Structural Adhesive P/N 08122

Hazard statements (CLP)

H315, H317, H319, H411

Code

Statements

H315

Causes skin irritation

SECTION 2: Hazards identification

Regulation (EC) No. 1272/2008 Classification of the substance or mixture

Signal word

WARNING.

Hazard pictograms

GHS07 (Exclamation mark) |GHS09 (Environment) | Ingredients: Ingredient CAS Nbr EC No. % by Wt bis-[4-(2,3-epoxipropoxi)phenyl]propane 1675-54-3 216-823-5 60 - 90 2,2'-[(1-Methylethylidene)bis[4,1-phenyleneoxy[1- 71033-08-4 275-143-7 5 - 15 (butoxymethyl)ethylene]oxymethylene]]bisoxirane

Hazard statements

H319 Causes serious eye irritation. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H411 Toxic to aquatic life with long lasting effects.

Prevention

P280E Wear protective gloves. P273 Avoid release to the environment. P280E Wear protective gloves.

Response

P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333 + P313 If skin irritation or rash occurs: Get medical advice/attention. P333 + P313 If skin irritation or rash occurs: Get medical advice/attention. 13% of the mixture consists of components of unknown acute oral toxicity.

Disposal

P501 Dispose of contents/container in accordance with applicable local/regional/national/international regulations. For containers not exceeding 125 ml the following Hazard and Precautionary statements may be used: <=125 ml Hazard statements H317 May cause an allergic skin reaction. <=125 ml Precautionary statements

Contains

27% of components with unknown hazards to the aquatic environment

2.1 Classification of the substance or mixture

CLP REGULATION (EC) No 1272/2008 The health and environmental classifications of this material have been derived using the calculation method, except in cases where test data are available or the physical form impacts classification. Classification(s) based on test data or physical form are noted below, if applicable. CLASSIFICATION: Serious Eye Damage/Eye Irritation, Category 2 - Eye Irrit. 2; H319 Skin Corrosion/Irritation, Category 2 - Skin Irrit. 2; H315 Skin Sensitization, Category 1 - Skin Sens. 1; H317 Hazardous to the Aquatic Environment (Chronic), Category 2 - Aquatic Chronic 2; H411 For full text of H phrases, see Section 16. 2.2. Label elements CLP REGULATION (EC) No 1272/2008 SIGNAL WORD WARNING. Symbols: GHS07 (Exclamation mark) |GHS09 (Environment) | Pictograms Ingredients: Ingredient CAS Nbr EC No. % by Wt bis-[4-(2,3-epoxipropoxi)phenyl]propane 1675-54-3 216-823-5 60 - 90 2,2'-[(1-Methylethylidene)bis[4,1-phenyleneoxy[1- 71033-08-4 275-143-7 5 - 15 (butoxymethyl)ethylene]oxymethylene]]bisoxirane HAZARD STATEMENTS: H319 Causes serious eye irritation. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H411 Toxic to aquatic life with long lasting effects. PRECAUTIONARY STATEMENTS Prevention: P280E Wear protective gloves. P273 Avoid release to the environment. Response: P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333 + P313 If skin irritation or rash occurs: Get medical advice/attention. Disposal: P501 Dispose of contents/container in accordance with applicable local/regional/national/international regulations. For containers not exceeding 125 ml the following Hazard and Precautionary statements may be used: <=125 ml Hazard statements H317 May cause an allergic skin reaction. <=125 ml Precautionary statements Prevention: P280E Wear protective gloves. Response: P333 + P313 If skin irritation or rash occurs: Get medical advice/attention. 13% of the mixture consists of components of unknown acute oral toxicity. Contains 27% of components with unknown hazards to the aquatic environment. 2.3. Other hazards Contains a substance that meets the criteria for PBT according to Regulation (EC) No 1907/2006, Annex XIII Contains a substance that meets the criteria for vPvB according to Regulation (EC) No 1907/2006, Annex XIII SECTION 3: Composition/information on ingredients Ingredient CAS Nbr EC No. REACH % by Classification Registration Wt No. bis-[4-(2,3-epoxipropoxi)phenyl]propane 1675-54-3 216-823- 01- 60 - Skin Irrit. 2, H315; Eye 5 2119456619- 90 Irrit. 2, H319; Skin 26 Sens. 1, H317 Aquatic Chronic 2, H411 2,2'-[(1-Methylethylidene)bis[4,1- 71033-08- 275-143- 5 - Skin Irrit. 2, H315; Skin phenyleneoxy[1- 4 7 15 Sens. 1, H317 (butoxymethyl)ethylene]oxymethylene]]bisoxirane COPOLYMER (BD/STY/MMA) Non- 7 - Substance not classified Material 13 as hazardous [3-(2,3-Epoxypropoxy)propyl] trimethoxysilane 2530-83-8 219-784- 01- 1 - 5 Eye Dam. 1, H318 2 2119513212- 58 Siloxanes and Silicones, di-Me, reaction products 67762-90- 1 - 5 Substance with an with silica 7 occupational exposure limit Please see section 16 for the full text of any H statements referred to in this section For information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDS SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation Remove person to fresh air. If you feel unwell, get medical attention. Skin contact Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. Eye contact Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical attention. If swallowed Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1 Information on toxicological effects 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Extinguishing media In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish. 5.2. Special hazards arising from the substance or mixture None inherent in this product. Hazardous Decomposition or By-Products Substance Condition Aldehydes. During combustion. Carbon monoxide During combustion. Carbon dioxide. During combustion.