3M ESPE Adper Prompt Part A

Hazard statements (CLP)

H314, H317, H318, H334

Code

Statements

H314

Causes severe skin burns and eye damage

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 Classification of the substance or mixture

Hazard pictograms

GHS05 (Corrosion) | GHS08 (Health Hazard) | Ingredients: Ingredient CAS Nbr EC No. % by Wt (1-methylethylidene)bis[4,1-phenyleneoxy(2- 1565-94-2 216-367-7 10 - 15 hydroxy-3,1-propanediyl)] bismethacrylate Phosphine oxide, (butylphenyl)bis(2,6- 117310-64-2 < 0.5 dichlorobenzoyl)- Mequinol 150-76-5 205-769-8 < 0.2

Hazard statements

H314 Causes severe skin burns and eye damage. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction.

Prevention

P260A Do not breathe vapours. P280D Wear protective gloves, protective clothing, and eye/face protection.

Response

P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P303 + P361 + P353A IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTRE or doctor/physician. Notes on labelling This product is classified as H314 and H318 based on the pH.

2.3 Other hazards

For information on hazards and safe use, please consider the corresponding sections of this document.

2.1 Classification of the substance or mixture

CLP REGULATION (EC) No 1272/2008 This product is a medical device as defined in Directive 93/42/EEC (MDD), which is invasive or used in direct physical contact with the human body, and therefore is exempt from the requirements of classification and labelling according to Regulation (EC) No. 1272/2008 (CLP; Article 1, paragraph 5). Although not required, the classification and label information, as applicable, is provided below. CLASSIFICATION: Serious Eye Damage/Eye Irritation, Category 1 - Eye Dam. 1; H318 Skin Corrosion/Irritation, Category 1 - Skin Corr. 1; H314 Respiratory Sensitization, Category 1A - Resp. Sens. 1A; H334 Skin Sensitization, Category 1B - Skin Sens. 1B; H317 For full text of H phrases, see Section 16. 2.2. Label elements CLP REGULATION (EC) No 1272/2008 SIGNAL WORD DANGER. Symbols: GHS05 (Corrosion) | GHS08 (Health Hazard) | Pictograms Ingredients: Ingredient CAS Nbr EC No. % by Wt (1-methylethylidene)bis[4,1-phenyleneoxy(2- 1565-94-2 216-367-7 10 - 15 hydroxy-3,1-propanediyl)] bismethacrylate Phosphine oxide, (butylphenyl)bis(2,6- 117310-64-2 < 0.5 dichlorobenzoyl)- Mequinol 150-76-5 205-769-8 < 0.2 HAZARD STATEMENTS: H314 Causes severe skin burns and eye damage. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction. PRECAUTIONARY STATEMENTS Prevention: P260A Do not breathe vapours. P280D Wear protective gloves, protective clothing, and eye/face protection. Response: P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P303 + P361 + P353A IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTRE or doctor/physician. Notes on labelling This product is classified as H314 and H318 based on the pH. 2.3. Other hazards For information on hazards and safe use, please consider the corresponding sections of this document. SECTION 3: Composition/information on ingredients Ingredient CAS Nbr EC No. REACH % by Wt Classification Registration No. 2-Propenoic acid, 2-methyl-, 2- 1187441- 70 - 90 Substance not classified as hydroxyethyl ester, reaction products 10-6 hazardous with phosphorus oxide (P2O5) (1-methylethylidene)bis[4,1- 1565-94-2 216-367-7 10 - 15 Skin Sens. 1B, H317 phenyleneoxy(2-hydroxy-3,1- propanediyl)] bismethacrylate dl-bornane-2,3-dione 10373-78-1 233-814-1 < 2 Substance not classified as hazardous Ethyl 4-dimethylaminobenzoate 10287-53-3 233-634-3 < 2 Substance not classified as hazardous Phosphine oxide, (butylphenyl)bis(2,6- 117310-64- < 0.5 Skin Sens. 1A, H317; dichlorobenzoyl)- 2 Aquatic Acute 1, H400,M=1; Aquatic Chronic 1, H410,M=1 Mequinol 150-76-5 205-769-8 01- < 0.2 Acute Tox. 4, H302; Eye 2119541813- Irrit. 2, H319; Skin Sens. 1, 40 H317 Aquatic Chronic 3, H412 Please see section 16 for the full text of any H statements referred to in this section For information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDS SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation Remove person to fresh air. If you feel unwell, get medical attention. Skin contact Immediately flush with large amounts of water for at least 15 minutes. Remove contaminated clothing. Get immediate medical attention. Wash clothing before reuse. Eye contact