3M Structural Adhesive 9820 (Part A)

Hazard statements (CLP)

H315, H317, H318, H411

Code

Statements

H315

Causes skin irritation

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

The retained Skin Corrosion/Irritation, Category 2 - Skin Irrit. 2; H315 Serious Eye Damage/Eye Irritation, Category 1 - Eye Dam. 1; H318 Skin Sensitization, Category 1 - Skin Sens. 1; H317 Hazardous to the Aquatic Environment (Chronic), Category 2 - Aquatic Chronic 2; H411 For full text of H phrases, see Section 16.

2.2 Label elements

The retained

Hazard pictograms

GHS05 (Corrosion) |GHS07 (Exclamation mark) |GHS09 (Environment) | Ingredient CAS Nbr EC No. % by Wt 3,3'-Oxybis(ethyleneoxy)bis(propylamine) 4246-51-9 224-207-2 25 - 60 Amine terminated adduct Trade Secret 20 - 50 Silica, vitreous 60676-86-0 262-373-8 5 - 10 Siloxanes and Silicones, di-Me, reaction products with silica 67762-90-7 5 - 10 2,4,6-tris(dimethylaminomethyl)phenol 90-72-2 202-013-9 5 - 10 Oxide glass chemicals 65997-17-3 266-046-0 1 - 5 PHENOL, 4,4'-(1-METHYLETHYLIDENE)BIS-, POLYMER 68698-70-4 500-230-6 1 - 5 WITH (CHLOROMETHYL)OXIRANE, N,N-DIETHYL-1,3- PROPANEDIAMINE AND 1-PIPERAZINEETHANAMINE Formaldehyde, oligomeric reaction products with phenol 9003-35-4 500-005-2 0.5 - 2.5 Bis[(dimethylamino)methyl]phenol 71074-89-0 275-162-0 0.5 - 1.5

Hazard statements

H315 Causes skin irritation. H318 Causes serious eye damage. H317 May cause an allergic skin reaction. H411 Toxic to aquatic life with long lasting effects.

Prevention

P273 Avoid release to the environment. P280B Wear protective gloves and eye/face protection. P280B Wear protective gloves and eye/face protection.

Response

P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTRE or doctor/physician. P333 + P313 If skin irritation or rash occurs: Get medical advice/attention. P391 Collect spillage. For containers not exceeding 125 ml the following Hazard and Precautionary statements may be used: <=125 ml Hazard statements H318 Causes serious eye damage. H317 May cause an allergic skin reaction. <=125 ml Precautionary statements P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTRE or doctor/physician. P333 + P313 If skin irritation or rash occurs: Get medical advice/attention. 45% of the mixture consists of components of unknown acute oral toxicity.

Contains

52% of components with unknown hazards to the aquatic environment

2.3 Other hazards

None known. This material does not contain any substances that are assessed to be a PBT or vPvB