3M Scotch-Weld EC-9323-2 B/A Black, (Part A)

3M United Kingdom PLC

Revision date : 2016-04-27

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GHS05 GHS07
Health risk rating 4
Safety risk rating 1
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

EC/CAS

202-013-9/90-72-2

Name of the chemical

2,4,6-tris(dimethylaminomethyl)phenol

Concentration

7-13

Listed in

EC/CAS

236-675-5/13463-67-7

Name of the chemical

Reaction mass of titanium dioxide and silver chloride

Concentration

1-5 2119489379-17

EC/CAS

205-411-0/140-31-8

Name of the chemical

2-piperazin-1-ylethylamine

Concentration

<=1

Listed in

General Information

Version

11.01

Revision date

2016-04-27

Product name

3M Scotch-Weld EC-9323-2 B/A Black, (Part A)

1.2.1 Relevant identified uses

Structural adhesive

Emergency telephone

+44 (0)1344 858 000

Icons in SDS

GHS05 GHS07

Company Information

company name

3M United Kingdom PLC

e-mail address of the competent person responsible for the Safety Data Sheet

tox.uk@mmm.com

GHS Information

Signal word

DANGER

Hazard Codes

Hazard statements (CLP)

H314, H317, H318

Hazard statements

Code

Statements

H314

Causes severe skin burns and eye damage

Section 2

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 Classification of the substance or mixture

Signal word

DANGER.

Hazard pictograms

GHS05 (Corrosion) | GHS07 (Exclamation mark) | Ingredients: Ingredient CAS Nbr % by Wt Fatty acids, C18-unsaturated, dimers, polymers with 3,3'- 68911-25-1 40 - 60 oxybis(ethyleneoxy)bis(propylamine) 3,3'-Oxybis(ethyleneoxy)bis(propylamine) 4246-51-9 10 - 30 2-Piperazin-1-ylethylamine 140-31-8 <= 1

Hazard statements

H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction.

Prevention

P260B Do not breathe dust. P280D Wear protective gloves, protective clothing, and eye/face protection.

Response

P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTRE or doctor/physician. P333 + P313 If skin irritation or rash occurs: Get medical advice/attention. 49% of the mixture consists of components of unknown acute oral toxicity. 51% of the mixture consists of components of unknown acute dermal toxicity. 92% of the mixture consists of components of unknown acute inhalation toxicity.

Contains

51% of components with unknown hazards to the aquatic environment

2.3 Other hazards

Persons previously sensitised to amines may develop a cross-sensitisation reaction to certain other amines. May cause chemical gastrointestinal burns.

2.1 Classification of the substance or mixture

CLP REGULATION (EC) No 1272/2008 CLASSIFICATION: Serious Eye Damage/Eye Irritation, Category 1 - Eye Dam. 1; H318 Skin Corrosion/Irritation, Category 1B - Skin Corr. 1B; H314 Skin Sensitization, Category 1 - Skin Sens. 1; H317 For full text of H phrases, see Section 16. 2.2. Label elements CLP REGULATION (EC) No 1272/2008 SIGNAL WORD DANGER. Symbols: GHS05 (Corrosion) | GHS07 (Exclamation mark) | Pictograms Ingredients: Ingredient CAS Nbr % by Wt Fatty acids, C18-unsaturated, dimers, polymers with 3,3'- 68911-25-1 40 - 60 oxybis(ethyleneoxy)bis(propylamine) 3,3'-Oxybis(ethyleneoxy)bis(propylamine) 4246-51-9 10 - 30 2-Piperazin-1-ylethylamine 140-31-8 <= 1 HAZARD STATEMENTS: H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. PRECAUTIONARY STATEMENTS Prevention: P260B Do not breathe dust. P280D Wear protective gloves, protective clothing, and eye/face protection. Response: P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTRE or doctor/physician. P333 + P313 If skin irritation or rash occurs: Get medical advice/attention. 49% of the mixture consists of components of unknown acute oral toxicity. 51% of the mixture consists of components of unknown acute dermal toxicity. 92% of the mixture consists of components of unknown acute inhalation toxicity. Contains 51% of components with unknown hazards to the aquatic environment. 2.3. Other hazards Persons previously sensitised to amines may develop a cross-sensitisation reaction to certain other amines. May cause chemical gastrointestinal burns. SECTION 3: Composition/information on ingredients Ingredient CAS Nbr EU Inventory % by Wt Classification Fatty acids, C18-unsaturated, dimers, 68911-25-1 40 - 60 Skin Irrit. 2, H315; Eye Dam. 1, polymers with 3,3'- H318; Skin Sens. 1, H317 (Self oxybis(ethyleneoxy)bis(propylamine) Classified) Amine Terminated Butadiene Acrylonitrile Trade Secret 10 - 30 Polymer 3,3'-Oxybis(ethyleneoxy)bis(propylamine) 4246-51-9 224-207-2 10 - 30 Skin Sens. 1, H317 (Vendor) Skin Corr. 1B, H314 (Self Classified) 2,4,6-Tris(dimethylaminomethyl)phenol 90-72-2 202-013-9 7 - 13 Acute Tox. 4, H302; Skin Irrit. 2, H315; Eye Irrit. 2, H319 (CLP) Siloxanes and Silicones, di-Me, reaction 67762-90-7 5 - 10 products with silica Bis[(dimethylamino)methyl]phenol 71074-89-0 275-162-0 1 - 5 Acute Tox. 4, H302; Skin Corr. 1B, H314 (Self Classified) Titanium dioxide (REACH Reg. No.:01- 13463-67-7 236-675-5 1 - 5 2119489379-17) 2-Piperazin-1-ylethylamine 140-31-8 205-411-0 <= 1 Acute Tox. 3, H311; Acute Tox. 4, H302; Skin Corr. 1B, H314; Skin Sens. 1B, H317; Aquatic Chronic 3, H412 (CLP) Toluene 108-88-3 203-625-9 <= 1 Flam. Liq. 2, H225; Asp. Tox. 1, H304; Skin Irrit. 2, H315; Repr. 2, H361d; STOT SE 3, H336; STOT RE 2, H373 (CLP) Aquatic Chronic 3, H412 (Vendor) Eye Irrit. 2, H319 (Self Classified) Please see section 16 for the full text of any H statements referred to in this section For information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDS SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation Remove person to fresh air. If you feel unwell, get medical attention. Skin contact Immediately flush with large amounts of water for at least 15 minutes. Remove contaminated clothing. Get immediate medical attention. Wash clothing before reuse. Eye contact Immediately flush with large amounts of water for at least 15 minutes. Remove contact lenses if easy to do. Continue

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