DP 6330 NS part A

Hazard statements (CLP)

H315, H317, H319, H334, H335, H351, H373

Code

Statements

H315

Causes skin irritation

SECTION 2: Hazards identification

No 1272/2008 Classification of the substance or mixture

Hazard pictograms

GHS07 (Exclamation mark) |GHS08 (Health Hazard) | Ingredient Identifier(s) EC No. % by Wt 4,4’-Methylenediphenyl diisocyanate, oligomers 500-040-3 30 - 60

Hazard statements

H315 Causes skin irritation. H319 Causes serious eye irritation. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction. H351 Suspected of causing cancer. H335 May cause respiratory irritation. H373 May cause damage to organs through prolonged or repeated exposure: respiratory system.

Prevention

P260A Do not breathe vapours. P280 Wear protective gloves and eye protection.

Response

P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333 + P313 If skin irritation or rash occurs: Get medical advice/attention. P342 + P311 If experiencing respiratory symptoms: Call a POISON CENTRE or doctor/physician.

Contains

2% of components with unknown hazards to the aquatic environment

2.3 Other hazards

Persons previously sensitised to isocyanates may develop a cross-sensitisation reaction to other isocyanates. This material does not contain any substances that are assessed to be a PBT or vPvB

2.1 Classification of the substance or mixture

The retained CLP Regulation (EU) No 1272/2008 as amended for Great Britain The health and environmental classifications of this material have been derived using the calculation method, except in cases where test data are available or the physical form impacts classification. Classification(s) based on test data or physical form are noted below, if applicable. CLASSIFICATION: Skin Corrosion/Irritation, Category 2 - Skin Irrit. 2; H315 Serious Eye Damage/Eye Irritation, Category 2 - Eye Irrit. 2; H319 Respiratory Sensitization, Category 1 - Resp. Sens. 1; H334 Skin Sensitization, Category 1 - Skin Sens. 1; H317 Carcinogenicity, Category 2 - Carc. 2; H351 Specific Target Organ Toxicity-Repeated Exposure, Category 2 - STOT RE 2; H373 Specific Target Organ Toxicity-Single Exposure, Category 3 - STOT SE 3; H335 For full text of H phrases, see Section 16. 2.2. Label elements The retained CLP Regulation (EU) No 1272/2008 as amended for Great Britain SIGNAL WORD DANGER. Symbols GHS07 (Exclamation mark) |GHS08 (Health Hazard) | Pictograms Ingredient Identifier(s) EC No. % by Wt 4,4’-Methylenediphenyl diisocyanate, oligomers 500-040-3 30 - 60 HAZARD STATEMENTS: H315 Causes skin irritation. H319 Causes serious eye irritation. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction. H351 Suspected of causing cancer. H335 May cause respiratory irritation. H373 May cause damage to organs through prolonged or repeated exposure: respiratory system. PRECAUTIONARY STATEMENTS Prevention: P260A Do not breathe vapours. P280 Wear protective gloves and eye protection. Response: P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333 + P313 If skin irritation or rash occurs: Get medical advice/attention. P342 + P311 If experiencing respiratory symptoms: Call a POISON CENTRE or doctor/physician. Contains 2% of components with unknown hazards to the aquatic environment. Information required per Regulation (EU) 2020/1149, amendment to REACH Regualtion (1907/2006) as amended for Great Britain, as regards diisocyanates: As from 24 August 2023 adequate training is required before industrial or professional use. Further information can be found at feica.eu/Puinfo 2.3. Other hazards Persons previously sensitised to isocyanates may develop a cross-sensitisation reaction to other isocyanates. This material does not contain any substances that are assessed to be a PBT or vPvB SECTION 3: Composition/information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Ingredient Identifier(s) % Classification according to Regulation (EC) No. 1272/2008 [CLP], as amended for GB 4,4’-Methylenediphenyl diisocyanate, (EC-No.) 500-040-3 30 - 60 Carc. 2, H351 oligomers Acute Tox. 4, H332 Skin Irrit. 2, H315 Eye Irrit. 2, H319 Resp. Sens. 1, H334 Skin Sens. 1, H317 STOT SE 3, H335 STOT RE 2, H373 Urethane Prepolymer Trade Secret 15 - 40 Substance not classified as hazardous Fillers Trade Secret 7 - 13 Substance not classified as hazardous Talc (CAS-No.) 14807-96-6 < 10 Substance with a national occupational (EC-No.) 238-877-9 exposure limit Silane, dichlorodimethyl-, reaction (CAS-No.) 68611-44-9 < 2.5 Substance with a national occupational products with silica