3M ESPE Protemp 4 Calalyst Paste

Hazard statements (CLP)

H412

Code

Statements

H412

Harmful to aquatic life with long lasting effects

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 Classification of the substance or mixture

Hazard statements

H412 Harmful to aquatic life with long lasting effects.

Disposal

P501 Dispose of contents/container in accordance with applicable local/regional/national/international regulations.

Supplemental label elements

EUH208

Contains

Tert-butyl 3,5,5-trimethylperoxyhexanoate. May produce an allergic reaction.

2.3 Other hazards

For information on hazards and safe use, please consider the corresponding sections of this document.

2.1 Classification of the substance or mixture

CLP REGULATION (EC) No 1272/2008 This product is a medical device as defined in Directive 93/42/EEC (MDD), which is invasive or used in direct physical contact with the human body, and therefore is exempt from the requirements of classification and labelling according to Regulation (EC) No. 1272/2008 (CLP; Article 1, paragraph 5). Although not required, the classification and label information, as applicable, is provided below. CLASSIFICATION: Hazardous to the Aquatic Environment (Chronic), Category 3 - Aquatic Chronic 3; H412 For full text of H phrases, see Section 16. 2.2. Label elements CLP REGULATION (EC) No 1272/2008 HAZARD STATEMENTS: H412 Harmful to aquatic life with long lasting effects. PRECAUTIONARY STATEMENTS Disposal: P501 Dispose of contents/container in accordance with applicable local/regional/national/international regulations. SUPPLEMENTAL INFORMATION Supplemental Hazard Statements: EUH208 Contains Tert-butyl 3,5,5-trimethylperoxyhexanoate. May produce an allergic reaction. 2.3. Other hazards For information on hazards and safe use, please consider the corresponding sections of this document. SECTION 3: Composition/information on ingredients Ingredient CAS Nbr EU Inventory % by Wt Classification 2,2'-[(1-methylethylidene)bis(4,1- 19224-29-4 242-895-2 70 - 80 phenyleneoxy)]bisethydiacetate (REACH Reg. No.:01-2120104948-51) 1-benzyl-5-phenyl barbituric acid 72846-00-5 276-940-2 5 - 15 Silanamine, 1,1,1-trimethyl-N- 68909-20-6 272-697-1 5 - 15 (trimethylsilyl)-, hydrolysis products with silica Tert-butyl 3,5,5-trimethylperoxyhexanoate 13122-18-4 236-050-7 < 0.4 Org. Perox. CD, H242; Aquatic Acute 1, H400,M=1; Aquatic Chronic 1, H410,M=1 (Vendor) Skin Sens. 1B, H317 (Self Classified) Please see section 16 for the full text of any H statements referred to in this section For information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDS SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation Remove person to fresh air. If you feel unwell, get medical attention. Skin contact Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. Eye contact Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention. If swallowed Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1 Information on toxicological effects 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Extinguishing media In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish. 5.2. Special hazards arising from the substance or mixture None inherent in this product. Hazardous Decomposition or By-Products Substance Condition Carbon monoxide. During combustion. Carbon dioxide. During combustion. Irritant vapours or gases. During combustion. 5.3. Advice for fire-fighters No special protective actions for fire-fighters are anticipated. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapours, in accordance with good industrial hygiene practice. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.