3M Scotch-Weld Structural Epoxy Adhesive EC-9100 part A

Hazard statements (CLP)

H314, H317, H318, H412

Code

Statements

H314

Causes severe skin burns and eye damage

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 Classification of the substance or mixture

Hazard pictograms

GHS05 (Corrosion) |GHS07 (Exclamation mark) | Ingredients: Ingredient C.A.S. No. EC No. % by Wt 2-PROPENENITRILE, POLYMER WITH 1,3- 68683-29-4 10 - 20 BUTADIENE, 1-CYANO-1-METHYL-4-OXO-4- [[2-(1-PIPERAZINYL)ETHYL]AMINO]BUTYL- TERMINATED 1,3-Cyclohexanedimethanamine 2579-20-6 219-941-5 7 - 13 BIS(3-AMINOPROPYL) ETHER OF DIETHYLENE 4246-51-9 224-207-2 7 - 13 GLYCOL Bisphenol A Diglycidyl Ether 1675-54-3 216-823-5 < 10 Tris(2,4,6-dimethylaminomonomethyl)phenol 90-72-2 202-013-9 3 - 7

Hazard statements

H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H412 Harmful to aquatic life with long lasting effects.

Prevention

P260A Do not breathe vapors. P280D Wear protective gloves, protective clothing, eye protection, and face protection.

Response

P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER or doctor. P333 + P313 If skin irritation or rash occurs: Get medical attention. 34% of the mixture consists of components of unknown acute oral toxicity. 34% of the mixture consists of components of unknown acute dermal toxicity.

Contains

40% of components with unknown hazards to the aquatic environment

2.3 Other hazards

Persons previously sensitized to amines may develop a cross-sensitization reaction to certain other amines. This material does not contain any substances that are assessed to be a PBT or vPvB

2.1 Classification of the substance or mixture

CLP REGULATION (EC) No 1272/2008 The health and environmental classifications of this material have been derived using the calculation method, except in cases where test data are available or the physical form impacts classification. Classification(s) based on test data or physical form are noted below, if applicable. CLASSIFICATION: Skin Corrosion/Irritation, Category 1A - Skin Corr. 1A; H314 Serious Eye Damage/Eye Irritation, Category 1 - Eye Dam. 1; H318 Skin Sensitization, Category 1 - Skin Sens. 1; H317 Hazardous to the Aquatic Environment (Chronic), Category 3 - Aquatic Chronic 3; H412 For full text of H phrases, see Section 16. 2.2. Label elements CLP REGULATION (EC) No 1272/2008 SIGNAL WORD Danger Symbols: GHS05 (Corrosion) |GHS07 (Exclamation mark) | Pictograms Ingredients: Ingredient C.A.S. No. EC No. % by Wt 2-PROPENENITRILE, POLYMER WITH 1,3- 68683-29-4 10 - 20 BUTADIENE, 1-CYANO-1-METHYL-4-OXO-4- [[2-(1-PIPERAZINYL)ETHYL]AMINO]BUTYL- TERMINATED 1,3-Cyclohexanedimethanamine 2579-20-6 219-941-5 7 - 13 BIS(3-AMINOPROPYL) ETHER OF DIETHYLENE 4246-51-9 224-207-2 7 - 13 GLYCOL Bisphenol A Diglycidyl Ether 1675-54-3 216-823-5 < 10 Tris(2,4,6-dimethylaminomonomethyl)phenol 90-72-2 202-013-9 3 - 7 HAZARD STATEMENTS: H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H412 Harmful to aquatic life with long lasting effects. PRECAUTIONARY STATEMENTS Prevention: P260A Do not breathe vapors. P280D Wear protective gloves, protective clothing, eye protection, and face protection. Response: P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER or doctor. P333 + P313 If skin irritation or rash occurs: Get medical attention. 34% of the mixture consists of components of unknown acute oral toxicity. 34% of the mixture consists of components of unknown acute dermal toxicity. Contains 40% of components with unknown hazards to the aquatic environment. 2.3. Other hazards Persons previously sensitized to amines may develop a cross-sensitization reaction to certain other amines. This material does not contain any substances that are assessed to be a PBT or vPvB SECTION 3: Composition/information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Ingredient Identifier(s) % Classification according to Regulation (EC) No. 1272/2008 [CLP] 1-Propanamine, 3,3'-[oxybis(2,1- (CAS-No.) 10 - 30 Substance not classified as hazardous ethanediyloxy)]bis-, polymer with 2,2'-[(1- 33970-61-5 methylethylidene)bis(4,1- phenyleneoxymethylene)]bis[oxirane] 2-PROPENENITRILE, POLYMER WITH (CAS-No.) 10 - 20 Skin Irrit. 2, H315 1,3-BUTADIENE, 1-CYANO-1-METHYL- 68683-29-4 Skin Sens. 1A, H317 4-OXO-4-[[2-(1- PIPERAZINYL)ETHYL]AMINO]BUTYL- TERMINATED 1,3-Cyclohexanedimethanamine