Marathon Natural Gas, Raw Liquid Mix

Hazard statements (CLP)

H220, H224, H280, H315, H319, H335, H336, H340, H350, H361, H372, H373, H411

Code

Statements

H220

Extremely flammable gas

SECTION 2: Hazards identification

OSHA HCS 2012 EU/EEC

2.1 Classification of the substance or mixture

CLP • Flammable Gases 1 - H220 Flammable Liquids 1 - H224 Liquefied Gas - H280 Skin Irritation 2 - H315 Eye Irritation 2 - H319 Specific Target Organ Toxicity Single Exposure 3: Narcotic Effects - H336 Germ Cell Mutagenicity 1B - H340 Carcinogenicity 1A - H350 Reproductive Toxicity 2 - H361 Specific Target Organ Toxicity Repeated Exposure 2 - H373 Hazardous to the aquatic environment Chronic 2 - H411 EUH066 DSD/DPD • Extremely Flammable (F+) Irritant (Xi) Harmful (Xn) Carcinogenic Substances - Category 1 Mutagenic Substances - Category 2 Substances Toxic To Reproduction - Category 3 Dangerous to the Environment (N) R12, R36/38, R45, R46, R48/20/21/22, R62, R66, R67, R51, R53

2.2 Label elements

CLP DANGER

Hazard statements

H220 - Extremely flammable gas H224 - Extremely flammable liquid and vapour H280 - Contains gas under pressure; may explode if heated H315 - Causes skin irritation H319 - Causes serious eye irritation H336 - May cause drowsiness or dizziness H340 - May cause genetic defects. H350 - May cause cancer. H361 - Suspected of damaging fertility or the unborn child. H373 - May cause damage to organs through prolonged or repeated exposure. H411 - Toxic to aquatic life with long lasting effects EUH066 - Repeated exposure may cause skin dryness or cracking. R12 - Extremely flammable. R36/38 - Irritating to eyes and skin. R45 - May cause cancer. R46 - May cause heritable genetic damage. R48/20/21/22 - Harmful: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed. R62 - Possible risk of impaired fertility. R66 - Repeated exposure may cause skin dryness or cracking. R67 - Vapours may cause drowsiness and dizziness. R51 - Toxic to aquatic organisms. R53 - May cause long-term adverse effects in the aquatic environment. Extremely flammable gas - H220 Extremely flammable liquid and vapour - H224 Contains gas under pressure; may explode if heated - H280 Causes skin irritation - H315 Causes serious eye irritation - H319 May cause respiratory irritation - H335 May cause drowsiness or dizziness - H336 May cause genetic defects. - H340 May cause cancer. - H350 Suspected of damaging fertility or the unborn child. - H361 Causes damage to organs - Blood, Bone Marrow through prolonged or repeated exposure - H372 May displace oxygen and cause rapid suffocation.

Prevention

P201 - Obtain special instructions before use. P202 - Do not handle until all safety precautions have been read and understood. P210 - Keep away from heat, sparks, open flames and/or hot surfaces. - No smoking. P233 - Keep container tightly closed. P240 - Ground and/or bond container and receiving equipment. P241 - Use explosion-proof electrical/ventilating/lighting/equipment. P242 - Use only non-sparking tools. P243 - Take precautionary measures against static discharge. P260 - Do not breathe mists, vapours, and/or spray. P264 - Wash thoroughly after handling. P270 - Do not eat, drink or smoke when using this product. P271 - Use only outdoors or in a well-ventilated area. P273 - Avoid release to the environment. P280 - Wear protective gloves/protective clothing/eye protection/face protection. Obtain special instructions before use. - P201 Do not handle until all safety precautions have been read and understood. - P202 Keep away from heat, sparks, open flames and/or hot surfaces. - No smoking. - P210 Keep container tightly closed. - P233 Ground and/or bond container and receiving equipment. - P240 Use explosion-proof electrical/ventilating/lighting/equipment. - P241 Use only non-sparking tools. - P242 Take precautionary measures against static discharge. - P243 Do not breathe mists, vapours, and/or spray. - P260 Wash thoroughly after handling. - P264 Do not eat, drink or smoke when using this product. - P270 Use only outdoors or in a well-ventilated area. - P271 Wear protective gloves/protective clothing/eye protection/face protection. - P280

Response

P377 - Leaking gas fire: Do not extinguish, unless leak can be stopped safely. P381 - Eliminate all ignition sources if safe to do so. P304+P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P303+P361+P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 - If eye irritation persists: Get medical advice/attention. P308+P313 - IF exposed or concerned: Get medical advice/attention. P312 - Call a POISON CENTER or doctor/physician if you feel unwell. P391 - Collect spillage. Storage/Disposal• P403+P233 - Store in a well-ventilated place. Keep container tightly closed. P405 - Store locked up. P501 - Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. DSD/DPD Leaking gas fire: Do not extinguish, unless leak can be stopped safely. - P377 In case of fire: Use appropriate media for extinction. - P370+P378 Eliminate all ignition sources if safe to do so. - P381 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. - P304+P340 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. - P303+P361+P353 If skin irritation occurs: Get medical advice/attention. - P332+P313 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. - P305+P351+P338 If eye irritation persists: Get medical advice/attention. - P337+P313 IF exposed or concerned: Get medical advice/attention. - P308+P313 Call a POISON CENTER or doctor/physician if you feel unwell. - P312 Storage/Disposal• Store in a well-ventilated place. Keep container tightly closed. - P403+P233 Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. - P501

Precautionary statements

S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S53 - Avoid exposure - obtain special instructions before use.

Other hazards

CLP • Simple asphyxiant. Will displace oxygen in containers, vessels and unventilated areas.