3M ESPE RelyX Unicem Aplicap/Maxicap Powder

Hazard statements (CLP)

H319

Code

Statements

H319

Causes serious eye irritation

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 Classification of the substance or mixture

Signal word

WARNING.

Hazard pictograms

GHS07 (Exclamation mark) |

Hazard statements

H319 Causes serious eye irritation.

Response

P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Supplemental label elements

EUH208

Contains

Disodium peroxodisulphate. May produce an allergic reaction

2.3 Other hazards

For information on hazards and safe use, please consider the corresponding sections of this document.

2.1 Classification of the substance or mixture

CLP REGULATION (EC) No 1272/2008 This product is a medical device as defined in Directive 93/42/EEC (MDD), which is invasive or used in direct physical contact with the human body, and therefore is exempt from the requirements of classification and labelling according to Regulation (EC) No. 1272/2008 (CLP; Article 1, paragraph 5). Although not required, the classification and label information, as applicable, is provided below. CLASSIFICATION: Serious Eye Damage/Eye Irritation, Category 2 - Eye Irrit. 2; H319 For full text of H phrases, see Section 16. 2.2. Label elements CLP REGULATION (EC) No 1272/2008 SIGNAL WORD WARNING. Symbols: GHS07 (Exclamation mark) | Pictograms HAZARD STATEMENTS: H319 Causes serious eye irritation. PRECAUTIONARY STATEMENTS Response: P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. SUPPLEMENTAL INFORMATION Supplemental Hazard Statements: EUH208 Contains Disodium peroxodisulphate. May produce an allergic reaction. 2.3. Other hazards For information on hazards and safe use, please consider the corresponding sections of this document. SECTION 3: Composition/information on ingredients Ingredient CAS Nbr EC No. REACH % by Wt Classification Registration No. OXIDE GLASS CHEMICALS (non- 65997-17-3 266-046-0 80 - 95 Substance with a fibrous) Community level exposure limit in the workplace Disodium peroxodisulphate 7775-27-1 231-892-1 < 1 Ox. Sol. 3, H272; Skin Irrit. 2, H315; Eye Irrit. 2, H319; Resp. Sens. 1, H334; Skin Sens. 1, H317; STOT SE 3, H335 Acute Tox. 4, H302 Titanium dioxide 13463-67-7 236-675-5 < 0.5 Substance with a Community level exposure limit in the workplace 2-Propenoic acid, 2-methyl-, 3- 122334-95- 310-178-4 1 - 10 Substance not classified as (trimethoxysilyl)propyl ester, reaction 6 hazardous products with vitreous silica Calcium Hydroxide 1305-62-0 215-137-3 < 5 Skin Corr. 1C, H314 1-benzyl-5-phenyl barbituric acid 72846-00-5 276-940-2 1 - 5 Substance not classified as hazardous Please see section 16 for the full text of any H statements referred to in this section For information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDS SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation Remove person to fresh air. If you feel unwell, get medical attention. Skin contact Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. Eye contact Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical attention. If swallowed Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1 Information on toxicological effects 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Extinguishing media Material will not burn. 5.2. Special hazards arising from the substance or mixture None inherent in this product. Hazardous Decomposition or By-Products Substance Condition None known. During combustion. 5.3. Advice for fire-fighters No special protective actions for fire-fighters are anticipated. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapours, in accordance with good industrial hygiene practice. 6.2. Environmental precautions Avoid release to the environment. 6.3. Methods and material for containment and cleaning up Collect as much of the spilled material as possible. Place in a closed container approved for transportation by appropriate authorities. Clean up residue. Seal the container. Dispose of collected material as soon as possible. 6.4. Reference to other sections Refer to Section 8 and Section 13 for more information SECTION 7: Handling and storage 7.1. Precautions for safe handling Do not handle until all safety precautions have been read and understood. Avoid breathing dust/fume/gas/mist/vapours/spray. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse. Do not get in eyes. Use personal protective equipment (eg. gloves, respirators…) as required. A no-touch technique is recommended. If skin contact occurs, wash skin with soap and water. If product contacts glove, remove and discard glove, wash hands immediately with soap and water and then re-glove. 7.2. Conditions for safe storage including any incompatibilities