3M Scotch-Weld Urethane Adhesive 3535 B/A, Part A

Hazard statements (CLP)

H315, H317, H319, H334, H335, H351, H373

Code

Statements

H315

Causes skin irritation

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 Classification of the substance or mixture

Hazard pictograms

GHS07 (Exclamation mark) |GHS08 (Health Hazard) | Ingredients: Ingredient CAS Nbr EC No. % by Wt Poly(methylene phenylene isocyanate) 9016-87-9 10 - 30 4,4'-methylenediphenyl diisocyanate 101-68-8 202-966-0 1 - 15 methylenediphenyl diisocyanate 26447-40-5 247-714-0 1 - 10

Hazard statements

H315 Causes skin irritation. H319 Causes serious eye irritation. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction. H351 Suspected of causing cancer. H335 May cause respiratory irritation. H373 May cause damage to organs through prolonged or repeated exposure.

Prevention

P261A Avoid breathing vapours. P280F Wear respiratory protection. P261A Avoid breathing vapours. P280F Wear respiratory protection.

Response

P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P342 + P311 If experiencing respiratory symptoms: Call a POISON CENTRE or doctor/physician. For containers not exceeding 125 ml the following Hazard and Precautionary statements may be used: <=125 ml Hazard statements H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction. H351 Suspected of causing cancer. <=125 ml Precautionary statements P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P342 + P311 If experiencing respiratory symptoms: Call a POISON CENTRE or doctor/physician. 42% of the mixture consists of components of unknown acute oral toxicity.

Contains

40% of components with unknown hazards to the aquatic environment

2.3 Other hazards

Persons previously sensitised to isocyanates may develop a cross-sensitisation reaction to other isocyanates.

2.1 Classification of the substance or mixture

CLP REGULATION (EC) No 1272/2008 The health and environmental classifications of this material have been derived using the calculation method, except in cases where test data are available or the physical form impacts classification. Classification(s) based on test data or physical form are noted below, if applicable. CLASSIFICATION: Skin Corrosion/Irritation, Category 2 - Skin Irrit. 2; H315 Serious Eye Damage/Eye Irritation, Category 2 - Eye Irrit. 2; H319 Respiratory Sensitization, Category 1 - Resp. Sens. 1; H334 Skin Sensitization, Category 1 - Skin Sens. 1; H317 Carcinogenicity, Category 2 - Carc. 2; H351 Specific Target Organ Toxicity-Repeated Exposure, Category 2 - STOT RE 2; H373 Specific Target Organ Toxicity-Single Exposure, Category 3 - STOT SE 3; H335 For full text of H phrases, see Section 16. 2.2. Label elements CLP REGULATION (EC) No 1272/2008 SIGNAL WORD DANGER. Symbols GHS07 (Exclamation mark) |GHS08 (Health Hazard) | Pictograms Ingredients: Ingredient CAS Nbr EC No. % by Wt Poly(methylene phenylene isocyanate) 9016-87-9 10 - 30 4,4'-methylenediphenyl diisocyanate 101-68-8 202-966-0 1 - 15 methylenediphenyl diisocyanate 26447-40-5 247-714-0 1 - 10 HAZARD STATEMENTS: H315 Causes skin irritation. H319 Causes serious eye irritation. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction. H351 Suspected of causing cancer. H335 May cause respiratory irritation. H373 May cause damage to organs through prolonged or repeated exposure. PRECAUTIONARY STATEMENTS Prevention: P261A Avoid breathing vapours. P280F Wear respiratory protection. Response: P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P342 + P311 If experiencing respiratory symptoms: Call a POISON CENTRE or doctor/physician. For containers not exceeding 125 ml the following Hazard and Precautionary statements may be used: <=125 ml Hazard statements H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction. H351 Suspected of causing cancer. <=125 ml Precautionary statements Prevention: P261A Avoid breathing vapours. P280F Wear respiratory protection. Response: P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P342 + P311 If experiencing respiratory symptoms: Call a POISON CENTRE or doctor/physician. 42% of the mixture consists of components of unknown acute oral toxicity. Contains 40% of components with unknown hazards to the aquatic environment. 2.3. Other hazards Persons previously sensitised to isocyanates may develop a cross-sensitisation reaction to other isocyanates. SECTION 3: Composition/information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Ingredient Identifier(s) % Classification according to Regulation (EC) No. 1272/2008 [CLP] Urethane Prepolymer (NJTS Reg. No. Trade Secret 30 - 50 Substance not classified as hazardous 14499600-5770P) Poly(methylene phenylene isocyanate) (CAS-No.) 9016-87-9 10 - 30 Acute Tox. 4, H332 Skin Irrit. 2, H315 Eye Irrit. 2, H319 Resp. Sens. 1, H334 Skin Sens. 1, H317 Carc. 2, H351 STOT SE 3, H335 STOT RE 2, H373 Talc (CAS-No.) 14807-96-6 10 - 30 Substance with a national occupational (EC-No.) 238-877-9 exposure limit 4,4'-methylenediphenyl diisocyanate (CAS-No.) 101-68-8 1 - 15 Acute Tox. 4, H332 (EC-No.) 202-966-0 Skin Irrit. 2, H315 Eye Irrit. 2, H319 Resp. Sens. 1, H334 Skin Sens. 1, H317 Carc. 2, H351 STOT SE 3, H335 STOT RE 2, H373 Nota 2,C methylenediphenyl diisocyanate (CAS-No.) 26447-40-5 1 - 10 Acute Tox. 4, H332 (EC-No.) 247-714-0 Skin Irrit. 2, H315 Eye Irrit. 2, H319 Resp. Sens. 1, H334 Skin Sens. 1, H317 Carc. 2, H351 STOT SE 3, H335 STOT RE 2, H373 Nota 2,C Zeolites (CAS-No.) 68989-22-0 1 - 5 Substance with a national occupational exposure limit Please see section 16 for the full text of any H statements referred to in this section Specific Concentration Limits Ingredient Identifier(s) Specific Concentration Limits methylenediphenyl diisocyanate (CAS-No.) 26447-40-5 (C >= 5%) Skin Irrit. 2, H315