > 40 Relative density, 15 °C 0.88 - 0.91 Water solubility Not soluble Partition coefficient, n-octanol/water Not known Other data - 10. STABILITY AND REACTIVITY Conditions / materials to avoid: Stable. May react with strong oxidizing agents. Hazardous decomposition products: Thermal decomposition or incomplete combustion may produce oxides of carbon and irritating fumes. 11. Bright and clear Weak pH: Slightly alkaline Boiling range, °C: Initial boiling point (oil base) > 300. Pour/melting point, °C: < -36 Flash point, °C: 200 (ASTM D92, COC) Autoflammability/ignition, °C: > 300 (oil base) Upper explosion limit: Not known Lower explosion limit: Not known Vapour pressure, 20 °C, kPa: < 0.01 (oil base) Viscosity, kinematic, 40 °C, mm2/s: 77 Relative density, 15 °C: 0.879 Water solubility: Not soluble Partition coefficient, n-octanol/water: Not known Other data: 10. STABILITY AND REACTIVITY Conditions/materials to avoid: Stable. May react with strong oxidising agents. Hazardous decomposition products: Thermal decomposition or incomplete combustion may produce oxides of carbon and irritating fumes. Bright & clear Weak pH Slightly alkaline Boiling range, °C Initial boiling point (oil base) > 300 Melting Point. °C < - 24 Flash Point, °C 206 (ASTM D93, P-M) Autoflammability/ ignition, °C > 300 (oil base) Upper explosion limit Not known Lower explosion limit Not known Vapour pressure, 20 °C, kPa < 0.01 (oil base) Viscosity, kinematic, 40 °C, mm²/s 102 Relative density, 15 °C 0.89 Water solubility Not soluble Partition coefficient, n-octanol/water Not known Other data - 10. STABILITY AND REACTIVITY Conditions / materials to avoid: Stable. May react with strong oxidizing agents. Hazardous decomposition products: Thermal decomposition or incomplete combustion may produce oxides of carbon and irritating fumes. 11. Bright and clear Weak pH: Slightly alkaline Boiling range, °C: Initial boiling point (oil base) > 300 Pour/melting point, °C: < -27 Flash point, °C: > 200 (ASTM D92, COC) Autoflammability/ignition, °C: > 300 (oil base) Upper explosion limit: Not known Lower explosion limit: Not known Vapour pressure, 20 °C, kPa: < 0.01 (oil base) Viscosity, kinematic, 40 °C, mm2/s: > 70 Relative density, 15 °C: 0.88 Water solubility: Not soluble Partition coefficient, n-octanol/water: Not known Other data: 10. STABILITY AND REACTIVITY Conditions/materials to avoid: Stable. May react with strong oxidising agents. Hazardous decomposition products: Thermal decomposition or incomplete combustion may produce oxides of carbon and irritating fumes. Bright & clear Characteristic pH Neutral Boiling range, °C Initial boiling point (oil base) > 300 Melting Point. °C < -24 Flash Point, °C > 176 (ASTM D92, COC) Autoflammability/ ignition, °C > 300 (oil base) Upper explosion limit Not known Lower explosion limit Not known Vapour pressure, 20 °C, kPa < 0.01 (oil base) Viscosity, kinematic, 40 °C, mm²/s Indicated by grade designation. Relative density, 15 °C 0.87 - 0.88 Water solubility Not soluble Partition coefficient, n-octanol/water Not known Other data - 10. STABILITY AND REACTIVITY Conditions / materials to avoid: Stable. May react with strong oxidizing agents. Hazardous decomposition products: Thermal decomposition or incomplete combustion may produce oxides of carbon and irritating fumes. 11. Bright & clear : Weak pH Neutral Boiling range, °C Initial boiling point (oil base) > 176 Melting Point. °C : < -30 Flash Point, °C : > 70 (ASTM D 93, P-M) Autoflammability/ ignition, °C 210 (oil base) Upper explosion limit 7.0 % vol. -air (oil base) Lower explosion limit 0.6 % vol. -air (oil base) Vapour pressure, 20 °C, kPa Appr. 0.04 (oil base) Viscosity, kinematic, 40 °C, mm²/s : 52 Relative density, 15 °C 0.88 Water solubility Not soluble Partition coefficient, n-octanol/water Not known Other data - 10. STABILITY AND REACTIVITY Conditions / materials to avoid: Stable. May react with strong oxidizing agents. Hazardous decomposition products: Thermal decomposition or incomplete combustion may produce oxides of carbon and irritating fumes. 11. Bright & clear Characteristic pH Neutral Boiling range, °C Initial boiling point (oil base) > 300 Melting Point. °C -12 Flash Point, °C : > 200 (ASTM D92, COC) Autoflammability/ ignition, °C : > 300 (oil base) Upper explosion limit Not known Lower explosion limit Not known Vapour pressure, 20 °C, kPa : < 0.01 Viscosity, kinematic, 40 °C, mm²/s 150 Relative density, 15 °C 0.89 Water solubility Not soluble Partition coefficient, n-octanol/water Not known Other data - 10. STABILITY AND REACTIVITY Conditions / materials to avoid: Stable. May react with strong oxidizing agents. Hazardous decomposition products: Thermal decomposition or incomplete combustion may produce oxides of carbon and irritating fumes. 11. Bright & clear Characteristic pH Neutral Boiling range, °C Initial boiling point (oil base) > 300 Melting Point. °C : < -12 Flash Point, °C : > 180 (ASTM D93, P-M) Autoflammability/ ignition, °C : > 300 (oil base) Upper explosion limit Not known Lower explosion limit Not known Vapour pressure, 20 °C, kPa : < 0.01 (oil base) Viscosity, kinematic, 40 °C, mm²/s : 68 Relative density, 15 °C 0.88 Water solubility Not soluble Partition coefficient, n-octanol/water Not known Other data - 10. STABILITY AND REACTIVITY Conditions / materials to avoid: Stable. May react with strong oxidizing agents. Hazardous decomposition products: Thermal decomposition or incomplete combustion may produce oxides of carbon and irritating fumes. 11. Bright & clear : Weak pH Slightly alkaline Boiling range, °C Initial boiling point (oil base) > 300 Melting Point. °C : < -21 Flash Point, °C : > 200 (ASTM D92, COC) Autoflammability/ ignition, °C : > 300 (oil base) Upper explosion limit Not known Lower explosion limit Not known Vapour pressure, 20 °C, kPa : < 0.01 (oil base) Viscosity, kinematic, 40 °C, mm²/s : 90 Relative density, 15 °C 0.89 Water solubility Not soluble Partition coefficient, n-octanol/water Not known Other data - 10. STABILITY AND REACTIVITY Conditions / materials to avoid: Stable. May react with strong oxidizing agents. Hazardous decomposition products: Thermal decomposition or incomplete combustion may produce oxides of carbon and irritating fumes. 11. Bright and clear Characteristic pH: Neutral Boiling range, °C: Initial boiling point (oil base) > 300 Pour/melting point, °C: < -39 - < -12 Flash point, °C: > 166 (ASTM D92, COC) Autoflammability/ignition, °C: > 300 (oil base) Upper explosion limit: Not known Lower explosion limit: Not known Vapour pressure, 20 °C, kPa: < 0.01 (oil base) Viscosity, kinematic, 40 °C, mm2/s: 25 - 431 Relative density, 15 °C: 0.88 - 0.91 Water solubility: Not soluble Partition coefficient, n-octanol/water: Not known Other data: 10. STABILITY AND REACTIVITY Conditions/materials to avoid: Stable. May react with strong oxidising agents. Hazardous decomposition products: Thermal decomposition or incomplete combustion may produce oxides of carbon and irritating fumes. Dark amber liquid Mild nineral Specific gravity @ 15.6 °C: 0.874 pH: Not applicable Vapour pressure (mm Hg)@ 20 °C: < 0.01 Vapour density (air=1): > 1 Boiling point (°C): Pour/melting point, (°: Flash point, (°C, PMCC): > 150 Autoignition temperature, °: Flammability limit in air, % by volume: LEL: UEL: Volatile organic compounds, %: Kinematic viscosity (cSt) 40 °C: 95 Solubility: Insoluble in water. Soluble in petroleum solvents. PLEASE NOTE: THESE PROPERTIES ARE FOR GUIDANCE ONLY. THEY DO NOT CONSTITUTE A SPECIFICATION 10. STABILITY AND REACTIVITY Stability: The product is stable and not subject to polymerisation. Conditions to avoid: Avoid exposure to extreme heat. Materials to avoid: Incompatible with strong oxidising agents. Hazardous decomposition products: Oxides of carbon and water vapour with unidentified organic compounds, dense, white, irritating smoke.

Hazard pictograms

None I64;' None None None None None None OES 8hr ppm OES 15min ppm HARMFUL Named Substances: White spirit Warning label phrases: Flammable. Harmful if swallowed. Do not breathe vapour/spray. In case of insufficient ventilation, wear suitable respiratory equipment. Use only in well ventilated areas. The information contained in this data sheet does not constitute the user’s own assessment of workplace risks as required by other health and safety legislation. The provisions of the Health and Safety at Work etc. Act and the Control of Substances Hazardous to Health Regulations apply to the use of this product at work. HARMFUL Named Substances: White spirit Warning label phrases: Flammable. Harmful if swallowed. Do not breathe vapour/spray. In case of insufficient ventilation, wear suitable respiratory equipment. Use only in well ventilated areas. For colours containing lead chromate (see Section 1): TOXIC Named Substances: Lead Chromates White spirit Warning label phrases: Contains lead. Should not be used on surfaces that are liable to be chewed or sucked by children. Restricted to professional users. Flammable. Danger of cumulative effects. Possible risk of irreversible effects. May cause harm to the unborn child. Possible risk of impaired fertility. When using do not eat, drink or smoke. Do not breathe vapour/spray. During spraying wear air-fed respiratory protective equipment. Use only in well ventilated areas. The information contained in this data sheet does not constitute the user’s own assessment of workplace risks as required by other health and safety legislation. The provisions of the Health and Safety at Work etc. Act and the Control of Substances Hazardous to Health Regulations apply to the use of this product at work. 9804/8927 ISSUE 3 (REV.), MARCH 1997 TOXIC Named Substances: Lead Chromates White spirit Warning label phrases: Contains lead. Should not be used on surfaces that are liable to be chewed or sucked by children. Restricted to professional users. Flammable. Danger of cumulative effects. Possible risk of irreversible effects. May cause harm to the unborn child. Possible risk of impaired fertility. When using do not eat, drink or smoke. Do not breathe vapour/spray. During spraying wear air-fed respiratory protective equipment. Use only in well ventilated areas. The information contained in this data sheet does not constitute the user’s own assessment of workplace risks as required by other health and safety legislation. The provisions of the Health and Safety at Work etc. Act and the Control of Substances Hazardous to Health Regulations apply to the use of this product at work. HARMFUL Named Substances: White spirit Warning label phrases: Flammable. Harmful if swallowed. Do not breathe vapour/spray. in case of insufficient ventilation, wear suitable respiratory equipment. Use only in well ventilated areas. cont’d 9804/8923 ISSUE 5 (REV.), JUNE 2002 TOXIC Named Substances: Lead Chromates White spirit Warning label phrases: Contains lead. Should not be used on surfaces that are liable to be chewed or sucked by children. Restricted to professional users. Flammable. Danger of cumulative effects. Possible risk of irreversible effects. May cause harm to the unborn child. Possible risk of impaired fertility. When using, do not eat, drink or smoke. Do not breathe vapour/spray. During spraying wear air-fed respiratory protective equipment. Use only in well ventilated areas. The information contained in this data sheet does not constitute the user’s own assessment of workplace risks as required by other health and safety legislation. The provisions of the Health and Safety at Work etc. Act and the Control of Substances Hazardous to Health Regulations apply to the use of this product at work. TOXIC Named Substances: Lead Chromates White spirit Warning label phrases: Contains lead. Should not be used on surfaces that are liable to be chewed or sucked by children. Restricted to professional users. Fammable. Danger of cumulative effects. Possible risk of irreversible effects. May cause harm to the unborn child. Possible risk of impaired fertility When using do not eat, drink or smoke Do not breathe vapour/spray. During spraying wear air-fed respiratory protective equipment. Use only in well ventilated areas. The information contained in this data sheet does not constitute the user’s own assessment of workplace risks as required by other health and safety legislation. The provisions of the Health and Safety at Work etc. Act and the Control of Substances Hazardous to Health Regulations apply to the use of this product at work. Warning label phrases: Flammable. Keep away from sources of ignition - No smoking Keep out of reach of children Ensure maximum ventilation during application and drying. When applying by brush or roller to large interior surfaces or in confined spaces, wear a suitable cartridge respirator or air-fed respiratory protective equipment. Avoid contact with skin and eyes. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. After contact with skin, wash immediately with plenty of soap and water or proprietary skin cleanser. cont’d 9804/8964 ISSUE 3 (REV.), JUNE 2002 * Warning label phrases: Flammable. Keep away from sources of ignition - No Smoking. Keep out of reach of children. Ensure maximum ventilation during application and drying. When spraying, do not breathe spray, wear suitable respiratory equipment. On large interior surfaces or in confined spaces, wear air-fed respiratory equipment. Avoid contact with skin and eyes. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. After contact with skin, wash immediately with plenty of soap and water or proprietary skin cleanser. 9804/8965 ISSUE 3 (REV.), NOVEMBER 1997 15. REGULATORY INFORMATION continued Additive:- HARMFUL Named Substances: Aliphatic polyepoxide * Warning label phrases: Flammable. Irritating to respiratory system. Possible risk of irreversible effects. When using do not eat, drink or smoke Do not breathe vapour/spray. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. During spraying wear air-fed respiratory protective equipment. The information contained in this data sheet does not constitute the user’s own assessment of workplace risks as required by other health and safety legislation. The provisions of the Health and Safety at Work etc. Act and the Control of Substances Hazardous to Health Regulations apply to the use of this product at work. Warning label phrases: Flammable Keep away from sources of ignition - No smoking. Keep out of reach of children. Ensure maximum ventilation during application and drying. When spraying, do not breathe spray, wear suitable respiratory equipment. On large interior surfaces or in confined spaces, wear air-fed respiratory equipment. Avoid contact with skin and eyes. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. After contact with skin, wash immediately with plenty of soap and water or proprietary skin cleanser. Additive:- No label code for VH2371 The information contained in this data sheet does not constitute the user’s own assessment of workplace risks as required by other health and safety legislation. The provisions of the Health and Safety at Work etc. Act and the Control of Substances Hazardous to Health Regulations apply to the use of this product at work. HIGHLY TOXIC FLAMMABLE Named Substances: Lead Chromates Warning label phrases: Contains lead. Should not be used on surfaces that are liable to be chewed or sucked by children. Restricted to professional users. Danger of cumulative effects. Possible risk of irreversible effects. May cause harm to the unborn child. Possible risk of impaired fertility. Keep away from sources of ignition - No smoking. When using, do not eat, drink or smoke. Do not breathe vapour/spray. During spraying wear air-fed respiratory protective equipment. The information contained in this data sheet does not constitute the user’s own assessment of workplace risks as required by other health and safety legislation. The provisions of the Health and Safety at Work etc. Act and the Control of Substances Hazardous to Health Regulations apply to the use of this product at work. HIGHLY TOXIC FLAMMABLE Named Substances: Lead Chromates Warning label phrases: Contains lead. Should not be used on surfaces that are liable to be chewed or sucked by children. Restricted to professional users. Danger of cumulative effects. Possible risk of irreversible effects. May cause harm to the unborn child. Possible risk of impaired fertility. Keep away from sources of ignition - No smoking. When using, do not eat, drink or smoke. Do not breathe vapour/spray. During spraying wear air-fed respiratory protective equipment. The information contained in this data sheet does not constitute the user’s own assessment of workplace risks as required by other health and safety legislation. The provisions of the Health and Safety at Work etc. Act and the Control of Substances Hazardous to Health Regulations apply to the use of this product at work. HARMFUL Named Substances: Xylene (mixture of isomers) Warning label phrases: Flammable Harmful by inhalation and in contact with skin. Do not breathe vapour/spray. In case of insufficient ventilation, wear suitable respiratory equipment. Use only in well ventilated areas. Base for colours containing lead chromate (see Section 1): TOXIC Named Substances: Lead Chromates Xylene (mixture of isomers) Warning label phrases: Contains lead. Should not be used on surfaces that are liable to be chewed or sucked by children. Restricted to professional users. Flammable. Danger of cumulative effects. Possible risk of irreversible effects May cause harm to the unborn child Possible risk of impaired fertility When using do not eat, drink or smoke Do not breathe vapour/spray. During spraying wear air-fed respiratory protective equipment. Use only in well ventilated areas. Additive: HARMFUL Named Substances: Aliphatic polyepoxide cont’d 9804/9012 ISSUE 2, NOVEMBER 1997 Warning label phrases: Flammable. Irritating to respiratory system Possible risk of irreversible effects When using do not eat, drink or smoke Do not breathe vapour/spray. In case of contact with eyes, rinse immediately with planty of water and seek medical advice. During spraying wear air-fed respiratory protective equipment. The information contained in this data sheet does not constitute the user’s own assessment of workplace risks as required by other health and safety legislation. The provisions of the Health and Safety at Work etc. Act and the Control of Substances Hazardous to Health Regulations apply to the use of this product at work. L;9@' K;9A( nr. 3 Page: 3175 Packaging group: II Marine pollutant: no IATA/ICAO Un no.: 1987 Class: 3 flammable liquid Packaging group: II Name: Alcohols, n.o.s. OES 8hr OES OES 8hr OES OES 8 hr OES OES 8 hr OES None OES 8hr OES OES 8hr OES None None None None None None None None R Phrases 1 Severely solvent refined mineral oil Ca. 85 - 4002/1223, 4002/1224 (IP346 DMSO extract < 3 %) 2 Aliphatic hydrocarbon solvent 265-149-9 64742-47-8 10 - 15 Xn JCB High Performance Biodegradable Hydraulic Fluid R65,R66 3 Functional additives - 4 Calcium sulphonates 0.1 - 0.5 Xi R43 International Product code & Name: 32082 HYDRA 46 No substances are present in concentrations regarded to present a hazard (Directive 1999/45/EC). Description: Hydraulic Oil 3. Distributor: JCB SERVICE Health: Unlikely to cause eye irritation. Unlikely to cause immediate irritation but prolonged and repeated contact may be harmful to the skin. Not volatile. It is not likely to be an inhalation hazard at normal ambient temperatures. *2. COMPOSITION/INFORMATION ON INGREDIENTS If overheated, fumes and vapours are slightly irritating to the breathing passages and lungs. Ingestion is unlikely to cause adverse systemic health effects. Name % Wt CAS No. EC No. Environmental: Although no specific ecological hazards are expected and bioaccumulation is unlikely, Fatty acid ester 95 - 99.99 CBI spillage into the environment should always be avoided. Additive 1 - 2.99 CBI Physical / Chemical: Not applicable Additional None Information: 4. FIRST AID MEASURES Warning statement None considered necessary. Acute effects of exposure to man Inhalation Vapours or mist in unusually high concentrations, as from exposure in poorly ventilated areas or confined spaces, may cause irritation of the nose and throat, headache, nausea and drowsiness. Skin Contact file://C:\My Documents\Oils\5670_JCBTwoStrokeOil_E.htm Brief contact is not irritating. Prolonged contact, as with clothing wetted with material, may cause defatting of skin or 3/4/03 irritation, seen as local redness with possible mild discomfort. Eye Contact May cause minimal irritation, experienced as temporary discomfort. Ingestion No adverse effects expected. If more than several mouthfuls are swallowed, abdominal discomfort, nausea, and diarrhoea may occur. Continued..... JCB Two Stroke Oil 9804/9042 ISSUE 1, MARCH 2003 None R Phrases 1 Severely solvent refined mineral oil > 99 - 4002/1223, 4002/1224 (IP346 DMSO extract < 3 %) 2 Functional additives JCB High Performance Biodegradable Hydraulic Fluid No substances are present in concentrations regarded to present a hazard (Directive 1999/45/EC). International Product code & Name: 32082 HYDRA 46 3. Description: Hydraulic Oil Health: Unlikely to cause eye irritation. Unlikely to cause immediate irritation but prolonged and repeated contact may be harmful to the skin. Distributor: JCB SERVICE Not volatile. It is not likely to be an inhalation hazard at normal ambient temperatures. If overheated, fumes and vapours are irritating to the breathing passages and lungs. Ingestion is unlikely to cause adverse systemic health effects. *2. COMPOSITION/INFORMATION ON INGREDIENTS Environmental: Although no specific ecological hazards are expected and bioaccumulation is unlikely, spillage into the environment should always be avoided. Name % Wt CAS No. EC No. Fatty acid ester 95 - 99.99 CBI Physical / Chemical: Not applicable Additive 1 - 2.99 CBI None R Phrases 1 Severely solvent refined mineral oil > 99 - - 4002/1223, 4002/1224 (IP346 DMSO extract < 3 %) 2 Functional additives < 1 Xi,N R36/38,R51/53 JCB High Performance Biodegradable Hydraulic Fluid No substances are present in concentrations regarded to present a hazard (Directive 1999/45/EC). International Product code & Name: 32082 HYDRA 46 3. Description: Hydraulic Oil Health: Unlikely to cause eye irritation. Unlikely to cause immediate irritation but prolonged and repeated contact may be harmful to the skin. Distributor: JCB SERVICE Not volatile. It is not likely to be an inhalation hazard at normal ambient temperatures. If overheated, fumes and vapours are slightly irritating to the breathing passages and lungs. Ingestion is unlikely to cause adverse systemic health effects. *2. COMPOSITION/INFORMATION ON INGREDIENTS Environmental: Although no specific ecological hazards are expected and bioaccumulation is unlikely, spillage into the environment should always be avoided. Name % Wt CAS No. EC No. Fatty acid ester 95 - 99.99 CBI Physical / Chemical: Not applicable Additive 1 - 2.99 CBI None R Phrases 1 Severely solvent refined mineral oil Ca. 95 - - 4002/1223, 4002/1224 (IP346 DMSO extract < 3 %) 2 Zinc alkyldithiophosphate 272-028-3 68649-42-3 0.5 - 1.5 Xi R38,R41,R51/53 JCB High Performance Biodegradable Hydraulic Fluid 3 Calcium/magnesium sulphonates & - phenates 4 Hydrocarbon polymers - International Product code & Name: 32082 HYDRA 46 No substances are present in concentrations regarded to present a hazard (Directive 1999/45/EC). Description: Hydraulic Oil 3. Distributor: JCB SERVICE Health: Slightly irritating to the eye. Unlikely to cause immediate irritation but prolonged and repeated contact may be harmful to the skin. *2. COMPOSITION/INFORMATION ON INGREDIENTS Not volatile. It is not likely to be an inhalation hazard at normal ambient temperatures. If overheated, fumes and vapours are irritating to the breathing passages and lungs. Ingestion is unlikely to cause adverse systemic health effects. Name % Wt CAS No. EC No. Fatty acid ester 95 - 99.99 CBI Environmental: Although no specific ecological hazards are expected and bioaccumulation is unlikely, Additive 1 - 2.99 CBI spillage into the environment should always be avoided. Physical / Chemical: Not applicable None None

EC Classification

and Labelling EC labelling not required The following product ingredients are cited on the lists below: Chemical Name: CAS Number: List Citations: No reportable ingredients Regulatory Lists Searched: 1 = IARC 1 6 = NO ALLERGI 11 = DE TERAT B 16 = DE CARC B 21 = CH CARC 2 = IARC 2A 7 = SE ALLERGY 12 = DE TERAT C 17 = AT TERAT A 3 = IARC 2B 8 = SE CARC 13 = DE TERAT D 18 = AT TERAT B 4 = NTP CARC 9 = DK CARC 14 = DE CARC A1 19 = AT TERAT C 5 = NTP SUS 10 = DE TERAT A 15 = DE CARC A2 20 = AT TERAT D CARC = Carcinogen SUS = Suspected Carcinogen TERAT = Teratogenic AT = Austria DE = Germany NO = Norway CH = Switzerland DK = Denmark SE = Sweden and Labelling EC labelling not required The following product ingredients are cited on the lists below: Chemical Name: CAS Number: List Citations: No reportable ingredients Regulatory Lists Searched: 1 = IARC 1 6 = NO ALLERGI 11 = DE TERAT B 16 = DE CARC B 21 = CH CARC 2 = IARC 2A 7 = SE ALLERGY 12 = DE TERAT C 17 = AT TERAT A 3 = IARC 2B 8 = SE CARC 13 = DE TERAT D 18 = AT TERAT B 4 = NTP CARC 9 = DK CARC 14 = DE CARC A1 19 = AT TERAT C 5 = NTP SUS 10 = DE TERAT A 15 = DE CARC A2 20 = AT TERAT D CARC = Carcinogen SUS = Suspected Carcinogen TERAT = Teratogenic AT = Austria DE = Germany NO = Norway CH = Switzerland DK = Denmark SE = Sweden 9804/8897 ISSUE 3 (REV.), NOVEMBER 1997 and Labelling EC labelling not required The following product ingredients are cited on the lists below: Chemical Name: CAS Number: List Citations: No reportable ingredients Regulatory Lists Searched: 1 = IARC 1 6 = NO ALLERGI 11 = DE TERAT B 16 = DE CARC B 21 = CH CARC 2 = IARC 2A 7 = SE ALLERGY 12 = DE TERAT C 17 = AT TERAT A 3 = IARC 2B 8 = SE CARC 13 = DE TERAT D 18 = AT TERAT B 4 = NTP CARC 9 = DK CARC 14 = DE CARC A1 19 = AT TERAT C 5 = NTP SUS 10 = DE TERAT A 15 = DE CARC A2 20 = AT TERAT D cont’d 9804/8944 ISSUE 3 (REV.), NOVEMBER 1997 CARC = Carcinogen SUS = Suspected Carcinogen TERAT = Teratogenic AT = Austria DE = Germany NO = Norway CH = Switzerland DK = Denmark SE = Sweden Butyl titanate 1.00 5.00 Harmful R10, R20, R36/38 Isopropyl alcohol 90.00 98.00 N/A R11 Main Hazards: Highly flammable. Diphenylmethandiisocyanate 0.01 0.50 Harmful R36/37/38, R20, R42 Isophorondiisocyanate 0.01 0.50 Toxic R23, R36/37/38, R42/43 White Spirit 1.00 5.00 N/A R10 Xylene 1.00 5.00 Harmful R10, R20/21, R38 Main Hazards: The product contains minute quantities of monomeric isocyanates. Persons known to be hypersensitive (asthma, chronic bronchitis, etc.) should refrain from handling the product. 4. FIRST-AID MEASURES Eye Contact: Wash out eye with plenty of water. Obtain medical attention urgently. Skin Contact: Wipe off as much as possible with a clean dry cloth. Wash skin thoroughly with soap and water. Solvents should not be used to clean skin because they may increase the penetration of the material. Contaminated clothing should be washed or dry-cleaned before re-use. Ingestion: Do not induce vomiting. Wash out mouth with water. Obtain medical attention. Inhalation: Unlikely to occur. However provide symptomatic medical treatment if required. 9804/8974 ISSUE 4, (REV.) NOVEMBER 1997 5. FIRE-FIGHTING MEASURES Extinguishing Media: Use water spray, foam, dry chemical or carbon dioxide. Special Hazards of Product: Thermal decomposition or burning may release oxides of carbon, nitrogen and other toxic gases and vapours. Protective Equipment for Fire-Fighting: Wear full protective clothing and self-contained breathing apparatus. 6. ACCIDENTAL RELEASE MEASURES Personal Precautions: Wear appropriate protective clothing. Spillages: Remove spilled/leaked product by scraping from surfaces. Allow to solidify normally. Clean surfaces with a suitable solvent. Environmental Precautions: Try to prevent the material from entering drains or water courses. 7. HANDLING AND STORAGE Handling: Use in well ventilated area. Avoid contact with eyes, skin and clothing. Diphenylmethandiisocyanate 0.01 0.50 Harmful R36/37/38, R20, R42 Isophorondiisocyanate 0.01 0.50 Toxic R23, R36/37/38, R42/43 Xylene 1.00 5.00 Harmful R10, R20/21, R38 Main Hazards: The product contains minute quantities of monomeric isocyanates. Persons known to be hypersensitive (asthma, chronic bronchitis, etc.) should refrain from handling the product. 4. FIRST-AID MEASURES Eye Contact: Wash out eye with plenty of water. Obtain medical attention urgently. Skin Contact: Wipe off as much as possible with a clean dry cloth. Wash skin thoroughly with soap and water. Solvents should not be used to clean skin because they may increase the penetration of the material. Contaminated clothing should be washed or dry-cleaned before re-use. Ingestion: Do not induce vomiting. Wash out mouth with water. Obtain medical attention. Inhalation: Unlikely to occur. However provide symptomatic medical treatment if required. 9804/8989 ISSUE 3, (REV.) NOVEMBER 1996 5. FIRE-FIGHTING MEASURES Extinguishing Media: Use water spray, foam, dry chemical or carbon dioxide. Special Hazards of Product: Thermal decomposition or burning may release oxides of carbon, nitrogen and other toxic gases and vapours. Protective Equipment for Fire-Fighting: Wear full protective clothing and self-contained breathing apparatus. 6. ACCIDENTAL RELEASE MEASURES Personal Precautions: Wear appropriate protective clothing. Spillages: Remove spilled/leaked product by scraping from surfaces. Allow to solidify normally. Clean surfaces with a suitable solvent. Environmental Precautions: Try to prevent the material from entering drains or water courses. 7. HANDLING AND STORAGE Handling: Use in well ventilated area. Avoid contact with eyes, skin and clothing. Ethyl acetate 60.00 70.00 N/A Ethyl Benzene 1.00 5.00 Harmful R11 R20 Xylene 5.00 10.00 Harmful R10 R20/21 R38 Main Hazards: Highly flammable

Disposal

by incineration or by methods approved by Local Authority 14. TRANSPORT INFORMATION Not applicable - non-hazardous 15. REGULATORY INFORMATION As far as is known not classified according to EEC Directives 67/548/EEC and 88/379/EEC. Methods Dispose of in accordance with Local Authority requirements. Do not allow the product to enter drains or water courses, or be deposited where it can affect ground or surface waters. 14. TRANSPORT INFORMATION Road UN No. 1263 ADR item No.: 31 ADR Class: 3 Cefic Tec (R) No.: N/D Marginal: (c) Label for Conveyance: No transport warning sign required. Air UN No.: 1263 Air Transport Class No.: N/D Sea UN No.: 1263 Sea Transport Class No.: 3.3 Sea Pack GR: III Marine Pollutant: yes Rail Rail Transport Class No.: N/D 9804/8895 ISSUE 3 (REV.), NOVEMBER 1997 15. REGULATORY INFORMATION Label for supply: Flammable (no symbol required) Dispose in accordance with local laws and regulations governing disposal of chemicals. * 14. TRANSPORT INFORMATION Not regulated * 15. REGULATORY INFORMATION Standard procedures for 'water insoluble' non-toxic chemicals recommended. Dispose of in accordance with local and national regulations. 9804/8984 ISSUE 2, SEPTEMBER 1995 Page 3 of 4 9804/8984 ISSUE 2, SEPTEMBER 1995 SDS 128249 14. TRANSPORT INFORMATION UN No.: None Air(IATA): Not classified Sea(IMO): Not classified. Road/Rail (ADR/RID): Not classified. 15. REGULATORY INFORMATION Hazard Label: none Evaporation and incinerations recommended. Dispose of in accordance with local and national regulations. 9804/8982 ISSUE 2, SEPTEMBER 1995 Page 3 of 4 9804/8982 ISSUE 2, SEPTEMBER 1995 SDS 178061 14. TRANSPORT INFORMATION UN No.: 1993 (1950 for aerosol version) Air(IATA): Flammable liquid, n.o.s. Glass 3, Pkg, Grp. II. (Aerosol, flammable, n.o.s., Class 2.1, flammable gas.) Sea(IMO): Flammable liquid n.o.s. Class 3.2, Pkg. Grp. II, (Aerosol, Class 9 Pkg. Grp. II.) Road/Rail (ADR/RID): Inflammable liquid, Class 3, label No. 3 (Gas, compressed, Class 2, Aerosol). 15. REGULATORY INFORMATION Hazard Label: Highly flammable Product Disposal: Dispose of as Special Waste. Container Disposal: Empty containers may contain hazardous residues. Do not incinerate closed containers. 9804/8990 ISSUE 4, NOVEMBER 1997 14. TRANSPORT INFORMATION (See also section 9) Dispose in accordance with local laws and regulations. 14. TRANSPORT INFORMATION Not regulated. 15. REGULATORY INFORMATION Product can be used completely. Rinse bottle with water: normal waste disposal Methods Empty containers must not be burned because of explosion hazard. Dispose of in accordance with Local Authority requirements. Contact specialist disposal companies. 14. TRANSPORT INFORMATION Label for Conveyance: Road: UN No: 1950 HAZARD CLASS (ADR): Class 2: Gases; Compressed, liquefied or dissolved under pressure. ADR CLASS No: 2 ADR ITEM No: 5F MARGINAL: 2201 PROPER SHIPPING NAME I: AEROSOLS ROAD TRANSPORT NOTES: Exempted from control as Limited Quantity provisions apply. Rail: RAIL TRANSPORT CLASS No: 2.1 RAILROAD PT: 5F Sea: UN SEA: 1950 SEA TRANSPORT CLASS No: 2.1 IMDG Page No: 2102 EmS No.: 2-13 MFAG Table No: 620 Air: UN AIR: 1950 AIR TRANSPORT CLASS No: 2.1 15. REGULATORY INFORMATION Label for Supply: Remit the soiled material to an authorised waste collector. 7. HANDLING AND STORAGE Handling Technical Measures - Prevention of user exposure: Provide adequate ventilation in case of the potential formation of vapour, mist or spray. Keep away from flammable material: keep away from food and beverages. - Prevention of fire and explosion: Product-impregnated cloths and paper or material used to mop up spills can constitute a fire hazard. Do not allow these to accumulate in a pile. Discard these with all safety precautions immediately after use. Dispose of in accordance with local regulations. Used Packaging: - Disposal methods: Transmit to an authorised waste contractor for disposal. 14. TRANSPORT INFORMATION International Regulations - by land: Not applicable - by sea: Not applicable - by air: Not applicable - UN Classification number: Not applicable 15. REGULATORY INFORMATION European Regulations EC labelling Product Disposal Dispose of as Special Waste. Arrange for disposal via a licensed waste contractor. Container Disposal Dispose of containers with care. Empty containers my contain hazardous residues. Empty packaging should be removed by a licensed waste contractor. 14. TRANSPORT INFORMATION UN Product Disposal Dispose of as Special Waste. If possible allow the product to cure naturally in open air. When cure the product may be landfilled. Dispose of bulk quantities and/or containers should be made through an authorised waste contractor. 14. TRANSPORT INFORMATION ADR/RID Substance Identification Not regulated under ADR/RID Number IMDG Proper Shipping Name Not regulated under IMDG IATA Proper Shipping Name Not regulated under ICAO 15. REGULATORY INFORMATION Label Requirements Harmful. Methods Dispose of in accordance with Local Authority requirements. * 14. TRANSPORT INFORMATION Road Transport Notes: Not Classified. Rail Transport Notes: Not Classified. Sea Transport Notes: Not Classified. Continued................ 9804/8962 ISSUE 4, (REV) AUGUST 2002

2.1 Classification of the substance or mixture

1. Hydrogenated hydrocarbon (<0.1% w/w benzene) 20.00 - 50.00 R65, R10 Xn, f 2. White spirit (<0.1% w/w benzene) 2.00 - 20.00 R10, R65, R51/53 f, Xn, N 3. Carbon Dioxide 1.00 - 5.00 Main Hazards Flammable Irritant Xn - Harmful F - Highly Flammable Xn - Harmful Flammable Xn - Harmful Flammable Xn - Harmful Flammable Phrases* Number White spirit 25-50% Xn R65 064742-82-1 For colours listed in Section 1 as containing lead chromate:- White spirit 25-50% Xn R65 064742-82-1 Lead Chromates >1 R33 7758-97-6 Carc. Cat. 3 R40 Repr. Cat. 1 R61 Repr. Cat. 3 R62 (*) For full details of R-phrases, see Section 16. 9804/8926 ISSUE 5 (REV.), MARCH 2002 Phrases* Number White Spirit >50% Xn R65 064742-82-1 (*) For full details of R-phrases, see Section 16. * Xn R10 Flammable R65 Harmful: may cause lung damage if swallowed 9804/8958 ISSUE 3 (REV.), FEB 2002 Phrases* Number White spirit 25-50% Xn R22 064742-82-1 (*) For full details of R-phrases, see Section 16. This material has been assessed under the Chemicals (Hazard Information and Packaging for Supply) Regulations 1994 and has been classified as follows:- R10 Flammable Xn R22 Harmful if swallowed 9804/8914 ISSUE 2 (REV.), MARCH 1997 4. FIRST-AID MEASURES In all cases of doubt, or where symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. Inhalation: Remove to fresh air, keep patient warm and at rest. If breathing has stopped, administer artificial respiration. Give nothing by mouth. If unconscious, place in the recovery position and seek medical advice. Eye Contact: Contact lenses should be removed. Irrigate copiously with clean, fresh water for at least 10 minutes, holding the eyelids apart and seek medical advice. Skin Contact: Remove contaminated clothing. Wash skin thoroughly with soap and water, or use a proprietary skin cleanser. Do NOT use solvents or thinners. Ingestion: If accidentally swallowed obtain immediate medical attention. Keep at rest. Do NOT induce vomiting. 5. FIRE-FIGHTING MEASURES Extinguishing Media: Use alcohol resistant foam, carbon dioxide, dry powder or water spray/mist. Do NOT use water jet. Recommendations: Fire will produce dense black smoke containing hazardous products or combustion (see Section 10). Exposure to decomposition products may be a hazard to health. Appropriate self-contained breathing apparatus may be required. Cool closed containers exposed to fire with water spray. Do not allow run-off from fire-fighting to enter drains or water courses. 6. ACCIDENTAL RELEASE MEASURES Exclude sources of ignition and ventilate the area. Exclude non-essential personnel. Avoid breathing vapours. Refer to protective measures listed in sections 7 and 8. Contain and collect spillages with non-combustible absorbent materials e.g. sand, earth, vermiculite, diatomaceous earth and place in a suitable container for disposal in accordance with the waste regulations (see Section 13). Do not allow to enter drains or water courses. Clean preferably with a detergent; avoid the use of solvents. If the product enters drains or sewers, the local water company should be contacted immediately; in the case of contamination of streams, rivers or lakes, the National Rivers Authority. 7. HANDLING AND STORAGE Handling Vapours are heavier than air and may spread along floors. They may form explosive mixtures with air. Prevent the creation of flammable or explosive concentrations of vapour in air and avoid concentrations higher than the occupational exposure limits. Additionally, the product should only be used in areas from which all naked lights and other sources of ignition have been excluded. Electrical equipment should be protected to the appropriate standard. Keep the container tightly closed. Exclude sources of heat, sparks and open flame. Non-sparking tools should be used. Required air quantity to 141 m3/ltr ventilate to 10% of the LEL The above figure is given as a guide only. Ventilation and extraction must be arranged so that all parts of the workplace are properly ventilated i.e. there are no recesses or pockets where high vapour concentrations are allowed to build up. If there is any doubt about the adequacy of the ventilation/extraction of solvent vapour, regular monitoring of confined workplaces should be carried out. cont’d 9804/8914 ISSUE 2 (REV.), MARCH 1997 Avoid skin and eye contact. Avoid inhalation of vapour and spray mist. Smoking, eating and drinking should be prohibited in areas of storage and use. For personal protection, see Section 8. Never use pressure to empty; the container is not a pressure vessel. Good housekeeping standards and regular safe removal of waste material will minimise the risks of spontaneous combustion and other fire hazards. The Manual Handling Operations Regulations may apply to the handling of containers/packages of this product. The following guide weight indicators are given to enable users to carry out assessments. This information is also shown on the container label. 20 litre unit 22.0 kg 5 litre unit 5.5 kg Phrases* Number White spirit 25-50% Xn R22 064742-82-1 For colours listed in Section 1 as containing lead chromate:- Weight Risk CAS Substance in paint Phrases* Number Lead Chromates >0.5% Repr. Cat. 1 R61 7758-97-6 Repr. Cat. 3 R62 R33 Carc. Cat. 3 R40 (*) For full details of R-phrases, see Section 16. This material has been assessed under the Chemicals (Hazard Information and Packaging for Supply) Regulations 1994 and has been classified as follows:- R10 Flammable Xn R22 Harmful if swallowed Colours containing lead chromate pigment (see Section 1) have been classified as follows:- R10 Flammable Xn R22 Harmful if swallowed R33 Danger of cumulative effects Carc. Cat. 3 R40 Possible risk of irreversible effects Repr. Cat. 1 R61 May cause harm to the unborn child Repr. Cat. 3 R62 Possible risk of impaired fertility 4. FIRST-AID MEASURES In all cases of doubt, or where symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. Inhalation: Remove to fresh air, keep patient warm and at rest. If breathing has stopped, administer artificial respiration. Give nothing by mouth. If unconscious, place in the recovery position and seek medical advice. Eye Contact: Contact lenses should be removed. Irrigate copiously with clean, fresh water for at least 10 minutes, holding the eyelids apart and seek medical advice. Skin Contact: Remove contaminated clothing. Wash skin thoroughly with soap and water, or use a proprietary skin cleanser. Do NOT use solvents or thinners. Ingestion: If accidentally swallowed obtain immediate medical attention. Keep at rest. Do NOT induce vomiting. 5. FIRE-FIGHTING MEASURES Extinguishing Media: Use alcohol resistant foam, carbon dioxide, dry powder or water spray/mist. Do NOT use water jet. Recommendations: Fire will produce dense black smoke containing hazardous products or combustion (see Section 10). Exposure to decomposition products may be a hazard to health. Appropriate self-contained breathing apparatus may be required. Cool closed containers exposed to fire with water spray. Do not allow run-off from fire-fighting to enter drains or water courses. 9804/8927 ISSUE 3 (REV.), MARCH 1997 6. ACCIDENTAL RELEASE MEASURES Exclude sources of ignition and ventilate the area. Exclude non-essential personnel. Avoid breathing vapours. Refer to protective measures listed in sections 7 and 8. Contain and collect spillages with non-combustible absorbent materials e.g. sand, earth, vermiculite, diatomaceous earth and place in a suitable container for disposal in accordance with the waste regulations (see Section 13). Do not allow to enter drains or water courses. Clean preferably with a detergent; avoid the use of solvents. If the product enters drains or sewers, the local water company should be contacted immediately; in the case of contamination of streams, rivers or lakes, the National Rivers Authority. 7. HANDLING AND STORAGE Handling For colours containing lead chromate (listed in Section 1), avoid the inhalation of dusts, particulates and spray mist rising from the use of these products. Vapours are heavier than air and may spread along floors. They may form explosive mixtures with air. Prevent the creation of flammable or explosive concentrations of vapour in air and avoid concentrations higher than the occupational exposure limits. Additionally, the product should only be used in areas from which all naked lights and other sources of ignition have been excluded. Electrical equipment should be protected to the appropriate standard. Keep the container tightly closed. Exclude sources of heat, sparks and open flame. Non-sparking tools should be used. Required air quantity to 136 m3/ltr ventilate to 10% of the LEL The above figure is given as a guide only. Ventilation and extraction must be arranged so that all parts of the workplace are properly ventilated i.e. there are no recesses or pockets where high vapour concentrations are allowed to build up. If there is any doubt about the adequacy of the ventilation/extraction of solvent vapour, regular monitoring of confined workplaces should be carried out. Avoid skin and eye contact. Avoid inhalation of vapour and spray mist. Smoking, eating and drinking should be prohibited in areas of storage and use. For personal protection, see Section 8. Never use pressure to empty; the container is not a pressure vessel. Good housekeeping standards and regular safe removal of waste material will minimise the risks of spontaneous combustion and other fire hazards. The Manual Handling Operations Regulations may apply to the handling of containers/packages of this product. The following guide weight indicators are given to enable users to carry out assessments. This information is also shown on the container label. 200 litre unit 220.0 - 280.0 kg 20 litre unit 22.0 - 28.0 kg 5 litre unit 5.5 - 7.0 kg 2.5 litre unit 2.8 - 3.5 kg 1 litre unit 1.1 - 1.4 kg Phrases* Number White spirit 25 - 50% Xn R22 064742-82-1 Lead Chromates >0.5% Repr. Cat. 1 R61 7758-97-6 Repr. Cat. 3 R62 R33 Carc. Cat. 3 R40 (*) For full details of R-phrases, see Section 16. This material has been assessed under the Chemicals (Hazard Information and Packaging for Supply) Regulations 1994 and has been classified as follows:- R10 Flammable Xn R22 Harmful if swallowed R33 Danger of cumulative effects Carc. Cat. 3 R40 Possible risk of irreversible effects Repr. Cat. 1 R61 May cause harm to the unborn child Repr. Cat. 3 R62 Possible risk of impaired fertility 9804/8957 ISSUE 4 (REV.), JUNE 2002 Phrases* Number White spirit 25-50% Xn R65 064742-82-1 (*) For full details of R-phrases, see Section 16. This material has been assessed under the Chemicals (Hazard Information and Packaging for Supply) Regulations 1994 and has been classified as follows:- R10 Flammable 9804/8916 ISSUE 5 (REV.), JUNE 2002 Phrases* Number White spirit 25 - 50% Xn R22 064742-82-1 (*) For full details of R-phrases, see Section 16. This material has been assessed under the Chemicals (Hazard Information and Packaging for Supply) Regulations 1994 and has been classified as follows:- R10 Flammable Xn R22 Harmful if swallowed 4. FIRST-AID MEASURES In all cases of doubt, or where symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. Inhalation: Remove to fresh air, keep patient warm and at rest. If breathing has stopped, administer artificial respiration. Give nothing by mouth. If unconscious, place in the recovery position and seek medical advice. cont’d 9804/8923 ISSUE 5 (REV.), JUNE 2002 Phrases* Number White spirit 25-50% Xn R22 064742-82-1 Lead Chromates >0.5% Repr. Cat. 1 R61 7758-97-6 Repr. Cat. 3 R62 R33 Carc. Cat. 3 R40 (*) For full details of R-phrases, see Section 16. This material has been assessed under the Chemicals (Hazard Information and Packaging for Supply) Regulations 1994 and has been classified as follows:- R10 Flammable Xn R22 Harmful if swallowed R33 Danger of cumulative effects Carc. Cat. 3 R40 Possible risk of irreversible effects Repr. Cat. 1 R61 May cause harm to the unborn child Repr. Cat. 3 R62 Possible risk of impaired fertility 9804/8915 ISSUE 4 (REV.), NOVEMBER 1997 4. FIRST-AID MEASURES In all cases of doubt, or where symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. Inhalation: Remove to fresh air, keep patient warm and at rest. If breathing has stopped, administer artificial respiration. Give nothing by mouth. If unconscious, place in the recovery position and seek medical advice. Eye Contact: Contact lenses should be removed. Irrigate copiously with clean, fresh water for at least 10 minutes, holding the eyelids apart and seek medical advice. Skin Contact: Remove contaminated clothing. Wash skin thoroughly with soap and water, or use a proprietary skin cleanser. Do NOT use solvents or thinners. Ingestion: If accidentally swallowed obtain immediate medical attention. Keep at rest. Do NOT induce vomiting. 5. FIRE-FIGHTING MEASURES Extinguishing Media: Use alcohol resistant foam, carbon dioxide, dry powder or water spray/mist. Do NOT use water jet. Recommendations: Fire will produce dense black smoke containing hazardous products of combustion (see Section 10). Exposure to decomposition products may be a hazard to health. Appropriate self-contained breathing apparatus may be required. Cool closed containers exposed to fire with water spray. Do not allow run-off from fire-fighting to enter drains or water courses. 6. ACCIDENTAL RELEASE MEASURES Exclude sources of ignition and ventilate the area. Exclude non-essential personnel. Avoid breathing vapours. Refer to protective measures listed in sections 7 and 8. Contain and collect spillages with non-combustible absorbent materials e.g. sand, earth, vermiculite, diatomaceous earth and place in a suitable container for disposal in accordance with the waste regulations (see Section 13). Do not allow to enter drains or water courses. Clean preferably with a detergent; avoid the use of solvents. If the product enters drains or sewers, the local water company should be contacted immediately; in the case of contamination of streams, rivers or lakes, the National Rivers Authority. 7. HANDLING AND STORAGE Handling Avoid the inhalation of dust, particulates and spray mist arising from the use of this lead chromate containing product. For colours containing lead chromate (listed in Section 1), avoid the inhalation of dusts, particulates and spray mist arising from the use of these products. Vapours are heavier than air and may spread along floors. They may form explosive mixtures with air. Prevent the creation of flammable or explosive concentrations of vapour in air and avoid concentrations higher than the occupational exposure limits. Additionally, the product should only be used in areas from which all naked lights and other sources of ignition have been excluded. Electrical equipment should be protected to the appropriate standard. Keep the container tightly closed. Exclude sources of heat, sparks and open flame. Non-sparking tools should be used. Required air quantity to ventilate to 10% of the LEL 126 m3/ltr The above figure is given as a guide only. Ventilation and extraction must be arranged so that all parts of the workplace are properly ventilated i.e. there are no recesses or pockets where high vapour concentrations are allowed to build up. cont’d 9804/8915 ISSUE 4 (REV.), NOVEMBER 1997 If there is any doubt about the adequacy of the ventilation/extraction of solvent vapour, regular monitoring of confined workplaces should be carried out. Avoid skin and eye contact. Avoid inhalation of vapour and spray mist. Smoking, eating and drinking should be prohibited in areas of storage and use. For personal protection, see Section 8. Never use pressure to empty; the container is not a pressure vessel. Good housekeeping standards and regular safe removal of waste material will minimise the risks of spontaneous combustion and other fire hazards. The Manual Handling Operations Regulations may apply to the handling of containers/packages of this product. The following guide weight indicators are given to enable users to carry out assessments. This information is also shown on the container label. 5 litre unit 7.5 kg Phrases* Number White spirit 25-50% Xn R22 064742-82-1 Lead Chromates >0.5% Repr. Cat. 1 R61 7758-97-6 Repr. Cat. 3 R62 R33 Carc. Cat. 3 R40 (*) For full details of R-phrases, see Section 16. This material has been assessed under the Chemicals (Hazard Information and Packaging for Supply) Regulations 1994 and has been classified as follows:- R10 Flammable Xn R22 Harmful if swallowed R33 Danger of cumulative effects Carc. Cat. 3 R40 Possible risk of irreversible effects Repr. Cat. 1 R61 May cause harm to the unborn child Repr. Cat. 3 R62 Possible risk of impaired fertility 9804/8922 ISSUE 5 (REV.), JUNE 2002 Phrases* Number Mesitylene 2.5 - 10% Xi R37 108-67-8 Propylbenzene 2.5 - 10% Xi R37 103-65-1 Xylene (mixture of isomers) 2.5 - 10% Xn R20/21 1330-20-7 Xi R38 (*) For full details of R-phrases, see Section 16. The following ingredients have not been assigned hazard symbols or risk phrases, but have recognised exposure limits (see Section 8 for details of the limits). Weight CAS Substance in paint Number 1-methoxypropan-2-ol 25 - 50% 107-98-2 This material has been assessed under the Chemicals (Hazard Information and Packaging for Supply) Regulations 1994 and has been classified as follows:- R10 Flammable 9804/8964 ISSUE 3 (REV.), JUNE 2002 Phrases* Number Mesitylene 10 - 25% Xi R37 108-67-8 Xylene (mixture of isomers) 2.5 - 10% Xn R20/21 1330-20-7 Xi R38 Propylbenzene 2.5 - 10% Xi R37 103-65-1 * Aliphatic polyepoxide <2.5% Xn R40 68412-01-1 Xi R36/38 (*) For full details of R-phrases, see Section 16. The following ingredients have not been assigned hazard symbols or risk phrases, but have recognised exposure limits (see Section 8 for details of the limits). Weight CAS Substance in paint Number 1-methoxypropan-2-ol 10 - 25% 107-98-2 cont’d 9804/8965 ISSUE 3 (REV.), NOVEMBER 1997 This material has been assessed under the Chemicals (Hazard Information and Packaging for Supply) Regulations 1994 and the components have been classified as follows:- Base: R10 Flammable Additive: R10 Flammable. * Xi R37 Irritating to respiratory system Xn R40 Possible risk of irreversible effects 4. FIRST-AID MEASURES In all cases of doubt, or where symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. Inhalation: Remove to fresh air, keep patient warm and at rest. If breathing has stopped, administer artificial respiration. Give nothing by mouth. If unconscious, place in the recovery position and seek medical advice. Eye Contact: Contact lenses should be removed. Irrigate copiously with clean, fresh water for at least 10 minutes, holding the eyelids apart and seek medical advice. Skin Contact: Remove contaminated clothing. Wash skin thoroughly with soap and water, or use a proprietary skin cleanser. Do NOT use solvents or thinners. Ingestion: If accidentally swallowed obtain immediate medical attention. Keep at rest. Do NOT induce vomiting. 5. FIRE-FIGHTING MEASURES Extinguishing Media: Use alcohol resistant foam, carbon dioxide, dry powder or water spray/mist. Do NOT use water jet. Recommendations: Fire will produce dense black smoke containing hazardous products of combustion (see Section 10). Exposure to decomposition products may be a hazard to health. Appropriate self-contained breathing apparatus may be required. Cool closed containers exposed to fire with water spray. Do not allow run-off from fire-fighting to enter drains or water courses. 6. ACCIDENTAL RELEASE MEASURES Exclude sources of ignition and ventilate the area. Exclude non-essential personnel. Avoid breathing vapours. Refer to protective measures listed in sections 7 and 8. Contain and collect spillages with non-combustible absorbent materials e.g. sand, earth, vermiculite, diatomaceous earth and place in a suitable container for disposal in accordance with the waste regulations (see Section 13). Do not allow to enter drains or water courses. Clean preferably with a detergent; avoid the use of solvents. If the product enters drains or sewers, the local water company should be contacted immediately; in the case of contamination of streams, rivers or lakes, the National Rivers Authority. 7. HANDLING AND STORAGE Handling Vapours are heavier than air and may spread along floors. They may form explosive mixtures with air. Prevent the creation of flammable or explosive concentrations of vapour in air and avoid concentrations higher than the occupational exposure limits. Additionally, the product should only be used in areas from which all naked lights and other sources of ignition have been excluded. Electrical equipment should be protected to the appropriate standard. cont’d 9804/8965 ISSUE 3 (REV.), NOVEMBER 1997 7. HANDLING AND STORAGE continued Keep the container tightly closed. Exclude sources of heat, sparks and open flame. Non-sparking tools should be used. * Required air quantity to ventilate to 10% of the LEL 152m3/ltr The above figure is given as a guide only. Ventilation and extraction must be arranged so that all parts of the workplace are properly ventilated i.e. there are no recesses or pockets where high vapour concentrations are allowed to build up. If there is any doubt about the adequacy of the ventilation/extraction of solvent vapour, regular monitoring of confined workplaces should be carried out. Avoid skin and eye contact. Avoid inhalation of vapour and spray mist. Smoking, eating and drinking should be prohibited in areas of storage and use. For personal protection, see Section 8. Never use pressure to empty; the container is not a pressure vessel. Good housekeeping standards and regular safe removal of waste material will minimise the risks of spontaneous combustion and other fire hazards. The Manual Handling Operations Regulations may apply to the handling of containers/packages of this product. The following guide weight indicators are given to enable users to carry out assessments. This information is also shown on the container label. Base Additive Composite * 5 litre unit 6.0 kg 1.1 kg 7.1 kg Phrases* Number Aliphatic polyepoxide <2.5% Xn R40 68412-01-1 Xi R36/38 Mesitylene <2.5% Xi R37 108-67-8 (*) For full details of R-phrases, see Section 16. The following ingredients have not been assigned hazard symbols or risk phrases, but have recognised exposure limits (see Section 8 for details of the limits). Weight CAS Substance in paint Number 1-methoxypropan-2-ol 25 - 50% 107-98-2 This material has been assessed under the Chemicals (Hazard Information and Packaging for Supply) Regulations 1994 and has been classified as follows:- Base: R10 Flammable Additive: R10 Flammable. Xn R40 Possible risk of irreversible effects 9804/8966 ISSUE 3 (REV.), JUNE 2002 Phrases* Number White spirit 10-25% Xn R22 064742-82-1 Lead Chromates >0.5% Repr. Cat. 1 R61 7758-97-6 Repr. Cat. 3 R62 R33 Carc. Cat. 3 R40 (*) For full details of R-phrases, see Section 16. The following ingredients have not been assigned hazard symbols or risk phrases, but have recognised exposure limits (see Section 8 for details of the limits). Weight CAS Substance in paint Number Acetone 25-50% 67-64-1 Butane 10-25% 106-97-8 This material has been assessed under the Chemicals (Hazard Information and Packaging for Supply) Regulations 1994 and has been classified as follows:- cont’d 9804/9010 ISSUE 1, MAY 1997 F R11 Highly Flammable R33 Danger of cumulative effects Carc. Cat. 3 R40 Possible risk of irreversible effects Repr. Cat. 1 R61 May cause harm to the unborn child Repr. Cat. 3 R62 Possible risk of impaired fertility 4. FIRST-AID MEASURES In all cases of doubt, or where symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. Inhalation: Remove to fresh air, keep patient warm and at rest. If breathing has stopped, administer artificial respiration. Give nothing by mouth. If unconscious, place in the recovery position and seek medical advice. Eye Contact: Contact lenses should be removed. Irrigate copiously with clean, fresh water for at least 10 minutes, holding the eyelids apart and seek medical advice. Skin Contact: Remove contaminated clothing. Wash skin thoroughly with soap and water, or use a proprietary skin cleanser. Do NOT use solvents or thinners. Ingestion: If accidentally swallowed obtain immediate medical attention. Keep at rest. Do NOT induce vomiting. 5. FIRE-FIGHTING MEASURES Extinguishing Media: Use alcohol resistant foam, carbon dioxide, dry powder or water spray/mist. Do NOT use water jet. Recommendations: Fire will produce dense black smoke containing hazardous products of combustion (see Section 10). Exposure to decomposition products may be a hazard to health. Appropriate self-contained breathing apparatus may be required. Cool closed containers exposed to fire with water spray. Do not allow run-off from fire-fighting to enter drains or water courses. 6. ACCIDENTAL RELEASE MEASURES Exclude sources of ignition and ventilate the area. Exclude non-essential personnel. Avoid breathing vapours. Refer to protective measures listed in sections 7 and 8. Contain and collect spillages with non-combustible absorbent materials e.g. sand, earth, vermiculite, diatomaceous earth and place in a suitable container for disposal in accordance with the waste regulations (see Section 13). Do not allow to enter drains or water courses. Clean preferably with a detergent; avoid the use of solvents. If the product enters drains or sewers, the local water company should be contacted immediately; in the case of contamination of streams, rivers or lakes, the National Rivers Authority. 7. HANDLING AND STORAGE Handling Avoid the inhalation of dust, particulates and spray mist arising from the use of this lead chromate containing product. For colours containing lead chromate (listed in Section 1), avoid the inhalation of dusts, particulates and spray mist arising from the use of these products. Vapours are heavier than air and may spread along floors. They may form explosive mixtures with air. Prevent the creation of flammable or explosive concentrations of vapour in air and avoid concentrations higher than the occupational exposure limits. Additionally, the product should only be used in areas from which all naked lights and other sources of ignition have been excluded. Electrical equipment should be protected to the appropriate standard. cont’d 9804/9010 ISSUE 1, MAY 1997 Keep the container tightly closed. Exclude sources of heat, sparks and open flame. Non-sparking tools should be used. Required air quantity to ventilate to 10% of the LEL 382 m3/ltr The above figure is given as a guide only. Ventilation and extraction must be arranged so that all parts of the workplace are properly ventilated i.e. there are no recesses or pockets where high vapour concentrations are allowed to build up. If there is any doubt about the adequacy of the ventilation/extraction of solvent vapour, regular monitoring of confined workplaces should be carried out. Avoid skin and eye contact. Avoid inhalation of vapour and spray mist. Smoking, eating and drinking should be prohibited in areas of storage and use. For personal protection, see Section 8. Never use pressure to empty; the container is not a pressure vessel. Good housekeeping standards and regular safe removal of waste material will minimise the risks of spontaneous combustion and other fire hazards. The Manual Handling Operations Regulations may apply to the handling of containers/packages of this product. The following guide weight indicators are given to enable users to carry out assessments. This information is also shown on the container label. 0.4 litre unit 0.4 kg Phrases* Number White spirit 10-25% Xn R22 064742-82-1 Lead Chromates >0.5% Repr. Cat. 1 R61 7758-97-6 Repr. Cat. 3 R62 R33 Carc. Cat. 3 R40 (*) For full details of R-phrases, see Section 16. The following ingredients have not been assigned hazard symbols or risk phrases, but have recognised exposure limits (see Section 8 for details of the limits). Weight CAS Substance in paint Number Acetone 25-50% 67-64-1 Butane 10-25% 106-97-8 This material has been assessed under the Chemicals (Hazard Information and Packaging for Supply) Regulations 1993 and has been classified as follows:- cont’d 9804/9009 ISSUE 1, MARCH 1997 F R11 Highly Flammable R33 Danger of cumulative effects Carc. Cat. 3 R40 Possible risk of irreversible effects Repr. Cat. 1 R61 May cause harm to the unborn child Repr. Cat. 3 R62 Possible risk of impaired fertility 4. FIRST-AID MEASURES In all cases of doubt, or where symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. Inhalation: Remove to fresh air, keep patient warm and at rest. If breathing has stopped, administer artificial respiration. Give nothing by mouth. If unconscious, place in the recovery position and seek medical advice. Eye Contact: Contact lenses should be removed. Irrigate copiously with clean, fresh water for at least 10 minutes, holding the eyelids apart and seek medical advice. Skin Contact: Remove contaminated clothing. Wash skin thoroughly with soap and water, or use a proprietary skin cleanser. Do NOT use solvents or thinners. Ingestion: If accidentally swallowed obtain immediate medical attention. Keep at rest. Do NOT induce vomiting. 5. FIRE-FIGHTING MEASURES Extinguishing Media: Use alcohol resistant foam, carbon dioxide, dry powder or water spray/mist. Do NOT use water jet. Recommendations: Fire will produce dense black smoke containing hazardous products of combustion (see Section 10). Exposure to decomposition products may be a hazard to health. Appropriate self-contained breathing apparatus may be required. Cool closed containers exposed to fire with water spray. Do not allow run-off from fire-fighting to enter drains or water courses. 6. ACCIDENTAL RELEASE MEASURES Exclude sources of ignition and ventilate the area. Exclude non-essential personnel. Avoid breathing vapours. Refer to protective measures listed in sections 7 and 8. Contain and collect spillages with non-combustible absorbent materials e.g. sand, earth, vermiculite, diatomaceous earth and place in a suitable container for disposal in accordance with the waste regulations (see Section 13). Do not allow to enter drains or water courses. Clean preferably with a detergent; avoid the use of solvents. If the product enters drains or sewers, the local water company should be contacted immediately; in the case of contamination of streams, rivers or lakes, the National Rivers Authority. 7. HANDLING AND STORAGE Handling Avoid the inhalation of dust, particulates and spray mist arising from the use of this lead chromate containing product. For colours containing lead chromate (listed in Section 1), avoid the inhalation of dusts, particulates and spray mist arising from the use of these products. Vapours are heavier than air and may spread along floors. They may form explosive mixtures with air. Prevent the creation of flammable or explosive concentrations of vapour in air and avoid concentrations higher than the occupational exposure limits. Additionally, the product should only be used in areas from which all naked lights and other sources of ignition have been excluded. Electrical equipment should be protected to the appropriate standard. cont’d 9804/9009 ISSUE 1, MARCH 1997 Keep the container tightly closed. Exclude sources of heat, sparks and open flame. Non-sparking tools should be used. Required air quantity to ventilate to 10% of the LEL 382 m3/ltr The above figure is given as a guide only. Ventilation and extraction must be arranged so that all parts of the workplace are properly ventilated i.e. there are no recesses or pockets where high vapour concentrations are allowed to build up. If there is any doubt about the adequacy of the ventilation/extraction of solvent vapour, regular monitoring of confined workplaces should be carried out. Avoid skin and eye contact. Avoid inhalation of vapour and spray mist. Smoking, eating and drinking should be prohibited in areas of storage and use. For personal protection, see Section 8. Never use pressure to empty; the container is not a pressure vessel. Good housekeeping standards and regular safe removal of waste material will minimise the risks of spontaneous combustion and other fire hazards. The Manual Handling Operations Regulations may apply to the handling of containers/packages of this product. The following guide weight indicators are given to enable users to carry out assessments. This information is also shown on the container label. 0.4 litre unit 0.4 kg Phrases* Number Xylene (mixtures of isomers) 10-25% Xn R20/21 1330-20-7 Xi R38 Mesitylene 2.5-10% Xi R37 108-67-8 Propylbenzene 2.5-10% Xi R37 103-65-1 Aliphatic polyepoxide 2.5-10% Xn R40 68412-01-1 Xi R36/38 (*) For full details of R-phrases, see Section 16. The following ingredients have not been assigned hazard symbols or risk phrases, but have recognised exposure limits (see Section 8 for details of the limits). Weight CAS Substance in paint Number 1-methoxypropan-2-ol 10 - 25% 107-98-2 9804/9012 ISSUE 2, NOVEMBER 1997 This material has been assessed under the Chemicals (Hazard Information and Packaging for Supply) Regulations 1994 and the components have been classified as follows:- Base: R10 Flammable Xn R20/21 Harmful by inhalation and in contact with skin Base (with R10 Flammable lead chromate): Xn R20/21 Harmful by inhalation and in contact with skin. R33 Danger of cumulative effects. Carc. Cat. 3 R40 Possible risk of irreversible effects Repr. Cat. 1 R61 May cause harm to the unborn child Repr. Cat. 3 R62 Possible risk of impaired fertility Additive: R10 Flammable. Xi R37 Irritating to respiratory system Xn R40 Possible risk of irreversible effects 4. FIRST-AID MEASURES In all cases of doubt, or where symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. Inhalation: Remove to fresh air, keep patient warm and at rest. If breathing has stopped, administer artificial respiration. Give nothing by mouth. If unconscious, place in the recovery position and seek medical advice. Eye Contact: Contact lenses should be removed. Irrigate copiously with clean, fresh water for at least 10 minutes, holding the eyelids apart and seek medical advice. Skin Contact: Remove contaminated clothing. Wash skin thoroughly with soap and water, or use a proprietary skin cleanser. Do NOT use solvents or thinners. Ingestion: If accidentally swallowed obtain immediate medical attention. Keep at rest. Do NOT induce vomiting. 5. FIRE-FIGHTING MEASURES Extinguishing Media: Use alcohol resistant foam, carbon dioxide, dry powder or water spray/mist. Do NOT use water jet. Recommendations: Fire will produce dense black smoke containing hazardous products of combustion (see Section 10). Exposure to decomposition products may be a hazard to health. Appropriate self-contained breathing apparatus may be required. Cool closed containers exposed to fire with water spray. Do not allow run-off from fire-fighting to enter drains or water courses. 6. ACCIDENTAL RELEASE MEASURES Exclude sources of ignition and ventilate the area. Exclude non-essential personnel. Avoid breathing vapours. Refer to protective measures listed in sections 7 and 8. Contain and collect spillages with non-combustible absorbent materials e.g. sand, earth, vermiculite, diatomaceous earth and place in a suitable container for disposal in accordance with the waste regulations (see Section 13). Do not allow to enter drains or water courses. Clean preferably with a detergent; avoid the use of solvents. If the product enters drains or sewers, the local water company should be contacted immediately; in the case of contamination of streams, rivers or lakes, the National Rivers Authority. 9804/9012 ISSUE 2, NOVEMBER 1997 7. HANDLING AND STORAGE Handling For colours containing lead chromate (listed in Section 1), avoid the inhalation of dusts, particulates and spray mist arising from the use of these products. Vapours are heavier than air and may spread along floors. They may form explosive mixtures with air. Prevent the creation of flammable or explosive concentrations of vapour in air and avoid concentrations higher than the occupational exposure limits. Additionally, the product should only be used in areas from which all naked lights and other sources of ignition have been excluded. Electrical equipment should be protected to the appropriate standard. Keep the container tightly closed. Exclude sources of heat, sparks and open flame. Non-sparking tools should be used. Required air quantity to ventilate to 10% of the LEL 163 m3/ltr The above figure is given as a guide only. Ventilation and extraction must be arranged so that all parts of the workplace are properly ventilated i.e. there are no recesses or pockets where high vapour concentrations are allowed to build up. If there is any doubt about the adequacy of the ventilation/extraction of solvent vapour, regular monitoring of confined workplaces should be carried out. Avoid skin and eye contact. Avoid inhalation of vapour and spray mist. Smoking, eating and drinking should be prohibited in areas of storage and use. For personal protection, see Section 8. Never use pressure to empty; the container is not a pressure vessel. Good housekeeping standards and regular safe removal of waste material will minimise the risks of spontaneous combustion and other fire hazards. The Manual Handling Operations Regulations may apply to the handling of containers/packages of this product. The following guide weight indicators are given to enable users to carry out assessments. This information is also shown on the container label. Base Additive Composite 5 litre unit 5.2 kg 1.1 kg 6.3 kg 1 litre unit 1.0 kg 0.2 kg 1.3 kg 0.5 litre unit 0.5 kg 0.1 kg 0.6 kg Phrases* Number White Spirit 25-50% Xn R65 064742-82-1 (*) For full details of R-phrases, see Section 16. R10 Flammable 4. FIRST-AID MEASURES In all cases of doubt, or where symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. cont’d 9804/9022 ISSUE 1, JANUARY 2002 Packaging containing product-rests: In compliance with local/national regulations 9804/9028 ISSUE 1, JANUARY 2002 Xn - Harmful Flammable Xn - Harmful F - Highly Flammable T - Toxic Flammable Xn - Harmful Flammable None according to the amended 88/379/EEC directive. Emergency overview: If the skin exposed to high-pressure spray, the product may enter the human organism. In all such cases the affected person must be taken to hospital, even if no sign of injury can be detected. 4. FIRST-AID MEASURES IN CASE OF SERIOUS MANIFESTATIONS - CALL IN A DOCTOR OR EMERGENCY MEDICAL CARE Inhalation: In case of exposure to heavy concentration of vapour, fumes or spray, transport the person into fresh air, keep warm and allow to rest. Contact with the skin: If the product comes into contact with the skin, wash the affected area immediately and repeatedly with soap and water. If the skin is exposed to high-pressure spray, the product may enter the human organism. In all such cases the affected person must be taken to hospital, even if no sign of injury can be detected. Contact with the eyes: Keep eyes open and rinse immediately and repeatedly with water for at least 15 minutes, and consult a specialist. Ingestion: Generally no special treatment is necessary. DO NOT INDUCE VOMITING Instructions for the doctor: In case of incidents, treat symptoms as required. 5. FIRE-FIGHTING MEASURES Flash point: Not applicable Fire Extinguishers: - suitable: Foam, C02 powder - not suitable: Water under strong pencil like jet forbidden. Specific Hazards: Incomplete combustion and thermolysis produce more of less toxic gases such as CO, CO2, various hydrocarbons, aldehydes, and soot. Firefighter protection: An insulated breathing apparatus must be worn in confined premises with heavy concentrations of fumes and gases. 6. ACCIDENTAL RELEASE MEASURES Precautions for personal Hydrocarbon-proof clothing, gloves, goggles and boots should be worn, as protection: applicable. Surfaces on which the product has been spilled become slippery. Precautions for environmental Plan the installations and take all necessary measures to prevent water and protection: ground pollution. Set up sewer protection to reduce the risk of pollution through accidental release. Cont’d 9804/9021 ISSUE1, MARCH 2002 Clean-up method: - Recovery: Use mechanical means such as pumps and skimmers. Contain and collect the spilled product with sand or any other inert material. Do not discard into drains or sewers. Xn - Harmful Flammable Xn - Harmful Flammable Phrases* Number White Spirit 25-50% Xn R65 064742-82-1 (*) For full details of R-phrases, see Section 16. R10 Flammable 4. FIRST-AID MEASURES In all cases of doubt, or where symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. cont’d 9804/9022 ISSUE 2 (REV), JUNE 2002

UN Number

1950 Un Proper Shipping Name Aerosols, flammable, n.o.s. UN Class 2.2 UN Packaging Group II ADR/RID Substance Identification 1950 Number ADR/RID - Description Aerosols. ADR/RID - Class 2 ADR/RID - Item No. 10b1 IMDG - Proper Shipping Name Aerosol Dispensers. IMDG - Packaging Group II IMDG - Class 2 IMDG - Marine Pollutant No. IMDG - Ems Number 2-13 IMDG - MFAG Table Number 311 IATA - Proper Shipping Name Aerosols, flammable, n.o.s. IATA - Packaging Group II IATA - Class 2.1 Tremcard No. TEC(R) 20G26-2 9804/8894 ISSUE 3 (REV.), NOVEMBER 1997 15. REGULATORY INFORMATION 1993 UN Proper Shipping Name: Flammable Liquid, n.o.s. UN Class 3.2 UN Packaging Group: 2 ADR/RID - Class: 3.2 ADR/RID - Hazard Identification Number: 33 IMDG - Proper Shipping Name: Flammable Liquid, N.O.S. (contains Iso propyl alcohol) IMDG - Packaging Group: 3.2 IMDG - Class: 3 IMDG - Ems Number: 3-07 IMDG - MFAG Table Number: 3230 IATA - Proper Shipping Name: Flammable Liquid, N.O.S. IATA - Packaging Group: 2 IATA - Class 3 15. REGULATORY INFORMATION 1263 Main Risk: FLAMMABILITY Sub Risk: NARCOSIS Shipping Name: PAINT PRODUCT Air Packing Grp.: < = 30lts III Packing Grp.: > 30lts III 1263 Main Risk: FLAMMABILITY Sub Risk: NARCOSIS Shipping Name: PAINT PRODUCT International Packing Grp.: III Class: 3 Road/Rail Item Number: 31C 1263 Main Risk: FLAMMABILITY Sub Risk: NARCOSIS Shipping Name: PAINT PRODUCT 15. REGULATORY INFORMATION The product is classified and labelled for supply in accordance with the Chemicals (Hazard Information & Packaging) Regulations as follows. 1263 Main Risk: FLAMMABILITY Sub Risk: NARCOSIS Shipping Name: PAINT PRODUCT Air Packing Grp.: < = 30lts III Packing Grp.: > 30lts III 1263 Main Risk: FLAMMABILITY Sub Risk: NARCOSIS Shipping Name: PAINT PRODUCT International Packing Grp.: III Class: 3 Road/Rail Item Number: 31C 1263 Main Risk: FLAMMABILITY Sub Risk: NARCOSIS Shipping Name: PAINT PRODUCT 15. REGULATORY INFORMATION The product is classified and labelled for supply in accordance with the Chemicals (Hazard Information & Packaging) Regulations as follows. 1263 Main Risk: FLAMMABILITY Sub Risk: NARCOSIS Shipping Name: Flammable Liquid Air Packing Grp.: < = 30lts III Packing Grp.: > 30lts III Class: 3.3 1263 Main Risk: FLAMMABILITY Sub Risk: NARCOSIS Shipping Name: Flammable Liquid International Packing Grp.: III Class: 3.3 Road/Rail 1263 Main Risk: FLAMMABILITY Sub Risk: NARCOSIS Shipping Name: Flammable Liquid 15. REGULATORY INFORMATION The product is classified and labelled for supply in accordance with the Chemicals (Hazard Information & Packaging) Regulations as follows. 1263 Shipping Name PAINT Class 3 Sub. Hazard Packing Group III Item Number 31 º(C) Trem Card 30G35 Category 3 Marine EmS 3-05 MFAG 310 Marine Pollutant Yes This information does not apply to carriage by air. Please contact JCB Supply Department if transport by air is required. * 15. REGULATORY INFORMATION This product has been classified and labelled for supply in accordance with the CHIP 2 regulations as follows:- For all colours except those listed in Section 1 as containing lead chromate:- Flammable Keep away from sources of ignition - No smoking. Keep out of reach of children. Ensure maximum ventilation during application and drying. When spraying, do not breathe spray, wear suitable respiratory equipment. On large interior surfaces or in confined spaces, wear air-fed respiratory equipment. Avoid contact with skin and eyes. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. After contact with skin, wash immediately with plenty of soap and water or proprietary skin cleanser. For colours listed in Section 1 as containing lead chromate: Lead Chromates TOXIC Contains lead. Should not be used on surfaces that are liable to be chewed or sucked by children. Restricted to professional users. Flammable. Danger of cumulative effects. Possible risk of irreversible effects. May cause harm to the unborn child. Possible risk of impaired fertility. When using do not eat, drink or smoke. Do not breathe vapour/spray. During spraying wear air-fed respiratory protective equipment. Cont..... 9804/8926 ISSUE 5 (REV.), MARCH 2002 : 1263 Packaging Group : III Flash point : 38°C For International Road/Rail Transport Chemical Name : N/A Item Number : N/A For Sea Transport Marine Pollutant : Yes Em S : 3 - 05 MFAG : 310 C.D.G. (CPL) : Exempt from Classification as flammable under C.D.G. (CPL) Regulations by virtue of Part III of Schedule I (high viscosity). 15. REGULATORY INFORMATION This product is classified and labelled for supplying in accordance with the Chemicals (Hazard Information and Packaging) Regulations as follows:- T Toxic R61 May cause harm to the unborn child. R40 Possible risk of irreversible effects. R33 Danger of cumulative effects. P90 Contains lead. Should not be used on surfaces that are liable to be chewed or sucked by children. R10 Flammable. S20\21 When using do not eat, drink or smoke. S45 In case of accident or if you feel inwell, seek medical advice immediately (show the label where possible). S23 Do not breathe gas/fumes/vapour/spray. S28 After contact with skin, wash immediately with plenty of soap and water. The information contained in this data sheet does not constitute the user’s own assessment of workplace risks as required by other Health and Safety Legislation. The provisions of the Health and Safety at Work etc. and the Control of Substances Hazardous to Health regulation, apply to the use of this product at work. 9804/8919 ISSUE 3 (REV.), APRIL 1997 : 1263 Packaging Group : III Flash point : 38°C For International Road/Rail Transport Chemical Name : N/A Item Number : N/A For Sea Transport Marine Pollutant : Yes Em S : 3 - 05 MFAG : 310 C.D.G. (CPL) : Exempt from Classification as flammable under C.D.G. (CPL) Regulations by virtue of Part III of Schedule I (high viscosity). 15. REGULATORY INFORMATION This product is classified and labelled for supplying in accordance with the Chemicals (Hazard Information and Packaging) Regulations as follows:- T Toxic R61 May cause harm to the unborn child. R40 Possible risk of irreversible effects. R33 Danger of cumulative effects. P90 Contains lead. Should not be used on surfaces that are liable to be chewed or sucked by children. R10 Flammable. S20\21 When using do not eat, drink or smoke. S45 In case of accident or if you feel inwell, seek medical advice immediately (show the label where possible). S23 Do not breathe gas/fumes/vapour/spray. S28 After contact with skin, wash immediately with plenty of soap and water. The information contained in this data sheet does not constitute the user’s own assessment of workplace risks as required by other Health and Safety Legislation. The provisions of the Health and Safety at Work etc. and the Control of Substances Hazardous to Health regulation, apply to the use of this product at work. 9804/8918 ISSUE 4 (REV.), NOVEMBER 1997 : 1263 Packaging Group : III Flash point : 38°C For International Road/Rail Transport Chemical Name : N/A Item Number : N/A For Sea Transport Marine Pollutant : Yes Em S : 3 - 05 MFAG : 310 C.D.G. (CPL) : Exempt from Classification as flammable under C.D.G. (CPL) Regulations by virtue of Part III of Schedule I (high viscosity). 15. REGULATORY INFORMATION This product is classified and labelled for supplying in accordance with the Chemicals (Hazard Information and Packaging) Regulations as follows:- T Toxic R61 May cause harm to the unborn child. R40 Possible risk of irreversible effects. R33 Danger of cumulative effects. P90 Contains lead. Should not be used on surfaces that are liable to be chewed or sucked by children. R10 Flammable. S20\21 When using do not eat, drink or smoke. S45 In case of accident or if you feel inwell, seek medical advice immediately (show the label where possible). S23 Do not breathe gas/fumes/vapour/spray. S28 After contact with skin, wash immediately with plenty of soap and water. The information contained in this data sheet does not constitute the user’s own assessment of workplace risks as required by other Health and Safety Legislation. The provisions of the Health and Safety at Work etc. and the Control of Substances Hazardous to Health regulation, apply to the use of this product at work. 9804/8917 ISSUE 4 (REV.), NOVEMBER 1997 1300 Shipping Name TURPENTINE SUBSTITUTE Class 3 Sub. Hazard Packing Group III Item Number 31°C Trem card 30G35 Category 3 Marine EmS 3-05 MFAG 310 Marine Pollutant Yes This information does not apply to carriage by air. Please contact JCB Supply Department if transport by air is required. * 15. REGULATORY INFORMATION This product has been classified and labelled for supply in accordance with the CHIP 2 regulations as follows:- White spirit HARMFUL Flammable Harmful: may cause lung damage if swallowed In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible) Avoid exposure - obtain special instruction before use. The information contained in this data sheet does not constitute the user’s own assessment of workplace risks as required by other health and safety legislation. The provisions of the Health and Safety at Work etc. Act and the Control of Substances Hazardous to Health Regulations apply to the use of this product at work. 9804/8958 ISSUE 3 (REV.), FEB 2002 : 1263 Packing Group : III Flash point : 38°C For International Road/Rail Transport Chemical Name : N/A Item Number : N/A For Sea Transport Marine Pollutant : Yes Em S : 3-05 cont’d 9804/8920 ISSUE 5 (REV.), JUNE 2002 : 1263 Packing Group : III Ensure drivers have adequate training. For International Road/Rail Chemical Name : Paint Item Number : 31 °C Trem Card : 30G35 For Sea Transport Marine Pollutant : Yes EmS : 3 - 05 MFAG : 310 This information does not apply to carriage by air. Please contact JCB Supply Department if transport by air is required. 9804/8914 ISSUE 2 (REV.), MARCH 1997 15. REGULATORY INFORMATION This product has been classified and labelled for supply in accordance with the CHIP 2 regulations as follows:- : 1263 Packing Group : III Ensure drivers have adequate training. For International Road/Rail Chemical Name : Paint Item Number : 31 °C Trem Card : 30G35 For Sea Transport Marine Pollutant : Yes EmS : 3 - 05 MFAG : 310 This information does not apply to carriage by air. Please contact JCB Supply Department if transport by air is required. 9804/8927 ISSUE 3 (REV.), MARCH 1997 15. REGULATORY INFORMATION This product has been classified and labelled for supply in accordance with the CHIP 2 regulations as follows:- For all colours except those listed in Section 1 as containing lead chromate:- : 1263 Packing Group : III Ensure drivers have adequate training. cont’d 9804/8957 ISSUE 4 (REV.), JUNE 2002 1263 Shipping Name PAINT Class 3 Sub. Hazard Packing Group III Item Number 31 °C Trem Card 30G53 Category 3 Marine EmS 3-05 MFAG 310 Marine Pollutant Yes This information does not apply to carriage by air. Please contact JCB Supply Department if transport by air is required. 15. REGULATORY INFORMATION This product has been classified and labelled for supply in accordance with the CHIP 2 regulations as follows:- Flammable. Keep away from sources of ignition - No smoking. Keep out of reach of children. Ensure maximum ventilation during application and drying. When spraying, do not breathe spray, wear suitable respiratory equipment. On large interior surfaces or in confined spaces, wear air-fed respiratory equipment. Do not breathe vapour/spray. Avoid contact with skin and eyes. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. After contact with skin, wash immediately with plenty of soap and water or proprietary skin cleanser. In case of insufficient ventilation, wear suitable respiratory equipment. The information contained in this data sheet does not constitute the user’s own assessment of workplace risks as required by other health and safety legislation. The provisions of the Health and Safety at Work etc. Act and the Control of Substances Hazardous to Health Regulations apply to the use of this product at work. 9804/8916 ISSUE 5 (REV.), JUNE 2002 : 1263 Packaging Group : III Ensure drivers have adequate training. For International Road/Rail Chemical Name : Paint Item Number : 31 °C Trem Card : 30G35 For Sea Transport Marine Pollutant : Yes EmS : 3 - 05 MFAG : 310 This information does not apply to carriage by air. Please contact JCB Supply Department if transport by air is required. 15. REGULATORY INFORMATION This product has been classified and labelled for supply in accordance with the CHIP 2 regulations as follows:- : 1263 Packing Group : III Ensure drivers have adequate training. For International Road/Rail Chemical Name : Paint Item Number : 31 °C Trem Card : 30G35 For Sea Transport Marine Pollutant : Yes EmS : 3 - 05 MFAG : 310 This information does not apply to carriage by air. Please contact JCB Supply Department if transport by air is required. 9804/8915 ISSUE 4 (REV.), NOVEMBER 1997 15. REGULATORY INFORMATION This product has been classified and labelled for supply in accordance with the CHIP 2 regulations as follows:- : 1263 Packaging Group : III Ensure drivers have adequate training. For International Road/Rail Chemical Name : Paint Item Number : 31 ° C Trem Card : 30G35 cont’d 9804/8922 ISSUE 5 (REV.), JUNE 2002 : 1263 Packing Group : III Ensure drivers have adequate training. For International Road/Rail Chemical Name : Paint related material Item Number : 31 °C Trem Card : 30G35 For Sea Transport Marine Pollutant : No EmS : 3 - 05 MFAG : 310 This information does not apply to carriage by air. Please contact JCB Supply Department if transport by air is required. 15. REGULATORY INFORMATION This product has been classified and labelled for supply in accordance with the CHIP 2 regulations as follows:- : 1263 Packing Group : III Ensure drivers have adequate training. 9804/8965 ISSUE 3 (REV.), NOVEMBER 1997 14. TRANSPORT INFORMATION continued For International Road/Rail Chemical Name : Paint Item Number : 31 °C Trem Card : 30G35 For Sea Transport Marine Pollutant : Yes EmS : 3 - 05 MFAG : 310 Additive: Transport details Class : 3 Proper Shipping Name : Paint Sub Hazard : - : 1263 Packing Group : III Ensure drivers have adequate training. For international Road/Rail Chemical Name : Paint Item Number : 31°C Trem Card : 30G35 For Sea Transport Marine Pollutant : Yes EmS : 3 - 05 MFAG : 310 This information does not apply to carriage by air. Please contact JCB Supply Department if transport by air is required. 15. REGULATORY INFORMATION This product has been classified and labelled for supply in accordance with the CHIP 2 regulations as follows:- For all colours except those listed in Section 1 as containing lead chromate:- Base: : 1263 Packing Group : III Ensure drivers have adequate training. For International Road/Rail Chemical Name : Paint Item Number : 31 °C Trem Card : 30G35 For Sea Transport Marine Pollutant : No EmS : 3 - 05 MFAG : 310 Additive: Transport details Class : 3 Proper Shipping Name : Paint Sub Hazard : - : 1263 Packing Group : III Ensure drivers have adequate training. For international Road/Rail Chemical Name : Paint Item Number : 31°C Trem Card : 30G35 cont’d 9804/8966 ISSUE 3 (REV.), JUNE 2002 None assigned. UN Proper Shipping Name: Not applicable. ADR/RID Substance Identification Number: Non Hazardous. IMDG - Packaging Group: Not applicable. IMDG - Class: Non Hazardous. IATA - Class: Non Hazardous. 15. REGULATORY INFORMATION None assigned. UN Proper Shipping Name: Not applicable. ADR/RID Substance Identification Number: Non Hazardous. IMDG - Packaging Group: Not applicable. IMDG - Class: Non Hazardous. IATA - Class: Non Hazardous. 15. REGULATORY INFORMATION 1993 UN Proper Shipping Name: Flammable liquid, n.o.s. UN Class: 3.2 UN Packaging Group: 2 ADR/RID - Class: 3.2 ADR/RID - Hazard Identification Number: 33 IMDG - Proper Shipping Name: Flammable liquid, N.O.S. (contains ethyl acetate) IMDG - Packaging Group: 3.2 IMDG - Class: 3 IMDG - Ems Number: 3-07 IMDG - MFAG Table Number: 3230 IATA - Proper Shipping Name: Flammable liquid, N.O.S. IATA - Packaging Group: 2 IATA - Class: 3 15. REGULATORY INFORMATION : 1950 Packing Group Ensure drivers have adequate training. cont’d 9804/9010 ISSUE 1, MAY 1997 For International Road/Rail Chemical Name : Aerosol dispenser Item Number : 10 ° (b) Trem Card : 20G26 For Sea Transport Marine Pollutant : Yes EmS : 2 - 13 MFAG This information does not apply to carriage by air. Please contact JCB Supply Department if transport by air is required. 15. REGULATORY INFORMATION This product has been classified and labelled for supply in accordance with the CHIP 2 regulations as follows:- : 1950 Packing Group Ensure drivers have adequate training. cont’d 9804/9009 ISSUE 1, MARCH 1997 For International Road/Rail Chemical Name : Aerosol dispenser Item Number : 10 ° (b) Trem Card : 20G26 For Sea Transport Marine Pollutant : Yes EmS : 2 - 13 MFAG This information does not apply to carriage by air. Please contact JCB Supply Department if transport by air is required. 15. REGULATORY INFORMATION This product has been classified and labelled for supply in accordance with the CHIP 2 regulations as follows:- : 1263 Packing Group : III Ensure drivers have adequate training. For International Road/Rail Chemical Name : Paint Item Number : 31 °C Trem Card : 30G35 For Sea Transport Marine Pollutant : Yes EmS : 3 - 05 MFAG : 310 Additive: Transport details Class : 3 Proper Shipping Name : Paint Sub Hazard : - : 1263 Packing Group : III Ensure drivers have adequate training. For international Road/Rail Chemical Name : Paint Item Number : 31°C Trem Card : 30G35 For Sea Transport Marine Pollutant : Yes EmS : 3 - 05 MFAG : 310 This information does not apply to carriage by air. Please contact JCB Supply Department if transport by air is required. 9804/9012 ISSUE 2, NOVEMBER 1997 15. REGULATORY INFORMATION This product has been classified and labelled for supply in accordance with the CHIP 2 regulations as follows:- Base: 2794 IMDG Class 8 Corrosive IMDG Page 8120 Packing Group 3 IMDG Label BATTERIES, WET, FILLED WITH ACID MFAG 700 EmS 8-10 Air: 2794 Proper Ship Name BATTERIES, WET, FILLED WITH ACID IATA Class 8 IATA Packaging Group 3 IATA Label RCM CORROSIVE CLASS 8 9804/8942 ISSUE 2, FEBRUARY 1998 *15. REGULATORY INFORMATION CHIP: No label required for supply For conveyance see TRANSPORT INFORMATION. COSHH: Sulphuric acid mist - for occupational Exposure Limit see UK HSE Guidance Note EH40. Lead: The repair of most automotive batteries is impracticable due to the materials and the type of construction used. In cases where repairs are possible, (e.g. the replacement of a traction battery cell), only competent persons should be allowed to undertake the work and a reference should be made to the Control of Lead at Work Regulations (Revised 1985). Waste: All spent batteries and waste arising from spillages and fires must be disposed of in conformance with the Environmental Protection Act, the Special Waste Regulations 1996 and the Environmental Protection (Duty of Care) Regulations 1991 and/or other local territory regulations. 1950 Shipping Name AEROSOL Class 2.1 Sub. Hazard Packing Group II Item 5°(b) Trem Card 20G26 Category 2 Number Marine EmS 3-05 MFAG 310 Marine Pollutant Yes This information does not apply to carriage by air. Please contact JCB Service Department if transport by air is required. 15. REGULATORY INFORMATION The product has been classified and labelled for supply in accordance with the CHIP 2 regulations as follows:- EXTREMELY IRRITANT FLAMMABLE Cont’d 9804/9019 ISSUE1, JANUARY 2002 Extremely flammable Irritating to eyes Do not breathe vapour/spray. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. In case of insufficient ventilation, wear suitable respiratory equipment. The information contained in this data sheet does not constitute the user's own assessment of workplace risks as required by other health and safety legislation. The provisions of the Health and Safety at Work etc. Act and the Control of Substances Hazardous to Health Regulations apply to the use of this product at work. 1263 Shipping Name PAINT Class 3 Sub. Hazard Packing Group III Item Number 31°C Trem card 30G35 Category 3 Marine EmS 3-05 MFAG 310 Marine Pollutant Yes This information does not apply to carriage by air. Please contact JCB Supply Department if transport by air is required. 15. REGULATORY INFORMATION This product has been classified and labelled for supply in accordance with the CHIP 2 regulations as follows:- Flammable Keep away from sources of ignition - No smoking. Keep out of reach of children. Ensure maximum ventilation during application and drying. When spraying, do not breathe spray, wear suitable respiratory equipment. On large interior surfaces or in confined spaces, wear air-fed respiratory equipment. Do not breathe vapour/spray. Avoid contact with skin and eyes. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. After contact with skin, wash immediately with plenty of soap and water or proprietary skin cleanser. In case of insufficient ventilation, wear suitable respiratory equipment. The information contained in this data sheet does not constitute the user’s own assessment of workplace risks as required by other health and safety legislation. The provisions of the Health and Safety at Work etc. Act and the Control of Substances Hazardous to Health Regulations apply to the use of this product at work. 1263 Shipping Name PAINT Class 3 Sub. Hazard Packing Group III Item 31°(c) Trem Card 30G35 Category 3 Number Marine EmS 3-05 MFAG 310 Marine Pollutant No Additive: 1263 Shipping Name PAINT Class 3 Sub. Hazard Packing Group III Item 31°(c) Trem Card 30G35 Category 3 Number Marine EmS 3-05 MFAG 310 Marine Pollutant No This information does not apply to carriage by air. Please contact the Export Department of W. & J. Leigh & Co. if transport by air is required. 15. REGULATORY INFORMATION The product has been classified and labelled for supply in accordance with the CHIP 2 regulations as follows:- Base: Xylene (mixture of isomers) HARMFUL Flammable Harmful by inhalation and in contact with skin. Do not breathe vapour/spray. In case of insufficient ventilation, wear suitable respiratory equipment. cont’d 9804/9027 ISSUE 1, JANUARY 2002 1263 Shipping Name PAINT Class 3 Sub. Hazard Packing Group III Item 31°(c) Trem Card 30G35 Category 3 Number Marine EmS 3-05 MFAG 310 Marine Pollutant No Additive: 1263 Shipping Name PAINT Class 3 Sub. Hazard Packing Group III Item 31°(c) Trem Card 30G35 Category 3 Number Marine EmS 3-05 MFAG 310 Marine Pollutant No This information does not apply to carriage by air. Please contact JCB Service if transport by air is required. 15. REGULATORY INFORMATION The product has been classified and labelled for supply in accordance with the CHIP 2 regulations as follows:- Base: Flammable Keep away from sources of ignition - No smoking. Keep out of reach of children. Ensure maximum ventilation during application and drying. When spraying, do not breathe spray, wear suitable respiratory equipment. On large interior surfaces or in confined spaces, wear air-fed respiratory equipment. Do not breathe vapour/spray. Avoid contact with skin and eyes. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. After contact with skin, wash immediately with plenty of soap and water or proprietary skin cleanser. In case of insufficient ventilation, wear suitable respiratory equipment. Additive: Aliphatic polyepoxide HARMFUL Flammable Possible risk of irreversible effects When using do not eat, drink or smoke Do not breathe vapour/spray. In case of insufficient ventilation, wear suitable respiratory equipment. The information contained in this data sheet does not constitute the user's own assessment of workplace risks as required by other health and safety legislation. The provisions of the Health and Safety at Work etc. Act and the Control of Substances Hazardous to Health Regulations apply to the use of this product at work. 9804/9033 ISSUE 1, JANUARY 2002 1263 Shipping Name PAINT Class 3 Sub. Hazard Packing Group III Item 31°(C) Trem Card 30G35 Category 3 Number Marine EmS 3-05 MFAG 310 Marine Pollutant No Additive: 1263 Shipping Name PAINT Class 3 Sub. Hazard Packing Group III Item 31°(C) Trem Card 30G35 Category 3 Number Marine EmS 3-05 MFAG 310 Marine Pollutant No This information does not apply to carriage by air. Please contact JCB Service if transport by air is required. 15. REGULATORY INFORMATION The product has been classified and labelled for supply in accordance with the CHIP 2 regulations as follows:- Base: Xylene (mixture of isomers) HARMFUL Flammable Harmful by inhalation and in contact with skin. Do not breathe vapour/spray. In case of insufficient ventilation, wear suitable respiratory equipment. cont’d 9804/9034 ISSUE 1, JANUARY 2002 (S.I.N.) Not applicable UN class, packing group: Not applicable 15. REGULATORY INFORMATION Adhesive EEC Hazard classification: Irritant 1263 Shipping Name PAINT Class 3 Sub. Hazard Packing Group III Item Number 31°C Trem card 30G35 Category 3 Marine EmS 3-05 MFAG 310 Marine Pollutant Yes This information does not apply to carriage by air. Please contact JCB Supply Department if transport by air is required. 15. REGULATORY INFORMATION This product has been classified and labelled for supply in accordance with the CHIP 2 regulations as follows:- Flammable Keep away from sources of ignition - No smoking. Keep out of reach of children. Ensure maximum ventilation during application and drying. When spraying, do not breathe spray, wear suitable respiratory equipment. On large interior surfaces or in confined spaces, wear air-fed respiratory equipment. Do not breathe vapour/spray. Avoid contact with skin and eyes. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. After contact with skin, wash immediately with plenty of soap and water or proprietary skin cleanser. In case of insufficient ventilation, wear suitable respiratory equipment. The information contained in this data sheet does not constitute the user’s own assessment of workplace risks as required by other health and safety legislation. The provisions of the Health and Safety at Work etc. Act and the Control of Substances Hazardous to Health Regulations apply to the use of this product at work. 1950 Shipping Name AEROSOL Class 2.1 Sub. Hazard Packing Group II Item 5°(b) Trem Card 20G26 Category 2 Number Marine EmS 3-05 MFAG 310 Marine Pollutant Yes This information does not apply to carriage by air. Please contact JCB Service Department if transport by air is required. 15. REGULATORY INFORMATION The product has been classified and labelled for supply in accordance with the CHIP 2 regulations as follows:- EXTREMELY IRRITANT FLAMMABLE Cont’d 9804/9019 ISSUE 2 (REV), JUNE 2002 Extremely flammable Irritating to eyes Do not breathe vapour/spray. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. In case of insufficient ventilation, wear suitable respiratory equipment. The information contained in this data sheet does not constitute the user's own assessment of workplace risks as required by other health and safety legislation. The provisions of the Health and Safety at Work etc. Act and the Control of Substances Hazardous to Health Regulations apply to the use of this product at work. 1866 UN Class 3.2 UN Packing Group 2 ADR/RID Substance Identification 1866 Number ADR/RID Proper Shipping Name Resins in solution in inflammable liquids - flash point below 21 ºC ADR/RID Class 3.2 ADR/RID Item Number 5(b) ADR/RID Number 33 IMDG Proper Shipping Name Resin solution, flammable. IMDG Packing Group 3.2 IMDG Class 3 IMDG Ems Number 3 - 05 IATA Proper Shipping Name Resin Solution, flammable IATA Packing Group 2 IATA Class 3 15. REGULATORY INFORMATION Label Requirements Highly flammable. Harmful. NA Packing Group: NA UN Class: NA Marine pollutant: NA ADR/RID: NA EmS number: ICAO/IATA: NA MFAG number: 15. REGULATORY INFORMATION Not classified as hazardous for supply. Hazard label data: Non assigned R S Phrases: Non assigned EC directives: Framework waste directive, 91/156/EEC Waste oil directive, 87/101/EEC Statutory information: HASW A. Control of Substances Hazardous to Health Regulations. chemicals (Hazard Information and Packaging) Regs., as amended (CHIP 3). Environmental Protection Act. Waste Management Duty of Care Regs. Special waste Regs. European Waste Catalogue No: 13 02 02

2.2 Label elements

Information Flammable Information Requirements Special Phrases: Information Highly Flammable. Information Highly flammable Information Not classified according to EC Directive 88/379/EEC

Hazard statements

R-10 Flammable Not applicable Methacrylic acid 201-204-4 1 - 5 C XN R35 R21/22 Cumene hydroperoxide 201-254-7 1 - 5 O XN T C XI N R7 R21/22 R48/20/22 R23 R34 R37 R51/53 N,N-Dimethyl-p-toluidine 202-805-4 <0.5 T R23/24/25 R33 R52/53 For full text of risk phrases, please refer to Section 16. EMERGENCY OVERVIEW IRRITANT Eye: Contact with eyes causes redness and discomfort which is transient. Skin Contact: Unlikely to be hazardous by skin absorption. Inhalation: Vapour may be irritant to the respiratory tract. Ingestion: Unlikely to be hazardous if swallowed. No hazard in normal industrial use. Physico-Chemical: No unusual hazards are expected. Environmental: Unknown. 9804/9000 ISSUE 2, (REV) SEPTEMBER 2002 R37 - Irritating to respiratory system. EINECS: All components of this product are listed in EINECS or ELINCS, or are otherwise exempt from EU notification requirements. R36/37/38 - Irritating to eyes, respiratory system and skin. Xn HARMFUL Xn R22 Harmful if swallowed. Safety phrases for public use: S 2 Keep out of reach of children. S 46 If swallowed, seek medical advice immediately and show this container or label. Safety phrases for industrial use: S 36/37 Wear suitable protective clothing and gloves. None R36/38 (Contains Alkaline Detergent blend) Irritating to eyes and skin. None R52/53 - Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R36 - Irritating to eyes. R66 - Repeated exposure may cause skin dryness or cracking. R67 - Vapours may cause drowsiness and dizziness. R10 - Flammable. None 20/21: Harmful by inhalation and in contact with skin. None None Notation White spirit >1% & = <5% 100.00 125.00 OES Higher Aromatics >40% & = <50% Xn,, 50.00 20/21-36/37/38-65-10 OES Shella, Solvesso 100 Butanol, ISO-Butanol >1% & = <5% Xn, 50.00 75.00 20-10 OES Diacetone Alcohol, Technical >1% & = <5% Xi,F 50.00 75.00 36-11 OES Notes Notations = Sk - risk of absorption through skin Sen - respiratory sensitiser. cont’d 9804/8978 ISSUE 2, (REV.) MARCH 1997 OES = Occupational Exposure Standard MEL = Maximum Exposure Limit OEL’s are from EH40 except where marked SUP which are assigned by the supplier of the substance. General Protection All ppe, including rpe, used to control exposure to hazardous substances must be selected to meet the requirements of the COSHH regulations. Respiratory Protection Air fed respiratory equipment should be worn when spraying if levels cannot be controlled below OELs and engineering methods cannot be reasonably improved. Hand Protection Full physical protection is best. Seek relevant advice from glove manufacturers. Barrier cream may be of help but should not be applied after exposure has occurred. Eye Protection Eye protection designed to protect against liquid splashes should be worn. Skin Protection Cotton or cotton/synthetic overalls or coveralls are normally suitable. Grossly contaminated clothing should be removed and the skin washed with soap and water or a proprietary skin cleaner. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Flash Point: Viscosity: Specific Gravity: .969 gms/cc Method Hydrometer Vapour Density: HEAVIER than Air Lower Explosion Limit: .8% Vol. Solubility In Water: PARTIALLY MISCIBLE 10. STABILITY AND REACTIVITY Stable under the recommended storage and handling conditions (see Sect.7). In a fire, hazardous decomposition products such as smoke, carbon monoxide, carbon dioxide, and oxides of nitrogen may be produced. Keep away from oxidising agents and strongly alkaline and acid materials to prevent the possibility of exothermic reaction. 11 Highly Flammable 20/21/65 Harmful by inhalation, in contact with skin and may cause lung damage if swallowed. 36/37/38 Irritating to eyes, respiratory system and skin. Notation Higher Aromatics >50% & = <75% Xn,, 50.00 20/21-36/37/38-65-10 OES Shella, Solvesso 100 Butanol, ISO-Butanol >1% & = <5% Xn, 50.00 75.00 20-10 OES Diacetone Alcohol, Technical >1% & = <5% Xi,F 50.00 75.00 36-11 OES Notes Notations = Sk - risk of absorption through skin Sen - respiratory sensitiser. OES = Occupational Exposure Standard MEL = Maximum Exposure Limit OEL’s are from EH40 except where marked SUP which are assigned by the supplier of the substance. General Protection All ppe, including rpe, used to control exposure to hazardous substances must be selected to meet the requirements of the COSHH regulations. cont’d 9804/8979 ISSUE 2, (REV.) MARCH 1997 Respiratory Protection Air fed respiratory equipment should be worn when spraying if levels cannot be controlled below OELs and engineering methods cannot be reasonably improved. Hand Protection Full physical protection is best. Seek relevant advice from glove manufacturers. Barrier cream may be of help but should not be applied after exposure has occurred. Eye Protection Eye protection designed to protect against liquid splashes should be worn. Skin Protection Cotton or cotton/synthetic overalls or coveralls are normally suitable. Grossly contaminated clothing should be removed and the skin washed with soap and water or a proprietary skin cleaner. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Flash Point: ≥ 21°C & ≤ 55°C Method Equilibrium Method to ISO 1516 & ISO 3680. Viscosity: Specific Gravity: .905 gms/cc Method Calculation Vapour Density: HEAVIER than Air Lower Explosion Limit: .8% Vol. Solubility In Water: PARTIALLY MISCIBLE 10. STABILITY AND REACTIVITY Stable under the recommended storage and handling conditions (see Sect.7). In a fire, hazardous decomposition products such as smoke, carbon monoxide, carbon dioxide, and oxides of nitrogen may be produced. Keep away from oxidising agents and strongly alkaline and acid materials to prevent the possibility of an exothermic reaction. 10 Flammable 20/21 Harmful by inhalation and in contact with skin. 36/37/38 Irritating to eyes, respiratory system and skin. 65 Harmful: may cause lung damage if swallowed 10 Flammable 20/21 Harmful by inhalation and in contact with skin. 36/37/38 Irritating to eyes, respiratory system and skin. 65 Harmful: may cause lung damage if swallowed Notation Xylene, Mixture of Isomers, Xylol >75% & = <100% Xn, Xi, 100.00 150.00 20/21-38-65-10 Sk OES Notes Notations = Sk - risk of absorption through skin Sen - respiratory sensitiser. OES = Occupational Exposure Standard MEL = Maximum Exposure Limit OEL’s are from EH40 except where marked SUP which are assigned by the supplier of the substance. cont’d 9804/8981 ISSUE 2, (REV.) MARCH 1997 General Protection All ppe, including rpe, used to control exposure to hazardous substances must be selected to meet the requirements of the COSHH regulations. Respiratory Protection Air fed respiratory equipment should be worn when spraying if levels cannot be controlled below OELs and engineering methods cannot be reasonably improved. Hand Protection Full physical protection is best. Seek relevant advice from glove manufacturers. Barrier cream may be of help but should not be applied after exposure has occurred. Eye Protection Eye protection designed to protect against liquid splashes should be worn. Skin Protection Cotton or cotton/synthetic overalls or coveralls are normally suitable. Grossly contaminated clothing should be removed and the skin washed with soap and water or a proprietary skin cleaner. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Mobile Liquid Flash Point: ≥ 21°C & ≤ 55°C Method Equilibrium Method to ISO 1516 & ISO 3680. Viscosity: Specific Gravity: .865 gms/cc Method Calculation Vapour Density: HEAVIER than Air Lower Explosion Limit: .8% Vol. Solubility In Water: PARTIALLY MISCIBLE 10. STABILITY AND REACTIVITY Stable under the recommended storage and handling conditions (see Sect.7). In a fire, hazardous decomposition products such as smoke, carbon monoxide, carbon dioxide, and oxides of nitrogen may be produced. Keep away from oxidising agents and strongly alkaline and acid materials to prevent the possibility of an exothermic reaction. 10 Flammable 20/21 Harmful by inhalation and in contact with skin. 36/37/38 Irritating to eyes, respiratory system and skin. 65 Harmful: may cause lung damage if swallowed None Not applicable Cumene hydroperoxide 201-254-7 1 - 5 O XN T C XI N R7 R21/22 R48/20/22 R23 R34 R37 R51/53 N,N-Dimethyl-p-toluidine 202-805-4 <1 T R23/24/25 R33 R52/53 For full text of risk phrases, please refer to Section 16. EMERGENCY OVERVIEW IRRITANT HARMFUL Eye: Contact with eyes causes redness and discomfort which is transient. Skin Contact: Unlikely to be hazardous by skin absorption. Inhalation: Harmful if inhaled. Vapour may be irritant to the respiratory tract. Ingestion: Unlikely to be hazardous if swallowed. No hazard in normal industrial use. Physico-chemical: No unusual hazards are expected. Environmental: Unknown. 9804/8997 ISSUE 2, (REV) SEPTEMBER 2002 R20 - Harmful by inhalation. R37 - Irritating to respiratory system. EINECS All components of this product are listed in EINECS or ELINCS, or are otherwise exempt from EU notification requirements. Not applicable None Methacrylic acid 201-204-4 1 - 5 C XN R35 R21/22 Cumene hydroperoxide 201-254-7 1 - 5 O XN T C XI N R7 R21/22 R48/20/22 R23 R34 R37 R51/53 N,N-Dimethyl-p-toluidine 202-805-4 <0.5 T R23/24/25 R33 R52/53 For full text of risk phrases, please refer to Section 16. EMERGENCY OVERVIEW IRRITANT Eye: Contact with eyes causes redness and discomfort which is transient. Skin Contact: Unlikely to be hazardous by skin absorption. Inhalation: Vapour may be irritant to the respiratory tract. Ingestion: Unlikely to be hazardous if swallowed. No hazard in normal industrial use. Physico-chemical: No unusual hazards are expected. Environmental: Unknown. 9804/9002 ISSUE 2, (REV) SEPTEMBER 2002 R37 - Irritating to respiratory system. EINECS: All components of this product are listed in EINECS or ELINCS, or are otherwise exempt from EU notification requirements. None None R11 - Highly flammable. Methacrylic acid 201-204-4 1 - 5 XN R35 R21/22 Cumene hydroperoxide 201-254-7 1 - 5 O XN T C XI N R7 R21/22 R48/20/22 R23 R34 R37 R51/53 N,N-Dimethyl-p-toluidine 202-805-4 <0.5 T R23/24/25 R33 R52/53 For full text of risk phrases, please refer to Section 16. EMERGENCY OVERVIEW IRRITANT Eye: Contact with eyes causes redness and discomfort which is transient. Skin Contact: Unlikely to be hazardous by skin absorption. Inhalation: Vapour may be irritant to the respiratory tract. Ingestion: Unlikely to be hazardous if swallowed. No hazard in normal industrial use. Physico-Chemical: No unusual hazards are expected. Environmental: Unknown. 9804/9005 ISSUE 2, (REV) SEPTEMBER 2002 R37 - Irritating to respiratory system. EINECS All components of this product are listed in EINECS or ELINCS, or are otherwise exempt from EU notification requirements. R38 - Irritating to skin. R67 - Vapours may cause drowsiness and dizziness. * CAS Number Paint Acetone 25-50% R66 67-64-1 Xi R36 Butane 10-25% 106-97-8 White spirit 10-25% Xn R65 064742-82-1 *For full details of R-phrases, see Section 16. F+ R12 Extremely flammable Xi R36 Irritating to eyes 9804/9019 ISSUE1, JANUARY 2002 4. FIRST-AID MEASURES In all cases of doubt, or where symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. Inhalation Remove to fresh air, keep patient warm and at rest. If breathing has stopped, administer artificial respiration. Give nothing by mouth. If unconscious, place in the recovery position and seek medical advice. Eye contact Contact lenses should be removed. Irrigate copiously with clean, fresh water for at least 10 minutes, holding the eyelids apart and seek medical advice. Skin contact Remove contaminated clothing. Wash skin thoroughly with soap and water, or use a proprietary skin cleanser. Do NOT use solvents or thinners. Ingestion If accidentally swallowed obtain immediate medical attention. Keep at rest. Do NOT induce vomiting. 5. FIRE-FIGHTING MEASURES Extinguishing Media Use alcohol resistant foam, carbon dioxide, dry powder or water spray/mist. Do NOT use water jet. Recommendations Fire will produce dense black smoke containing hazardous products of combustion (see Section 10). Exposure to decomposition products may be a hazard to health. Appropriate self-contained breathing apparatus may be required. Cool closed containers exposed to fire with water spray. Do not allow run-off from fire-fighting to enter drains or water courses. 6. ACCIDENTAL RELEASE MEASURES Exclude sources of ignition and ventilate the area. Exclude non-essential personnel. Avoid breathing vapours. Refer to protective measures listed in sections 7 and 8. Contain and collect spillages with non-combustible absorbent materials e.g. sand, earth, vermiculite, diatomaceous earth and place in a suitable container for disposal in accordance with the waste regulations (see Section 13). Do not allow to enter drains or water courses. Clean preferably with a detergent; avoid the use of solvents. If the product enters drains or sewers, the local water company should be contacted immediately; in the case of contamination of streams, rivers or lakes, the relevant environment agency. 7. STORAGE AND HANDLING Handling Vapours are heavier than air and may spread along floors. They may form explosive mixtures with air. Prevent the creation of flammable or explosive concentrations of vapour in air and avoid concentrations higher than the occupational exposure limits. Additionally the product should only be used in areas from which all naked lights and other sources of ignition have been excluded. Electrical equipment should be protected to the appropriate standard. Keep the container tightly closed. Exclude sources of heat, sparks and open flame. Non-sparking tools should be used. Required air quantity to 389 m³/ltr ventilate to 10% of the LEL. The above figure is given as a guide only. Ventilation and extraction must be arranged so that all parts of the workplace are properly ventilated i.e. there are no recesses or pockets where high vapour concentrations are allowed to build up. Cont’d 9804/9019 ISSUE1, JANUARY 2002 If there is any doubt about the adequacy of the ventilation/extraction of solvent vapour, regular monitoring of confined workplaces should be carried out. Avoid skin and eye contact. Avoid inhalation of vapour and spray mist. Smoking, eating and drinking should be prohibited in areas of storage and use. For personal protection, see Section 8. Never use pressure to empty; the container is not a pressure vessel. The accumulation of contaminated rags and dry overspray, particularly in spray booth filters, may result in spontaneous combustion. Good housekeeping standards, regular safe removal of waste materials and regular maintenance of spray booth filters will minimise the risks of spontaneous combustion and other fire hazards. The Manual Handling Regulations may apply to the handling of containers/packages of this product. The following guide weight indicators are given to enable users to carry out assessments. Package Weight 0.4 litre can 0.4 kg 10 Flammable Notation Range ppm 15 min ppm HIGHER AROMATICS OEL’s are >50% & = <75% Xn, 50.00 20/21-36/37/38-65-10 OES SHELLA, SOLVESSO 100 N-BUTANOL OEL’s are ISO-BUTANOL >1% & =<5% Xn, Xi 50.00 22-37/38-41-67 Sk OES DIACETONE ALCOHOL, TECHNICAL >1% & - <5% Xi 50.00 75.00 36 OES cont’d 9804/9023 ISSUE 1, JANUARY 2002 10 Flammable 20/21 Harmful by inhalation and in contact with skin 36/37/38 Irritating to eyes, respiratory system and skin 65 Harmful: may cause lung damage if swallowed Notation Range ppm 15 min ppm WHITE SPIRIT >1% & =<5% 100.00 125.00 OES HIGHER AROMATICS OEL’s are >40% & = <50% Xn, 50.00 20/21-36/37/38-65-10 OES SHELLA, SOLVESSO 100 N-BUTANOL OEL’s are ISO-BUTANOL >1% & =<5% Xn, Xi 50.00 22-37/38-41-67 Sk OES DIACETONE ALCOHOL, TECHNICAL >1% & =<5% Xi 50.00 75.00 36 OES Notes: Notations = Sk - risk or absorption through skin Sen = respiratory sensitiser Notations = SK - Risk of absorption through skin SEN - Respiratory Sensitiser Bmgv - Biological Monitoring may be appropriate (see Biological Monitoring Guidance Value in EH40 Table 3) OEL’s are from EH40 except where marked SUP which are assigned by the supplier of the substance. General Protection All ppe, including rpe, used to control exposure to hazardous substances must be selected to meet the requirements of the COSHH regulations. Respiratory Protection Air-fed respiratory equipment should be worn when spraying if levels cannot be controlled below OELs and engineering methods cannot be reasonably improved. Hand Protection Full physical protection is best. Seek relevant advice from glove manufacturers. Barrier cream may be of help but should not be applied after exposure has occurred. Eye Protection Eye protection designed to protect against liquid splashes should be worn. Skin Protection Cotton or cotton/synthetic overalls or coveralls are normally suitable. Grossly contaminated clothing should be removed and the skin washed with soap and water or a proprietary skin cleaner. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Flash Point: Viscosity: Specific Gravity: .969 gms/cc Method Hydrometer Vapour Density: HEAVIER than Air Lower Explosion Limit: .8% Vol. Solubility in Water: Partially miscible 10. STABILITY AND REACTIVITY Stable under the recommended storage and handling conditions (see Section 7). In a fire, hazardous decomposition products such as smoke, carbon monoxide, carbon dioxide and oxides of nitrogen may be produced. Keep away from oxidising agents and strongly alkaline and strongly acidic materials to prevent the possibility of an exothermic reaction. 11 Highly Flammable. 20/21/65 Harmful by inhalation, in contact with skin and may cause lung damage if swallowed. 36/37/38 Irritating to eyes, respiratory system and skin. R-12 Extremely flammable cont’d 9804/9026 ISSUE 1, JANUARY 2002 CAS Number Paint Base: Xylene (mixture of isomers) 10-25% Xi R38 1330-20-7 Xn R20/21 1-methoxy-2-propyl acetate 10-25% Xi R36 108-65-6 Ethylbenzene 2.5-10% Xn R20 100-41-4 Base (for colours containing lead chromate): Lead Chromates >1% R33 7758-97-6 Carc. Cat. 3 R40 N R50 N R53 Repr. Cat. 1 R61 Repr. Cat. 3 R62 cont’d 9804/9027 ISSUE 1, JANUARY 2002 CAS Number Paint Base (for colours containing lead chromate): Xylene (mixture of isomers) 10-25% Xi R38 1330-20-7 Xn R20/21 1-methoxy-2-propyl acetate 2.5-10% Xi R36 108-65-6 Ethylbenzene 2.5-10% Xn R20 100-41-4 Additive: Aliphatic polyisocyanate 25-50% Xi R43 28182-81-2 Xylene (mixture of isomers) 2.5-10% Xi R38 1330-20-7 Xn R20/21 1-methoxy-2-propyl acetate 2.5-10% Xi R36 108-65-6 Mesitylene 2.5-10% N R51 108-67-8 N R53 Xi R37 Propylbenzene <2.5% N R51 103-65-1 N R53 Xi R37 Xn R65 Ethylbenzene <2.5% Xn R20 100-41-4 Hexamethylene-di-isocyanate <1% T R53 822-06-0 Xi R36/37/38 Xn R42/43 *For full details of R-phrases, see Section 16. Base: R10 Flammable Xn R20/21 Harmful by inhalation and in contact with skin. Base (for colours containing lead chromate): R10 Flammable Xn R20/21 Harmful by inhalation and in contact with skin. R33 Danger of cumulative effects. Carc. Cat. 3 R40 Possible risk of irreversible effects Repr. Cat. 1 R61 May cause harm to the unborn child Repr. Cat. 3 R62 Possible risk of impaired fertility Additive: R10 Flammable Xn R20 Harmful by inhalation. Xi R43 May cause sensitisation by skin contact. 4. FIRST-AID MEASURES In all cases of doubt, or where symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. Inhalation Remove to fresh air, keep patient warm and at rest. If breathing has stopped, administer artificial respiration. Give nothing by mouth. If unconscious, place in the recovery position and seek medical advice. Eye contact Contact lenses should be removed. Irrigate copiously with clean, fresh water for at least 10 minutes, holding the eyelids apart and seek medical advice. cont’d 9804/9027 ISSUE 1, JANUARY 2002 Notation Range ppm 15 min ppm WHITE SPIRIT >1% & = <5% 100.00 125.00 OES XYLENE, MIXTURE OF >30% & = <40% Xn, xi 100.00 150.00 20/21-38 Sk OES ISOMERS OEL’s are XYLOL SOLVESSO100/AROMATIC >10% & = <20% Xn 50.00 36/37/38-20/21/65 OES 100/SHELLSOLA/AROMASOLN LEAD CHROMATE OEL’s >10% & = <20% T, 0.15* 61-33 OES are as lead Notes Notations = Sk - risk of absorption through skin Sen - respiratory sensitizer. Notations = SK - Risk of absorption through skin SEN - Respiratory Sensitiser. Bmgv - Biological Monitoring may be appropriate (see Biological Monitoring Guidance Value in EH40 Table 3) OEL’s are from EH40 except where marked SUP which are assigned by the supplier of the substance. *=OES given in mg/cubic metre - no figures available for parts per million General Protection All ppe, including rpe, used to control exposure to hazardous substances must be selected to meet the requirements of the COSHH regulations. Respiratory Protection Air fed respiratory equipment should be worn when spraying if levels cannot be controlled below OELs and engineering methods cannot be reasonably improved. Hand Protection Full physical protection is best. Seek relevant advice from glove manufacturers. Barrier cream may be of help but should not be applied after exposure has occurred. Eye Protection Eye protection designed to protect against liquid splashes should be worn. Skin Protection Cotton or cotton/synthetic overalls or coveralls are normally suitable. Grossly contaminated clothing should be removed and the skin washed with soap and water or a proprietary skin cleaner. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Flash Point: > 21ºC &< 32 ºC Method Equilibrium Method to ISO 1516 & ISO 3680 Viscosity Specific Gravity 1.116 gms/cc Method Calculation Vapour Density HEAVIER than Air Lower Explosion Limit .8% Vol. Solubility in Water PARTIALLY MISCIBLE 9804/9030 ISSUE1, JANUARY 2002 10. STABILITY AND REACTIVITY Stable under the recommended storage & handling conditions (see Sect. 7). In a fire, hazardous decomposition products such as smoke, carbon monoxide, carbon dioxide, and oxides of nitrogen may be produced. Keep away from oxidising agents and strongly alkaline and acid materials to prevent the possibility of an exothermic reaction. 10 Flammable 33 Danger of cumulative effects 36/37/38 Irritating to eyes, respiratory system and skin. 40/20/21/65 Harmful: possible risk of irreversible effects through inhalation, in contact with skin and may cause lung damage if swallowed. Notation Range ppm 15 min ppm SOLVESS0100/AROMATIC >20% & = <30% Xn 50.00 36/37/38-20/21/65 OES 100/SHELLSOLA/ARMMASOLN XYLENE, MIXTURE OF >20% & = <30% Xn, Xi 100.00 150.00 20/21-18 Sk OES ISOMERS OEL’s are XYLOL cont’d 9804/9031 ISSUE1, JANUARY 2002 Notes Notations = Sk - risk of absorption through skin Sen - respiratory sensittizer. Notations = SK - Risk of absorption through skin SEN - Respiratory Sensitiser. Bmgv - Biological Monitoring may be appropriate (see Biological Monitoring Guidance Value in EH40 Table 3) OEL’s are from EH40 except where marked SUP which are assigned by the supplier of the substance. General Protection All ppe, including rpe, used to control exposure to hazardous substances must be selected to meet the requirements of the COSHH regulations. Respiratory Protection air fed respiratory equipment should be worn when spraying if levels cannot be controlled below OELs and engineering methods cannot be reasonably improved. Hand Protection Full physical protection is best. Seek relevant advice from glove manufacturers. Barrier cream may be of help but should not be applied after exposure has occured. Eye Protection Eye protection designed to protect against liquid splashes should be worn. Skin Protection Cotton or cotton/synthetic overalls or coveralls are normally suitable. Grossly contaminated clothing should be removed and the skin washed with soap and water or a proprietary skin cleaner. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Flash Point: ≥ 21ºC & ≤ 55 ºC Method Equilibrium Method to ISO 1516 & ISO 3680 Viscosity Specific Gravity 1.066 gms/cc Method Calculation Vapour Density HEAVIER than Air Lower Explosion Limit .8% Vol. Solubility in Water PARTIALLY MISCIBLE 10. STABILITY AND REACTIVITY Stable under the recommended storage & handling conditions (see Sect. 7). In a fire, hazardous decomposition products such as smoke, carbon monoxide, carbon dioxide, and oxides of nitrogen may be produced. Keep away from oxidising agents and strongly alkaline and acid materials to prevent the possibility of an exothermic reaction. 10 Flammable 20/21 Harmful by inhalation and in contact with skin 36/37/38 Irritating to eyes, respiratory system and skin. 65 Harmful: may cause lung damage if swallowed CAS Number Paint Base: Xylene (mixture of isomers) 10-25% Xi R38 1330-20-7 Xn R20/21 1-methoxypropan-2-ol 10-25% 107-98-2 Mesitylene <2.5% N R51 108-67-8 N R53 Xi R37 Additive: 1-methoxypropan-2-ol 10-25% 107-98-2 Aliphatic polyepoxide 10-25% Xi R36/38 68412-01-1 Xn R40 Mesitylene 2.5-10% N R51 108-67-8 N R53 Xi R37 cont’d 9804/9033 ISSUE 1, JANUARY 2002 CAS Number Paint Additive: Propylbenzene 2.5-10% N R51 103-65-1 N R53 Xi R37 Xn R65 Xylene (mixture of isomers) 2.5-10% Xi R38 1330-20-7 Xn R20/21 *For full details of R-phrases, see Section 16. Base: R10 Flammable Additive: R10 Flammable Xn R40 Possible risk of irreversible effects 4. FIRST-AID MEASURES In all cases of doubt, or where symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. Inhalation Remove to fresh air, keep patient warm and at rest. If breathing has stopped, administer artificial respiration. Give nothing by mouth. If unconscious, place in the recovery position and seek medical advice. Eye contact Contact lenses should be removed. Irrigate copiously with clean, fresh water for at least 10 minutes, holding the eyelids apart and seek medical advice. Skin contact Remove contaminated clothing. Wash skin thoroughly with soap and water, or use a proprietary skin cleanser. Do NOT use solvents or thinners. Ingestion If accidentally swallowed obtain immediate medical attention. Keep at rest. Do NOT induce vomiting. 5. FIRE-FIGHTING MEASURES Extinguishing Media Use alcohol resistant foam, carbon dioxide, dry powder or water spray/mist. Do NOT use water jet. Recommendations Fire will produce dense black smoke containing hazardous products of combustion (see Section 10). Exposure to decomposition products may be a hazard to health. Appropriate self-contained breathing apparatus may be required. Cool closed containers exposed to fire with water spray. Do not allow run-off from fire-fighting to enter drains or water courses. 9804/9033 ISSUE 1, JANUARY 2002 CAS Number Paint Base: Xylene (mixture of isomers) 10-25% Xi R38 1330-20-7 Xn R20/21 1-methoxypropan-2-ol 10-25% 107-98-2 Mesitylene 2.5-10% N R51 108-67-8 N R53 Xi R37 Propylbenzene <2.5% N R51 103-65-1 N R53 Xi R37 Xn R65 cont’d 9804/9034 ISSUE 1, JANUARY 2002 CAS Number Paint Base Xylene (mixture of isomers) 10-25% Xi R38 1330-20-7 Xn R20/21 1-methoxypropan-2-ol 10-25% 107-98-2 Mesitylene 2.5-10% N R51 108-67-8 N R53 Xi R37 Propylbenzene <2.5% N R51 103-65-1 N R53 Xi R37 Xn R65 Base (for colours containing lead chromate): Lead Chromates >1% R33 7758-97-6 Carc. Cat. 3 R40 N R50 N R53 Repr. Cat. 1 R61 Repr. Cat. 3 R62 Xylene (mixture of isomers) 10-25% Xi R38 1330-20-7 Xn R20/21 1-methoxypropan-2-ol 2.5-10% 107-98-2 Mesitylene 2.5-10% N R51 108-67-8 N R53 Xi R37 Propylbenzene <2.5% N R51 103-65-1 N R53 Xi R37 Xn R65 Additive: 1-methoxypropan-2-ol 10-25% 107-98-2 Aliphatic polyepoxide 10-25% Xi R36/38 68412-01-1 Xn R40 Mesitylene 2.5-10% N R51 108-67-8 N R53 Xi R37 Propylbenzene 2.5-10% N R51 103-65-1 N R53 Xi R37 Xn R65 Xylene (mixture of isomers) 2.5-10% Xi R38 1330-20-7 Xn R20/21 *For full details of R-phrases, see Section 16. Base: R10 Flammable Xn R20/21 Harmful by inhalation and in contact with skin. cont’d 9804/9034 ISSUE 1, JANUARY 2002 Epoxy resin 28064 - 14 - 4 >50% Xi R36/38, R43 Trimethylolpropane 30499 - 70 - 8 20-<35% Xi triglycidyl ether R36/38, R43 Hardener No components which pose a risk. Adhesive Irritant. Sensitiser Eye: Irritating, but does not injure eye tissue. Skin Contact: Frequent or prolonged contact may irritate the skin and cause sensitisation. Inhalation: Based on its low volatility, product is not considered to be a respiratory hazard under normal conditions of use. Cont’d..... 9804/9025 ISSUE 1, MARCH 2002 R36/38 - Irritating to eyes and skin. R43 - May cause sensitisation by skin contact. Notation Range ppm 15 min ppm XYLENE, MIXTURE OF ISOMERS OEL’S >20% & = <30% XN, Xi 100.00 150.00 20/21-38 Sk OES are XYLOL LEAD CHROMATE OES’s are as Lead >20% & = <30% T, 0.15* 61-33 OES BUTYL ACETATE >10% & = <20% Xn 150.00 200.00 10 OES Notes Notations = Sk - risk of absorption through skin Sen - respiratory sensitizer. Notations = SK - Risk of absorption through skin SEN - Respiratory Sensitiser. Bmgv - Biological Monitoring may be appropriate (see Biological Monitoring Guidance Value in EH40 Table 3) OEL’s are from EH40 except where marked SUP which are assigned by the supplier of the substance. *=OES given in mg/cubic metre - no figures available for parts per million General Protection All ppe, including rpe, used to control exposure to hazardous substances must be selected to meet the requirements of the COSHH regulations. cont’d 9804/9035 ISSUE 1, MARCH 2002 Notation Range ppm 15 min ppm BUTYL ACETATE >40% & = <50% Xn 150.00 200.00 10 OES XYLENE, MIXTURE OF ISOMERS OEL’s >5% & = <10% Xn, Xi 100.00 150.00 20/21-38 Sk OES are XYLOL METHOXY PROPYL >5% & = 10% Xn 50.00 20/21/22 OES ACETATE/PROPYLENE GLYCOL MON-METHYL ETHER ACETATE,ARCOSOLV PMA ALIPHATIC POLY- >40% & = <50% Xn, Xi 0.02* 20-36/37/ Sen OES ISOCYANATE 38-42-43 HEXAMETHYLENE-DI >0% & = <1% T, Xi 0.02* 0.07* 23-36/37 Sen MEL ISOCYANATE 38-42/43 Notes Notations = Sk - risk of absorption through skin Sen - respiratory sensitizer. Notations = SK - Risk of absorption through skin SEN - Respiratory Sensitiser. Bmgv - Biological Monitoring may be appropriate (see Biological Monitoring Guidance Value in EH40 Table 3) OEL’s are from EH40 except where marked SUP which are assigned by the supplier of the substance. *=OES given in mg/cubic metre - no figures available for parts per million General Protection Air-fed equipment should be worn when this product is sprayed. This is in addition to other measures taken to reduce exposure. Non-essential people should be excluded from the area if exposure is possible. Respiratory Protection Air fed respiratory equipment should be worn when spraying if levels cannot be controlled below OELs and engineering methods cannot be reasonably improved. Hand Protection Full physical protection is best. Seek relevant advice from glove manufacturers. Barrier cream may be of help but should not be applied after exposure has occurred. Eye Protection Eye protection designed to protect against liquid splashes should be worn. cont’d 9804/9035 ISSUE 1, MARCH 2002 40/20/21/65 Harmful: possible risk of irreversible effects through inhalation, in contact with skin and may cause lung damage if swallowed. 36/37/38 Irritating to eyes, respiratory system and skin 10 Flammable 33 Danger of cumulative effects 10 Flammable 42 May cause sensitisation by inhalation 20/65 Harmful by inhalation and may cause lung damage if swallowed 36/37/38 Irritating to eyes, respiratory system and skin * CAS Number Paint Acetone 25-50% R66 67-64-1 Xi R36 Butane 10-25% 106-97-8 White spirit 10-25% Xn R65 064742-82-1 *For full details of R-phrases, see Section 16. F+ R12 Extremely flammable Xi R36 Irritating to eyes 9804/9019 ISSUE 2 (REV), JUNE 2002 4. FIRST-AID MEASURES In all cases of doubt, or where symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. Inhalation Remove to fresh air, keep patient warm and at rest. If breathing has stopped, administer artificial respiration. Give nothing by mouth. If unconscious, place in the recovery position and seek medical advice. Eye contact Contact lenses should be removed. Irrigate copiously with clean, fresh water for at least 10 minutes, holding the eyelids apart and seek medical advice. Skin contact Remove contaminated clothing. Wash skin thoroughly with soap and water, or use a proprietary skin cleanser. Do NOT use solvents or thinners. Ingestion If accidentally swallowed obtain immediate medical attention. Keep at rest. Do NOT induce vomiting. 5. FIRE-FIGHTING MEASURES Extinguishing Media Use alcohol resistant foam, carbon dioxide, dry powder or water spray/mist. Do NOT use water jet. Recommendations Fire will produce dense black smoke containing hazardous products of combustion (see Section 10). Exposure to decomposition products may be a hazard to health. Appropriate self-contained breathing apparatus may be required. Cool closed containers exposed to fire with water spray. Do not allow run-off from fire-fighting to enter drains or water courses. 6. ACCIDENTAL RELEASE MEASURES Exclude sources of ignition and ventilate the area. Exclude non-essential personnel. Avoid breathing vapours. Refer to protective measures listed in sections 7 and 8. Contain and collect spillages with non-combustible absorbent materials e.g. sand, earth, vermiculite, diatomaceous earth and place in a suitable container for disposal in accordance with the waste regulations (see Section 13). Do not allow to enter drains or water courses. Clean preferably with a detergent; avoid the use of solvents. If the product enters drains or sewers, the local water company should be contacted immediately; in the case of contamination of streams, rivers or lakes, the relevant environment agency. 7. STORAGE AND HANDLING Handling Vapours are heavier than air and may spread along floors. They may form explosive mixtures with air. Prevent the creation of flammable or explosive concentrations of vapour in air and avoid concentrations higher than the occupational exposure limits. Additionally the product should only be used in areas from which all naked lights and other sources of ignition have been excluded. Electrical equipment should be protected to the appropriate standard. Keep the container tightly closed. Exclude sources of heat, sparks and open flame. Non-sparking tools should be used. Required air quantity to 389 m³/ltr ventilate to 10% of the LEL. The above figure is given as a guide only. Ventilation and extraction must be arranged so that all parts of the workplace are properly ventilated i.e. there are no recesses or pockets where high vapour concentrations are allowed to build up. Cont’d 9804/9019 ISSUE 2 (REV), JUNE 2002 If there is any doubt about the adequacy of the ventilation/extraction of solvent vapour, regular monitoring of confined workplaces should be carried out. Avoid skin and eye contact. Avoid inhalation of vapour and spray mist. Smoking, eating and drinking should be prohibited in areas of storage and use. For personal protection, see Section 8. Never use pressure to empty; the container is not a pressure vessel. The accumulation of contaminated rags and dry overspray, particularly in spray booth filters, may result in spontaneous combustion. Good housekeeping standards, regular safe removal of waste materials and regular maintenance of spray booth filters will minimise the risks of spontaneous combustion and other fire hazards. The Manual Handling Regulations may apply to the handling of containers/packages of this product. The following guide weight indicators are given to enable users to carry out assessments. Package Weight 0.4 litre can 0.4 kg R51/53 - Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R36/38 - Irritating to eyes and skin. R43 - May cause sensitisation by skin contact. Ethyl acetate 141-78-6 25.00% - 50.00% F, Xi R11. R36, R66, R67 Butan-2-one 78-93-3 10.00% - 25.00% F, Xi R11, R36, R66, R67 Butyl acetate 123-86-4 10.00% - 25.00% - R10, R66, R67 Diphenylmethandiisocyanate 101-68-8 2.50% - 10.00% Xn R20, R36/37/38, R42/43 Main Hazards Highly flammable. Irritating to eyes, respiratory system and skin. May cause sensitisation by inhalation and skin contact. Vapours may cause drowsiness and dizziness 4. FIRST-AID MEASURES Eye Contact Immediately flood the eye with plenty of water for at least 15 minutes, holding the eye open. Obtain medical attention urgently. cont’d 9804/9036 ISSUE 1, AUGUST 2002 Highly flammable. Irritating to eyes., respiratory system and skin. May cause sensitisation by inhalation and skin contact. Vapours may cause drowsiness and dizziness. 1,2-Benzenedicarboxylic acid 25.00% - 50.00% - diisodecyl ester Isophorondiisocyanate 0.10% - 10.00% T R23, R36/37/38, R42/43 Diphenylmethandiisocyanate 0.10% - 10.00% Xn R20, R36/37/38, R42/43 Main Hazards May cause sensitisation by inhalation. 4. FIRST-AID MEASURES Eye Contact Immediately flood the eye with plenty of water for at least 15 minutes, holding the eye open. Obtain medical attention immediately. cont’d 9804/9037 ISSUE 1, AUGUST 2002 May cause sensitisation by inhalation. Not Classified.

Precautionary statements

S-2 Keep out of reach of children. S-26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S-51 Use only in well ventilated areas. S-62 If swallowed, do not induce vomiting. Seek medical advice immediately and show this container or label. S-23a Do not breathe vapour/spray. S28a After contact with skin, wash immediately with plenty of soap and water. UK regulatory references: Chemical (Hazard Information & Packaging) Regulations 1994. Not applicable S23 - Do not breathe gas/fumes/vapour/spray. S24/25 - Avoid contact with skin and eyes. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Special Phrases: Cyanoacrylate. Danger. Bonds skin and eyes in seconds. Keep out of the reach of children. EINECS: All components of this product are listed in EINECS or ELINCS, or are otherwise exempt from EU notification requirements. 2: Keep out of the reach of children. 23: Do not breathe vapour/spray. 46: If swallowed seek medical advice immediately and show this container or label. REGULATORY REFERENCES: The Chemicals (Hazard Information and Packaging)Regulations 1993. Wear appropriate personal protection gear - see section 8. Environmental Precautions: Prevent entry into drains. Clean up Procedure: * Contain in confined area using sand, earth or suitable material. Neutralise with addition of acetic acid or dilute mineral acid. For disposal of residues see section 13. 7. HANDLING AND STORAGE Read the label before opening the container. Store in a dry, well ventilated area, protected from extremes of temperatures. Store in containers provided. 9804/8941 ISSUE 4, (REV.) SEPTEMBER 2001 S26 (Contains Alkaline Detergent blend) In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S37 (Contains Alkaline Detergent blend) Wear suitable gloves. Protect from freezing. Do not use neat - Dilute as recommended. STEL 1-methoxy-2-propanol 300ppm (1080 mg per cu.m) (skin) LTEL 1-methoxy-2-propanol 100ppm (360 mg per cu.m) (skin) 2: Keep out of the reach of children. 23: Do not breathe vapour/spray. 46: If swallowed seek medical advice immediately and show this container or label. REGULATORY REFERENCES: The Chemicals (Hazard Information and Packaging) Regulations 1993. S16 - Keep away from sources of ignition - No smoking. S23 - Do not breathe gas/fumes/vapour/spray. S51 - Use only in well ventilated areas. S9 - Keep container in a well ventilated place. EINECS: All components of this product are listed in EINECS or ELINCS, or are otherwise exempt from EU notification requirements. 9804/9004 ISSUE 2, (REV) SEPTEMBER 2002 2: Keep out of the reach of children. 16: Keep away from sources of ignition - No Smoking. 23: Do not breathe vapour/spray. 51: Use only in well ventilated areas. Regulatory references: The Chemicals (Hazard Information and Packaging) Regulations 1994 and CHIP 1996 amendment. 2: Keep out of the reach of children. 23: Do not breathe vapour/spray. 25: Avoid contact with eyes. 51: Use only in well ventilated areas. Regulatory references: The Chemicals (Hazard Information and Packaging) Regulations 1994 and CHIP 1996 amendment. 2: Keep out of the reach of children. 16: Keep away from sources of ignition - No Smoking. 23: Do not breathe vapour/spray. 51: Use only in well ventilated areas. Regulatory references: The Chemicals (Hazard Information and Packaging) Regulations 1994 and CHIP 1996 amendment. 2: Keep out of the reach of children. 16: Keep away from sources of ignition - No Smoking. 23: Do not breathe vapour/spray. 51: Use only in well ventilated areas. Regulatory references: The Chemicals (Hazard Information and Packaging) Regulations 1994 and CHIP 1996 amendment. 28 After contact with skin, wash immediately with plenty of water. 7/9 Keep container tightly closed and in a well ventilated place 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. Do not breathe Vapour or Spray Restricted to professional users The information contained in this Safety Data Sheet does not constitute the user’s own assessment of the workplace risks as required by other health and safety legislation. The provisions of the Health & Safety at Work etc. Act and the Control of Substances Hazardous to Health Regulations apply to the use of this product at work. 28 After contact with skin, wash immediately with plenty of water. 7/9 Keep container tightly closed and in a well ventilated place 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. Do not breathe Vapour or Spray The information contained in this Safety Data Sheet does not constitute the user’s own assessment of the workplace risks as required by other health and safety legislation. The provisions of the Health & Safety at Work etc. Act and the Control of Substances Hazardous to Health Regulations apply to the use of this product at work. 28 After contact with skin, wash immediately with plenty of water. 7/9 Keep container tightly closed and in a well ventilated place 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. Do not breathe Vapour or Spray The information contained in this Safety Data Sheet does not constitute the user’s own assessment of the workplace risks as required by other health and safety legislation. The provisions of the Health & Safety at Work etc. Act and the Control of Substances Hazardous to Health Regulations apply to the use of this product at work. 46 If swallowed seek medical advice immediately and show this container or label. 7 Keep container tightly closed 9 Keep container in a well ventilated place 2 Keep out of reach of children Do not breathe Vapour or Spray The information contained in this Safety Data Sheet does not constitute the user’s own assessment of the workplace risks as required by other health and safety legislation. The provisions of the Health & Safety at Work etc. Act and the Control of Substances Hazardous to Health Regulations apply to the use of this product at work. 9804/8981 ISSUE 2, (REV.) MARCH 1997 2: Keep out of the reach of children. 16: Keep away from sources of ignition - No Smoking. 23: Do not breathe vapour/spray. 51: Use only in well ventilated areas. Regulatory references: The Chemicals (Hazard Information and Packaging) Regulations 1994 and CHIP 1996 amendment. Not applicable Not applicable None S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Directives 88/379/EEC and 91/155/EEC have been considered when compiling this SDS; the information is provided for health and safety assessment by an industrial user. Reference should be made to any relevant local or national health, safety, and environmental legislation. This information does not constitute indication of suitability for specific uses. S9 Keep container in a well-ventilated place. S16 Keep away from sources of ignition - No smoking. S23 Do not inhale vapours/spray. S33 Take precautionary measures against static discharges. (Aerosol Text) None S9 - Keep container in a well-ventilated place S16 - Keep away from sources of ignition - No smoking. S33 - Take precautionary measures against static discharges Directives 88/379/EEC and 91/155/EEC have been considered when compiling this SDS; the information is provided for health and safety assessment by an industrial user. Reference should be made to any relevant local or national health, safety, and environmental legislation. This information does not constitute indication of suitability for specific uses. S9 - Keep container in a well ventilated place. S16 - Keep away from sources of ignition - No smoking. S23 - Do not breathe gas/fumes/vapour/spray. S51 - Use only in well ventilated areas. EINICS: All components of this product are listed in EINECS or ELINCS Directives 88/379/EEC and 91/155/EEC have been considered when compiling this document; the information is provid-ed for health and safety assessment by an industrial user. Reference should be made to any relevant local or national health, safety, and environmental legislation. This information does not constitute indication of suitability for specific uses. 9804/9007 ISSUE 2, SEPTEMBER 2001 Evacuate personnel. Extinguish naked lights and any source of ignition. Wear breathing apparatus. Wear appropriate personal protection gear - see section 8. Environmental Procedure: Prevent entry into drains. If material has entered drains notify local authorities (Fire Service). Clean up Procedure: Absorb or contain with earth, sand or suitable absorbent material. Remove to suitable outside containment area. Leave to degrade and evaporate. 7. HANDLING AND STORAGE Keep out or reach of children. Store away from sources of ignition. Use in a well ventilated area, away from sources of ignition. Seal container tightly after use. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Wear goggles or safety classes. Wear protective gloves (Rubber or Plastic). Respiratory protection if misting, poor ventilation or high concentrations (e.g. spillage) are present. Consult BS2901. Avoid breathing mist or spray. 9. PHYSICAL AND CHEMICAL PROPERTIES The properties in this section are typical and may be varied or updated to reflect changes in product design at any time. Property Typical Analysis Appearance: Yellow/Straw Liquid Flash Point: 79 deg C Odour: Mild hydrocarbon Relative Density: 0.795 10. STABILITY AND REACTIVITY Stable under normal conditions. Thermal decomposition will produce oxides of carbon. High temperatures can cause evaporation leading to flammable or explosive mixtures with air. Avoid contact with hot surfaces or sources of ignition. 9804/9020 ISSUE1, JANUARY 2002 2 Keep out of the reach of children. 46 If swallowed, seek medical advice immediately and show this container or label. 28 After contact with skin,wash immediately with plenty of water 7/9 Keep container tightly closed and in a well ventilated place 36/37/39 Wear suitable protective clothing, gloves and eye/face protection The information contained in this Safety Data Sheet does not constitute the user’s own assessment of workplace risks as required by other health and safety legislation. The provisions of the Health and Safety at Work etc. Act and the Control of Substances Hazardous to Health Regulations apply to the use of this product at work. 9804/9023 ISSUE 1, JANUARY 2002 28 After contact with skin,w ash immediately with plenty of water. 7/9 Keep container tightly closed and in a well ventilated place. 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. Do not breathe Vapour or Spray. FOR USE IN INDUSTRIAL INSTALLATIONS ONLY The information contained in this Safety Data Sheet does not constitute the user’s own assessment of the workplace risks as required by other health & safety legislation. The provisions of the Health & Safety at Work etc. Act and the Control of Substances Hazardous to Health Regulations apply to the use of this product at work. S-2 Keep out of reach of children. S-16 Keep away from sources of ignition - No Smoking. S-23A Do not breathe vapour/spray. S-51 Use only in well ventilated areas. UK Regulatory References: The Control of Substances Hazardous to Health Regulations 1988. Chemicals (Hazard Information & Packaging) Regulations 1993. UK Environmental Listings: Rivers (Prevention of Pollution) Act 1961. Control of Pollution (Special Waste Regulations) Act 1980. Statutory Instruments: Chemicals (Hazard Information and Packaging) Regulations. Approved Code of Practice: Classification and Labelling of Substances and Preparations Dangerous for Supply. Guidance Notes: Occupational Exposure Limits EH40. Introduction to Local Exhaust Ventilation HS(G)37. CHIP for everyone HSG(108). 28 After contact with skin, wash immediately with plenty of water 7/9 Keep container tightly closed and in a well ventilated place 36/37 Wear suitable protective clothing and gloves. Do not breathe Vapour or Spray 28 After contact with skin, wash immediately with plenty of water 7/9 Keep container tightly closed and in a well ventilated place 36/37/39 Wear suitable protective clothing, gloves and eye/face protection Do not breathe Vapour or Spray The information contained in this Safety Data Sheet does not constitute the user’s own assessment of the workplace risks as required by other health and safety legislation. The provisions of the Health and Safety at Work etc. Act and the Control of Substances Hazardous to Health Regulations apply to the use of this product at work. 9804/9031 ISSUE1, JANUARY 2002 S24 - Avoid contact with skin. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S37 - Wear suitable gloves. EEC label information: Contains epoxy constituents. See information supplied by the manufacturer. Hardener EEC Hazard classification: None Directives 88/379/EEC and 91/155/EEC have been considered when compiling this SDS; the information is provided for health and safety assessment by an industrial user. Reference should be made to any relevant local or national health, safety, and environmental legislation. This information does not constitute indication of suitability for specific uses. Reduce fire hazards by arranging and setting up machines and equipment so as to avoid accidental spill and splasher onto hot machine parts and electrical contacts. Avoid prolonged or repeated skin contact with the product and product-stained clothing, which may lead to skin rashes and eruptions, particularly in case of pen cuts or scratches. Avoid splashes and spills. If the product has been in contact with the skin, wash the affected area immediately and repeatedly with soap and water. Use no abrasives, solvents or petroleum spirits. Do not use cloths stained with the product to dry hands. If clothing becomes stained, change immediately. Do not inhale vapours while handling the product. Do not eat, drink or smoke while handling the product. - Safe handling advice: Avoid contact with strong oxidising agents. Use only hydrocarbon-resistant containers, joints, pipes etc. 46 If swallowed seek medical advice immediately and show this container or label. 7/9 Keep container tightly closed and in a well ventilated place 2 Keep out of reach of children 43 In case of fire do not use water Do not breathe vapour or spray Contains lead. Should not be used on surfaces that are liable to be chewed or sucked by children. Hardener 28 After contact with skin, wash immediately with plenty of water 7/8 Keep container tightly closed and dry 24/25 Do not breathe vapour or spray FOR USE IN INDUSTRIAL INSTALLATIONS ONLY The information contained in this Safety Data Sheet does not constitute the user’s own assessment of the workplace risks as required by other health and safety legislation. The provisions of the Health and Safety at Work etc. Act and the Control of Substances Hazardous to Health Regulations apply to the use of this product at work. 9804/9035 ISSUE 1, MARCH 2002 S24 - Avoid contact with skin. Cont’d..... 9804/9025 ISSUE 2, SEPTEMBER 2002 Avoid contact with skin. Do not breathe gas/fumes/vapour/spray. Take precautionary measures against static discharges. In case of accident or if you feel unwell seek medical advice immediately (show the label where possible). Use only in well-ventilated areas. Contains isocyanates. See information supplied by the manufacturer. Keep out of reach of children. Do not breathe gas/fumes/vapour/spray. If swallowed seek medical advice immediately and show this container or label. Contains isocyanates. See information supplied by the manufacturer. Not Classified. Statutory Instruments: Chemicals (Hazard Information and Packing) Regulations. Approved Code of Practice: Classification and Labelling of Substances and Preparations Dangerous for Supply. Guidance Notes: Occupational Exposure Limits EH40. Introduction to Local Exhaust Ventilation HS(G)37. CHIP for everyone HSG(108). *

Transport classification

ICAO/IATA - DGR : IMO/IMDG - Code : RID/ADR : Hazard labelling : UK CPL/EEC classification : Not applicable ICAO/IATA - DGR : IMO/IMDG - Code : RID/ADR : Hazard labelling : UK CPL/EEC classification : Flammable/Harmful ICAO/IATA - DGR : Not classified IMO/IMDG - Code : Not classified RID/ADR : Not classified Hazard labelling : UK CPL/EEC classification : Not applicable Base: Base: Base:

IATA CLASSIFICATION

Not classified as dangerous. IMDG Classification: Not classified as dangerous. ADR/RID: Not classified as dangerous. *15. REGULATORY INFORMATION EC Indication of Danger: IRRITANT EC Symbol: Proper Shipping Name: Aviation Regulated Liquid n.o.s. (applies only to inner containers >1 litre) Technical Name: Proper Shipping Name: Aerosols, Flammable, N.O.S. Not classified as dangerous. IMDG Classification: Not classified as dangerous. ADR/RID: Not classified as dangerous. *15. REGULATORY INFORMATION EC Indication of Danger: HARMFUL EC Symbol: Not applicable Marine Pollutant: No U.N. Number (S.I.N.): Not applicable U.N. Class, Packing Group: Not applicable 15. REGULATORY INFORMATION EEC Hazard Classification: None Directives 88/379/EEC and 91/155/EEC have been considered when compiling this SDS; the information is provided for health and safety assessment by an industrial user. Reference should be made to any relevant local or national health, safety, and environmental legislation. This information does not constitute indication of suitability for specific uses. Not applicable Marine Pollutant: No U.N. Number (S.I.N.): Not applicable U.N. Class, Packing Group: Not applicable 15. REGULATORY INFORMATION EEC Hazard Classification: None Directives 88/379/EEC and 91/155/EEC have been considered when compiling this SDS; the information is provided for health and safety assessment by an industrial user. Reference should be made to any relevant local or national health, safety, and environmental legislation. This information does not constitute indication of suitability for specific uses. Not applicable Marine Pollutant: No U.N. Number (S.I.N.): Not applicable U.N. Class, Packing Group: Not applicable 15. REGULATORY INFORMATION EEC Hazard Classification: None Directives 88/379/EEC and 91/155/EEC have been considered when compiling this SDS; the information is provided for health and safety assessment by an industrial user. Reference should be made to any relevant local or national health, safety, and environmental legislation. This information does not constitute indication of suitability for specific uses. Not applicable Marine Pollutant: No U.N. Number (S.I.N.): Not applicable U.N. Class, Packing Group: Not applicable 15. REGULATORY INFORMATION EEC Hazard Classification: Irritant Rick Phrases: R36 - Irritating to eyes Not classified as dangerous. IMDG Classification: Not classified as dangerous. ADR/RID: Not classified as dangerous. *15. REGULATORY INFORMATION EC Indication of danger: IRRITANT EC Symbol: Not applicable U.N. Number (S.I.N.): Not applicable U.N. Class, Packing Group: Not applicable 9804/8982 ISSUE 2, SEPTEMBER 1995 Loctite International SDS 178061 NBD - Health & Regulatory Affairs Safety Data Sheet - Made For JCB By Loctite Revision Date: 22/06/93 1. PRODUCT IDENTIFICATION 1.1. Product Name JCB Cleaner and Degreaser - Part No. 4104/1538 (Loctite 7061) 1.2. Company Name Manufacturer : LOCTITE (Ireland) Limited Local Distributor : Loctite UK 1.3. Emergency Contact (24 Hour Service): First Call Local Distributor Tel - 0707 331277 Contact Name : Health & Safety Officer Manufacturer Tel +353-1-510433 or +353-1-519466, Fax +353-1-519073 2. COMPOSITIONAL INFORMATION Nature : Solvent-based surface treatment for use with certain Loctite adhesive. Component % by Wt* 3 Marine Pollutant: No U.N. Number (S.I.N.): 3295 U.N. Class, Packing Group: 11 15. REGULATORY INFORMATION EEC Hazard Classification: Highly Flammable Not classified as dangerous. IMDG Classification: Not classified as dangerous. ADR/RID: Not classified as dangerous. *15. REGULATORY INFORMATION EC Indication of Danger: IRRITANT EC Symbol Not restricted Marine pollutant: No Proper Shipping Name: Environmentally hazardous substance, liquid N.O.S. Technical Name: Not classified as dangerous IMDG Classification Not classified as dangerous ADR/RID Classification Not classified as dangerous 15. REGULATORY INFORMATION Resin EC Indication of Danger Dangerous for the environment Irritant

Hazard categories

9 U.N. Number: UN3334 Packaging Group: N/A IMDG CLASSIFICATION: Not classified as dangerous. ADR/RID: Not classified as dangerous. *15. REGULATORY INFORMATION EC Indication of danger: IRRITANT EC Symbol: 2.1 Subsidiary Hazard Class: U.N. Number: UN1950 Packaging Group: IMDG CLASSIFICATION Proper Shipping Name: Aerosols 2.1 Subsidiary Hazard Class: U.N. Number: UN1950 Packaging Group: ADR/RIN Proper Shipping Name: Aerosols 2.1 Subsidiary Hazard Class: U.N. Number: UN1950 *15. REGULATORY INFORMATION EC Indication of Danger: IRRITANT FLAMMABLE EC Symbol: (1f >EC limit) Polyethyleneglycol dimethacrylate 70 - Polyethyleneglycol di-aliphatic saturated ester 40 - Polyester thickener 30 - Saccharin 4.0 - Diethyl and dimethyl toluidine 1.5 T, R23/24/25, 33 Organic peroxide 4.0 O, C, Xn, R7-20/22-34 PHYSICAL PROPERTIES Appearance : Thixotropic, Green Paste * Specific gravity : 1.08 g/ml at 20 °C Odour : Mild characteristic * Melting point : NA pH : 3 - 6 * Pour point : NA * Viscosity : NA * Boiling point : > 200 °C * Flash point (Closed cup) : >100 °C * Solubility : Immiscible * Vapour pressure : mm Hg at 20 °C: < 0.1 *To be interpreted within the meaning of Directive 67/548/EEC. HEALTH HAZARD DATA Effects of over exposure : An allergic reaction can occur when the product comes in contact with damaged skin. Not considered to be an eye irritant. Occupational exposure limit : NA SPECIAL PROTECTION INFORMATION Eye protection : No special equipment required. Skin protection : No special equipment required, use of applicators recommended to avoid contact with damaged skin. Respiratory protection : No special equipment required. EMERGENCY & FIRST AID PROCEDURES Eye contact : Flush with water for at least 15 mins SEEK MEDICAL ADVICE. Skin contact : Wash contact area with soap and water. Inhalation : If inhalation of vapours excessive, remove patient to fresh air. Ingestion : Give plenty of milk or water to drink. DO NOT INDUCE VOMITING. FIRE & EXPLOSION HAZARD DATA Flash point : > 100 °C IP Classification : Unclassified Flammable limits : LEL : UEL : Extinguishing media : Dry powder, foam, CO2 Special fire fighting procedures: None 9804/8934 ISSUE 2, SEPTEMBER 1995 Page 1 of 2 9804/8934 ISSUE 2, SEPTEMBER 1995 REACTIVITY DATA Stability (thermal, light, etc.) : Stable under normal conditions of use. Conditions to avoid : Extreme heat. Incompatibility (materials to avoid) : NA Hazardous decomposition products : NA Hazard polymerisation : NA SPILLAGE LEAKAGE AND WASTE DISPOSAL PROCEDURES Environmental impact : No information available. Procedures if material is released or spilled : Ventilate area. Large spills absorb into inert absorbant material, place in container for disposal. Small spills wipe up with paper towel and place in container for disposal. Waste disposal : In accordance with local and national regulations. ADDITIONAL HANDLING AND STORAGE INFORMATION Store only in the original containers or applicators, to avoid contamination never return residual unused product to original container. Storage temperature range 5 - 28 °C. TOXICOLOGICAL DATA Oral toxicity : Considered to be low toxicity, having an acute oral LD50 (rat) > 5000 mg/kg by analogy to other simi- lar products. Dermal toxicity : Non toxic - can cause allergic reaction to damaged skin. Inhalation toxicity : Non toxic - under normal condition of use. Eye irritation : Non toxic Skin irritation : Non toxic SUBCHRONIC TOXICOLOGY (SUMMARY) : NA CHRONIC TOXICOLOGY (SUMMARY) : NA OTHER TOXICOLOGY DATA : NA REGULATORY INFORMATION (If>EC limit) Polyethyleneglycol dimethacrylate 60 --- Polyethyleneglycol dialkyl ester 20 --- Long chain monomethacrylate 10 Xi, R36/38 Thickeners + fillers (including PTFE) 3 --- Organic peroxide 0.6 O,C, Xn, R7-20/22-34 Silicon dioxide type thixotrope 5 --- Dyes, stabilisers + other minor constituents 6 --- Substituted Hydrazide 0.9 T. R23/24/25, 33, 36/38, 43 * (percentages are less than those given.) This product is not classified as hazardous. 9804/8984 ISSUE 2, SEPTEMBER 1995 Page 1 of 4 9804/8984 ISSUE 2, SEPTEMBER 1995 SDS 128249 4. FIRST AID MEASURES Inhalation: Should not be a problem as product is of low volatility. However, if feeling unwell, remove patient to fresh air. Skin Contact: Wash skin with plenty of soap and water. Eye Contact: Flush eyes immediately with plenty of water for at least 15 minutes. Ingestion Rinse mouth with water, then give plenty of water or milk to drink. Do not induce vomiting. 5. FIRE FIGHTING MEASURES Non flammable product (flash point is greater than 100°C (CC)). If product is involved in fire extinguish with dry powder, foam or carbon dioxide. Trace amounts of toxic fumes may be released on incineration and the use of breathing apparatus is recommended. 6. ACCIDENTAL RELEASE MEASURES For small spills wipe up with paper towel and place in container for disposal. For large spills absorb onto inert absorbent material and place in sealed container for disposal. 7. HANDLING & STORAGE 7.1. Handling: Loctite applicators are recommended to minimise skin contact particularly where workers are handling sharp or threaded parts which might result in microlaceration of sensitive areas of the skin. Prolonged or repeated skin contact should be avoided. (If>EC limit) Acetone 75 F, R11 Ethanol 35 F, R11 * (percentages are less than those given.) This product is highly flammable as flash point is approx. - 18°C. Solvent will have a defatting action on the skin making it more susceptible to dermatitis and sensitisation. Inhalation of vapour may cause headaches or dizziness. The aerosol container is under pressure. Do not expose to high temperatures. Explosive limits in air are 2.5 - 13%. 9804/8982 ISSUE 2, SEPTEMBER 1995 Page 1 of 4 9804/8982 ISSUE 2, SEPTEMBER 1995 SDS 178061 4. FIRST AID MEASURES Inhalation: Remove affected person to fresh air. Skin Contact: Wash skin with plenty of soap and water and apply replenishing cream if necessary. Eye Contact: Flush eyes immediately with plenty of water for at least 15 minutes. Seek medical attention immediately. Ingestion Rinse mouth with water, then give plenty of water or milk to drink. Do not induce vomiting. 5. FIRE FIGHTING MEASURES This product is highly flammable having a flash point of Keep unaffected containers cool with water spray. Aerosol containers may explode when exposed to high temperatures. If product is involved in fire extinguish with dry powder, foam or carbon dioxide. 6. ACCIDENTAL RELEASE MEASURES Ventilate area. Eliminate sources of ignition. For large spillages wear gloves and eye protection. Absorb spillage into inert absorbent material and place into sealed container for disposal. 7. HANDLING & STORAGE 7.1. Handling Avoid sources of ignition - no smoking. Vapours should be extracted to avoid inhalation. 2.1 U.N. Number (S.I.N.): 1950, Forbidden for air transport Packaging group: N/A IMDG Classification proper shipping name: Aerosols, Flammable. 2.1 Subsidiary hazard class U.N.Number: UN1950 Packaging group: N/A ADR/RID Proper shipping name: Aerosols, Flammable 2.1 Subsidiary hazard class U.N.Number: UN1950 Packaging group: N/A ADR Item number: Item 5 F 15. REGULATORY INFORMATION EC Indication of danger: Irritant extremely flammable EC symbol: 2 x symbols - a broad cross diagonally and another box with the flame emblem. 9 Subsidiary Hazard Class: U.N. Number: UN3082 Packaging Group: III IMDG Classification Proper Shipping Name: Environmentally hazardous substance, liquid N.O.S. Technical Name: 9 Subsidiary Hazard Class: U.N. Number: UN3082 Packaging Group: III ADR/RID Classification Proper Shipping Name: Environmentally hazardous substance, liquid N.O.S. Technical Name: 9 Subsidiary Hazard Class: U.N. Number: UN3082 Packaging Group: III Resin

Medical Conditions Generally Aggravated by Exposure

Repeated overexposure may aggravate an existing kidney disease Because of its irritating properties, repeated skin contact may aggravate an existing dermatitis (skin condition). Effects of exposure to the environment: Believed not to be toxic to aquatic species. * 4. FIRST-AID MEASURES Because of its defatting properties, prolonged and repeated skin contact may aggravate an existing dermatitis (skin condition). Effects of Exposure to the Environment May form an oil film leading to deoxygenation of water and possible harmful effects on aquatic life. 4. FIRST-AID MEASURES

Principle Routes of Exposure

Inhalation: If irritation, headache, nausea, or drowsiness occurs, remove to fresh air. Get medical attention if breathing becomes difficult or symptoms persist. Skin contact: Wash skin with plenty of soap and water for several minutes. Get medical attention if skin irritation develops or persists. Eye contact: Immediately flush eyes with plenty of water for at least 15 minutes. Hold eyelids apart while flushing to rinse entire surface of eye and lids with water. Get medical attention. Ingestion: Get immediate medical attention. If person is conscious and can swallow, immediately give two glasses of water (500 ml) but do not induce vomiting. If vomiting occurs, give fluids again. Have physician determine if condition of person will permit induction of vomiting or evacuation of stomach. Do not give anything by mouth to an unconscious or convulsing person. Other recommendations: Ethylene glycol poisoning may initially produce behaviour changes, drowsiness, vomiting, diarrhoea, thirst and convulsions. Renal damage or failure with metabolic acidosis are late signs or poisoning. Immediate treatment may reduce toxic effects, supplemented, if necessary with haemodialysis. Intravenous ethanol in sodium bicarbonate solution is a recognised antidote. Contact a poison centre for further treatment information. * 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media: Use water fog, dry powder, foam, or carbon dioxide. Water or foam may cause frothing. Use water to cool fire-exposed containers. If a leak or spill has not ignited, use water fog to disperse the vapours and to provide protection for persons attempting to stop the leak. Extinguishing media which must not be used for safety reasons: Water jet. Special exposure hazards arising from the substance or preparation itself, combustion products, resulting gases: None Special protective The nature of special protective equipment required will depend upon the size of the equipment for firefighters: fire, the degree of confinement of the fire and the natural ventilation available. Fire resistant clothing and self-contained breathing apparatus is recommended for fires in confined spaces and poorly-ventilated areas. Full fire-proof clothing is recommended for any large fires involving this product. 9804/8892 ISSUE 4*, OCTOBER 2001 Eyes Symptoms: Irritation. Treatment: Irrigate immediately and thoroughly with water (or sterile isotonic solution) for at least 10 minutes. Obtain prompt medical attention. Skin Symptoms: Slight irritation/dryness. Treatment: Wash thoroughly with soap and water. Inhalation (Mist or Spray) Symptoms: Irritation to mouth, throat and trachea. Treatment: Not applicable. Likely occurrence negligible or not possible. Ingestion Symptoms: Nausea/discomfort. Treatment: Do not induce vomiting. Wash mouth with water. Seek immediate medical advice preferably showing data sheet or label. 5. FIRE-FIGHTING MEASURES JCB Plantwash is non-combustible. Extinguishing Media: Not special requirements. Special Exposure Hazards: Fire may result in spillage/release which can cause personal exposure hazard. Refer to section 8. Thermal decomposition at high temperatures or due to direct involvement in fire will produce oxides of carbon and nitrogen (trace). Special Precautions: Wear breathing apparatus. 6. ACCIDENTAL RELEASE MEASURES Eye contact Effects of Chronic Exposure: Although this product has not been tested for chronic effects it is judged as having a low order of toxicity based on components information. Use of good industrial hygiene practices is recommended. Target Organs: Not applicable Special Health Effects: None known Eye contact Effects of Chronic Exposure: Although this product has not been tested for chronic effects it is judged as having a low order of toxicity based on component information. Use of good industrial hygiene practices is recommended. Target Organs: Not applicable Special Health Effects: None known 9804/8999 ISSUE 2 (REV), JUNE 2002 Eye contact Effects of Chronic Exposure: Although this product has not been tested for chronic effects it is judged as having a low order of toxicity based on component information. Use of good industrial hygiene practices is recommended. Target Organs: Not applicable Special Health Effects: None known Eye contact Effects of Chronic Exposure: Although this product has not been tested for chronic effects it is judged as having a low order of toxicity based on component information. Use of good industrial hygiene practices is recommended. Target Organs: Not applicable Special Health Effects: None known Inhalation; Skin contact; Eye contact; Ingestion Effects of Chronic Exposure: Not established. Target Organs: None known. Special Health Effects: None known. Skin contact Effects of Chronic Exposure: Although this product has not been tested for chronic effects it is judged as having a low order of toxicity based on component information. Use of good industrial hygiene practices is recommended. Target Organs: Not applicable Special Health Effects: None known Inhalation If irritation, headache, nausea, or drowsiness occurs, remove to fresh air. Get medical attention if breathing becomes difficult or symptoms persist. Skin Contact Wash skin with plenty of soap and water for several minutes. Get medical attention if skin irritation develops or persists. Eye Contact Flush eyes with plenty of water for several minutes. Get medical attention if eye irritation persists. Ingestion Do not induce vomiting. Get medical attention. Never give anything by mouth to an unconscious or convulsing person. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use water fog, dry powder, foam or carbon dioxide. Use water to cool fire-exposed containers. If a leak or spill has not ignited, use water fog to disperse the vapours and to provide protection for persons attempting to stop the leak. Extinguishing media which must not be used for safety reasons Water jet. Special exposure hazards arising from the substance of preparation itself, combustion products, resulting gases None. Special Protective Equipment for Firefighters The nature of special protective equipment required will depend upon the size of the fire, the degree of confinement of the fire and the natural ventilation available. Fire-resistant clothing and self-contained breathing apparatus is recommended for fires in confined spaces and poorly-ventilated areas. Full fire-proof clothing is recommended for any large fires involving this product. In case of fire - Always call the fire brigade. Small fires, such as those capable of being fought with a hand-held extinguisher, can normally be fought by a person who has received instruction on the hazards of flammable liquid fire. Fires that are beyond that stage should only be tackled by people who have received hands-on training. Ensure escape path is available. 6. ACCIDENTAL RELEASE MEASURES Procedures in Case of Accidental Release or Leakage: Contain spill if possible. Wipe up or absorb on suitable material and shovel up. Prevent liquid run-off from entering waterways and sewer systems. 9804/9011 ISSUE 4, (REV) MARCH 2003 EYES Symptoms: Irritation Treatment: Rinse immediately and thoroughly with water for a few minutes, then seek medical advice. SKIN Symptoms: Slight irritation/dryness. Treatment: Wash thoroughly with soap and plenty of water. Remove contaminated clothing and wash before re- use. Seek medical attention if adverse skin reaction occurs. Cont’d 9804/9020 ISSUE1, JANUARY 2002 INHALATION (Mist or Spray) Symptoms: Drowsiness. Treatment: If affected remove from exposure to well ventilated area. Rest and keep warm. If recovery is not rapid or if feeling unwell then seek medical attention. INGESTION Symptoms: Nausea/discomfort. Treatment: Do not induce vomiting. Wash mouth with water. Seek immediate medical advice preferably showing data sheet or label. 5. FIRE-FIGHTING MEASURES JCB PDI Enhancer: JCB PDI/Enhancer is combustible. Extinguishing media: Water fog, dry powder, carbon dioxide or vapourising liquids. Special Exposure Hazards: Thermal decomposition at high temperatures or due to direct involvement in air will produce oxides of carbon. Special Precautions: Wear breathing apparatus. Spray containers with water to keep cool. 6. ACCIDENTAL RELEASE MEASURES Inhalation. Skin and/or eye contact. Skin contact; Eye contact Effects of chronic exposure: Although this product has not been tested for chronic effects it is judged as having a low order of toxicity based on component information. Use of good industrial hygiene practices is recommended. Target organs: Skin Special health effects: Sensitiser Hardener Not known. Effects of chronic exposure: Although this product has not been tested for chronic effects it is judged as having a low order of toxicity based on component information. Use of good industrial hygiene practices is recommended. Target organs: Not Applicable. Special health effects: None known.

Remarks

Releases of small quantities are unlikely to affect adversely the functioning of water treatment plants. * 13. DISPOSAL CONSIDERATIONS Believed not to represent a long-term danger to the aquatic environment. WGK=1 13. DISPOSAL CONSIDERATIONS 1987 Alcohols, n.o.s., (ethanol and isopropanol), 3, II, ADR 15. REGULATORY INFORMATION EC supply labelling Class EEC label name:

Product definition

Solvent wipe adhesion promoter for use with JCB sealants/adhesives. Manufacturer: Sika Limited, Watchmead, Welwyn Garden City, Hertfordshire. AL7 1BQ. Phone Number: 0(1)707 394444 Fax Number: 0(1)707 329129 2. COMPOSITION/INFORMATION ON INGREDIENTS Preparation - Hazardous Components Component Min % Max % One component moisture curing polyurethane based adhesive/sealant. Manufacturer: Sika Limited, Watchmead, Welwyn Garden City, Hertfordshire. AL7 1BQ. Phone Number: 0(1)707 394444 Fax Number: 0(1)707 329129 Preparation - Hazardous Components Component Min % Max % One component moisture curing polyurethane based adhesive/sealant. Manufacturer: Sika Limited, Watchmead, Welwyn Garden City, Hertfordshire. AL7 1BQ. Phone Number: 0(1)707 394444 Fax Number: 0(1)707 329129 2. COMPOSITION/INFORMATION ON INGREDIENTS Preparation - Hazardous Components Component Min % Max %

Non Hazardous Components

None 10-25 1-Methoxy Propan-2-ol Acetate 108-65-6 None 1-5 Aromatic hydrocarbon (contains <0.1% benzene) 64742-95-6 Xn 22 Eye contact: Irritating to eyes. Skin contact: Slight skin irritant. Prolonged or repeated contact can cause dermatitis. Inhalation: High levels of vapour/mist may cause dizziness. Can cause irritation of the respiratory tract. Ingestion: Accidental ingestion is an unlikely event. 9804/8951 ISSUE 2 (REV.), APRIL 1997 4. FIRST-AID MEASURES Eye contact: Contact lenses should be removed. Irrigate copiously with clean, fresh water for at least 10 minutes, holding the eyelids apart, and seek medical advice. Skin contact: Remove contaminated clothing. Wash skin thoroughly with soap and water or use a proprietary skin cleaner. DO NOT use solvents or thinners. If in doubt, seek medical advice. Inhalation: Remove to fresh air, keep the patient warm and at rest. If breathing is irregular or has stopped, administer artificial respiration. Give nothing by mouth. If unconscious, place in the recovery position and seek medical advice. Ingestion: If accidentally swallowed, obtain immediate medical attention. Keep at rest. DO NOT induce vomiting. 5. FIRE-FIGHTING MEASURES Extinguishing media: Alcohol resistant foam; CO2; powder; water spray/mist. Do not use: Water jet. Special fire fighting procedures: Fire exposed containers should be sprayed with water to lesson risk of explosion. Unusual fire and explosion hazards: Fire will produce dense black smoke containing combustion products which may be a health hazard. Appropriate self-contained breathing apparatus may be required. Run off from fire must not enter drains. 6. ACCIDENTAL RELEASE MEASURES Procedures for leaks or spillage: Exclude sources of ignition and ventilate the area. Exclude non-essential personnel. Avoid breathing vapours. Refer to protective measures listed in Sections 7 & 8. Contain and collect spillages with non-combustible absorbent materials, e.g. sand, earth, vermiculite, diatomaceous earth and place in a suitable container for disposal in accordance with waste regulations (see Section 13). Do not allow to enter drains or water courses. Clean preferably with a detergent; avoid the use of solvents. If the product enters drains or sewers, the local water company should be contacted immediately; in the case of contamination of streams, rivers or lakes, the National Rivers Authority. 7. HANDLING AND STORAGE Handling: Vapours are heavier than air and may spread along floors. They may form explosive mixtures with air. Prevent the creation of flammable or explosive concentrations of vapour in air and avoid vapour concentrations higher than the occupational exposure limits. Use only in areas from which all sources of heat, sparks and open flame have been excluded. Avoid skin and eye contact. Avoid inhalation of vapour and spray mist. Smoking, eating and drinking should be prohibited in areas of use and storage. None 10-25 1-Methoxy Propan-2-ol Acetate 108-65-6 None 1-5 Aromatic hydrocarbon (contains <0.1% benzene) 64742-95-6 Xn 22 Eye contact: Irritating to eyes. Skin contact: Slight skin irritant. Prolonged or repeated contact can cause dermatitis. Inhalation: High levels of vapour/mist may cause dizziness. Can cause irritation of the respiratory tract. Ingestion: Accidental ingestion is an unlikely event. 9804/8953 ISSUE 2 (REV.), APRIL 1997 4. FIRST-AID MEASURES Eye contact: Contact lenses should be removed. Irrigate copiously with clean, fresh water for at least 10 minutes, holding the eyelids apart, and seek medical advice. Skin contact: Remove contaminated clothing. Wash skin thoroughly with soap and water or use a proprietary skin cleaner. DO NOT use solvents or thinners. If in doubt, seek medical advice. Inhalation: Remove to fresh air, keep the patient warm and at rest. If breathing is irregular or has stopped, administer artificial respiration. Give nothing by mouth. If unconscious, place in the recovery position and seek medical advice. Ingestion: If accidentally swallowed, obtain immediate medical attention. Keep at rest. DO NOT induce vomiting. 5. FIRE-FIGHTING MEASURES Extinguishing media: Alcohol resistant foam; CO2; powder; water spray/mist. Do not use: Water jet. Special fire fighting procedures: Fire exposed containers should be sprayed with water to lesson risk of explosion. Unusual fire and explosion hazards: Fire will produce dense black smoke containing combustion products which may be a health hazard. Appropriate self-contained breathing apparatus may be required. Run off from fire must not enter drains. 6. ACCIDENTAL RELEASE MEASURES Procedures for leaks or spillage: Exclude sources of ignition and ventilate the area. Exclude non-essential personnel. Avoid breathing vapours. Refer to protective measures listed in Sections 7 & 8. Contain and collect spillages with non-combustible absorbent materials, e.g. sand, earth, vermiculite, diatomaceous earth and place in a suitable container for disposal in accordance with waste regulations (see Section 13). Do not allow to enter drains or water courses. Clean preferably with a detergent; avoid the use of solvents. If the product enters drains or sewers, the local water company should be contacted immediately; in the case of contamination of streams, rivers or lakes, the National Rivers Authority. 7. HANDLING AND STORAGE Handling: Vapours are heavier than air and may spread along floors. They may form explosive mixtures with air. Prevent the creation of flammable or explosive concentrations of vapour in air and avoid vapour concentrations higher than the occupational exposure limits. Use only in areas from which all sources of heat, sparks and open flame have been excluded. Avoid skin and eye contact. Avoid inhalation of vapour and spray mist. Smoking, eating and drinking should be prohibited in areas of use and storage. None 10-25 1-Methoxy Propan-2-ol Acetate 108-65-6 None 1-5 Aromatic hydrocarbon (contains <0.1% benzene) 64742-95-6 Xn 22 Eye contact: Irritating to eyes. Skin contact: Slight skin irritant. Prolonged or repeated contact can cause dermatitis. Inhalation: High levels of vapour/mist may cause dizziness. Can cause irritation of the respiratory tract. Ingestion: Accidental ingestion is an unlikely event. 9804/8954 ISSUE 2 (REV.), APRIL 1997 4. FIRST-AID MEASURES Eye contact: Contact lenses should be removed. Irrigate copiously with clean, fresh water for at least 10 minutes, holding the eyelids apart, and seek medical advice. Skin contact: Remove contaminated clothing. Wash skin thoroughly with soap and water or use a proprietary skin cleaner. DO NOT use solvents or thinners. If in doubt, seek medical advice. Inhalation: Remove to fresh air, keep the patient warm and at rest. If breathing is irregular or has stopped, administer artificial respiration. Give nothing by mouth. If unconscious, place in the recovery position and seek medical advice. Ingestion: If accidentally swallowed, obtain immediate medical attention. Keep at rest. DO NOT induce vomiting. 5. FIRE-FIGHTING MEASURES Extinguishing media: Alcohol resistant foam; CO2; powder; water spray/mist. Do not use: Water jet. Special fire fighting procedures: Fire exposed containers should be sprayed with water to lessen risk of explosion. Unusual fire and explosion hazards: Fire will produce dense black smoke containing combustion products which may be a health hazard. Appropriate self-contained breathing apparatus may be required. Run off from fire must not enter drains. 6. ACCIDENTAL RELEASE MEASURES Procedures for leaks or spillage: Exclude sources of ignition and ventilate the area. Exclude non-essential personnel. Avoid breathing vapours. Refer to protective measures listed in Sections 7 & 8. Contain and collect spillages with non-combustible absorbent materials, e.g. sand, earth, vermiculite, diatomaceous earth and place in a suitable container for disposal in accordance with waste regulations (see Section 13). Do not allow to enter drains or water courses. Clean preferably with a detergent; avoid the use of solvents. If the product enters drains or sewers, the local water company should be contacted immediately; in the case of contamination of streams, rivers or lakes, the National Rivers Authority. 7. HANDLING AND STORAGE Handling: Vapours are heavier than air and may spread along floors. They may form explosive mixtures with air. Prevent the creation of flammable or explosive concentrations of vapour in air and avoid vapour concentrations higher than the occupational exposure limits. Use only in areas from which all sources of heat, sparks and open flame have been excluded. Avoid skin and eye contact. Avoid inhalation of vapour and spray mist. Smoking, eating and drinking should be prohibited in areas of use and storage. None 10-25 1-Methoxy Propan-2-ol Acetate 108-65-6 None 1-5 Aromatic hydrocarbon (contains <0.1% benzene) 64742-95-6 Xn 22 Eye contact: Irritating to eyes. Skin contact: Slight skin irritant. Prolonged or repeated contact can cause dermatitis. Inhalation: High levels of vapour/mist may cause dizziness. Can cause irritation of the respiratory tract. Ingestion: Accidental ingestion is an unlikely event. 9804/8955 ISSUE 2 (REV.), APRIL 1997 4. FIRST-AID MEASURES Eye contact: Contact lenses should be removed. Irrigate copiously with clean, fresh water for at least 10 minutes, holding the eyelids apart, and seek medical advice. Skin contact: Remove contaminated clothing. Wash skin thoroughly with soap and water or use a proprietary skin cleaner. DO NOT use solvents or thinners. If in doubt, seek medical advice. Inhalation: Remove to fresh air, keep the patient warm and at rest. If breathing is irregular or has stopped, administer artificial respiration. Give nothing by mouth. If unconscious, place in the recovery position and seek medical advice. Ingestion: If accidentally swallowed, obtain immediate medical attention. Keep at rest. DO NOT induce vomiting. 5. FIRE-FIGHTING MEASURES Extinguishing media: Alcohol resistant foam; CO2; powder; water spray/mist. Do not use: Water jet. Special fire fighting procedures: Fire exposed containers should be sprayed with water to lessen risk of explosion. Unusual fire and explosion hazards: Fire will produce dense black smoke containing combustion products which may be a health hazard. Appropriate self-contained breathing apparatus may be required. Run off from fire must not enter drains. 6. ACCIDENTAL RELEASE MEASURES Procedures for leaks or spillage: Exclude sources of ignition and ventilate the area. Exclude non-essential personnel. Avoid breathing vapours. Refer to protective measures listed in Sections 7 & 8. Contain and collect spillages with non-combustible absorbent materials, e.g. sand, earth, vermiculite, diatomaceous earth and place in a suitable container for disposal in accordance with waste regulations (see Section 13). Do not allow to enter drains or water courses. Clean preferably with a detergent; avoid the use of solvents. If the product enters drains or sewers, the local water company should be contacted immediately; in the case of contamination of streams, rivers or lakes, the National Rivers Authority. 7. HANDLING AND STORAGE Handling: Vapours are heavier than air and may spread along floors. They may form explosive mixtures with air. Prevent the creation of flammable or explosive concentrations of vapour in air and avoid vapour concentrations higher than the occupational exposure limits. Use only in areas from which all sources of heat, sparks and open flame have been excluded. Avoid skin and eye contact. Avoid inhalation of vapour and spray mist. Smoking, eating and drinking should be prohibited in areas of use and storage.

Long term hazards

Effects of exposure Effects of exposure Effects of Exposure Effects of exposure Effects of Exposure Effects of Exposure Effects of Exposure Effects of Chronic Exposure: Although this product has not been tested for chronic effects it is judged as having a low order of toxicity based on component information. Use of good industrial hygiene practices is recommended. Target Organs: Not applicable Skin sensitization: No Possible birth defect hazzard: No Carcinogen: No 9804/9007 ISSUE 2, SEPTEMBER 2001

Environmental hazards

No data is available on the product itself. 13. DISPOSAL CONSIDERATIONS

Environmental effects

Experiments with similar virgin products indicate little danger for aquatic or land- living organisms and intrinsic biodegradability. However, the discharge of oil and lubricants into the environment is prohibited by law. Cont’d 9804/9021 ISSUE1, MARCH 2002

Other physicochemical hazards

No specific risk of fire or explosion. Specific Hazards: None to our knowledge, in normal use.