3M Scotchcast 1402FR Part A

Hazard statements (CLP)

H361d, H412

Code

Statements

H361d

Suspected of damaging the unborn child

SECTION 2: Hazards identification

No 1272/2008 Classification of the substance or mixture

Signal word

WARNING.

Hazard pictograms

GHS08 (Health Hazard) | Ingredient Identifier(s) EC No. % by Wt Reaction mass of 3-methylphenyl diphenyl phosphate, 4- 945-730-9 5 - 10 methylphenyl diphenyl phosphate, bis(3-methylphenyl) phenyl phosphate, 3-methylphenyl 4-methylphenyl phenyl phosphate and triphenyl phosphate

Hazard statements

H361d Suspected of damaging the unborn child. H412 Harmful to aquatic life with long lasting effects.

Prevention

P280E Wear protective gloves.

Supplemental label elements

EUH208

Contains

Fatty acids, C16-18 and C18-unsatd., Me esters, epoxidized . | Fatty acids, tall-oil, compds. with oleylamine . | Fatty acids, C18-unsatd., trimers, compds. with oleylamine. May produce an allergic reaction. 93% of the mixture consists of components of unknown acute oral toxicity. 93% of components with unknown hazards to the aquatic environment

2.3 Other hazards

None known. This material does not contain any substances that are assessed to be a PBT or vPvB

2.1 Classification of the substance or mixture

The retained CLP Regulation (EU) No 1272/2008 as amended for Great Britain The health and environmental classifications of this material have been derived using the calculation method, except in cases where test data are available or the physical form impacts classification. Classification(s) based on test data or physical form are noted below, if applicable. CLASSIFICATION: Reproductive Toxicity, Category 2 - Repr. 2; H361d Hazardous to the Aquatic Environment (Chronic), Category 3 - Aquatic Chronic 3; H412 For full text of H phrases, see Section 16. 2.2. Label elements The retained CLP Regulation (EU) No 1272/2008 as amended for Great Britain SIGNAL WORD WARNING. Symbols GHS08 (Health Hazard) | Pictograms Ingredient Identifier(s) EC No. % by Wt Reaction mass of 3-methylphenyl diphenyl phosphate, 4- 945-730-9 5 - 10 methylphenyl diphenyl phosphate, bis(3-methylphenyl) phenyl phosphate, 3-methylphenyl 4-methylphenyl phenyl phosphate and triphenyl phosphate HAZARD STATEMENTS: H361d Suspected of damaging the unborn child. H412 Harmful to aquatic life with long lasting effects. PRECAUTIONARY STATEMENTS Prevention: P280E Wear protective gloves. SUPPLEMENTAL INFORMATION: Supplemental Hazard Statements: EUH208 Contains Fatty acids, C16-18 and C18-unsatd., Me esters, epoxidized . | Fatty acids, tall-oil, compds. with oleylamine . | Fatty acids, C18-unsatd., trimers, compds. with oleylamine. May produce an allergic reaction. 93% of the mixture consists of components of unknown acute oral toxicity. Contains 93% of components with unknown hazards to the aquatic environment. 2.3. Other hazards None known. This material does not contain any substances that are assessed to be a PBT or vPvB SECTION 3: Composition/information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Ingredient Identifier(s) % Classification according to Regulation (EC) No. 1272/2008 [CLP], as amended for GB Non-Hazardous Ingredients Trade Secret 80 - 100 Substance not classified as hazardous Reaction mass of 3-methylphenyl diphenyl (EC-No.) 945-730-9 5 - 10 Repr. 2, H361d phosphate, 4-methylphenyl diphenyl Aquatic Acute 1, H400,M=1 phosphate, bis(3-methylphenyl) phenyl Aquatic Chronic 3, H412 phosphate, 3-methylphenyl 4- methylphenyl phenyl phosphate and triphenyl phosphate triethyl phosphate (CAS-No.) 78-40-0 < 3 Acute Tox. 4, H302 (EC-No.) 201-114-5 Eye Irrit. 2, H319 TRIMETHYLOLPROPANE (CAS-No.) 77-99-6 < 3 Repr. 2, H361df (EC-No.) 201-074-9 Triphenyl phosphate (CAS-No.) 115-86-6 < 2 Repr. 2, H361d (EC-No.) 204-112-2 Aquatic Acute 1, H400,M=1 Aquatic Chronic 2, H411 Fatty acids, C18-unsatd., trimers, compds. (CAS-No.) 147900-93-4 < 1 Aquatic Chronic 2, H411 with oleylamine (EC-No.) 604-612-4 Acute Tox. 4, H302 Skin Sens. 1, H317 Fatty acids, C16-18 and C18-unsatd., Me (CAS-No.) 158318-67-3 < 1 Skin Sens. 1B, H317 esters, epoxidized Fatty acids, tall-oil, compds. with (CAS-No.) 85711-55-3 < 0.1 Eye Dam. 1, H318 oleylamine (EC-No.) 288-315-1 Skin Sens. 1A, H317 Any entry in the Identifier(s) column that begins with the numbers 6, 7, 8, or 9 are a Provisional List Number provided by ECHA pending publication of the official EC Inventory Number for the substance. Please see section 16 for the full text of any H statements referred to in this section For information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDS SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation Remove person to fresh air. If you feel unwell, get medical attention. Skin contact Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. Eye contact If exposed, flush eyes with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms develop, get medical attention. If swallowed Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed No critical symptoms or effects. See Section 11.1, information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Extinguishing media In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish. 5.2. Special hazards arising from the substance or mixture None inherent in this product. Hazardous Decomposition or By-Products Substance Condition Carbon monoxide During combustion. Carbon dioxide. During combustion. 5.3. Advice for fire-fighters Wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapours, in accordance with good industrial hygiene practice. Observe precautions from other sections. Use personal protective equipment based on the results of an exposure assessment. Refer to Section 8 for PPE recommendations. If anticipated exposure resulting from an accidental release exceeds the protective capabilities of the PPE listed in Section 8, or are unknown, select PPE that offers an appropriate level of protection. Consider the physical and chemical hazards of the material when doing so. Examples of PPE ensembles for emergency response could include wearing bunker gear for a release of flammable material; wearing chemical protective clothing if the spilled material is a corrosive, a sensitizer, a significant dermal irritant, or can be absorbed through the skin; or donning a positive pressure supplied-air respirator for chemicals with inhalation hazards. For information regarding physical and health hazards, refer to sections 2 and 11 of the SDS. 6.2. Environmental precautions Avoid release to the environment. For larger spills, cover drains and build dykes to prevent entry into sewer systems or bodies of water. 6.3. Methods and material for containment and cleaning up Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially