3M(tm) Bumper Repair Material P/N 05900/05901

Hazard statements (CLP)

H315, H317, H319, H400, H410

Code

Statements

H315

Causes skin irritation

SECTION 2: Hazards identification

No 1272/2008 Classification of the substance or mixture

Signal word

WARNING.

Hazard pictograms

GHS07 (Exclamation mark) |GHS09 (Environment) | Ingredient CAS Nbr EC No. % by Wt bis-[4-(2,3-epoxipropoxi)phenyl]propane 1675-54-3 216-823-5 10 - 30

Hazard statements

H315 Causes skin irritation. H319 Causes serious eye irritation. H317 May cause an allergic skin reaction. H410 Very toxic to aquatic life with long lasting effects.

Prevention

P273 Avoid release to the environment. P280E Wear protective gloves. P280E Wear protective gloves.

Response

P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333 + P313 If skin irritation or rash occurs: Get medical advice/attention. P391 Collect spillage. For containers not exceeding 125 ml the following Hazard and Precautionary statements may be used: <=125 ml Hazard statements H317 May cause an allergic skin reaction. <=125 ml Precautionary statements P333 + P313 If skin irritation or rash occurs: Get medical advice/attention. 1% of the mixture consists of components of unknown acute oral toxicity. 69% of the mixture consists of components of unknown acute inhalation toxicity.

Contains

3% of components with unknown hazards to the aquatic environment

2.3 Other hazards

None known. This material does not contain any substances that are assessed to be a PBT or vPvB

2.1 Classification of the substance or mixture

The retained CLP Regulation (EU) No 1272/2008 as amended for Great Britain The health and environmental classifications of this material have been derived using the calculation method, except in cases where test data are available or the physical form impacts classification. Classification(s) based on test data or physical form are noted below, if applicable. CLASSIFICATION: Skin Corrosion/Irritation, Category 2 - Skin Irrit. 2; H315 Serious Eye Damage/Eye Irritation, Category 2 - Eye Irrit. 2; H319 Skin Sensitization, Category 1 - Skin Sens. 1; H317 Hazardous to the Aquatic Environment (Acute), Category 1 - Aquatic Acute 1; H400 Hazardous to the Aquatic Environment (Chronic), Category 1 - Aquatic Chronic 1; H410 For full text of H phrases, see Section 16. 2.2. Label elements The retained CLP Regulation (EU) No 1272/2008 as amended for Great Britain SIGNAL WORD WARNING. Symbols GHS07 (Exclamation mark) |GHS09 (Environment) | Pictograms Ingredient CAS Nbr EC No. % by Wt bis-[4-(2,3-epoxipropoxi)phenyl]propane 1675-54-3 216-823-5 10 - 30 HAZARD STATEMENTS: H315 Causes skin irritation. H319 Causes serious eye irritation. H317 May cause an allergic skin reaction. H410 Very toxic to aquatic life with long lasting effects. PRECAUTIONARY STATEMENTS Prevention: P273 Avoid release to the environment. P280E Wear protective gloves. Response: P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333 + P313 If skin irritation or rash occurs: Get medical advice/attention. P391 Collect spillage. For containers not exceeding 125 ml the following Hazard and Precautionary statements may be used: <=125 ml Hazard statements H317 May cause an allergic skin reaction. <=125 ml Precautionary statements Prevention: P280E Wear protective gloves. Response: P333 + P313 If skin irritation or rash occurs: Get medical advice/attention. 1% of the mixture consists of components of unknown acute oral toxicity. 69% of the mixture consists of components of unknown acute inhalation toxicity. Contains 3% of components with unknown hazards to the aquatic environment. 2.3. Other hazards None known. This material does not contain any substances that are assessed to be a PBT or vPvB SECTION 3: Composition/information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Ingredient Identifier(s) % Classification according to Regulation (EC) No. 1272/2008 [CLP], as amended for GB Limestone (CAS-No.) 1317-65-3 30 - 60 Substance with a national occupational (EC-No.) 215-279-6 exposure limit Formaldehyde, oligomeric reaction (CAS-No.) 9003-36-5 20 - 50 Skin Irrit. 2, H315 products with 1-chloro-2,3-epoxypropane (EC-No.) 500-006-8 Skin Sens. 1A, H317 and phenol Aquatic Acute 1, H400,M=1 Aquatic Chronic 1, H410,M=1 bis-[4-(2,3-epoxipropoxi)phenyl]propane (CAS-No.) 1675-54-3 10 - 30 Skin Irrit. 2, H315 (EC-No.) 216-823-5 Eye Irrit. 2, H319 Skin Sens. 1, H317 Aquatic Chronic 2, H411 Siloxanes and Silicones, di-Me, reaction (CAS-No.) 67762-90-7 1 - 5 Substance with a national occupational products with silica exposure limit Surface Treatment Trade Secret < 2 Substance not classified as hazardous Please see section 16 for the full text of any H statements referred to in this section Specific Concentration Limits Ingredient Identifier(s) Specific Concentration Limits bis-[4-(2,3-epoxipropoxi)phenyl]propane (CAS-No.) 1675-54-3 (C >= 5%) Skin Irrit. 2, H315 (EC-No.) 216-823-5 (C >= 5%) Eye Irrit. 2, H319 For information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDS SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation Remove person to fresh air. If you feel unwell, get medical attention. Skin contact Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. Eye contact Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention. If swallowed Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed The most important symptoms and effects based on the GB CLP classification include: Irritation to the skin (localized redness, swelling, itching, and dryness). Allergic skin reaction (redness, swelling, blistering, and itching). Serious irritation to the eyes (significant redness, swelling, pain, tearing, and impaired vision). 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Extinguishing media In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish. 5.2. Special hazards arising from the substance or mixture None inherent in this product. Hazardous Decomposition or By-Products Substance Condition Aldehydes. During combustion. Carbon monoxide