3M Scotch-Weld Structural Epoxy Adhesive EC-9100 part A

Hazard statements (CLP)

H314, H317, H318, H412

Code

Statements

H314

Causes severe skin burns and eye damage

SECTION 2: Hazards identification

No 1272/2008 Classification of the substance or mixture

Hazard pictograms

GHS05 (Corrosion) |GHS07 (Exclamation mark) | Ingredient Identifier(s) EC No. % by Wt 2-Propenenitrile, polymer with 1,3-butadiene, 1-cyano-1-methyl- 68683-29-4 10 - 20 4-oxo-4-[[2-(1-piperazinyl)ethyl]amino]butyl-terminated 1,3-Cyclohexanedimethanamine 2579-20-6 219-941-5 7 - 13 3,3'-Oxybis(ethyleneoxy)bis(propylamine) 4246-51-9 224-207-2 7 - 13 bis-[4-(2,3-epoxipropoxi)phenyl]propane 1675-54-3 216-823-5 < 10 2,4,6-tris(dimethylaminomethyl)phenol 90-72-2 202-013-9 3 - 7

Hazard statements

H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H412 Harmful to aquatic life with long lasting effects.

Prevention

P260A Do not breathe vapours. P280D Wear protective gloves, protective clothing, and eye/face protection.

Response

P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTRE or doctor/physician. P333 + P313 If skin irritation or rash occurs: Get medical advice/attention. 34% of the mixture consists of components of unknown acute oral toxicity. 34% of the mixture consists of components of unknown acute dermal toxicity.

Contains

40% of components with unknown hazards to the aquatic environment

2.3 Other hazards

Persons previously sensitised to amines may develop a cross-sensitisation reaction to certain other amines. This material does not contain any substances that are assessed to be a PBT or vPvB

2.1 Classification of the substance or mixture

The retained CLP Regulation (EU) No 1272/2008 as amended for Great Britain The health and environmental classifications of this material have been derived using the calculation method, except in cases where test data are available or the physical form impacts classification. Classification(s) based on test data or physical form are noted below, if applicable. CLASSIFICATION: Skin Corrosion/ Irritation, Category 1A - Skin Corr. 1A; H314 Serious Eye Damage/Eye Irritation, Category 1 - Eye Dam. 1; H318 Skin Sensitization, Category 1 - Skin Sens. 1; H317 Hazardous to the Aquatic Environment (Chronic), Category 3 - Aquatic Chronic 3; H412 For full text of H phrases, see Section 16. 2.2. Label elements The retained CLP Regulation (EU) No 1272/2008 as amended for Great Britain SIGNAL WORD DANGER. Symbols GHS05 (Corrosion) |GHS07 (Exclamation mark) | Pictograms Ingredient Identifier(s) EC No. % by Wt 2-Propenenitrile, polymer with 1,3-butadiene, 1-cyano-1-methyl- 68683-29-4 10 - 20 4-oxo-4-[[2-(1-piperazinyl)ethyl]amino]butyl-terminated 1,3-Cyclohexanedimethanamine 2579-20-6 219-941-5 7 - 13 3,3'-Oxybis(ethyleneoxy)bis(propylamine) 4246-51-9 224-207-2 7 - 13 bis-[4-(2,3-epoxipropoxi)phenyl]propane 1675-54-3 216-823-5 < 10 2,4,6-tris(dimethylaminomethyl)phenol 90-72-2 202-013-9 3 - 7 HAZARD STATEMENTS: H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H412 Harmful to aquatic life with long lasting effects. PRECAUTIONARY STATEMENTS Prevention: P260A Do not breathe vapours. P280D Wear protective gloves, protective clothing, and eye/face protection. Response: P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTRE or doctor/physician. P333 + P313 If skin irritation or rash occurs: Get medical advice/attention. 34% of the mixture consists of components of unknown acute oral toxicity. 34% of the mixture consists of components of unknown acute dermal toxicity. Contains 40% of components with unknown hazards to the aquatic environment. 2.3. Other hazards Persons previously sensitised to amines may develop a cross-sensitisation reaction to certain other amines. This material does not contain any substances that are assessed to be a PBT or vPvB SECTION 3: Composition/information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Ingredient Identifier(s) % Classification according to Regulation (EC) No. 1272/2008 [CLP], as amended for GB 1-Propanamine, 3,3'-[oxybis(2,1- (CAS-No.) 33970-61-5 10 - 30 Substance not classified as hazardous ethanediyloxy)]bis-, polymer with 2,2'-[(1- methylethylidene)bis(4,1- phenyleneoxymethylene)]bis[oxirane] 2-Propenenitrile, polymer with 1,3- (CAS-No.) 68683-29-4 10 - 20 Skin Irrit. 2, H315 butadiene, 1-cyano-1-methyl-4-oxo-4-[[2- Skin Sens. 1A, H317 (1-piperazinyl)ethyl]amino]butyl- terminated 1,3-Cyclohexanedimethanamine