KETAC-FIL PLUS APLICAP / KETAC FIL PLUS POWDER

SECTION 2: Hazards identification

29 CFR 1910.1200) 3.1 EMERGENCY OVERVIEW Specific Physical Form: Fine Powder (less than 10 microns) Odor, Color, Grade: Different colored, odorless powders General Physical Form: Solid Immediate health, physical, and environmental hazards: No immediate health, physical, or environmental hazards are anticipated.

Potential health effects

Eye Contact: Mechanical eye irritation: Signs/symptoms may include pain, redness, tearing and corneal abrasion. Skin Contact: Contact with the skin during product use is not expected to result in significant irritation. Inhalation: Upper Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Ingestion: Ingestion may cause: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, nausea, diarrhea and vomiting. SECTION 4: FIRST AID MEASURES 4.1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed. Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention. Skin Contact: No need for first aid is anticipated. Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention. If Swallowed: Do not induce vomiting. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get immediate medical attention. SECTION 5: FIRE FIGHTING MEASURES 5.1 FLAMMABLE PROPERTIES Autoignition temperature No Data Available Flash Point Not Applicable Flammable Limits - LEL Not Applicable Flammable Limits - UEL Not Applicable 5.2 EXTINGUISHING MEDIA Non-combustible. Choose material suitable for surrounding fire. Material will not burn. 5.3 PROTECTION OF FIRE FIGHTERS Special Fire Fighting Procedures: Wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head. Unusual Fire and Explosion Hazards: No unusual fire or explosion hazards are anticipated. Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information. SECTION 6: ACCIDENTAL RELEASE MEASURES Accidental Release Measures: Observe precautions from other sections. Call 3M- HELPS line (1-800-364-3577) for more information on handling and managing the spill. Collect as much of the spilled material as possible. Clean up residue with detergent and water. Collect the resulting residue containing solution. Place in a closed container approved for transportation by appropriate authorities. In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations. SECTION 7: HANDLING AND STORAGE 7.1 HANDLING Avoid eye contact. Avoid prolonged or repeated skin contact.

Storage

Not applicable. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 ENGINEERING CONTROLS Not applicable. 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) 8.2.1 Eye/Face Protection Avoid eye contact. The following eye protection(s) are recommended: Safety Glasses with side shields. 8.2.2 Skin Protection Avoid prolonged or repeated skin contact. Gloves not normally required. 8.2.3 Respiratory Protection Under normal use conditions, airborne exposures are not expected to be significant enough to require respiratory protection. 8.2.4 Prevention of Swallowing Do not ingest. 8.3 EXPOSURE GUIDELINES Ingredient Authority Type Limit

Additional information

GLASS POWDER 3M TWA - as dust 10 mg/m3 SOURCE OF EXPOSURE LIMIT DATA: ACGIH: American Conference of Governmental Industrial Hygienists CMRG: Chemical Manufacturer Recommended Guideline

TOXICOLOGICAL INFORMATION

Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components. Not Determined CHEMICAL FATE INFORMATION Not Determined SECTION 13: DISPOSAL CONSIDERATIONS Waste Disposal Method: Dispose of waste product in a facility permitted to accept chemical waste. EPA Hazardous Waste Number (RCRA): Not regulated Since regulations vary, consult applicable regulations or authorities before disposal. SECTION 14:TRANSPORT INFORMATION ID Number(s): LE-FSFD-5501-1, PP-ESPE-5500-1 Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this material. SECTION 15: REGULATORY INFORMATION US FEDERAL REGULATIONS Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - No STATE REGULATIONS Contact 3M for more information. CHEMICAL INVENTORIES All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS), or are exempt polymers whose monomers are listed on EINECS. This material contains one or more substances not listed on the TSCA Inventory. Commercial use of this material is regulated by the FDA. Contact 3M for more information. INTERNATIONAL REGULATIONS Contact 3M for more information. This MSDS has been prepared to meet the U.S.

Further information

NFPA Hazard Classification Health 0 Flammability 0 Reactivity 0 Special None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. No revision information is available. DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M. 3M MSDSs are available at www.3M.com SECTION 1: PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: KETAC-FIL PLUS APLICAP / KETAC FIL PLUS LIQUID MANUFACTURER: 3M DIVISION: 3M ESPE Dental Products ADDRESS: 3M Center St. Paul, MN 55144-1000 EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours) Issue date 12/04/2002 Supercedes Date: 11/30/2001 Document Group: 16-2700-9 Product Use: Limitations on Use: For use only by dental professionals Specific Use: Dental restorative SECTION 2: INGREDIENTS Ingredient C.A.S. No. % by Wt WATER 7732-18-5 60 - 65 POLYETHYLENE POLYCARBONIC ACID 29132-58-9 30 - 40 TARTARIC ACID 87-69-4 5 - 10 SECTION 3: HAZARDS IDENTIFICATION 3.1 EMERGENCY OVERVIEW Specific Physical Form: Liquid Odor, Color, Grade: Colorless, slightly acidic odor General Physical Form: Liquid Immediate health, physical, and environmental hazards: No immediate health, physical or environmental hazards are expected. 3.2 POTENTIAL HEALTH EFFECTS Eye Contact: Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Skin Contact: Prolonged or repeated exposure may cause: Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Inhalation: No health effects are expected. Ingestion: Ingestion may cause: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, nausea, diarrhea and vomiting.