3M Impact Resistant Structural Adhesive Part A, PNs 07333, 57333

Hazard statements (CLP)

H302, H314, H317, H318

Code

Statements

H302

Harmful if swallowed

SECTION 2: Hazards identification

No 1272/2008 Classification of the substance or mixture

Hazard pictograms

GHS05 (Corrosion) |GHS07 (Exclamation mark) | Ingredient Identifier(s) EC No. % by Wt 3,3'-Oxybis(ethyleneoxy)bis(propylamine) 4246-51-9 224-207-2 15 - 40 2-Propenenitrile, polymer with 1,3-butadiene, 1-cyano-1-methyl- 68683-29-4 5 - 10 4-oxo-4-[[2-(1-piperazinyl)ethyl]amino]butyl-terminated 4,4'-Methylenebis(cyclohexylamine) 1761-71-3 217-168-8 5 - 9 2,4,6-tris(dimethylaminomethyl)phenol 90-72-2 202-013-9 < 3 Formaldehyde, polymer with benzenamine, hydrogenated 135108-88-2 603-894-6 < 2 m-Xylene-.alpha.alpha'.-diamine 1477-55-0 216-032-5 < 2 2-piperazin-1-ylethylamine 140-31-8 205-411-0 < 0.25 1-chloro-2,3-epoxypropane 106-89-8 203-439-8 < 0.03

Hazard statements

H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction.

Prevention

P260A Do not breathe vapours. P280D Wear protective gloves, protective clothing, and eye/face protection.

Response

P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTRE or doctor/physician. P333 + P313 If skin irritation or rash occurs: Get medical advice/attention. 37% of the mixture consists of components of unknown acute oral toxicity. 37% of the mixture consists of components of unknown acute dermal toxicity.

Contains

31% of components with unknown hazards to the aquatic environment

2.3 Other hazards

Persons previously sensitised to amines may develop a cross-sensitisation reaction to certain other amines. This material does not contain any substances that are assessed to be a PBT or vPvB

2.1 Classification of the substance or mixture

The retained CLP Regulation (EU) No 1272/2008 as amended for Great Britain The health and environmental classifications of this material have been derived using the calculation method, except in cases where test data are available or the physical form impacts classification. Classification(s) based on test data or physical form are noted below, if applicable. CLASSIFICATION: Acute Toxicity, Category 4 - Acute Tox. 4; H302 Skin Corrosion/Irritation, Category 1B - Skin Corr. 1B; H314 Serious Eye Damage/Eye Irritation, Category 1 - Eye Dam. 1; H318 Skin Sensitization, Category 1 - Skin Sens. 1; H317 For full text of H phrases, see Section 16. 2.2. Label elements The retained CLP Regulation (EU) No 1272/2008 as amended for Great Britain SIGNAL WORD DANGER. Symbols GHS05 (Corrosion) |GHS07 (Exclamation mark) | Pictograms Ingredient Identifier(s) EC No. % by Wt 3,3'-Oxybis(ethyleneoxy)bis(propylamine) 4246-51-9 224-207-2 15 - 40 2-Propenenitrile, polymer with 1,3-butadiene, 1-cyano-1-methyl- 68683-29-4 5 - 10 4-oxo-4-[[2-(1-piperazinyl)ethyl]amino]butyl-terminated 4,4'-Methylenebis(cyclohexylamine) 1761-71-3 217-168-8 5 - 9 2,4,6-tris(dimethylaminomethyl)phenol 90-72-2 202-013-9 < 3 Formaldehyde, polymer with benzenamine, hydrogenated 135108-88-2 603-894-6 < 2 m-Xylene-.alpha.alpha'.-diamine 1477-55-0 216-032-5 < 2 2-piperazin-1-ylethylamine 140-31-8 205-411-0 < 0.25 1-chloro-2,3-epoxypropane 106-89-8 203-439-8 < 0.03 HAZARD STATEMENTS: H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. PRECAUTIONARY STATEMENTS Prevention: P260A Do not breathe vapours. P280D Wear protective gloves, protective clothing, and eye/face protection. Response: P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTRE or doctor/physician. P333 + P313 If skin irritation or rash occurs: Get medical advice/attention. 37% of the mixture consists of components of unknown acute oral toxicity. 37% of the mixture consists of components of unknown acute dermal toxicity. Contains 31% of components with unknown hazards to the aquatic environment. 2.3. Other hazards Persons previously sensitised to amines may develop a cross-sensitisation reaction to certain other amines. This material does not contain any substances that are assessed to be a PBT or vPvB SECTION 3: Composition/information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Ingredient Identifier(s) % Classification according to Regulation (EC) No. 1272/2008 [CLP], as amended for GB 3,3'-Oxybis(ethyleneoxy)bis(propylamine) (CAS-No.) 4246-51-9 15 - 40 Skin Corr. 1B, H314 (EC-No.) 224-207-2 Eye Dam. 1, H318 Skin Sens. 1, H317 Epoxy Copolymer (NJTS Reg No. Trade Secret 10 - 30 Substance not classified as hazardous 04499600-7155) Acrylic copolymer Trade Secret 5 - 15 Substance not classified as hazardous Aluminium (CAS-No.) 7429-90-5 5 - 10 Flam. Sol. 1, H228 (EC-No.) 231-072-3 Water-react. 2, H261 Nota T 2-Propenenitrile, polymer with 1,3-