Structural Adhesive SA 9820 Black: Part A

Hazard statements (CLP)

H315, H317, H318, H411

Code

Statements

H315

Causes skin irritation

SECTION 2: Hazards identification

No 1272/2008 Classification of the substance or mixture

Hazard pictograms

GHS05 (Corrosion) |GHS07 (Exclamation mark) |GHS09 (Environment) | Ingredient CAS Nbr EC No. % by Wt 3,3'-Oxybis(ethyleneoxy)bis(propylamine) 4246-51-9 224-207-2 25 - 55 2,4,6-tris(dimethylaminomethyl)phenol 90-72-2 202-013-9 < 10 Formaldehyde, oligomeric reaction products with phenol 9003-35-4 500-005-2 < 2.5

Hazard statements

H315 Causes skin irritation. H318 Causes serious eye damage. H317 May cause an allergic skin reaction. H411 Toxic to aquatic life with long lasting effects.

Prevention

P273 Avoid release to the environment. P280B Wear protective gloves and eye/face protection.

Response

P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTRE or doctor/physician. P333 + P313 If skin irritation or rash occurs: Get medical advice/attention. P391 Collect spillage. 45% of the mixture consists of components of unknown acute oral toxicity. 51% of the mixture consists of components of unknown acute dermal toxicity.

Contains

52% of components with unknown hazards to the aquatic environment

2.3 Other hazards

None known. This material does not contain any substances that are assessed to be a PBT or vPvB

2.1 Classification of the substance or mixture

The retained CLP Regulation (EU) No 1272/2008 as amended for Great Britain The health and environmental classifications of this material have been derived using the calculation method, except in cases where test data are available or the physical form impacts classification. Classification(s) based on test data or physical form are noted below, if applicable. A similar mixture has been tested for skin corrosion/irritation and the test results are reflected in the assigned classification. CLASSIFICATION: Skin Corrosion/Irritation, Category 2 - Skin Irrit. 2; H315 Serious Eye Damage/Eye Irritation, Category 1 - Eye Dam. 1; H318 Skin Sensitization, Category 1 - Skin Sens. 1; H317 Hazardous to the Aquatic Environment (Chronic), Category 2 - Aquatic Chronic 2; H411 For full text of H phrases, see Section 16. 2.2. Label elements The retained CLP Regulation (EU) No 1272/2008 as amended for Great Britain SIGNAL WORD DANGER. Symbols GHS05 (Corrosion) |GHS07 (Exclamation mark) |GHS09 (Environment) | Pictograms Ingredient CAS Nbr EC No. % by Wt 3,3'-Oxybis(ethyleneoxy)bis(propylamine) 4246-51-9 224-207-2 25 - 55 2,4,6-tris(dimethylaminomethyl)phenol 90-72-2 202-013-9 < 10 Formaldehyde, oligomeric reaction products with phenol 9003-35-4 500-005-2 < 2.5 HAZARD STATEMENTS: H315 Causes skin irritation. H318 Causes serious eye damage. H317 May cause an allergic skin reaction. H411 Toxic to aquatic life with long lasting effects. PRECAUTIONARY STATEMENTS Prevention: P273 Avoid release to the environment. P280B Wear protective gloves and eye/face protection. Response: P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTRE or doctor/physician. P333 + P313 If skin irritation or rash occurs: Get medical advice/attention. P391 Collect spillage. 45% of the mixture consists of components of unknown acute oral toxicity. 51% of the mixture consists of components of unknown acute dermal toxicity. Contains 52% of components with unknown hazards to the aquatic environment. 2.3. Other hazards None known. This material does not contain any substances that are assessed to be a PBT or vPvB SECTION 3: Composition/information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Ingredient Identifier(s) % Classification according to Regulation (EC) No. 1272/2008 [CLP], as amended for GB 3,3'-Oxybis(ethyleneoxy)bis(propylamine) (CAS-No.) 4246-51-9 25 - 55 Skin Corr. 1B, H314 (EC-No.) 224-207-2 Eye Dam. 1, H318 Skin Sens. 1, H317 Amine terminated adduct Trade Secret 20 - 50 Substance not classified as hazardous 2,4,6-tris(dimethylaminomethyl)phenol (CAS-No.) 90-72-2 < 10 Acute Tox. 4, H302 (EC-No.) 202-013-9 Skin Corr. 1C, H314 Eye Dam. 1, H318 Silica, vitreous (CAS-No.) 60676-86-0 3 - 7 Substance with a national occupational (EC-No.) 262-373-8 exposure limit Siloxanes and Silicones, di-Me, reaction (CAS-No.) 67762-90-7 3 - 7 Substance with a national occupational products with silica exposure limit PHENOL, 4,4'-(1- (CAS-No.) 68698-70-4 < 5 Acute Tox. 4, H302 METHYLETHYLIDENE)BIS-, (EC-No.) 500-230-6 Skin Irrit. 2, H315 POLYMER WITH Eye Irrit. 2, H319 (CHLOROMETHYL)OXIRANE, N,N- Aquatic Acute 1, H400,M=1 DIETHYL-1,3-PROPANEDIAMINE Aquatic Chronic 1, H410,M=1 AND 1-PIPERAZINEETHANAMINE Formaldehyde, oligomeric reaction (CAS-No.) 9003-35-4 < 2.5 Skin Sens. 1, H317