3M ESPE RELYX TEMP NE NP CATALYST PASTE

Hazard statements (CLP)

H319, H412

Code

Statements

H319

Causes serious eye irritation

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 Classification of the substance or mixture

Signal word

WARNING.

Hazard pictograms

GHS07 (Exclamation mark) |

Hazard statements

H319 Causes serious eye irritation. H412 Harmful to aquatic life with long lasting effects.

Response

P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Disposal

P501 Dispose of contents/container in accordance with applicable local/regional/national/international regulations.

2.3 Other hazards

For information on hazards and safe use, please consider the corresponding sections of this document.

2.1 Classification of the substance or mixture

CLP REGULATION (EC) No 1272/2008 This product is a medical device as defined in Directive 93/42/EEC (MDD), which is invasive or used in direct physical contact with the human body, and therefore is exempt from the requirements of classification and labelling according to Regulation (EC) No. 1272/2008 (CLP; Article 1, paragraph 5). Although not required, the classification and label information, as applicable, is provided below. CLASSIFICATION: Serious Eye Damage/Eye Irritation, Category 2 - Eye Irrit. 2; H319 Hazardous to the Aquatic Environment (Chronic), Category 3 - Aquatic Chronic 3; H412 For full text of H phrases, see Section 16. 2.2. Label elements CLP REGULATION (EC) No 1272/2008 SIGNAL WORD WARNING. Symbols: GHS07 (Exclamation mark) | Pictograms HAZARD STATEMENTS: H319 Causes serious eye irritation. H412 Harmful to aquatic life with long lasting effects. PRECAUTIONARY STATEMENTS Response: P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Disposal: P501 Dispose of contents/container in accordance with applicable local/regional/national/international regulations. 2.3. Other hazards For information on hazards and safe use, please consider the corresponding sections of this document. SECTION 3: Composition/information on ingredients Ingredient CAS Nbr EC No. REACH % by Wt Classification Registration No. Rosin, reaction products with acrylic 83137-13-7 280-192-2 60 - 70 Substance not classified as acid hazardous Nonanoic Acid 112-05-0 203-931-2 30 - 40 Skin Irrit. 2, H315; Eye Irrit. 2, H319; Aquatic Chronic 3, H412 Silanamine, 1,1,1-trimethyl-N- 68909-20-6 272-697-1 1 - 5 Substance not classified as (trimethylsilyl)-, hydrolysis products hazardous with silica Please see section 16 for the full text of any H statements referred to in this section For information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDS SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation Remove person to fresh air. If you feel unwell, get medical attention. Skin contact Wash with soap and water. If signs/symptoms develop, get medical attention. Eye contact Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical attention. If swallowed Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1 Information on toxicological effects 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Extinguishing media In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish. 5.2. Special hazards arising from the substance or mixture None inherent in this product. Hazardous Decomposition or By-Products Substance Condition Formaldehyde During combustion. Carbon monoxide. During combustion. Carbon dioxide. During combustion. 5.3. Advice for fire-fighters No special protective actions for fire-fighters are anticipated. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapours, in accordance with good industrial hygiene practice. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. 6.3. Methods and material for containment and cleaning up Collect as much of the spilled material as possible. Place in a closed container approved for transportation by appropriate authorities. Clean up residue. Seal the container. Dispose of collected material as soon as possible. 6.4. Reference to other sections Refer to Section 8 and Section 13 for more information SECTION 7: Handling and storage 7.1. Precautions for safe handling Avoid eye contact. Avoid prolonged or repeated skin contact. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid release to the environment. 7.2. Conditions for safe storage including any incompatibilities Store away from heat. 7.3. Specific end use(s) See information in Section 7.1 and 7.2 for handling and storage recommendations. See Section 8 for exposure controls and personal protection recommendations. SECTION 8: Exposure controls/personal protection 8.1 Control parameters Occupational exposure limits No occupational exposure limit values exist for any of the components listed in Section 3 of this Safety Data Sheet. Biological limit values No biological limit values exist for any of the components listed in Section 3 of this safety data sheet.