3M Scotch-Weld Epoxy Structural Adhesive DP-100: Part A

Hazard statements (CLP)

H314, H317, H318, H412

Code

Statements

H314

Causes severe skin burns and eye damage

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 Classification of the substance or mixture

Hazard pictograms

GHS05 (Corrosion) |GHS07 (Exclamation mark) | Ingredients: Ingredient CAS Nbr EC No. % by Wt Reaction products of pentaerythritol, propoxylated 72244-98-5 701-196-7 80 - 100 and 1-chloro-2,3-epoxypropane with hydrogen sulphide 2,4,6-tris(dimethylaminomethyl)phenol 90-72-2 202-013-9 5 - 10

Hazard statements

H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H412 Harmful to aquatic life with long lasting effects.

Prevention

P260A Do not breathe vapours. P280D Wear protective gloves, protective clothing, and eye/face protection. P260A Do not breathe vapours. P280D Wear protective gloves, protective clothing, and eye/face protection.

Response

P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTRE or doctor/physician. P333 + P313 If skin irritation or rash occurs: Get medical advice/attention. For containers not exceeding 125 ml the following Hazard and Precautionary statements may be used: <=125 ml Hazard statements H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H412 Harmful to aquatic life with long lasting effects. <=125 ml Precautionary statements P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTRE or doctor/physician. P333 + P313 If skin irritation or rash occurs: Get medical advice/attention. 2% of the mixture consists of components of unknown acute dermal toxicity.

Contains

2% of components with unknown hazards to the aquatic environment

2.3 Other hazards

None known. This material does not contain any substances that are assessed to be a PBT or vPvB

2.1 Classification of the substance or mixture

CLP REGULATION (EC) No 1272/2008 The health and environmental classifications of this material have been derived using the calculation method, except in cases where test data are available or the physical form impacts classification. Classification(s) based on test data or physical form are noted below, if applicable. CLASSIFICATION: Skin Corrosion/ Irritation, Category 1C - Skin Corr. 1C; H314 Serious Eye Damage/Eye Irritation, Category 1 - Eye Dam. 1; H318 Skin Sensitization, Category 1B - Skin Sens. 1B; H317 Hazardous to the Aquatic Environment (Chronic), Category 3 - Aquatic Chronic 3; H412 For full text of H phrases, see Section 16. 2.2. Label elements CLP REGULATION (EC) No 1272/2008 SIGNAL WORD DANGER. Symbols GHS05 (Corrosion) |GHS07 (Exclamation mark) | Pictograms Ingredients: Ingredient CAS Nbr EC No. % by Wt Reaction products of pentaerythritol, propoxylated 72244-98-5 701-196-7 80 - 100 and 1-chloro-2,3-epoxypropane with hydrogen sulphide 2,4,6-tris(dimethylaminomethyl)phenol 90-72-2 202-013-9 5 - 10 HAZARD STATEMENTS: H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H412 Harmful to aquatic life with long lasting effects. PRECAUTIONARY STATEMENTS Prevention: P260A Do not breathe vapours. P280D Wear protective gloves, protective clothing, and eye/face protection. Response: P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTRE or doctor/physician. P333 + P313 If skin irritation or rash occurs: Get medical advice/attention. For containers not exceeding 125 ml the following Hazard and Precautionary statements may be used: <=125 ml Hazard statements H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H412 Harmful to aquatic life with long lasting effects. <=125 ml Precautionary statements Prevention: P260A Do not breathe vapours. P280D Wear protective gloves, protective clothing, and eye/face protection. Response: P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTRE or doctor/physician. P333 + P313 If skin irritation or rash occurs: Get medical advice/attention. 2% of the mixture consists of components of unknown acute dermal toxicity. Contains 2% of components with unknown hazards to the aquatic environment. 2.3. Other hazards None known. This material does not contain any substances that are assessed to be a PBT or vPvB SECTION 3: Composition/information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Ingredient Identifier(s) % Classification according to Regulation (EC) No. 1272/2008 [CLP] Reaction products of pentaerythritol, (CAS-No.) 72244-98-5 80 - 100 Aquatic Chronic 3, H412 propoxylated and 1-chloro-2,3- (EC-No.) 701-196-7 Skin Sens. 1B, H317 epoxypropane with hydrogen sulphide Bis[(dimethylamino)methyl]phenol (CAS-No.) 71074-89-0 <= 1.5 Acute Tox. 4, H302 (EC-No.) 275-162-0 Skin Corr. 1C, H314 2,4,6-tris(dimethylaminomethyl)phenol (CAS-No.) 90-72-2 5 - 10 Acute Tox. 4, H302 (EC-No.) 202-013-9 Skin Corr. 1C, H314 (REACH-No.) 01- Eye Dam. 1, H318 2119560597-27 Please see section 16 for the full text of any H statements referred to in this section For information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDS SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation Remove person to fresh air. If you feel unwell, get medical attention. Skin contact Immediately flush with large amounts of water for at least 15 minutes. Remove contaminated clothing. Get immediate medical attention. Wash clothing before reuse. Eye contact