3M Scotch-Weld Structural Plastic Adhesive DP8010 and Structural Plastic Adhesive 8010, Part A

Hazard statements (CLP)

H302, H317, H318, H330, H334, H341, H411

Code

Statements

H302

Harmful if swallowed

SECTION 2: Hazards identification

No 1272/2008 Classification of the substance or mixture

Hazard pictograms

GHS05 (Corrosion) |GHS07 (Exclamation mark) |GHS08 (Health Hazard) |GHS09 (Environment) | Ingredient CAS Nbr EC No. % by Wt Polyfunctional Aziridine 64265-57-2 264-763-3 10 - 30 Amine Borane Complex 223674-50-8 426-100-8 1 - 15

Hazard statements

H302 Harmful if swallowed. H318 Causes serious eye damage. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction. H341 Suspected of causing genetic defects. H411 Toxic to aquatic life with long lasting effects.

Prevention

P261A Avoid breathing vapours. P280B Wear protective gloves and eye/face protection. P261A Avoid breathing vapours. P280B Wear protective gloves and eye/face protection.

Response

P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTRE or doctor/physician. P342 + P311 If experiencing respiratory symptoms: Call a POISON CENTRE or doctor/physician. For containers not exceeding 125 ml the following Hazard and Precautionary statements may be used: <=125 ml Hazard statements H318 Causes serious eye damage. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction. H341 Suspected of causing genetic defects. <=125 ml Precautionary statements P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTRE or doctor/physician. P342 + P311 If experiencing respiratory symptoms: Call a POISON CENTRE or doctor/physician. 62% of the mixture consists of components of unknown acute oral toxicity.

Contains

17% of components with unknown hazards to the aquatic environment Polyfunctional aziridine is classified as Acute Tox. 2 (H330) based on dust/mist (aerosol) data. When incorporated into this product, this substance cannot become aerosolized. Based on available toxicology data and this substance's very low vapour pressure, the saturated vapour of polyfunctional aziridine is not expected to be acutely toxic. Therefore, the classification is not applicable for this material when used as intended.

2.3 Other hazards

Persons previously sensitised to amines may develop a cross-sensitisation reaction to certain other amines. This material does not contain any substances that are assessed to be a PBT or vPvB

2.1 Classification of the substance or mixture

The retained CLP Regulation (EU) No 1272/2008 as amended for Great Britain The health and environmental classifications of this material have been derived using the calculation method, except in cases where test data are available or the physical form impacts classification. Classification(s) based on test data or physical form are noted below, if applicable. CLASSIFICATION: Acute Toxicity, Category 4 - Acute Tox. 4; H302 Serious Eye Damage/Eye Irritation, Category 1 - Eye Dam. 1; H318 Respiratory Sensitization, Category 1 - Resp. Sens. 1; H334 Skin Sensitization, Category 1 - Skin Sens. 1; H317 Germ Cell Mutagenicity, Category 2 - Muta. 2; H341 Hazardous to the Aquatic Environment (Chronic), Category 2 - Aquatic Chronic 2; H411 For full text of H phrases, see Section 16. 2.2. Label elements The retained CLP Regulation (EU) No 1272/2008 as amended for Great Britain SIGNAL WORD DANGER. Symbols GHS05 (Corrosion) |GHS07 (Exclamation mark) |GHS08 (Health Hazard) |GHS09 (Environment) | Pictograms Ingredient CAS Nbr EC No. % by Wt Polyfunctional Aziridine 64265-57-2 264-763-3 10 - 30 Amine Borane Complex 223674-50-8 426-100-8 1 - 15 HAZARD STATEMENTS: H302 Harmful if swallowed. H318 Causes serious eye damage. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction. H341 Suspected of causing genetic defects. H411 Toxic to aquatic life with long lasting effects. PRECAUTIONARY STATEMENTS Prevention: P261A Avoid breathing vapours. P280B Wear protective gloves and eye/face protection. Response: P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTRE or doctor/physician. P342 + P311 If experiencing respiratory symptoms: Call a POISON CENTRE or doctor/physician. For containers not exceeding 125 ml the following Hazard and Precautionary statements may be used: <=125 ml Hazard statements H318 Causes serious eye damage. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction. H341 Suspected of causing genetic defects. <=125 ml Precautionary statements Prevention: P261A Avoid breathing vapours. P280B Wear protective gloves and eye/face protection. Response: P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTRE or doctor/physician. P342 + P311 If experiencing respiratory symptoms: Call a POISON CENTRE or doctor/physician. 62% of the mixture consists of components of unknown acute oral toxicity. Contains 17% of components with unknown hazards to the aquatic environment. Polyfunctional aziridine is classified as Acute Tox. 2 (H330) based on dust/mist (aerosol) data. When incorporated into this product, this substance cannot become aerosolized. Based on available toxicology data and this substance's very low vapour pressure, the saturated vapour of polyfunctional aziridine is not expected to be acutely toxic. Therefore, the classification is not applicable for this material when used as intended. 2.3. Other hazards Persons previously sensitised to amines may develop a cross-sensitisation reaction to certain other amines. This material does not contain any substances that are assessed to be a PBT or vPvB SECTION 3: Composition/information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Ingredient Identifier(s) % Classification according to Regulation (EC) No. 1272/2008 [CLP], as amended for GB Synthetic Rubber Oligomer Trade Secret 40 - 70 Substance not classified as hazardous Polyfunctional Aziridine (CAS-No.) 64265-57-2 10 - 30 Acute Tox. 2, H330 (EC-No.) 264-763-3 Eye Dam. 1, H318 Resp. Sens. 1, H334 Skin Sens. 1, H317 Muta. 2, H341 Aquatic Chronic 2, H411 Amine Borane Complex (CAS-No.) 223674-50-8 1 - 15 Acute Tox. 4, H302 (EC-No.) ELINCS 426- Eye Irrit. 2, H319 100-8 Skin Sens. 1, H317 Silane, trimethoxyoctyl-, hydrolysis (CAS-No.) 67762-90-7 1 - 5 Substance with a national occupational products with silica exposure limit Please see section 16 for the full text of any H statements referred to in this section For information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDS SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation Remove person to fresh air. If you feel unwell, get medical attention. Skin contact Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. Eye contact Immediately flush with large amounts of water for at least 15 minutes. Remove contact lenses if easy to do. Continue rinsing. Immediately get medical attention. If swallowed Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed