Scotch-Weld DP-804, Clear, Part B

3M United Kingdom PLC

Revision date : 2023-10-27

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GHS02 GHS05 GHS07 GHS08
Health risk rating 4
Safety risk rating 2
Environmental risk rating 3

Note: Ingredients listed on restricted chemical lists

EC/CAS

201-297-1/80-62-6

Name of the chemical

methacrylic acid, methyl ester

Concentration

25-45

EC/CAS

201-204-4/79-41-4

Name of the chemical

methacrylic acid

Concentration

5-15

General Information

Version

6.00

Revision date

2023-10-27

Product name

Scotch-Weld DP-804, Clear, Part B

1.2.1 Relevant identified uses

Adhesive

Emergency telephone

+44 (0)1344 858 000

Icons in SDS

GHS02 GHS05 GHS07 GHS08 M004 M009 M010 M013 M017

Company Information

company name

3M United Kingdom PLC

e-mail address of the competent person responsible for the Safety Data Sheet

tox.uk@mmm.com

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H226, H315, H317, H318, H335, H372, H412

Hazard statements

Code

Statements

H226

Flammable liquid and vapour

Section 2

SECTION 2: Hazards identification

No 1272/2008 Classification of the substance or mixture

Hazard pictograms

GHS02 (Flame) |GHS05 (Corrosion) |GHS07 (Exclamation mark) |GHS08 (Health Hazard) | Ingredient CAS Nbr EC No. % by Wt methyl methacrylate 80-62-6 201-297-1 30 - 40 methacrylic acid 79-41-4 201-204-4 < 5

Hazard statements

H226 Flammable liquid and vapour. H315 Causes skin irritation. H318 Causes serious eye damage. H317 May cause an allergic skin reaction. H335 May cause respiratory irritation. H372 Causes damage to organs through prolonged or repeated exposure: sensory organs. H412 Harmful to aquatic life with long lasting effects.

Prevention

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P260A Do not breathe vapours. P280B Wear protective gloves and eye/face protection. P260A Do not breathe vapours. P280B Wear protective gloves and eye/face protection.

Response

P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTRE or doctor/physician. P333 + P313 If skin irritation or rash occurs: Get medical advice/attention. For containers not exceeding 125 ml the following Hazard and Precautionary statements may be used: <=125 ml Hazard statements H318 Causes serious eye damage. H317 May cause an allergic skin reaction. H372 Causes damage to organs through prolonged or repeated exposure: sensory organs. H412 Harmful to aquatic life with long lasting effects. <=125 ml Precautionary statements P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTRE or doctor/physician. P333 + P313 If skin irritation or rash occurs: Get medical advice/attention. 2% of the mixture consists of components of unknown acute oral toxicity. 42% of the mixture consists of components of unknown acute dermal toxicity.

2.3 Other hazards

None known. This material does not contain any substances that are assessed to be a PBT or vPvB

2.1 Classification of the substance or mixture

The retained CLP Regulation (EU) No 1272/2008 as amended for Great Britain The health and environmental classifications of this material have been derived using the calculation method, except in cases where test data are available or the physical form impacts classification. Classification(s) based on test data or physical form are noted below, if applicable. CLASSIFICATION: Flammable Liquid, Category 3 - Flam. Liq. 3; H226 Skin Corrosion/Irritation, Category 2 - Skin Irrit. 2; H315 Serious Eye Damage/Eye Irritation, Category 1 - Eye Dam. 1; H318 Skin Sensitization, Category 1 - Skin Sens. 1; H317 Specific Target Organ Toxicity-Repeated Exposure, Category 1 - STOT RE 1; H372 Specific Target Organ Toxicity-Single Exposure, Category 3 - STOT SE 3; H335 Hazardous to the Aquatic Environment (Chronic), Category 3 - Aquatic Chronic 3; H412 For full text of H phrases, see Section 16. 2.2. Label elements The retained CLP Regulation (EU) No 1272/2008 as amended for Great Britain SIGNAL WORD DANGER. Symbols GHS02 (Flame) |GHS05 (Corrosion) |GHS07 (Exclamation mark) |GHS08 (Health Hazard) | Pictograms Ingredient CAS Nbr EC No. % by Wt methyl methacrylate 80-62-6 201-297-1 30 - 40 methacrylic acid 79-41-4 201-204-4 < 5 HAZARD STATEMENTS: H226 Flammable liquid and vapour. H315 Causes skin irritation. H318 Causes serious eye damage. H317 May cause an allergic skin reaction. H335 May cause respiratory irritation. H372 Causes damage to organs through prolonged or repeated exposure: sensory organs. H412 Harmful to aquatic life with long lasting effects. PRECAUTIONARY STATEMENTS Prevention: P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P260A Do not breathe vapours. P280B Wear protective gloves and eye/face protection. Response: P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTRE or doctor/physician. P333 + P313 If skin irritation or rash occurs: Get medical advice/attention. For containers not exceeding 125 ml the following Hazard and Precautionary statements may be used: <=125 ml Hazard statements H318 Causes serious eye damage. H317 May cause an allergic skin reaction. H372 Causes damage to organs through prolonged or repeated exposure: sensory organs. H412 Harmful to aquatic life with long lasting effects. <=125 ml Precautionary statements Prevention: P260A Do not breathe vapours. P280B Wear protective gloves and eye/face protection. Response: P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTRE or doctor/physician. P333 + P313 If skin irritation or rash occurs: Get medical advice/attention. 2% of the mixture consists of components of unknown acute oral toxicity. 42% of the mixture consists of components of unknown acute dermal toxicity. 2.3. Other hazards None known. This material does not contain any substances that are assessed to be a PBT or vPvB SECTION 3: Composition/information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Ingredient Identifier(s) % Classification according to Regulation (EC) No. 1272/2008 [CLP], as amended for GB Acrylate/methacrylate copolymer Trade Secret 25 - 45 Substance not classified as hazardous methyl methacrylate (CAS-No.) 80-62-6 30 - 40 Flam. Liq. 2, H225 (EC-No.) 201-297-1 Skin Irrit. 2, H315 Skin Sens. 1, H317 STOT SE 3, H335 Nota D acetyl-2-thiourea (CAS-No.) 591-08-2 < 2.5 Substance not classified as hazardous (EC-No.) 209-699-9 2-Phenoxyethyl methacrylate (CAS-No.) 10595-06-9 5 - 15 Aquatic Chronic 2, H411 (EC-No.) 234-201-1 Skin Irrit. 2, H315 Eye Irrit. 2, H319 methacrylic acid (CAS-No.) 79-41-4 < 5 Acute Tox. 3, H311 (EC-No.) 201-204-4 Acute Tox. 4, H302 Skin Corr. 1A, H314 Eye Dam. 1, H318 STOT SE 3, H335 Nota D Acute Tox. 4, H332 Please see section 16 for the full text of any H statements referred to in this section Specific Concentration Limits Ingredient Identifier(s) Specific Concentration Limits methacrylic acid (CAS-No.) 79-41-4

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