Scotchcast Electrical insulating Resin 40 part B

Hazard statements (CLP)

H315, H317, H319, H332, H334, H335, H351, H373

Code

Statements

H315

Causes skin irritation

SECTION 2: Hazards identification

No 1272/2008 Classification of the substance or mixture

Hazard pictograms

GHS07 (Exclamation mark) |GHS08 (Health Hazard) | Ingredient CAS Nbr EC No. % by Wt Polymethylene polyphenylene isocyanate 9016-87-9 < 100

Hazard statements

H332 Harmful if inhaled. H315 Causes skin irritation. H319 Causes serious eye irritation. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction. H351 Suspected of causing cancer. H335 May cause respiratory irritation. H373 May cause damage to organs through prolonged or repeated exposure: respiratory system.

Prevention

P261A Avoid breathing vapours. P280K Wear protective gloves and respiratory protection.

Response

P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333 + P313 If skin irritation or rash occurs: Get medical advice/attention. P342 + P311 If experiencing respiratory symptoms: Call a POISON CENTRE or doctor/physician.

2.3 Other hazards

Persons previously sensitised to isocyanates may develop a cross-sensitisation reaction to other isocyanates. This material does not contain any substances that are assessed to be a PBT or vPvB

2.1 Classification of the substance or mixture

The retained CLP Regulation (EU) No 1272/2008 as amended for Great Britain The health and environmental classifications of this material have been derived using the calculation method, except in cases where test data are available or the physical form impacts classification. Classification(s) based on test data or physical form are noted below, if applicable. CLASSIFICATION: Acute Toxicity, Category 4 - Acute Tox. 4; H332 Skin Corrosion/Irritation, Category 2 - Skin Irrit. 2; H315 Serious Eye Damage/Eye Irritation, Category 2 - Eye Irrit. 2; H319 Respiratory Sensitization, Category 1 - Resp. Sens. 1; H334 Skin Sensitization, Category 1 - Skin Sens. 1; H317 Carcinogenicity, Category 2 - Carc. 2; H351 Specific Target Organ Toxicity-Repeated Exposure, Category 2 - STOT RE 2; H373 Specific Target Organ Toxicity-Single Exposure, Category 3 - STOT SE 3; H335 For full text of H phrases, see Section 16. 2.2. Label elements The retained CLP Regulation (EU) No 1272/2008 as amended for Great Britain SIGNAL WORD DANGER. Symbols GHS07 (Exclamation mark) |GHS08 (Health Hazard) | Pictograms Ingredient CAS Nbr EC No. % by Wt Polymethylene polyphenylene isocyanate 9016-87-9 < 100 HAZARD STATEMENTS: H332 Harmful if inhaled. H315 Causes skin irritation. H319 Causes serious eye irritation. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction. H351 Suspected of causing cancer. H335 May cause respiratory irritation. H373 May cause damage to organs through prolonged or repeated exposure: respiratory system. PRECAUTIONARY STATEMENTS Prevention: P261A Avoid breathing vapours. P280K Wear protective gloves and respiratory protection. Response: P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333 + P313 If skin irritation or rash occurs: Get medical advice/attention. P342 + P311 If experiencing respiratory symptoms: Call a POISON CENTRE or doctor/physician. Information required per Regulation (EU) 2020/1149, amendment to REACH Regualtion (1907/2006) as amended for Great Britain, as regards diisocyanates: As from 24 August 2023 adequate training is required before industrial or professional use. Further information can be found at feica.eu/Puinfo 2.3. Other hazards Persons previously sensitised to isocyanates may develop a cross-sensitisation reaction to other isocyanates. This material does not contain any substances that are assessed to be a PBT or vPvB SECTION 3: Composition/information on ingredients 3.1. Substances Ingredient Identifier(s) % Classification according to Regulation (EC) No. 1272/2008 [CLP], as amended for GB Polymethylene polyphenylene isocyanate (CAS-No.) 9016-87-9 < 100 Acute Tox. 4, H332 Skin Irrit. 2, H315 Eye Irrit. 2, H319 Resp. Sens. 1, H334 Skin Sens. 1, H317 Carc. 2, H351 STOT SE 3, H335 STOT RE 2, H373 Please see section 16 for the full text of any H statements referred to in this section Specific Concentration Limits Ingredient Identifier(s) Specific Concentration Limits Polymethylene polyphenylene isocyanate (CAS-No.) 9016-87-9 (C >= 5%) Skin Irrit. 2, H315 (C >= 5%) Eye Irrit. 2, H319 (C >= 0.1%) Resp. Sens. 1, H334 (C >= 5%) STOT SE 3, H335 For information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDS 3.2. Mixtures Not applicable SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation Remove person to fresh air. If you feel unwell, get medical attention. Skin contact Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. Eye contact Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical attention. If swallowed Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed The most important symptoms and effects based on the GB CLP classification include: Irritating to the respiratory tract (coughing, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain). Allergic respiratory reaction (difficulty breathing, wheezing, cough, and tightness of chest). Harmful if inhaled. Irritation to the skin (localized redness, swelling, itching, and dryness). Allergic skin reaction (redness, swelling, blistering, and itching). Serious irritation to the eyes (significant redness, swelling, pain, tearing, and impaired vision). Target organ effects. See Section 11 for additional details. 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Extinguishing media In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish. 5.2. Special hazards arising from the substance or mixture Closed containers exposed to heat from fire may build pressure and explode. Hazardous Decomposition or By-Products Substance Condition Isocyanates During combustion. Carbon monoxide During combustion. Carbon dioxide. During combustion. Hydrogen cyanide. During combustion. Oxides of nitrogen. During combustion. 5.3. Advice for fire-fighters Wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Use personal protective equipment based on the results of an exposure assessment. Refer to Section 8 for PPE recommendations. If anticipated exposure resulting from an accidental release exceeds the protective capabilities of the PPE listed in Section 8, or are unknown, select PPE that offers an appropriate level of protection. Consider the physical and chemical hazards of the material when doing so. Examples of PPE ensembles for emergency response could include wearing bunker gear for a release of flammable material; wearing chemical protective clothing if the spilled material is a corrosive, a sensitizer, a significant dermal irritant, or can be absorbed through the skin; or donning a positive pressure supplied-air respirator for chemicals with inhalation hazards. For information regarding physical and health hazards, refer to sections 2 and 11 of the SDS. Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapours, in accordance with good industrial hygiene practice. 6.2. Environmental precautions Avoid release to the environment. For larger spills, cover drains and build dykes to prevent entry into sewer systems or bodies of water. 6.3. Methods and material for containment and cleaning up Contain spill. Pour isocyanate decontaminant solution (90% water, 8% concentrated ammonia, 2% detergent) on spill and allow to react for 10 minutes. Or pour water on spill and allow to react for more than 30 minutes. Cover with absorbent material. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does